CN1110265A - Organic compound fertilizer and its process - Google Patents
Organic compound fertilizer and its process Download PDFInfo
- Publication number
- CN1110265A CN1110265A CN 94103905 CN94103905A CN1110265A CN 1110265 A CN1110265 A CN 1110265A CN 94103905 CN94103905 CN 94103905 CN 94103905 A CN94103905 A CN 94103905A CN 1110265 A CN1110265 A CN 1110265A
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- China
- Prior art keywords
- amino acid
- sugar
- potassium
- auxiliary
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000000034 method Methods 0.000 title abstract description 11
- 150000002894 organic compounds Chemical class 0.000 title abstract description 4
- 150000001413 amino acids Chemical class 0.000 claims abstract description 27
- 239000002366 mineral element Substances 0.000 claims abstract description 14
- 230000032050 esterification Effects 0.000 claims abstract description 7
- 238000005886 esterification reaction Methods 0.000 claims abstract description 7
- 239000013522 chelant Substances 0.000 claims abstract description 6
- 235000000346 sugar Nutrition 0.000 claims description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- 235000015097 nutrients Nutrition 0.000 claims description 14
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 12
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- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- 239000011591 potassium Substances 0.000 claims description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 11
- 230000007062 hydrolysis Effects 0.000 claims description 11
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to a formula of organic compound fertilizer and its preparation process. It mainly consists of amino acid mineral element chelate, saccharophosphate, azophoska and adjuvant, and the above-mentioned materials are passed through such processes of hydrolyzing, chelating esterification and homogenizing, and made into a colloidal suspension miscible body. The invented product can be used for foliage dressing, root fertilization and seed dressing, and can notably raise the yield and disease resistance of crop, and improve its quality.
Description
The invention belongs to fertilizer, be used for the organic composite fertilizer of plant husbandry, by amino acid mineral element inner complex, nitrogen, phosphorus, potassium, compositions such as organic nutrient.
The required fertilizer of plant-growth except nitrogen, phosphorus, potassium three elements, also needs constant and trace mineral element and other nutrition.Photosynthesis is the main path of all kinds of farm crop substance accumulations, and it is the photosynthetic cycle process of the phosphoric acid sugar under the enzyme catalysis, and the respiration that accompanies with it is the oxidising process of glucose, and the intermediate product of this process and nitrogen are the bases of protein synthesis.Amino acid and ribose are again the bases that enzyme forms.Photosynthesis not only needs mineral nutrient, also needs sugared nutrition.Traditional fertilizer supply crop inorganic states mineral nutrient element.U.S. Pat-4,169,716, form with metalloprotein salt provides trace mineral element, improved trace elements absorbed and utilization than inorganic salt, but the phosphoric acid ester of the nutrition of photosynthetic important nutrient sugar, sugar has been left in the basket, thereby influenced photosynthetic efficient and output.In addition, on manufacturing process, also there is weak point.Such as this type of leaf fertilizer, be to provide with liquid form, effective component content is low, and productive expense is than higher.
The objective of the invention is shortcoming at prior art, design a kind of by amino acid mineral substance inner complex and sugar phosphoric ester and other nutrient substance compound organic fertilizer, to strengthen the synergism function of each nutrient substance, thereby raising photosynthetic efficiency, improve the quality of photosynthate and increase output, reduce the agricultural-food production cost.
Another object of the present invention is a production technique of improving compoiste fertilizer, and hydrolysis, chelating and Phosphation are combined, and forms the outstanding molten mixed body of glue through the homogeneous Combined Processing.
One of to achieve these goals, strengthen photosynthesis of plants, the present invention makes it compound with amino acid mineral element inner complex with sugar phosphoric esterization, and with the nitrogen synergism, provide high-effect catalysis nutrient substance to photosynthetic cycle.
The present invention is by amino acid mineral nutrient inner complex, nitrogen, phosphorus, potassium, and sugar phosphoric ester, auxiliary and water are formed.
Mineral nutrient comprises nitrogen, phosphorus, potassium three elements, also comprises essential elements such as calcium, magnesium, sulphur, iron, manganese, zinc, boron, copper, molybdenum, and cobalt, nickel, selenium, rare earth element etc.Rare earth element is based on lanthanum, cerium, praseodymium, neodymium.Above-mentioned element is denitrogenated, phosphorus, potassium all provides with the amino-acid chelate form outward; The phosphorus element can be provided by forms such as phosphoric acid salt and/or polyphosphoric acid salts; Potassium can be provided by forms such as Repone K, saltpetre, vitriolate of tartar.
Amino acid is aminoacids complex and/or simple peptide, is obtained by proteolysis, also can be strengthened by the part total free aminoacids.Amino acid is the main sequestering agent of mineral element.
Sugar nutrition is monose and/or simple sugars, can be obtained by starch and cellulose hydrolysis, combines with phosphoric acid and forms sugar phosphoric ester.
Auxiliary is simple organic nutrient, plant hormone and growth regulatory substance, and tensio-active agent etc., the simple organic nutrient here is acetate, citric acid, humic acids, glycerine etc.Plant hormone and growth regulatory substance are Plant hormones regulators,gibberellins, indolylacetic acid, cytokinin, 2,4-D, naphthylacetic acid etc.Also can contain triacontanol price quote, guaiacolate etc.
Tensio-active agent is alkylbenzene sulfonate, peregal, polyvinyl alcohol, class of department, tween, phosphatide, gelatin etc.
Naphthenic acid, VITAMIN, zymin also can be used as assistant agent and use.
(quality %) composed as follows of the present invention:
Nitrogen, phosphorus, potassium three elements:
Total nitrogen (N) 0.5-8.0
Phosphorus (P) 1.0-6.0
Potassium (K) 0.5-4.0
Amino acid mineral element inner complex 3.0-25.0
Its Mineral Elements in Jadeite Shellfish is magnesium, calcium, iron, manganese, zinc, boron, copper, molybdenum or/and rare earth element, and its content distribution is:
Element term Ca Mg Fe Mo rare earth
Content 0.3-0.6 0.1-0.5 0.01-0.1 0.0001-0.0004 0.1-0.5
Element term Mn Zn B Cu
Content 0.05-0.10 0.001-0.04 0.005-0.02 0.0004-0.004
In the amino-acid chelate, sequestrant is 6-25 to the ratio of mineral element, and the rare earth element that is chelated is based on lanthanum, cerium, praseodymium, neodymium, and the ratio in the rare earth element is determined with natural form.
Sugar phosphoric ester 3-20
The sugar that forms phosphoric acid ester is made up of monose and/or simple sugars.Monose can be three to seven carbon sugar, and simple sugars can be sucrose, maltose.They can be obtained by starch and/or cellulose hydrolysis, monose to the simple sugars ratio from 0.1-10 than 1.Sugar and phosphoric acid or phosphoric acid salt esterification.
Amino acid mineral element inner complex and sugar phosphoric ester here are not simple mixtures, but a kind of mixture, they can physics mode and/or chemical mode (as coordination) compound, thereby help between them and the synergy between they and other nutrient substance.
Auxiliary: 0.1-12
Auxiliary is made up of simple organic nutrient, plant hormone and surface agent, and simple organic nutrient refers to acetate, citric acid, glycerine, humic acids etc.Plant hormone is Plant hormones regulators,gibberellins, indolylacetic acid, cytokinin.Tensio-active agent is benzene sulfonate, peregal, polyvinyl alcohol, class of department, tween, phosphatide, gelatin or their mixture.Simple organic nutrient accounts for 1-6% in the auxiliary, and plant hormone accounts for 0.0025 * 10
-3-2.5%, surface agent accounts for 0.03-4%, naphthenic acid, and VITAMIN, zymin can account for 0.1-2%.
Water 25-60
The consumption of water reaches 100 to guarantee total amount among the present invention.
The best of this compoiste fertilizer is formed (quality %): amino acid mineral element inner complex 15.0, total nitrogen 2.5, phosphorus 3.0, potassium 2.0, sugar phosphoric ester 10.0, auxiliary 3.0, water to 100.
The foliage fertilizer in past mainly is dissolved into liquid by nutrient and is provided, and is difficult to provide the nutrition form of the best, and the liquid product effective ingredient is few, and cost is also higher.The present invention has overcome these shortcomings, and reaction and homogeneous recombining process are provided.Preparation technology of the present invention comprises three main processes, at first is that proteolysis is an amino acid, and starch is hydrolyzed to sugar; Second step was chelating and esterification; The 3rd step was that homogeneous is compound, made the outstanding molten mixed body fertilizer of organic composite gum.
Protein is hydrolyzed to amino acid and simple peptide under the effect of acid or alkali.Protein can be animal proteinum such as hair, send out, hoof, first, blood, pupa, skin, low-quality fish etc.; Also can be vegetable-protein, as: Zein powder, dregs of beans, cottonseed meal, rapeseed meal or other vegetable seed protein white powder.Starch is hydrolyzed to sugar.Starch can derive from the seed of plant such as corn, jowar; Also can derive from the piece root, as potato, Ipomoea batatas, cassava etc.Hydrolyst is mineral acid or mineral alkali.Mineral acid example hydrochloric acid, sulfuric acid, phosphoric acid; Mineral alkali is a caustic alkali, as sodium hydroxide, potassium hydroxide.Promote the proton of hydrolysis, can also provide by inorganic and organic compound acid, for example compound acid of phosphoric acid and acetate, hydrolysis can also be carried out under metal ion participates in.Acid-hydrolyzed pH value 1-5, the PH of basic hydrolysis are at 8-12, and hydrolysis temperature is at 50-110 ℃, and the reaction times, acid or the alkali ratio in protein or starch was at 2-20% at 2-8 hour.
By amino acid and sugared mixture and the mineral element Ca that protein and starch hydrolysis obtain, Mg, Fe, Mn, Zn, B, Cu, Mo produces esterification or/and rare earth element etc. produce chelatropic reaction with phosphoric acid salt and/or phosphoric acid, forms amino-acid chelate, sugar phosphoric ester mixture.Chelating esterification and complex reaction temperature are at 20-80 ℃, PH3-10, time 30-200min, mineral element can be provided by multi-form, as vitriol, hydrochloride, nitrate, carbonate etc., in amino-acid chelate sugar phosphoric ester composite system, add N, P, K three major fertilizer, auxiliary and water, carry out homogenization treatment via clarifixator, and obtain the outstanding organic molten mixed compound fertilizer of attitude of glue.Clarifixator can be sand mill, ball mill, colloidal mill etc.The homogenizing treatment temp can 15-50 ℃, and the homogenizing time is at 10-160min, PH4-8.
Optimum process condition of the present invention is 105 ℃ of hydrolysis temperatures, PH2,6 hours reaction times; 75 ℃ of chelating esterification temperatures, PH7.5, time 100min; 25 ℃ of homogenization temperatures, time 20min, PH6.
The contained organic composite fertilizer of the present invention can be used as leaf fertilizer, root manure use, also can dress seed, for photosynthesis and plant growth provide the comprehensive nutrient element, have good synergy, easy to use, be beneficial to healthy growth, the root system development of crop, the effect of volume increase, joint fertilizer, water saving is remarkable.
Full root is extracted in the corn seed dressing test of for example doing in Shunyi behind the two weeks, bright root weight ratio control group increases by 50%, and dry weight improves 94%, after product 2% seed dressing of the present invention, and thousand mu of corn yield increasings 11%.Foliar spray twice, volume increase 20%.300 times of liquid of the present invention spray Beijing peach (early fragrant beautiful, greening) volume increase 26%, and pol improves 2 percentage points.The present invention all has good effect of increasing production, seed protein content percentage point can improve 1-2 to wheat, paddy rice, vegetables and economic fruit-bearing forest etc., can economize on water more than the fertile 5-10% of joint.
Embodiment 1:
Add entry 40kg in reactor, vitriol oil 1kg adds blood meal 6kg, be warming up to 100 ℃ under stirring, kept 2 hours, add tapioca (flour) 6kg, potassium primary phosphate 6kg kept 1 hour, was cooled to 50 ℃ then, add sal epsom 1kg, ferric sulfate 0.25kg, zinc sulfate 0.044kg, manganous sulfate 0.16kg, copper sulfate 0.039kg keeps 90min, add ammoniacal liquor and transfer PH, add urea 1.43kg then, Repone K 3.1kg to neutral, nitrocalcite 0.9kg, borax 0.09kg, Sodium orthomolybdate 0.00025kg stirs, add peregal 0.05kg at last, and add suitable quantity of water and make system's total amount reach 100kg, with sand mill homogeneous 1 hour, the colloidal suspension compound manure.
Embodiment 2:
On the basis of example 1, add rare earth oxide 0.15kg, obtain containing the compoiste fertilizer of chelating rare earth.
Embodiment 3:
On the basis of embodiment 1,, obtain being rich in the compound manure of amino-acid zinc with the zinc sulfate replacement 0.044kg wherein of 0.44kg.
Embodiment 4:
On the basis of example 3,, obtain being rich in the compoiste fertilizer of zinc and boron with the original 0.09kg of borax replacement of 0.4kg.
Embodiment 5:
On the basis of embodiment 1, add the 2kg Sodium salts humic acids, citric acid 500g just obtains containing the composite fertilizer of Sodium salts humic acids.
Embodiment 6:
On the basis of embodiment 1, when adding peregal, add Plant hormones regulators,gibberellins 0.0057g simultaneously and/or add cytokinin 0.0005g, obtain containing the composite fertilizer of plant growth hormones.
Embodiment 7:
In embodiment 1, replace sulfuric acid with Ke Xingjia 0.57kg, regulate PH to neutral with salt acid substitution ammoniacal liquor, adopt the ball mill homogeneous, other is with example 1.
Embodiment 8:
In embodiment 1, with rapeseed meal 10kg replacement blood meal wherein, other is with example 1.
Embodiment 9:
In embodiment 1, replace tapioca (flour) with W-Gum 5kg, other is with example 1.
Embodiment 10:
In embodiment 1, in homogenizing process, add nicotinic acid 0.040kg, obtain to contain the composite fertilizer of VITAMIN.
Embodiment 11:
In embodiment 10, add α-Dian Fenmei 0.060kg, obtain to contain the composite fertilizer of VITAMIN and enzyme.
Claims (5)
1, a kind of organic composite fertilizer, by amino acid mineral element inner complex, nitrogen phosphorus potassium, sugar, auxiliary are formed, and it is characterized in that contained sugar part changes into sugar phosphoric ester and mutually compound with amino acid mineral substance inner complex.(quality %) is as follows for its composition:
Amino acid mineral element inner complex: 3-25
Total nitrogen (N) 0.5-8
Phosphorus (P) 1-6
Potassium (K) 0.5-4
Sugar phosphoric ester 3-20
Auxiliary 0.1-12
Water 25-60.
2,, it is characterized in that best composition (quality %) is as follows according to the organic composite fertilizer of claim 1:
Amino acid mineral element inner complex 15.0
Total nitrogen (N) 2.5
Phosphorus (P) 3.0
Potassium (K) 2.0
Sugar phosphoric ester 10.0
Auxiliary 3.0
Water to 100.0
3,, it is characterized in that rare earth provides with the amino-acid chelate form according to the organic composite fertilizer of claim 1.
4, a kind of manufacturing process of organic composite fertilizer, its step comprises hydrolysis, chelating, esterification, compound, homogeneous, packing, it is characterized in that protein and/or sugar part amino acid and/or simple sugars and mineral substance formation chelating salt and/or ester through the hydrolysis generation, and form the outstanding molten mixed bodies of glue with the clarifixator homogeneous with nutrients such as nitrogen phosphorus potassium, auxiliary, homogenizing temperature is at 15-50 ℃, PH4-8, time 10-160min.
5,, it is characterized in that best processing condition is 25 ℃ of temperature, PH6, time 20min according to the manufacturing process of claim 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94103905 CN1110265A (en) | 1994-04-11 | 1994-04-11 | Organic compound fertilizer and its process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94103905 CN1110265A (en) | 1994-04-11 | 1994-04-11 | Organic compound fertilizer and its process |
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| Publication Number | Publication Date |
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| CN1110265A true CN1110265A (en) | 1995-10-18 |
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| CN 94103905 Pending CN1110265A (en) | 1994-04-11 | 1994-04-11 | Organic compound fertilizer and its process |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0880878A3 (en) * | 1997-05-31 | 1999-05-26 | Heiner Rogmann | Method for fertilising a lawn |
| CN100422120C (en) * | 2005-10-13 | 2008-10-01 | 黑龙江禾芙康农药制造有限公司 | A kind of formula of polypeptide liquid fertilizer and preparation method thereof |
| US7776124B2 (en) | 2005-10-14 | 2010-08-17 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| CN101948884A (en) * | 2010-09-17 | 2011-01-19 | 西南大学 | Method for producing biological oil by sweet potato full-matrix fermentation |
| CN101560119B (en) * | 2009-04-29 | 2013-06-12 | 大连三禾生物有限公司 | Production method of germanium-rich amino acid compound fertilizer |
| CN103936479A (en) * | 2014-03-07 | 2014-07-23 | 刘业成 | Special potato efficient fertilizer and preparation method thereof |
| CN107285919A (en) * | 2017-08-10 | 2017-10-24 | 糖化实业（上海）有限公司 | A kind of multi-functional water-soluble fertilizer and application |
| CN111533602A (en) * | 2020-04-24 | 2020-08-14 | 安徽汉合生物科技有限公司 | Special foliar fertilizer for selenium-rich biological rice |
-
1994
- 1994-04-11 CN CN 94103905 patent/CN1110265A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0880878A3 (en) * | 1997-05-31 | 1999-05-26 | Heiner Rogmann | Method for fertilising a lawn |
| US6074452A (en) * | 1997-05-31 | 2000-06-13 | Rogmann; Heiner | Method of fertilizing a lawn |
| CN100422120C (en) * | 2005-10-13 | 2008-10-01 | 黑龙江禾芙康农药制造有限公司 | A kind of formula of polypeptide liquid fertilizer and preparation method thereof |
| US7776124B2 (en) | 2005-10-14 | 2010-08-17 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| US7811352B2 (en) | 2005-10-14 | 2010-10-12 | Archer-Daniels-Midland Company | Fertilizer compositions and methods of using |
| CN101560119B (en) * | 2009-04-29 | 2013-06-12 | 大连三禾生物有限公司 | Production method of germanium-rich amino acid compound fertilizer |
| CN101948884A (en) * | 2010-09-17 | 2011-01-19 | 西南大学 | Method for producing biological oil by sweet potato full-matrix fermentation |
| CN103936479A (en) * | 2014-03-07 | 2014-07-23 | 刘业成 | Special potato efficient fertilizer and preparation method thereof |
| CN107285919A (en) * | 2017-08-10 | 2017-10-24 | 糖化实业（上海）有限公司 | A kind of multi-functional water-soluble fertilizer and application |
| CN111533602A (en) * | 2020-04-24 | 2020-08-14 | 安徽汉合生物科技有限公司 | Special foliar fertilizer for selenium-rich biological rice |
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