CN114226164A - Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof - Google Patents
Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof Download PDFInfo
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- CN114226164A CN114226164A CN202111557036.6A CN202111557036A CN114226164A CN 114226164 A CN114226164 A CN 114226164A CN 202111557036 A CN202111557036 A CN 202111557036A CN 114226164 A CN114226164 A CN 114226164A
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- 238000000576 coating method Methods 0.000 title claims abstract description 63
- 239000011248 coating agent Substances 0.000 title claims abstract description 61
- 239000007772 electrode material Substances 0.000 title claims abstract description 39
- 238000000034 method Methods 0.000 title claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 26
- 206010067171 Regurgitation Diseases 0.000 claims abstract description 12
- 230000008859 change Effects 0.000 claims abstract description 11
- 238000001125 extrusion Methods 0.000 claims description 27
- 238000007765 extrusion coating Methods 0.000 claims description 22
- 238000001514 detection method Methods 0.000 claims description 9
- 230000007246 mechanism Effects 0.000 claims description 9
- 230000009471 action Effects 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims 1
- 230000003287 optical effect Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000006872 improvement Effects 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 2
- 244000287353 Crassocephalum crepidioides Species 0.000 description 1
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C5/00—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work
- B05C5/02—Apparatus in which liquid or other fluent material is projected, poured or allowed to flow on to the surface of the work the liquid or other fluent material being discharged through an outlet orifice by pressure, e.g. from an outlet device in contact or almost in contact, with the work
- B05C5/0254—Coating heads with slot-shaped outlet
- B05C5/0258—Coating heads with slot-shaped outlet flow controlled, e.g. by a valve
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
- B05C11/1002—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves
- B05C11/1005—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves responsive to condition of liquid or other fluent material already applied to the surface, e.g. coating thickness, weight or pattern
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
- B05D1/265—Extrusion coatings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Coating Apparatus (AREA)
Abstract
A method for coating electrode material, a precision program-controlled type coating and feeding cerium-suction spitting valve and a coating head thereof, wherein the method comprises a control module controlling the cerium-suction spitting valve to perform material regurgitation at a thick part and material spitting at a thin part according to data of a coating thickness change rule of an electrode slice in a longitudinal direction within a predetermined period; the present invention is characterized in that the optical output valve draws back excess electrode material at a thick portion to make the thickness of the thick portion equal to a standard thickness and supplies electrode material at a thin portion to make the thickness of the thin portion equal to the standard thickness during the same cycle of electrode sheet coating, thereby providing an advantage of substantially uniform thickness of the electrode material of the electrode sheet in the longitudinal direction.
Description
Technical Field
The invention relates to a method for coating an electrode material, a precision program-controlled type coating feeding abruption valve and a coating head thereof.
Background
In the prior art, electrode materials (such as electrode materials of lithium batteries, electrode materials of lithium iron phosphate batteries, and the like) are mostly coated on two sides of a traveling substrate by an extrusion coater, and are dried, rolled, sliced, and packaged to form corresponding batteries. In the process of coating the electrode material on the substrate by the extrusion coater, it is preferable that the electrode material is distributed more uniformly on the substrate, i.e., the thickness of the electrode sheet is uniform in the transverse direction and the longitudinal direction, the transverse direction in the present invention means a direction in which the electrode sheet is perpendicular to the direction in which the substrate travels during coating, and the longitudinal direction means a direction in which the electrode sheet is uniform with the direction in which the substrate travels during coating.
In the actual coating process, the thickness of the electrode plate in the transverse direction is well controlled, and the thickness of the electrode plate in the transverse direction can be ensured to be consistent by adjusting the coating gap of the extrusion coating head; however, the thickness of the electrode sheet in the longitudinal direction (seen from the longitudinal section) is influenced by various factors and is always unstable, and the thickness of the electrode sheet coated by the extrusion coating heads of the same type and produced by the same factory is different from the thickness of the electrode sheet coated by the extrusion coating heads in the longitudinal direction after the extrusion coating heads are installed on site; the electrode material formula is changed in the same machine coater, and even if the same electrode material formula is used, the thickness in the longitudinal direction changes after the same machine coater is used for a period of time. Therefore, how to ensure that the thickness of the extrusion coater in the longitudinal direction is basically consistent is an urgent problem to be solved in the electrode material coating industry.
Disclosure of Invention
In order to solve the above-described problems, the present invention provides a method for coating an electrode material that can achieve a substantially uniform thickness of the electrode material of an electrode sheet in a longitudinal direction, a precision programmable coating feeding valve, and a coating head thereof.
The technical scheme of the invention is as follows: providing a method for coating an electrode material using an extrusion coating head having a programmable throughput valve, wherein the throughput valve is controlled by a control module;
the method comprises the following steps:
s1, the control module controlling the throughput valve to perform a material-regurgitation operation at a thick portion and a material-regurgitation operation at a thin portion according to a predetermined data on a change rule of a coating thickness of the electrode sheet in a longitudinal direction during one cycle;
s2, the throughput valve being configured to reduce a difference between a throughput and a throughput of the throughput to zero on a same cycle of electrode chip coating, and finally, returning a metering piston of the throughput valve to a start position;
s3, stopping coating at a preset distance to form a blank belt;
s4, repeating the steps S1-S3 to coat the electrode material in the next period;
and S5, repeating the step S4 until the coating is finished.
As an improvement to the present invention, the step S1 is preceded by the following steps:
s101, taking a plurality of thickness detection points at preset intervals from a starting point to an end point in the longitudinal direction on a dried electrode sheet coated by the same extrusion coating head, and measuring the thickness of the thickness detection points;
and S102, corresponding each thickness detection point to the detected thickness data one by one, establishing data of the coating thickness change rule of the electrode plate in the longitudinal direction, and storing for later use.
The invention also provides a precise program-controlled coating and feeding abruption valve which comprises a valve body, a linear driving device, a metering piston and a control module, wherein the metering piston is arranged in the valve body and driven by the linear driving device, the control module is electrically connected with the linear driving device, and the control module controls the abruption valve to perform material abruption action at a thick part and perform material abruption action at a thin part according to the data of the coating thickness change rule of the electrode slice in the longitudinal direction within one period measured in advance.
As an improvement of the present invention, the linear driving device is a servo linear motor or a linear driving mechanism driven by a servo rotary motor.
As an improvement to the present invention, the linear drive mechanism is a linear nut mechanism.
The invention also provides a precision program-controlled extrusion coating head for coating and feeding, which comprises an extrusion coating head main body, wherein the aforementioned material-collecting and discharging valve is arranged below the material-storing cavity at the lower lip of the extrusion head of the extrusion coating head main body, and the material-collecting and discharging channel of the material-collecting and discharging valve is communicated with the material-storing cavity.
As an improvement of the invention, the extrusion coating head main body comprises an extrusion head upper lip and an extrusion head lower lip, an extrusion channel is arranged between the extrusion head upper lip and the extrusion head lower lip, and the extrusion channel is communicated with a material storage cavity arranged in the extrusion head lower lip.
According to the invention, the control module is adopted to control the material regurgitation valve to perform the material regurgitation action at the thick part and the material regurgitation action at the thin part according to the data of the coating thickness change rule of the electrode slice in the longitudinal direction within one period, which is measured in advance; the present invention is characterized in that the optical output valve draws back excess electrode material at a thick portion to make the thickness of the thick portion equal to a standard thickness and supplies electrode material at a thin portion to make the thickness of the thin portion equal to the standard thickness during the same cycle of electrode sheet coating, thereby providing an advantage of substantially uniform thickness of the electrode material of the electrode sheet in the longitudinal direction.
Drawings
FIG. 1 is a schematic block diagram of the process of the present invention.
Fig. 2 is a block diagram of the method of fig. 1, which is further complementary to the method.
Fig. 3 is a schematic longitudinal cross-sectional view of the electrode sheet when the electrode sheet is thick.
Fig. 4 is an enlarged schematic view of a structure at a in fig. 3.
FIG. 5 is a schematic longitudinal cross-sectional view of the electrode sheet with a thick head and a groove in the middle.
Fig. 6 is a diagrammatic illustration of a level of throughput and a level of throughput of a corresponding output valve of fig. 5.
Fig. 7 is a schematic diagram of a configuration of a throughput valve according to the present invention.
Fig. 8 is a schematic view of the structure of the coating head of the present invention.
Detailed Description
Referring to fig. 1 and 2, fig. 1 and 2 disclose a method for coating an electrode material using an extrusion coating head with a programmable flow-control valve controlled by a control module;
the method comprises the following steps:
s1, the control module controlling the throughput valve to perform a material-regurgitation operation at a thick portion and a material-regurgitation operation at a thin portion according to a predetermined data on a change rule of a coating thickness of the electrode sheet in a longitudinal direction during one cycle;
s2, the throughput valve being configured to return to a starting level on a level of a throughput of the throughput valve being zero on a same cycle of electrode chip coating;
as shown in fig. 3 and 4, the dashed line in fig. 3 is the designed electrode material thickness 32, the material belt advances along the arrow 30 direction, when the coating is started, a convex strip 31 along the transverse direction is formed at the starting end for various reasons, the industry is commonly called the head thickness, the longitudinal section of the convex strip 31 is in the shape of a circular arc, and the material throughput of the exhaust valve is equal to the product of the area of the longitudinal section of the convex strip 31 multiplied by the length of the transverse direction; for accurate performance of the data-reception, the rib 31 may be divided into a plurality of segments 311, as shown in fig. 4, wherein the control module controls a flow-control valve to gradually divide the data-reception for each segment 311; after the material collection is completed, the material is slowly and evenly regurgitated to the electrode segments behind the raised strips 31, so that the thickness of the electrode material of the following electrode segments is basically equal to the designed thickness 32 of the electrode material (through experiments, because slow and even regurgitation is adopted, the thickness of the electrode material of the following electrode segments is basically equal to the designed thickness 32 of the electrode material, the design requirement can be met), and the measurement piston of the material collection valve returns to the start position after the material collection is completed, so that the next smoking action can be facilitated; in summary, in this step, when only one rib 31 is present during coating, a material-gating operation is performed on the rib 31, followed by a gradual and even feedback of the material to the electrode segments following the rib 31, and finally a returning of the metering piston of the gating valve to the start position.
Referring to fig. 5 and 6, fig. 5 and 6 disclose that during the coating process, both the rib 31 may be present, and the first groove 33 and the second groove 34 may be present, wherein the rib 31 may require a throughput V0, the first groove 33 may be a first throughput V1 requiring throughput, and the second groove 34 may be a second throughput V2 requiring throughput (of course, the throughput V0 may be plural, or one or more throughput may be possible). In the present invention, only one rib 31 and two grooves are used to describe the relationship between the throughput and the throughput of the present invention. As shown in fig. 5 and 6, in the present embodiment, the rib 31 may correspond to a throughput V0 equal to the sum of a first throughput V1 and a second throughput V2, and when coated, the rib 31 may extend into a corresponding electrode material according to the electrode length occupied by the rib 31, and when the electrode is coated with respect to the first groove 33, the rib may discharge the first throughput V1 to fill the first groove 33 with the designed electrode material thickness 32; when the electrode is coated on the opposing second groove 34, the valve may output a second output V2 to fill the second groove 34 to the design electrode material thickness 32, and finally, the metering piston of the valve may revert to the starting position. The above-described method is suitable for a capacity V0 equal to the throughput, i.e., a capacity V0 as the throughput, and finally, a metering piston of the throughput valve is configured to revert to an initial position.
While the above analysis shows that the throughput V0 is equal to the sum of the first throughput V1 and the second throughput V2, the present invention is also suitable for throughput V0 which is greater than the sum of the first throughput V1 and the second throughput V2; or the throughput V0 is less than the sum of the first throughput V1 and the second throughput V2.
When the throughput V0 is greater than the sum of the first throughput V1 and the second throughput V2, the excess throughput V0 minus the sum of the first throughput V1 and the second throughput V2 may be evenly distributed over a length of the electrode minus the throughput V0, a length of the first throughput V1 and a length of the electrode remaining after the throughput V2, and finally the metering piston of the metering valve may be returned to the start position; the method is suitable for situations where the throughput V0 is greater than the throughput. I.e. the difference between the throughput and the throughput is evenly distributed over the entire electrode length minus the throughput V0, the remaining electrode length after the throughput, and finally the metering piston of the throughput valve is returned to its start position.
When the throughput V0 is less than the sum of the first throughput V1 and the second throughput V2, the throughput of the sum of the first throughput V1 and the second throughput V2 minus the throughput V0 may be averaged over the entire electrode length minus the throughput V0, over a length corresponding to the first throughput V1 and over a remaining electrode length following the length corresponding to the second throughput V2, and finally the metering piston of the metering valve may revert to the start position; the method is suitable for a capacity of throughput V0 being smaller than capacity, i.e. the capacity of throughput less the capacity is measured, and the capacity of the metering piston is averaged over the entire electrode length minus the capacity V0 and the remaining electrode length over the capacity corresponding to the capacity, and finally the capacity is returned to the start position.
S3, stopping coating at a preset distance to form a blank belt;
s4, repeating the steps S1-S3 to coat the electrode material in the next period;
and S5, repeating the step S4 until the coating is finished.
As an improvement to the present invention, the step S1 is preceded by the following steps:
s101, taking a plurality of thickness detection points at preset intervals from a starting point to an end point in the longitudinal direction on a dried electrode sheet coated by the same extrusion coating head, and measuring the thickness of the thickness detection points;
and S102, corresponding each thickness detection point to the detected thickness data one by one, establishing data of the coating thickness change rule of the electrode plate in the longitudinal direction, and storing for later use.
The invention also provides a precise program-controlled coating and feeding abruption and discharge valve, which comprises a valve body 1, a linear driving device 2, a metering piston 3 and a control module 4, wherein the metering piston 3 and the control module 4 are arranged in the valve body 1 and driven by the linear driving device 2, the control module 4 is electrically connected with the linear driving device 2, and the control module 4 controls the abruption and discharge valve to perform material regurgitation at a thick part and material spitting at a thin part according to the data of the coating thickness change rule of an electrode slice in one period measured in advance in the longitudinal direction; the channel may have a zero difference between a throughput and a throughput of the channel during a same cycle of electrode sheet coating.
The valve body 1 is a revolving body formed by revolving a section with an I-shaped section, and the center hole 11 is positioned at the center of the I-shaped section.
Preferably, the linear drive 2 is a servo linear motor.
The linear driving device 2 is composed of a servo rotating motor and a linear driving mechanism driven by the servo rotating motor.
Preferably, the linear drive mechanism is a linear nut mechanism.
The present invention further provides a precision programmable extrusion coating head for coating and feeding, comprising an extrusion coating head main body 20, wherein the aforementioned optical throughput valve 10 is disposed below a material storage chamber 211 of a lower lip 21 of the extrusion head main body 20, and a material output channel 11 of the optical throughput valve 10 is communicated with the material storage chamber 211; the storage chamber 211 is connected to a feed pump (not shown) via a feed pipe 212.
Preferably, the extrusion coating head body 20 comprises an extrusion head upper lip 22 and an extrusion head lower lip 21, an extrusion channel 23 is arranged between the extrusion head upper lip 22 and the extrusion head lower lip 21, and the extrusion channel 23 is communicated with a material storage cavity 211 arranged in the extrusion head lower lip 21.
Claims (9)
1. A method for coating an electrode material, characterized by: employing an extrusion coating head with a programmable throughput valve, wherein the throughput valve is controlled by a control module;
the method comprises the following steps:
s1, the control module controlling the throughput valve to perform a material-regurgitation operation at a thick portion and a material-regurgitation operation at a thin portion according to a predetermined data on a change rule of a coating thickness of the electrode sheet in a longitudinal direction during one cycle;
s2, the throughput valve being configured to reduce a difference between a throughput and a throughput of the throughput to zero on a same cycle of electrode chip coating, and finally, returning a metering piston of the throughput valve to a start position;
s3, stopping coating at a preset distance to form a blank belt;
s4, repeating the steps S1-S3 to coat the electrode material in the next period;
and S5, repeating the step S4 until the coating is finished.
2. The method for coating an electrode material according to claim 1, characterized in that: the step of S1 is preceded by the steps of:
s101, taking a plurality of thickness detection points at preset intervals from a starting point to an end point in the longitudinal direction on a dried electrode sheet coated by the same extrusion coating head, and measuring the thickness of the thickness detection points;
and S102, corresponding each thickness detection point to the detected thickness data one by one, establishing data of the coating thickness change rule of the electrode plate in the longitudinal direction, and storing for later use.
3. The method for coating an electrode material according to claim 1 or 2, characterized in that: the step S2 is specifically divided into: (1) and, during coating, performing a material-gating operation on the rib, followed by slowly and evenly returning the material to an electrode segment following the rib, and finally returning the metering piston of the gating valve to a start position, if only the rib is present; or, (2) when the throughput is equal to the throughput, a corresponding electrode material may be received on a side of the metering piston corresponding to the groove on a side of the metering piston corresponding to the rib; or (3) when the throughput is greater than the throughput, evenly distributing an excess of a difference between the throughput and the throughput over a length of the electrode remaining after subtracting a length corresponding to the throughput and a length corresponding to the throughput from a total length of the electrode, and returning a metering piston of the throughput to a starting position; alternatively, (4) when the throughput is less than the throughput, a remaining electrode length segment after the throughput is subtracted from the total electrode length by a length corresponding to the throughput and a length corresponding to the throughput is considered to be an average throughput as an throughput, and finally, a metering piston of the throughput valve is returned to the start position.
4. A precision programmable coating throughput valve for implementing the method of coating an electrode material of claim 1, wherein the valve comprises: the measuring valve comprises a valve body (1), a linear driving device (2), a measuring piston (3) which is arranged in a middle hole (11) of the valve body (1) and driven by the linear driving device (2), and a control module (4), wherein the control module (4) is electrically connected with the linear driving device (2), and the control module (4) controls the material gathering and discharging valve to perform the material gathering action at a thick position and the material discharging action at a thin position according to the data of the coating thickness change rule of an electrode slice in one period measured in advance in the longitudinal direction.
5. The precision programmable throughput valve of claim 4, wherein: the valve body (1) is a revolving body formed by revolving a section with an I-shaped section, wherein the middle hole (11) is positioned in the center of the I-shaped section.
6. The precision programmable throughput valve of claim 4 or 5, wherein: the linear driving device (2) is a servo linear motor or a linear driving mechanism driven by a servo rotating motor.
7. The precision programmable throughput valve of claim 6, wherein: the linear drive mechanism is a linear nut mechanism.
8. A precision programmable extrusion coating head useful for coating feeds for implementing the method of coating electrode materials of claim 1, characterized in that: comprising an extrusion coating head body (20), a throughput valve (10) according to any one of claims 4 to 6 being arranged below a storage chamber (211) of a lower lip (21) of an extrusion head of the extrusion coating head body (20), a throughput channel (11) of the throughput valve (10) being in communication with the storage chamber (211).
9. A precision programmable extrusion coating head useful for coating a feed according to claim 8, wherein: extrusion coating head main part (20) are including extrusion head upper lip (22) and extrusion head lower lip (21), have extrusion passageway (23) between extrusion head upper lip (22) and the extrusion head lower lip (21), extrusion passageway (23) and the material chamber (211) intercommunication of depositing that sets up in extrusion head lower lip (21).
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111557036.6A CN114226164A (en) | 2021-12-18 | 2021-12-18 | Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof |
| CN202211386636.5A CN115646747A (en) | 2021-12-18 | 2022-11-07 | Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111557036.6A CN114226164A (en) | 2021-12-18 | 2021-12-18 | Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof |
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| Publication Number | Publication Date |
|---|---|
| CN114226164A true CN114226164A (en) | 2022-03-25 |
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| CN202111557036.6A Withdrawn CN114226164A (en) | 2021-12-18 | 2021-12-18 | Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof |
| CN202211386636.5A Pending CN115646747A (en) | 2021-12-18 | 2022-11-07 | Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202211386636.5A Pending CN115646747A (en) | 2021-12-18 | 2022-11-07 | Method for coating electrode material, and precision programmable coating feeding abruption valve and coating head thereof |
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| CN (2) | CN114226164A (en) |
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2021
- 2021-12-18 CN CN202111557036.6A patent/CN114226164A/en not_active Withdrawn
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2022
- 2022-11-07 CN CN202211386636.5A patent/CN115646747A/en active Pending
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| CN101279315A (en) * | 2007-04-06 | 2008-10-08 | 中外炉工业株式会社 | Intermittent coating method and apparatus |
| CN110000050A (en) * | 2013-12-06 | 2019-07-12 | 武藏工业株式会社 | Liquid material application device |
| CN110382123A (en) * | 2017-03-17 | 2019-10-25 | 株式会社斯库林集团 | Applying device and coating method |
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