CN1388387A - Polarized light conversion element and projection liquid crystal display using the same polarized light conversion element - Google Patents
Polarized light conversion element and projection liquid crystal display using the same polarized light conversion element Download PDFInfo
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Abstract
提供一种偏光转换元件,以实现对比高、无黑显示的画面不均、显示品质高的投射型液晶显示装置,以及提供适用此偏光转换元件的投射型液晶显示装置。此偏光转换元件,把于基板膜上涂布液晶性化合物所构成的2片光学补偿板,叠合到直线偏光板一边的面以构成。此时,2片的光学补偿板,以其配向轴呈相互直交的方式配置。此偏光转换元件,较有利的是采叠合在透明玻璃板。光学补偿板和空气相接的面上,较佳的是设有反射防止层。在直线偏光板和光学补偿板相反侧的面上可叠合相位差板。把此些的偏光转换元件配置到液晶单元一边的面上,以构成投射型液晶显示装置。
A polarization conversion element is provided to realize a projection type liquid crystal display device with high contrast, no black display unevenness, and high display quality, and a projection type liquid crystal display device suitable for the polarization conversion element. This polarization conversion element is constructed by laminating two optical compensation plates formed by coating a liquid crystal compound on a substrate film with one side of a linear polarizing plate. At this time, the two optical compensation plates are arranged such that their alignment axes are perpendicular to each other. The polarized light conversion element is more advantageously laminated on a transparent glass plate. The surface of the optical compensation plate in contact with the air is preferably provided with an anti-reflection layer. A retardation plate may be laminated on the surface opposite to the linear polarizing plate and the optical compensation plate. These polarization conversion elements are arranged on one side of the liquid crystal cell to form a projection type liquid crystal display device.
Description
技术领域technical field
本发明是有关于一种适用于投射型液晶显示装置的偏光转换元件,以及使用此偏光转换元件的投射型液晶显示装置。The invention relates to a polarization conversion element suitable for a projection type liquid crystal display device, and a projection type liquid crystal display device using the polarization conversion element.
背景技术Background technique
投射型液晶显示装置,也称为液晶放映机(projector),其为可放大个人计算机及电视等的画面并将其写到屏幕的装置,目前已被广泛地使用。A projection type liquid crystal display device, also called a liquid crystal projector (projector), is a device that can magnify the screen of a personal computer, television, etc. and write it on the screen, and has been widely used at present.
投射型液晶显示装置结构的一例是根据图6概略地说明,投射型液晶显示装置一般具有光源系统、反射◆分光系统及放大投射系统。光源系统具有白色光源11、集光透镜13以及UV◆IR滤镜(cut filter)14。以透镜13把从白色光源11而来的白色光集光,再以UV◆IR滤镜14去除紫外线和红外线,并往分色镜(dichroic mirror)1传送。白色光源11通常采用金属卤素灯(metal halide lamp)或是高压水银灯等。An example of the structure of a projection-type liquid crystal display device is schematically described with reference to FIG. 6 . A projection-type liquid crystal display device generally has a light source system, a reflective spectroscopic system, and an enlarged projection system. The light source system has a
反光◆分光系统具有:4种分光镜1、2、3、4,2个全反射镜5、6,分别对应红光R、绿光G、蓝光B的液晶单元(cell)7R、7G、7B、入射侧偏光转换元件8R、8G、8B、出射侧偏光转换元件9R、9G、9B,以及集光透镜10R、10G及10B。公知的偏光转换元件采用,直线偏光板、在直线偏光板上叠合1片光学补偿板,还有采用在此些板上叠合相位差板。Reflective light splitting system has: 4 kinds of
然后,第一分光镜1仅透过绿光G及蓝光B,且透过的绿光G和蓝光B,往第二分光镜2传送。第一分光镜1反射的红光R往第一全反射镜5传送,并在此反射后,透过红光的集光透镜10R、入射侧偏光转换元件8R、液晶单元7R及出射侧偏光转换元件9R,往第三分光镜3传送。一方面,第二分光镜2仅透过蓝光B,在透过第一分光镜1的绿光G和蓝光R中,透过第二分光镜2的蓝光B,通过蓝光的集光透镜10B、入射侧偏光转换元件8B、液晶单元7B及出射侧偏光转换元件9B,往第二全反射镜6传送。又,第二分光镜2反射的绿光G,通过绿光的集光透镜10G、入射侧偏光转换元件8G、液晶单元7G及出射侧偏光转换元件9G,往第三分光镜3传送。第三分光镜3为仅透过红光R的,透过由第一全反射镜5而来的红光集光透镜10R、入射侧偏光转换元件8R、液晶单元7R及出射侧偏光转换元件9R的红光R,原封不动地透过第三分光镜3,而透过从第二分光镜2而来的绿光集光透镜10G、入射侧偏光转换元件8G、液晶单元7G及出射侧偏光转换元件9G的绿光G,被第三分光镜3反射而往第四分光镜4传送。第四分光镜4仅透过红光R及绿光G,从第三分光镜3而来的红光R及绿光G原封不动地透过此第四分光镜4,且从第二全反射镜6而来的蓝光B在此处被反射而分别往投射透镜16传送。Then, the
放大投射系统具有投射透镜16,以在此处把对应各个光的影像放大并把放大的影像往屏幕17投影。又,对应各色的液晶单元7R、7G、7B的入射侧偏光转换元件8R、8G、8B及出射侧偏光转换元件9R、9G、9B虽也有采用贴合到液晶单元7R、7G、7B的,然而,一般和液晶单元7R、7G、7B间隔配置,此间隔作为冷却用的通风路。而且,入射侧偏光转换元件8R、8G、8B也和集光透镜10R、10G、10B保持间隔。以此方式,将偏光转换元件8R、8G、8B、9R、9G、9B离开液晶单元7R、7G、7B及集光透镜以配置时,直线偏光板采用贴合到玻璃等的补强材料。The magnified projection system has a
像这样的投射型液晶显示装置,各液晶单元7R、7G、7B分别配置在2片的偏光转换元件,即入射侧偏光转换元件8R、8G、8B及出射侧偏光转换元件9R、9G、9B之间。这些偏光转换元件8、9因需透过必要的光量以把影像放大并投射到屏幕上,发热量极大。又,在红光R、绿光G以及/或是蓝光B偏光的场合,当入射到液晶单元7R、7G、7B时会使偏光面产生多次的旋转。而且,从液晶单元7R、7G、7B出射的偏光亦会再旋转到偏光面。In such a projection-type liquid crystal display device, each
为了旋转偏光面,可使用相位差板,相位差板一般是配置在入射侧偏光转换元件8R、8G、8B的光源11侧,或是出射侧偏光转换元件9R、9G、9B的投射透镜16侧。相位差板具有容易取得及价格等的优点,一般使用树脂制的。此相位差板,在入射侧偏光转换元件8R、8G、8B或是出射侧偏光转换元件9R、9G、9B中,采用贴合到直线偏光板者。(例如,日本专利申请号2000-137202及2000-352615A)In order to rotate the polarization plane, a phase difference plate can be used, and the phase difference plate is generally arranged on the
像这样的投影型液晶显示装置,因液晶单元的复屈折性和光源而来的光的广度并不十分配合,投影到屏幕的影像的对比(contrast)不高,因黑显示的画面不均而有显示品质不良的问题。Such a projection-type liquid crystal display device does not match well with the birefringence of the liquid crystal unit and the width of the light from the light source. There is a problem with poor display quality.
发明内容Contents of the invention
在此,本发明人进行偏光转换元件的开发、研究,以实现更高的对比,及显示品质佳的投射型液晶显示装置。结果是,把在基材膜(film)上涂布液晶性化合物所构成的2片光学补偿板叠合到直线偏光板的一边的面,以此结构,发现可提升投影到屏幕上影像的对比,并得到无黑显示的画面不均且显示品质优良的投射型液晶显示装置的偏光转换元件。Here, the inventors of the present invention developed and researched the polarization conversion element to realize a projection-type liquid crystal display device with higher contrast and better display quality. As a result, it was found that the contrast of the image projected on the screen can be improved by laminating two optical compensation plates composed of a base film (film) coated with a liquid crystal compound on one side of the linear polarizing plate. , and a polarization conversion element for a projection-type liquid crystal display device with no black display unevenness and excellent display quality can be obtained.
本发明提供一种偏光转换元件,把于基板膜上涂布液晶性化合物所构成的2片光学补偿板,叠合到直线偏光板一边的面,以及提供利用此偏光转换元件的投射型液晶显示装置。The present invention provides a polarization conversion element. Two optical compensation plates formed by coating a liquid crystal compound on a substrate film are stacked on one side of a linear polarizer, and a projection-type liquid crystal display using the polarization conversion element is provided. device.
此偏光转换元件,应用2片于基材膜上涂布液晶性化合物的光学补偿板,以第2光学补偿板和第1光学补偿板相邻接的方式,即以直线偏光板/第1光学补偿板/第2光学补偿板的顺序配置。而第2光学补偿板,其配向轴和第1光学补偿板的配向轴呈略直交配置。此些的偏光转换元件,一般采用在透明玻璃板上叠合的方式,在此场合,较有利的是,在和叠合光学补偿板面的相反侧的直线偏光板的面上,配置透明的玻璃板。较佳的是,在其和空气相接的面上设有反射防止层。更直线偏光板的叠合光学补偿板面的相反侧的面上,可叠合相位差板。In this polarization conversion element, two optical compensation plates coated with a liquid crystal compound on the base film are used, and the second optical compensation plate and the first optical compensation plate are adjacent to each other, that is, the linear polarizer/the first optical compensation plate. Sequential arrangement of compensation plate/second optical compensation plate. On the other hand, the alignment axis of the second optical compensation plate is substantially perpendicular to the alignment axis of the first optical compensation plate. Such polarized light conversion elements are generally laminated on a transparent glass plate. In this case, it is more advantageous to configure a transparent polarizer on the surface of the linear polarizer opposite to the surface of the laminated optical compensation plate. glass plate. Preferably, an antireflection layer is provided on the surface in contact with the air. A phase difference plate may be laminated on the surface of the linear polarizing plate opposite to the surface on which the optical compensation plate is laminated.
此些的偏光转换元件,被利用组装到投射型液晶型显示装置的液晶单元一边的面上。此投射型液晶显示装置,更具体地说,具有由白色光源、从白色光源而来把白光分光成红光、绿光、蓝光三原色的分光镜、全反射镜及集光透镜所构成的光学系统的零件、液晶单元,以及上述的偏光转换元件。Such polarization conversion elements are used and assembled on one side of the liquid crystal cell of a projection liquid crystal display device. This projection type liquid crystal display device, more specifically, has an optical system composed of a white light source, a beam splitter that splits the white light into three primary colors of red light, green light, and blue light from the white light source, a total reflection mirror, and a light-collecting lens. parts, liquid crystal unit, and the above-mentioned polarization conversion element.
附图说明Description of drawings
图1为本发明的偏光转换元件的一例的断面示意图;Fig. 1 is a cross-sectional schematic diagram of an example of the polarization conversion element of the present invention;
图2为本发明的偏光转换元件的别例的断面示意图;Fig. 2 is a schematic cross-sectional view of another example of the polarization conversion element of the present invention;
图3为本发明的偏光转换元件中,直线偏光板和光学补偿板2片的轴角度关系的一例示配置图;Fig. 3 is an exemplary configuration diagram of the axial angle relationship between two linear polarizers and optical compensation plates in the polarization conversion element of the present invention;
图4为本发明的偏光转换元件中,直线偏光板和光学补偿板2片的轴角度关系的另例示配置图;Fig. 4 is another exemplary configuration diagram of the axial angle relationship between the linear polarizing plate and the optical compensation plate in the polarization conversion element of the present invention;
图5为本发明的偏光转换元件中,直线偏光板和光学补偿板2片的轴角度关系的另例示配置图;以及Fig. 5 is another exemplary configuration diagram of the axial angle relationship between the two linear polarizing plates and the optical compensation plate in the polarization conversion element of the present invention; and
图6为投射型液晶显示装置的组成例的概略示意图。FIG. 6 is a schematic diagram showing a configuration example of a projection type liquid crystal display device.
附图标记说明:Explanation of reference signs:
1、2、3、4:分色镜1, 2, 3, 4: dichroic mirrors
5、6:全反射镜5, 6: total reflection mirror
7R、7G、7B:液晶单元7R, 7G, 7B: Liquid crystal unit
8R、8G、8B:入射侧偏光转换元件8R, 8G, 8B: incident side polarization conversion elements
9R、9G、9B:出射侧偏光转换元件9R, 9G, 9B: Exit side polarization conversion elements
10R、10G、10B:集光透镜10R, 10G, 10B: Concentrating lens
L:白光(光源光)L: white light (light source light)
R:红光R: red light
G:绿光G: green light
B:蓝光B: Blu-ray
11:白色光源11: white light source
13:集光透镜13: Collecting lens
14:UV◆IR滤镜14: UVIR filter
16:投射透镜16: Projection lens
17:屏幕17: screen
20:偏光转换元件20: Polarization conversion element
21:直线偏光板21: linear polarizer
22:光学补偿板22: Optical compensation plate
23:光学补偿板23: Optical compensation plate
24:玻璃板24: glass plate
25:相位差板25: phase difference plate
26:具有反射防止层的透明膜26: Transparent film with anti-reflection layer
27:反射防止层27: anti-reflection layer
28:反射防止层28: anti-reflection layer
具体实施方式Detailed ways
本发明所采用的直线偏光板也可以是,具有吸收在吸收轴方向上具平行振动面的直线偏光,实质上不让它透过的性质,且具有透过在吸收轴方向上具直交振动面的直线偏光的性质。一般直线偏光板是,采用在偏光子膜的一面或两面上叠合保护膜。偏光子膜是,举例而言,较佳的是,采用在聚乙烯醇(polyvinylalcohol)系树脂膜上吸着配向着二色性染料。偏光子膜的厚度一般为1~50微米。保护膜,举例而言,采用由像是二乙醯纤维素(diacetyl cellulose)或是三乙醯纤维素(triacetylcellulose)的纤维素系树脂所构成的膜、像原冰片烷(norborane)系树脂膜所代表的非晶性烯烃(olefin)系树脂膜的烯烃膜、丙烯基系树脂膜、聚酯系树脂膜等。保护膜的厚一般为10~200微米。偏光膜和保护膜,举例而言,经由聚乙烯醇系接着剂层叠合。像这样的直线偏光板亦可以应用于公知的投射型液晶显示装置。The linear polarizing plate used in the present invention may also have the property of absorbing linearly polarized light having a parallel vibration plane in the direction of the absorption axis, substantially preventing it from passing through, and having the property of transmitting linearly polarized light having a plane of vibration perpendicular to the direction of the absorption axis. properties of linearly polarized light. Generally, a linear polarizing plate is made by laminating a protective film on one or both sides of a polarizer film. The polarizer film is, for example, preferably formed by absorbing and aligning a dichroic dye on a polyvinylalcohol resin film. The thickness of the polarizer film is generally 1-50 microns. For the protective film, for example, a film made of a cellulose-based resin such as diacetyl cellulose or triacetyl cellulose, a film of a norborane-based resin such as Representative amorphous olefin (olefin) resin films include olefin films, acrylic resin films, polyester resin films, and the like. The thickness of the protective film is generally 10 to 200 microns. The polarizing film and the protective film are, for example, laminated via a polyvinyl alcohol-based adhesive layer. Such a linear polarizer can also be applied to known projection-type liquid crystal display devices.
在本发明中,把直线偏光板和把液晶性化合物涂布到基材膜面而获得配向的光学补偿板组合应用。光学补偿板的基材膜,举例而言,像具有烯烃骨架的变性聚碳酸酯等的聚碳酸酯系树脂、像二乙醯纤维素或是三乙醯纤维素纤维素系树脂、原冰片烷系单体(monomer)的聚合物的环状聚烯烃(polyolefin)系树脂、聚(polysulfone)系树脂、聚醚(polyethersulfone)系树脂、聚酯系树脂、聚亚醯胺(polyimide)、聚醯胺(polyamide)、聚丙烯酸酯(polyarylate)系树脂等。基材膜的厚一般为10~1,000微米。涂布于其上的液晶性化合物,举例而言,圆盘状(discotic)液晶性化合物、高分子液晶化合物等。以一般的方法使液晶性化合物配向亦可,例如,可采用将基材表面预先进行配向处理,把液晶性化合物涂布于其上,使其干燥后,以热处理使液晶性化合物配向的方法。涂布配向液晶性化合物的市售的光学补偿板,举例而言为富士照相底片(股)所出售的“WIDE VIEW A”或是日石三菱(股)所出售的“日石LC底片”。In the present invention, a linear polarizing plate is used in combination with an optical compensation plate obtained by applying a liquid crystalline compound to the film surface of a substrate to achieve alignment. The base film of the optical compensation plate is, for example, a polycarbonate-based resin such as denatured polycarbonate having an olefin skeleton, a cellulose-based resin such as diacetyl cellulose or triacetyl cellulose, orthobornane Cyclic polyolefin resins, polysulfone resins, polyethersulfone resins, polyester resins, polyimides, polyamides, which are polymers of monomers Amine (polyamide), polyacrylate (polyarylate) resin, etc. The thickness of the base film is generally 10 to 1,000 micrometers. The liquid crystal compound coated thereon is, for example, a discotic liquid crystal compound, a polymer liquid crystal compound, and the like. Orientation of the liquid crystal compounds can also be carried out by a common method. For example, the method of aligning the substrate surface in advance, coating the liquid crystal compound on it, drying it, and then heat-treating the liquid crystal compound can be used. A commercially available optical compensation plate coated with an alignment liquid crystal compound is, for example, "WIDE VIEW A" sold by Fuji Photo Film Co., Ltd. or "Nisseok LC Film" sold by Nippon Mitsubishi Co., Ltd.
叠合在直线偏光板一边的面的2片光学补偿板,较佳的是,前者的吸收轴和后者的配向轴的配置为略直交或平行。又,2片的光学补偿板,较佳的是,各别的配向轴配置成直交。2片的光学补偿板贴合到直线偏光板时,直线偏光板的吸收轴和1片的光学补偿板的配向轴为直交,直线偏光板的吸收轴和再1片的光学补偿板的配向轴,较佳的是,配置成和直线偏光板的吸收轴平行。In the two optical compensation plates laminated on one side of the linear polarizing plate, it is preferable that the absorption axis of the former and the alignment axis of the latter be arranged to be substantially perpendicular or parallel. In addition, in the two optical compensation plates, it is preferable that the respective alignment axes are arranged so as to be perpendicular to each other. When two optical compensation plates are attached to the linear polarizer, the absorption axis of the linear polarizer and the alignment axis of the first optical compensation plate are perpendicular to each other, and the absorption axis of the linear polarizer is perpendicular to the alignment axis of the second optical compensation plate. , preferably arranged parallel to the absorption axis of the linear polarizer.
由直线偏光板和光学补偿板所构成的偏光转换元件一般是贴合到透明玻璃板以使用。在此场合,透过接着剂层叠合两者。构成接着剂层的接着剂,举例而言是使用,丙烯基是感压型接着剂、胺基甲酸酯是感压型接着剂等的感压型接着剂。感压型接着剂一般为透明的光学等方性的接着剂层。接着剂层的厚度一般为10~60微米。又感压型接着剂亦可称为黏着剂。The polarization conversion element composed of a linear polarizer and an optical compensation plate is generally bonded to a transparent glass plate for use. In this case, both are laminated through an adhesive layer. As the adhesive constituting the adhesive layer, for example, pressure-sensitive adhesives such as acrylic pressure-sensitive adhesives and urethane pressure-sensitive adhesives are used. The pressure-sensitive adhesive is generally a transparent optically isotropic adhesive layer. The thickness of the adhesive layer is generally 10-60 microns. The pressure-sensitive adhesive can also be called adhesive.
透明玻璃板,使用一般称为蓝板玻璃或是白板玻璃的硅系玻璃板。又,较佳的是使用高热传导率的蓝宝石玻璃。而且,亦可以使用水晶玻璃、石英玻璃。蓝宝石玻璃是使用铝(Al2O3)的单结晶体,例如以EFG法(Edge-defined Film-fed Growth)形成的板状。在透明玻璃板一边的面,即露出面上,较佳的是具有反射防止层。又,形成分色层(dichroic),只透过特定波长的光,然而,亦可用不透过其它波长范围光的可调滤波器(trimming filter)。透明玻璃板厚一般为0.1~2mm,较佳的是,0.3mm以上,0.8mm以下。透明玻璃板的面积,根据作为目的的投射型液晶显示装置的大小适宜的选择。代表例是,一边为10~100mm的长方形或正方形,直径为5~100mm的圆形或椭圆形等。As the transparent glass plate, a silicon-based glass plate generally called blue plate glass or white plate glass is used. Also, it is preferable to use sapphire glass with high thermal conductivity. Furthermore, crystal glass and quartz glass can also be used. The sapphire glass is a single crystal of aluminum (Al 2 O 3 ), and is formed in a plate shape by, for example, the EFG method (Edge-defined Film-fed Growth). It is preferable to have an antireflection layer on one side of the transparent glass plate, that is, the exposed surface. Also, a dichroic layer is formed to only transmit light of a specific wavelength, however, a tunable filter (trimming filter) that does not transmit light of other wavelength ranges may also be used. The thickness of the transparent glass plate is generally 0.1 to 2 mm, preferably more than 0.3 mm and less than 0.8 mm. The area of the transparent glass plate is appropriately selected according to the size of the intended projection-type liquid crystal display device. Representative examples are rectangles or squares with a side of 10 to 100 mm, circles or ellipses with a diameter of 5 to 100 mm, and the like.
在透明玻璃板上叠合着直线偏光板和光学补偿板。直线偏光板和光学补偿板,包夹透明玻璃板,以两面各自分开的方式贴合着,然而,亦可以是在透明玻璃板一边的面叠合直线偏光板,再于此直线偏光板上叠合光学补偿板。直线偏光板及光学补偿的面积一般是和透明玻璃板的面积相同,或者是略微小一点。面积略小者容易贴着于玻璃面上,从透明玻璃板的边缘往内侧0.5~5mm贴合,做成小者较佳。A linear polarizing plate and an optical compensation plate are stacked on a transparent glass plate. The linear polarizing plate and the optical compensation plate are sandwiched by a transparent glass plate, and the two sides are separately bonded. However, the linear polarizing plate can also be laminated on one side of the transparent glass plate, and then laminated Combined optical compensation plate. The area of the linear polarizer and optical compensation is generally the same as that of the transparent glass plate, or slightly smaller. Those with a slightly smaller area are easy to stick to the glass surface, 0.5-5mm from the edge of the transparent glass plate to the inner side, and the smaller ones are better.
在本发明的偏光转换元件中,光学补偿板,较佳的是,在其外面,即和空气的接触面,具有反射防止层。反射防止层,降低和空气层界面上的反射光,以防止因反射光产成的散射光(stray light)。在此处,较佳的是,装设此面的反射率为2%以下,特别是1%以下的反射防止层。反射防止层,举例而言,一般使用选自于由金属、金属氧化物及金属氟化物的化合物所构成的单层或多层者。金属举例而言,为银,金属氧化物举例而言,为氧化硅、氧化铝、氧化钛、氧化钽、氧化钇、氧化锆等,而金属氟化物举例而言,为氟化镁等。反射防止层可以是单层,多层,例如,2层、3层或4层以上都可以。反射防止层厚,或是多层时各层的厚度是根据其层数、各层所采用物质的曲折率等适宜地选择。In the polarization conversion element of the present invention, the optical compensation plate preferably has an anti-reflection layer on its outer surface, that is, on a contact surface with air. The anti-reflection layer reduces the reflected light on the interface with the air layer to prevent stray light caused by reflected light. Here, it is preferable to provide an antireflection layer having a reflectance of 2% or less, particularly 1% or less, on this surface. As the antireflection layer, for example, a single layer or a multilayer selected from compounds of metals, metal oxides, and metal fluorides is generally used. The metal is, for example, silver, the metal oxide is, for example, silicon oxide, aluminum oxide, titanium oxide, tantalum oxide, yttrium oxide, zirconium oxide, etc., and the metal fluoride is, for example, magnesium fluoride. The antireflection layer may be a single layer or multiple layers, for example, 2 layers, 3 layers, or 4 or more layers. The thickness of the antireflection layer, or the thickness of each layer in the case of multiple layers, is appropriately selected in accordance with the number of layers, the curvature of the material used for each layer, and the like.
把像这样的反射防止层直接设在光学补偿板上亦可以,但此时光学补偿板的特性会变化。在透明基材膜上形成反射防止层的反射防止膜,较佳的是,叠合到光学补偿板上。形成反射防止层的膜,举例而言,像具有聚碳酸酯或是芴(fluorene)骨架的变性聚碳酸酯等的聚碳酸酯系树脂、像二乙醯纤维素或是三乙醯纤维素纤维素系树脂、原冰片烷系单体的聚合物的环状聚烯烃系树脂、聚砜系树脂、聚醚砜系树脂、聚酯系树脂、聚亚醯胺、聚醯胺、聚丙烯酸酯系树脂等。特别是环状聚烯烃系树脂,其光弹性系数小,适于作为膜基材。环状烯烃系树脂膜,举例而言为JAYIDARE(股)制的“ARTON”(玻璃转换温度约摄氏170度,光弹性系数约4×10-13平方公分/达因),积水化学工业(股)制的“IDSHEENA”(玻璃转换温度约摄氏140度,光弹性系数约6×10-13平方公分/达因)等市售的。装设反射防止层的基板的厚,一般为10~1,000微米。It is also possible to directly provide such an antireflection layer on the optical compensation plate, but in this case, the characteristics of the optical compensation plate will change. The antireflection film in which the antireflection layer is formed on the transparent base film is preferably laminated on the optical compensation plate. The film forming the antireflection layer is, for example, a polycarbonate-based resin such as polycarbonate or denatured polycarbonate having a fluorene skeleton, or a fiber such as diacetyl cellulose or triacetyl cellulose Plain resin, cyclic polyolefin resin, polysulfone resin, polyethersulfone resin, polyester resin, polyimide, polyamide, polyacrylate resin resin etc. In particular, cyclic polyolefin-based resins have a small photoelastic coefficient and are suitable as film base materials. Cyclic olefin-based resin film, for example, "ARTON" manufactured by JAYIDARE Co., Ltd. (glass transition temperature about 170 degrees Celsius, photoelastic coefficient about 4×10 -13 cm2/dyne), Sekisui Chemical Industry ( Co., Ltd.) "IDSHEENA" (glass transition temperature about 140 degrees Celsius, photoelastic coefficient about 6 × 10 -13 cm2/dyne) and other commercially available products. The thickness of the substrate on which the antireflection layer is provided is generally 10 to 1,000 micrometers.
又,直线偏光板/玻璃板/2片的光学补偿板的组成,较佳的是,在直线偏光板的外面也装设如上述那样的反射防止层。因具有反射防止层的直线偏光板亦为市售的,可将其原封不动地用于上述组成中的直线偏光板。In addition, in the composition of the linear polarizing plate/glass plate/two optical compensation plates, it is preferable that the above-mentioned antireflection layer is also provided on the outer surface of the linear polarizing plate. Since a linear polarizing plate having an antireflection layer is also commercially available, it can be used as it is for the linear polarizing plate in the above composition.
反射防止层的表面的接触角度为80度以上,较佳的是100度以上。在此所谓的接触角度是,使用水当液体时的值。当和空气相接的面的接触角度未满80度时,因为很容易附着微粒子,使用具有像那样表面的偏光转换元件的投射型液晶显示装置,在长期使用的场合,对比容易有降低的倾向。接触角度的上限为180度。The contact angle of the surface of the antireflection layer is 80 degrees or more, preferably 100 degrees or more. Here, the contact angle is a value when water is used as a liquid. When the contact angle of the surface in contact with the air is less than 80 degrees, fine particles are likely to adhere, and a projection-type liquid crystal display device having a polarizing conversion element with such a surface tends to decrease the contrast after long-term use. . The upper limit of the contact angle is 180 degrees.
当反射防止层的表面满足此处规定的接触角度的场合,具有反射防止层的反射防止膜或是直线偏光板可原封不动地应用于本发明的偏光转换元件。一般来说,反射防止层多的场合,因不具此处规定的接触角度,在此场合,由在反射防止层的上面装设由氟化物构成的层,以达成此接触角度。氟化合物所构成的层,可由包含此化合物涂布液的涂层(coating)以设置。为此目的采用的氟化物,并不特别限定其表面的接触角度为80度以上,通常采用防止表面污染的东西,例如,可采用含氟硅烷(siliane)化合物。像这样的化合物可防止在表面上附着指纹等的脏污。When the surface of the antireflection layer satisfies the contact angle specified here, the antireflection film having the antireflection layer or the linear polarizer can be applied to the polarization conversion element of the present invention as it is. Generally, when there are many antireflection layers, the contact angle specified here is not available. In this case, a layer made of fluoride is provided on the antireflection layer to achieve the contact angle. A layer composed of a fluorine compound can be provided by a coating liquid containing the compound. The fluoride used for this purpose is not particularly limited to a surface contact angle of 80 degrees or more, and is usually used to prevent surface contamination, for example, a fluorine-containing silane (siliane) compound can be used. Compounds like this prevent dirt such as fingerprints from sticking to the surface.
在由直线偏光板和光学补偿板叠合的偏光转换元件中,在直线偏光板的一面贴合相位差板亦可。此处所用的相位差板,和用于一般的液晶显示装置者相同,可以是由树脂构成者,例如可使用使基板膜往一轴方向延伸的相位差膜。树脂,举例而言为聚乙烯醇系树脂、包含具有芴骨架的变性聚碳酸酯的聚碳酸酯系树脂、像二乙醯纤维素或是三乙醯纤维素纤维素系树脂、原冰片烷系单体的聚合物的环状聚烯烃系树脂、聚砜系树脂、聚醚砜系树脂、聚酯系树脂、聚亚醯胺、聚醯胺、聚丙烯酸酯系树脂等。相位差板的厚一般为10~1,000微米。In the polarization conversion element in which a linear polarizing plate and an optical compensation plate are laminated, a retardation plate may be bonded to one side of the linear polarizing plate. The retardation plate used here may be made of resin, as is the case for general liquid crystal display devices, and for example, a retardation film in which a substrate film is extended in one axis direction may be used. Resins, for example, polyvinyl alcohol-based resins, polycarbonate-based resins containing denatured polycarbonate having a fluorene skeleton, cellulose-based resins such as diacetyl cellulose or triacetyl cellulose, orthobornane-based Cyclic polyolefin-based resins, polysulfone-based resins, polyethersulfone-based resins, polyester-based resins, polyimides, polyamides, polyacrylate-based resins, etc., which are polymers of monomers. The thickness of the retardation plate is generally 10 to 1,000 micrometers.
相位差板,较佳的是使用1/2波长板,例如,对于红光1/2波长板为290~320nm,较佳的是具有300~310nm的延迟(retardation)者,对于绿光1/2波长板为260~290nm,较佳的是具有270~280nm的延迟者,而对于蓝光1/2波长板为210~240nm,较佳的是具有220~230nm的延迟者。可用市售的相位差板,举例而言,对于蓝光来说,可采用由住友化学(股)所贩卖的“SMICALITE SEF460225”(由聚碳酸酯系树脂所构成,玻璃转换温度约为摄氏150度,延迟约为225nm者)等,对于绿光来说,可采用同样由住友化学(股)所出售的“SMICALITESEF460275”(由聚碳酸酯系树脂所构成,玻璃转换温度约为摄氏150度,延迟约为275nm)等,对于红光来说,可采用同样由住友化学(股)所出售的“SMICALITE SEF460305”(由聚碳酸酯系树脂所构成,玻璃转换温度约为摄氏150度,延迟约为305nm)等。相位差板亦可原封不动地使用延伸膜,其一面或两面亦可采用叠合像是二乙酸纤维素或是二乙酸纤维素的纤维素系树脂所构成的保护膜的状态。Retardation plate, it is preferable to use 1/2 wavelength plate, for example, for
相位差板的形状一般是略和直线偏光板相同,又,和透明玻璃板的形状约略相同,或是略小亦可。而,相位差板的外面,即具有和空气相接面的场合时,在其相位差板的外面装设反射防止层,较佳的是,此面的接触角为80度以上。在此所谓的接触角亦为用水当作液体的场合的值。在相位差外面装设的反射防止层,和装设在如先前所述的直线偏光板或是光学补偿板外面的反射防止层相同者。而且,当具有反射防止层的面满足此处规定的接触角度时,具有反射防止层的相位差板亦可原封不动地适用本发明的偏光转换元件。但是,在一般反射防止层多的场合,因没有此处规定的接触角度,在此场合,反射防止层的上面亦可设置氟化物所构成的层。由氟化物所构成层的具体例及装设方法和上述的说明相同。The shape of the phase difference plate is generally the same as that of the linear polarizer, and the shape of the transparent glass plate is roughly the same, or it can be slightly smaller. On the other hand, when the phase difference plate has a surface in contact with the air, an anti-reflection layer is provided on the outside of the phase difference plate. Preferably, the contact angle of this surface is 80 degrees or more. The contact angle referred to here is also a value when water is used as a liquid. The antireflection layer provided on the outside of the phase difference is the same as the antireflection layer provided on the outside of the linear polarizing plate or the optical compensation plate as described above. Furthermore, when the surface having the antireflection layer satisfies the contact angle specified here, the polarized light conversion element of the present invention can also be applied to the retardation film having the antireflection layer as it is. However, in the case of many antireflection layers, there is no contact angle specified here. In this case, a layer made of fluoride may be provided on the antireflection layer. Specific examples and mounting methods of the layer made of fluoride are the same as those described above.
图1~图2为本发明的偏光转换元件的例示。如图1,叠合直线偏光板21和光学补偿板22、23,在其直线偏光板21侧贴合玻璃板24,在光学补偿板23侧,把设有反射防止层27的透明膜26以反射防止层27在外侧的方式贴合,以构成偏光转换元件20。在往玻璃板24的直线偏光板21贴合面的相反侧的外面,设有反射防止层28。光学补偿板22和23以其配向轴直交的方式配置。又,较佳的是,涂布液晶性化含物的面,和反对的面以重合的方式配置。当玻璃板具有异方性的场合,其结晶轴和透过偏光的偏光轴需为平行或直交,蓝宝石的C轴和透过偏光的偏光轴以平行或直交的方式配置。图2,在图1加入层结构,在直线偏光板21和玻璃板24之间配置相位差板25,以构成偏光转换元件20。1 to 2 are examples of the polarization conversion element of the present invention. As shown in Fig. 1, the linear
当然,本发明的偏光转换元件的层结构并不限于图中的例示,举例而言,可像先前说明的那样,把直线偏光板叠合到玻璃板一边的面,把2片的光学补偿板叠合到另边的面。在此场合,亦可往直线偏光板的玻璃板贴合面的相反侧配置相位差板。较佳的是,在直线偏光板或相位差板的空气相接的面上,设置反射防止层,更较佳的是,在和光学补偿板相接的面上,设有反射防止层。Of course, the layer structure of the polarization conversion element of the present invention is not limited to the illustration in the figure. For example, as previously explained, a linear polarizer can be laminated to one side of a glass plate, and two optical compensation plates Fold to the other face. In this case, the phase difference plate may be disposed on the opposite side of the glass plate bonding surface of the linear polarizing plate. Preferably, an anti-reflection layer is provided on the surface of the linear polarizer or phase difference plate that is in contact with air, more preferably, an anti-reflection layer is provided on the surface that is in contact with the optical compensation plate.
图3,为构成本发明的偏光转换元件的直线偏光板和光学补偿板的轴角度关系。在直线偏光板21一边的面上,叠合2片光学补偿板,即叠合第1光学补偿板22和第2光学补偿板23时轴角度的关系,在此场合,直线偏光板21的吸收轴(箭头)和第1光学补偿板22的配向轴(箭头)以略直交的方式配置,第2光学补偿板23,其配向轴(箭头)和第1光学补偿板的配向轴直交,因此,以和直线偏光板21的吸收轴平行的方式配置。又,2片的光学补偿板是以涂布液晶性化合物的面和其反对的面相面对的方式配置。图4和图5,为构成本发明的偏光转换元件的直线偏光板和光学补偿板轴角度的关系。其绘示,在直线偏光板21一边的面上,叠合2片的光学补偿板,即叠合第1光学补偿板22和第2光学补偿板23时轴角度的关系,在此场合,直线偏光板21的吸收轴和第1光学补偿板22的配向轴以略平行的方式配置,第2光学补偿板23,其配向轴是和第1光学补偿板的配向轴直交,因此,是以和直线偏光板21的吸收轴直交的方式配置。2片的光学补偿板是,和图3的场合相同,以涂布液晶性化合物的面和反对的面相面对的方向配置。Fig. 3 is the axis-angle relationship of the linear polarizer and the optical compensation plate constituting the polarization conversion element of the present invention. On the surface of one side of the linear
本发明的偏光转换元件,较佳的是,可适用于投射型液晶显示装置。例如,在投射型液晶显示装置中,可插入并使用从白色光源而来的白光光路中,或是白光分光的后的红光、绿光或是蓝光的各原色光的光路中。Preferably, the polarization conversion element of the present invention can be applied to a projection type liquid crystal display device. For example, in a projection-type liquid crystal display device, it can be inserted and used in the optical path of white light from a white light source, or in the optical path of each primary color light of red, green, or blue light after splitting the white light.
具体而言,在图6绘示的投射型液晶显示装置中,可使用对应各三原色的液晶单元7R、7G、7B的入射侧偏光转换元件8R、8G、8B,或是出射侧偏光转换元件9R、9G、9B中之一。此偏光转换元件,一般是把光学补偿板配置在比玻璃板更靠近液晶单元7R、7G、7B之侧。Specifically, in the projection-type liquid crystal display device shown in FIG. 6 , the incident-side
虽然,也有以单板形式,把从滤色镜(color filter)而来的分光光直接放大的投射型液晶显示装置,在此场合中,是在白光的光路中配置本发明的偏光转换元件。Although, there is also a projection type liquid crystal display device that directly amplifies the spectroscopic light coming from a color filter in the form of a single plate. In this case, the polarization conversion element of the present invention is arranged in the optical path of white light.
实施例Example
以下,虽以具体的实施例详细地说明本发明,然而,本发明并不限定于此例。Hereinafter, although the present invention will be described in detail using specific examples, the present invention is not limited to these examples.
对比由亮显示的照度L1及暗显示的照度L2,利用其次的式子算出。Comparing the illuminance L1 of bright display and the illuminance L2 of dark display, it is calculated by the following formula.
对比C=L1/L2 式(1)Contrast C=L1/L2 Formula (1)
实施例1Example 1
在由KYOCERA(股)所出售的对角0.9英时的蓝宝石玻璃板的一边上,透过黏着剂贴合住友化学工业所出售的聚乙烯醇/二色性染料是直线偏光板“SMICARANE SWW832A”和富士照片(股)所出售的光学补偿板“WIDE VIEW WVA02B”2片。直线偏光板和2片的光学补偿板是,和图3所示为相同的配置。2片的光学补偿板分别把液晶性化合物涂布面和反对侧的面,以面对面的方式贴合。在此光学补偿板和空气的接触面上,其一边把具有反射防止层厚度80微米的透明膜做在反射防止层的外侧,透过黏着剂贴合以制作出偏光转换元件。On one side of a 0.9-inch diagonal sapphire glass plate sold by KYOCERA Co., Ltd., a polyvinyl alcohol/dichroic dye sold by Sumitomo Chemical Industry is a linear polarizer "SMICARANE SWW832A" through an adhesive. And two optical compensation plates "WIDE VIEW WVA02B" sold by Fuji Photo Co., Ltd. The linear polarizing plate and the two optical compensation plates are the same arrangement as shown in Fig. 3 . Two optical compensation plates are bonded face to face with the liquid crystal compound-coated side and the opposite side, respectively. On the contact surface between the optical compensation plate and the air, a transparent film with an anti-reflection layer thickness of 80 microns is made on the outside of the anti-reflection layer on one side, and bonded through an adhesive to produce a polarization conversion element.
在投射型液晶显示装置(液晶放映机)中,在绿频道(channel)的液晶单元的光源侧,该偏光转换元件被设定(set)成,光学补偿板比蓝宝石玻璃板更靠近液晶单元侧,只让绿光投影到屏幕上且测定的对比为550。比较例In the projection type liquid crystal display device (liquid crystal projector), on the light source side of the liquid crystal cell of the green channel (channel), the polarization conversion element is set so that the optical compensation plate is closer to the liquid crystal cell side than the sapphire glass plate, Only green light was projected onto the screen and a contrast of 550 was measured. comparative example
除了不使用光学补偿板以外,其余和实施例1相同,制作偏光转换元件。更同样地测出对比,其为300。Except that the optical compensation plate is not used, the rest is the same as that of
实施例2Example 2
在KYOCERA(股)所出售的对角0.9英时的蓝宝石玻璃板的一边上,透过接着剂依序贴合住友化学工业(股)所出售的聚乙烯醇系相位差板“SMICALITE SEF460275”和同样是住友化学所出售的聚乙烯醇/二色性染料是直线偏光板“SMICARANE SWW832A”。再于此直线偏光板的表面上,如图3所示同样地配置由富士照片(股)所出售的光学补偿板“Wide View WVA02B”。2片的光学补偿板,透过接着剂,面对面分别地贴合液晶性化合物涂布面和其反对面。在光学补偿板和空气的接触面上,和实施例1同样的在一边上,透过接着剂,贴合具有反射防止层厚度80微米的透明膜,以制作偏光转换元件。On one side of a 0.9-inch diagonal sapphire glass plate sold by KYOCERA Co., Ltd., the polyvinyl alcohol-based phase difference plate "SMICALITE SEF460275" sold by Sumitomo Chemical Co., Ltd. and The polyvinyl alcohol/dichroic dye also sold by Sumitomo Chemical is a linear polarizing plate "SMICARANE SWW832A". On the surface of this linear polarizing plate, an optical compensation plate "Wide View WVA02B" sold by Fuji Photo Co., Ltd. was similarly arranged as shown in FIG. 3 . The two optical compensation plates are bonded face-to-face with the liquid crystal compound-coated surface and the opposite surface through the adhesive agent. On the contact surface of the optical compensation plate and the air, on one side as in Example 1, a transparent film having a thickness of 80 μm of an anti-reflection layer was attached through an adhesive to produce a polarization conversion element.
实施例3Example 3
除了把相位差板变更成由住友化学工业(股)所出售的聚碳酸酯系相位差板“SMICALITE SEF460305”以外,其余和实施例2相同,以制作出偏光转换元件。Except that the retardation plate was changed to a polycarbonate-based retardation plate “SMICALITE SEF460305” sold by Sumitomo Chemical Co., Ltd., the rest was the same as in Example 2 to produce a polarization conversion element.
实施例4Example 4
除了把相位差板变更成由住友化学工业(股)所出售的聚碳酸酯系相位差板“SMICALITE SEF460225”,且把偏光板变更成由住友化学工业(股)所出售的聚乙烯醇/二色性染料系直线偏光板以外,其余和实施例2相同,以制作出偏光转换元件。In addition to changing the retardation plate to the polycarbonate-based retardation plate “SMICALITE SEF460225” sold by Sumitomo Chemical Co., Ltd., and changing the polarizer to polyvinyl alcohol/di Except that the chromatic dye is a linear polarizing plate, the rest are the same as in Example 2 to manufacture a polarization conversion element.
实施例5Example 5
在投射型液晶显示装置(液晶放映机)的液晶单元的出射侧上,把在实施例2、实施例3、实施例4所制作的偏光转换元件设定成,分别在绿频道、红频道、蓝频道的投射透镜侧上,光学补偿板比蓝宝石玻璃板更靠近液晶单元侧,屏幕上的对比可提升非常多,黑显示的画面不均也会变小,而使得显示品质提高。比较例2On the exit side of the liquid crystal unit of the projection type liquid crystal display device (liquid crystal projector), the polarization conversion elements made in
除了叠合了1片光学补偿板以外,其余和实施例2、3、4相同,以制作出偏光转换元件,并和实施例5相同,设定出投射型液晶显示装置(液晶放映机)时,其屏幕上的对比不会上升,显示品质亦不会提高。Except stacking 1 optical compensation plate, all the other are the same as
实施例7Example 7
除了在光学补偿板和空气的接触面上,一边无叠合具有反射防止层的透明膜以外,其余和实施例2、3、4相同,以制作出偏光转换元件,并和实施例5相同,以设定成投射型液晶显示装置(液晶放映机)时,屏幕上的对比会稍微提升,黑显示的画面不均会减少,显示品质并没有提升得那么高。Except that on the contact surface between the optical compensation plate and the air, there is no laminated transparent film with an anti-reflection layer on one side, all the other are the same as in Examples 2, 3, and 4 to make a polarization conversion element, and are the same as in Example 5, When it is set as a projection type liquid crystal display device (liquid crystal projector), the contrast on the screen will be slightly improved, and the unevenness of the black display screen will be reduced, but the display quality is not so high.
因为本发明的偏光转换元件是,配置直线偏光板,并在其一边的面配置2片光学补偿板,可有效地应用于投射型液晶显示装置,把此偏光转换元件配置在液晶单元的入射/或出射侧的投射型液晶显示装置,投射影像的对比高、黑显示的画面不均会减少,因而可提高显示品质。Because the polarization conversion element of the present invention is to configure a linear polarizing plate, and configure two optical compensation plates on one side of it, it can be effectively applied to a projection type liquid crystal display device, and this polarization conversion element is configured on the incident/ Or the projection-type liquid crystal display device on the output side, the contrast of the projected image is high, and the unevenness of the black display screen is reduced, so the display quality can be improved.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100378533C (en) * | 2004-09-29 | 2008-04-02 | 精工爱普生株式会社 | Projection-type display device |
| US7593076B2 (en) | 2006-02-24 | 2009-09-22 | Seiko Epson Corporation | Optical device and method for manufacturing optical device |
| CN1993647B (en) * | 2005-03-15 | 2010-05-19 | 索尼株式会社 | Retardation compensation sheet, retardation compensator, liquid crystal display device, and projection image display |
| CN102426401A (en) * | 2003-07-31 | 2012-04-25 | 住友化学株式会社 | Polarization conversion element and reflective liquid crystal projector using it |
| CN106094237A (en) * | 2016-08-23 | 2016-11-09 | 孟玲 | Optical unit and the projection-type liquid crystal display device of this optical unit of use |
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2002
- 2002-05-23 CN CN 02120370 patent/CN1388387A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102426401A (en) * | 2003-07-31 | 2012-04-25 | 住友化学株式会社 | Polarization conversion element and reflective liquid crystal projector using it |
| CN100378533C (en) * | 2004-09-29 | 2008-04-02 | 精工爱普生株式会社 | Projection-type display device |
| CN1993647B (en) * | 2005-03-15 | 2010-05-19 | 索尼株式会社 | Retardation compensation sheet, retardation compensator, liquid crystal display device, and projection image display |
| US7593076B2 (en) | 2006-02-24 | 2009-09-22 | Seiko Epson Corporation | Optical device and method for manufacturing optical device |
| CN106094237A (en) * | 2016-08-23 | 2016-11-09 | 孟玲 | Optical unit and the projection-type liquid crystal display device of this optical unit of use |
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