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CN1204095C - 流化床反应器中烷基芳香化合物脱氢和催化剂再生 - Google Patents

流化床反应器中烷基芳香化合物脱氢和催化剂再生 Download PDF

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Publication number
CN1204095C
CN1204095C CNB008171262A CN00817126A CN1204095C CN 1204095 C CN1204095 C CN 1204095C CN B008171262 A CNB008171262 A CN B008171262A CN 00817126 A CN00817126 A CN 00817126A CN 1204095 C CN1204095 C CN 1204095C
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CN
China
Prior art keywords
catalyst
regeneration
zone
dehydrogenation
fluidized bed
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Expired - Fee Related
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CNB008171262A
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English (en)
Chinese (zh)
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CN1409695A (zh
Inventor
R·A·科科
W·M·卡斯托
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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Publication of CN1409695A publication Critical patent/CN1409695A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/26—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations
    • B01J8/28—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with two or more fluidised beds, e.g. reactor and regeneration installations the one above the other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818—Feeding of the fluidising gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1854—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement inside the reactor to form a loop
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB008171262A 1999-12-17 2000-12-13 流化床反应器中烷基芳香化合物脱氢和催化剂再生 Expired - Fee Related CN1204095C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US17227499P 1999-12-17 1999-12-17
US60/172,274 1999-12-17

Publications (2)

Publication Number Publication Date
CN1409695A CN1409695A (zh) 2003-04-09
CN1204095C true CN1204095C (zh) 2005-06-01

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CNB008171262A Expired - Fee Related CN1204095C (zh) 1999-12-17 2000-12-13 流化床反应器中烷基芳香化合物脱氢和催化剂再生

Country Status (13)

Country Link
EP (1) EP1242344A1 (es)
JP (1) JP2003517027A (es)
CN (1) CN1204095C (es)
AR (1) AR026963A1 (es)
AU (1) AU2273401A (es)
BR (1) BR0016762A (es)
CA (1) CA2396486A1 (es)
EG (1) EG22595A (es)
MX (1) MXPA02005987A (es)
RU (1) RU2234491C2 (es)
TR (1) TR200201581T2 (es)
WO (1) WO2001044146A1 (es)
ZA (1) ZA200204070B (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103121917A (zh) * 2011-11-18 2013-05-29 中国石油化工股份有限公司 降低乙苯脱氢反应过程中乙苯分压的方法

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005077867A2 (en) * 2004-02-09 2005-08-25 The Dow Chemical Company Process for the preparation of dehydrogenated hydrocarbon compounds
RU2285559C1 (ru) * 2005-03-23 2006-10-20 Открытое акционерное общество "Нижнекамскнефтехим" Способ регенерации алюмооксидного катализатора дегидратации метилфенилкарбинола
RU2294914C1 (ru) * 2005-09-01 2007-03-10 Открытое акционерное общество "Салаватнефтеоргсинтез" Способ получения стирола
RU2292327C1 (ru) * 2005-10-17 2007-01-27 Открытое акционерное общество "Салаватнефтеоргсинтез" Способ получения стирола
ES2335174B1 (es) 2008-06-19 2010-12-30 Universidad De Zaragoza Reactor de lecho fluido de dos zonas.
FR2966456B1 (fr) 2010-10-26 2013-03-15 Adisseo France Sas Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
CN103566838B (zh) * 2012-08-02 2018-04-13 宁波科元塑胶有限公司 丙烯腈流化反应系统及丙烯腈流化床生产方法
CN103922880B (zh) * 2013-01-15 2015-12-23 中国石油大学(华东) 一种利用硫化催化剂进行烷烃脱氢的连续反应再生装置
KR102349195B1 (ko) * 2015-03-09 2022-01-10 피나 테크놀러지, 인코포레이티드 촉매 응집 개선
US9889418B2 (en) * 2015-09-29 2018-02-13 Dow Global Technologies Llc Fluidized fuel gas combustor system for a catalytic dehydrogenation process
CN106582715B (zh) * 2015-10-16 2019-08-02 中国石油化工股份有限公司 烷基芳烃脱氢催化剂的再生方法
AR109242A1 (es) * 2016-05-09 2018-11-14 Dow Global Technologies Llc Un proceso para la deshidrogenación catalítica
CN108786669B (zh) 2017-04-27 2021-01-12 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
CN108794294B (zh) * 2017-04-27 2020-12-11 中国科学院大连化学物理研究所 流化床气体分布器、应用其的反应器及生产对二甲苯联产低碳烯烃的方法
RU2652195C1 (ru) * 2017-07-04 2018-04-25 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Распределитель катализатора и транспортного газа для системы реактор - регенератор дегидрирования парафиновых углеводородов С3-С5 с кипящим слоем
RU2652198C1 (ru) * 2017-07-04 2018-04-25 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Распределитель катализатора для системы реактор-регенератор дегидрирования парафиновых углеводородов С3-С5 с кипящим слоем
CN108485716A (zh) * 2018-04-28 2018-09-04 余军 生物质垃圾气化炉
JP7482868B2 (ja) * 2018-11-27 2024-05-14 キング・アブドゥッラー・ユニバーシティ・オブ・サイエンス・アンド・テクノロジー 炭化水素原料の石油化学製品への触媒転換のためのゾーン分けされた流動化プロセス
CN109694304B (zh) * 2018-12-28 2021-10-15 陕西师范大学 二氧化碳氧化乙苯制苯乙烯的连续化生产工艺
CN109999729B (zh) * 2019-04-26 2022-08-02 上海华畅环保设备发展有限公司 沸腾床加氢反应器中催化剂原位在线旋流活性恢复方法和装置

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1418047A1 (de) * 1958-02-15 1968-10-10 Basf Ag Verfahren zur katalytischen Spaltung von Kohlenwasserstoffen
US4758543A (en) * 1987-07-01 1988-07-19 The Dow Chemical Company Dehydrogenation catalyst
US5461179A (en) * 1993-07-07 1995-10-24 Raytheon Engineers & Constructors, Inc. Regeneration and stabilization of dehydrogenation catalysts

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103121917A (zh) * 2011-11-18 2013-05-29 中国石油化工股份有限公司 降低乙苯脱氢反应过程中乙苯分压的方法
CN103121917B (zh) * 2011-11-18 2015-09-09 中国石油化工股份有限公司 降低乙苯脱氢反应过程中乙苯分压的方法

Also Published As

Publication number Publication date
TR200201581T2 (tr) 2002-10-21
JP2003517027A (ja) 2003-05-20
RU2002119004A (ru) 2004-01-10
WO2001044146A1 (en) 2001-06-21
BR0016762A (pt) 2002-09-03
CA2396486A1 (en) 2001-06-21
MXPA02005987A (es) 2004-08-12
AR026963A1 (es) 2003-03-05
ZA200204070B (en) 2003-05-22
EP1242344A1 (en) 2002-09-25
EG22595A (en) 2003-04-30
RU2234491C2 (ru) 2004-08-20
CN1409695A (zh) 2003-04-09
AU2273401A (en) 2001-06-25

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