The objective of the invention is to be devoted to address the above problem, the container that it provides a kind of natural decomposition material compositions and is made by said composition, the blank of article that wherein constitutes container etc. is after this article waste treatment, article material destruction such as the Decomposition by microorganism, daylight, ultraviolet ray in short duration makes it resolve into harmless soil, decomposed substance works the material etc. of improving the soil, and simultaneously mechanical properties such as its in use rigidity, intensity, shape-holding property also are good.
Another object of the present invention provides a kind of manufacture method of natural decomposition containers, wherein will mix equably by the raw material mixing material that plant material forms with natural decomposition material separated pulverizing, perhaps the additional lamelliform that is made of the natural decomposition material is weaved cotton cloth and/or non-woven fabrics in this raw material mixing material, according to circumstances, can easily create by having bleaching and sterilizing, water tolerance, the conversion of the material of thermotolerance etc., the container of compressed moulding by heating and pressurizing, formation need not be burnt by the composition of the container of forming process, and the container material after the waste treatment can be by the Decomposition of microorganism in short duration, daylight, H is resolved in ultraviolet rays etc.
2O, CO
2Deng and destroy, decompose like this in the harmless soil, decomposed substance works the material etc. of improving the soil, and can improve simultaneously lightweight, thin-walled property, the productivity of container itself, and mechanical properties such as its in use rigidity, intensity, shape-holding property also are good.
The present invention relates to a kind of natural decomposition material compositions, its by with the husk be principal constituent the plant material powder, contain the mixing material that the natural decomposition material of tackiness agent mixes and constitute.
The proportioning of aforementioned mixing material is to be made of 60~90% aforementioned plant material powder and 10~40% aforementioned natural decomposition material.And, can in aforementioned mixing material, add moisture.
In addition, above-mentioned natural decomposition material is to be made of shellac, rosin, dammar, Resin copal, gelatin, starch, lime carbonate, natural degradation plastics or their mixed powder.And the tackiness agent in the above-mentioned natural decomposition material is to be made of shellac, rosin, dammar, Resin copal, gelatin, starch or their mixed powder.
This natural decomposition material compositions is compared with the blank of the article of making container used in everyday etc., market value is identical, but but, natural decomposition is converted into harmless soil in the soil owing to turning back to, therefore in the occasion of making container, after using, can save technologies such as the recovery of burning, regenerate, utilize owing to can be used as the soil improvement material that farm crop use in addition, therefore container and basin jar etc. cheaply can be provided generally speaking.
Can be in above-mentioned mixing material mixed oxidization sanitas and/or SYNTHETIC OPTICAL WHITNER.Particularly, in above-mentioned mixing material, can mix by weaving cotton cloth and/or non-woven fabrics that the natural decomposition material constitutes.
In addition, the invention still further relates to and use above-mentioned natural decomposition material compositions, the natural decomposition containers of making by this natural decomposition material compositions of heating and pressurizing, by compressed moulding.
Say further, the present invention relates to the manufacture method of natural decomposition containers, it comprises following operation: will be that the plant material of principal constituent is pulverized the plant material powder form and pulverized the natural decomposition raw material powder that forms by the natural decomposition material that contains tackiness agent and mix making mixing raw material powder equably with the husk; Then, compressed moulding is the shape of container by heating and pressurizing with above-mentioned mixing raw material powder.
The manufacture method of this natural decomposition containers is formed body in the middle of above-mentioned mixing raw material powder heating and pressurizing moulding is made; Then, configurablely on the surface of formed body in the middle of described make formed body by weaving cotton cloth of constituting of natural decomposition material and/or non-woven fabrics; Then, with the compressed moulding of described formed body with predetermined shape heating and pressurizing.
And, the manufacture method of this natural decomposition containers is, by above-mentioned mixing raw material powder constitute mud, with the mud coating on weaving cotton cloth of constituting by the natural decomposition material and/or non-woven fabrics, make it dry and produce sheet material, at the above-mentioned mixing material of described sheet material superimposed layer, with the compressed moulding of given shape by heating and pressurizing integratedly.
In addition, the present invention is also relevant with the manufacture method of such natural decomposition containers, this method will contain at least with the husk be the mud coating of vegetable fibre powder, shellac powder and/or the shellac solution of principal constituent and natural decomposition paraffin or be impregnated into that the stratiform that is made of the natural decomposition material is weaved cotton cloth and/or non-woven fabrics on, after the dipping infiltration, make it dry, produce the flaggy parts; Compressed moulding has given shapes of containers by heating and pressurizing with above-mentioned flaggy parts then.
Can in described mud, add titanium oxide and lime carbonate or inorganic filling materials such as talcum and/or mica.
And described shellac powder and/or shellac solution have the performance as tackiness agent and water tolerance material at least.Described titanium oxide has the performance as reodorant and bleaching disinfectant at least, and preceding described natural decomposition paraffin has the performance as water tolerance material, release materials and water-proof material at least.For example, the occasion of using as tableware at container is for the stink of eliminating husk etc. or in order to sterilize, the titanium oxide that adds as reodorant and disinfectant is effective.
The described flaggy parts of compressed moulding are made of the multilayer of 1 layer or lamination.And, the operation of the aforementioned flaggy parts of lamination be with contain above-mentioned vegetable fibre powdered material, above-mentioned stratiform is weaved cotton cloth and/or the packing material of natural decomposition material such as non-woven fabrics adds between the above-mentioned flaggy parts aptly, adjusts thermal insulation, thermotolerance, thickness and the intensity of container thus.For example,, then have gas cloud, increased substantially thermal insulation thus in porous portion if described packing material adopts the porous insert structure.
Can on the surface of the described container of moulding, be coated with above-mentioned natural decomposition paraffin and silicon coating agent by described flaggy parts heating and pressurizing.
Described vegetable fibre powdered material is made of the powder of the pulverizing that is ground into 50~300 mesh size.In addition, the heating and pressurizing compressed moulding condition of described flaggy parts is, for example temperature at 100~250 ℃, pressure at 30~200kg/cm
2, and in the scope of molding time between 3~60 seconds.
Described mud is to be mixed and made into by 40~90% above-mentioned vegetable fibre powdered material, 5~40% above-mentioned shellac, 1~30% above-mentioned titanium oxide, 1~40% above-mentioned natural decomposition paraffin, 1~20% above-mentioned lime carbonate and remaining water or organic solvent.
In above-mentioned vegetable fibre, can in described husk, add sponge such as selected raw material from vegetable materials such as bamboo, sugarcane, straw, coconut coke, bagasse, wood chip, Bombay fiber crops, staple bits, paper pulp and two or more mixing material thereof.In addition, described husk can use by exsiccant grain and mill and from the isolated husk of brown rice.
In above-mentioned mud, can add the tackiness agent of from Resin copal, rosin, distillatory toluene oil, toluene fatty acid oil, terpene polymer, starch, gelatin, casein, dammar, Sudan Gum-arabic, gilsonite and two or more mixing material thereof, selecting.
The operation that described flaggy parts are impregnated in the described mud is reached like this, is promptly extracted out above-mentioned flaggy parts from roll, make it with the dipping state by being contained in the aforementioned mud in the case groove.
The manufacture method of this container is, make that to contain at least with the husk be vegetable fibre powdered material, shellac powder and/or the shellac solution of principal constituent and the mud drying of natural decomposition paraffin, produce the flaggy parts, then with described flaggy parts heating and pressurizing and compressed moulding has given shapes of containers.
The manufacturing process of the described flaggy parts that undertaken by described mud reaches like this, is about to sieve and immerses and be equipped with in the case groove of mud, and this mud is spread on sieve, picks up above-mentioned sieve and makes the mud drying.
Here employed husk needn't be cleaned and dry disinfection is handled, and when described mixing material hot briquetting, owing to carried out sufficient sterilising treatment, therefore can resemble same use the common tableware.
And aforementioned container is considered intensity and use, and its thickness is preferably in more than the 0.5mm.Though the angle of inclination is better in time more than 15 °, also can form writing board shape.
The manufacture method of this natural decomposition containers is, for example will be applied to by the mud that described mixing material constitutes aforementioned weave cotton cloth and/or non-woven fabrics on, make it dry and produce the flaggy parts, obtain blank at the described mixing material of this flaggy parts superimposed layer, with this blank with given shape extrusion forming.
This natural decomposition material compositions all is made up of the natural decomposition material, particularly can constitute to have by weaving cotton cloth and/or the goods of the intensity that the effect of non-woven fabrics brings.
This container only needs with simple manufacturing process, just can be principal constituent with the husk, by weaving cotton cloth and/or non-woven fabrics improves intensity, bondd by the tackiness agent of natural decomposition material and make.
On the surface of container for moulding, can be coated with aforementioned natural decomposition paraffin and silicon coating agent by described flaggy parts heating and pressurizing.In addition, described natural decomposition paraffin can add selected material in native paraffins such as driven plant paraffin, fossil wax, petroleum paraffin and the two or more mixing material thereof.Though described natural decomposition paraffin does not have thermotolerance with respect to general high temperature, using the water tolerance in field in order to improve container, be preferably on the surface of container and carry out coating.
In the manufacture method of this container, the manufacturing process of the described flaggy parts that undertaken by aforementioned mud reaches like this, is about to sieve and immerses and be equipped with in the case groove of described mud, and described mud is spread on sieve, picks up described sieve and makes the mud drying.
The operation that described flaggy parts are impregnated in the mud is reached like this, promptly extracted out the flaggy parts from roll, the state with dipping of making it is by being contained in the described mud in the case groove.
The manufacture method of this natural decomposition containers constitutes like that by above-mentioned, because shellac (shellac powder and/or shellac solution) has water tolerance and thermotolerance, natural decomposition paraffin has water tolerance in addition, therefore in the occasion of using as food product containers, can not cause container to absorb moisture and expand, variable color and rotten, thereby good container can be provided.
In addition, since the flaggy parts that will be impregnated with the mud that constitutes by the natural decomposition material at least lamination therefore can guarantee conformality, the intensity of container, thereby produce good container more than 2 layers.
That is,, can adjust the lamination number of plies of flaggy according to the purposes of container owing to also can make with the container of flaggy parts lamination more than 1 layer or 2 layers, thus the intensity of adjustable lift face device or water-proof degree.More and, since can be between the flaggy of lamination clamping natural decomposition material, increase the thickness of container according to the situation of clamping, can keep other performance of container according to the character of clamping material, for example thermal insulation, thermotolerance.
And, the manufacture method of this container is owing to add as the bleaching disinfectant of natural decomposition material and have the titanium oxide of deodorizing effect, and add and to improve release property, water-repellancy, flowability and glossy natural decomposition paraffin, therefore can improve the characteristic of container.
The manufacture method of this container is according to above-mentioned formation, manufacturing is impregnated into the flaggy parts flaggy parts in the mud that is made of the natural decomposition material, perhaps make the flaggy parts of getting wet by mud itself, these flaggy parts are made the container of compressed moulding by heating and pressurizing, therefore compare with goods in the past, can realize improving the advantage of intensity, container lightweight and wall thickness reductionization, and the manufacturing that can obtain container can improve productive effect because of operating facility.
And, this container can be used as tableware, the tableware pallet, the basin jar of plant-growth, hold the uses such as object of various materials, after using as containers for food use, placement container itself, also can it is discarded, the material itself that constitutes container is decomposed by microorganism etc., by daylight, particularly destroy by ultraviolet ray, in soil, revert to harmless soil, owing to change into water and carbonic acid gas, thereby needn't carry out burning of container, regeneration recovery etc., can save such processing, in addition, the soil of natural decomposition can be used as the soil improvement material of farm crop and is used.
And by the container that this manufacture method is made, the price of its container itself is identical with market value, but owing to have performance as described above, thereby very cheap generally container can be provided.
Below, natural decomposition material compositions of the present invention is described respectively, reaches each embodiment by the said composition container for moulding.
Natural decomposition material compositions of the present invention is mainly used in tableware, accommodation tool, tr, earthenware, bag etc., also can utilize aspect container in plant growings such as plant pottery, plant-growth basin jars, said composition is with the husk in 60~90% the plant material powder of plant material that is principal constituent, mix 10~40% the natural decomposition material contain tackiness agent and constitute mixing material, constitute by in raw material, adding the mixing material of moisture.In addition, the Decomposition of the material of main raw material that constitutes natural decomposition material compositions by microorganism, daylight, ultraviolet ray etc. destroy, and are transformed in the harmless soil, utilize as soil improvement material.
And plant material can add the raw material by selected sponge in bamboo, sugarcane, straw, paper pulp and this two or more mixing raw material etc. in husk.That is,, not only can only constitute, also can in husk, cooperate vegetable fibres such as straw, paper pulp by husk as plant material.
The natural decomposition material can use rosin, dammar (natural resin), Resin copal (natural resin), gelatin, starch, shellac, natural decomposition plastics, lime carbonate or their mixed powder, and wherein rosin, dammar, Resin copal, gelatin, starch, shellac have the function of tackiness agent.
And, can be in the mixing material that constitutes by plant material and natural decomposition raw material mixed oxidization sanitas and/or SYNTHETIC OPTICAL WHITNER.As husk, can use by the grain of dry paddy mill and from brown rice isolating husk, thereby can save other drying treatment.
Husk is relevant with the additive that constitutes article such as container, itself has natural decomposition, in order to reduce cost, can adopt 60~90%, preferably 65~85% content.
The lime carbonate that is contained in the natural decomposition material compositions has corollary failure, though its cost is low, the thermotolerance height and the hardness of container have also improved simultaneously, but because the flowability in the moulding worsens, so its addition must adjust corresponding to goods, so have limitation.
The natural decomposition plastics that constitute natural decomposition material compositions are made of natural decomposition aliphatic polyester, natural decomposition aliphatic polyether etc., it for example is the aliphatic polyester that heavy aggregation obtained by the di-carboxylic acid of the polyvalent alcohol of 1,4 butyleneglycol etc. and succsinic acid, hexanodioic acid and so on.
Shellac is a kind of of natural resin, and it has the thermosetting characteristic, but corollary failure and have natural decomposition therefore in order to mix equably with plant material, can use powder.Shellac is dissolvable in water in the alcohol, and the while can be heated and be dissolved, and in the time of in being dissolved in the spirituous solution (25~50%) or the aqueous solution (25%), can be used as liquid the use.
The rosin that serves as the tackiness agent function, it is a natural resin, has corollary failure, but because bonding force and thermotolerance are low, must consider that therefore this point adjusts addition.
Gelatin is a kind of of animal protein, has natural decomposition, but because bonding force, characteristic that thermotolerance is low are adjusted addition so must consider this point.
Starch has natural decomposition, though with low cost, because bonding force, characteristic that thermotolerance is low are adjusted addition so must consider this point.
First embodiment of this natural decomposition material compositions is, as the cooperate ratio of plant material with the natural decomposition material, by 80% form as the husk of plant material and 20% the starch as the natural decomposition material.Second embodiment is, as the cooperate ratio of plant material with the natural decomposition material, and the husk by 70%, 20% form as the starch of natural decomposition material and 10% lime carbonate as plant material.The 3rd embodiment is, as the cooperate ratio of plant material with the natural decomposition material, by 80% form as the husk of plant material and 20% the shellac as the natural decomposition material.The 4th embodiment is, as the cooperate ratio of plant material with the natural decomposition material, and the husk by 85%, 5% form as the shellac of natural decomposition material and 10% materials such as lime carbonate as plant material.Here employed shellac is the solution that is dissolved in the alcohol, carries out coating and use on the surface of husk formed body.The 5th embodiment is, as the cooperate ratio of plant material with the natural decomposition material, by 80% form as the husk of plant material and 20% the rosin as the natural decomposition material.The 6th embodiment is, as the cooperate ratio of plant material with the natural decomposition material, by 80% form as the husk of plant material and 20% the gelatin as the natural decomposition material.And the 7th embodiment is, as the cooperate ratio of plant material with the natural decomposition material, the husk as plant material by 70%, 20% aliphatic polyester and other lime carbonate that contains tackiness agent of 10% as the natural decomposition material are formed.
Below, an embodiment of the manufacture method of the explanation natural decomposition containers of the present invention that sees figures.1.and.2.
The container of being made by this manufacture method 1 is mainly used in tableware, accommodation tool, tr, earthenware, bag etc., also can be used in plant growing containers such as plant pottery, plant-growth basin jar, mainly utilize above-mentioned natural decomposition material compositions to be made.The material that constitutes the main raw material of container 1 can be destroyed by the Decomposition of microorganism or daylight, ultraviolet ray etc., transforms in harmless soil.
The manufacture method of container 1 comprises following operation: the plant material that will be principal constituent with the husk is pulverized, the comminuted plants raw material powder is mixed equably with the natural decomposition raw material powder that is formed by the natural decomposition material pulverizing that contains tackiness agent, thereby produce the raw materials mixed powder; Then, aforementioned mixing raw material powder is carried out heating and pressurizing, thereby make the container compressed moulding by pressing machine.At first, (step 10) is pulverized selected plant material by pulverizer etc. that (step 11) is made plant material powder (step 12) to the selected plant material that mainly contains husk with the size of 50~300 meshes.In addition, (step 13) is pulverized selected natural decomposition material by pulverizer etc. that (step 14) is made natural decomposition raw material powder (step 15) to the selected natural decomposition material that contains tackiness agent with the size of 50~300 meshes.
Then, the plant material powder is cooperated with given ratio with the natural decomposition raw material powder, produce mixed uniformly mixing raw material (step 16) with agitator etc.At this moment, for keeping the shape of container, the mixing raw material powder can mix with the ratio that cooperates of 10~40% natural decomposition material in 60~90% plant material, preferably mixes with the ratio that cooperates of 15~35% natural decomposition material in 65~85% plant material.
By shaped device the mixing raw material powder being carried out heating and pressurizing during compressed moulding, the selected raw material of respective production mixing raw material powder can add the moisture of specified rate.At this moment, much less selected material also can be the material that needn't add moisture.Then, with the mixing raw material powder with given shaped device, for example adopt shaped device shown in Figure 2 to be filled between mold 2 and the bed die 3, to charging with respect to mold 2 and the well heater 4 that bed die 3 is provided with, pressing machine (pressure head) 5 actions simultaneously, applied load P is to mixing raw material powder heating and pressurizing and compressed moulding (step 17).At this moment, the compressed moulding condition of shaped device preferably is set at: mold temperature in 100~200 ℃ scope, forming pressure at 20~80kg/cm
2Scope and molding time in 3~30 seconds scope.
And the thickness of the container 1 that is formed by the compressed moulding of mixing raw material powder can be set at various size, but preferably is shaped to the above thickness of 0.5mm because this moment container 1 mechanical properties such as intensity, shape-holding property better (step 18).
Container 1 can be made into plane tabular shape, but in the occasion of using as tableware, its pitch angle is when being shaped to for example more than 15 °, and then intensity and practicality are better.
Make the used plant material of container 1 and contain the natural decomposition material of tackiness agent identical with the material of above-mentioned composition.
At this, plant materials such as husk are the additives that constitutes container 1, and it has natural decomposition, in order to reduce cost, can adopt 60~90%, preferably 65~85% content.
The raw material that is used by the manufacture method of container 1 specifically can use forming of first of above-mentioned natural decomposition material compositions~the 7th embodiment.
Below with reference to Fig. 3~Fig. 5 natural decomposition material compositions of the present invention is described, the natural decomposition containers that constitutes by said composition with and another embodiment of manufacture method.
The natural decomposition material compositions of this embodiment is by with the husk being weaving cotton cloth of constituting of the plant material comminuted plants raw material powder of principal constituent, tackiness agent that the natural decomposition material constitutes and natural decomposition material and/or non-woven fabrics is formed.The tackiness agent of natural decomposition material uses same as the previously described embodiments.
The above-mentioned natural decomposition material compositions manufacturing of container 1 usefulness of this embodiment.
Container 1 is weaved cotton cloth and/or non-woven fabrics has improved intensity owing to having added, therefore its thickness can approach and can guarantee the intensity that container is enough, thereby can reduce the usage quantity of the mixing material of forming by husk and rosin etc. itself, reduce the weight of container, make the container lightweight.And container 1 is main as tableware, accommodation tool, tr, earthenware, bag etc., also can be used in plant growing containers such as plant pottery, plant-growth basin jar.
The manufacture method of this natural decomposition containers is, the plant material that will be principal constituent with the husk is pulverized, in the comminuted plants raw material powder, add the tackiness agent that constitutes by the natural decomposition material and form mixing material 7, on mixing material 7, apply by weaving cotton cloth of constituting of natural decomposition material and/or non-woven fabrics 8 and make blank, this blank is made container with predetermined shape extrusion forming.
Container 1 for example shown in Fig. 4 (A) weave cotton cloth and/or non-woven fabrics 8 on, shown in Fig. 4 (B), the mud that coating (coating) is formed by mixing material 7 is made exsiccant sheet material 9 with its extrusion forming.Then, shown in Fig. 4 (C),, it is produced container 1 shown in Fig. 4 (D) with given shape heating and pressurizing moulding at sheet material 9 superimposed layer mixing materials 7.
The manufacture method of container 1 be 60~90% be that the plant material of principal constituent is pulverized the tackiness agent that mixes 10~40% natural decomposition material in the plant material powder of the pulverised material form with the husk, mixing material 7 by the raw materials mixed powdered material constitutes container 1, difference according to circumstances can be made of the mud that adds moisture in mixing material 7.The material of the main raw material of formation container destroys by decomposition or daylight, the ultraviolet ray etc. of microorganism, can be converted into harmless soil, H
2O, CO
2
This embodiment is identical by the condition of plant material powder by heating and pressurizing and compressed moulding and previous embodiment.
Below, the manufacturing process of container 1 is described with reference to Fig. 3.
This manufacture method is to be made of following operation: will be that the plant material of principal constituent is pulverized the plant material powder form and pulverized the natural decomposition raw material powder that forms by the tackiness agent of natural decomposition material and mix making mixing raw material powder equably with the husk; Then, aforementioned mixing raw material powder is made the container compressed moulding by the pressurizing device heating and pressurizing.At first, preparing (preparation) mainly is the plant material (step 20) that contains husk, and the plant material prepared is ground into the size (step 21) of 50~300 meshes, making plant material powder (step 22) with pulverizer etc.In addition, prepare the tackiness agent (step 23) of natural decomposition material, the natural decomposition material prepared is ground into the size (step 24) of 50~300 meshes with pulverizer etc., make natural decomposition raw material powder (step 25).
Then, the plant material powder is cooperated with given ratio with the natural decomposition tackiness agent, mix equably with agitator etc. and make mixing material 7 (step 26).At this moment, the mixing material of mixing raw material powder keeps characteristics in order to have good shape, and wherein the raw material powder of the plant material powder of husk and tackiness agent cooperates ratio by the tackiness agent of 60~90% plant material and 10~40%, preferably 65~85% plant material and 15~35% tackiness agent constitute.In addition, this manufacture method is, with mixing raw material powder heating and pressurizing and the occasion of compressed moulding according to making the raw material that the mixing raw material powder is selected, can be made with the mud that adds specified rate moisture.At this moment, according to the moisture amount of selected material, self-evidently also can adopt the material that needn't add moisture.
On the other hand, prepare non-woven fabrics 8 (step 27) by weaving cotton cloth of forming of natural decomposition material and/or lamination.Therefore, shown in Fig. 4 (A), will weave cotton cloth and/or the non-woven fabrics 8 of lamination for example is configured on the bed die 3.Shown in Fig. 4 (B), weave cotton cloth and/or the non-woven fabrics 8 of lamination on be coated with the mud of blended mixing material 7 equably, then, with respect to being coated with weaving cotton cloth and/or the non-woven fabrics 8 of lamination and drive pressurizing device 5 of mixing material 7, applied load P, the extrusion forming by pressurization make sheet material 9 dry solidifications (step 28) of extrusion forming on mold 2.Then, the mixing material 7 that constitutes by plant material and rosin at exsiccant sheet material 9 superimposed layers, it is configured on the bed die 3, make well heater 4 energisings that are provided with respect to mold 2 and bed die 3, drive pressurizing device 5 simultaneously, applied load P ground moulding (step 29) on mold 2 by heating and pressurizing, thus natural decomposition containers 1 (step 30) made.
In the rosiny occasion of using as the natural decomposition material of tackiness agent, because the rosiny thermotolerance is low, melt the prolongation of molding time in order to prevent it, can control clamping time and mold temperature by controller 6.
By controller 6 can be with mold temperature, for example the Heating temperature with the mold 2 of mould is set in 160~170 ℃, the Heating temperature of the bed die 3 of mould is set in 150~160 ℃.In this embodiment, the temperature of mold 2 is set than the height of bed die 3, but with the moulding of mixing material heating and pressurizing the time,, therefore be that the moulding product on bed die 3 may be incomplete in this embodiment because the incomplete phenomenon of moulding product takes place on the mould of low temperature side.When the temperature of mold 2 and bed die 3 is set in below 150 ℃, mutual bonding reaction between the husk particle that is caused by rosin will lag behind, thereby cause the phenomenon that molding time prolongs, the associativity variation of husk has the bad possibility of moulding product simultaneously.When the temperature of mold 2 and bed die 3 is set in more than 170 ℃, even the pyrogenic phenomenon of moulding product also can take place a little growth of molding time.Therefore, if molding time is the degree about 30 seconds, mold temperature 150~170 ℃ temperature preferably then.
And forming pressure is preferably 10~80kg/cm fastening with the mold temperature of mould and the pass of molding time
2Degree.And the thickness of the container 1 that is formed by the extrusion forming of mixing material 7 can adopt various designs, is the thickness more than the 0.5mm but be preferably formed as, and mechanical characteristics such as the intensity of container 1, shape maintenance is better like this.
In addition, therefore plant materials such as husk can use the composition identical with the material of above-mentioned composition owing to be to constitute the additive that forms container, and it has natural decomposition, for reducing cost, can adopt 60~90%, preferably 65~85% content.
6 explanations are about another embodiment of the manufacturing process of the container of the manufacture method of this natural decomposition containers with reference to the accompanying drawings.
This embodiment is identical with the manufacturing process up to step 26 of the foregoing description, therefore saves its explanation here.By step 26 the plant material powder is cooperated, is mixed into mixing material equably by agitator with given ratio with the natural decomposition tackiness agent, with this mixing material heating and pressurizing moulding, formed body (step 31) in the middle of producing.On the other hand, prepare non-woven fabrics 8 (step 32) by weaving cotton cloth of constituting of natural decomposition material and/or lamination.Then, for example as illustrated in fig. 5, middle formed body is configured on the bed die 3, configuration is weaved cotton cloth and/or the non-woven fabrics of lamination and make formed body on middle formed body.Then, switch on the well heater 4 on the bed die 3 to being arranged on mold 2, drive pressurizing device 5 simultaneously, with respect to middle formed body and weave cotton cloth and/or the non-woven fabrics applied load P of lamination, the heating and pressurizing moulding (step 33) by heating and pressurizing, thus produce natural decomposition containers 1 (step 34).
Other embodiment of the manufacture method of natural decomposition containers is described below with reference to Fig. 7~10.
The manufacture method of this natural decomposition material compositions is, as shown in Figure 7, prepare at least by husk pulverize the vegetable fibre powder that forms, tackiness agent, as the shellac powder and/or the shellac solution of water tolerance and thermotolerance material and be used to improve water-proof natural decomposition paraffin (step 41~43), it cooperated with given amount and produce blended mud (sposh) 14 (steps 46).In this case, can in mud 14, add titanium oxide as reodorant and bleaching disinfectant, and as the lime carbonate (step 44,45) of additive.On the other hand, prepare the sheet material (step 47) of weaving cotton cloth and/or constituting by non-woven fabrics by tabular (stratiform) that the natural decomposition material constitutes.Be impregnated into sheet material in the mud 14 or on sheet material winding-up mud wait and be coated with (step 48), produce the flaggy parts 11 (step 49) that sheet material are impregnated with natural decomposition material mud 14.Then, make flaggy parts 11 dryings (step 50), lamination one deck or two-layer above exsiccant flaggy parts 11 (steps 51).Then, with the flaggy parts 11 of lamination with given shape heating and pressurizing moulding (step 52), thereby produce given natural decomposition containers 18 (step 53).
And, for the lamination procedure of flaggy parts 11, shown in the C of Figure 10, packing material 19 can be got involved aptly thermal insulation, thermotolerance, thickness and the intensity of adjusting container 18 between the flaggy parts 11.Packing material 19 can be weaved cotton cloth and/or raw mineral materials such as natural decomposition material such as non-woven fabrics or lime carbonate, calcium hydroxide, calcium oxide, titanium oxide, mica powder is made by for example vegetable fibre powdered material, stratiform.
The condition of flaggy parts 11 compressed mouldings by heating and pressurizing is along with the water ratio of the cooperation ratio of material and material and different, and for example, Heating temperature is set in 100~250 ℃, moulding pressure and is set in 30~200kg/cm
2And molding time is set in the scope between 3~60 seconds, and, also can similarly set with the foregoing description.
The mud 14 that is made of mixing material is to mix by the material fiting ratio example of listing below to make: 40~90% vegetable fibre powdered material, 5~40% shellac solution adhesive, 1~30% titanium oxide deodorizing bleaching disinfectant, 1~40% natural decomposition paraffin, 1~20% lime carbonate and as the water of nubbin.
The vegetable fibre powder is made of the pulverized powder that is ground into 50~350 mesh size.And, can in husk, add selected material from vegetable material such as bamboo, sugarcane, straw, coconut coke, bagasse, wood chip, staple bits, Bombay fiber crops (the annual grass that careless section rose of Sharon plant belongs to), paper pulp and two or more mixing material thereof.This plant material preferably adopts pulverizes the powder form, but according to the purposes of container 18, also can adopt the degree of grinding of coarse state.
In shellac, can add from as the material of selecting the Resin copal of tackiness agent, rosin, distillatory toluene oil, toluene fatty acid oil, terpene polymer, starch, gelatin, casein, dammar, Sudan Gum-arabic, gilsonite and the two or more mixing material thereof.
The stratiform that constitutes sheet material is weaved cotton cloth and/or non-woven fabrics for example can be by making such as cotton material, kapok, numb material, jute, natural decomposition resin, thin,tough silk material or natural materials etc. that fiber is mutually combined or cotton fibre, glass fibre.And, as reodorant and bleaching disinfectant, can add zeolite, gac etc.
In order to improve water tolerance, for example can add selected material in native paraffins such as driven plant paraffin, fossil wax, petroleum paraffin and the two or more mixing material thereof to natural decomposition paraffin.Natural decomposition paraffin a little less than the thermotolerance, for example just may dissolve when the temperature that touches more than 100 ℃ in general, is therefore carrying out on the surface of container 18 under the situation of coating, must consider the purposes of container 18.When on the surface of container 18, being coated with natural decomposition paraffin, preferably adopt the silicon coating agent.And, can in mud 14, add inorganic fillers such as talcum powder and/or mica.
The operations that the flaggy parts are impregnated in above-mentioned such mud of making 14 reach like this: as shown in Figure 8, extract flaggy parts 11 out from the roll 12 that is wound with flaggy parts 11, the state with dipping of making it is by being contained in the mud 14 in the case groove 13.In addition, impregnated flaggy parts 11 are sent by conveying cylinder 16 in the mud 14 in case groove 13, are transported to the drying machine 15 with well heater 27.And, near the place ahead of conveying cylinder 16 etc., can be provided for adjusting the scraper plate 20 of flaggy parts 11 thickness.Flaggy parts 11 are owing to can make mud 14 dry solidifications that infiltrate on flaggy parts 11 by drying machine 15.Infiltration has the flaggy parts 11 of mud 14 for example can carry out drying with 1~2 hour about 100 ℃, proceeds to then in the drying machine 3.As shown in Figure 9, the heating and pressurizing forming press 17 of dried flaggy parts 11 by being made of mold 21 with well heater 24 and bed die 22 can be with the pressure-controlling of the temperature of well heater 24 and pressurizing device 25 at for example 100~250 ℃, 30~200kg/cm by the control of controller 26
2And the condition in the scope in 3~60 seconds, be stamped to form type 1~3 time repeatedly, then, the edge part of pruning the container 18 of formed body grades, thereby finishes container 18.At this moment, the residual flaggy parts 11 that taken out behind the container molding 18 can be discarded or be batched by roll.
In the occasion of making container 18,, shown in the A of Figure 10, can make container 18 by the 11 heating and pressurizing moulding of flaggy parts without lamination flaggy parts 11.Perhaps, if the container 18 of the purposes of service requirements intensity, the manufacture method of this natural decomposition containers is then shown in the B of Figure 10, and flaggy parts 11 laminations that will two-layer at least above (among the figure being 2 layers) have given shapes of containers 18 with the flaggy parts 11 heating and pressurizing moulding of lamination.The lamination quantity of flaggy can change along with the kind of the container of making 18.For example, can lamination 5 layers flaggy.Perhaps, require the occasion of the container 18 of thermotolerance, thermal insulation etc. in manufacturing, the manufacture method of this natural decomposition containers is shown in the C of Figure 10, the material that will have this performance is as packing material 19, it is configured between the flaggy parts 11, also can be with the flaggy parts 11 and packing material 19 heating and pressurizing moulding simultaneously of lamination.In addition, if packing material 19 constitutes porous insert with filamentary material etc., the air that then is present in porous portion just forms thermofin, thereby can improve thermal insulation significantly.For example, in the occasion of the solution etc. of the heat of packing in container 18, the outside of container 18 does not have waste heat, thereby takes easily.
Container 18 is main as for example tableware, accommodation tool, tr, earthenware, bag etc., also can be used in plant growing containers such as plant pottery, plant-growth basin jar.And the blank that constitutes container 18 destroys by the Decomposition of microorganism or by daylight, ultraviolet ray etc., is converted into harmless soil, H
2O, CO
2, or recurrence (recovery) becomes natural mineral.
Further other embodiment of the manufacture method of natural decomposition containers of the present invention is described below with reference to Figure 11.
This embodiment does not use stratiform to weave cotton cloth and/or non-woven fabrics, but so a kind of manufacture method for example, uses and the same method of paper being got wet filtering, and mud itself is watered on the tabular flaggy parts 30 and moulding.Promptly, the manufacture method of this natural decomposition containers mainly is, make mud 14 dryings that contain with the husk vegetable fibre powdered material, shellac powder and/or the shellac solution and the natural decomposition paraffin that are principal constituent at least, produce flaggy parts 30, then the 30 heating and pressurizing moulding of flaggy parts are had given shapes of containers.The manufacturing process of this natural decomposition containers is, for example as shown in figure 11, with mud 14 pack into (step H) in the case groove 13, the sieve 31 that mesh is little immerses in the case groove 13 that mud 14 is housed (step I), makes the part of mud 14 move (step J) on sieve 31 by shaking sieve 31 with being disperse state.Pick up sieve 31 and make mud implantation layeredly on the sieve 31, thereby make cover sheet materials 30 (step K).Flaggy parts 30 from implantation in sieve on 31 filter out moisture and solidify (step L), upset sieve 31 and flaggy parts 30 are broken away from from sieve.Make thus by sheet material 30 exsiccant flaggy parts 11.With method shown in Figure 10 similarly, by flaggy parts 30 container moldings 18.
Shown in Figure 10 (C), this embodiment can will make container 18 by sheet material 30 exsiccant flaggy parts 11 laminations.Its lamination procedure is that the packing material 19 that contains the natural decomposition material of vegetable fibre powdered material is at least got involved between the flaggy parts 11 aptly, adjusts thermal insulation, thermotolerance, thickness and the intensity of container 18 thus.