CN1174658A - A kind of compound broad-spectrum bactericidal pesticide - Google Patents
A kind of compound broad-spectrum bactericidal pesticide Download PDFInfo
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- CN1174658A CN1174658A CN 96111880 CN96111880A CN1174658A CN 1174658 A CN1174658 A CN 1174658A CN 96111880 CN96111880 CN 96111880 CN 96111880 A CN96111880 A CN 96111880A CN 1174658 A CN1174658 A CN 1174658A
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Abstract
The present invention belongs to the field of chemical technology, and is characterized by that it mainly contains a certain quantity of ethylicin, contains a certain quantity of at least one of organic phosphorus fungicide, organic sulfur fungicide, substituted benzene fungicide, heterocyclic fungicide and antibiotic fungicide, and is compounded into binary, ternary and quaternary … … multielement compound broad-spectrum bactericidal pesticide, and can be extensively used for foliage spraying, seed treatment and root-irrigating application of grain crops, economic crops, forest and fruit flowers, vegetables and melons, etc. so that it can effectively prevent and cure various diseases due to fungi, bacteria and virus.
Description
The invention belongs to technical field of chemistry, is a kind of compound broad spectrum pesticide new product and compound method thereof.
Existing sterilization pesticide, as " S-Ethyl ethylthio sulfonate antibacterial agent ", its effective content (percentage by weight) is more than 40-80%, it is big to exist corrosivity, seriously polluted, to dispenser personnel's health, the seed of plant or plant there are damage and can only be used for seed and shortcoming that main earth is handled, though S-Ethyl ethylthio sulfonate antibacterial agent fungicidal spectrum is extensive, but still exist shortcoming to the disease-controlling effect differences such as higher powdery mildew, rust, Leucoplakia, virus disease of falling ill.Other bactericide agricultural chemicals is as organic phosphorus type disinfectant: kitazine, Ppyrazophos etc.; As organic sulfurcontaining fungicide: captan, folpet etc.; As substituted beneze-group fungicides: thiophanate-methyl, metalaxyl, Wakil, Seedvax etc.; As heterocyclic nitrogen-group fungicide: triazolone, propiconazole, Isoprothiolane, triforine etc.; As antibiotics bactericide (containing medical): blasticidin-S, chloramphenicol etc., exist or fungicidal spectrum single, or easily develop immunity to drugs, or healing of focus waits shortcoming slowly.In a word, existing sterilization pesticide owing to exist above-mentioned major defect, is therefore applied all undesirablely in agricultural production, and agricultural plant protection presses for a kind of disinfecting agricultural chemicals.
Purpose of the present invention is intended to overcome the shortcoming that existing sterilization pesticide exists, be adapted to pressing for of present agricultural production, provide a kind of fungicidal spectrum that makes more extensive, corrosivity, damaging small or non-corrosiveness, pollution abatement, healing of focus is accelerated, delayed novel compound broad spectrum pesticide and compound method thereof that pesticide resistance and cost reduce.
The technical scheme that the present invention takes is, main adopt a certain amount of S-Ethyl ethylthio sulfonate antibacterial agent add a certain amount of at least a have several Phosphorus bactericide or and the organic sulfur series bactericidal agent or and substituted beneze-group fungicides or and heterocyclic nitrogen-group fungicide or and antibiotics bactericide (containing medical), be aided with an amount of relevant auxiliary agent or the composition of auxiliary agent and filler, the composite binary that forms or ternary or quaternary ... or polynary a kind of compound broad spectrum pesticide.
The compound method of a kind of compound broad spectrum pesticide of the present invention, the effective content of S-Ethyl ethylthio sulfonate antibacterial agent are 2-95% by weight percentage; The organic phosphorus type disinfectant effective content is 3-70% by weight; Organic sulfur series bactericidal agent effective content is 1-70% by weight; The substituted beneze-group fungicides effective content is 0.5-60% by weight; The heterocyclic nitrogen-group fungicide effective content is 1-65% by weight; Antibiotics bactericide (containing medical) is by weight being 0.1-30%, and the composition of auxiliary agent or auxiliary agent and filler is an amount of, through mixing the composite possible corresponding formulation that forms.
The present invention adds organic phosphorus type disinfectant in the S-Ethyl ethylthio sulfonate composition after, because the S-Ethyl ethylthio sulfonate antibacterial agent is difficult for producing resistance, the most of kinds of organic phosphorus type disinfectant have the control leafhopper, the effect of plant hopper, the viral disease and leafhopper etc. can spread disease, so not only delayed the pesticide resistance of organic phosphorus type disinfectant, and fungicidal spectrum has increased the merit spectrum of preventing and treating virus disease on the basis of S-Ethyl ethylthio sulfonate fungicidal spectrum wide spectrum, as composite by a certain percentage with kitazine and S-Ethyl ethylthio sulfonate, be applied to prevent and treat rice disease, effect is higher than single agent, reach more than 95%, synergy is obvious, and can prevent infecting of virus disease.Organic sulfur series bactericidal agent pathogen is difficult for developing immunity to drugs to it, and the effect that stimulates plant growth is arranged under the low concentration, with S-Ethyl ethylthio sulfonate composite after, overcome the development of resistance basically.After substituted beneze-group fungicides and S-Ethyl ethylthio sulfonate are composite, not only overcome and delayed pesticide resistance, enlarged fungicidal spectrum, and, reduced cost, still can meet or exceed the control efficiency of single agent owing to reduced the effective dose of substituted beneze-group fungicides.The most kinds of heterocyclic nitrogen-group fungicide are more outstanding to powdery mildew, Leucoplakia, rust control efficiency, and be difficult for producing resistance, but to the downy mildew weak effect, after being mixed, fungicidal spectrum can enlarge on the basis of S-Ethyl ethylthio sulfonate fungicidal spectrum, and pesticide resistance is almost disappeared, as after allocating triforine into, be applied to foliage-spray in concurrent, the mixed field of vegetables of sending out of Leucoplakia and downy mildew, control efficiency is brought up to more than 90%, and does not develop immunity to drugs.The antibiotics bactericide has seriously produced pesticide resistance, price is also expensive, not only overcome after being mixed and delayed pesticide resistance, reduced cost, and because some antibiosis have the effect that prevents and treats virus disease, thereby strengthened the effect of preventing and treating virus disease, promoted the growth of crop greatly, as after allocating medical chloramphenicol into, also S-Ethyl ethylthio sulfonate there is very strong synergistic effect etc.In a word, compound broad spectrum pesticide of the present invention is compared with existing sterilization pesticide, has following tangible advantage:
1. application point increases, and fungicidal spectrum enlarges.
2. synergistic effect is remarkable, stimulates plant growth.
3. toxicity reduces, and poisoning alleviates, healing of focus fast (advanceing to 1-3 days) by 5-7 days, and the lasting period prolongs.
4. pesticide resistance is delayed and is overcome.
5. dispenser is convenient, and formulation is flexible, is applicable to that foliage-spray, seed dressing, the filling root of possible various formulations (as missible oil, liquor etc.) all can.
6. reduce cost pollution abatement.
7. make existing bactericide obtain new vitality, produce conveniently, can make the very fast listing of new drug, to satisfy the urgent need in current agricultural plant protection field.
Compound broad spectrum pesticide of the present invention, good stability, penetration is strong, toxicity is at low middling, and is safe in utilization, generally can not produce poisoning, the people there are not pathogenic, carcinogenic, mutagenesis, stable in acid medium, meet metal or the easy decomposition failures of alkaline matter such as iron aluminium.
Compound broad spectrum pesticide of the present invention can be widely used in various crops such as cotton, vegetables, wheat, fruit tree, paddy rice, tobacco, soybean, corn, sweet potato, sesame, peanut, flowers, sugarcane.Can effectively prevent and treat cotton wilt, verticillium wilt, damping off, anthracnose, cotton boll blight; Vegetables, downy mildew of cucurbits, fusarium wilt, angular leaf spot; Fruit tree anthracnose, rot; Wheat scab, powdery mildew, rust, bunt; Rice blast, bakanae disease, seedling rot, banded sclerotial blight, bacterial leaf-blight; Soybean yellow disease; Tobacco sesame shin rot; The corn northern leaf blight, bacterial wilt; Sweet potato black rot; The peanut root rot; The sugarcane root rot; Multiple common disease and difficult disease such as floral crops diseases and jowar anthracnose, the millet downy mildew, ginger bacterial wilt of ginger all have the fancy effect of rapid healing.
The compound method of compound broad spectrum pesticide of the present invention:
(binary built):
One of example formulations S-Ethyl ethylthio sulfonate antibacterial agent (effective content is weight percentage, and is as follows) 95%, organic phosphorus type disinfectant (kitazine or and Ppyrazophos) 3%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Two S-Ethyl ethylthio sulfonate antibacterial agents 2% of example formulations, organic phosphorus type disinfectant (kitazine or and Ppyrazophos) 70%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Three S-Ethyl ethylthio sulfonate antibacterial agents 65% of example formulations, organic sulfur series bactericidal agent (captan or and folpet) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
The tetrem allicin antibacterial agent 20% of example formulations, organic sulfur series bactericidal agent (captan or and folpet) 40%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Five S-Ethyl ethylthio sulfonate antibacterial agents 40% of example formulations, substituted beneze-group fungicides (thiophanate-methyl or and metalaxyl or and Wakil or and Seedvax) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Six S-Ethyl ethylthio sulfonate antibacterial agents 20% of example formulations, substituted beneze-group fungicides (thiophanate-methyl or and metalaxyl or and Wakil or and Seedvax) 30%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Seven S-Ethyl ethylthio sulfonate antibacterial agents 50% of example formulations, heterocyclic nitrogen-group fungicide (triazolone or and propiconazole or and Isoprothiolane or and triforine) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Eight S-Ethyl ethylthio sulfonate antibacterial agents 20% of example formulations, heterocyclic nitrogen-group fungicide (triazolone or and propiconazole or and Isoprothiolane or and triforine) 40%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Nine S-Ethyl ethylthio sulfonate antibacterial agents 40% of example formulations, antibiotics bactericide (blasticidin-S or medical chloramphenicol) 1%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Ten S-Ethyl ethylthio sulfonate antibacterial agents 10% of example formulations, antibiotics bactericide (blasticidin-S or medical chloramphenicol) 5%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
(ternary built):
11 S-Ethyl ethylthio sulfonate antibacterial agents 10% of example formulations, organic phosphorus type disinfectant (ditto) 30%, organic sulfur series bactericidal agent (ditto) 30%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
12 S-Ethyl ethylthio sulfonate antibacterial agents 40% of example formulations, organic phosphorus type disinfectant (ditto) 10%, organic sulfur series bactericidal agent (ditto) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
13 S-Ethyl ethylthio sulfonate antibacterial agents 20% of example formulations, organic phosphorus type disinfectant (ditto) 30%, substituted beneze-group fungicides (ditto) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Ten tetrem allicin antibacterial agents 20% of example formulations, organic phosphorus type disinfectant (ditto) 10%, heterocyclic nitrogen-group fungicide (ditto) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
15 S-Ethyl ethylthio sulfonate antibacterial agents 40% of example formulations, organic phosphorus type disinfectant (ditto) 10%, antibiotics bactericide (ditto) 1%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
16 S-Ethyl ethylthio sulfonate antibacterial agents 20% of example formulations, organic sulfur series bactericidal agent (ditto) 10%, substituted beneze-group fungicides (ditto) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
17 S-Ethyl ethylthio sulfonate antibacterial agents 40% of example formulations, substituted beneze-group fungicides (ditto) 10%, heterocyclic nitrogen-group fungicide (ditto) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
18 S-Ethyl ethylthio sulfonate antibacterial agents 30% of example formulations, heterocyclic nitrogen-group fungicide (ditto) 10%, antibiotics bactericide (ditto) 2%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
(quaternary built):
19 S-Ethyl ethylthio sulfonate antibacterial agents 10% of example formulations, organic phosphorus type disinfectant (ditto) 10%, organic sulfur series bactericidal agent (ditto) 5%, substituted beneze-group fungicides (ditto) 5%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
20 S-Ethyl ethylthio sulfonate antibacterial agents 20% of example formulations, organic phosphorus type disinfectant (ditto) 5%, organic sulfur series bactericidal agent (ditto) 5%, heterocyclic nitrogen-group fungicide (ditto) 10%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
21 S-Ethyl ethylthio sulfonate antibacterial agents 20% of example formulations, organic phosphorus type disinfectant (ditto) 15%, organic sulfur series bactericidal agent (ditto) 10%, antibiotics bactericide (ditto) 1%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
22 S-Ethyl ethylthio sulfonate antibacterial agents 25% of example formulations, organic sulfur series bactericidal agent (ditto) 5%, heterocyclic nitrogen-group fungicide (ditto) 10%, antibiotics bactericide (ditto) 1%, surplus is the composition of auxiliary agent or auxiliary agent and filler.
Claims (2)
1, a kind of compound broad spectrum pesticide, it is characterized in that mainly containing a certain amount of S-Ethyl ethylthio sulfonate, contain a certain amount of at least a organic phosphorus type disinfectant or/and the organic sulfur series bactericidal agent or/and substituted beneze-group fungicides or/and heterocyclic nitrogen-group fungicide or/and the antibiotics bactericide, and an amount of relevant auxiliary agent or the composition of auxiliary agent and filler, composite binary that forms or ternary, quaternary ... polynary compound sterilization pesticide.
2, compound broad spectrum pesticide as claimed in claim 1, it is characterized in that described compound method constituent content is by the effective content weight ratio, S-Ethyl ethylthio sulfonate is 2-95%, organic phosphorus type disinfectant is 3-70%, the organic sulfur series bactericidal agent is 1-70%, and substituted beneze-group fungicides are 0.5-60%, and heterocyclic nitrogen-group fungicide is 1-65%, the antibiotics bactericide is 0.1-30%, and the composition of auxiliary agent or auxiliary agent and filler is an amount of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96111880A CN1080995C (en) | 1996-08-27 | 1996-08-27 | A kind of agricultural fungicide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96111880A CN1080995C (en) | 1996-08-27 | 1996-08-27 | A kind of agricultural fungicide composition |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01144624 Division CN1393136A (en) | 2001-12-21 | 2001-12-21 | Agricultural disinfecting composition containing organic phosphorus type disinfectant |
| CNB011446250A Division CN1178578C (en) | 2001-12-21 | 2001-12-21 | Agricultural bactericide composition containing substituted benzene bactericide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1174658A true CN1174658A (en) | 1998-03-04 |
| CN1080995C CN1080995C (en) | 2002-03-20 |
Family
ID=5121287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96111880A Expired - Fee Related CN1080995C (en) | 1996-08-27 | 1996-08-27 | A kind of agricultural fungicide composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1080995C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102726415A (en) * | 2012-06-19 | 2012-10-17 | 河南省大地农化有限责任公司 | Allicin-containing prevention and treatment pesticide for crop plant diseases |
| CN103141484A (en) * | 2013-03-20 | 2013-06-12 | 海南正业中农高科股份有限公司 | Bactericidal composition containing penthiopyrad |
| CN104145961A (en) * | 2014-08-13 | 2014-11-19 | 海南正业中农高科股份有限公司 | Composition comprising ethylicin and dithianon |
| CN105961417A (en) * | 2016-05-06 | 2016-09-28 | 山东东信生物农药有限公司 | Composition with sterilizing and plant growth regulating functions as well as manufacturing method thereof |
| WO2018086633A1 (en) * | 2016-11-11 | 2018-05-17 | 江苏辉丰生物农业股份有限公司 | Bactericide composition including benzisothiazolinone and ethylicin |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100518507C (en) * | 2006-12-08 | 2009-07-29 | 罗山峰 | Composition containing organic ether polysulfide and its application |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1060310C (en) * | 1994-12-04 | 2001-01-10 | 张长兴 | Specific pesticide for control of plant diseases |
-
1996
- 1996-08-27 CN CN96111880A patent/CN1080995C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102726415A (en) * | 2012-06-19 | 2012-10-17 | 河南省大地农化有限责任公司 | Allicin-containing prevention and treatment pesticide for crop plant diseases |
| CN103141484A (en) * | 2013-03-20 | 2013-06-12 | 海南正业中农高科股份有限公司 | Bactericidal composition containing penthiopyrad |
| CN103141484B (en) * | 2013-03-20 | 2014-07-09 | 海南正业中农高科股份有限公司 | Bactericidal composition containing penthiopyrad |
| CN104145961A (en) * | 2014-08-13 | 2014-11-19 | 海南正业中农高科股份有限公司 | Composition comprising ethylicin and dithianon |
| CN104145961B (en) * | 2014-08-13 | 2016-05-11 | 海南正业中农高科股份有限公司 | Containing the composition of S-Ethyl ethylthio sulfonate and dithianon |
| CN105961417A (en) * | 2016-05-06 | 2016-09-28 | 山东东信生物农药有限公司 | Composition with sterilizing and plant growth regulating functions as well as manufacturing method thereof |
| WO2018086633A1 (en) * | 2016-11-11 | 2018-05-17 | 江苏辉丰生物农业股份有限公司 | Bactericide composition including benzisothiazolinone and ethylicin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1080995C (en) | 2002-03-20 |
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: ZHENGZHOU MODERN CHEMICAL INDUSTRY Co.,Ltd. Assignor: Zhang Changxing Contract fulfillment period: In December 31, 2004, 2 years Contract record no.: 200210041 Denomination of invention: Agricultural bactericidal composition Granted publication date: 20020320 License type: Common License Record date: 20020531 |
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| LIC | Patent licence contract for exploitation submitted for record |
Free format text: LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2004.12.31, 2 YEARS Name of requester: ZHENG ZHOU XIANDAI CHEMICAL CO., LTD. Effective date: 20020531 |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20020320 Termination date: 20100827 |