CN1566289A - Production process for lignin alcohol fuel - Google Patents
Production process for lignin alcohol fuel Download PDFInfo
- Publication number
- CN1566289A CN1566289A CN 03134347 CN03134347A CN1566289A CN 1566289 A CN1566289 A CN 1566289A CN 03134347 CN03134347 CN 03134347 CN 03134347 A CN03134347 A CN 03134347A CN 1566289 A CN1566289 A CN 1566289A
- Authority
- CN
- China
- Prior art keywords
- liquid
- ethanol
- lignin
- pulping
- raffinate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 229920005610 lignin Polymers 0.000 title claims abstract description 14
- 239000000446 fuel Substances 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 239000007788 liquid Substances 0.000 claims abstract description 23
- 238000004537 pulping Methods 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000010411 cooking Methods 0.000 claims abstract 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 239000011575 calcium Substances 0.000 claims 2
- 239000001639 calcium acetate Substances 0.000 claims 2
- 229960005147 calcium acetate Drugs 0.000 claims 2
- 235000011092 calcium acetate Nutrition 0.000 claims 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims 1
- 239000000706 filtrate Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 7
- 239000006227 byproduct Substances 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 2
- 238000005265 energy consumption Methods 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 238000009835 boiling Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
Landscapes
- Liquid Carbonaceous Fuels (AREA)
Abstract
本发明涉及一种木素醇燃料制造工艺，尤其涉及一种用乙醇法造纸制浆所得蒸煮残液为主要原料，制作木素醇这种液体清洁燃料的工艺。该发明解决了以往乙醇法制浆蒸煮残液处理过程中，存在的乙醇回收能量消耗高、副产品木质素的高效利用技术尚不成熟等问题，促进制浆企业经济效益的进一步提高，并对缓解矿物能源日趋紧缺的局面有帮助，因而具有良好的社会效益和经济效益。The invention relates to a lignin alcohol fuel manufacturing process, in particular to a process for producing lignin alcohol as a liquid clean fuel by using the cooking raffinate obtained from ethanol papermaking and pulping as the main raw material. The invention solves the problems of high energy consumption of ethanol recovery and immature technology of high-efficiency utilization of by-product lignin in the process of processing raffinate of ethanol pulping in the past, and promotes the further improvement of the economic benefits of pulping enterprises, and alleviates the The situation of increasing shortage of mineral energy is helpful, so it has good social and economic benefits.
Description
One, affiliated technical field
The present invention relates to a kind of lignin alcohol fuel manufacturing operation, relating in particular to a kind of is main raw material with Ethanol Method paper-making pulping gained boiling raffinate, makes a kind of technology of liquid cleaning fuel.Belong to the pulping technology for paper-making field.
Two, background technology
The ethanol pulping technology is considered to one of clean paper making pulping technique of potentialization.Yet this technology will use a large amount of aqueous ethanolic solutions to dissolve organic substances such as xylogen in the fibrous material, when carrying out fiber separation, produces a large amount of pulping and digesting raffinates.Exist the ethanol recovered energy to consume problems such as efficient technique of rainwater utilization high, the byproduct xylogen is still immature in the boiling raffinate treating processes in the past, influenced the further raising of slurrying business economic benefit.
Three, summary of the invention
Consume problems such as efficient technique of rainwater utilization high, the byproduct xylogen is still immature in order to solve the ethanol recovered energy that exists in the ethanol pulping boiling raffinate treating processes, the invention provides one and apply mechanically the pulping and digesting raffinate as main raw material, make a kind of novel clean fuel liquid that is called lignin alcohol, no longer carry out the lock out operation of alcoholic acid recovery and xylogen.Can effectively improve the ethanol pulping economic benefit of enterprises.
The present invention solves the technology that its technical problem adopts: the Ethanol Method paper-making pulping raffinate (temperature is at 75～200 ℃) in the storage tank is pumped in the settler, and add CaO or Ca (HO)
2, make the liquid pH value between 6.5～8; Add 3～35% (in liquid mass) xylogen or alkali lignins again, and an amount of additive and stirring fully, be incubated 20～60 minutes, make the acetate neutralization in the raw material and generate lime acetate; Then, it is cooled to room temperature, left standstill 12～48 hours, make most of insoluble substance precipitation and separation; At last clear liquid is filtered or centrifugation, remove trickle solid matters such as wherein contained lime acetate, fiber fines and dust, the gained homogeneous liquid is the liquid lignin alcohol fuel of cleaning.
The invention has the beneficial effects as follows: the ethanol pulping raffinate changes into New-type fuel through processing, can realize the comprehensive utilization of fibrous material; And need not reclaim ethanol, energy expenditure is low; Simplify technological process and equipment, reduced the slurrying production cost, helpful to alleviating fossil energy situation in short supply day by day, thereby have good social benefit and economic benefit.
Four, embodiment
Ethanol Method paper-making pulping raffinate (temperature is at 75～200 ℃) in the storage tank is pumped in the settler, and add CaO or Ca (HO)
2, make the liquid pH value between 6.5～7.5; Add 3～35% (in liquid mass) xylogen and an amount of additive and stirring fully again, be incubated 20～60 minutes, make the acetate neutralization in the raw material and generate lime acetate; Then, it is cooled to room temperature, left standstill 12～48 hours, make most of insoluble substance precipitation and separation; At last clear liquid is filtered, remove trickle solid matters such as wherein contained lime acetate, fiber fines and dust, the gained homogeneous liquid is the lignin alcohol liquid fuel of cleaning.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03134347 CN1566289A (en) | 2003-07-03 | 2003-07-03 | Production process for lignin alcohol fuel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03134347 CN1566289A (en) | 2003-07-03 | 2003-07-03 | Production process for lignin alcohol fuel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1566289A true CN1566289A (en) | 2005-01-19 |
Family
ID=34470170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03134347 Pending CN1566289A (en) | 2003-07-03 | 2003-07-03 | Production process for lignin alcohol fuel |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1566289A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101932670A (en) * | 2007-08-14 | 2010-12-29 | 卑尔根技术交易股份公司 | One-step conversion of solid lignin to liquid products |
| CN102154036A (en) * | 2011-03-10 | 2011-08-17 | 杜良才 | Method for producing boiler fuel by utilizing papermaking black liquid |
| CN102182095A (en) * | 2011-03-31 | 2011-09-14 | 陕西科技大学 | Method for recycling ethanol pulping waste liquor |
| WO2011131144A1 (en) * | 2010-04-23 | 2011-10-27 | Qin Caidong | Mixed fuel containing lignin, production process thereof and fuel injector using the same |
| CN102277760A (en) * | 2011-08-30 | 2011-12-14 | 内蒙古科技大学 | Pre-processing method in process of producing paper pulp |
-
2003
- 2003-07-03 CN CN 03134347 patent/CN1566289A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101932670A (en) * | 2007-08-14 | 2010-12-29 | 卑尔根技术交易股份公司 | One-step conversion of solid lignin to liquid products |
| US8673027B2 (en) | 2007-08-14 | 2014-03-18 | Bergen Teknologioverforing As | One-step conversion of solid lignin to liquid products |
| CN101932670B (en) * | 2007-08-14 | 2014-04-02 | 卑尔根技术交易股份公司 | One-step conversion of solid lignin to liquid products |
| WO2011131144A1 (en) * | 2010-04-23 | 2011-10-27 | Qin Caidong | Mixed fuel containing lignin, production process thereof and fuel injector using the same |
| CN102858926A (en) * | 2010-04-23 | 2013-01-02 | 秦才东 | Mixed fuel containing lignin, production method thereof, and fuel injector capable of using the mixed fuel |
| CN102154036A (en) * | 2011-03-10 | 2011-08-17 | 杜良才 | Method for producing boiler fuel by utilizing papermaking black liquid |
| CN102154036B (en) * | 2011-03-10 | 2013-07-24 | 杜良才 | Method for producing boiler fuel by utilizing papermaking black liquid |
| CN102182095A (en) * | 2011-03-31 | 2011-09-14 | 陕西科技大学 | Method for recycling ethanol pulping waste liquor |
| CN102277760A (en) * | 2011-08-30 | 2011-12-14 | 内蒙古科技大学 | Pre-processing method in process of producing paper pulp |
| CN102277760B (en) * | 2011-08-30 | 2014-05-14 | 内蒙古科技大学 | Pre-processing method in process of producing paper pulp |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |