CN1449313A - Method and device for continuous casting of metals in a mold - Google Patents
Method and device for continuous casting of metals in a mold Download PDFInfo
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- CN1449313A CN1449313A CN01814799A CN01814799A CN1449313A CN 1449313 A CN1449313 A CN 1449313A CN 01814799 A CN01814799 A CN 01814799A CN 01814799 A CN01814799 A CN 01814799A CN 1449313 A CN1449313 A CN 1449313A
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Abstract
Description
技术领域technical field
本发明涉及在一种沿着浇注方向两端敞开的铸模中连续或半连续铸造例如钢的金属和合金的方法和设备。The present invention relates to a method and apparatus for the continuous or semi-continuous casting of metals and alloys such as steel in a casting mold which is open at both ends in the casting direction.
背景技术Background technique
在连续铸钢作业中借助于外部施加的低频交流电磁场来搅动连续铸造铸模内的钢液是一种沿用已久的实践。电磁搅动,即通常所说的EMS,广泛应用于连续铸钢中,以便改进铸态产品的质量和过程生产率。已经证实,为了满足不同的铸造实践条件,需要控制紧邻通常称作弯液面的熔融物自由表面区域内的搅动运动。因此在弯液面区域内需要一定强度的搅动运动,以便控制主要用Si-Mn脱氧钢生产的钢坯和钢锭内的表面和次表面孔隙率、表面夹杂物以及其他缺陷。另一种铸造实践,即通常所说的在铸模粉末下方的浸没浇注需要弯液面稳定,因此它对弯液面处的搅动运动施加限制。除了从铸造实践发出的这两种相反需要之外,在弯液面区域和铸模主体中的某些组的股坯缺陷和搅动强度之间也存在直接的相关性。因此控制那些铸模区域搅动运动的需求使一些建立在应用直流或交流电磁场基础上的技术成为必要。因此在美国专利NO.4,933,005中曾描述借助于水平直流磁场来控制铸模弯液面区域内的搅动运动。根据这个专利,外部施加直流磁场与由主搅动器形成的弯液面区域搅动流动相互作用。由这个相互作用生成电磁力,并且该力与液态金属运动相反,借此降低该运动的速度。这种搅动速度控制法具有局限性。在用于连续铸造钢坯和钢锭的设备的普通外廓内,制动线圈的尺寸受到限制,其结果是由该制动器产生的直流磁场强度只足以使弯液面处的搅动速度减少到速度初始值的百分之五十至六十。It is a long-established practice in continuous casting steel operations to agitate molten steel in continuous casting molds by means of externally applied low frequency AC electromagnetic fields. Electromagnetic stirring, commonly known as EMS, is widely used in continuous steel casting to improve the quality of as-cast products and process productivity. It has been demonstrated that, in order to meet the conditions of different casting practices, it is necessary to control the stirring motion in the region immediately adjacent to the free surface of the melt, commonly referred to as the meniscus. A certain intensity of agitation motion is therefore required in the meniscus region in order to control surface and subsurface porosity, surface inclusions and other defects in billets and ingots produced primarily from Si-Mn deoxidized steels. Another casting practice, commonly known as submersion pouring below the mold powder, requires a stable meniscus, so it imposes a limit on the stirring motion at the meniscus. In addition to these two opposing demands emanating from casting practice, there is also a direct correlation between certain sets of strand defects and agitation strength in the meniscus region and in the mold body. The need to control the agitating motion in those areas of the mold thus necessitates techniques based on the application of DC or AC electromagnetic fields. Thus in US Patent No. 4,933,005 the control of the stirring movement in the region of the meniscus of the casting mold by means of a horizontal DC magnetic field is described. According to this patent, an externally applied DC magnetic field interacts with the agitation flow in the meniscus region formed by the main agitator. An electromagnetic force is generated from this interaction, and this force opposes the liquid metal motion, thereby reducing the speed of that motion. This method of agitation rate control has limitations. In the usual outlines of equipment for continuous casting of billets and ingots, the size of the brake coil is limited, as a result of which the DC magnetic field strength generated by the brake is only sufficient to reduce the stirring speed at the meniscus to the initial value of the speed fifty to sixty percent of that.
以控制弯液面区搅动运动为目标的另一种现有技术已知方法是以交流电流操作的双线圈EMS系统,它在美国专利No.5,699,850中得到描述。根据这个专利,布置在铸模上部弯液面区域内的感应线圈用电源供电,该电源与布置在铸模下部的主搅动器电源无关。因此由上感应线圈产生的旋转交流磁场相对于主搅动器磁场独立地进行控制。当由上和主搅动器产生的磁场一致时,在弯液面内的搅动速度增加。这种速度增加可由输入上线圈的电流进行控制。在旋转方向彼此相反的情况下,上搅动器相对于弯液面区域内的搅动流动变成磁制动器。借助于调节制动器电流,能将弯液面区域内的搅动速度控制在一范围内,该范围从其不施加制动作用时的初始值到制动转矩与弯液面区域搅动流动的角动量平衡时的实际零值。Another prior art known method aimed at controlling the agitation motion of the meniscus region is a dual coil EMS system operated with alternating current, which is described in US Patent No. 5,699,850. According to this patent, the induction coils arranged in the upper meniscus region of the casting mold are powered by a power supply which is independent of the main stirrer power supply arranged in the lower part of the casting mould. The rotating AC magnetic field generated by the upper induction coil is thus controlled independently of the main stirrer magnetic field. When the magnetic fields generated by the upper and main agitators coincide, the agitation velocity within the meniscus increases. This speed increase can be controlled by the current input to the upper coil. With the directions of rotation opposite to each other, the upper agitator becomes a magnetic brake with respect to the agitated flow in the region of the meniscus. By adjusting the brake current, the agitation velocity in the meniscus region can be controlled within a range from its initial value when no braking action is applied to the braking torque and the angular momentum of the agitated flow in the meniscus region Actual zero value at equilibrium.
作为这种方法的缺点,制动作用仅对由搅动或由排入铸模的浇注流冲击产生的流体流动水平分量具有影响。这些流动的纵向分量保持不受上感应线圈产生的交流磁场影响。这些纵向流体流动,根据它们的强度,使弯液面处以及在邻近弯液面的区域内的熔融物产生明显的紊流,因而影响浇注实践的工作状态和产品质量。As a disadvantage of this method, the braking effect only has an effect on the horizontal component of the fluid flow produced by agitation or by impingement of the pouring stream discharged into the mould. The longitudinal components of these flows remain unaffected by the AC magnetic field generated by the upper induction coil. These longitudinal fluid flows, according to their intensity, cause significant turbulence in the melt at the meniscus and in the region adjacent to the meniscus, thus affecting the performance of the pouring practice and the quality of the product.
发明内容Contents of the invention
本发明的目标是在用来生产例如钢坯和钢锭的连续铸造铸模熔融物弯液面区域内提供一种更加灵活的搅动速度和也就是液态金属流的熔融物流控制。It is an object of the present invention to provide a more flexible agitation rate and therefore melt flow control of the liquid metal flow in the region of the meniscus of the melt of a continuous casting mold used to produce eg billets and ingots.
本发明的目标借助于一种具有权利要求1特征的设备、一种具有权利要求7特征的方法以及一种具有权利要求11特征的方法来实现。The object of the invention is achieved by means of a device with the features of claim 1 , a method with the features of
根据本发明,双线圈搅动系统的上感应线圈,此处称之为“第二感应线圈”根据对邻近熔融物的上自由表面区域内熔融物搅动运动的所需的作用由直流或交流电流供电,而主感应线圈,此处称之为“第一感应线圈”总是作为由交流电流供电即产生交流磁场的搅动器在工作。According to the invention, the upper induction coil of the dual-coil agitation system, referred to herein as the "second induction coil", is powered by direct or alternating current depending on the desired effect on the agitation motion of the melt in the region adjacent to the upper free surface of the melt. The main induction coil, referred to as "the first induction coil" here, is always working as a stirrer powered by alternating current, that is, generating an alternating magnetic field.
第二感应线圈最好由来自相对于主搅动器即相对于第一感应线圈独立的电源的交流电流供电。当该搅动系统使用定径喷嘴的浇注并且需要增强弯液面区域内的搅动运动时,上感应线圈以协助主搅动器的模式工作。当浸没浇注铸造实践的弯液面处需要完全或几乎完全降低的搅动速度时,交流电流也用来激励上感应线圈。The second induction coil is preferably powered by alternating current from a power source independent from the main stirrer, ie from the first induction coil. When the agitation system uses pouring with sizing nozzles and it is desired to enhance the agitation motion in the meniscus region, the upper induction coil operates in mode assisting the main agitator. Alternating current is also used to energize the upper induction coil when a completely or nearly completely reduced agitation velocity is required at the meniscus for submerged pour casting practices.
在弯液面处的搅动速度局部降低能借助于施加水平直流磁场来实现。在下述情况下需要这种局部制动作用:使用定径喷嘴或浸没入口喷嘴的铸造,而且在弯液面处的搅动速度需要控制在其初始值的至多百分之六十或五十范围内。在这种情况下使用直流电流来激励上感应线圈。经验显示,这样的制动强度在许多浸没浇注铸造实践情况下和用于通过定径喷嘴的浇注是足够的。在高水平搅动强度情况下,借助于施加交流磁场来实现进一步降低搅动速度。将电流从交流转换为直流或者相反最好由电子和编程装置来完成,该装置构成系统电力供应的一部分。从由主搅动器产生的搅动、液态金属的排出流和/或铸模运动形成的弯液面区域流体流动会与由上感应线圈产生的水平直流磁场相互作用。作为该直流磁场和任何以不等于零度的角度横过该磁场流体流动之间相互作用的结果,会形成磁力并阻碍这些流动的运动。在该磁场和流体流动之间成90°角时相互作用达到最大程度。其结果是,搅动运动速度和包括排放笔直向下的浇注流的纵向流动会减小。弯液面紊流也会因此而减小,从而导致弯液面稳定性、过程工作状态和浇注产品质量的改善。A local reduction in the stirring speed at the meniscus can be achieved by applying a horizontal DC magnetic field. This local braking action is required in the following cases: Casting with sizing nozzles or submerged inlet nozzles, and the agitation velocity at the meniscus needs to be controlled within at most sixty or fifty percent of its initial value . In this case a direct current is used to excite the upper induction coil. Experience has shown that such a braking strength is sufficient in many submerged pouring casting practices and for pouring through sizing nozzles. At high levels of agitation intensity, a further reduction in agitation speed was achieved by means of the application of an alternating magnetic field. Converting the current from AC to DC or vice versa is best done by electronic and programming means which form part of the system's power supply. Fluid flow in the meniscus region resulting from agitation by the main agitator, discharge flow of liquid metal and/or movement of the mold interacts with the horizontal DC magnetic field generated by the upper induction coil. As a result of the interaction between the DC magnetic field and any fluid flows traversing the magnetic field at angles other than zero degrees, magnetic forces develop and impede the movement of these flows. The maximum degree of interaction occurs at an angle of 90° between the magnetic field and the fluid flow. As a result, the speed of the stirring motion and the longitudinal flow including discharge of the pouring stream straight down will be reduced. Meniscus turbulence is also reduced as a result, resulting in improved meniscus stability, process behavior and cast product quality.
因此鉴于由单个搅动系统提供并由布置在铸模弯液面区域的同一感应线圈产生的交流和直流磁场的可互换性,本发明为控制搅动速度和弯液面紊流的灵活性带来了明显改进,并导致冶金性能有效性和搅动系统效率的提高。The present invention therefore brings flexibility to control agitation speed and meniscus turbulence in view of the interchangeability of the AC and DC magnetic fields provided by a single agitation system and generated by the same induction coil placed in the meniscus region of the mold. Significant improvement and results in increased metallurgical performance effectiveness and agitation system efficiency.
本发明是双线圈搅动系统方法和设备的一种进一步改进。本发明可广泛应用于所有能电磁搅动的也就是金属和合金的导电材料,以及需要在某个或多个区域控制搅动运动的场合,所述区域与该流体金属柱其他区域的搅动运动即使有干扰,该干扰也是最小。本发明可应用于变化广泛的特殊铸模取向。铸模可垂直、水平或倾斜放置。The present invention is a further improvement of the double-coil agitation system method and equipment. The present invention can be widely applied to all conductive materials that can be electromagnetically stirred, that is, metals and alloys, and where it is necessary to control the stirring motion in one or more areas, even if the stirring motion of said area and other areas of the fluid metal column has interference, which is also minimal. The invention is applicable to a wide variety of specific mold orientations. Casting molds can be placed vertically, horizontally or obliquely.
附图说明Description of drawings
现在只通过实例参照不同实施例和附图更加详细地解释本发明。The invention is now explained in more detail, by way of example only, with reference to different embodiments and figures.
图1示意地披露与根据本发明实施例的铸模相关的双线圈搅动系统;Figure 1 schematically discloses a dual coil agitation system associated with a casting mold according to an embodiment of the present invention;
图2是根据本发明实施例设备的感应线圈可能电连接的单线图;Figure 2 is a single-line diagram of a possible electrical connection of an induction coil of a device according to an embodiment of the present invention;
图3是在水银柱中的直流磁力制动器电流与弯液面处以及电磁搅动器中间平面内的搅动速度之间关系的图解表示;以及Figure 3 is a graphical representation of the relationship between DC magnetic brake current in a mercury column and the stirring velocity at the meniscus and in the mid-plane of the electromagnetic stirrer; and
图4是用于在有和没有交流和直流磁场制动器情况下操作的双线圈EMS系统的方形截面水银槽内多个测定搅动速度的轴向断面的图解表示。Figure 4 is a diagrammatic representation of multiple axial sections for measuring agitation velocities within a square section mercury bath for a dual coil EMS system operating with and without AC and DC magnetic field brakes.
具体实施方式Detailed ways
图1披露一种根据本发明实施例的用来连续或半连续浇注金属的设备。该设备包括沿着浇注方向两端敞开的铸模1,以及用来给该铸模供应热熔融物的装置2。该设备装备着双线圈电磁搅动(EMS)系统,它包括第一感应线圈4和第二感应线圈3。第二感应线圈3安置在铸模顶端,并处于第一感应线圈4的上游。因此,第一感应线圈4安置在第二感应线圈3的下游。第一感应线圈4作为搅动器工作并由产生交流磁场的交流电流供电。第一感应线圈4构成交流电磁搅动器,并设计成在供电时使铸模1内的熔融金属7产生围绕铸模1纵轴线的旋转运动。在图1中熔融物借助于浇注管2供应到铸模内,浇注管2在熔融物上表面(弯液面5)下方敞开。当然也可利用其他类型的装置来给铸模1供应熔融物。Figure 1 discloses an apparatus for continuous or semi-continuous casting of metal according to an embodiment of the present invention. The apparatus comprises a casting mold 1 open at both ends in the pouring direction, and means 2 for supplying the casting mold with hot melt. The device is equipped with a dual-coil electromagnetic stirring (EMS) system comprising a
根据本发明,第二感应线圈3根据在邻近熔融物上自由表面5区域内所需熔融物搅动运动的作用由直流或交流电流可互换地供电。为了控制供应到第二感应线圈3上的电流类型,该设备最好装备着图2示意地表示的装置12,它用来将到达第二感应线圈3的电流从交流转换成直流或者相反。将该电流从交流转换成直流或者相反最好由电子和编程装置12来实现,该装置构成系统电力供应的一部分。According to the invention, the
第二感应线圈3最好由来自相对于第一感应线圈4独立的电源的交流电流供电。根据本发明优选实施例,第一电源10提供来给第一感应线圈4供应交流电流,而第二电源11提供来给第二感应线圈3可互换地供应交流和直流电流。在图2中示意地表示所述第一和第二电源。用来将电流从交流转换成直流或者相反的装置也在图2中以12示意地表示。因此,交流或者直流电流均能选择来为第二线圈3供电。这种布置允许不管由第一感应线圈4产生的搅动方向图案如何而独立控制第一或第二感应线圈的搅动动作。The
根据本发明的优选实施例,第一感应线圈包括围绕铸模1周边排列的一系列线圈8。这些线圈8最好具有多相和多极布置。最好是第二感应线圈3也包括围绕铸模1周边排列的一系列线圈9。这些线圈9最好也具有多相和多极布置。According to a preferred embodiment of the invention, the first induction coil comprises a series of
根据本发明的一方面,第二感应线圈3能提供至少三种不同的工作模式,即:According to one aspect of the present invention, the
-第一模式,其中第二感应线圈3由交流电流供电,而且由第二感应线圈3产生的磁场旋转方向与由第一感应线圈4产生的磁场旋转方向一致,因此由第二感应线圈3产生的磁场加强由第一感应线圈4在邻近熔融物上自由表面5的熔融物区域内产生的搅动运动速度,在所述区域内的熔融物搅动速度通过调节供应到第二感应线圈3的交流电流值进行控制,- a first mode in which the
-第二模式,其中第二感应线圈3由交流电流供电,而且由第二感应线圈3产生的磁场旋转方向与由第一感应线圈4产生的磁场旋转方向相反,因此由第二感应线圈3产生的磁场减低由第一感应线圈4在邻近熔融物上自由表面5的熔融物区域内产生的搅动运动速度,在所述区域内的熔融物搅动速度通过调节供应到第二感应线圈3的交流电流值进行控制,以及- a second mode in which the
-第三模式,其中第二感应线圈3由直流电流供电,以致于产生水平取向的直流磁场,它在邻近熔融物上自由表面5的熔融物区域内在铸模1的横向以及纵向空间平面内在熔融物7内产生与流体流动方向相反的电磁力,借此由第二感应线圈3产生的磁场减低由第一感应线圈4在邻近熔融物上自由表面5的熔融物区域内产生的搅动运动的速度,以及由第一感应线圈4的搅动作用在熔融物7内产生的纵向流动和借助于将熔融物连续排入铸模1产生的纵向流动的速度。- a third mode, in which the
符合需要的工作模式根据所采用的浇注方法从上述多种模式中选择。第二感应线圈3对于在邻近弯液面5区域内的熔融物搅动运动的所需效果随所采用浇注方法的类型而改变。The desired working mode is selected from the above-mentioned various modes according to the pouring method adopted. The required effect of the
根据本发明第二感应线圈3由任一直流或交流电流供电,以便在铸模弯液面区域内产生制动作用从而改进搅动运动的控制。此外,EMS系统的冶金有效性也实现。用交流磁场实施的制动作用能在包括实际速度为零的广阔范围内控制弯液面处的搅动速度。通过在铸模主体内制动搅动运动而产生的反向冲击使得在这个区域内的搅动速度能减低多达百分之二十。由水平直流磁场提供制动作用能在相当于原始速度值百分之五十范围内控制弯液面区域内的搅动速度,并且不影响铸模主体内的搅动运动。这对于大多数在浸没浇注情况下的连续铸钢实践来说是足够的。According to the invention the
从第二感应线圈3生成的水平直流磁场和弯液面区域内旋转搅动流动之间相互作用产生的制动作用大部分限制在弯液面和该磁制动器底端部之间的界限内。由也就是第一感应线圈4的主搅动器产生的铸模主体内部搅动运动实际上保持不受由水平直流磁场产生的弯液面区域内制动作用影响。The braking action resulting from the interaction between the horizontal DC magnetic field generated from the
熔融物7内部的旋转流动强度的特征为:其旋转(角)速度U本身又取决于磁转矩参数和它在熔融物内的空间分布,以及铸模横截面的尺寸和几何形状。对于相对较小的轴对称几何形状即圆柱形或正方形横截面系统来说,磁转矩能按照下述公式来确定:The intensity of the rotational flow inside the
T=0.5πfσB2R4LT=0.5πfσB 2 R 4 L
此处:here:
T为由两相或三相交流磁场产生的磁转矩,T is the magnetic torque generated by two-phase or three-phase AC magnetic field,
f为电流频率,f is the current frequency,
σ为液态金属导电率,σ is the conductivity of the liquid metal,
B为磁通量密度,B is the magnetic flux density,
R为搅动槽半径,以及R is the radius of the stirring tank, and
L为搅动器轭铁长度。L is the length of the yoke iron of the agitator.
由可互换地使用用于激励第二感应线圈3的交流或直流电流在弯液面5处提供的独立控制搅动运动使得更灵活和更准确地控制搅动过程以及弯液面区域内的紊流,所述紊流由第一感应线圈4,图1中标号18所示的浇注流以及铸模1振动引入的纵向流体流动造成。The independently controlled agitation motion at the
在直流电流供电时由也就是第二感应线圈4的直流制动器在横向和纵向平面内减少流体流动,是作为在直流磁场和运动导电流体流之间根据下述公式相互作用的结果出现电磁力即Lorentz力而发生的:The reduction of the fluid flow in the transverse and longitudinal planes by the DC brake, i.e. the
F=B×JF=B×J
J=σ(E+UB)J=σ(E+UB)
此处:here:
J为在熔融物内部的感应电流密度,J is the induced current density inside the melt,
U为熔融物流的速度,以及U is the velocity of the melt stream, and
E为电位。E is the electric potential.
电磁力F根据磁通量密度B和流体流动速度U的大小,显而易见,需要显著地加大电流以便将流体流动速度减小到接近零水平。在许多连续铸造实践情况下这种速度减小是不需要的。如图3所示,在水银槽弯液面处的搅动速度在直流电流当前输入值为250A时从初始的7.3弧度/秒(rad/s)减少到2.7弧度/秒。速度减小的线性外插法指出为了将搅动速度减至实际零水平需要335A。The electromagnetic force F depends on the magnitude of the magnetic flux density B and the fluid flow velocity U. Obviously, it is necessary to significantly increase the current in order to reduce the fluid flow velocity to a level close to zero. This speed reduction is unnecessary in many continuous casting practices. As shown in Figure 3, the agitation speed at the meniscus of the mercury bath decreases from the initial 7.3 rad/s to 2.7 rad/s when the current input value of the DC current is 250A. Linear extrapolation of the velocity reduction indicates that 335A is required to reduce the agitation velocity to a practical zero level.
借助于直流制动器减少弯液面区域内的搅动速度还对主EMS即第一感应线圈4中间平面的搅动速度施加制动效果,这与由交流制动器产生的影响类似。图3和4显示,在弯液面处的搅动速度直流制动减少到2.7弧度/秒时在EMS中间平面处的搅动速度为大约11.7弧度/秒或初始值13.6弧度/秒的86%。Reducing the agitation velocity in the meniscus region by means of a DC brake also exerts a braking effect on the agitation velocity of the main EMS, ie the midplane of the
本发明提供一种控制铸模弯液面区域内沿着水平和纵向液态金属运动的改进方法。由主EMS和由其他装置例如排入铸模的液态金属浇注流产生的液态金属运动纵向分量会最小化,这是因为采用以搅动调节器为形式的感应线圈即第二感应线圈并将其布置在熔融物弯液面区域周围并用直流电流供电的结果,而比较复杂的搅动速度即水平分量控制借助于使用由该搅动调节器产生的交流磁场来实现。The present invention provides an improved method of controlling the movement of liquid metal in the meniscus region of a casting mold both horizontally and vertically. The longitudinal component of the liquid metal motion produced by the main EMS and by other means such as the liquid metal pouring stream discharged into the mould, is minimized by employing an induction coil in the form of an agitation regulator, the second induction coil, and placing it in the Around the meniscus region of the melt and powered by DC current, the more complex agitation speed, that is, the horizontal component control, is achieved by using the AC magnetic field generated by the agitation regulator.
用于本说明书和所附权利要求的表达方式“感应线圈”还包括含有几个单独线圈的感应线圈,如图2所示。The expression "induction coil" used in this description and in the appended claims also includes an induction coil comprising several individual coils, as shown in FIG. 2 .
当然,本发明不受上述优选实施例的任何限制,十分明显,一般地本领域技术人员能在不超越所附权利要求确定的本发明基本思想的情况下对其作出许多变型。Of course, the invention is not restricted in any way to the preferred embodiments described above, and it is obvious that a person skilled in the art can make many variations thereon without going beyond the basic idea of the invention defined in the appended claims.
Claims (13)
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| SE00024596 | 2000-06-27 | ||
| SE0002459A SE519840C2 (en) | 2000-06-27 | 2000-06-27 | Method and apparatus for continuous casting of metals |
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| US (1) | US20030106667A1 (en) |
| EP (1) | EP1303370A1 (en) |
| JP (1) | JP4831917B2 (en) |
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| AU (1) | AU2001267977A1 (en) |
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| CN101316670B (en) * | 2005-11-28 | 2011-08-31 | 罗泰莱克公司 | Method and device for adjusting the mode of electromagnetic stirring over the height of a continuous casting mould |
| CN103162550A (en) * | 2011-12-09 | 2013-06-19 | 北京有色金属研究总院 | Device and method for processing metal melt for casting |
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- 2001-06-27 WO PCT/SE2001/001498 patent/WO2002000374A1/en not_active Ceased
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| Publication number | Publication date |
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| SE0002459D0 (en) | 2000-06-27 |
| SE0002459L (en) | 2001-12-28 |
| CN1293965C (en) | 2007-01-10 |
| RU2266798C2 (en) | 2005-12-27 |
| JP2004501770A (en) | 2004-01-22 |
| KR20030036247A (en) | 2003-05-09 |
| WO2002000374A1 (en) | 2002-01-03 |
| SE519840C2 (en) | 2003-04-15 |
| US20030106667A1 (en) | 2003-06-12 |
| JP4831917B2 (en) | 2011-12-07 |
| EP1303370A1 (en) | 2003-04-23 |
| AU2001267977A1 (en) | 2002-01-08 |
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