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CN111952239B - Semiconductor substrate with cavity structure and preparation method thereof - Google Patents

Semiconductor substrate with cavity structure and preparation method thereof Download PDF

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CN111952239B
CN111952239B CN202010849584.5A CN202010849584A CN111952239B CN 111952239 B CN111952239 B CN 111952239B CN 202010849584 A CN202010849584 A CN 202010849584A CN 111952239 B CN111952239 B CN 111952239B
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cavity structure
semiconductor substrate
substrate
cavity
layer
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CN111952239A (en
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俞文杰
刘强
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Shanghai Institute of Microsystem and Information Technology of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/76Making of isolation regions between components
    • H01L21/762Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
    • H01L21/7624Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology
    • H01L21/76251Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology using bonding techniques
    • H01L21/76254Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology using bonding techniques with separation/delamination along an ion implanted layer, e.g. Smart-cut, Unibond
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/76Making of isolation regions between components
    • H01L21/764Air gaps
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D86/00Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
    • H10D86/201Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates the substrates comprising an insulating layer on a semiconductor body, e.g. SOI

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Abstract

本发明提供一种具有空腔结构的半导体衬底及其制备方法,制备方法包括:提供第一基底和第二基底,在第一基底中进行离子注入形成预设剥离层,预设剥离层与需要形成的空腔结构之间具有预设距离,预设距离大于空腔结构的空腔特征尺寸的1/8,将第一基底和第二基底相键合,沿预设剥离层剥离,得到具有空腔结构的半导体衬底。本发明在进行离子注入形成剥离界面时依据需要形成的空腔结构预制预设剥离层,预设剥离层与需要形成的空腔结构之间的预设距离大于所述空腔结构的空腔特征尺寸的1/8,从而可以保证空腔结构上方的材料层在制备得到具有空腔结构的半导体衬底的过程中不发生破损,提高器件良率及性能。

The present invention provides a semiconductor substrate with a cavity structure and a preparation method thereof, the preparation method comprising: providing a first substrate and a second substrate, performing ion implantation in the first substrate to form a preset peeling layer, a preset distance between the preset peeling layer and the cavity structure to be formed, the preset distance being greater than 1/8 of the cavity characteristic size of the cavity structure, bonding the first substrate and the second substrate, and peeling along the preset peeling layer to obtain a semiconductor substrate with a cavity structure. The present invention prefabricates a preset peeling layer according to the cavity structure to be formed when performing ion implantation to form a peeling interface, the preset distance between the preset peeling layer and the cavity structure to be formed being greater than 1/8 of the cavity characteristic size of the cavity structure, thereby ensuring that the material layer above the cavity structure is not damaged during the process of preparing the semiconductor substrate with the cavity structure, thereby improving the device yield and performance.

Description

具有空腔结构的半导体衬底及其制备方法Semiconductor substrate with cavity structure and preparation method thereof

技术领域Technical Field

本发明属于半导体器件结构设计制造技术领域,特别是涉及一种具有空腔结构的半导体衬底及其制备方法。The invention belongs to the technical field of semiconductor device structure design and manufacturing, and in particular relates to a semiconductor substrate with a cavity structure and a preparation method thereof.

背景技术Background technique

在半导体衬底内部制备空腔,空腔可以起到绝缘等作用,半导体功能器件可以制备在空腔上,可以保持器件良好的亚阈值等特性。为了提高集成电路芯片的性能和性能价格比,缩小器件特征尺寸从而提高集成度是一个主要的途径。但随着器件体积的缩小,功耗与漏电流成为最关注的问题。绝缘体上硅SOI(Silicon-On-Insulator)结构因能很好地抑制短沟效应,并提高器件按比例缩小的能力,已成为深亚微米MOS器件的优选结构。随着SOI技术的不断发展,研究人员开发出一种新型的晶体管结构SON(Silicon onnothing)晶体管。SON通过“空洞”结构在沟道下形成局域的绝缘体上硅,SON技术是降低SOI器件短沟等效应的一种方法。与SO1器件相比,SON器件去除了沟道下方的埋氧层,减少了顶层硅底部的界面态,减少了埋氧层中体电荷对沟道导电特性的影响,减少了沟道与衬底之间的寄生电容,同时使器件具有良好的抗总剂量辐射能力。SON器件相比于SOI器件,由于去除了背部电荷、电容影响,对短沟道效应的抑制能力有一定增强。A cavity is prepared inside the semiconductor substrate, which can play an insulating role. Semiconductor functional devices can be prepared on the cavity, which can maintain good subthreshold characteristics of the device. In order to improve the performance and performance-price ratio of integrated circuit chips, reducing the device feature size and thus improving the integration is a major way. However, as the size of the device decreases, power consumption and leakage current become the most concerned issues. The silicon-on-insulator SOI (Silicon-On-Insulator) structure has become the preferred structure for deep submicron MOS devices because it can well suppress the short channel effect and improve the ability of the device to be scaled down. With the continuous development of SOI technology, researchers have developed a new transistor structure SON (Silicon on nothing) transistor. SON forms a localized silicon-on-insulator under the channel through a "hole" structure. SON technology is a method to reduce the short channel effect of SOI devices. Compared with SO1 devices, SON devices remove the buried oxide layer under the channel, reduce the interface state at the bottom of the top silicon, reduce the influence of the body charge in the buried oxide layer on the conductive characteristics of the channel, reduce the parasitic capacitance between the channel and the substrate, and make the device have good total dose radiation resistance. Compared with SOI devices, SON devices have a certain degree of enhanced ability to suppress short channel effects because the back charge and capacitance effects are eliminated.

然而,在现有的制备具有空腔的半导体衬底的工艺中,往往需要沿剥离层进行智能剥离(Smart-cut)的工艺,例如,在SON衬底制备时需要对顶层硅进行智能剥离,例如,以注入氢离子形成剥离层为例,在智能剥离过程中,剥离界面产生了氢气泡,氢气泡对剥离层产生了较大压力,从而导致最终得到的剥离层破损,当SON衬底中部分顶层硅发生破损时,该衬底不能满足集成电路、微机电系统等应用需求。现有工艺中,如果空腔尺寸较大,空腔上方的材料层(如顶层硅)容易发生破损,如图26所示,显示出了现有技术中,对于不同尺寸的空腔结构,空腔上方的顶层硅的破损情况。随着空腔尺寸增大,空腔上方顶层硅破损概率迅速增大,部分没有完全破损的空腔边缘出现了裂缝。严重影响器件的良率及性能。However, in the existing process of preparing semiconductor substrates with cavities, it is often necessary to perform smart-cut along the stripping layer. For example, when preparing a SON substrate, it is necessary to perform smart-cut on the top silicon. For example, taking the injection of hydrogen ions to form a stripping layer as an example, during the smart stripping process, hydrogen bubbles are generated at the stripping interface, and the hydrogen bubbles exert a large pressure on the stripping layer, thereby causing the final stripping layer to be damaged. When part of the top silicon in the SON substrate is damaged, the substrate cannot meet the application requirements of integrated circuits, micro-electromechanical systems, etc. In the existing process, if the cavity size is large, the material layer above the cavity (such as the top silicon) is prone to damage. As shown in FIG26, the damage of the top silicon above the cavity for cavity structures of different sizes in the prior art is shown. As the cavity size increases, the probability of damage to the top silicon above the cavity increases rapidly, and cracks appear at the edges of some cavities that are not completely damaged. This seriously affects the yield and performance of the device.

因此,如何提供一种具有空腔结构的半导体衬底及其制备方法,以解决现有技术中的上述技术问题实属必要。Therefore, it is necessary to provide a semiconductor substrate with a cavity structure and a preparation method thereof to solve the above technical problems in the prior art.

发明内容Summary of the invention

鉴于以上所述现有技术的缺点,本发明的目的在于提供一种具有空腔结构的半导体衬底及制备方法,用于解决现有技术中制备具有空腔的衬底时空腔上方材料层易破损等问题。In view of the above-mentioned shortcomings of the prior art, an object of the present invention is to provide a semiconductor substrate with a cavity structure and a preparation method thereof, so as to solve the problem that the material layer above the cavity is easily damaged when preparing a substrate with a cavity in the prior art.

为实现上述目的及其他相关目的,本发明提供一种具有空腔结构的半导体衬底的制备方法,所述制备方法包括步骤:To achieve the above-mentioned object and other related objects, the present invention provides a method for preparing a semiconductor substrate having a cavity structure, the preparation method comprising the steps of:

提供第一基底及第二基底;Providing a first substrate and a second substrate;

对所述第一基底进行离子注入,以于所述第一基底中形成预设剥离层,所述预设剥离层与需要形成的空腔结构之间具有预设距离,所述预设距离依据所述空腔结构设定,其中,所述设定方式包括所述预设距离大于所述空腔结构的空腔特征尺寸的1/8;Performing ion implantation on the first substrate to form a preset peeling layer in the first substrate, wherein a preset distance exists between the preset peeling layer and the cavity structure to be formed, and the preset distance is set according to the cavity structure, wherein the setting method includes that the preset distance is greater than 1/8 of the cavity characteristic size of the cavity structure;

所述空腔特征尺寸的定义方式包括:定义所述空腔结构上方平行于所述空腔结构表面的二维平面;在所述二维平面内,所述空腔结构上方具有若干选定点;对于每一所述选定点,具有经过所述选定点的若干条直线;每一条所述直线与所述空腔结构的边缘之间具有至少两个接触点,选择经过所述选定点的所述直线延伸的两个方向分别与所述选定点近邻的第一接触点及第二接触点,所述第一接触点与所述第二接触点之间的距离定义为空腔尺寸;基于经过每一所述选定点的若干所述直线得到最小的所述空腔尺寸;基于所述空腔结构上方的若干所述选定点,选取所有所述空腔尺寸中的最大值,获得所述空腔特征尺寸;The method for defining the characteristic size of the cavity includes: defining a two-dimensional plane above the cavity structure and parallel to the surface of the cavity structure; in the two-dimensional plane, there are a plurality of selected points above the cavity structure; for each of the selected points, there are a plurality of straight lines passing through the selected point; each of the straight lines has at least two contact points with the edge of the cavity structure, a first contact point and a second contact point adjacent to the selected point in two directions of the straight line passing through the selected point are selected, and the distance between the first contact point and the second contact point is defined as the cavity size; the minimum cavity size is obtained based on the plurality of straight lines passing through each of the selected points; based on the plurality of selected points above the cavity structure, the maximum value of all the cavity sizes is selected to obtain the characteristic size of the cavity;

将所述第一基底进行所述离子注入的一侧及所述第二基底进行键合,得到初始键合结构,所述初始键合结构包括具有所述空腔结构的图形化介质层,且所述图形化介质层与所述预设剥离层之间具有间距;以及Bonding the side of the first substrate subjected to the ion implantation and the second substrate to obtain an initial bonding structure, wherein the initial bonding structure comprises a patterned dielectric layer having the cavity structure, and a gap exists between the patterned dielectric layer and the preset peeling layer; and

沿所述预设剥离层剥离所述第一基底,使所述第一基底的一部分转移到所述图形化介质层上,以在所述图形化介质层上形成转移衬底膜层,得到具有空腔结构的半导体衬底。The first substrate is peeled off along the preset peeling layer, so that a portion of the first substrate is transferred to the patterned dielectric layer to form a transfer substrate film layer on the patterned dielectric layer, thereby obtaining a semiconductor substrate with a cavity structure.

可选地,所述第一基底包括第一半导体衬底,所述预设剥离层形成在所述第一半导体衬底中,所述第二基底包括第二半导体衬底及形成在所述第二半导体衬底上的所述图形化介质层,所述第一基底进行所述离子注入的一侧及所述第二基底的所述图形化介质层相键合。Optionally, the first substrate includes a first semiconductor substrate, the preset peeling layer is formed in the first semiconductor substrate, the second substrate includes a second semiconductor substrate and the patterned dielectric layer formed on the second semiconductor substrate, and the side of the first substrate where the ion implantation is performed is bonded to the patterned dielectric layer of the second substrate.

可选地,进行所述离子注入之前还包括步骤:于所述第一半导体衬底表面形成牺牲介质层,自形成有所述牺牲介质层的一侧进行所述离子注入,在完成所述离子注入之后去除所述牺牲介质层。Optionally, before performing the ion implantation, the method further includes the steps of: forming a sacrificial dielectric layer on the surface of the first semiconductor substrate, performing the ion implantation from the side where the sacrificial dielectric layer is formed, and removing the sacrificial dielectric layer after completing the ion implantation.

可选地,所述第二半导体衬底与所述图形化介质层之间还形成有隔离层,所述空腔结构显露所述隔离层。Optionally, an isolation layer is formed between the second semiconductor substrate and the patterned dielectric layer, and the cavity structure exposes the isolation layer.

可选地,所述第一基底包括第一半导体衬底及形成在所述第一半导体衬底上的所述图形化介质层,所述预设剥离层形成在所述第一半导体衬底中,所述第二基底包括第二半导体衬底,其中,所述第一基底的所述图形化介质层与所述第二基底相键合。Optionally, the first substrate includes a first semiconductor substrate and the patterned dielectric layer formed on the first semiconductor substrate, the preset peeling layer is formed in the first semiconductor substrate, and the second substrate includes a second semiconductor substrate, wherein the patterned dielectric layer of the first substrate is bonded to the second substrate.

可选地,形成所述第一基底的步骤包括:提供所述第一半导体衬底;于所述第一半导体衬底上形成牺牲介质层;自形成有所述牺牲介质层的一侧对所述第一半导体衬底进行所述离子注入;图形化所述牺牲介质层,以得到具有所述空腔结构的所述图形化介质层。Optionally, the step of forming the first base includes: providing the first semiconductor substrate; forming a sacrificial dielectric layer on the first semiconductor substrate; performing the ion implantation on the first semiconductor substrate from the side where the sacrificial dielectric layer is formed; and patterning the sacrificial dielectric layer to obtain the patterned dielectric layer having the cavity structure.

可选地,所述第二基底还包括形成在所述第二半导体衬底上的隔离层,所述隔离层与所述第一基底的所述图形化介质层相键合,且所述图形化介质层中的所述空腔结构显露所述隔离层。Optionally, the second substrate further includes an isolation layer formed on the second semiconductor substrate, the isolation layer is bonded to the patterned dielectric layer of the first substrate, and the cavity structure in the patterned dielectric layer exposes the isolation layer.

可选地,进行所述离子注入形成所述预设剥离层的步骤包括:对所述第一基底进行第一离子注入,以在所述第一基底中形成初始剥离层;在所述初始剥离层的位置进行第二离子注入,以形成所述预设剥离层,其中,所述第一离子注入的注入粒子包括含B杂质,所述第二离子注入的注入粒子包括H离子、He离子中的至少一种。Optionally, the step of performing the ion implantation to form the preset stripping layer includes: performing a first ion implantation on the first substrate to form an initial stripping layer in the first substrate; performing a second ion implantation at the position of the initial stripping layer to form the preset stripping layer, wherein the implanted particles of the first ion implantation include B-containing impurities, and the implanted particles of the second ion implantation include at least one of H ions and He ions.

可选地,所述第一离子注入的注入剂量小于所述第二离子注入的注入剂量;其中,所述第一离子注入的注入剂量介于1e11~1e13/cm2之间,所述第二离子注入的注入剂量介于1e16~1e17/cm2之间。Optionally, the implantation dose of the first ion implantation is smaller than the implantation dose of the second ion implantation; wherein the implantation dose of the first ion implantation is between 1e11 and 1e13/cm 2 , and the implantation dose of the second ion implantation is between 1e16 and 1e17/cm 2 .

可选地,沿所述预设剥离层剥离所述第一基底后包括步骤:对所述具有空腔结构的半导体衬底进行加固处理,所述加固处理包括对所述具有空腔结构的半导体衬底进行加热处理。Optionally, after peeling off the first base along the preset peeling layer, the method includes the step of: performing a reinforcement treatment on the semiconductor substrate with the cavity structure, wherein the reinforcement treatment includes heating the semiconductor substrate with the cavity structure.

可选地,所述加热处理在预设氛围下进行,所述预设氛围包括氧气气氛,以在所述转移衬底膜层表面形成表面氧化层,并在完成所述加热处理之后去除所述表面氧化层,以减薄所述转移衬底膜层。Optionally, the heating treatment is performed under a preset atmosphere, which includes an oxygen atmosphere to form a surface oxide layer on the surface of the transfer substrate film layer, and the surface oxide layer is removed after the heating treatment is completed to thin the transfer substrate film layer.

可选地,所述空腔结构还延伸至所述图形化介质层下方的材料层中。Optionally, the cavity structure further extends into a material layer below the patterned dielectric layer.

可选地,所述预设剥离层与所述空腔结构之间的所述预设距离介于2nm-10μm之间。Optionally, the preset distance between the preset peeling layer and the cavity structure is between 2 nm and 10 μm.

可选地,所述预设距离与所述空腔结构的特征尺寸的比的设定方式包括:定义剥离过程中所述空腔结构上表面的压强为p,定义指向面内所述空腔结构的长度无限长,定义最恶劣情况为所述空腔上方的所述转移衬底膜层的中心位置两侧仅以所述图形化介质层为支撑点,得到所述转移衬底膜层中的最大应力Mmax∝pL2,最大应力σmax∝qL2/h2,其中,h为所述预设距离,L为所述空腔结构的特征尺寸,基于所述转移衬底膜层能承受的最大应力,采用试验设计的方式得到所述预设距离与所述空腔结构的特征尺寸的比。Optionally, the method for setting the ratio of the preset distance to the characteristic size of the cavity structure includes: defining the pressure on the upper surface of the cavity structure during the peeling process as p, defining the length of the cavity structure in the pointing plane as infinite, defining the worst case as the center position of the transfer substrate film layer above the cavity with only the patterned dielectric layer as support points on both sides, and obtaining the maximum stress Mmax∝pL2 and the maximum stress σmax∝qL2/h2 in the transfer substrate film layer, wherein h is the preset distance, and L is the characteristic size of the cavity structure, and based on the maximum stress that the transfer substrate film layer can withstand, the ratio of the preset distance to the characteristic size of the cavity structure is obtained by experimental design.

可选地,得到具有空腔结构的半导体衬底后还包括步骤:对所述转移膜层结构进行减薄处理,所述减薄处理包括采用化学机械研磨工艺进行第一减薄及采用氧化减薄工艺进行第二减薄。Optionally, after obtaining the semiconductor substrate with a cavity structure, the method further includes the step of thinning the transferred film layer structure, wherein the thinning process includes a first thinning process using a chemical mechanical polishing process and a second thinning process using an oxidation thinning process.

可选地,进行所述减薄处理之后还包括步骤:对所述减薄处理后的表面进行修复处理,以使所述减薄处理后的表面达到原子级平整,所述修复处理包括对所述具有空腔结构的半导体衬底在氢气氛围下退火,退火温度介于800℃-1300℃之间。Optionally, after the thinning treatment, the step of: repairing the surface after the thinning treatment to make the surface after the thinning treatment atomically flat, the repairing treatment includes annealing the semiconductor substrate with a cavity structure in a hydrogen atmosphere, and the annealing temperature is between 800°C and 1300°C.

本发明还提供一种具有空腔结构的半导体衬底结构,其中,所述具有空腔结构的半导体衬底优选采用本发明的具有空腔结构的半导体衬底的制备方法制备得到,当然,也可以采用其他方法制备得到。所述半导体衬底结构包括:The present invention further provides a semiconductor substrate structure with a cavity structure, wherein the semiconductor substrate with a cavity structure is preferably prepared by the method for preparing a semiconductor substrate with a cavity structure of the present invention, and of course, it can also be prepared by other methods. The semiconductor substrate structure includes:

第一基底,包括空腔上膜层,所述空腔上膜层基于转移衬底膜层减薄得到;The first substrate comprises a cavity upper film layer, wherein the cavity upper film layer is obtained by thinning the transfer substrate film layer;

第二基底,与所述第一基底相键合,所述第二基底包括第二半导体衬底;A second substrate bonded to the first substrate, wherein the second substrate comprises a second semiconductor substrate;

具有空腔结构的图形化介质层,形成于所述第二半导体衬底与所述空腔上膜层之间,所述转移衬底膜层具有靠近所述空腔结构的第一表面及与所述第一表面相对的第二表面,所述第二表面与所述空腔结构之间的距离大于所述空腔结构的空腔特征尺寸的1/8。A patterned dielectric layer having a cavity structure is formed between the second semiconductor substrate and the cavity upper film layer, the transfer substrate film layer has a first surface close to the cavity structure and a second surface opposite to the first surface, and the distance between the second surface and the cavity structure is greater than 1/8 of the cavity characteristic size of the cavity structure.

可选地,所述第二半导体衬底与所述图形化介质层之间还形成有隔离层,所述空腔结构显露所述隔离层。Optionally, an isolation layer is formed between the second semiconductor substrate and the patterned dielectric layer, and the cavity structure exposes the isolation layer.

可选地,所述空腔结构贯穿所述图形化介质层且所述空腔结构还延伸至所述第二半导体衬底及所述转移衬底膜层中的至少一者之中。Optionally, the cavity structure penetrates the patterned dielectric layer and further extends into at least one of the second semiconductor substrate and the transfer substrate film layer.

如上所述,本发明的具有空腔结构的半导体衬底及其制备方法中,在进行离子注入形成剥离界面时依据需要形成的空腔结构预制预设剥离层,预设剥离层与需要形成的空腔结构之间的预设距离大于所述空腔结构的空腔特征尺寸的1/8,从而可以保证空腔结构上方的材料层在制备得到具有空腔结构的半导体衬底的过程中不发生破损,提高器件良率及性能。As described above, in the semiconductor substrate with a cavity structure and the preparation method thereof of the present invention, a preset peeling layer is prefabricated according to the cavity structure to be formed when ion implantation is performed to form a peeling interface, and the preset distance between the preset peeling layer and the cavity structure to be formed is greater than 1/8 of the cavity characteristic size of the cavity structure, thereby ensuring that the material layer above the cavity structure is not damaged during the process of preparing the semiconductor substrate with a cavity structure, thereby improving the device yield and performance.

附图说明BRIEF DESCRIPTION OF THE DRAWINGS

图1显示为本发明实施例中提供的具有空腔结构的半导体衬底的制备方法。FIG. 1 shows a method for preparing a semiconductor substrate with a cavity structure provided in an embodiment of the present invention.

图2-21显示为本发明实施例中提供的具有空腔结构的半导体衬底的制备过程中各步骤得到的结构示意图。2-21 are schematic diagrams showing the structures obtained in each step of the preparation process of a semiconductor substrate with a cavity structure provided in an embodiment of the present invention.

图22示意出预设剥离层形成过程中的具有长方形形状的空腔结构的空腔特征尺寸。FIG. 22 illustrates the cavity feature size of a cavity structure having a rectangular shape during the formation of a preset peeling layer.

图23显示为基于本发明的方案制备得到的一种SON结构的立体图。FIG. 23 is a three-dimensional diagram of a SON structure prepared based on the solution of the present invention.

图24(a)和图24(b)显示为本发明实施例中支撑结构的至少一端与空腔结构的侧壁相接触的示意图。FIG. 24( a ) and FIG. 24( b ) are schematic diagrams showing that at least one end of the support structure is in contact with the side wall of the cavity structure in an embodiment of the present invention.

图25(a)和图25(b)显示为本发明实施例中支撑结构位于空腔结构内的示意图。Figures 25(a) and 25(b) are schematic diagrams showing a support structure located within a cavity structure in an embodiment of the present invention.

图26显示为现有技术中不同尺寸的空腔上的顶层硅受损的情况。FIG. 26 shows the damage of the top silicon layer on cavities of different sizes in the prior art.

图27当显示为顶层硅剥离厚度(顶层硅厚度为1μm)小于等于空腔特征尺寸的1/8时,空腔上方顶层硅发生不同程度的破损的情况。FIG. 27 shows that when the top silicon peeling thickness (top silicon thickness is 1 μm) is less than or equal to 1/8 of the cavity feature size, the top silicon above the cavity is damaged to varying degrees.

图28显示为采用本发明方案形成预设剥离层时不同尺寸空腔上的顶层硅受损的情况。FIG. 28 shows the damage of the top silicon layer on cavities of different sizes when the preset peeling layer is formed using the solution of the present invention.

图29显示为采用本发明方案制备的含有大面积、高密度封闭空腔结构的SON衬底。FIG. 29 shows a SON substrate having a large-area, high-density closed cavity structure prepared using the solution of the present invention.

图30显示为智能剥离过程中空腔结构上方材料层受力示意图。FIG30 is a schematic diagram showing the force on the material layer above the cavity structure during the smart peeling process.

图31显示为在空腔上方对应的剥离层中线位置,上下边缘承受最大的压应力和拉应力,且下边缘处容易发生破损。FIG31 shows that at the midline position of the peeling layer corresponding to the cavity, the upper and lower edges are subjected to the maximum compressive stress and tensile stress, and the lower edge is prone to damage.

元件标号说明Component number description

100 第一基底100 First Base

101 第一半导体衬底101 first semiconductor substrate

101a 预设剥离层101a Pre-set peeling layer

102 牺牲介质层102 Sacrificial dielectric layer

103 图形化介质层103 Patterned dielectric layer

103a 空腔结构103a Cavity structure

104 转移衬底膜层104 Transfer substrate film layer

105 表面氧化层105 Surface oxide layer

106 减薄处理后结构106 Structure after thinning

107 空腔上膜层107 Cavity upper membrane layer

200 第二基底200 Second Base

201 第二半导体衬底201 second semiconductor substrate

202 隔离层202 Isolation Layer

203 图形化介质层203 Patterned dielectric layer

203a 空腔结构203a Cavity structure

S1~S4 步骤Steps S1 to S4

具体实施方式Detailed ways

以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。The following describes the embodiments of the present invention through specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the contents disclosed in this specification. The present invention can also be implemented or applied through other different specific embodiments, and the details in this specification can also be modified or changed in various ways based on different viewpoints and applications without departing from the spirit of the present invention.

如在详述本发明实施例时,为便于说明,表示器件结构的剖面图会不依一般比例作局部放大,而且所述示意图只是示例,其在此不应限制本发明保护的范围。此外,在实际制作中应包含长度、宽度及深度的三维空间尺寸。For example, when describing the embodiments of the present invention in detail, for the sake of convenience, the cross-sectional view showing the device structure will not be partially enlarged according to the general scale, and the schematic view is only an example, which should not limit the scope of protection of the present invention. In addition, in actual production, the three-dimensional space dimensions of length, width and depth should be included.

为了方便描述,此处可能使用诸如“之下”、“下方”、“低于”、“下面”、“上方”、“上”等的空间关系词语来描述附图中所示的一个元件或特征与其他元件或特征的关系。将理解到,这些空间关系词语意图包含使用中或操作中的器件的、除了附图中描绘的方向之外的其他方向。此外,当一层被称为在两层“之间”时,它可以是所述两层之间仅有的层,或者也可以存在一个或多个介于其间的层。本文使用的“介于……之间”表示包括两端点值。For ease of description, spatial relational terms such as "under", "below", "below", "below", "above", "on", etc. may be used herein to describe the relationship of one element or feature shown in the drawings to other elements or features. It will be understood that these spatial relational terms are intended to include other directions of the device in use or operation in addition to the directions depicted in the drawings. In addition, when a layer is referred to as being "between" two layers, it can be the only layer between the two layers, or there can be one or more intervening layers. As used herein, "between..." means including the end point values.

在本申请的上下文中,所描述的第一特征在第二特征“之上”的结构可以包括第一和第二特征形成为直接接触的实施例,也可以包括另外的特征形成在第一和第二特征之间的实施例,这样第一和第二特征可能不是直接接触。In the context of the present application, a structure in which a first feature is described as being "above" a second feature may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features are formed between the first and second features, such that the first and second features may not be in direct contact.

需要说明的是,本实施例中所提供的图示仅以示意方式说明本发明的基本构想,遂图示中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,其组件布局型态也可能更为复杂。It should be noted that the illustrations provided in this embodiment are only used to illustrate the basic concept of the present invention in a schematic manner, and therefore the illustrations only show components related to the present invention rather than being drawn according to the number, shape and size of components in actual implementation. In actual implementation, the type, quantity and proportion of each component may be changed arbitrarily, and the component layout may also be more complicated.

如图1所示,本发明提供一种具有空腔结构的半导体衬底的制备方法,包括步骤:As shown in FIG. 1 , the present invention provides a method for preparing a semiconductor substrate having a cavity structure, comprising the steps of:

S1:提供第一基底及第二基底;S1: providing a first substrate and a second substrate;

S2:对所述第一基底进行离子注入,以于所述第一基底中形成预设剥离层,所述预设剥离层与需要形成的空腔结构之间具有预设距离,所述预设距离依据所述空腔结构设定,其中,所述设定的方式包括所述预设距离大于所述空腔结构的空腔特征尺寸的1/8;S2: performing ion implantation on the first substrate to form a preset peeling layer in the first substrate, wherein a preset distance exists between the preset peeling layer and the cavity structure to be formed, and the preset distance is set according to the cavity structure, wherein the setting method includes that the preset distance is greater than 1/8 of the cavity characteristic size of the cavity structure;

S3:将所述第一基底进行所述离子注入的一侧及所述第二基底进行键合,得到初始键合结构,所述初始键合结构包括具有所述空腔结构的图形化介质层,且所述图形化介质层与所述预设剥离层之间具有间距;以及S3: bonding the side of the first substrate subjected to the ion implantation to the second substrate to obtain an initial bonding structure, wherein the initial bonding structure comprises a patterned dielectric layer having the cavity structure, and a gap exists between the patterned dielectric layer and the preset peeling layer; and

S4:沿所述预设剥离层剥离所述第一基底,使所述第一基底的一部分转移到所述图形化介质层上,以在所述图形化介质层上形成转移衬底膜层,得到具有空腔结构的半导体衬底。S4: peeling off the first substrate along the preset peeling layer, so that a portion of the first substrate is transferred to the patterned dielectric layer to form a transfer substrate film layer on the patterned dielectric layer, and obtaining a semiconductor substrate with a cavity structure.

下面将结合附图详细说明本发明的具有空腔结构的半导体衬底的制备方法,其中,需要说明的是,上述顺序并不严格代表本发明所保护的具有空腔结构的半导体衬底的制备方法的制备顺序,本领域技术人员可以依据实际工艺进行步骤顺序之间的改变,例如,提供所述第二基底可以在步骤对第一基底进行离子注入形成预设剥离层之后提供。其中,图1仅示出了本发明一种示例中的具有空腔结构的半导体衬底的制备方法的制备步骤。The following will describe in detail the method for preparing a semiconductor substrate with a cavity structure of the present invention in conjunction with the accompanying drawings. It should be noted that the above sequence does not strictly represent the preparation sequence of the method for preparing a semiconductor substrate with a cavity structure protected by the present invention. Those skilled in the art can change the sequence of steps according to the actual process. For example, providing the second substrate can be provided after the step of ion implanting the first substrate to form a preset peeling layer. FIG1 only shows the preparation steps of the method for preparing a semiconductor substrate with a cavity structure in an example of the present invention.

实施例1:Embodiment 1:

本实施例1提供一种具体的具有空腔结构的半导体衬底的制备方法。首先,如图1中的S1及图2和5-7所示,进行步骤S1,提供第一基底100及第二基底200。所述第一基底100和所述第二基底200用于制备本发明的具有空腔结构的半导体衬底,二者可以依据实际的工艺方式提供。其中,所述第一基底100可以是单层材料层构成基底,也可以是由叠层材料层结构构成的基底。同理,所述第一基底200可以是单层材料层构成基底,也可以是由叠层材料层结构构成的基底。This embodiment 1 provides a specific method for preparing a semiconductor substrate with a cavity structure. First, as shown in S1 in Figure 1 and Figures 2 and 5-7, step S1 is performed to provide a first substrate 100 and a second substrate 200. The first substrate 100 and the second substrate 200 are used to prepare the semiconductor substrate with a cavity structure of the present invention, and the two can be provided according to the actual process method. Among them, the first substrate 100 can be a substrate composed of a single layer of material layer, or a substrate composed of a stacked material layer structure. Similarly, the first substrate 200 can be a substrate composed of a single layer of material layer, or a substrate composed of a stacked material layer structure.

作为示例,如图2所示,所述第一基底100包括第一半导体衬底101,后续离子注入形成的预设剥离层形成在所述第一半导体衬底101中。其中,所述第一半导体衬底101可以为Si、Ge、GaN、SiC、GaAs、AlGaN、Ga2O3、InP材料层,也可以上述材料层中的两者及其以上的组合。当然,还可以为其他晶体半导体,并不局限于此。As an example, as shown in FIG2 , the first base 100 includes a first semiconductor substrate 101, and a preset peeling layer formed by subsequent ion implantation is formed in the first semiconductor substrate 101. The first semiconductor substrate 101 may be a material layer of Si, Ge, GaN, SiC, GaAs, AlGaN, Ga 2 O 3 , InP, or a combination of two or more of the above material layers. Of course, it may also be other crystalline semiconductors, and is not limited thereto.

在进一步可选示例中,所述第一基底100还包括形成在所述第一半导体衬底101上的牺牲介质层102,所述牺牲介质层102可以为SiO2、氮化硅、氮氧化硅、氧化铝材料层,也可以上述材料层中的两者及其以上的组合。当然,还可以为其他绝缘牺牲介质层,并不局限于此。所述牺牲介质层102可以但不限于采用热氧化的方式形成在所述第一半导体衬底101上。所述牺牲介质层102可以在后续离子注入等工艺中保护所述第一半导体衬底101表面,也可以用于器件功能层的制备,依据器件实际的制备需求选择使用。In a further optional example, the first base 100 further includes a sacrificial dielectric layer 102 formed on the first semiconductor substrate 101, and the sacrificial dielectric layer 102 may be a SiO 2 , silicon nitride, silicon oxynitride, aluminum oxide material layer, or a combination of two or more of the above material layers. Of course, it may also be other insulating sacrificial dielectric layers, but is not limited thereto. The sacrificial dielectric layer 102 may be formed on the first semiconductor substrate 101 by, but is not limited to, thermal oxidation. The sacrificial dielectric layer 102 may protect the surface of the first semiconductor substrate 101 in subsequent processes such as ion implantation, and may also be used for the preparation of a device functional layer, and may be selected for use according to the actual preparation requirements of the device.

作为示例,如图5-7所示,所述第二基底200包括第二半导体衬底201及形成在所述第二半导体衬底201上的所述图形化介质层203,如图6所示。其中,所述第二半导体衬底201可以为Si、Ge、GaN、SiC、GaAs、AlGaN、Ga2O3、InP材料层,也可以上述材料层中的两者及其以上的组合。当然,还可以为其他晶体半导体,并不局限于此。另外,所述图形化介质层203中形成有空腔结构203a以用于作为后续得到的具有空腔结构的半导体衬底中的所述空腔结构。所述图形化介质层203可以为SiO2、氮化硅、氮氧化硅、氧化铝材料层,也可以上述材料层中的两者及其以上的组合。当然,还可以为其他绝缘牺牲介质层,并不局限于此。另外,所述空腔结构203a的数量及排布方式可以依据实际需求设定,如呈周期性阵列排布。As an example, as shown in FIGS. 5-7 , the second base 200 includes a second semiconductor substrate 201 and the patterned dielectric layer 203 formed on the second semiconductor substrate 201 , as shown in FIG. 6 . The second semiconductor substrate 201 may be a material layer of Si, Ge, GaN, SiC, GaAs, AlGaN, Ga 2 O 3 , InP, or a combination of two or more of the above material layers. Of course, it may also be other crystalline semiconductors, but is not limited thereto. In addition, a cavity structure 203a is formed in the patterned dielectric layer 203 to be used as the cavity structure in the semiconductor substrate with a cavity structure obtained later. The patterned dielectric layer 203 may be a material layer of SiO 2 , silicon nitride, silicon oxynitride, aluminum oxide, or a combination of two or more of the above material layers. Of course, it may also be other insulating sacrificial dielectric layers, but is not limited thereto. In addition, the number and arrangement of the cavity structures 203a may be set according to actual needs, such as being arranged in a periodic array.

在进一步可选示例中,如图5所示,所述第二半导体衬底201与所述图形化介质层203之间还形成有隔离层202,所述空腔结构203a显露所述隔离层202。所述隔离层202可以用于将所述空腔结构203a与所述第二半导体衬底201相隔离开,以利于基于该结构层对器件性能进行调节。所述隔离层202可以为SiO2、氮化硅、氮氧化硅、氧化铝材料层,也可以上述材料层中的两者及其以上的组合。当然,还可以为其他绝缘牺牲介质层,并不局限于此。在一示例中,所述隔离层202的材料与所述图形化介质层203的材料不同,以利于所述图形化介质层203的制备,有利于基于所述隔离层202提高器件性能。所述隔离层与所述图形化介质层支撑层可以是同种材料,也可以是异种材料,当为异种材料时,两个结构层之间具有一定的选择刻蚀比,便于后续器件制备过程中,定义器件结构。In a further optional example, as shown in FIG5 , an isolation layer 202 is further formed between the second semiconductor substrate 201 and the patterned dielectric layer 203, and the cavity structure 203a exposes the isolation layer 202. The isolation layer 202 can be used to isolate the cavity structure 203a from the second semiconductor substrate 201, so as to facilitate the adjustment of device performance based on the structural layer. The isolation layer 202 can be a layer of SiO 2 , silicon nitride, silicon oxynitride, or aluminum oxide, or a combination of two or more of the above material layers. Of course, it can also be other insulating sacrificial dielectric layers, but is not limited thereto. In one example, the material of the isolation layer 202 is different from that of the patterned dielectric layer 203, so as to facilitate the preparation of the patterned dielectric layer 203 and to improve the device performance based on the isolation layer 202. The isolation layer and the patterned dielectric layer support layer can be the same material or different materials. When they are different materials, there is a certain selective etching ratio between the two structural layers, which is convenient for defining the device structure in the subsequent device preparation process.

作为示例,如图7所示,所述图形化介质层203中的所述空腔结构203a还延伸至所述图形化介质层203下方的材料层中,可以通过控制所述空腔结构203a形成时的刻蚀条件实现所述空腔结构203a的延伸。例如,所述空腔结构203a还延伸至所述第二半导体衬底201中,以利于依据器件性能需求调节空腔结构的尺寸,当然,当还行有所述隔离层202时,所述空腔结构203也可以穿过所述隔离层202延伸至所述第二半导体衬底201中。在一示例中,所述第二基底200的所述第二半导体衬底层201作为后续形成的SON结构的底层硅,所述图形化介质层203作为中间绝缘层,本实施例中的所述第一基底100中的所述第一半导体衬底层101作为形成顶层硅的材料层。该示例中,所述空腔结构203a延伸至SON的底层硅中。As an example, as shown in FIG7 , the cavity structure 203a in the patterned dielectric layer 203 also extends to the material layer below the patterned dielectric layer 203, and the extension of the cavity structure 203a can be achieved by controlling the etching conditions when the cavity structure 203a is formed. For example, the cavity structure 203a also extends to the second semiconductor substrate 201, so as to facilitate adjusting the size of the cavity structure according to the device performance requirements. Of course, when the isolation layer 202 is also present, the cavity structure 203 can also extend through the isolation layer 202 to the second semiconductor substrate 201. In one example, the second semiconductor substrate layer 201 of the second substrate 200 serves as the bottom silicon of the SON structure formed subsequently, the patterned dielectric layer 203 serves as the intermediate insulating layer, and the first semiconductor substrate layer 101 in the first substrate 100 in this embodiment serves as the material layer for forming the top silicon. In this example, the cavity structure 203a extends to the bottom silicon of the SON.

接着,如图1中的S2及图3-4和22所示,进行步骤S2,对所述第一基底100进行离子注入,以于所述第一基底100中形成预设剥离层101a,所述预设剥离层101a与需要形成的空腔结构(如所述空腔结构203a)之间具有预设距离,参见图8中的d所示。其中,本发明中所述预设距离d依据所述空腔结构203a设定,所述设定方式为所述预设距离d大于所述空腔结构203a的空腔特征尺寸D的1/8。在另一可选示例中,设置所述预设距离介于2nm-10μm之间,可以是小于1.8μm,可以选择为:5nm、10nm、50nm、1μm、5μm、8μm,有利于得到均匀材料层表面。该步骤中通过进行离子注入形成后续衬底剥离的所述预设剥离层101a,所述预设剥离层101a的位置依据需要形成的所述空腔结构203a进行设定,可以有利于在后续工艺中保护所述空腔结构203a上方的材料层,避免空腔上方材料层例如在研磨的过程中发生破损。保证空腔上方的材料层具有接近100%的概率不发生破损。简化工艺,节约成本。另外,所述预设剥离层101a当然还可以参考实际需求的厚度进行设定,例如,当所需要的后续小于所述空腔结构203a的空腔特征尺寸D的1/8时,还可以基于后续的减薄工艺实现。Next, as shown in S2 in FIG. 1 and FIGS. 3-4 and 22, step S2 is performed to perform ion implantation on the first substrate 100 to form a preset peeling layer 101a in the first substrate 100, and a preset distance is provided between the preset peeling layer 101a and the cavity structure to be formed (such as the cavity structure 203a), as shown in d in FIG. 8. The preset distance d in the present invention is set according to the cavity structure 203a, and the setting method is that the preset distance d is greater than 1/8 of the cavity characteristic size D of the cavity structure 203a. In another optional example, the preset distance is set between 2nm-10μm, which can be less than 1.8μm, and can be selected as: 5nm, 10nm, 50nm, 1μm, 5μm, 8μm, which is conducive to obtaining a uniform material layer surface. In this step, the preset peeling layer 101a for subsequent substrate peeling is formed by ion implantation. The position of the preset peeling layer 101a is set according to the cavity structure 203a to be formed, which can be beneficial to protect the material layer above the cavity structure 203a in the subsequent process, and avoid the material layer above the cavity from being damaged, for example, during the grinding process. Ensure that the material layer above the cavity has a probability of nearly 100% not being damaged. Simplify the process and save costs. In addition, the preset peeling layer 101a can of course be set with reference to the actual required thickness. For example, when the required subsequent thickness is less than 1/8 of the cavity characteristic size D of the cavity structure 203a, it can also be achieved based on the subsequent thinning process.

本实施例中,所述预设距离d大于所述空腔结构203a的空腔特征尺寸D的1/8,其中,所述空腔特征尺寸D的定义可以为:在空腔(即,所述空腔结构203)上方的二维平面内,所述二维平面可以是所述空腔结构203a的顶部开口所在的二维平面,因空腔为封闭结构,对于空腔上方的任意一点A,过该点做任一直线,该直线与空腔边缘有超过两个接触点,取A点直线延伸的两个方向上,与A点近邻的两个点A’、A”,即为所述第一接触点及所述第二接触点,参见图22所示,A’、A”两点之间的距离为一段空腔尺寸,改变过A点直线的方向,可以找到最小的一段空腔尺寸。对于空腔上方所有的点,都有对应的最小空腔尺寸。在所有的最小空腔尺寸中,选出最大的一个尺寸,定义为空腔特征尺寸。例如,如图22所示,对于俯视图形状为长方形的所述空腔结构,其空腔特征尺寸D的大小为长方形的短边长度。In this embodiment, the preset distance d is greater than 1/8 of the cavity characteristic size D of the cavity structure 203a, wherein the cavity characteristic size D may be defined as follows: in a two-dimensional plane above the cavity (i.e., the cavity structure 203), the two-dimensional plane may be a two-dimensional plane where the top opening of the cavity structure 203a is located. Since the cavity is a closed structure, for any point A above the cavity, any straight line is drawn through the point, and the straight line has more than two contact points with the edge of the cavity. The two points A' and A", which are adjacent to point A in two directions extending from the straight line of point A, are the first contact point and the second contact point. As shown in FIG. 22, the distance between points A' and A", is a section of the cavity size. By changing the direction of the straight line through point A, the smallest section of the cavity size can be found. For all points above the cavity, there is a corresponding minimum cavity size. Among all the minimum cavity sizes, the largest size is selected and defined as the cavity characteristic size. For example, as shown in FIG. 22, for the cavity structure having a rectangular shape in the top view, the size of its cavity characteristic size D is the length of the short side of the rectangle.

作为示例,进行所述离子注入形成所述预设剥离层101a的步骤包括:对所述第一基底100进行第一离子注入,以在所述第一基底100中形成初始剥离层(图中未示出),其中,所述第一离子注入的注入粒子包括含B杂质;在所述初始剥离层的位置进行第二离子注入,以形成所述预设剥离层101a,其中,所述第二离子注入的注入粒子包括H离子、He离子中的至少一种。通过上述方式,在定义剥离界面过程中,预先在剥离界面处注入B+、BF2等离子,从而可以以较低的剂量定义出表清晰的注入粒子分布轮廓,并减少后续离子注入剂量,第二次离子注入的注入离子富集在第一注入粒子处,从而精确定义剥离界面,减小剥离损伤,降低剥离表面粗糙度。在一示例中,所述第一离子注入的注入剂量小于所述第二离子注入的注入剂量。可选地,所述第一离子注入的注入剂量介于1e11~1e13/cm2之间,如可以是1e12/cm2;在进行了第一次粒子注入的基础上,进行第二离子注入,即然后注入氢离子,注入剂量为1e16~1e17/cm2,如可以是6e16/cm2,当然,也可以是He离子或其他离子,从而使氢离子富集在B+离子附近,从而精确定义剥离界面,减小剥离损伤,降低剥离表面粗糙度。As an example, the step of performing the ion implantation to form the preset peeling layer 101a includes: performing a first ion implantation on the first substrate 100 to form an initial peeling layer (not shown in the figure) in the first substrate 100, wherein the implanted particles of the first ion implantation include B-containing impurities; performing a second ion implantation at the position of the initial peeling layer to form the preset peeling layer 101a, wherein the implanted particles of the second ion implantation include at least one of H ions and He ions. In the above manner, in the process of defining the peeling interface, B+, BF2 and other ions are pre-implanted at the peeling interface, so that a clear distribution profile of the implanted particles can be defined at a lower dose, and the subsequent ion implantation dose can be reduced. The implanted ions of the second ion implantation are enriched at the first implanted particles, thereby accurately defining the peeling interface, reducing peeling damage, and reducing the peeling surface roughness. In one example, the implantation dose of the first ion implantation is less than the implantation dose of the second ion implantation. Optionally, the implantation dose of the first ion implantation is between 1e 11 and 1e 13 /cm 2 , such as 1e 12 /cm 2 ; based on the first particle implantation, the second ion implantation is performed, that is, hydrogen ions are then implanted with an implantation dose of 1e 16 to 1e 17 /cm 2 , such as 6e 16 /cm 2. Of course, He ions or other ions can also be used, so that the hydrogen ions are enriched near the B+ ions, thereby accurately defining the peeling interface, reducing peeling damage, and reducing the peeling surface roughness.

作为示例,如图4所示,该示例中,进行所述离子注入之前还包括步骤:于所述第一半导体衬底101表面形成牺牲介质层102,自形成有所述牺牲介质层102的一侧进行所述离子注入,参考图2-3所示,并且,在完成所述离子注入之后去除所述牺牲介质层102,即,使用去除所述牺牲介质层102之后的所述第一半导体衬底101进行后续的键合。As an example, as shown in FIG4 , in this example, before performing the ion implantation, the steps are also included: forming a sacrificial dielectric layer 102 on the surface of the first semiconductor substrate 101, performing the ion implantation from the side where the sacrificial dielectric layer 102 is formed, as shown in FIG2-3 , and removing the sacrificial dielectric layer 102 after completing the ion implantation, that is, using the first semiconductor substrate 101 after removing the sacrificial dielectric layer 102 for subsequent bonding.

作为示例,所述预设距离与所述空腔结构的特征尺寸的比的设定方式包括:定义剥离过程中所述空腔结构上表面的压强为p,定义指向面内所述空腔结构的长度无限长,定义最恶劣情况为所述空腔上方的所述转移衬底膜层的中心位置两侧仅以所述图形化介质层为支撑点,得到所述转移衬底膜层中的最大应力Mmax∝pL2,最大应力σmax∝qL2/h2,其中,h为所述预设距离,L为所述空腔结构的特征尺寸,基于所述转移衬底膜层能承受的最大应力,采用试验设计的方式得到所述预设距离与所述空腔结构的特征尺寸的比。As an example, the method for setting the ratio of the preset distance to the characteristic size of the cavity structure includes: defining the pressure on the upper surface of the cavity structure during the peeling process as p, defining the length of the cavity structure in the pointing plane as infinite, defining the worst case as the center position of the transfer substrate film layer above the cavity with only the patterned dielectric layer as support points on both sides, and obtaining the maximum stress Mmax∝pL2 and the maximum stress σmax∝qL2/h2 in the transfer substrate film layer, wherein h is the preset distance, and L is the characteristic size of the cavity structure, and based on the maximum stress that the transfer substrate film layer can withstand, the ratio of the preset distance to the characteristic size of the cavity structure is obtained by experimental design.

具体的,参见图30和31所示,在智能剥离过程中,氢气泡将剥离层与原衬底剥开。由于剥离层厚度有限,其承受应力最大。在最恶劣的情况下,氢气气泡对剥离层施加压力的面积覆盖了整个空腔上方压强为p。在定义空腔的特征尺寸时,假设位于该尺寸位置的剥离层上方处处受到氢气泡的等大压强,剥离层仅通过左右两侧埋氧层获得支撑。此时剥离层的应力情况最恶劣。通过简单应力分析可知,最大内应力位于剥离层中心位置。假设z方向上(指向面内)空腔的长度较长,对其进行应力分析时,可近似为无限长,剥离层仅以左右两侧埋氧层为支撑点,此时剥离层所承受的应力为最恶劣情况。则剥离层的最大应力Mmax∝pL2,(∝表示正比于),剥离层内所承受的最大应力σmax∝pL2/h2,即σmax∝(L/h)2,即空腔宽度L与剥离层厚度h之比定义了剥离层所承受的最大应力。考虑到剥离层所能承受的最大应力上限是一个常数,是由材料性质决定的。可通过实验来找到剥离层承受最大应力上限时,空腔宽度L与剥离层厚度h之比。Specifically, as shown in Figures 30 and 31, during the intelligent stripping process, hydrogen bubbles peel the stripping layer from the original substrate. Due to the limited thickness of the stripping layer, it is subjected to the greatest stress. In the worst case, the area where the hydrogen bubbles exert pressure on the stripping layer covers the entire pressure above the cavity, which is p. When defining the characteristic size of the cavity, it is assumed that the stripping layer located at this size position is subjected to equal pressure from hydrogen bubbles everywhere, and the stripping layer is supported only by the buried oxide layers on the left and right sides. At this time, the stress condition of the stripping layer is the worst. Through simple stress analysis, it can be seen that the maximum internal stress is located at the center of the stripping layer. Assuming that the length of the cavity in the z direction (pointing inwardly) is long, when performing stress analysis on it, it can be approximated to be infinitely long, and the stripping layer is supported only by the buried oxide layers on the left and right sides. At this time, the stress borne by the stripping layer is the worst. Then the maximum stress of the peeling layer is Mmax∝pL 2 , (∝ means proportional to), the maximum stress in the peeling layer is σmax∝pL 2 /h 2 , that is, σmax∝(L/h) 2 , that is, the ratio of the cavity width L to the peeling layer thickness h defines the maximum stress borne by the peeling layer. Considering that the upper limit of the maximum stress that the peeling layer can withstand is a constant, it is determined by the material properties. The ratio of the cavity width L to the peeling layer thickness h when the peeling layer withstands the maximum stress upper limit can be found through experiments.

接着,如图1中的S3及图8-9所示,进行步骤S3,将所述第一基底100进行所述离子注入的一侧及所述第二基底200进行键合,得到初始键合结构,所述初始键合结构包括具有所述空腔结构203a的图形化介质层203,且所述图形化介质层203与所述预设剥离层101a之间具有间距。键合方式可以依据实际进行选择,如直接键合。所述空腔结构203a的数量及排布可以依据实际需求进行选择。Next, as shown in S3 in FIG. 1 and FIGS. 8-9 , step S3 is performed to bond the side of the first substrate 100 subjected to the ion implantation to the second substrate 200 to obtain an initial bonding structure, wherein the initial bonding structure includes a patterned dielectric layer 203 having the cavity structure 203a, and a gap is provided between the patterned dielectric layer 203 and the preset peeling layer 101a. The bonding method can be selected according to actual needs, such as direct bonding. The number and arrangement of the cavity structures 203a can be selected according to actual needs.

在本实施例中,所述第一基底100进行所述离子注入的一侧与所述第二基底200的所述图形化介质层203相键合,其中,所述预设剥离层101a与所述图形化介质层203之间的间距是指,在所述图形化介质层203与所述预设剥离层101a排布的平面内,所述图形化介质层203具有相对的两侧,一侧为靠近所述预设剥离层101a的一侧,另一侧为远离所述预设剥离层101a的一侧,所述间距是指所述图形化介质层203靠近所述预设剥离层101a的一侧与所述预设剥离层101a之间的距离。当所述空腔结构203a贯穿所述图形化介质层203时,这一间距也为所述空腔结构203与所述预设剥离层101a之间的距离。在该实施例中,这里描述的所述间距等于上一步骤依据所述空腔结构203a进行离子注入时所设定的所述预设距离d。In this embodiment, the side of the first substrate 100 where the ion implantation is performed is bonded to the patterned dielectric layer 203 of the second substrate 200, wherein the spacing between the preset peeling layer 101a and the patterned dielectric layer 203 means that, in the plane where the patterned dielectric layer 203 and the preset peeling layer 101a are arranged, the patterned dielectric layer 203 has two opposite sides, one side is the side close to the preset peeling layer 101a, and the other side is the side away from the preset peeling layer 101a, and the spacing refers to the distance between the side of the patterned dielectric layer 203 close to the preset peeling layer 101a and the preset peeling layer 101a. When the cavity structure 203a penetrates the patterned dielectric layer 203, this spacing is also the distance between the cavity structure 203 and the preset peeling layer 101a. In this embodiment, the spacing described here is equal to the preset distance d set in the previous step when the ion implantation is performed according to the cavity structure 203a.

其中。如图8所示,显示为键合过程中,依据图4中方案去除了所述牺牲介质层102之后的所述第一半导体衬底101的表面与所述第二基底200的所述图形化介质层203进行键合,从而得到封闭的所述空腔结构203a,即得到了所述具有空腔结构的半导体衬底的初始键合结构。另外,如图9所示,进一步显示出了所述空腔结构203a延伸到所述第二半导体衬底201中时与所述第一基底100的键合后的初始键合结构。As shown in FIG8 , during the bonding process, the surface of the first semiconductor substrate 101 after the sacrificial dielectric layer 102 is removed according to the scheme in FIG4 is bonded to the patterned dielectric layer 203 of the second base 200, thereby obtaining the closed cavity structure 203a, that is, obtaining the initial bonding structure of the semiconductor substrate with the cavity structure. In addition, as shown in FIG9 , the initial bonding structure after bonding with the first base 100 when the cavity structure 203a extends into the second semiconductor substrate 201 is further shown.

作为示例,所述空腔结构203a中还具有支撑结构203b,所述支撑结构203b的顶部表面与所述图形化介质层203的上表面相平齐,所述支撑结构203b位于所述空腔结构203a内或者所述支撑结构203b的至少一端与所述空腔结构203a的侧壁相接触。可选地,可以在刻蚀形成所述空腔结构203a时同时形成所述支撑结构203b。所述支撑结构203b的存在,可以在剥离界面已经确定的情况下,在一定区域内,获得较大的空腔面积,本方案设计了含有半包围、全包围结构的环岛空腔,以减少空腔的特征尺寸,避免顶层硅发生破损。其中,所述空腔结构203a的形状包括但不限于三角形、四边形、多边形、圆形、以及其它具有封闭边界的图案。岛状所述支撑结构203b可以与空腔四周相连或断开,岛状支撑结构的形状不做限制,可以为四边形、三角形。另外,如图24(a)和(b)及25(a)和(b)所示,显示采用包含支撑结构的所述空腔结构的SON衬底的形貌图,图24(a)和(b)显示出所述支撑结构203b的至少一端与所述空腔结构203a的侧壁相接触,图25(a)和(b)显示出所述支撑结构203b位于所述空腔结构203a内。采用含有图形化支撑结构的空腔,可以制备出面积更大,无顶层硅破损的SON衬底。采用本发明的设计,可制备含有大面积、高密度封闭空腔结构的SON衬底,空腔面积占衬底总面积的比例超过12%,适用于制备集成电路。As an example, the cavity structure 203a also has a support structure 203b, the top surface of the support structure 203b is flush with the upper surface of the patterned dielectric layer 203, the support structure 203b is located in the cavity structure 203a or at least one end of the support structure 203b is in contact with the side wall of the cavity structure 203a. Optionally, the support structure 203b can be formed simultaneously when the cavity structure 203a is etched. The existence of the support structure 203b can obtain a larger cavity area in a certain area when the peeling interface has been determined. This scheme designs an island cavity with a semi-enclosed and fully enclosed structure to reduce the characteristic size of the cavity and avoid damage to the top silicon. Among them, the shape of the cavity structure 203a includes but is not limited to a triangle, a quadrilateral, a polygon, a circle, and other patterns with a closed boundary. The island-shaped support structure 203b can be connected or disconnected with the cavity around, and the shape of the island-shaped support structure is not limited, and can be a quadrilateral or a triangle. In addition, as shown in Figures 24(a) and (b) and 25(a) and (b), the morphology of the SON substrate using the cavity structure including the support structure is shown. Figures 24(a) and (b) show that at least one end of the support structure 203b is in contact with the side wall of the cavity structure 203a, and Figures 25(a) and (b) show that the support structure 203b is located in the cavity structure 203a. By using the cavity containing the patterned support structure, a SON substrate with a larger area and no top silicon damage can be prepared. By using the design of the present invention, a SON substrate containing a large area and high density closed cavity structure can be prepared, and the proportion of the cavity area to the total area of the substrate exceeds 12%, which is suitable for preparing integrated circuits.

另外,在一示例中,对于所述支撑结构的设计,可以依据以下方式:对于任一空腔结构,可根据空腔平面上所有的点,例如,以点1、点2、点3、…点n为例;首先找到每一点对应的最小空腔尺寸,例如为:尺寸1、尺寸2、尺寸3、…、尺寸n,其中,空腔尺寸的定义可以参见本发明说明书在特征尺寸定义处的描述;接着,从1~n个最小空腔尺寸中,可找到最大尺寸D,定义为空腔特征尺寸,与前文所述空腔特征尺寸定义一致;然后,设1~n个点中,共有m(m<n)个点的最小空腔尺寸等于空腔特征尺寸D;最后,在空腔中增加半岛式/环岛式支撑结构后,该结构同时使上述m个点对应的最小空腔尺寸都减小了,则该支撑结构可以减小空腔的特征尺寸。在一示例中,可以是对所述空腔结构内的所有支撑结构而言,其在所述空腔结构的每一侧壁上的投影均覆盖该侧壁,没有显露的侧壁。从而基于所述支撑结构减小所述空腔结构的特征尺寸。In addition, in one example, the design of the support structure can be based on the following method: for any cavity structure, all points on the cavity plane can be used, for example, point 1, point 2, point 3, ... point n as an example; first find the minimum cavity size corresponding to each point, for example: size 1, size 2, size 3, ..., size n, where the definition of the cavity size can refer to the description of the characteristic size definition in the specification of the present invention; then, from 1 to n minimum cavity sizes, the maximum size D can be found, which is defined as the cavity characteristic size, which is consistent with the definition of the cavity characteristic size described above; then, suppose that among 1 to n points, there are m (m < n) points with the minimum cavity size equal to the cavity characteristic size D; finally, after adding a peninsula/island support structure to the cavity, the structure simultaneously reduces the minimum cavity sizes corresponding to the above m points, and the support structure can reduce the characteristic size of the cavity. In one example, for all support structures in the cavity structure, their projections on each side wall of the cavity structure cover the side wall, and there is no exposed side wall. Therefore, the characteristic size of the cavity structure is reduced based on the support structure.

最后,如图1中的S4及图17-21所示,进行步骤S4,沿所述预设剥离层101a剥离所述第一基底100,使所述第一基底100的一部分转移到所述图形化介质层203上,以在所述图形化介质层203上形成转移衬底膜层104,得到具有空腔结构的半导体衬底,如图17所示。Finally, as shown in S4 in Figure 1 and Figures 17-21, step S4 is performed to peel off the first substrate 100 along the preset peeling layer 101a, so that a portion of the first substrate 100 is transferred to the patterned dielectric layer 203 to form a transfer substrate film layer 104 on the patterned dielectric layer 203, and a semiconductor substrate with a cavity structure is obtained, as shown in Figure 17.

具体的,可以采用加热退火的方式自所述预设剥离层101a的位置剥离所述第一基底100,例如,可以采用在400℃~700℃之间的温度对上述初始键合结构退火,当然,也可以采用本领域熟知的其他剥离方式。此时,由于本发明中所述预设剥离层101a的位置的设定,所述转移衬底膜层104的厚度即为所述预设距离d,所述转移衬底膜层104的厚度大于所述空腔结构203a的空腔特征尺寸的1/8。Specifically, the first substrate 100 can be peeled off from the position of the preset peeling layer 101a by heating annealing. For example, the initial bonding structure can be annealed at a temperature between 400°C and 700°C. Of course, other peeling methods well known in the art can also be used. At this time, due to the setting of the position of the preset peeling layer 101a in the present invention, the thickness of the transfer substrate film layer 104 is the preset distance d, and the thickness of the transfer substrate film layer 104 is greater than 1/8 of the cavity feature size of the cavity structure 203a.

作为示例,沿所述预设剥离层101a剥离所述第一基底后还包括步骤:对所述具有空腔结构的半导体衬底进行加固处理,所述加固处理包括对所述具有空腔结构的半导体衬底进行加热处理,如高温加热处理,例如在1000℃~1300℃下进行。当然,也可以采用其他加固方式。As an example, after peeling off the first substrate along the preset peeling layer 101a, the method further includes: performing a reinforcement treatment on the semiconductor substrate with a cavity structure, wherein the reinforcement treatment includes heating the semiconductor substrate with a cavity structure, such as high-temperature heating treatment, for example, at 1000° C. to 1300° C. Of course, other reinforcement methods may also be used.

在进一步可选示例中,所述加热处理在预设氛围下进行,所述预设氛围包括氧气气氛,以将所述转移衬底膜层104表面氧化形成表面氧化层105,如图18所示,在进行所述加热处理之后去除所述表面氧化层105,如图19所示,以减薄所述转移衬底膜层104。通过该方式,可以在加固所述具有空腔结构的半导体衬底这一复合衬底结构的过程中通过氧化的方式减薄所述转移衬底膜层104。在一示例中,使用氢氟酸腐蚀所述表面氧化层105,以减薄所述转移衬底膜层104。In a further optional example, the heating treatment is performed under a preset atmosphere, and the preset atmosphere includes an oxygen atmosphere, so as to oxidize the surface of the transfer substrate film layer 104 to form a surface oxide layer 105, as shown in FIG18, and the surface oxide layer 105 is removed after the heating treatment, as shown in FIG19, so as to thin the transfer substrate film layer 104. In this way, the transfer substrate film layer 104 can be thinned by oxidation during the process of reinforcing the composite substrate structure of the semiconductor substrate with a cavity structure. In one example, the surface oxide layer 105 is etched with hydrofluoric acid to thin the transfer substrate film layer 104.

作为示例,得到具有空腔结构的半导体衬底后还包括步骤:对所述转移衬底膜层104进行减薄处理,所述减薄处理包括采用化学机械研磨工艺机械第一减薄及采用氧化减薄工艺进行第二减薄,得到减薄处理后结构106。也就是说,采用两步减薄的方式对所述转移衬底膜层104进行减薄,其中,第一步减薄可以成为是粗抛光,例如,可以采用CPM的方式进行,进行第一减薄的时间等可以依据实际经验选定。接着,在此基础上进行第二减薄,可以采用氧化减薄的工艺,也就是说,氧化所述第一减薄之后的所述转移衬底膜层的表面形成氧化层,再去除所述氧化层,进一步实现减薄,以精确定义减薄后剩余的所述转移衬底膜层的厚度。As an example, after obtaining the semiconductor substrate with a cavity structure, the following steps are further included: thinning the transfer substrate film layer 104, wherein the thinning process includes first mechanical thinning by chemical mechanical polishing process and second thinning by oxidation thinning process, to obtain the thinned structure 106. That is, the transfer substrate film layer 104 is thinned by two-step thinning, wherein the first step of thinning can be rough polishing, for example, it can be performed by CPM, and the time for the first thinning can be selected based on actual experience. Then, on this basis, the second thinning is performed, and an oxidation thinning process can be used, that is, the surface of the transfer substrate film layer after the first thinning is oxidized to form an oxide layer, and then the oxide layer is removed to further achieve thinning, so as to accurately define the thickness of the transfer substrate film layer remaining after thinning.

在一示例中,优选在进行完上述示例中的氧气氛围下加热固化处理及去除所述表面氧化层105之后进行本示例中的所述第一减薄和所述第二减薄的工艺,得到所述减薄处理后结构106,如图20所示。在上述示例的氧化减薄完成后,即去除所述表面氧化层105之后,所述转移衬底膜层107(如顶层硅)的厚度减少,所述空腔结构203a上方转移衬底膜层能够承受的压力减小,此时如果采用CMP工艺对所述转移衬底膜层进一步减薄、抛光,容易造成顶层硅破损,因此,可以采用本示例中先用CMP进行粗减薄再用氧化减薄工艺继续二次氧化减薄,利于精确定义厚度。In one example, it is preferred that the first thinning and the second thinning processes in this example are performed after the heating curing treatment in the oxygen atmosphere and the removal of the surface oxide layer 105 in the above example are completed to obtain the thinned structure 106, as shown in Figure 20. After the oxidation thinning in the above example is completed, that is, after the surface oxide layer 105 is removed, the thickness of the transfer substrate film layer 107 (such as the top silicon) is reduced, and the pressure that the transfer substrate film layer above the cavity structure 203a can withstand is reduced. At this time, if the CMP process is used to further thin and polish the transfer substrate film layer, it is easy to cause damage to the top silicon. Therefore, in this example, CMP can be used for rough thinning first and then the oxidation thinning process can be used to continue secondary oxidation thinning, which is conducive to accurately defining the thickness.

作为示例,进行所述减薄处理之后还包括步骤:对所述减薄处理后的表面进行修复处理,以使所述减薄处理后的表面达到原子级平整,得到空腔上膜层107,如图21所示。在一示例中,所述修复处理包括对所述具有空腔结构的半导体衬底在氢气氛围下退火,退火温度介于800℃-1300℃之间,例如可以是1000℃。另外,图23显示为经过本实施例的上述步骤后得到的半导体衬底结构(SON衬底),可以得到性能优异几乎无破损的空腔上膜层107。所述第二半导体衬底201作为底层硅这一层,所述图形化介质层203作为SON中的中间埋氧层这一层,所述空腔结构203a作为衬底空腔,所述空腔上膜层107作为顶层硅这一层。As an example, after the thinning process is performed, the step of repairing the surface after the thinning process is also included, so that the surface after the thinning process is flat at the atomic level, and the cavity upper film layer 107 is obtained, as shown in FIG21. In one example, the repair process includes annealing the semiconductor substrate with the cavity structure in a hydrogen atmosphere, and the annealing temperature is between 800°C and 1300°C, for example, it can be 1000°C. In addition, FIG23 shows the semiconductor substrate structure (SON substrate) obtained after the above steps of this embodiment, and the cavity upper film layer 107 with excellent performance and almost no damage can be obtained. The second semiconductor substrate 201 is used as the bottom silicon layer, the patterned dielectric layer 203 is used as the middle buried oxide layer in the SON, the cavity structure 203a is used as the substrate cavity, and the cavity upper film layer 107 is used as the top silicon layer.

为了进一步说明本发明的效果,参见图27-28所示,图27显示为当顶层硅剥离厚度(顶层硅厚度为1μm)小于等于空腔特征尺寸的1/8时,空腔上方顶层硅发生不同程度的破损;通过如图27实验可知,顶层硅厚度为1μm,在空腔特征尺寸为8μm时,顶层硅发生了破损。通过图27可知,顶层硅厚度应至少大于空腔特征尺寸的1/8,才能保证顶层硅的完整。当然,还可以进一步选择顶层硅的其他厚度值如2μm、3μm、5μm等,取得其他厚度时保证顶层硅的完整的范围。图28显示为采用本发明预设剥离层的形成方式形成的具有空腔结构的半导体衬底中空腔结构上方的顶层硅的受损情况,可见,采用本发明方案空腔结构上方的顶层硅基本没有破损。图29显示为采用本发明方案制备的含有大面积、高密度封闭空腔结构的SON衬底,图中顶层硅是半透明的,下方含有0.5μm*3μm空腔。采用本专利优化技术(通过特征尺寸设置初始剥离厚度)后,可以制备出含有大面积空腔,顶层硅100%无破损的SON衬底,可应用于高密度集成电路中。采用本发明的设计,可制备含有大面积、高密度封闭空腔结构的SON衬底,空腔面积占衬底总面积的比例超过12%,适用于制备集成电路。To further illustrate the effect of the present invention, see Figures 27-28. Figure 27 shows that when the top silicon peeling thickness (top silicon thickness is 1 μm) is less than or equal to 1/8 of the cavity feature size, the top silicon above the cavity is damaged to varying degrees; as shown in the experiment in Figure 27, the top silicon thickness is 1 μm, and when the cavity feature size is 8 μm, the top silicon is damaged. As shown in Figure 27, the top silicon thickness should be at least greater than 1/8 of the cavity feature size to ensure the integrity of the top silicon. Of course, other thickness values of the top silicon such as 2 μm, 3 μm, 5 μm, etc. can be further selected to ensure the integrity of the top silicon when other thicknesses are obtained. Figure 28 shows the damage of the top silicon above the cavity structure in the semiconductor substrate with a cavity structure formed by the formation method of the preset peeling layer of the present invention. It can be seen that the top silicon above the cavity structure of the present invention is basically not damaged. Figure 29 shows a SON substrate containing a large-area, high-density closed cavity structure prepared by the present invention. In the figure, the top silicon is translucent and contains a 0.5 μm*3 μm cavity below. By adopting the patented optimization technology (setting the initial peeling thickness by feature size), a SON substrate with a large-area cavity and 100% undamaged top silicon can be prepared, which can be used in high-density integrated circuits. By adopting the design of the present invention, a SON substrate with a large-area, high-density closed cavity structure can be prepared, and the cavity area accounts for more than 12% of the total substrate area, which is suitable for preparing integrated circuits.

实施例2:Embodiment 2:

本实施例2提供另外一种具有空腔结构的半导体衬底的制备方法,该实施例2与实施例1的不同在于形成初始键合结构的过程不同,详见图2、3、10-16。本实施例2中:所述第一基底100包括第一半导体衬底101及形成在所述第一半导体衬底101上的所述图形化介质层103,如图10所示,所述预设剥离层101a形成在所述第一半导体衬底101中。This embodiment 2 provides another method for preparing a semiconductor substrate with a cavity structure. The difference between this embodiment 2 and embodiment 1 is that the process of forming the initial bonding structure is different, see Figures 2, 3, 10-16 for details. In this embodiment 2: the first base 100 includes a first semiconductor substrate 101 and the patterned dielectric layer 103 formed on the first semiconductor substrate 101, as shown in Figure 10, and the preset peeling layer 101a is formed in the first semiconductor substrate 101.

其中,所述图形化介质层103的形成工艺为:所述第一半导体衬底101上形成所述牺牲介质层102,再自形成有所述牺牲介质层的一侧进行所述离子注入形成所述预设剥离层101a,对所述牺牲介质层102进行图形化,得到所述图形化介质层103,所述图形化介质层103中具有所述空腔结构103a,参见图2、3及图10。Among them, the formation process of the patterned dielectric layer 103 is: the sacrificial dielectric layer 102 is formed on the first semiconductor substrate 101, and then the ion implantation is performed from the side where the sacrificial dielectric layer is formed to form the preset stripping layer 101a, and the sacrificial dielectric layer 102 is patterned to obtain the patterned dielectric layer 103, and the patterned dielectric layer 103 has the cavity structure 103a, see Figures 2, 3 and 10.

在一示例中,所述空腔结构103a延伸至所述图形化介质层103下方的材料层中,延伸至所述第一半导体衬底101中,如图11所示。当所述空腔结构103a需要延伸至所述第一半导体衬底101中时,所述预设距离d即所述延伸至所述第一半导体衬底101中的所述空腔结构103a的底部与所述预设剥离层101a之间的距离,在进行离子注入时依据实施例1中的方式设定,通过注入离子的能量等定义。在一示例中,进行键合得到初始键合结构后,所述第一基底100作为SON衬底的顶层硅,即所述空腔结构103a延伸在了顶层硅中。In one example, the cavity structure 103a extends into the material layer below the patterned dielectric layer 103 and into the first semiconductor substrate 101, as shown in FIG11. When the cavity structure 103a needs to extend into the first semiconductor substrate 101, the preset distance d, i.e., the distance between the bottom of the cavity structure 103a extending into the first semiconductor substrate 101 and the preset peeling layer 101a, is set according to the method in Example 1 during ion implantation, and is defined by the energy of the implanted ions, etc. In one example, after bonding to obtain an initial bonding structure, the first substrate 100 serves as the top silicon of the SON substrate, i.e., the cavity structure 103a extends into the top silicon.

另外,该实施例2中,所述第二基底200包括第二半导体衬底201,如图13所示,其中,所述第一基底100的所述图形化介质层103与所述第二基底200相键合。在一可选示例中,所述第二基底200还包括形成在所述第二半导体衬底201上的隔离层202,如图12所示,所述隔离层202与所述第一基底100的所述图形化介质层103相键合,且所述图形化介质层103中的所述空腔结构103a显露所述隔离层202,以利于器件空腔的隔离。In addition, in this embodiment 2, the second substrate 200 includes a second semiconductor substrate 201, as shown in FIG13, wherein the patterned dielectric layer 103 of the first substrate 100 is bonded to the second substrate 200. In an optional example, the second substrate 200 also includes an isolation layer 202 formed on the second semiconductor substrate 201, as shown in FIG12, the isolation layer 202 is bonded to the patterned dielectric layer 103 of the first substrate 100, and the cavity structure 103a in the patterned dielectric layer 103 exposes the isolation layer 202, so as to facilitate the isolation of the device cavity.

在本实施例2中,基于所述第一基底及所述第二基底键合得到的初始键合结构如图14-16的三种示例所示。其中,图14显示为键合初始结构中,第二基底200具有隔离层202;图15显示为键合初始结构中,第一基底100的图形化介质层103中的空腔结构103a延伸至第一半导体衬底101中,且第二基底200具有隔离层202;图16显示为键合初始结构中,第一基底100的图形化介质层103中的空腔结构103a延伸至第一半导体衬底101中,第二基底200不具有隔离层202。当然,还可以依据第一基底及第二基底的描述形成其他初始键合结构。In this embodiment 2, the initial bonding structure obtained by bonding the first substrate and the second substrate is shown in three examples of Figures 14-16. Among them, Figure 14 shows that in the initial bonding structure, the second substrate 200 has an isolation layer 202; Figure 15 shows that in the initial bonding structure, the cavity structure 103a in the patterned dielectric layer 103 of the first substrate 100 extends into the first semiconductor substrate 101, and the second substrate 200 has an isolation layer 202; Figure 16 shows that in the initial bonding structure, the cavity structure 103a in the patterned dielectric layer 103 of the first substrate 100 extends into the first semiconductor substrate 101, and the second substrate 200 does not have an isolation layer 202. Of course, other initial bonding structures can also be formed according to the description of the first substrate and the second substrate.

实施例3:Embodiment 3:

如图17、23所示,参见图1-16,本实施例3提供一种具有空腔结构的半导体衬底结构,其中,所述具有空腔结构的半导体衬底优选采用本发明实施例1或实施例2提供的具有空腔结构的半导体衬底的制备方法制备得到,当然,也可以采用其他方法制备得到。本实施例中的所述具有空腔结构的半导体衬底中的各个结构层的特征可以参见实施例1及实施例2中的描述,在此不再赘述。As shown in Figures 17 and 23, referring to Figures 1-16, this embodiment 3 provides a semiconductor substrate structure with a cavity structure, wherein the semiconductor substrate with a cavity structure is preferably prepared by the method for preparing a semiconductor substrate with a cavity structure provided in Embodiment 1 or Embodiment 2 of the present invention, and of course, it can also be prepared by other methods. The features of each structural layer in the semiconductor substrate with a cavity structure in this embodiment can be referred to the description in Embodiment 1 and Embodiment 2, and will not be repeated here.

所述半导体衬底结构包括:第一基底100,包括空腔上膜层107,所述空腔上膜层107基于第一半导体衬底101剥离得到,进一步基于转移衬底膜层104减薄得到;以及第二基底200,与所述第一基底100相键合,所述第二基底200包括第二半导体衬底201;所述半导体衬底还包括具有空腔结构203a或103a的图形化介质层203或103,所述图形化介质层203或103形成于所述第二半导体衬底201与所述空腔上膜层107之间,其中,所述转移衬底膜层104具有靠近所述空腔结构203a或103a的第一表面及与所述第一表面相对的第二表面,所述第二表面与所述空腔结构203a或103a之间的距离大于空腔特征尺寸的1/8,这里,所述转移衬底膜层104的靠近所述图形化介质层的表面即为所述空腔上膜层107靠近所述图形化介质层的表面,所述空腔上膜层107的上表面基于所述第二表面减薄得到。在另一示例中,所述第二表面与所述空腔结构203a或103a之间的距离小于2μm。其中,本实施例3中,所述第一基底100与所述第二基底200采用与实施例1和实施例2一致的描述,所述图形化介质层203或103相对于实施例1和实施例2分开描述,独立于第一基底100与第二基底200进行描述,这里本领域技术人员可以理解的。The semiconductor substrate structure comprises: a first substrate 100, comprising a cavity upper film layer 107, wherein the cavity upper film layer 107 is obtained by peeling off the first semiconductor substrate 101 and further thinning the transferred substrate film layer 104; and a second substrate 200, bonded to the first substrate 100, wherein the second substrate 200 comprises a second semiconductor substrate 201; the semiconductor substrate further comprises a patterned dielectric layer 203 or 103 having a cavity structure 203a or 103a, wherein the patterned dielectric layer 203 or 103 is formed on the second semiconductor substrate 2 01 and the cavity upper film layer 107, wherein the transfer substrate film layer 104 has a first surface close to the cavity structure 203a or 103a and a second surface opposite to the first surface, and the distance between the second surface and the cavity structure 203a or 103a is greater than 1/8 of the cavity feature size. Here, the surface of the transfer substrate film layer 104 close to the patterned dielectric layer is the surface of the cavity upper film layer 107 close to the patterned dielectric layer, and the upper surface of the cavity upper film layer 107 is obtained by thinning the second surface. In another example, the distance between the second surface and the cavity structure 203a or 103a is less than 2μm. In this embodiment 3, the first substrate 100 and the second substrate 200 are described in accordance with the same description as in embodiment 1 and embodiment 2, and the patterned dielectric layer 203 or 103 is described separately from embodiment 1 and embodiment 2, and is described independently of the first substrate 100 and the second substrate 200, which can be understood by those skilled in the art.

作为示例,所述空腔结构203a或103a中具有支撑结构300,所述支撑结构300的顶部表面与所述图形化介质层203或103的上表面相平齐,所述支撑结构300位于所述空腔结构203a或103a内或者所述支撑结构300的至少一端与所述空腔结构203的侧壁相接触。将空腔结构设计为具有支撑结构的空腔结构,即形成半包围式、全包围式环岛空腔,在剥离界面已经确定的情况下,可以在一定区域内,获得较大的空腔面积,含有半包围、全包围结构的环岛空腔,可以减少空腔的特征尺寸,避免顶层硅发生破损。As an example, the cavity structure 203a or 103a has a support structure 300, the top surface of the support structure 300 is flush with the upper surface of the patterned dielectric layer 203 or 103, the support structure 300 is located in the cavity structure 203a or 103a, or at least one end of the support structure 300 is in contact with the side wall of the cavity structure 203. The cavity structure is designed as a cavity structure with a support structure, that is, a semi-enclosed or fully-enclosed island cavity is formed. When the stripping interface has been determined, a larger cavity area can be obtained in a certain area. The island cavity with a semi-enclosed or fully-enclosed structure can reduce the characteristic size of the cavity and avoid damage to the top silicon.

作为示例,所述第二半导体衬底200与所述图形化介质层203或103之间还形成有隔离层202,所述空腔结构203a或103a显露所述隔离层202。As an example, an isolation layer 202 is further formed between the second semiconductor substrate 200 and the patterned dielectric layer 203 or 103 , and the cavity structure 203 a or 103 a exposes the isolation layer 202 .

作为示例,所述空腔结构203a或103a贯穿所述图形化介质层203或103且所述空腔结构203a或103a延伸至所述第二半导体衬底201及所述转移衬底膜层107中的至少一者之中。As an example, the cavity structure 203 a or 103 a penetrates the patterned dielectric layer 203 or 103 and extends into at least one of the second semiconductor substrate 201 and the transfer substrate film layer 107 .

综上所述,本发明的具有空腔结构的半导体衬底及其制备方法中,在进行离子注入形成剥离界面时依据需要形成的空腔结构预制预设剥离层,预设剥离层与需要形成的空腔结构之间的预设距离大于所述空腔结构的空腔特征尺寸的1/8,从而可以保证空腔结构上方的材料层在制备得到具有空腔结构的半导体衬底的过程中不发生破损,提高器件良率及性能。所以,本发明有效克服了现有技术中的种种缺点而具高度产业利用价值。In summary, in the semiconductor substrate with a cavity structure and the preparation method thereof of the present invention, a preset peeling layer is prefabricated according to the cavity structure to be formed when ion implantation is performed to form a peeling interface, and the preset distance between the preset peeling layer and the cavity structure to be formed is greater than 1/8 of the cavity characteristic size of the cavity structure, thereby ensuring that the material layer above the cavity structure is not damaged during the process of preparing the semiconductor substrate with a cavity structure, thereby improving the device yield and performance. Therefore, the present invention effectively overcomes various shortcomings in the prior art and has a high industrial utilization value.

上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。The above embodiments are merely illustrative of the principles and effects of the present invention, and are not intended to limit the present invention. Anyone familiar with the art may modify or alter the above embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or alterations made by a person of ordinary skill in the art without departing from the spirit and technical ideas disclosed by the present invention shall still be covered by the claims of the present invention.

Claims (19)

1.一种具有空腔结构的半导体衬底的制备方法,其特征在于,所述制备方法包括步骤:1. A method for preparing a semiconductor substrate having a cavity structure, characterized in that the preparation method comprises the steps of: 提供第一基底及第二基底;Providing a first substrate and a second substrate; 对所述第一基底进行离子注入,以于所述第一基底中形成预设剥离层,所述预设剥离层与需要形成的空腔结构之间具有预设距离,所述预设距离依据所述空腔结构设定,其中,所述设定方式包括所述预设距离大于所述空腔结构的空腔特征尺寸的1/8;Performing ion implantation on the first substrate to form a preset peeling layer in the first substrate, wherein a preset distance exists between the preset peeling layer and the cavity structure to be formed, and the preset distance is set according to the cavity structure, wherein the setting method includes that the preset distance is greater than 1/8 of the cavity characteristic size of the cavity structure; 所述空腔特征尺寸的定义方式包括:定义所述空腔结构上方平行于所述空腔结构表面的二维平面;在所述二维平面内,所述空腔结构上方具有若干选定点;对于每一所述选定点,具有经过所述选定点的若干条直线;每一条所述直线与所述空腔结构的边缘之间具有至少两个接触点,选择经过所述选定点的所述直线延伸的两个方向分别与所述选定点近邻的第一接触点及第二接触点,所述第一接触点与所述第二接触点之间的距离定义为空腔尺寸;基于经过每一所述选定点的若干所述直线得到最小的所述空腔尺寸;基于所述空腔结构上方的若干所述选定点,选取所有所述空腔尺寸中的最大值,获得所述空腔特征尺寸;将所述第一基底进行所述离子注入的一侧及所述第二基底进行键合,得到初始键合结构,所述初始键合结构包括具有所述空腔结构的图形化介质层,且所述图形化介质层与所述预设剥离层之间具有间距;以及The method for defining the characteristic size of the cavity includes: defining a two-dimensional plane above the cavity structure and parallel to the surface of the cavity structure; in the two-dimensional plane, there are a plurality of selected points above the cavity structure; for each of the selected points, there are a plurality of straight lines passing through the selected point; each of the straight lines has at least two contact points with the edge of the cavity structure, a first contact point and a second contact point are selected that are adjacent to the selected point in two directions of extension of the straight line passing through the selected point, and the distance between the first contact point and the second contact point is defined as the cavity size; the minimum cavity size is obtained based on the plurality of straight lines passing through each of the selected points; based on the plurality of selected points above the cavity structure, the maximum value of all the cavity sizes is selected to obtain the characteristic size of the cavity; bonding the side of the first substrate subjected to the ion implantation and the second substrate to obtain an initial bonding structure, the initial bonding structure comprising a patterned dielectric layer having the cavity structure, and a spacing between the patterned dielectric layer and the preset peeling layer; and 沿所述预设剥离层剥离所述第一基底,使所述第一基底的一部分转移到所述图形化介质层上,以在所述图形化介质层上形成转移衬底膜层,得到具有空腔结构的半导体衬底。The first substrate is peeled off along the preset peeling layer, so that a portion of the first substrate is transferred to the patterned dielectric layer to form a transfer substrate film layer on the patterned dielectric layer, thereby obtaining a semiconductor substrate with a cavity structure. 2.根据权利要求1所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述第一基底包括第一半导体衬底,所述预设剥离层形成在所述第一半导体衬底中,所述第二基底包括第二半导体衬底及形成在所述第二半导体衬底上的所述图形化介质层,其中,所述第一基底进行所述离子注入的一侧及所述第二基底的所述图形化介质层相键合。2. The method for preparing a semiconductor substrate with a cavity structure according to claim 1 is characterized in that the first base includes a first semiconductor substrate, the preset peeling layer is formed in the first semiconductor substrate, the second base includes a second semiconductor substrate and the patterned dielectric layer formed on the second semiconductor substrate, wherein the side of the first substrate where the ion implantation is performed is bonded to the patterned dielectric layer of the second substrate. 3.根据权利要求2所述的具有空腔结构的半导体衬底的制备方法,其特征在于,进行所述离子注入之前还包括步骤:于所述第一半导体衬底表面形成牺牲介质层,自形成有所述牺牲介质层的一侧进行所述离子注入,且在完成所述离子注入之后去除所述牺牲介质层。3. The method for preparing a semiconductor substrate with a cavity structure according to claim 2 is characterized in that before performing the ion implantation, it also includes the steps of: forming a sacrificial dielectric layer on the surface of the first semiconductor substrate, performing the ion implantation from the side where the sacrificial dielectric layer is formed, and removing the sacrificial dielectric layer after completing the ion implantation. 4.根据权利要求2所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述第二半导体衬底与所述图形化介质层之间还形成有隔离层,所述空腔结构显露所述隔离层。4 . The method for preparing a semiconductor substrate with a cavity structure according to claim 2 , wherein an isolation layer is formed between the second semiconductor substrate and the patterned dielectric layer, and the cavity structure exposes the isolation layer. 5.根据权利要求1所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述第一基底包括第一半导体衬底及形成在所述第一半导体衬底上的所述图形化介质层,所述预设剥离层形成在所述第一半导体衬底中,所述第二基底包括第二半导体衬底,其中,所述第一基底的所述图形化介质层与所述第二基底相键合。5. The method for preparing a semiconductor substrate with a cavity structure according to claim 1 is characterized in that the first substrate includes a first semiconductor substrate and the patterned dielectric layer formed on the first semiconductor substrate, the preset peeling layer is formed in the first semiconductor substrate, and the second substrate includes a second semiconductor substrate, wherein the patterned dielectric layer of the first substrate is bonded to the second substrate. 6.根据权利要求5所述的具有空腔结构的半导体衬底的制备方法,其特征在于,形成所述第一基底的步骤包括:提供所述第一半导体衬底;于所述第一半导体衬底上形成牺牲介质层;自形成有所述牺牲介质层的一侧对所述第一半导体衬底进行所述离子注入;图形化所述牺牲介质层,以得到具有所述空腔结构的所述图形化介质层。6. The method for preparing a semiconductor substrate with a cavity structure according to claim 5 is characterized in that the step of forming the first base comprises: providing the first semiconductor substrate; forming a sacrificial dielectric layer on the first semiconductor substrate; performing the ion implantation on the first semiconductor substrate from the side where the sacrificial dielectric layer is formed; and patterning the sacrificial dielectric layer to obtain the patterned dielectric layer with the cavity structure. 7.根据权利要求5所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述第二基底还包括形成在所述第二半导体衬底上的隔离层,所述隔离层与所述第一基底的所述图形化介质层相键合,且所述图形化介质层中的所述空腔结构显露所述隔离层。7. The method for preparing a semiconductor substrate with a cavity structure according to claim 5 is characterized in that the second substrate also includes an isolation layer formed on the second semiconductor substrate, the isolation layer is bonded to the patterned dielectric layer of the first substrate, and the cavity structure in the patterned dielectric layer exposes the isolation layer. 8.根据权利要求1所述的具有空腔结构的半导体衬底的制备方法,其特征在于,进行所述离子注入形成所述预设剥离层的步骤包括:对所述第一基底进行第一离子注入,以在所述第一基底中形成初始剥离层;在所述初始剥离层的位置进行第二离子注入,以形成所述预设剥离层,其中,所述第一离子注入的注入粒子包括含B杂质,所述第二离子注入的注入粒子包括H离子、He离子中的至少一种。8. The method for preparing a semiconductor substrate with a cavity structure according to claim 1 is characterized in that the step of performing the ion implantation to form the preset stripping layer comprises: performing a first ion implantation on the first substrate to form an initial stripping layer in the first substrate; performing a second ion implantation at the position of the initial stripping layer to form the preset stripping layer, wherein the implanted particles of the first ion implantation include B-containing impurities, and the implanted particles of the second ion implantation include at least one of H ions and He ions. 9.根据权利要求8所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述第一离子注入的注入剂量小于所述第二离子注入的注入剂量;其中,所述第一离子注入的注入剂量介于1e11~1e13/cm2之间,所述第二离子注入的注入剂量介于1e16~1e17/cm2之间。9. The method for preparing a semiconductor substrate with a cavity structure according to claim 8 is characterized in that the implantation dose of the first ion implantation is less than the implantation dose of the second ion implantation; wherein the implantation dose of the first ion implantation is between 1e11 and 1e13/ cm2 , and the implantation dose of the second ion implantation is between 1e16 and 1e17/ cm2 . 10.根据权利要求1所述的具有空腔结构的半导体衬底的制备方法,其特征在于,沿所述预设剥离层剥离所述第一基底之后还包括步骤:对所述具有空腔结构的半导体衬底进行加固处理,所述加固处理包括对所述具有空腔结构的半导体衬底进行加热处理。10. The method for preparing a semiconductor substrate with a cavity structure according to claim 1 is characterized in that after peeling off the first base along the preset peeling layer, it also includes the step of: reinforcing the semiconductor substrate with a cavity structure, and the reinforcement treatment includes heating the semiconductor substrate with a cavity structure. 11.根据权利要求10所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述加热处理在预设氛围下进行,所述预设氛围包括氧气气氛,以在所述转移衬底膜层表面形成表面氧化层,并在完成所述加热处理后去除所述表面氧化层以减薄所述转移衬底膜层。11. The method for preparing a semiconductor substrate with a cavity structure according to claim 10 is characterized in that the heat treatment is carried out under a preset atmosphere, and the preset atmosphere includes an oxygen atmosphere to form a surface oxide layer on the surface of the transfer substrate film layer, and after completing the heat treatment, the surface oxide layer is removed to thin the transfer substrate film layer. 12.根据权利要求1所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述图形化介质层中的所述空腔结构还延伸至所述图形化介质层下方的材料层中。12 . The method for preparing a semiconductor substrate with a cavity structure according to claim 1 , wherein the cavity structure in the patterned dielectric layer also extends into a material layer below the patterned dielectric layer. 13.根据权利要求1所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述预设剥离层与所述空腔结构之间的所述预设距离介于2nm-10μm之间。13 . The method for preparing a semiconductor substrate with a cavity structure according to claim 1 , wherein the preset distance between the preset peeling layer and the cavity structure is between 2 nm and 10 μm. 14.根据权利要求1所述的具有空腔结构的半导体衬底的制备方法,其特征在于,所述预设距离与所述空腔结构的特征尺寸的比的设定方式包括:定义剥离过程中所述空腔结构上表面的压强为p,定义指向面内所述空腔结构的长度无限长,定义最恶劣情况为所述空腔上方的所述转移衬底膜层的中心位置两侧仅以所述图形化介质层为支撑点,得到所述转移衬底膜层中的最大应力Mmax∝pL2,最大应力σmax∝qL2/h2,其中,h为所述预设距离,L为所述空腔结构的特征尺寸,基于所述转移衬底膜层能承受的最大应力,采用试验设计的方式得到所述预设距离与所述空腔结构的特征尺寸的比。14. The method for preparing a semiconductor substrate with a cavity structure according to claim 1 is characterized in that the setting method of the ratio of the preset distance to the characteristic size of the cavity structure includes: defining the pressure on the upper surface of the cavity structure during the peeling process as p, defining the length of the cavity structure in the pointing plane as infinite, defining the worst case as the center position of the transfer substrate film layer above the cavity with only the patterned dielectric layer as support points on both sides, and obtaining the maximum stress Mmax∝pL2 and the maximum stress σmax∝qL2/h2 in the transfer substrate film layer, wherein h is the preset distance, L is the characteristic size of the cavity structure, and based on the maximum stress that the transfer substrate film layer can withstand, the ratio of the preset distance to the characteristic size of the cavity structure is obtained by experimental design. 15.根据权利要求1-14中任意一项所述的具有空腔结构的半导体衬底的制备方法,其特征在于,得到具有空腔结构的半导体衬底后还包括步骤:对所述转移衬底膜层结构进行减薄处理,所述减薄处理包括采用化学机械研磨进行第一减薄及采用氧化减薄进行第二减薄。15. The method for preparing a semiconductor substrate with a cavity structure according to any one of claims 1 to 14, characterized in that after obtaining the semiconductor substrate with a cavity structure, it also includes the step of: thinning the transfer substrate film layer structure, the thinning treatment including a first thinning by chemical mechanical polishing and a second thinning by oxidation thinning. 16.根据权利要求15所述的具有空腔结构的半导体衬底的制备方法,其特征在于,进行所述减薄处理之后还包括步骤:对所述减薄处理后的表面进行修复处理,以使所述减薄处理后的表面达到原子级平整,所述修复处理的工艺包括对所述减薄处理后的所述具有空腔结构的半导体衬底在氢气氛围下退火,退火温度介于800℃-1300℃之间。16. The method for preparing a semiconductor substrate with a cavity structure according to claim 15 is characterized in that after the thinning treatment, it also includes the step of: repairing the surface after the thinning treatment to make the surface after the thinning treatment atomic-level flat, and the repair treatment process includes annealing the semiconductor substrate with a cavity structure after the thinning treatment in a hydrogen atmosphere, and the annealing temperature is between 800°C and 1300°C. 17.一种具有空腔结构的半导体衬底结构,其特征在于,所述半导体衬底结构包括:17. A semiconductor substrate structure with a cavity structure, characterized in that the semiconductor substrate structure comprises: 第一基底,包括空腔上膜层,所述空腔上膜层基于转移衬底膜层减薄得到;The first substrate comprises a cavity upper film layer, wherein the cavity upper film layer is obtained by thinning the transfer substrate film layer; 第二基底,与所述第一基底相键合,所述第二基底包括第二半导体衬底;A second substrate bonded to the first substrate, wherein the second substrate comprises a second semiconductor substrate; 具有空腔结构的图形化介质层,形成于所述第二半导体衬底与所述空腔上膜层之间,所述转移衬底膜层具有靠近所述空腔结构的第一表面及与所述第一表面相对的第二表面,所述第二表面与所述空腔结构之间的距离大于所述空腔结构的空腔特征尺寸的1/8;A patterned dielectric layer having a cavity structure is formed between the second semiconductor substrate and the cavity upper film layer, the transfer substrate film layer having a first surface close to the cavity structure and a second surface opposite to the first surface, and a distance between the second surface and the cavity structure is greater than 1/8 of a cavity feature size of the cavity structure; 其中,所述空腔特征尺寸的定义方式包括:定义所述空腔结构上方平行于所述空腔结构表面的二维平面;在所述二维平面内,所述空腔结构上方具有若干选定点;对于每一所述选定点,具有经过所述选定点的若干条直线;每一条所述直线与所述空腔结构的边缘之间具有至少两个接触点,选择经过所述选定点的所述直线延伸的两个方向分别与所述选定点近邻的第一接触点及第二接触点,所述第一接触点与所述第二接触点之间的距离定义为空腔尺寸;基于经过每一所述选定点的若干所述直线得到最小的所述空腔尺寸;基于所述空腔结构上方的若干所述选定点,选取所有所述空腔尺寸中的最大值,获得所述空腔特征尺寸。Among them, the definition method of the cavity characteristic size includes: defining a two-dimensional plane above the cavity structure and parallel to the surface of the cavity structure; in the two-dimensional plane, there are several selected points above the cavity structure; for each of the selected points, there are several straight lines passing through the selected point; each of the straight lines has at least two contact points with the edge of the cavity structure, and a first contact point and a second contact point that are adjacent to the selected point in two directions of extension of the straight line passing through the selected point are selected, and the distance between the first contact point and the second contact point is defined as the cavity size; based on the several straight lines passing through each of the selected points, the minimum cavity size is obtained; based on the several selected points above the cavity structure, the maximum value of all the cavity sizes is selected to obtain the cavity characteristic size. 18.根据权利要求17所述的具有空腔结构的半导体衬底,其特征在于,所述第二半导体衬底与所述图形化介质层之间还形成有隔离层,所述空腔结构显露所述隔离层。18 . The semiconductor substrate with a cavity structure according to claim 17 , wherein an isolation layer is formed between the second semiconductor substrate and the patterned dielectric layer, and the cavity structure exposes the isolation layer. 19.根据权利要求17-18中任意一项所述的具有空腔结构的半导体衬底,其特征在于,所述空腔结构贯穿所述图形化介质层且所述空腔结构还延伸至所述第二半导体衬底及所述转移衬底膜层中的至少一者之中。19. The semiconductor substrate with a cavity structure according to any one of claims 17-18, characterized in that the cavity structure penetrates the patterned dielectric layer and the cavity structure also extends into at least one of the second semiconductor substrate and the transfer substrate film layer.
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