CN1109270A - Paretin cream - Google Patents
Paretin cream Download PDFInfo
- Publication number
- CN1109270A CN1109270A CN 94103655 CN94103655A CN1109270A CN 1109270 A CN1109270 A CN 1109270A CN 94103655 CN94103655 CN 94103655 CN 94103655 A CN94103655 A CN 94103655A CN 1109270 A CN1109270 A CN 1109270A
- Authority
- CN
- China
- Prior art keywords
- picrocetin
- emulsifiable concentrate
- angulatin
- emulsifier
- root bark
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006071 cream Substances 0.000 title 1
- 239000002917 insecticide Substances 0.000 claims abstract description 12
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- 239000003960 organic solvent Substances 0.000 claims abstract description 8
- 239000004495 emulsifiable concentrate Substances 0.000 claims abstract 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 11
- 239000000284 extract Substances 0.000 claims description 11
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 9
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N dimethyl sulfoxide Natural products CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 5
- 230000000149 penetrating effect Effects 0.000 claims 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims 2
- JYCQQPHGFMYQCF-UHFFFAOYSA-N 4-tert-Octylphenol monoethoxylate Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCO)C=C1 JYCQQPHGFMYQCF-UHFFFAOYSA-N 0.000 claims 1
- 241000227585 Alstonia constricta Species 0.000 claims 1
- IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical group [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 claims 1
- 229940011871 estrogen Drugs 0.000 claims 1
- 239000000262 estrogen Substances 0.000 claims 1
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 229920002113 octoxynol Polymers 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 229930192747 angulatin Natural products 0.000 abstract description 14
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 231100000419 toxicity Toxicity 0.000 abstract description 5
- 230000001988 toxicity Effects 0.000 abstract description 5
- 230000000749 insecticidal effect Effects 0.000 abstract description 4
- 241001465754 Metazoa Species 0.000 abstract description 3
- 238000003756 stirring Methods 0.000 abstract description 2
- 239000013543 active substance Substances 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 231100000518 lethal Toxicity 0.000 abstract 1
- 230000001665 lethal effect Effects 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 description 11
- 241000296609 Celastrus angulatus Species 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 241000125167 Rhopalosiphum padi Species 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 241000238631 Hexapoda Species 0.000 description 4
- 230000000740 bleeding effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- SIEZSHWOPJNWFA-UHFFFAOYSA-N 1??,2??,6??,8??,13-Pentaacetoxy-9??-benzoyloxy-4??-hydroxy-??-dihydroagarofuran Natural products CC(=O)OCC12C(OC(C)=O)C(OC(C)=O)CC(C)(O)C1(C1OC(C)=O)OC(C)(C)C1C(OC(C)=O)C2OC(=O)C1=CC=CC=C1 SIEZSHWOPJNWFA-UHFFFAOYSA-N 0.000 description 3
- 239000005946 Cypermethrin Substances 0.000 description 3
- 229930188654 celangulin Natural products 0.000 description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 3
- 229960005424 cypermethrin Drugs 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 231100000225 lethality Toxicity 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 241000255969 Pieris brassicae Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 244000144977 poultry Species 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241000255749 Coccinellidae Species 0.000 description 1
- 240000006927 Foeniculum vulgare Species 0.000 description 1
- 235000004204 Foeniculum vulgare Nutrition 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- WGKMWBIFNQLOKM-UHFFFAOYSA-N [O].[Cl] Chemical compound [O].[Cl] WGKMWBIFNQLOKM-UHFFFAOYSA-N 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 230000001887 anti-feedant effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229930101531 artemisinin Natural products 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- BLUAFEHZUWYNDE-XRNKLDBLSA-N chembl77 Chemical compound C([C@@](OO1)(C)O2)C[C@H]3[C@H](C)CC[C@@H]4C31[C@@H]2OC(=O)[C@@H]4C BLUAFEHZUWYNDE-XRNKLDBLSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000004434 industrial solvent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种天然植物质杀虫剂苦皮素乳油，其主要杀虫 成分苦皮素(Angulatin)是苦皮藤根皮中提出的活性物质，分子式为C34H46O13。苦皮素与乳化剂、渗透剂、有机溶剂在室温下按比例混合，搅拌至全溶即配制而成。该乳油配制方法简单，成本低，杀虫效果好，对天敌杀伤力明显较小，对温血动物毒性极低，生产安全，无三废，无污染，有利环境保护。A natural botanical insecticide Angulatin EC, the main insecticidal component Angulatin is the active substance extracted from the root bark of the vine, and its molecular formula is C 34 H 46 O 13 . It is prepared by mixing picrocetin with emulsifier, penetrant and organic solvent in proportion at room temperature, stirring until completely dissolved. The preparation method of the emulsifiable concentrate is simple, low in cost, good in insecticidal effect, obviously less lethal to natural enemies, extremely low in toxicity to warm-blooded animals, safe in production, free of three wastes and pollution, and beneficial to environmental protection.
Description
The invention belongs to a kind of high-efficiency low-toxicity, nuisance-free plant matter insecticide, particularly a kind of insecticide-emulsion oil of Angulatin of root bark of celastrus angulatus extraction of substance.
Modern age, being extensive use of of organic insecticide alleviated the harm of damage by disease and insect to crops widely, protected agricultural production.But along with a large amount of uses of agricultural chemicals, the increase of insect tolerance, natural enemy minimizing, environmental pollution, the ecological balance are destroyed, sometimes even cause the person poultry poisoning.Over past ten years, broad research is extracted bioactivator from natural products both at home and abroad, purifies through separating, and measures molecular structure, as the template of synthetic novel pesticide.As pyrethroid, clam worm poison derivative, margosine, fennel artemisin etc.Though above insecticide good disinsection effect, cost is higher, and the cultivation area is subject to certain restrictions.CN1081570A discloses a kind of Celastrus angulatus insecticidal anti-feedant.This insecticide extraction of substance consumption is big, and cost is higher relatively, and insecticidal effect is not best.
Purpose of the present invention just provides a kind of good disinsection effect, and obviously less to natural enemy lethality, extremely low to the person poultry toxicity, with low cost emulsion oil of Angulatin.
A kind of natural plants matter insecticide emulsion oil of Angulatin contains root bark of celastrus angulatus extract, emulsifier, bleeding agent, organic solvent, and its percentage composition is: root bark of celastrus angulatus extract 5-20, emulsifier 5-20, bleeding agent 5-15, organic solvent 60-85.
Root bark of celastrus angulatus extract among the present invention extracts with industrial solvent ethyl acetate, chloroform, benzene, toluene, and effective ingredient is Celangulin (Angulatin), and molecular formula is C
34H
46O
13Celangulin has very strong food refusal, repellent, stomach toxicity, anesthesia and bactericidal action, and is extremely low to warm blooded animal toxicity.
The said emulsifier of the present invention is the alkylphenol polyoxyethylene non-ionic surface active agent, has performance acidproof, anti-hard water, has solubilization concurrently.The best is Zhong Xin phenol polyethenoxy ether or OPEO.
The said bleeding agent of the present invention is dimethyl sulfoxide (DMSO) or dimethyl formamide, and it has very strong penetration power to the shell of insect.
Organic solvent of the present invention can be chosen industrial crude benzol wantonly, and wherein aromatic hydrocarbon is effective insecticidal agent, bactericide.Select toluene or dimethylbenzene for use.
Manufacture method of the present invention is as follows:
1, gets the raw material root bark of celastrus angulatus, clean, dry, pulverize, add ethyl acetate or chloroform or benzene and extract the Celangulin active principle.
2, root bark of celastrus angulatus extract, emulsifier, bleeding agent and organic solvent at room temperature mixed in proportion, stir to molten entirely.
The present invention has the following advantages: (1) Main Ingredients and Appearance is the high Celangulin of biologically active, good disinsection effect.Wheat aphid, vegetable aphid, cabbage caterpillar control efficiency are respectively: 86-95%, 80.4-87.9%, 90.5-95.1%; (2) drug resource is abundant, and production technology is simple, and cost is low; (3) strong to insect poisoning power, but extremely low to warm blooded animal toxicity, obviously less to natural enemy lethality, the favourable protection ecological balance; (4) production safety, the no three wastes, pollution-free, favorable environment protection.
Embodiment 1, the emulsion oil of Angulatin percentage composition:
Root bark of celastrus angulatus extract 8, Zhong Xin phenol polyethenoxy ether 10, dimethyl sulfoxide (DMSO) 3, toluene 79%.
Above-mentioned substance is mixed in proportion, at room temperature be stirred to molten entirely, emulsion oil of Angulatin.
1, get the emulsion oil of Angulatin for preparing, dilute 1000,2000,3000 times,
2, commercially available 40% flolimat, 10% cypermethrin dilutes 2000 times respectively, and clear water is contrast.
3, pest control: wheat aphid
4, dispenser is after 48 hours, and 3000 times of preventive effects of emulsion oil of Angulatin are 89.84%, 2000 times, and to be 94.41%, 1000 times be 94.74%; 40% flolimat is 98.88% for 2000 times; 10% cypermethrin is 98.91% for 2000 times.
Influence to natural enemy: after the dispenser the 4th, 6,8 day, observe accumulated result: spider, ladybug etc., emulsion oil of Angulatin is respectively 11 for 3000,2000,1000 times, and 6,19; 2000 times 3 of 40% flolimats; 10% chlorine oxygen chrysanthemum ester is 4; The clear water contrast is 20.
Evidence:
1, emulsion oil of Angulatin is remarkable to the wheat aphid control efficiency, and especially 1000 times control efficiency approaches 40% flolimat and 10% cypermethrin, and residual few, low toxicity.
2, obviously less to the lethality of natural enemy.
Embodiment 2, the percentage composition of emulsion oil of Angulatin:
Root bark of celastrus angulatus extract 10, OPEO 10, dimethyl formamide 3, dimethylbenzene 77.
Manufacture method is prevented and treated the wheat aphid test of pesticide effectiveness with embodiment 1, and mu formulation rate 50g dilutes 2000 times, is 95% to the wheat aphid preventive effect.Test also shows: to vegetable aphid control efficiency 80.4-87.9%; To cabbage caterpillar control efficiency 90.5-95.1%.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94103655A CN1047503C (en) | 1994-03-30 | 1994-03-30 | Emulsion oil of angulatin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94103655A CN1047503C (en) | 1994-03-30 | 1994-03-30 | Emulsion oil of angulatin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1109270A true CN1109270A (en) | 1995-10-04 |
| CN1047503C CN1047503C (en) | 1999-12-22 |
Family
ID=5031191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94103655A Expired - Fee Related CN1047503C (en) | 1994-03-30 | 1994-03-30 | Emulsion oil of angulatin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1047503C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086111C (en) * | 1999-06-25 | 2002-06-12 | 西北农业大学 | Two kinds of celastrus angulatus water base insecticidal preparation |
| CN100384333C (en) * | 2002-02-05 | 2008-04-30 | 西北农林科技大学农药研究所 | Plant pesticide composition for preventing and treating diseases and pests of tea tree |
| CN103109810A (en) * | 2011-11-16 | 2013-05-22 | 中国科学院海洋研究所 | Rotifer killing medicine, and preparation method and application thereof |
| CN103461354B (en) * | 2013-09-15 | 2016-07-06 | 上海悦萌环保科技有限公司 | Celastrus angulatus vegetable source pesticide cream |
| CN108576070A (en) * | 2018-03-02 | 2018-09-28 | 金华市胤宏农业科技有限公司 | The special pest and disease damage preparation of day lily |
| CN112125731A (en) * | 2020-09-10 | 2020-12-25 | 河南省科学院 | Plant-source multifunctional liquid pesticide fertilizer and preparation method thereof |
-
1994
- 1994-03-30 CN CN94103655A patent/CN1047503C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086111C (en) * | 1999-06-25 | 2002-06-12 | 西北农业大学 | Two kinds of celastrus angulatus water base insecticidal preparation |
| CN100384333C (en) * | 2002-02-05 | 2008-04-30 | 西北农林科技大学农药研究所 | Plant pesticide composition for preventing and treating diseases and pests of tea tree |
| CN103109810A (en) * | 2011-11-16 | 2013-05-22 | 中国科学院海洋研究所 | Rotifer killing medicine, and preparation method and application thereof |
| CN103109810B (en) * | 2011-11-16 | 2014-08-06 | 中国科学院海洋研究所 | Rotifer killing medicine, and preparation method and application thereof |
| CN103461354B (en) * | 2013-09-15 | 2016-07-06 | 上海悦萌环保科技有限公司 | Celastrus angulatus vegetable source pesticide cream |
| CN108576070A (en) * | 2018-03-02 | 2018-09-28 | 金华市胤宏农业科技有限公司 | The special pest and disease damage preparation of day lily |
| CN112125731A (en) * | 2020-09-10 | 2020-12-25 | 河南省科学院 | Plant-source multifunctional liquid pesticide fertilizer and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1047503C (en) | 1999-12-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 19991222 |