CN111117800A - 生物膜去除清洗剂及其制备方法 - Google Patents
生物膜去除清洗剂及其制备方法 Download PDFInfo
- Publication number
- CN111117800A CN111117800A CN201911362803.0A CN201911362803A CN111117800A CN 111117800 A CN111117800 A CN 111117800A CN 201911362803 A CN201911362803 A CN 201911362803A CN 111117800 A CN111117800 A CN 111117800A
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- CN
- China
- Prior art keywords
- acid
- cleaning agent
- surfactant
- composite
- removal cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 33
- 239000012528 membrane Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000002131 composite material Substances 0.000 claims abstract description 23
- 230000003373 anti-fouling effect Effects 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 19
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 11
- 239000003899 bactericide agent Substances 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 9
- 230000000996 additive effect Effects 0.000 claims abstract description 9
- 239000002738 chelating agent Substances 0.000 claims abstract description 9
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims abstract description 5
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical group [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims abstract description 5
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 4
- 229920013813 TRITON H-66 Polymers 0.000 claims abstract description 3
- 229920000768 polyamine Polymers 0.000 claims abstract description 3
- 229920000642 polymer Polymers 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 27
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- -1 Polyoxyethylene Polymers 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- BAERPNBPLZWCES-UHFFFAOYSA-N (2-hydroxy-1-phosphonoethyl)phosphonic acid Chemical compound OCC(P(O)(O)=O)P(O)(O)=O BAERPNBPLZWCES-UHFFFAOYSA-N 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 claims description 6
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- QGJDXUIYIUGQGO-UHFFFAOYSA-N 1-[2-[(2-methylpropan-2-yl)oxycarbonylamino]propanoyl]pyrrolidine-2-carboxylic acid Chemical compound CC(C)(C)OC(=O)NC(C)C(=O)N1CCCC1C(O)=O QGJDXUIYIUGQGO-UHFFFAOYSA-N 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910003638 H2SiF6 Inorganic materials 0.000 claims description 2
- 229910004039 HBF4 Inorganic materials 0.000 claims description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 2
- BVBIQASDHXEFKW-UHFFFAOYSA-N P1(OCCCCO1)=O.C(CN)N.[Na] Chemical compound P1(OCCCCO1)=O.C(CN)N.[Na] BVBIQASDHXEFKW-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 125000006177 alkyl benzyl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical group 0.000 claims description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 239000002280 amphoteric surfactant Substances 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 claims description 2
- 229960001950 benzethonium chloride Drugs 0.000 claims description 2
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 claims description 2
- 229960003237 betaine Drugs 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 239000003093 cationic surfactant Substances 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 235000011167 hydrochloric acid Nutrition 0.000 claims description 2
- GSWAOPJLTADLTN-UHFFFAOYSA-N oxidanimine Chemical compound [O-][NH3+] GSWAOPJLTADLTN-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 239000010452 phosphate Substances 0.000 claims description 2
- 235000011007 phosphoric acid Nutrition 0.000 claims description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 claims description 2
- 229940061605 tetrasodium glutamate diacetate Drugs 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- 239000008213 purified water Substances 0.000 claims 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims 2
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 claims 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-O N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonic acid Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS(O)(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-O 0.000 claims 1
- PDIZYYQQWUOPPK-UHFFFAOYSA-N acetic acid;2-(methylamino)acetic acid Chemical compound CC(O)=O.CC(O)=O.CNCC(O)=O PDIZYYQQWUOPPK-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims 1
- 229960002216 methylparaben Drugs 0.000 claims 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 19
- 238000000034 method Methods 0.000 abstract description 8
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 8
- 230000001954 sterilising effect Effects 0.000 abstract description 6
- 238000005202 decontamination Methods 0.000 abstract description 5
- 230000003588 decontaminative effect Effects 0.000 abstract description 5
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- 238000005956 quaternization reaction Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- 238000009636 ATP test Methods 0.000 description 1
- 208000035143 Bacterial infection Diseases 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- MLDWGLQSBBCMMO-UHFFFAOYSA-N [Na].[Na].[Na].CNCC(=O)O Chemical compound [Na].[Na].[Na].CNCC(=O)O MLDWGLQSBBCMMO-UHFFFAOYSA-N 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 208000022362 bacterial infectious disease Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000032770 biofilm formation Effects 0.000 description 1
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical group 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2017—Monohydric alcohols branched
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
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Abstract
本发明公开了一种生物膜去除清洗剂，包含如下质量百分比的原料：增溶剂1％～10％、复合表面活性剂5％～30％、抗污垢添加剂1～5％、复合酸1％～10％、过氧化氢5％～15％、溶剂2％～15％、杀菌剂1％～3％、螯合剂1％～3％、余量为水。增溶剂为二甲苯磺酸钠、Tomamine Amphoteric 400、TRITON H‑66、CRODATERICTM PI中一种或者多种的混合物。抗污垢添加剂为聚丙烯酸酯、EO/PO嵌段季铵化的聚胺型聚合物中的一种或者两者混合物。本发明还公开了其制备方法，生物膜去除清洗剂制备简单方便，去污高效，且具有阻垢、杀菌抑菌性能，尤其适合硬表面清洁和抗污垢。
Description
技术领域
本发明涉及一种生物膜去除清洗剂及其制备方法，尤其涉及一种抗污垢生物膜去除清洗剂及其制备方法，属于清洗剂技术领域。
背景技术
使用后的手术器械下送后，首先要做的工作就是需要将其倒在台面上进行回收清点并去除纱布、胶带等杂物，在这个过程中，器械上的污物会掉落在台面上造成污染。除去这个过程，污染在的器械再消毒供应中心流转的过程都会对消毒供应中心的常见硬表面如清洗台面、运转车交叉污染。如果不进行及时的清洗消毒，长期以往会滋生生物膜。值得一提的是，一般的清洗方法很难将其彻底清除生物膜。生物膜具有很大的危害性，据估计65％的人体细菌感染都与生物膜相关。生物膜形成后，需要2400倍的抗生素用量，很多院内相关感染的爆发都是与生物膜密切相关。
目前消毒供应中心常常会自行稀释一些碱性清洗剂进行擦拭和清洁，或者稀释一些含酶的手术器械清洗剂进行清洗，或者购买一些民用的厨房清洁用品进行去污。这些方法或多或少存在一些问题，如去污和杀菌效果不能兼顾，去污不彻底或者效果差，硬表面常常越擦越暗且角落都存在泛黄和污垢堆积现象。
而且目前常用的清洗剂起到的效果仅仅是即时的去污，清洁完的硬表面很快会再次被污染，下次清洁依然需要消耗相同的时间和精力进行去污。
发明内容
本发明的目的在于克服现有的生物膜去除清洗剂无法实现清洗后抗污垢的不足，提供一种生物膜去除清洗剂，技术方案如下：
生物膜去除清洗剂，包含如下质量百分比的原料：
增溶剂1％～10％、复合表面活性剂5％～30％、抗污垢添加剂1～10％、复合酸1％～10％、过氧化氢5％～15％、溶剂2％～15％、杀菌剂1％～10％、螯合剂1％～3％、余量为水。
进一步地，增溶剂为二甲苯磺酸钠、Tomamine Amphoteric 400、TRITON H-66、CRODATERICTMPI中一种或者多种的混合物。
进一步地，复合表面活性剂为非离子表面活性剂、阴离子和两性表面活性剂中的两种或者多种的混合物。
优选地，非离子表面活性剂为C6～C18聚氧乙烯醚分子结构式为R-A-OH，R为C6～C18线型或者支化烷基，A为-(OC2H4)x-，其中X为3～9。
阴离子表面活性剂为烷基苯磺酸钠、α-烯烃磺酸盐、烷基磺酸盐、α-磺基脂肪酸甲酯、脂肪酸磺烷基酯、脂肪醇硫酸盐、仲烷基硫酸盐、脂肪醇聚氧乙烯醚硫酸酯盐、醇醚磷酸酯盐中的一种或者多种混合物。
两性离子表面活性剂为羧酸基甜菜碱、磺基甜菜碱、氧化铵类表面活性剂中的一种或者多种混合物。
抗污垢添加剂为聚丙烯酸酯、EO/PO嵌段季铵化的聚胺型聚合物中的一种或者两者混合物。
优选地，复合酸为柠檬酸、乳酸、甲酸、磷酸、盐酸、硫酸、羟基乙酸、草酸、HF、H2SiF6、HBF4中的一种或者多种混合物。
进一步地，杀菌剂为1，2-苯并异噻唑啉-3-酮、2-甲基-4-异噻唑啉酮-3-酮、重氮洁马、尼泊金甲酯、苄索氯铵、十二烷基二丙烯三胺、椰油烷基苄基二甲基氯化铵、双葵基二甲基氯化铵中的一种或者多种混合物。
优选地，螯合剂为羟基乙叉二膦酸(HEDP)、二乙烯三胺五甲叉膦酸(DTPMPA)、乙二胺四甲叉膦酸钠(EDTMPS)、三聚磷酸钠、硅酸盐类、葡庚糖酸钠(Crodaquest A300)、谷氨酸二乙酸四钠(GLDA 47)和甲基甘氨酸二乙酸三钠盐(Trilion M)中的一种或者多种混合物。
生物膜去除清洗剂的制备方法，包括以下步骤：
将增溶剂、螯合剂、表面活性剂、溶剂、杀菌剂、复合酸、抗污垢添加剂和水在搅拌釜中混合搅拌至溶解制得。
进一步地，将部分水加入搅拌釜中，加入增溶剂升温并搅拌至溶解；
加入表面活性剂——C8～C18聚氧乙烯醚、阴离子表面活性剂，阳离子表面活性剂和溶剂，搅拌至溶解；
加入螯合剂搅拌至均匀；
降到室温后加入复合酸搅拌至溶解；
加入杀菌剂搅拌至溶解；
将剩余水加入，再搅拌后过滤，得到抗污垢生物膜去除剂。
与现有技术相比，本发明所达到的有益效果：
本发明中的生物膜去除清洗剂制备简单方便，去污高效，且具有阻垢、杀菌抑菌性能，适用于医院各个科室尤其是消毒供应中心的硬表面清洗。
具体实施方式
下面对本发明作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1
抗污垢生物膜去除剂，包括以下质量分数的组分：
二甲苯磺酸钠8％、复合表面活性剂20％、ModiSurf 5％、复合酸6％、过氧化氢10％、异丙醇5％、卡松3％、HEDP 2％、余量水。
制备方法：搅拌釜清洗消毒后，先通入80％的水，开启搅拌器，后加入8％增溶剂二甲苯磺酸钠，升温至65℃，搅拌至溶解，分别将10％表面活性剂LF221、3％LAS、7％N，N-二甲基十二烷基氧化铵、5％异丙醇加入搅拌釜中，搅拌至溶解，再加入3％HEDP和过氧化氢，降到室温后加入复合酸和3％卡松搅拌至溶解，其中复合酸比例为：柠檬酸：草酸：甲酸＝7：2：1，再加入1％ModiSurf搅拌至溶解后，再添加余量的水，再搅拌半小时后过滤，得到抗污垢生物膜去除剂。
实施例2
抗污垢生物膜去除剂，包括以下质量分数的组分：
PI 7％、复合表面活性剂30％、聚丙烯酸酯5％、复合酸10％、过氧化氢10％、丙二醇丁醚5％、卡松3％、DTPMPA2％、余量水。
制备方法：搅拌釜清洗消毒后，先通入80％的水，开启搅拌器，后加入8％增溶剂PI，升温至65℃，搅拌至溶解，分别将10％表面活性剂LF401、2％AES、3％N，N-二甲基十六烷基氧化铵、5％丙二醇丁醚加入搅拌釜中，搅拌至溶解，再加入2％DTPMPA和过氧化氢，降到室温后加入复合酸和3％卡松搅拌至溶解，其中复合酸比例为：柠檬酸：乳酸：磷酸＝7：2：1，再加入5％ModiSurf搅拌至溶解后，再添加余量的水，再搅拌半小时后过滤，得到抗污垢生物膜去除剂。
性能测试结果
将上述实施例2中制得的生物膜去除清洗剂与市面销售的一般硬表面清洗剂(产品A、产品B、产品C)在清洗效果、生物膜去除性能(杀菌性能)进行评价，结果见表1。
防污垢性能：用测试配方预先处理需测试的材质(不锈钢)，然后涂上一层预先准备好的污垢，并让其变干。然后进行漂洗，并在20°角测量表面反射的光泽度。
清洗效果评价方法：预先准备好的污垢(猪血)，并让其变干。然后进行浸泡清洗。
生物膜去除效果：采用ATP测试和血液和细菌混合物的去除效果测试。
表1：实施例2与产品A、产品B、产品C性能对比
本发明的抗污垢生物膜去除剂克服了传统硬表面清洗剂不能同时兼具清洁、杀菌、去除生物膜和良好的抗污功能，具有高效去除生物膜、高效去污和抗污功能。
为了有效的解决上述硬表面的问题和缺点，同时在清洗时能保证良好的生物膜去除效果。本发明的原理是先通过表面活性剂等去污成分对硬表面进行去污，协同过氧化氢和杀菌剂对生物膜进行杀菌，两者同步进行直至表面清洁。最后通过清洁剂中的抗污垢添加剂对硬表面进行修饰调节，能在使硬表面在后续起到抗污垢性能。使硬表面变得更加亲水(水接触角变小)，硬表面具有一定的抗静电吸附、抑菌(清洁剂中的杀菌成分)功能，污物和细菌不容易附着，且在后续进行清洁时候，由于表面具有一定的亲水性，污物更易被润湿、易清洁，对后续进一步快速的松动脱落起到良好的清洁助推效果。
本发明的生物膜去除清洗剂制备过程和方法简单，性能可靠，绿色环保，无毒无害无污染，是一种理想的硬表面清洗剂。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变形，这些改进和变形也应视为本发明的保护范围。
Claims (10)
1.生物膜去除清洗剂，其特征在于，包含如下质量百分比的原料：
增溶剂1％～10％、复合表面活性剂5％～30％、抗污垢添加剂1～5％、复合酸1％～10％、过氧化氢5％～15％、溶剂2％～15％、杀菌剂1％～3％、螯合剂1％～3％、余量为纯化水。
2.根据权利要求1所述的生物膜去除清洗剂，其特征在于，所述增溶剂为二甲苯磺酸钠、Tomamine Amphoteric 400、TRITON H-66、CRODATERICTM PI中一种或者多种的混合物。
3.根据权利要求1所述的生物膜去除清洗剂，其特征在于，所述复合表面活性剂为非离子表面活性剂、阴离子和两性表面活性剂中的两种或者多种的混合物。
4.根据权利要求3所述的生物膜去除清洗剂，其特征在于，所述非离子表面活性剂为C6～C18聚氧乙烯醚，分子结构式为R-A-OH，R为C6～C18线型或者支化烷基，A为-(OC2H4)x-，其中X为3～9；
所述阴离子表面活性剂为烷基苯磺酸钠、α-烯烃磺酸盐、烷基磺酸盐、α-磺基脂肪酸甲酯、脂肪酸磺烷基酯、脂肪醇硫酸盐、仲烷基硫酸盐、脂肪醇聚氧乙烯醚硫酸酯盐、醇醚磷酸酯盐中的一种或者多种混合物；
所述两性离子表面活性剂为羧酸基甜菜碱、磺基甜菜碱、氧化铵类表面活性剂中的一种或者多种混合物。
5.根据权利要求1所述的生物膜去除清洗剂，其特征在于，所述抗污垢添加剂为聚丙烯酸酯、EO/PO嵌段季铵化的聚胺型聚合物中的一种或者两者混合物。
6.根据权利要求1所述的生物膜去除清洗剂，其特征在于，所述复合酸为柠檬酸、乳酸、甲酸、磷酸、盐酸、硫酸、羟基乙酸、草酸、HF、H2SiF6、HBF4中的一种或者多种混合物。
7.根据权利要求1所述的生物膜去除清洗剂，其特征在于，所述杀菌剂为1，2-苯并异噻唑啉-3-酮、2-甲基-4-异噻唑啉酮-3-酮、重氮洁马、尼泊金甲酯、苄索氯铵、十二烷基二丙烯三胺、椰油烷基苄基二甲基氯化铵、双葵基二甲基氯化铵中的一种或者多种混合物。
8.根据权利要求1所述的生物膜去除清洗剂，其特征在于，所述螯合剂为羟基乙叉二膦酸(HEDP)、二乙烯三胺五甲叉膦酸(DTPMPA)、乙二胺四甲叉膦酸钠(EDTMPS)、三聚磷酸钠、硅酸盐类、葡庚糖酸钠(Crodaquest A300)、谷氨酸二乙酸四钠(GLDA 47)和甲基甘氨酸二乙酸三钠盐(Trilion M)中的一种或者多种混合物。
9.生物膜去除清洗剂的制备方法，其特征在于，包括以下步骤：
增溶剂1％～10％、复合表面活性剂5％～30％、抗污垢添加剂1～5％、复合酸1％～10％、过氧化氢5％～15％、溶剂2％～15％、杀菌剂1％～3％、螯合剂1％～3％、余量的纯化水在搅拌釜中混合搅拌至溶解制得。
10.根据权利要求9的制备方法，其特征在于：
将80％的纯化水加入搅拌釜中，加入增溶剂升温并搅拌至溶解；
加入表面活性剂——C8～C18聚氧乙烯醚、阴离子表面活性剂，阳离子表面活性剂和溶剂，搅拌至溶解；
加入螯合剂搅拌至均匀；
降到室温后加入复合酸搅拌至溶解。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111454783A (zh) * | 2020-04-13 | 2020-07-28 | 山东利尔康医疗科技股份有限公司 | 一种生物膜清洗液配方及其制备方法 |
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| CN114747575A (zh) * | 2022-05-17 | 2022-07-15 | 山东新华莎罗雅生物技术有限公司 | 过氧乙酸消毒液及其制备方法 |
| CN114836273A (zh) * | 2022-04-26 | 2022-08-02 | 潍坊加易加生物科技有限公司 | 一种用于饲水线的清洁剂组合物及其使用方法 |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5942480A (en) * | 1994-12-30 | 1999-08-24 | Universite De Montreal | Synergistic detergent and disinfectant combinations for decontamination biofilm-coated surfaces |
| EP1027175A4 (en) * | 1997-06-23 | 2002-08-14 | Princeton Trade & Tech Inc | CLEANING COMPOSITION AND APPARATUS FOR THE REMOVAL OF ORGANIC FILM AND COATING OF PIPES AND PIPES AND METHOD THEREFOR |
| CN1973027A (zh) * | 2004-07-28 | 2007-05-30 | 株式会社Adeka | 有机无机复合污垢清洁剂及人工透析机的清洁方法 |
| JP2008266562A (ja) * | 2007-04-16 | 2008-11-06 | Floran Gmbh | 飲料水配管から固形沈積物を除去することを主たる目的とする、少なくとも４種の成分と水との混合物からなる洗浄剤 |
| CN104312807A (zh) * | 2014-10-23 | 2015-01-28 | 深圳市科玺化工有限公司 | 一种酸性洗瓶添加剂及应用 |
| CN106635446A (zh) * | 2016-09-26 | 2017-05-10 | 浙江工商大学 | 一种生物膜清洁剂及其制备和应用 |
| CN106800984A (zh) * | 2015-11-26 | 2017-06-06 | 瑞普（天津）生物药业有限公司 | 一种酸性管道清洗剂及其制备方法 |
-
2019
- 2019-12-26 CN CN201911362803.0A patent/CN111117800A/zh active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5942480A (en) * | 1994-12-30 | 1999-08-24 | Universite De Montreal | Synergistic detergent and disinfectant combinations for decontamination biofilm-coated surfaces |
| EP1027175A4 (en) * | 1997-06-23 | 2002-08-14 | Princeton Trade & Tech Inc | CLEANING COMPOSITION AND APPARATUS FOR THE REMOVAL OF ORGANIC FILM AND COATING OF PIPES AND PIPES AND METHOD THEREFOR |
| CN1973027A (zh) * | 2004-07-28 | 2007-05-30 | 株式会社Adeka | 有机无机复合污垢清洁剂及人工透析机的清洁方法 |
| JP2008266562A (ja) * | 2007-04-16 | 2008-11-06 | Floran Gmbh | 飲料水配管から固形沈積物を除去することを主たる目的とする、少なくとも４種の成分と水との混合物からなる洗浄剤 |
| CN104312807A (zh) * | 2014-10-23 | 2015-01-28 | 深圳市科玺化工有限公司 | 一种酸性洗瓶添加剂及应用 |
| CN106800984A (zh) * | 2015-11-26 | 2017-06-06 | 瑞普（天津）生物药业有限公司 | 一种酸性管道清洗剂及其制备方法 |
| CN106635446A (zh) * | 2016-09-26 | 2017-05-10 | 浙江工商大学 | 一种生物膜清洁剂及其制备和应用 |
Non-Patent Citations (1)
| Title |
|---|
| 闫永涛: "用于硬表面清洁产品中的新型表面改性添加剂", 《中国洗涤用品工业》 * |
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| CN111454783A (zh) * | 2020-04-13 | 2020-07-28 | 山东利尔康医疗科技股份有限公司 | 一种生物膜清洗液配方及其制备方法 |
| CN112625809A (zh) * | 2020-12-18 | 2021-04-09 | 广州立白企业集团有限公司 | 洗碗机机体洗涤剂液体组合物及制备方法 |
| CN114836273A (zh) * | 2022-04-26 | 2022-08-02 | 潍坊加易加生物科技有限公司 | 一种用于饲水线的清洁剂组合物及其使用方法 |
| CN114836273B (zh) * | 2022-04-26 | 2024-03-29 | 潍坊加易加生物科技有限公司 | 一种用于饲水线的清洁剂组合物及其使用方法 |
| CN114747575A (zh) * | 2022-05-17 | 2022-07-15 | 山东新华莎罗雅生物技术有限公司 | 过氧乙酸消毒液及其制备方法 |
| CN114747575B (zh) * | 2022-05-17 | 2024-03-26 | 山东新华莎罗雅生物技术有限公司 | 过氧乙酸消毒液及其制备方法 |
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