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CN115547803A - Atomic layer etching reaction device and etching method - Google Patents

Atomic layer etching reaction device and etching method Download PDF

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Publication number
CN115547803A
CN115547803A CN202211208673.7A CN202211208673A CN115547803A CN 115547803 A CN115547803 A CN 115547803A CN 202211208673 A CN202211208673 A CN 202211208673A CN 115547803 A CN115547803 A CN 115547803A
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atomic layer
substrate
platform assembly
vacuum mechanism
layer etching
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刘磊
唐继远
张洪国
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Jiangsu Pengju Semiconductor Equipment Technology Co ltd
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Jiangsu Pengju Semiconductor Equipment Technology Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32715Workpiece holder
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32009Arrangements for generation of plasma specially adapted for examination or treatment of objects, e.g. plasma sources
    • H01J37/32082Radio frequency generated discharge
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32733Means for moving the material to be treated
    • H10P50/242
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J2237/00Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
    • H01J2237/32Processing objects by plasma generation
    • H01J2237/33Processing objects by plasma generation characterised by the type of processing
    • H01J2237/334Etching

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

The embodiment of the invention discloses an atomic layer etching reaction device, wherein the atomic layer etching reaction device comprises: the vacuum mechanism provides a place for the atomic layer etching reaction; the ion source is communicated with the vacuum mechanism and is used for generating an ion field in the vacuum mechanism to form certain ion beam flow distribution; the platform assembly is arranged in the vacuum mechanism and is used for bearing the substrate; wherein, under the drive of the platform assembly, the substrate is etched according to the preset pattern by changing the position according to the preset path in the ion field. According to the invention, the energy of ions or neutral particles on the surface of the substrate can be accurately regulated and controlled, and the atomic layer etching of the substrate can be realized. The invention also discloses an etching method.

Description

原子层刻蚀反应装置及刻蚀方法Atomic layer etching reaction device and etching method

技术领域technical field

本发明涉及原子层刻蚀技术领域,特别涉及一种原子层刻蚀反应装置及刻蚀方法。The invention relates to the technical field of atomic layer etching, in particular to an atomic layer etching reaction device and an etching method.

背景技术Background technique

原子层刻蚀(ALE)是一种能够精密控制被去除的材料量的先进技术。实现这一技术的一大关键在于将刻蚀工艺分为两个步骤:改性(步骤A)和去除(步骤B)。第一步(步骤A)对表面层进行改性处理,使其在第二步(步骤B)中能够被轻易去除。每次循环只去除薄薄一层材料,可重复循环直至达到期望的深度。Atomic Layer Etching (ALE) is an advanced technique that enables precise control of the amount of material removed. One of the keys to realizing this technology is to divide the etching process into two steps: modification (step A) and removal (step B). The first step (step A) modifies the surface layer so that it can be easily removed in the second step (step B). Only a thin layer of material is removed with each cycle, and cycles can be repeated until the desired depth is achieved.

对于原子层刻蚀反应,需要对衬底表面的离子束或中性粒子束能量进行精准调控。现有常规的能量调控方式通常是对离子发生器本身进行调节(如调节功率、气压等),但上述方式会受到离子束或中性粒子束发生装置与衬底距离固定的局限。因此,如何对运动到衬底表面的离子束或中性粒子束的能量分布要求可以实现精准调控成为亟待解决的问题。For the atomic layer etching reaction, it is necessary to precisely control the energy of the ion beam or neutral particle beam on the substrate surface. The existing conventional energy control method is usually to adjust the ion generator itself (such as adjusting power, air pressure, etc.), but the above-mentioned method will be limited by the fixed distance between the ion beam or neutral particle beam generating device and the substrate. Therefore, how to accurately control the energy distribution requirements of the ion beam or neutral particle beam moving to the substrate surface has become an urgent problem to be solved.

发明内容Contents of the invention

本发明的实施例提供一种原子层刻蚀反应装置及刻蚀方法,精准调控基片表面离子或中性粒子的能量,实现基片的原子层刻蚀。Embodiments of the present invention provide an atomic layer etching reaction device and an etching method, which can accurately control the energy of ions or neutral particles on the surface of a substrate, and realize atomic layer etching of the substrate.

为了解决上述技术问题,本发明的实施例公开了如下技术方案:In order to solve the above technical problems, the embodiments of the present invention disclose the following technical solutions:

一方面,提供了一种原子层刻蚀反应装置,包括:真空机构,所述真空机构为原子层刻蚀反应提供场所;In one aspect, an atomic layer etching reaction device is provided, including: a vacuum mechanism that provides a place for the atomic layer etching reaction;

离子源,与所述真空机构相连通,所述离子源用于在真空机构内部产生离子场;an ion source, communicated with the vacuum mechanism, and the ion source is used to generate an ion field inside the vacuum mechanism;

平台总成,所述平台总成位于真空机构内部并用于承载基片;a platform assembly, the platform assembly is located inside the vacuum mechanism and is used to carry the substrate;

其中,在所述平台总成的带动下,所述基片能在离子场中按照预设路径变换位置以按预设图案被刻蚀。Wherein, driven by the platform assembly, the substrate can change its position in the ion field according to a preset path so as to be etched according to a preset pattern.

除了上述公开的一个或多个特征之外,或者作为替代,所述平台总成包括多轴并联臂平台总成、基片托盘和挡板,所述多轴并联臂平台总成设置在真空机构内部,所述多轴并联臂平台总成与基片托盘传动连接,所述基片托盘用于承载基片,所述挡板罩设在多轴并联臂平台总成上。In addition to one or more features disclosed above, or as an alternative, the platform assembly includes a multi-axis parallel arm platform assembly, a substrate tray and a baffle, and the multi-axis parallel arm platform assembly is arranged on the vacuum mechanism Inside, the multi-axis parallel arm platform assembly is in transmission connection with the substrate tray, the substrate tray is used to carry the substrate, and the baffle cover is arranged on the multi-axis parallel arm platform assembly.

除了上述公开的一个或多个特征之外,或者作为替代,所述多轴并联臂平台总成为六轴并联臂平台总成。In addition to one or more features disclosed above, or as an alternative, the multi-axis parallel arm platform assembly is a six-axis parallel arm platform assembly.

除了上述公开的一个或多个特征之外,或者作为替代,所述多轴并联臂平台总成包括底座、运动平台和若干个直线驱动装置,所述底座设置在真空机构内部,所述运动平台与基片托盘连接,每个所述直线驱动装置的两端分别与底座、运动平台多方位转动连接;In addition to one or more features disclosed above, or as an alternative, the multi-axis parallel arm platform assembly includes a base, a moving platform and several linear drive devices, the base is arranged inside the vacuum mechanism, and the moving platform Connected to the substrate tray, the two ends of each linear drive device are respectively connected to the base and the motion platform in multi-directional rotation;

所述挡板包括上挡板和下挡板,所述上挡板和下挡板罩设在底座和运动平台之间。The baffle includes an upper baffle and a lower baffle, and the upper baffle and the lower baffle cover are arranged between the base and the moving platform.

除了上述公开的一个或多个特征之外,或者作为替代,若干个所述直线驱动装置两两为一组,且每组的两个所述直线驱动装置一端均通过第一传动装置转动设置在底座的同一个边角处,每组的两个所述直线驱动装置另一端均通过第二传动装置转动设置在运动平台上的三角座的两个相邻的顶角处。In addition to one or more features disclosed above, or as an alternative, several linear drive devices are in groups of two, and one end of the two linear drive devices in each group is rotated and arranged on the first transmission device. At the same corner of the base, the other ends of the two linear drive devices in each group are rotated through the second transmission device at two adjacent top corners of the triangular seat on the motion platform.

除了上述公开的一个或多个特征之外,或者作为替代,所述第一传动装置和第二传动装置均包括双轴铰链。In addition to, or as an alternative to, one or more of the features disclosed above, the first transmission and the second transmission each comprise a biaxial hinge.

除了上述公开的一个或多个特征之外,或者作为替代,当所述运动平台处于初始水平状态时,每个所述直线驱动装置均处于倾斜状态。In addition to, or as an alternative to, one or more of the features disclosed above, each of the linear drives is in an inclined state when the motion platform is in an initially horizontal state.

除了上述公开的一个或多个特征之外,或者作为替代,所述真空机构内部壁上设置有防腐蚀材料。In addition to, or as an alternative to, one or more of the features disclosed above, an anti-corrosion material is provided on the inner wall of the vacuum mechanism.

除了上述公开的一个或多个特征之外,或者作为替代,所述离子源为电感耦合离子源、电容耦合离子源、射频离子源、霍尔离子源及考夫曼离子源中的至少一种。In addition to one or more features disclosed above, or as an alternative, the ion source is at least one of an inductively coupled ion source, a capacitively coupled ion source, a radio frequency ion source, a Hall ion source and a Kaufman ion source .

另一方面,进一步公开了一种刻蚀方法,利用如上述任一项原子层刻蚀反应装置,包括以下步骤:S100、向所述真空机构内部通入刻蚀气体,并开启所述离子源,激发刻蚀气体在所述真空机构内部形成离子场,并开启所述平台总成,所述平台总成带动所述基片在所述离子场中按照预设路径变换位置以致所述基片按预设图案被刻蚀。On the other hand, an etching method is further disclosed, using any one of the above-mentioned atomic layer etching reaction devices, including the following steps: S100, feeding an etching gas into the vacuum mechanism, and turning on the ion source , excite the etching gas to form an ion field inside the vacuum mechanism, and turn on the platform assembly, and the platform assembly drives the substrate to change its position in the ion field according to a preset path so that the substrate etched in a preset pattern.

上述技术方案中的原子层刻蚀反应装置具有如下优点或有益效果:本技术方案的多轴并联臂平台总成与基片托盘连接并能带动基片托盘做平移、旋转或倾斜运动,使基片托盘动起来,不必再拘泥于现有技术中的离子束或中性粒子束发生装置与衬底距离固定的局限,进而根据离子场的能量分布区域,并结合基片所需要精准调控的能量范畴,基片托盘能自如地在不同时刻出现在离子场不同位置,实现基片择优选择适宜的离子束能量分布区域,进而实现对基片精准地原子层刻蚀。The atomic layer etching reaction device in the above technical solution has the following advantages or beneficial effects: the multi-axis parallel arm platform assembly of the technical solution is connected to the substrate tray and can drive the substrate tray to perform translational, rotational or tilting movements, so that the substrate It is no longer necessary to stick to the limitation of the fixed distance between the ion beam or neutral particle beam generating device and the substrate in the prior art, and then according to the energy distribution area of the ion field and combined with the energy that needs to be precisely regulated by the substrate In this category, the substrate tray can freely appear in different positions of the ion field at different times, so as to realize the optimal selection of the appropriate ion beam energy distribution area for the substrate, and then realize the precise atomic layer etching of the substrate.

附图说明Description of drawings

下面结合附图,通过对本发明的具体实施方式详细描述,将使本发明的技术方案及其它有益效果显而易见。The technical solutions and other beneficial effects of the present invention will be apparent through the detailed description of specific embodiments of the present invention in conjunction with the accompanying drawings.

图1是根据本发明实施例提供的现有技术原子层刻蚀反应的反应过程流程图;Fig. 1 is a flow chart of the reaction process of an atomic layer etching reaction in the prior art provided according to an embodiment of the present invention;

图2是根据本发明实施例提供一种原子层刻蚀反应装置的结构图;2 is a structural diagram of an atomic layer etching reaction device according to an embodiment of the present invention;

图3是根据本发明实施例提供的一种原子层刻蚀反应装置的剖视图;3 is a cross-sectional view of an atomic layer etching reaction device provided according to an embodiment of the present invention;

图4是根据本发明实施例提供的平台总成的结构图;Fig. 4 is a structural diagram of a platform assembly provided according to an embodiment of the present invention;

图5是根据本发明实施例提供的平台总成的剖视图;Fig. 5 is a cross-sectional view of a platform assembly provided according to an embodiment of the present invention;

图6是根据本发明实施例提供的多轴并联臂平台总成的结构图;Fig. 6 is a structural diagram of a multi-axis parallel arm platform assembly provided according to an embodiment of the present invention;

图7是根据本发明实施例提供的真空室的结构示意图。Fig. 7 is a schematic structural diagram of a vacuum chamber provided according to an embodiment of the present invention.

具体实施方式detailed description

为了使本发明的目的、技术方案和有益效果更加清晰明白,以下结合附图和具体实施方式,对本发明进行进一步详细说明。应当理解的是,本说明书中描述的具体实施方式仅仅是为了解释本发明,并不是为了限定本发明。In order to make the object, technical solution and beneficial effect of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and specific embodiments. It should be understood that the specific implementations described in this specification are only for explaining the present invention, not for limiting the present invention.

在本发明的描述中,需要理解的是,术语“中心”、“纵向”、“横向”、“长度”、“宽度”、“厚度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”、“内”、“外”、“顺时针”、“逆时针”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。此外,术语“第一”、“第二”仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括一个或者更多个所述特征。在本发明的描述中,“多个”的含义是指两个或两个以上,除非另有明确具体的限定。In describing the present invention, it should be understood that the terms "center", "longitudinal", "transverse", "length", "width", "thickness", "upper", "lower", "front", " Orientation indicated by rear, left, right, vertical, horizontal, top, bottom, inside, outside, clockwise, counterclockwise, etc. The positional relationship is based on the orientation or positional relationship shown in the drawings, which is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, Therefore, it should not be construed as limiting the invention. In addition, the terms "first" and "second" are used for descriptive purposes only, and cannot be interpreted as indicating or implying relative importance or implicitly specifying the quantity of indicated technical features. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of said features. In the description of the present invention, "plurality" means two or more, unless otherwise specifically defined.

在本发明的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should be noted that unless otherwise specified and limited, the terms "installation", "connection" and "connection" should be understood in a broad sense, for example, it can be a fixed connection or a detachable connection. Connected, or integrally connected; it can be mechanically connected, directly connected, or indirectly connected through an intermediary, and can be an internal communication between two elements or an interactive relationship between two elements. Those of ordinary skill in the art can understand the specific meanings of the above terms in the present invention according to specific situations.

在本发明中,除非另有明确的规定和限定,第一特征在第二特征之“上”或之“下”可以包括第一和第二特征直接接触,也可以包括第一和第二特征不是直接接触而是通过它们之间的另外的特征接触。而且,第一特征在第二特征“之上”、“上方”和“上面”包括第一特征在第二特征正上方和斜上方,或仅仅表示第一特征水平高度高于第二特征。第一特征在第二特征“之下”、“下方”和“下面”包括第一特征在第二特征正上方和斜上方,或仅仅表示第一特征水平高度小于第二特征。In the present invention, unless otherwise clearly specified and limited, a first feature being "on" or "under" a second feature may include direct contact between the first and second features, and may also include the first and second features Not in direct contact but through another characteristic contact between them. Moreover, "above", "above" and "above" the first feature on the second feature include that the first feature is directly above and obliquely above the second feature, or simply means that the first feature is horizontally higher than the second feature. "Below", "below" and "under" the first feature to the second feature include that the first feature is directly above and obliquely above the second feature, or simply means that the first feature is less horizontal than the second feature.

现有常规的能量调控方式通常是对离子发生器本身的调节(如调节功率、气压等)。图1为原子层刻蚀反应的反应过程流程图。对于原子层刻蚀反应,首先,氯气(Cl2)或氯离子被导入刻蚀腔,氯气分子吸附于(或者被吸收入)硅材料的表面,形成一个氯化层。这一改性步骤(步骤A)具有“自限制性”:表面一旦饱和,反应立即停止。The existing conventional energy regulation method is usually to adjust the ion generator itself (such as adjusting power, air pressure, etc.). Fig. 1 is a flow chart of the reaction process of the atomic layer etching reaction. For the atomic layer etching reaction, first, chlorine gas (Cl2) or chlorine ions are introduced into the etching chamber, and chlorine gas molecules are adsorbed (or absorbed) on the surface of the silicon material to form a chloride layer. This modification step (step A) is "self-limiting": once the surface is saturated, the reaction stops immediately.

接着,清除刻蚀腔中过量的氯气,并引入氩离子(Ar+)。这些氩离子轰击硅片,物理性去除硅-氯反应后产生的氯化层,进而留下下层未经改性的硅表面。这一去除步骤(步骤B)仍然是有自限制性的,因为一旦氯化层被全部去除后,该过程也将终止。上述两个步骤完成后,一层极薄的材料就能被精确地从硅片上去除。Next, excess chlorine gas in the etching chamber is removed, and argon ions (Ar+) are introduced. These argon ions bombard the silicon wafer, physically removing the chloride layer created by the silicon-chlorine reaction, leaving the underlying unmodified silicon surface. This removal step (step B) is still self-limiting, since the process is also terminated once the chloride layer has been completely removed. After the above two steps are completed, an extremely thin layer of material can be precisely removed from the silicon wafer.

离子束或中性粒子束在刻蚀腔中必然存在一种分布。如对氩离子(Ar+)能量进行精准调控:氩离子(Ar+)从氩气被电离到扩散至衬底表面,存在一个分布,衬底处于氩离子分布的哪个区域会直接影响衬底表面的原子层刻蚀效率以及精准性。而我们对于运动到衬底表面离子束或中性粒子束的能量分布要求可以实现精准调控,不必再拘泥离子束或中性粒子束发生装置与衬底距离固定的局限。There must be a distribution of ion beam or neutral particle beam in the etching chamber. For example, the energy of argon ions (Ar+) is precisely regulated: argon ions (Ar+) are ionized from argon to diffuse to the substrate surface, there is a distribution, which area of the substrate is in the distribution of argon ions will directly affect the atoms on the substrate surface Layer etching efficiency and accuracy. However, we require that the energy distribution of the ion beam or neutral particle beam moving to the surface of the substrate can be precisely regulated, and there is no need to be limited by the fixed distance between the ion beam or neutral particle beam generating device and the substrate.

因此,本文公开的示例性择取粒子能量场区域的原子层刻蚀反应装置原子层刻蚀反应装置及刻蚀方法,多轴并联臂平台总成31与基片托盘32连接并能带动基片托盘32做平移、旋转或倾斜运动,基片托盘32能自如地在不同时刻出现在离子场不同位置,进而实现精准调控基片所需要的能量。Therefore, in the exemplary atomic layer etching reaction device and etching method for selecting the particle energy field region disclosed herein, the multi-axis parallel arm platform assembly 31 is connected to the substrate tray 32 and can drive the substrate The tray 32 moves in translation, rotation or inclination, and the substrate tray 32 can freely appear in different positions of the ion field at different times, so as to precisely control the energy required by the substrate.

在本发明的实施例中,如图2至图6所示,原子层刻蚀反应装置包括:真空机构1,所述真空机构1为原子层刻蚀反应提供场所。In an embodiment of the present invention, as shown in FIG. 2 to FIG. 6 , the atomic layer etching reaction device includes: a vacuum mechanism 1 , and the vacuum mechanism 1 provides a place for the atomic layer etching reaction.

其中,在真空机构1内部可以进行原子层刻蚀反应。Wherein, the atomic layer etching reaction can be carried out inside the vacuum mechanism 1 .

离子源2,所述离子源2设置在真空机构1外部并与真空机构1相连通,所述离子源2用于在真空机构1内部产生离子场。The ion source 2 is arranged outside the vacuum mechanism 1 and communicated with the vacuum mechanism 1 , and the ion source 2 is used to generate an ion field inside the vacuum mechanism 1 .

其中,离子场是指离子源2发生的若干离子的分布场,离子束能通过离子源2与真空机构1相连通的部位进入真空机构1内部。由若干离子形成离子束。Wherein, the ion field refers to the distribution field of several ions generated by the ion source 2 , and the ion beam can enter the interior of the vacuum mechanism 1 through the part where the ion source 2 communicates with the vacuum mechanism 1 . An ion beam is formed from a number of ions.

若增加电子中和器,电子中和器用于产生中性粒子,中性粒子能通过电子中和器与真空机构1相连通的部位进入真空机构1。此时的离子场是指若干离子和中性粒子的分布场。由若干中性粒子形成中性粒子束。If an electronic neutralizer is added, the electronic neutralizer is used to generate neutral particles, and the neutral particles can enter the vacuum mechanism 1 through the part where the electronic neutralizer communicates with the vacuum mechanism 1 . The ion field at this time refers to the distribution field of several ions and neutral particles. A neutral particle beam is formed from several neutral particles.

平台总成3,所述平台总成3位于真空机构1内部并用于承载基片。其中,平台总成3能在基片进行原子层刻蚀反应时将其固定。The platform assembly 3 is located inside the vacuum mechanism 1 and is used to carry the substrate. Wherein, the platform assembly 3 can fix the substrate when the atomic layer etching reaction is performed.

其中,在所述平台总成3的带动下,所述基片能在离子场中按照预设路径变换位置以按预设图案被刻蚀。基片的预设图案是指基片所要被刻蚀的区域。Wherein, driven by the platform assembly 3, the substrate can change its position in the ion field according to a preset path to be etched according to a preset pattern. The preset pattern of the substrate refers to the area of the substrate to be etched.

其中,平台总成3能调整位置,带动基片做平移、旋转或倾斜运动,使基片能自如地在不同时刻出现在离子场不同位置,实现基片有选择的进行原子层刻蚀。Among them, the platform assembly 3 can adjust the position to drive the substrate to perform translation, rotation or tilting movement, so that the substrate can freely appear in different positions of the ion field at different times, and realize selective atomic layer etching of the substrate.

上述原子层刻蚀反应装置,平台总成3可以带动基片做平移、旋转或倾斜运动,不必再拘泥于现有技术中的离子束或中性粒子束发生装置与衬底距离固定的局限,进而根据离子场的能量分布区域,并结合基片所需要精准调控的能量范畴,基片能自如地出现在离子场的不同位置,选择适宜的能量分布区间,对基片进行精准的原子层刻蚀。The above-mentioned atomic layer etching reaction device, the platform assembly 3 can drive the substrate to perform translation, rotation or tilting motion, and it is no longer necessary to stick to the limitation of the fixed distance between the ion beam or neutral particle beam generating device and the substrate in the prior art, Furthermore, according to the energy distribution area of the ion field, combined with the energy range that the substrate needs to be precisely regulated, the substrate can freely appear in different positions of the ion field, and an appropriate energy distribution interval is selected to perform precise atomic layer engraving on the substrate. eclipse.

在本发明实施例中,如图4至图5所示,所述平台总成3包括多轴并联臂平台总成31、基片托盘32和挡板33,所述多轴并联臂平台总成31设置在真空机构1内部,所述多轴并联臂平台总成31与基片托盘32活动连接,所述多轴并联臂平台总成31能带动基片托盘32做平移、旋转或倾斜运动,所述基片托盘32用于承载基片,所述挡板33罩设在多轴并联臂平台总成31上。In the embodiment of the present invention, as shown in Figures 4 to 5, the platform assembly 3 includes a multi-axis parallel arm platform assembly 31, a substrate tray 32 and a baffle 33, the multi-axis parallel arm platform assembly 31 is arranged inside the vacuum mechanism 1, the multi-axis parallel arm platform assembly 31 is movably connected with the substrate tray 32, and the multi-axis parallel arm platform assembly 31 can drive the substrate tray 32 to perform translation, rotation or tilting motion, The substrate tray 32 is used to carry the substrate, and the baffle plate 33 is covered on the multi-axis parallel arm platform assembly 31 .

结合集成检测手段,可以实时检测某点出的能量密度,并立即反馈给平台总成3,平台总成3自我调节到需要适宜的能量分布区域,让原子层刻蚀反应所需离子能量择取具有“自主思想”。具体地,集成检测手段可探测基片托盘32所处位置的能量,进而获得离子场的能量分布。Combined with the integrated detection means, the energy density at a certain point can be detected in real time, and immediately fed back to the platform assembly 3. The platform assembly 3 self-adjusts to the appropriate energy distribution area, allowing the ion energy required for the atomic layer etching reaction to be selected. Have "independent thought". Specifically, the integrated detection means can detect the energy at the position of the substrate tray 32 to obtain the energy distribution of the ion field.

根据离子场分布,编辑多轴并联臂平台总成31的运行轨迹,使得基片自如地在不同时刻出现在不同位置。具体地,开启多轴并联臂平台总成31,多轴并联臂平台总成31能带动基片托盘32做平移、旋转或倾斜运动,进而带动基片做平移、旋转或倾斜运动。基片托盘32、基片运动在离子场中,基片可以自由选择身处离子场的哪个分布区域进行原子层刻蚀。According to the ion field distribution, the running track of the multi-axis parallel arm platform assembly 31 is edited so that the substrate freely appears in different positions at different times. Specifically, when the multi-axis parallel arm platform assembly 31 is turned on, the multi-axis parallel arm platform assembly 31 can drive the substrate tray 32 to move in translation, rotation or tilt, and then drive the substrate to move in translation, rotation or tilt. The substrate tray 32 and the substrate move in the ion field, and the substrate can freely choose which distribution area of the ion field to perform atomic layer etching.

根据离子场分布,基片能处于离子场的不同区域,不同位置,再根据基片所需要精准调控的能量范畴,实现基片择优选择适宜的离子束能量分布区域,进而实现对基片精准地原子层刻蚀。同时,大大增加调控的自由度,能充分有效地进行原子层刻蚀,也提高了原子层刻蚀的精准性。According to the ion field distribution, the substrate can be in different areas and positions of the ion field, and then according to the energy range that needs to be precisely regulated by the substrate, the substrate can be optimally selected for the appropriate ion beam energy distribution area, and then the substrate can be precisely controlled. Atomic layer etching. At the same time, the freedom of regulation is greatly increased, the atomic layer etching can be fully and effectively performed, and the accuracy of atomic layer etching is also improved.

挡板33对多轴并联臂平台总成31起保护作用,避免其破损,受到外物干扰。The baffle 33 protects the multi-axis parallel arm platform assembly 31 from damage and interference from foreign objects.

在本发明实施例中,如图4至图6所示,所述多轴并联臂平台总成31为六轴并联臂平台总成。In the embodiment of the present invention, as shown in FIGS. 4 to 6 , the multi-axis parallel arm platform assembly 31 is a six-axis parallel arm platform assembly.

在本发明实施例中,如图6所示,所述多轴并联臂平台总成31包括底座311、运动平台312和若干个直线驱动装置313,所述底座311设置在真空机构1内部、固定不移动,所述运动平台312与基片托盘32连接,每个所述直线驱动装置313的两端分别与底座311、运动平台312多方位转动连接;所述挡板33包括上挡板331和下挡板332,所述上挡板331和下挡板332罩设在底座311和运动平台312之间。In the embodiment of the present invention, as shown in Figure 6, the multi-axis parallel arm platform assembly 31 includes a base 311, a motion platform 312 and several linear drive devices 313, the base 311 is arranged inside the vacuum mechanism 1, fixed Without moving, the moving platform 312 is connected to the substrate tray 32, and the two ends of each linear drive device 313 are respectively connected to the base 311 and the moving platform 312 in multi-directional rotation; the baffle 33 includes an upper baffle 331 and The lower baffle 332 , the upper baffle 331 and the lower baffle 332 are provided between the base 311 and the moving platform 312 .

根据离子场分布,编辑若干个直线驱动装置313的运行轨迹,使得基片自如地在不同时刻出现在不同位置。具体地,同时开启若干个直线驱动装置313,若干个直线驱动装置313能带动运动平台312、基片托盘32做平移、旋转或倾斜运动,进而带动基片做平移、旋转或倾斜运动。运动平台312、基片托盘32、基片运动在离子场中,基片可以自由选择身处离子场的哪个分布区域进行原子层刻蚀。According to the distribution of the ion field, the running trajectories of several linear driving devices 313 are edited so that the substrate freely appears in different positions at different times. Specifically, several linear driving devices 313 are turned on at the same time, and several linear driving devices 313 can drive the motion platform 312 and the substrate tray 32 to perform translational, rotational or tilting movements, and then drive the substrate to perform translational, rotational or tilting movements. The moving platform 312, the substrate tray 32, and the substrate move in the ion field, and the substrate can freely choose which distribution area of the ion field to perform atomic layer etching.

上挡板331和下挡板332对底座311、运动平台312和若干个直线驱动装置313多轴并联臂平台总成31起保护作用,避免其受损。The upper baffle 331 and the lower baffle 332 protect the base 311 , the motion platform 312 and several linear drive devices 313 multi-axis parallel arm platform assembly 31 from damage.

在本发明实施例中,所述平台总成3还包括充电接口,充电接口实现外部电源对若干个直线驱动装置313供电;可编程的控制电路,控制电路与若干个直线驱动装置313电性连接,并对其进行逻辑控制。In the embodiment of the present invention, the platform assembly 3 also includes a charging interface, which enables an external power supply to supply power to several linear drive devices 313; a programmable control circuit, and the control circuit is electrically connected to several linear drive devices 313 , and logically control it.

在本发明实施例中,运动平台312上设置有防腐蚀材料,防腐蚀材料能耐腐蚀性气体腐蚀,并对离子束轰击起到一定的防护作用。In the embodiment of the present invention, the motion platform 312 is provided with an anti-corrosion material, which is resistant to corrosion by corrosive gases and plays a certain protective role against ion beam bombardment.

在本发明实施例中,如图5至图6所示,若干个所述直线驱动装置313两两为一组,且每组的两个所述直线驱动装置313一端均通过第一传动装置转动设置在底座311的同一个边角处,每组的两个所述直线驱动装置313另一端均通过第二传动装置转动设置在运动平台312上的三角座两个相邻的顶角处。In the embodiment of the present invention, as shown in Fig. 5 to Fig. 6, several linear drive devices 313 form a group in pairs, and one end of the two linear drive devices 313 in each group is rotated by the first transmission device They are arranged at the same corner of the base 311 , and the other ends of the two linear drive devices 313 in each group are rotated and arranged at two adjacent top corners of the triangular seat on the motion platform 312 through the second transmission device.

其中,所述直线驱动装置313有六个,六个所述直线驱动装置313两两为一组,分为三组,分别为M组、N组、L组。M组中的两个直线驱动装置313分别命名为M1、M2,N组中的两个直线驱动装置313分别命名为N1、N2,L组中的两个直线驱动装置313分别命名为L1、L2。Wherein, there are six linear driving devices 313, and the six linear driving devices 313 form a group of two, and are divided into three groups, which are M group, N group and L group respectively. The two linear drive devices 313 in group M are named M1 and M2 respectively, the two linear drive devices 313 in group N are named N1 and N2 respectively, and the two linear drive devices 313 in group L are named L1 and L2 respectively .

其中,底座311的三个边角分别是A、B、C。三角座的三个顶角分别是X、Y、Z。Wherein, the three corners of the base 311 are A, B, and C respectively. The three top angles of the triangular base are X, Y, and Z respectively.

如图5至图6所示,M组,M1、M2的一端均通过第一传动装置转动设置在底座311的A处,M1、M2的另一端均通过第二传动装置转动设置在X、Z处。N组,N1、N2的一端均通过第一传动装置转动设置在底座311的B处,N1、N2的另一端均通过第二传动装置转动设置在X、Y处。L组,L1、L2的一端均通过第一传动装置转动设置在底座311的C处,L1、L2的另一端均通过第二传动装置转动设置在Z、Y处。As shown in Figures 5 to 6, in group M, one end of M1 and M2 is rotated at A of the base 311 through the first transmission device, and the other ends of M1 and M2 are rotated at X and Z through the second transmission device. place. In group N, one end of N1 and N2 is rotated at B of the base 311 through the first transmission device, and the other ends of N1 and N2 are rotated at X and Y through the second transmission device. In group L, one end of L1 and L2 is rotated at C of the base 311 through the first transmission device, and the other ends of L1 and L2 are rotated at Z and Y through the second transmission device.

第一传动装置和第二传动装置中的“第一”和“第二”只是为了能够区分每个所述传动装置,其并不是对传动装置的个数或者顺序的限制。The "first" and "second" in the first transmission device and the second transmission device are only for distinguishing each of the transmission devices, and are not intended to limit the number or order of the transmission devices.

在本发明实施例中,如图6所示,所述底座311为边角是弧形倒角的三角形。In the embodiment of the present invention, as shown in FIG. 6 , the base 311 is a triangle whose corners are curved and chamfered.

在本发明实施例中,所述运动平台312上设置有顶角是弧形倒角的三角座。In the embodiment of the present invention, the motion platform 312 is provided with a triangular seat with an arc-shaped chamfered corner.

在本发明实施例中,所述第一传动装置和第二传动装置均铰链包括双轴铰链。In an embodiment of the present invention, the hinges of the first transmission device and the second transmission device include biaxial hinges.

在本发明实施例中,所述双轴铰链包括转动连接的第一双轴铰链和第二双轴铰链,部分所述铰链的第一双轴铰链与边角转动连接、第二双轴铰链与直线驱动装置313一端转动连接,剩余所述铰链的第一双轴铰链与顶角转动连接、第二双轴铰链与直线驱动装置313另一端转动连接。In an embodiment of the present invention, the biaxial hinge includes a first biaxial hinge and a second biaxial hinge that are rotatably connected, and in some of the hinges, the first biaxial hinge is rotatably connected to the corner, and the second biaxial hinge is connected to the corner. One end of the linear drive device 313 is rotatably connected, the first two-axis hinge of the remaining hinges is rotatably connected to the top corner, and the second two-axis hinge is rotatably connected to the other end of the linear drive device 313 .

第一双轴铰链和第二双轴铰链中的“第一”和“第二”只是为了能够区分每个所述双轴铰链,其并不是对双轴铰链的个数或者顺序的限制。The "first" and "second" in the first biaxial hinge and the second biaxial hinge are only for distinguishing each biaxial hinge, which is not a limitation on the number or order of the biaxial hinges.

在本发明实施例中,如图5至图6所示,当所述运动平台312处于初始水平状态时,运动平台312底壁的各个点位与真空机构1内部底壁之间的距离均相等,每个点位与内部底壁之间的距离均为峰值。In the embodiment of the present invention, as shown in Fig. 5 to Fig. 6, when the moving platform 312 is in the initial horizontal state, the distance between each point of the bottom wall of the moving platform 312 and the inner bottom wall of the vacuum mechanism 1 is equal , the distance between each point and the inner bottom wall is the peak value.

每个所述直线驱动装置313均处于倾斜状态,每个所述直线驱动装置313与真空机构1内部底壁之间形成初始夹角。Each of the linear driving devices 313 is in an inclined state, and an initial angle is formed between each of the linear driving devices 313 and the inner bottom wall of the vacuum mechanism 1 .

当所述运动平台312处于平移状态时,运动平台312底壁的各个点位与真空机构1内部底壁之间的距离均相等,每个点位与内部底壁之间的距离均小于峰值。每个所述直线驱动装置313均处于倾斜状态,每个所述直线驱动装置313与真空机构1内部底壁之间形成第一夹角,第一夹角大于或小于初始夹角。When the moving platform 312 is in a translation state, the distances between each point on the bottom wall of the moving platform 312 and the inner bottom wall of the vacuum mechanism 1 are equal, and the distance between each point and the inner bottom wall is smaller than the peak value. Each of the linear driving devices 313 is in an inclined state, and a first included angle is formed between each of the linear driving devices 313 and the inner bottom wall of the vacuum mechanism 1 , and the first included angle is larger or smaller than the initial included angle.

当所述运动平台312处于倾斜状态时,运动平台312底壁的各个点位与真空机构1内部底壁之间的距离不相同,部分点位与内部底壁之间的距离均小于峰值、剩余点位与内部底壁之间的距离均大于峰值。每个所述直线驱动装置313均处于倾斜状态,每个所述直线驱动装置313与真空机构1内部底壁之间形成的第二夹角,第二夹角大于或小于初始夹角。When the moving platform 312 is in an inclined state, the distances between each point of the bottom wall of the moving platform 312 and the inner bottom wall of the vacuum mechanism 1 are different, and the distances between some points and the inner bottom wall are smaller than the peak value, the remaining The distance between the points and the inner bottom wall is larger than the peak value. Each of the linear driving devices 313 is in an inclined state, and a second included angle is formed between each of the linear driving devices 313 and the inner bottom wall of the vacuum mechanism 1 , and the second included angle is larger or smaller than the initial included angle.

第一夹角和第二夹角中的“第一”和“第二”只是为了能够区分每个所述直线驱动装置313与真空机构1内部底壁之间形成的不同夹角,其并不是对夹角的个数或者顺序的限制。The "first" and "second" in the first included angle and the second included angle are just to be able to distinguish the different included angles formed between each linear drive device 313 and the inner bottom wall of the vacuum mechanism 1, which are not Restrictions on the number or order of included angles.

在本发明实施例中,如图2至图3所示,所述真空机构1包括真空腔体11。值得说明的是,该真空腔体11只是示例性地给出,只要是真空空间均在本申请的保护范围内。In the embodiment of the present invention, as shown in FIGS. 2 to 3 , the vacuum mechanism 1 includes a vacuum cavity 11 . It is worth noting that the vacuum cavity 11 is only given as an example, as long as it is a vacuum space, it is within the protection scope of the present application.

在本发明实施例中,所述真空机构1内部壁上设置有防腐蚀材料。真空机构1内部要进行原子层刻蚀反应,因此真空机构1内部要做防腐蚀的特殊处理,以抵抗腐蚀性气体腐蚀,耐受离子束轰击,延长实用寿命。In the embodiment of the present invention, anti-corrosion materials are provided on the inner wall of the vacuum mechanism 1 . The atomic layer etching reaction is carried out inside the vacuum mechanism 1, so special anti-corrosion treatment is required inside the vacuum mechanism 1 to resist corrosive gas corrosion, withstand ion beam bombardment, and prolong the practical life.

在本发明实施例中,如图2所示,所述真空机构1上设置有检修门13。检修门13主要方便对真空机构1、平台总成3进行检修。In the embodiment of the present invention, as shown in FIG. 2 , the vacuum mechanism 1 is provided with an inspection door 13 . Inspection door 13 is mainly convenient to carry out inspection to vacuum mechanism 1, platform assembly 3.

在本发明实施例中,如图3所示,所述真空机构1具有抽真空口14。真空机构1通过抽真空口14抽气使其内部成真空条件,以满足原子层刻蚀反应的要求。In the embodiment of the present invention, as shown in FIG. 3 , the vacuum mechanism 1 has a vacuum port 14 . The vacuum mechanism 1 evacuates air through the vacuum port 14 to make the interior into a vacuum condition, so as to meet the requirements of the atomic layer etching reaction.

在本发明实施例中,如图2至3所示,所述抽真空口14处设置有抽真空法兰141。抽真空法兰141用于连接抽真空设备。In the embodiment of the present invention, as shown in FIGS. 2 to 3 , a vacuum flange 141 is provided at the vacuum port 14 . The vacuum flange 141 is used for connecting vacuum equipment.

在本发明实施例中,所述离子源2为电感耦合离子源、电容耦合离子源、射频离子源、霍尔离子源及考夫曼离子源中的至少一种。In the embodiment of the present invention, the ion source 2 is at least one of an inductively coupled ion source, a capacitively coupled ion source, a radio frequency ion source, a Hall ion source and a Kaufman ion source.

本发明实施例提供一种原子层刻蚀反应装置包括:真空机构1,所述真空机构1为原子层刻蚀反应提供场所,如图7所示,所述真空机构1包括真空室12;离子源2,所述离子源2设置在真空机构1外部并与真空机构1相连通,所述离子源2用于在真空机构1内部产生离子场;平台总成3,所述平台总成3位于真空机构1内部并用于承载基片;其中,在所述平台总成3的带动下,所述基片能在离子场中按照预设路径变换位置以按预设图案被刻蚀。An embodiment of the present invention provides an atomic layer etching reaction device including: a vacuum mechanism 1, which provides a place for the atomic layer etching reaction. As shown in FIG. 7, the vacuum mechanism 1 includes a vacuum chamber 12; Source 2, the ion source 2 is arranged outside the vacuum mechanism 1 and communicated with the vacuum mechanism 1, the ion source 2 is used to generate an ion field inside the vacuum mechanism 1; platform assembly 3, the platform assembly 3 is located The inside of the vacuum mechanism 1 is used to carry the substrate; wherein, driven by the platform assembly 3 , the substrate can change its position in the ion field according to a preset path to be etched according to a preset pattern.

值得说明的是,该真空室12只是示例性地给出,只要是真空空间均在本申请的保护范围内。It is worth noting that the vacuum chamber 12 is only provided as an example, as long as it is a vacuum space, it is within the protection scope of the present application.

上述原子层刻蚀反应装置,平台总成3可以带动基片做平移、旋转或倾斜运动,不必再拘泥于现有技术中的离子束或中性粒子束发生装置与衬底距离固定的局限,进而根据离子场的能量分布区域,并结合基片所需要精准调控的能量范畴,基片能自如地在不同时刻出现在离子场不同位置,实现基片精准的原子层刻蚀。The above-mentioned atomic layer etching reaction device, the platform assembly 3 can drive the substrate to perform translation, rotation or tilting motion, and it is no longer necessary to stick to the limitation of the fixed distance between the ion beam or neutral particle beam generating device and the substrate in the prior art, Furthermore, according to the energy distribution area of the ion field, combined with the energy range that the substrate needs to be precisely controlled, the substrate can freely appear in different positions of the ion field at different times, realizing precise atomic layer etching of the substrate.

其中,离子源2、平台总成3,在前面实施例中已经详细说明,在此不再赘述。Wherein, the ion source 2 and the platform assembly 3 have been described in detail in the previous embodiments, and will not be repeated here.

一种刻蚀方法,采用如上述任一项原子层刻蚀反应装置,包括以下步骤:S100、向所述真空机构1内部通入刻蚀气体,并开启所述离子源2,激发刻蚀气体在所述真空机构1内部形成离子场,并开启所述平台总成3,所述平台总成3带动所述基片在所述离子场中按照预设路径变换位置以致所述基片按预设图案被刻蚀。An etching method, using any one of the above-mentioned atomic layer etching reaction devices, comprising the following steps: S100, introducing an etching gas into the vacuum mechanism 1, and turning on the ion source 2 to excite the etching gas An ion field is formed inside the vacuum mechanism 1, and the platform assembly 3 is turned on, and the platform assembly 3 drives the substrate to change its position in the ion field according to a preset path so that the substrate follows a preset path. Let the pattern be etched.

其中,原子层刻蚀反应装置在前面针对原子层刻蚀反应装置的实施例中已经详细说明,在此不再赘述。Wherein, the atomic layer etching reaction device has been described in detail in the previous embodiments of the atomic layer etching reaction device, and will not be repeated here.

以上步骤所提供的介绍,只是用于帮助理解本发明的方法、结构及核心思想。对于本技术领域内的普通技术人员来说,在不脱离本发明原理的前提下,还可以对本发明进行若干改进和修饰,这些改进和修饰也同样属于本发明权利要求保护范围之内。The introduction provided by the above steps is only used to help understand the method, structure and core idea of the present invention. For those skilled in the art, without departing from the principle of the present invention, some improvements and modifications can be made to the present invention, and these improvements and modifications also belong to the protection scope of the claims of the present invention.

Claims (10)

1. An atomic layer etching reaction apparatus, comprising: the vacuum mechanism (1), the said vacuum mechanism (1) offers the place for atomic layer etching reaction;
the ion source (2) is communicated with the vacuum mechanism (1), and the ion source (2) is used for generating an ion field inside the vacuum mechanism (1);
the platform assembly (3) is positioned inside the vacuum mechanism (1) and is used for bearing the substrate;
wherein, under the drive of the platform assembly (3), the substrate is etched according to a preset pattern by changing the position in the ion field according to a preset path.
2. The atomic layer etching reaction device according to claim 1, wherein the platform assembly (3) comprises a multi-axis parallel arm platform assembly (31), a substrate tray (32) and a baffle plate (33), the multi-axis parallel arm platform assembly (31) is arranged inside the vacuum mechanism (1), the multi-axis parallel arm platform assembly (31) is in transmission connection with the substrate tray (32), the substrate tray (32) is used for bearing a substrate, and the baffle plate (33) covers the multi-axis parallel arm platform assembly (31).
3. The atomic layer etch reactor according to claim 2, wherein the multi-axis parallel arm platform assembly (31) is a six-axis parallel arm platform assembly.
4. The atomic layer etching reaction device according to any of claims 2 to 3, wherein the multi-axis parallel arm platform assembly (31) comprises a base (311), a moving platform (312) and a plurality of linear driving devices (313), the base (311) is disposed inside the vacuum mechanism (1), the moving platform (312) is connected with the substrate tray (32), and two ends of each linear driving device (313) are respectively connected with the base (311) and the moving platform (312) in a multi-directional rotation manner;
the baffle (33) comprises an upper baffle (331) and a lower baffle (332), and the upper baffle (33) and the lower baffle (33) are covered between the base (311) and the moving platform (312).
5. The atomic layer etching reaction device according to claim 4, wherein the plurality of linear driving devices (313) are grouped in pairs, one end of each group of two linear driving devices (313) is rotatably disposed at the same corner of the base (311) through a first transmission device, and the other end of each group of two linear driving devices (313) is rotatably disposed at two adjacent corners of the triangular seat on the moving platform (312) through a second transmission device.
6. The atomic layer etch reactor of claim 5, wherein the first actuator and the second actuator each comprise a biaxial hinge.
7. The atomic layer etching reaction device according to any of claims 4 to 5, wherein each of the linear driving devices (313) is in a tilted state when the moving platform (312) is in an initial horizontal state.
8. The atomic layer etching reaction device according to claim 1, wherein an anti-corrosive material is provided on an inner wall of the vacuum mechanism (1).
9. The atomic layer etch reactor of claim 1, wherein the ion source (2) is at least one of an inductively coupled ion source, a capacitively coupled ion source, a radio frequency ion source, a hall ion source, and a koffman ion source.
10. An etching method for performing atomic layer etching by using the atomic layer etching reaction device of any one of 1 to 9 is characterized by comprising the following steps:
s100, introducing etching gas into the vacuum mechanism (1), starting the ion source (2), exciting the etching gas to form an ion field in the vacuum mechanism (1), starting the platform assembly (3), and driving the substrate to change the position in the ion field according to a preset path by the platform assembly (3) so that the substrate is etched according to a preset pattern.
CN202211208673.7A 2022-09-30 2022-09-30 Atomic layer etching reaction device and etching method Pending CN115547803A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0556043A1 (en) * 1992-02-13 1993-08-18 Hughes Aircraft Company Apparatus for programmed plasma etching tool motion to modify solid layer thickness profiles
US20100330787A1 (en) * 2006-08-18 2010-12-30 Piero Sferlazzo Apparatus and method for ultra-shallow implantation in a semiconductor device
JP2010098051A (en) * 2008-10-15 2010-04-30 Showa Shinku:Kk Etching device, etching method, etching program, and film forming device
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