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CN1380360A - Method for making plastic sports ground and track by adopting nano material modified polyurethane - Google Patents

Method for making plastic sports ground and track by adopting nano material modified polyurethane Download PDF

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Publication number
CN1380360A
CN1380360A CN 01114616 CN01114616A CN1380360A CN 1380360 A CN1380360 A CN 1380360A CN 01114616 CN01114616 CN 01114616 CN 01114616 A CN01114616 A CN 01114616A CN 1380360 A CN1380360 A CN 1380360A
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China
Prior art keywords
nano material
modified polyurethane
material modified
component
runway
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CN 01114616
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CN1174050C (en
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师永昌
师建华
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Abstract

The present invention discloses a method for making plastic attletic field and track by using nano material modified polyurethane, and is characterized by that it selects and uses the nano materials of nano calcium carbonate and nano magnesium carbnate.

Description

Adopt nano material modified polyurethane to make the method for plastic sports ground and runway
The present invention relates to the manufacture method of plastic sports ground and runway, particularly adopt nano material modified polyurethane to make the method for plastic sports ground and runway.
The plastic sports ground of international standard and runway, the one, the employing polyurethane material is a main body, its shortcoming is that above-mentioned materials has little poison; The 2nd, adopt elastomeric material, its shortcoming is to involve great expense.The method of state-of-the-art making plastic sports ground of China and runway such as Chinese patent application number are 99107376.2 and 99106282.5 disclosed, its shortcoming is not adopt nano material to handle urethane resin at that time, so the product cost of making is higher, and it is slightly toxic, various technical indicators, as anti-oxidant, gasproof marquis, tint retention, anti-thickness etc., all not really desirable.
The objective of the invention is at above-mentioned shortcoming, introduce international up-to-date nanotechnology, adopt nano material modified polyurethane to make the method for plastic sports ground and race, not only reduce cost of manufacture, the product nontoxicity meets international standards, and obviously improve every technical indicator, make athletic ground and runway bring up to the level of renewal.
The object of the present invention is achieved like this:
Material mixture ratio of the present invention is (as follows) by weight percentage
1, preparation A component:
Take by weighing 10-50% two different hydrogen acid ethers, the dihydroxyl polyvalent alcohol of 70-90% and the nano material of 0.1-10%: nano-calcium carbonate, nano-calcium carbonate magnesium, uniform mixing is made the A component.
2, preparation B component:
Take by weighing the MOCA (3 of 0-4%, 3-two chloro-4, the 4-methylene-dianiline), the trihydroxy-of 0.3-10%, the tetrahydroxy polyvalent alcohol, the nano material of 0.01-40%: nano-calcium carbonate, nano-calcium carbonate magnesium, the stopping composition of 5-50%: talcum powder, lime carbonate, kaolin, the tenderizer of 10-55%: clorafin, the oxidation inhibitor of 0.01-0.1%: the four seasons penta tetrol, 1,3,5-trimethylammonium-2,4,6 triphens, the UV light absorber of 0.01-0.1% (UV-9), the pigment of 0.1-2%: red iron oxide, the phthalein viridescent, phthalocyanine blue, the sea is brilliant blue, chrome green, permanent bordeaux, permanent yellow, solid forever orange, orange forever etc., uniform mixing is made the B component.
3, preparation nano material modified polyurethane:
Above-mentioned A component, B component and catalyzer: superoxide, zinc naphthenate or lead, isocaprylic acid lead, in following ratio A group: B group: catalyzer=1: 1-4: the 0.05-0.13 uniform mixing, make nano material modified polyurethane.
4, lay athletic ground or runway:
Add stopping composition such as the damaged tire particle of 0-25%, old rubber grain at above-mentioned nano material modified polyurethane, press the thickness of 1-10 millimeter, be laid on the basal layer spontaneous curing, formation plastic cement race track primer layer with Slicking apparatus.The nano material modified polyurethane of coating 1-3 millimeter on primer layer, become mesogloea, sowing the particle diameter that the sheet material made by nano material modified polyurethane is ground into again is the particle of 2-5 millimeter, naturally bonding, form the runway skid resistant surface, wipe the particle that floating of skid resistant surface off, apply the nano material modified polyurethane of one deck 0.1-0.5 millimeter thickness then with the Slicking apparatus brute force, nano material modified polyurethane plastic sports ground and runway are promptly made in spontaneous curing, setting-out.
Adopt the present invention, the manufacturing cost of plastic sports ground and runway is reduced, the product nontoxicity meets international standards, and obviously improves the every technical indicator of product (seeing following table for details).
Performance is compared as follows table:
Project National standard Measured result Effect
Hardness (Shao Shi A) ????45-60 ????50 Meet
Tensile strength at yield Mpa 〉= ????0.7 ????1.5 ??114%
Draw elongation % 〉= ????90 ????260 ??190%
Rebound value % 〉= ????20 ????32 ??60%
Flame retardant rating ????1 ????1 Meet
International nontoxic require the content % of standard TDI trip drench amount in solidifying agent≤ ????0.5 ????0.48 Meet
In conjunction with the embodiments, further describe the present invention:
Embodiment one: make not threshing plastic cement motion runway
1, preparation A component:
Take by weighing 160kg two different hydrogen acid ethers, the dihydroxyl polyvalent alcohol of 600kg and the nano-calcium carbonate of 0.8kg, uniform mixing is made the A component.
2, preparation B component:
Take by weighing the MOCA (3 of 6kg, 3-two chloro-4, the 4-methylene-dianiline), the nano-calcium carbonate of the trihydroxy-of 11.2kg and tetrahydroxy polyvalent alcohol, 10kg, the talcum powder of 44kg, the clorafin of 76kg, 0.01kg the UV light absorber (UV-9) of the four seasons penta tetrol 0.01kg, the red iron oxide uniform mixing of 2kg is made the B component.
3, preparation nano material modified polyurethane:
Above-mentioned A component, B component and lead naphthenate, zinc mixture in 1: 2: 0.08 uniform mixing of following ratio, are made nano material modified polyurethane.
4, lay not threshing plastic cement motion runway:
Damaged tire particle in above-mentioned nano material modified polyurethane adding 25% with the thickness of Slicking apparatus by 10 millimeters, is laid on the basal layer, and spontaneous curing forms the plastic cement race track primer layer.On primer layer, apply 1.5 millimeters nano material modified polyurethane, become mesogloea, sow particle diameter that the sheet material made by nano material modified polyurethane is ground into again and be 4 millimeters particle, naturally bonding, form the runway skid resistant surface, wipe the particle that floating of skid resistant surface off with the Slicking apparatus brute force, then, the nano modified polyurethane spontaneous curing of coating one deck 0.5 mm thick, setting-out promptly constitutes not threshing of nano material modified polyurethane plastic cement motion runway.
Embodiment two: make plastic cement motion basketball place:
1, preparation A component:
Take by weighing 170kg two different hydrogen acid ethers, the dihydroxyl polyvalent alcohol of 600kg and the nano-calcium carbonate of 0.8kg, uniform mixing is made the A component.
2, preparation B component:
Take by weighing the MOCA (3 of 6kg, 3-two chloro-4, the 4-methylene-dianiline), the nano-calcium carbonate of the trihydroxy-of 11.2kg and tetrahydroxy polyvalent alcohol, 10kg, the talcum powder of 44kg, the clorafin of 76kg, 0.01kg the UV light absorber (UV-9) of the four seasons penta tetrol 0.01kg, the red iron oxide uniform mixing of 2kg is made the B component.
3, preparation nano material modified polyurethane:
Above-mentioned A component, B component and lead naphthenate, zinc mixture in 1: 2: 0.08 uniform mixing of following ratio, are made nano material modified polyurethane.
4, lay plastic cement basketball place:
Damaged tire particle in above-mentioned nano material modified polyurethane adding 25% with the thickness of Slicking apparatus by 5 millimeters, is laid on the basal layer, and spontaneous curing forms the plastic cement race track primer layer.On primer layer, apply 2 millimeters nano material modified polyurethane, spontaneous curing, setting-out promptly constitutes 7 millimeters nano material modified polyurethane plastic cement motion basketball fields.

Claims (2)

1, adopt nano material modified polyurethane to make the method for plastic sports ground and runway, it is characterized in that:
(1) preparation A component:
Take by weighing the dihydroxyl polyvalent alcohol of 10-50% two different hydrogen acid ethers, 70-90% and the nano material uniform mixing of 0.1-10% and make the A component;
(2) preparation B component:
Take by weighing the MOCA (3 of 0-4%, 3-two chloro-4, the 4-methylene-dianiline), the polyvalent alcohol of 0.3-10%, the nano material of 0.01-40%, the stopping composition of 5-50%, the tenderizer of 10-55%, the oxidation inhibitor of 0.01-0.1%, the UV light absorber of 0.01-0.1% (UV-9), the pigment of 0.1-2%, uniform mixing are made the B component;
(3) preparation nano material modified polyurethane:
Above-mentioned A component, B component and catalyzer are organized in following ratio A: B group: catalyzer=1: 1-4: the 0.05-0.13 uniform mixing, make nano material modified polyurethane;
(4) lay athletic ground or runway:
The damaged tire particle that adds 0-25% at above-mentioned nano material modified polyurethane, stopping composition such as old rubber grain, press the thickness of 1-10 millimeter with Slicking apparatus, be laid on the basal layer, spontaneous curing, form the plastic cement race track primer layer, the nano material modified polyurethane of coating 1-3 millimeter on primer layer, become mesogloea, sowing the particle diameter that the sheet material made by nano material modified polyurethane is ground into again is the particle of 2-5 millimeter, naturally bonding, form the runway skid resistant surface, wipe the particle that floating of skid resistant surface off with the Slicking apparatus brute force, apply the nano material modified polyurethane of one deck 0.1-0.5 millimeter thickness then, spontaneous curing, nano material modified polyurethane plastic sports ground and runway are promptly made in setting-out.
2, employing nano material modified polyurethane according to claim 1 is made the method for plastic sports ground and runway, it is characterized in that, above-mentioned nano material is a nano-calcium carbonate, nano-calcium carbonate magnesium, polyvalent alcohol is a trihydroxy-, tetrahydroxy, tenderizer is a clorafin, weighting agent is a talcum powder, lime carbonate, kaolin, oxidation inhibitor is pentaerythritol tetrathioglycollate 1,3,5-trimethylammonium-2,4, the 6-triphen, pigment is red iron oxide, the Chinese is husky yellow, the phthalein viridescent, the blue or green basket of phthalein, the sea is brilliant blue, chrome green, permanent yellow, solid forever orange, orange forever, catalyzer is a superoxide, zinc naphthenate or lead, isocaprylic acid lead.
CNB011146168A 2001-04-11 2001-04-11 Method for making plastic sports ground and track by adopting nano material modified polyurethane Expired - Lifetime CN1174050C (en)

Priority Applications (1)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103153594A (en) * 2010-09-01 2013-06-12 诺亚系统有限公司 Floor covering and method for producing the same
CN104292812A (en) * 2014-11-03 2015-01-21 苏州钧隆塑胶有限公司 Plastic used for racecourse
CN105419307A (en) * 2016-01-21 2016-03-23 苏州法斯特信息科技有限公司 Environment-friendly polyurethane composite plastic runway material and preparation method thereof
CN105949751A (en) * 2016-07-06 2016-09-21 苏州亚科塑胶有限公司 Preparation method of anti-skid, abrasion-resistant and high-elasticity composite plastic runway surface layer
CN106189793A (en) * 2016-07-11 2016-12-07 新昌县绿泰塑胶有限公司 A kind of flame-retardant polyurethane plastic cement race track material and construction method thereof
CN106398186A (en) * 2016-09-22 2017-02-15 许昌学院 Environment-friendly plastic slurry for sports ground and preparation method of environment-friendly plastic slurry
CN106589304A (en) * 2016-12-06 2017-04-26 安徽潜源教学设备有限公司 High-durability polyurethane plastic runway and preparation method thereof
CN106589303A (en) * 2016-12-06 2017-04-26 安徽潜源教学设备有限公司 Polyurethane plastic runway easy to clean and maintain and preparation method thereof
CN106939070A (en) * 2017-03-24 2017-07-11 张家港市金马克塑胶科技有限公司 Can be with the plastic cement road surface of releasing negative oxygen ion and its manufacture method
CN107057119A (en) * 2017-04-21 2017-08-18 深圳航天科技创新研究院 Environmentally friendly full-plastic plastic cement race track compounded mix and preparation method thereof
CN108102068A (en) * 2016-11-25 2018-06-01 丹阳市雅本化工技术有限公司 A kind of plastic cement race track and preparation method thereof
CN108948310A (en) * 2018-07-21 2018-12-07 济宁市伟松环保产品有限公司 A kind of silicon PU sports ground pavement material and its manufacturing method
CN111423713A (en) * 2020-05-15 2020-07-17 全洪晖 Water-based silicon PU plastic track material and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101085860B (en) * 2007-06-08 2010-08-25 江苏大学 Method of preparing water polyurethane urea/modified nano CaCO3 organic-inorganic hybridization material

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103153594A (en) * 2010-09-01 2013-06-12 诺亚系统有限公司 Floor covering and method for producing the same
US9303412B2 (en) 2010-09-01 2016-04-05 Nora Systems Gmbh Floor covering and method for producing the same
CN103153594B (en) * 2010-09-01 2016-08-03 诺亚系统有限公司 Mulching material and production method thereof
CN104292812A (en) * 2014-11-03 2015-01-21 苏州钧隆塑胶有限公司 Plastic used for racecourse
CN105419307A (en) * 2016-01-21 2016-03-23 苏州法斯特信息科技有限公司 Environment-friendly polyurethane composite plastic runway material and preparation method thereof
CN105949751A (en) * 2016-07-06 2016-09-21 苏州亚科塑胶有限公司 Preparation method of anti-skid, abrasion-resistant and high-elasticity composite plastic runway surface layer
CN106189793A (en) * 2016-07-11 2016-12-07 新昌县绿泰塑胶有限公司 A kind of flame-retardant polyurethane plastic cement race track material and construction method thereof
CN106398186A (en) * 2016-09-22 2017-02-15 许昌学院 Environment-friendly plastic slurry for sports ground and preparation method of environment-friendly plastic slurry
CN108102068A (en) * 2016-11-25 2018-06-01 丹阳市雅本化工技术有限公司 A kind of plastic cement race track and preparation method thereof
CN106589303A (en) * 2016-12-06 2017-04-26 安徽潜源教学设备有限公司 Polyurethane plastic runway easy to clean and maintain and preparation method thereof
CN106589304A (en) * 2016-12-06 2017-04-26 安徽潜源教学设备有限公司 High-durability polyurethane plastic runway and preparation method thereof
CN106939070A (en) * 2017-03-24 2017-07-11 张家港市金马克塑胶科技有限公司 Can be with the plastic cement road surface of releasing negative oxygen ion and its manufacture method
CN107057119A (en) * 2017-04-21 2017-08-18 深圳航天科技创新研究院 Environmentally friendly full-plastic plastic cement race track compounded mix and preparation method thereof
CN107057119B (en) * 2017-04-21 2019-02-01 深圳航天科技创新研究院 Environmentally friendly full-plastic plastic cement race track compounded mix and preparation method thereof
CN108948310A (en) * 2018-07-21 2018-12-07 济宁市伟松环保产品有限公司 A kind of silicon PU sports ground pavement material and its manufacturing method
CN111423713A (en) * 2020-05-15 2020-07-17 全洪晖 Water-based silicon PU plastic track material and preparation method thereof

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