CN1231559C - 采用三个催化剂区制备富芳烃产物的催化重整方法 - Google Patents

采用三个催化剂区制备富芳烃产物的催化重整方法 Download PDF

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Publication number: CN1231559C
Authority: CN; China
Prior art keywords: catalyst; zeolite; final; reforming; reforming catalyst
Prior art date: 1997-11-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CNB991062892A

Other languages

English (en)

Chinese (zh)

Other versions

CN1267708A (zh

Inventor

B·K·格劳瓦

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Honeywell UOP LLC

Universal Oil Products Co

Original Assignee

Universal Oil Products Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1997-11-04

Filing date

1999-03-23

Publication date

2005-12-14

1997-11-04 Priority to US08/963,739 priority Critical patent/US5885439A/en

1999-03-16 Priority to ZA9902109A priority patent/ZA992109B/xx

1999-03-17 Priority to CA002266218A priority patent/CA2266218C/en

1999-03-17 Priority to TW088104136A priority patent/TW513483B/zh

1999-03-19 Priority to JP07672899A priority patent/JP4344037B2/ja

1999-03-19 Priority to SG9901401A priority patent/SG87026A1/en

1999-03-22 Priority to ES99105744T priority patent/ES2215341T3/es

1999-03-22 Priority to RU99105929/04A priority patent/RU2204585C2/ru

1999-03-22 Priority to BR9901180-8A priority patent/BR9901180A/pt

1999-03-22 Priority to PT99105744T priority patent/PT1038943E/pt

1999-03-22 Priority claimed from KR1019990009601A external-priority patent/KR100555172B1/ko

1999-03-22 Priority to AT99105744T priority patent/ATE261487T1/de

1999-03-22 Priority to DE69915447T priority patent/DE69915447T2/de

1999-03-22 Priority to EP99105744A priority patent/EP1038943B1/en

1999-03-23 Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co

1999-03-23 Priority to CNB991062892A priority patent/CN1231559C/zh

2000-09-27 Publication of CN1267708A publication Critical patent/CN1267708A/zh

2005-12-14 Publication of CN1231559C publication Critical patent/CN1231559C/zh

2005-12-14 Application granted granted Critical

2019-03-23 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 title claims abstract description 141
238000000034 method Methods 0.000 title claims abstract description 45
150000004945 aromatic hydrocarbons Chemical class 0.000 title claims abstract description 33
238000001833 catalytic reforming Methods 0.000 title claims abstract description 11
230000008569 process Effects 0.000 title description 15
238000002407 reforming Methods 0.000 claims abstract description 78
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 66
239000010457 zeolite Substances 0.000 claims abstract description 66
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 58
229930195733 hydrocarbon Natural products 0.000 claims abstract description 56
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 56
229910052751 metal Inorganic materials 0.000 claims abstract description 36
239000002184 metal Substances 0.000 claims abstract description 36
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 34
230000002378 acidificating effect Effects 0.000 claims abstract description 8
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 50
239000001257 hydrogen Substances 0.000 claims description 27
229910052739 hydrogen Inorganic materials 0.000 claims description 27
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 26
229910052697 platinum Inorganic materials 0.000 claims description 23
239000000203 mixture Substances 0.000 claims description 20
230000008521 reorganization Effects 0.000 claims description 14
229910052809 inorganic oxide Inorganic materials 0.000 claims description 13
229910052736 halogen Inorganic materials 0.000 claims description 12
150000002367 halogens Chemical class 0.000 claims description 12
239000003795 chemical substances by application Substances 0.000 claims description 8
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
229910052738 indium Inorganic materials 0.000 claims description 5
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 5
229910052700 potassium Inorganic materials 0.000 claims description 5
239000011591 potassium Substances 0.000 claims description 5
239000007788 liquid Substances 0.000 claims description 4
229910052702 rhenium Inorganic materials 0.000 claims description 4
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 4
150000002739 metals Chemical class 0.000 claims 1
239000002994 raw material Substances 0.000 abstract description 15
238000005516 engineering process Methods 0.000 abstract description 9
-1 platinum group metals Chemical class 0.000 abstract description 7
238000012545 processing Methods 0.000 abstract description 6
230000001172 regenerating effect Effects 0.000 abstract description 6
230000003197 catalytic effect Effects 0.000 abstract description 4
238000004519 manufacturing process Methods 0.000 abstract description 2
230000001588 bifunctional effect Effects 0.000 abstract 2
238000006243 chemical reaction Methods 0.000 description 29
239000007789 gas Substances 0.000 description 26
239000008187 granular material Substances 0.000 description 19
239000000047 product Substances 0.000 description 19
230000008929 regeneration Effects 0.000 description 17
238000011069 regeneration method Methods 0.000 description 17
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 16
229910052760 oxygen Inorganic materials 0.000 description 16
239000001301 oxygen Substances 0.000 description 16
238000002485 combustion reaction Methods 0.000 description 14
239000002245 particle Substances 0.000 description 14
239000000571 coke Substances 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
238000002360 preparation method Methods 0.000 description 10
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
229910052799 carbon Inorganic materials 0.000 description 9
150000001875 compounds Chemical class 0.000 description 9
230000009467 reduction Effects 0.000 description 9
239000000126 substance Substances 0.000 description 9
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
238000009835 boiling Methods 0.000 description 8
238000001035 drying Methods 0.000 description 8
239000005864 Sulphur Substances 0.000 description 7
230000000694 effects Effects 0.000 description 7
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
238000009395 breeding Methods 0.000 description 6
230000001488 breeding effect Effects 0.000 description 6
238000006356 dehydrogenation reaction Methods 0.000 description 6
230000003647 oxidation Effects 0.000 description 6
238000007254 oxidation reaction Methods 0.000 description 6
229910052717 sulfur Inorganic materials 0.000 description 6
239000000460 chlorine Substances 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 5
239000011593 sulfur Substances 0.000 description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
230000009471 action Effects 0.000 description 4
229910052728 basic metal Inorganic materials 0.000 description 4
150000003818 basic metals Chemical class 0.000 description 4
125000004122 cyclic group Chemical group 0.000 description 4
238000006317 isomerization reaction Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
239000012188 paraffin wax Substances 0.000 description 4
239000000843 powder Substances 0.000 description 4
238000002203 pretreatment Methods 0.000 description 4
238000006057 reforming reaction Methods 0.000 description 4
229910052814 silicon oxide Inorganic materials 0.000 description 4
239000002594 sorbent Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
230000004913 activation Effects 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000012298 atmosphere Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000001354 calcination Methods 0.000 description 3
238000004517 catalytic hydrocracking Methods 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000002808 molecular sieve Substances 0.000 description 3
239000003921 oil Substances 0.000 description 3
239000003208 petroleum Substances 0.000 description 3
239000010970 precious metal Substances 0.000 description 3
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
229910052692 Dysprosium Inorganic materials 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
229910052770 Uranium Inorganic materials 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000002250 absorbent Substances 0.000 description 2
230000002745 absorbent Effects 0.000 description 2
229910021417 amorphous silicon Inorganic materials 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
235000011089 carbon dioxide Nutrition 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
239000004927 clay Substances 0.000 description 2
238000005336 cracking Methods 0.000 description 2
230000007812 deficiency Effects 0.000 description 2
KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
230000005484 gravity Effects 0.000 description 2
230000026030 halogenation Effects 0.000 description 2
238000005658 halogenation reaction Methods 0.000 description 2
239000012535 impurity Substances 0.000 description 2
230000002779 inactivation Effects 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
229910052752 metalloid Inorganic materials 0.000 description 2
150000002738 metalloids Chemical class 0.000 description 2
239000003607 modifier Substances 0.000 description 2
238000012958 reprocessing Methods 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
239000013589 supplement Substances 0.000 description 2
229910052716 thallium Inorganic materials 0.000 description 2
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 2
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
239000011787 zinc oxide Substances 0.000 description 2
BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
229910015372 FeAl Inorganic materials 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229910020068 MgAl Inorganic materials 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
206010000210 abortion Diseases 0.000 description 1
231100000176 abortion Toxicity 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
239000011324 bead Substances 0.000 description 1
DALDUXIBIKGWTK-UHFFFAOYSA-N benzene;toluene Chemical compound C1=CC=CC=C1.CC1=CC=CC=C1 DALDUXIBIKGWTK-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229910052810 boron oxide Inorganic materials 0.000 description 1
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
229910052794 bromium Inorganic materials 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
150000001768 cations Chemical group 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000013461 design Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
238000007599 discharging Methods 0.000 description 1
238000004821 distillation Methods 0.000 description 1
238000006253 efflorescence Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
238000005194 fractionation Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
229910052732 germanium Inorganic materials 0.000 description 1
CKSRCDNUMJATGA-UHFFFAOYSA-N germanium platinum Chemical compound [Ge].[Pt] CKSRCDNUMJATGA-UHFFFAOYSA-N 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
230000010354 integration Effects 0.000 description 1
239000011630 iodine Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000011812 mixed powder Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
238000011017 operating method Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000003825 pressing Methods 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
206010037844 rash Diseases 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000006833 reintegration Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G59/00—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha
- C10G59/02—Treatment of naphtha by two or more reforming processes only or by at least one reforming process and at least one process which does not substantially change the boiling range of the naphtha plural serial stages only

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CNB991062892A 1997-11-04 1999-03-23 采用三个催化剂区制备富芳烃产物的催化重整方法 Expired - Fee Related CN1231559C (zh)

Priority Applications (14)

Application Number	Priority Date	Filing Date	Title
US08/963,739 US5885439A (en)	1997-11-04	1997-11-04	Catalytic reforming process with multiple zones
ZA9902109A ZA992109B (en)	1997-11-04	1999-03-16	Catalytic reforming process with three catalyst zones to produce aromatic-rich product.
CA002266218A CA2266218C (en)	1997-11-04	1999-03-17	Catalytic reforming process with three catalyst zones to produce aromatic-rich product
TW088104136A TW513483B (en)	1997-11-04	1999-03-17	Catalytic reforming process with three catalyst zones to produce aromatic-rich product
JP07672899A JP4344037B2 (ja)	1997-11-04	1999-03-19	芳香族成分を多量に含む製品生産の３段触媒ゾーンによる接触改質法
SG9901401A SG87026A1 (en)	1997-11-04	1999-03-19	Catalytic reforming process with three catalyst zones to produce aromatic-rich product
BR9901180-8A BR9901180A (pt)	1997-11-04	1999-03-22	Processo para reforma catalìtica de hidrocarbonetos
PT99105744T PT1038943E (pt)	1997-11-04	1999-03-22	Processo para a reformacao catalitica de hidrocarbonetos
ES99105744T ES2215341T3 (es)	1997-11-04	1999-03-22	Procedimiento de reformado catalitico con tres zonas cataliticas para producir un producto rico en aromaticos.
AT99105744T ATE261487T1 (de)	1997-11-04	1999-03-22	Katalytisches reformierverfahren mit drei katalysatorzonen zurherstellung von einem aromareichen produkt
DE69915447T DE69915447T2 (de)	1997-11-04	1999-03-22	Katalytisches Reformierverfahren mit drei Katalysatorzonen zurHerstellung von einem aromareichen Produkt
EP99105744A EP1038943B1 (en)	1997-11-04	1999-03-22	Catalytic reforming process with three catalyst zones to produce aromatic-rich product
RU99105929/04A RU2204585C2 (ru)	1997-11-04	1999-03-22	Способ каталитического риформинга с тремя каталитическими зонами для получения ароматически обогащенного продукта
CNB991062892A CN1231559C (zh)	1997-11-04	1999-03-23	采用三个催化剂区制备富芳烃产物的催化重整方法

Applications Claiming Priority (10)

Application Number	Priority Date	Filing Date	Title
US08/963,739 US5885439A (en)	1997-11-04	1997-11-04	Catalytic reforming process with multiple zones
ZA9902109A ZA992109B (en)	1997-11-04	1999-03-16	Catalytic reforming process with three catalyst zones to produce aromatic-rich product.
CA002266218A CA2266218C (en)	1997-11-04	1999-03-17	Catalytic reforming process with three catalyst zones to produce aromatic-rich product
SG9901401A SG87026A1 (en)	1997-11-04	1999-03-19	Catalytic reforming process with three catalyst zones to produce aromatic-rich product
JP07672899A JP4344037B2 (ja)	1997-11-04	1999-03-19	芳香族成分を多量に含む製品生産の３段触媒ゾーンによる接触改質法
EP99105744A EP1038943B1 (en)	1997-11-04	1999-03-22	Catalytic reforming process with three catalyst zones to produce aromatic-rich product
BR9901180-8A BR9901180A (pt)	1997-11-04	1999-03-22	Processo para reforma catalìtica de hidrocarbonetos
KR1019990009601A KR100555172B1 (ko)	1999-03-22	1999-03-22	방향족 물질 함량이 높은 생성물을 제조하기 위한 3개의 촉매 영역을 갖춘 접촉 개질 방법
RU99105929/04A RU2204585C2 (ru)	1997-11-04	1999-03-22	Способ каталитического риформинга с тремя каталитическими зонами для получения ароматически обогащенного продукта
CNB991062892A CN1231559C (zh)	1997-11-04	1999-03-23	采用三个催化剂区制备富芳烃产物的催化重整方法

Publications (2)

Publication Number	Publication Date
CN1267708A CN1267708A (zh)	2000-09-27
CN1231559C true CN1231559C (zh)	2005-12-14

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Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CNB991062892A Expired - Fee Related CN1231559C (zh)	1997-11-04	1999-03-23	采用三个催化剂区制备富芳烃产物的催化重整方法

Country Status (14)

Country	Link
US (1)	US5885439A (pt)
EP (1)	EP1038943B1 (pt)
JP (1)	JP4344037B2 (pt)
CN (1)	CN1231559C (pt)
AT (1)	ATE261487T1 (pt)
BR (1)	BR9901180A (pt)
CA (1)	CA2266218C (pt)
DE (1)	DE69915447T2 (pt)
ES (1)	ES2215341T3 (pt)
PT (1)	PT1038943E (pt)
RU (1)	RU2204585C2 (pt)
SG (1)	SG87026A1 (pt)
TW (1)	TW513483B (pt)
ZA (1)	ZA992109B (pt)

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1997
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1999
- 1999-03-16 ZA ZA9902109A patent/ZA992109B/xx unknown
- 1999-03-17 CA CA002266218A patent/CA2266218C/en not_active Expired - Fee Related
- 1999-03-17 TW TW088104136A patent/TW513483B/zh not_active IP Right Cessation
- 1999-03-19 JP JP07672899A patent/JP4344037B2/ja not_active Expired - Fee Related
- 1999-03-19 SG SG9901401A patent/SG87026A1/en unknown
- 1999-03-22 EP EP99105744A patent/EP1038943B1/en not_active Expired - Lifetime
- 1999-03-22 BR BR9901180-8A patent/BR9901180A/pt not_active Application Discontinuation
- 1999-03-22 RU RU99105929/04A patent/RU2204585C2/ru not_active IP Right Cessation
- 1999-03-22 AT AT99105744T patent/ATE261487T1/de not_active IP Right Cessation
- 1999-03-22 PT PT99105744T patent/PT1038943E/pt unknown
- 1999-03-22 ES ES99105744T patent/ES2215341T3/es not_active Expired - Lifetime
- 1999-03-22 DE DE69915447T patent/DE69915447T2/de not_active Expired - Lifetime
- 1999-03-23 CN CNB991062892A patent/CN1231559C/zh not_active Expired - Fee Related

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Also Published As

Publication number	Publication date
DE69915447T2 (de)	2005-03-03
ES2215341T3 (es)	2004-10-01
CA2266218A1 (en)	2000-09-17
CN1267708A (zh)	2000-09-27
DE69915447D1 (de)	2004-04-15
PT1038943E (pt)	2004-06-30
ATE261487T1 (de)	2004-03-15
TW513483B (en)	2002-12-11
BR9901180A (pt)	2000-10-17
EP1038943B1 (en)	2004-03-10
SG87026A1 (en)	2002-03-19
JP4344037B2 (ja)	2009-10-14
EP1038943A1 (en)	2000-09-27
JP2000281597A (ja)	2000-10-10
CA2266218C (en)	2009-02-10
US5885439A (en)	1999-03-23
ZA992109B (en)	1999-12-29
RU2204585C2 (ru)	2003-05-20

Publication	Publication Date	Title
CN1231559C (zh)	2005-12-14	采用三个催化剂区制备富芳烃产物的催化重整方法
CN1022892C (zh)	1993-12-01	异构化催化剂及其用法
RU2180346C2 (ru)	2002-03-10	Способ непрерывного каталитического риформинга нафты
KR20110111280A (ko)	2011-10-10	중질 방향족 오일로부터의 방향족 제조에서 수소의 효율적 사용 방법
TW200902699A (en)	2009-01-16	Multi-zone process for the prodcution of diesel and aromatic compounds
CN1113830A (zh)	1995-12-27	用于将链烷烃转化成芳烃的多金属多梯度重整催化剂
CN1156976A (zh)	1997-08-13	对二甲苯的选择性重整/芳构化
CA2022298C (en)	2002-06-04	Cleanup of contaminated hydrocarbon conversion system to enable use with contaminant-sensitive catalyst
CN1151723A (zh)	1997-06-11	脱氢催化剂及方法
AU668035B2 (en)	1996-04-18	Sulfur tolerant reforming catalyst system containing a sulfur-sensitive ingredient
JP2598127B2 (ja)	1997-04-09	キシレンの異性化方法
RU2108153C1 (ru)	1998-04-10	Каталитическая система для риформинга углеводородного сырья и способ риформинга
CN1075106C (zh)	2001-11-21	有选择性的双功能多金属烃类转化催化剂组合物及其使用方法
JP2547968B2 (ja)	1996-10-30	硫黄に感受性のある成分を含む耐硫黄改質触媒系および同触媒系を用いた炭化水素の改質プロセス
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CN86104843A (zh)	1987-12-30	含二元碱金属组分的烃类转化催化剂
RU2123382C1 (ru)	1998-12-20	Катализатор для риформинга углеводородного сырья и способ риформинга парафинсодержащего углеводородного сырья
CA2123955C (en)	2005-02-15	Sulfur tolerant reforming catalyst system containing a sulfur-sensitive ingredient
KR100555172B1 (ko)	2006-03-03	방향족 물질 함량이 높은 생성물을 제조하기 위한 3개의 촉매 영역을 갖춘 접촉 개질 방법
CN117625239A (zh)	2024-03-01	一种生产芳烃和异构烷烃汽油的方法
KR970007494B1 (ko)	1997-05-09	감황 성분을 함유하는 내황성 개질 촉매계

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