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CN1282678A - Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface - Google Patents

Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface Download PDF

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CN1282678A
CN1282678A CN 00117410 CN00117410A CN1282678A CN 1282678 A CN1282678 A CN 1282678A CN 00117410 CN00117410 CN 00117410 CN 00117410 A CN00117410 A CN 00117410A CN 1282678 A CN1282678 A CN 1282678A
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powder
colour
pattern
ultrafine
supface
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杨德宁
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Abstract

A simulative marble slab with multiple kinds of ultrafine colour ceramic powder on surface layer is composed of a first surface layer consisting of 2-10 kinds of superfine colour ceramic powder with granulity of 0.001-0.3 mm (70-99%) to form pattern, a second surface layer consisting of colour ceramic particles with granulity of 0.3-1 mm (55-90%) to form colour pattern, and a substrate of ceramic body being ordinary ceramic tile particles with granulity of 0.3-1 mm (55-90%).

Description

Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface
The present invention relates to simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface, relate in particular to the parian material that is applicable to that permanent ground, metope and furniture panel are decorated as ornament materials.
Intermingling flower colour ceramic tile in the prior art can only show the marbling effect of shallow color, and can't show the effect of natural marbles as colors such as red, orange, pink, rhodo, purplish red, black, deep blue, blackish green, coffee color of dark color.
The inventor once proposed a kind of stereo ceramic granite, marble technology (WO97/36840, on October 9th, 1997 is open), according to the artificial grantie that this technology obtained, the pattern of marble products, each look district is made of silicate material, and the boundary between each look district is clear, and in the certain thickness scope of inside, the look district is consistent substantially from the surface, even thereby this artificial grantie, marble products through surperficial polishing, pattern still remains unchanged.Yet, this artificial grantie, marble products all are made up of at the colored powder particles that 0.3mm---1mm occupies the majority diameter, and this is the inevitable outcome that conventional spray tower technology is made powder, because particle is thicker, naked eyes can both be seen the look grain that mixes mutually mutually, so the transition of its pattern color is bad.The pattern characteristic of this and natural marble is not inconsistent, and two form and aspect of natural marble hand over the colour transition at edge not have what graininess mostly, are mixed mutually by not homochromy lava.And a kind of surface layer ultra fine powder craft goods are arranged on the market, but because the superfine powder flowability is bad, the processing technology difficulty, product pattern is more random, can not repeat, and can not make the pattern of regulation accurately.It is the throwing glazed brick of making the colored glaze paste-on-paste pate-surpate of the glaze of the high glassy phase composition of non-ceramic material that a kind of prior art is also arranged on market, it has many seam ditches, out-of-flatness, and the cost height of massed glaze among having the colored piece in top layer, not wear-resisting again, so the practicality defective of obvious deficiency is arranged.Also have a kind of color glazed brick and throw glazed brick, the various multicolour patterns in its top layer adopt the glaze of high glassy phase, general glassy phase composition reaches 70-100%, and is not wear-resisting, and the Imitation Rock Porcelain Tiles part of the coefficient of expansion of top layer glaze layer and lower floor is different, be easy to be full of cracks, should not make ground or big plate Flour product, and the glassy phase in the porcelain formula materials is generally about 50%, and other is many as crystalline phase etc., can be more wear-resisting, this is an important ring of ceramic material and glaze material fundamental difference.Thus, undesirable according to the effect of existing prior art marbling.
And will be as natural marble, the color lump edge transition exquisiteness of multicolour, do not have obviously visible 0.3---1mm fine granularity friendship and mix, have only and adopt the porcelain sintering zone of the multiple color lump of the ultra-fine porcelain powder powder constituent of diameter between the 0.3---0.001mm just can achieve the goal.And all present artificial stones, ceramic tile technology all can not be in goods, the superfine powder that produces plurality of color on the goods top layer controlledly by the design plurality of color or with the pattern of different weights of the same colour.This is subjected to the restriction of the whole ceramic tile production process technical merit of prior art up till now.
The object of the present invention is to provide a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface, to overcome the defective of prior art.Through a plurality of inventions and the production practices of the inventor at glass and ceramic field, on technology, use the porcelain superfines of diameter as the plurality of color that accounts for the 70%--99% ratio of 0.3mm-0.001mm, regulation layout according to natural marble, be distributed in the top layer of goods, obtain the pattern of the multiple Colour composition the same through punching press, the drying of Ceramic Tiles press, after burning till, polishing, and the mixed part of the friendship of all kinds of these patterns is the transition nature with natural marble.Because the particle diameter great majority that intersect the look district are in 0.3mm-0.001mm, naked eyes are not almost seen the existence of particle, so that product surface has the pattern texture of natural marble.The invention has the advantages that: (1). and since parian of the present invention have two kinds or three kinds to the stability of 10 kinds of different colored patterns and uniformity (or being called superimposed pattern characteristics) etc. be other technology the process advantage that can not accomplish; (2) can show natural marble such as various colors such as black, dark-grey, red, orange, green, blackish green, yellow, orange, white, indigo plants; (3). there are three-dimensional porcelain granite than prior art, marble in district of all kinds better as the good transition of natural marble on boundary line; In the dichromatism of the present invention district boundary line, the look grain of superfines is handed over mutually and is mixed, and can make porcelain look district hand over the place of mixing the trickle progressively natural transition in marmorean look district to occur and hand over the texture that mixes; (4). the present invention has that efficient height, transition are good, the advantage of pattern good stability; (5) because the present invention can adopt the method for die orifice, make not homochromy superfine powder controlledly be distributed into goods different pattern zone, so make multiple superfine powder color form different pattern, the meticulous transition of giving full play to as natural marble becomes possibility unusually.The relatively more general superfine powder technology of the present invention, process repeatability with pattern, and for same formed in mould each simulative marble slab, the color lump pattern of 80--90% all can be consistent and plyability each other, can make the marble pattern that general superfine powder technology can not done by the predetermined pattern of lithotome, it can show the various such as black of natural marble controllably, dark-grey, bright red, orange, pink, rhodo, purplish red, green, blackish green, yellow, orange grade is enriched gorgeous color, and intersection independent that makes the pattern of multicolour in each piece goods disperses to hand over and mixes powder 1 meter distance, naked eyes almost be can't see, really reach the goods of the imitating natural marble that can make various colors, and overcome stereo ceramic granite, in the marble technology too fine pattern to make the particle of the defective of difficulty and the transition of pattern color limit portion too thick and unlike the defective of natural marble.(6). marble is one of material of liking of people on decorating, but because the physicochemical property characteristics of natural marble have very big weakness, its hardness is too poor, its acid resistance is too poor, it is all bad to do outdoor metope ground, easy-weathering, the smooth surface that makes polishing is not just becoming completely without the due bright and clean effect in polishing back because of wearing and tearing or atmospheric acid drench with rain to soak for a long time, so building industry decoration of exterior wall and outdoor ground are decorated all without natural marble on example.And the present invention is owing to can make the natural marble multicolour intersection effect of trickle transition naturally, high rigidity, highly-acidproof that the Imitation Rock Porcelain Tiles material is arranged again, with ground outside making in the building industry outside the decoration of exterior wall neutralization chamber decorate use ceramic material of the present invention really to have natural marble decorative effect material to become feasible, this is the place of the invention, practicality, novelty.
The invention will be further described below by drawings and Examples:
Fig. 1 is the floor map of the simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of one embodiment of the present invention;
Fig. 2 is the generalized section of the simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of one embodiment of the present invention;
Fig. 3 is the enlarged diagram of juncture area between the pattern of the powder sintered pattern area of the ultra-fine porcelain of the Dark grey that accounts for the 70-99% ratio, light gray, salmon pink of 0.3mm-0.001mm for the diameter of the simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the preferred embodiment of the present invention;
Fig. 4 is used to make the simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface framed plane of a kind of steel mould generalized section on the make as described in Figure 1.
In above accompanying drawing:
Fig. 1 shows the floor map of the simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of a 300mm * 300mm according to one preferred embodiment of the present invention.As shown in Figure 1, the diameter that accounts for the 70-99% ratio of the 1 expression Dark grey of the black part among the figure is the pattern area of porcelain superfine powder behind sintering of 0.3mm0.001mm; The diameter that accounts for the 70-99% ratio of oblique line part 2 expression salmon pink is the pattern area of porcelain superfine powder behind sintering of 0.3mm-0.001mm; The diameter of the grayish 70-99% of the accounting for ratio of pore part 3 expressions is the pattern area of porcelain superfine powder behind sintering of 0.3mm-0.001mm; White portion 4 expression is the common Imitation Rock Porcelain Tiles white powder sintering district that the particle of 1mm-0.3mm accounts for 55-90% by diameter.More than four parts constituted the pattern of marmorean decorative pattern of imitative Rosso Norvegian and color on the goods top layer.
Fig. 2 shows the generalized section of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface.As seen from the figure, the diameter of the black part among the figure 1 expression Dark grey be 0.3mm-0.001mm account for the 70-99% ratio the pattern area of porcelain superfine powder behind sintering; The diameter of oblique line part 2 expression salmon pink be 0.3mm-0.001mm account for the 60-99% ratio the pattern area of porcelain superfine powder behind sintering; The grayish diameter of pore part 3 expression be 0.3mm-0.001mm account for the 60-99% ratio the pattern area of porcelain superfine powder behind sintering; White portion 4 expression is the common Imitation Rock Porcelain Tiles white powder sintering district that the particle of 1mm-0.3mm accounts for 55-90% by diameter; The white material of the common Imitation Rock Porcelain Tiles of white portion 5 expression of goods section bottom, it is to be that the porcelain powder sintering of the 55-90% ratio that accounts for of 1mm--0.3mm forms by diameter.More than five parts constituted the goods of imitative Rosso Norvegian natural marble pattern.
The diameter that Fig. 3 shows simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface is the Dark grey that accounts for the 70-99% ratio of 0.3mm-0.001mm; light grey; the amplification 5-10 of juncture area schematic diagram doubly between the pattern of the powder sintered pattern area of the ultra-fine porcelain of salmon pink: tiny pit part 1 expression Dark grey; the diameter of light gray or salmon pink is the sintering pattern area of ultra-fine porcelain powder of the 70-99% ratio that accounts for of 0.3mm-0.001mm, and white portion 2 expression diameters are the local enlarged diagram of common vitreous brick powder behind sintering of the 55-90% ratio that accounts for of 1mm-0.3mm.As seen from the figure, the diameter of the intersection 3 expression independent distribution of the pattern formed of two class materials is the enlarged diagram of ultra-fine powder actual product of the 70-99% ratio that accounts for of 0.3mm-0.001mm.As seen, during in 1: 1 ratio of former goods, independent color grains in--the white powder that is dispersed in intersection of the 0.001mm diameter of-3 meters distances with the naked eye looks like more not obvious, the color boundary texture that can manifest natural marble, here be noted that, if do not amplify, the particle of 0.001mm can't be made the effect schematic diagram.
Fig. 4 shows the framed horizontal profile schematic diagram of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface a kind of steel mould on the make.Passing through of horizontal line part 1 expression Dark grey porcelain powder among the figure is regional; The porcelain powder of oblique line part 2 expression salmon pink is by the zone; The light grey porcelain powder of pore part 3 expressions is by the zone; The white porcelain powder of white portion 4 expressions is by the zone; Lines 5 expressions of black are framed mouthful the horizontal profile position of the powder of various colours separation at the steel mould in different pattern zone.
Those skilled in the art will readily understand: if whole adobe levels all adopts diameter is the superfine powder of 0.3mm-0.001mm, and when pressing adobe, exhaust is ill, makes dry body layering junk easily.So as shown in Figure 2, plurality of color such as salmon pink of the present invention, Dark grey, light gray are that the superfine powder of 0.3mm-0.001mm diameter is that cloth is on the goods top layer, the majority of following base is common Imitation Rock Porcelain Tiles powder, so that the production of scale can be normal in batches, and the yield rate height.Those skilled in the art will readily understand: because superfine powder is mobile bad, to form aborning clocklike by the design distribution patterns, especially the diameter that will realize the different color of two kinds, three kinds even five kinds has very at the controllable pattern of the superfine powder of 0.3mm-0.001mm, and high-tech requires, but because the inventor is in the patent of having invented ten remainder silicate fields, through a large amount of production, tests, after technological progress to the consumption layout of various powder has been arranged, just formed the possibility of this invention thought and realization.
The embodiment that makes simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface is described below.
At first the powder of four kinds of porcelain prescriptions: (1) of Dark grey.Diameter is the Dark grey porcelain powder of the 70-99% ratio that accounts for of 0.3mm-0.001mm and (2) of salmon pink.Diameter is salmon pink porcelain powder and grayish (3) of the 70-99% ratio that accounts for of 0.3mm-0.001mm.Diameter is the powder that accounts for 70-99% of 0.3mm-0.001mm and (4) of white.Diameter be 0.3mm-1mm the common Imitation Rock Porcelain Tiles powder that accounts for 55-90% totally four kinds be respectively charged in four containers; The steel mould that the thickness of representing as Fig. 4 that predetermined pattern arranged is provided then is 4mm is framed; Again white powder is inserted a thick bottom white material layer of the framed interior 20mm of formation of punch forming of common 300mm * 300mm Imitation Rock Porcelain Tiles; Next step be again four kinds of different powders in above 4 containers getting ready respectively by as shown in Figure 4 the band of position, insert among the area of the pattern of steel mould, make powder of all kinds in pattern area separately, to falling into, be sieved into or vibrating above the white powder, controlling its four kinds of powder thickness is the 4mm that mould is filled powder along die orifice; Next step is that the pattern powder that cloth is good is pressurizeed by the Sheet Metal Forming Technology of Imitation Rock Porcelain Tiles again, pays special attention to the Sheet Metal Forming Technology time of exhaust bounce-back of extending, in order to avoid occur making goods produce interlayer because of exhaust is insufficient; At last base substrate is entered drying, firing process, just obtained the goods of the imitative Rosso Norvegian natural marble sheet material of the multiple superfine colour ceramic powder in top layer of 300mm * 300mm size.
Because pattern of the present invention is to be formed by the die orifice of stipulating, so, they are in the goods of producing with a collection of mould, and the pattern form of porcelain color lump block and the 80%---100% of position can be superimposed, and it can the error range of superimposed part all around be no more than ± 3cm.
The present invention is achieved like this:
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention, it is characterized in that, goods are made up of the material of three kinds of features: one of its top layer is two kinds or 2-10 kind different color or same color but as seen the pattern block district of different depth degrees is obviously arranged, be behind sintering, to form by accounting for the superfine powder of 70% to 99% ratio diameter at the ceramic material prescription of 0.3mm---0.001mm, and show especially in the boundary part in this look district and other look district that this diameter that is mixed in the simple grain color grains 70%--99% ratio in other look also is 0.3mm---0.001mm; Two of its top layer is that one deck is by accounting for the colour pattern area that 55% to 90% ratio diameter is formed behind sintering at the not homochromy colour porcelain particle of 1mm---0.3mm, and especially show this powder particle with the boundary part in other look district in, this diameter that is dispersed in the simple grain color grains powder 55%---90% ratio in other look also is 1mm---0.3mm; Its three for the brick body porcelain part at the goods back ofs the body end be that the powder that the particle of 1mm---0.3mm accounts for the 55---90% ratio is formed by the diameter of common Imitation Rock Porcelain Tiles, and especially show this powder particle with the boundary part in other look district in, this diameter that is dispersed in the simple grain color grains powder 55%---90% ratio in other look also is 1mm---0.3mm.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention, it is characterized in that, in the silicate composition porcelain structure of various compositions, its glassy phase composition is all within 35%--60%, one of its top layer is two kinds or 2-10 kind different color or same color but as seen the pattern block district of different depth degrees is obviously arranged, be behind sintering, to form by accounting for the superfine powder of 70% to 99% ratio diameter at the ceramic material prescription of 0.3mm---0.001mm, and especially show in the boundary part in this look district and other look district, this diameter that is mixed in the simple grain color grains 70%---99% ratio in other look also is 0.3mm--0.001mm, and has the 3-1000 block length to reach 5cm-300cm in its pattern.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention, it is characterized in that: the goods that adopt same pattern mold to produce, the multicolour pattern 80%---100% area that its superfine powder forms behind sintering can be superimposed, and the error of its scope all around is no more than ± 3cm.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention, it is characterized in that: 3 kinds or 3-10 kind different color or same color are wherein arranged but as seen the pattern block district of different depth degrees is obviously arranged, be behind sintering, to form by accounting for the superfine powder of 70% to 99% ratio diameter at the ceramic material prescription of 0.3mm---0.001mm, and show that especially in the boundary part in this look district and other look district, the diameter of this simple grain color grains 70%---99% ratio in other look also is 0.3mm---0.001mm.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention is characterized in that: its area is about 40cm 2To 5m 2, thick is 7mm-50mm, its overall geometry is surface plate shape or cylindrical or cambered plate shape or the spherical or many prismatics of partial circle cylindricality or circle or bar shaped or square.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention is characterized in that: it also has single color particle or the multicolour particle of diameter at 2mm-15mm.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention, it is characterized in that: in the silicate product area of the pattern, also have the glassy state composition and surpass 81% water white transparency, pattern translucent or that form such as the silicate composition by the graininess of scintillation properties or random geometry of transparent or the opaque or high refractive index of any colors such as black, blue, red, Huang.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention is characterized in that: go up by the degree of depth on its surface is that the concavo-convex non-slip patterns of 0.1mm---5mm cooperates with it to form relief pattern is more arranged, and the projecting surface of convex-concave non-slip patterns is through polishing.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention is characterized in that: also have transparent or semitransparent glassy particles in described intermingling flower colour zone, itself and silicate brick body colour piece and intermingling flower colour be common to form more stratified area of the pattern.
Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface of the present invention is characterized in that: its top layer also has a kind of to five kinds of pattern area that formed behind sintering by water-soluble intermingling flower colour.
Goods of the present invention are owing to the porcelain silicate composition of the polychrome that has adopted superfine powder and the colorful painting cloth powder formation pattern of process mould control, make color can be gorgeous, can be steady, can be dull, can be light, also can form between pattern and the district of all kinds as handing over naturally of natural marble and sneak out the native texture that crosses, can have than comprehensive advantages such as natural marble is more wear-resisting again, hardness is bigger, the harm of brighter, more corrosion-resistant, no colour of sky stone material radioactivity pernicious gas.
The present invention describes as above in conjunction with the preferred embodiments, yet it is not to be limitation of the present invention, and protection domain of the present invention should be determined by appended claims.

Claims (10)

1, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface, it is characterized in that, goods are made up of the material of three kinds of features: one of its top layer is two kinds or 2-10 kind different color or same color but as seen the pattern block district of different depth degrees is obviously arranged, be behind sintering, to form by accounting for the superfine powder of 70% to 99% ratio diameter at the ceramic material prescription of 0.3mm---0.001mm, and show especially in the boundary part in this look district and other look district that this diameter that is mixed in the simple grain color grains 70%---99% ratio in other look also is 0.3mm---0.001mm; Two of its top layer is that one deck is by accounting for the colour pattern area that 55% to 90% ratio diameter is formed behind sintering at the not homochromy colour porcelain particle of 1mm---0.3mm, and especially show this powder particle with the boundary part in other look district in, this diameter that is dispersed in the simple grain color grains powder 55%---90% ratio in other look also is 1mm---0.3mm; Its three for the brick body porcelain part at the goods back ofs the body end be that the powder that the particle of 1mm---0.3mm accounts for the 55---90% ratio is formed by the diameter of common Imitation Rock Porcelain Tiles, and especially show this powder particle with the boundary part in other look district in, this diameter that is dispersed in the simple grain color grains powder 55%---90% ratio in other look also is 1mm---0.3mm.
2, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1, it is characterized in that, in the silicate composition porcelain structure of various compositions, its glassy phase composition is all within 35%--60%, one of its top layer is two kinds or 2-10 kind different color or same color but as seen the pattern block district of different depth degrees is obviously arranged, be behind sintering, to form by accounting for the superfine powder of 70% to 99% ratio diameter at the ceramic material prescription of 0.3mm---0.001mm, and especially show in the boundary part in this look district and other look district, this diameter that is mixed in the simple grain color grains 70%---99% ratio in other look also is 0.3mm---0.001mm, and has the 3-1000 block length to reach 5cm-300cm in its pattern.
3, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1, it is characterized in that: the goods that adopt same pattern mold to produce, the multicolour pattern 80%---100% area that its superfine powder forms behind sintering can be superimposed, and the error of its scope all around is no more than ± 3cm.
4, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1, it is characterized in that: 3 kinds or 3-10 kind different color or same color are wherein arranged but as seen the pattern block district of different depth degrees is obviously arranged, be behind sintering, to form by accounting for the superfine powder of 70% to 99% ratio diameter at the ceramic material prescription of 0.3mm---0.001mm, and show that especially in the boundary part in this look district and other look district, the diameter of this simple grain color grains 70%---99% ratio in other look also is 0.3mm---0.001mm.
5, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1, it is characterized in that: its area is about 40cm 2To 5m 2, thick is 7mm-50mm, its overall geometry is surface plate shape or cylindrical or cambered plate shape or the spherical or many prismatics of partial circle cylindricality or circle or bar shaped or square.
6, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1 is characterized in that: it also has single color particle or the multicolour particle of diameter at 2mm-15mm.
7, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1, it is characterized in that: in the silicate product area of the pattern, also have the glassy state composition and surpass 81% water white transparency, pattern translucent or that form such as the silicate composition by the graininess of scintillation properties or random geometry of transparent or the opaque or high refractive index of any colors such as black, blue, red, Huang.
8, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1, it is characterized in that: go up by the degree of depth on its surface is that the concavo-convex non-slip patterns of 0.1mm---5mm cooperates with it to form relief pattern is more arranged, and the projecting surface of convex-concave non-slip patterns is through polishing.
9, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1, it is characterized in that: also have transparent or semitransparent glassy particles in described intermingling flower colour zone, itself and silicate brick body colour piece and intermingling flower colour be common to form more stratified area of the pattern.
10, a kind of simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface according to claim 1 is characterized in that: its top layer also has a kind of to five kinds of pattern area that formed behind sintering by water-soluble intermingling flower colour.
CN 00117410 2000-09-11 2000-09-11 Simulative marble slab with multiple kinds of ultrafine colour ceramic powder on its supface Pending CN1282678A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005047021A1 (en) * 2003-11-17 2005-05-26 Dening Yang Tridimensional imitated stone pattern porcelain plate with the micropowder patterns and the manufacturing method and the final products of this plate
CN102249693A (en) * 2011-04-25 2011-11-23 霍镰泉 Process for preparing Hussein stone

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005047021A1 (en) * 2003-11-17 2005-05-26 Dening Yang Tridimensional imitated stone pattern porcelain plate with the micropowder patterns and the manufacturing method and the final products of this plate
CN102249693A (en) * 2011-04-25 2011-11-23 霍镰泉 Process for preparing Hussein stone
CN102249693B (en) * 2011-04-25 2013-05-15 霍镰泉 Process for preparing Hussein stone

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