CN103828811A - Pesticide composition containing fenhexamid and fluazinam - Google Patents
Pesticide composition containing fenhexamid and fluazinam Download PDFInfo
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- CN103828811A CN103828811A CN201310634440.8A CN201310634440A CN103828811A CN 103828811 A CN103828811 A CN 103828811A CN 201310634440 A CN201310634440 A CN 201310634440A CN 103828811 A CN103828811 A CN 103828811A
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- fluazinam
- fenhexamid
- pesticide
- pesticide composition
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- 239000005776 Fenhexamid Substances 0.000 title claims abstract description 49
- 239000005780 Fluazinam Substances 0.000 title claims abstract description 49
- VDLGAVXLJYLFDH-UHFFFAOYSA-N fenhexamid Chemical compound C=1C=C(O)C(Cl)=C(Cl)C=1NC(=O)C1(C)CCCCC1 VDLGAVXLJYLFDH-UHFFFAOYSA-N 0.000 title claims abstract description 49
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 239000000575 pesticide Substances 0.000 title claims abstract description 26
- 241000607479 Yersinia pestis Species 0.000 claims description 3
- 239000004480 active ingredient Substances 0.000 claims description 2
- 201000010099 disease Diseases 0.000 abstract description 12
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 4
- 230000002411 adverse Effects 0.000 abstract description 3
- 230000002265 prevention Effects 0.000 abstract 2
- 239000003814 drug Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000009472 formulation Methods 0.000 description 8
- 239000000375 suspending agent Substances 0.000 description 8
- 241000123650 Botrytis cinerea Species 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 229920001732 Lignosulfonate Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000004562 water dispersible granule Substances 0.000 description 6
- 241000227653 Lycopersicon Species 0.000 description 5
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 5
- 238000009736 wetting Methods 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007884 disintegrant Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- 206010059866 Drug resistance Diseases 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- QFUSCYRJMXLNRB-UHFFFAOYSA-N 2,6-dinitroaniline Chemical class NC1=C([N+]([O-])=O)C=CC=C1[N+]([O-])=O QFUSCYRJMXLNRB-UHFFFAOYSA-N 0.000 description 1
- 241001465180 Botrytis Species 0.000 description 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- 241000233629 Phytophthora parasitica Species 0.000 description 1
- 241000233626 Plasmopara Species 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241000813090 Rhizoctonia solani Species 0.000 description 1
- 241000221662 Sclerotinia Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000008056 dicarboxyimides Chemical class 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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Abstract
The invention discloses a pesticide composition containing fenhexamid and fluazinam. The pesticide composition comprises common assistants, fenhexamid and fluazinam. A weight part ratio of fenhexamid to fluazinam is in a range of 15: 1 to 1: 15. The pesticide composition is suitable for prevention and control of diseases of crops and especially has good effects of prevention and treatment on Botryis cinerea-caused gray mold of various crops. Compared with a single-component pesticide, the pesticide composition has obvious synergism, reduces a pesticide use amount, reduces a pesticide use cost, prolongs a pesticide service life and reduces the adverse influences caused by the pesticide on the ecological environment.
Description
Technical field
The composition pesticide the present invention relates to, is taking fenhexamid and fluazinam as active ingredient, is applicable to prevent and treat crop pest, is particularly useful for preventing and treating crop gray mold.
Background technology
In crop growth process, be easily subject to various diseases and contaminate, particularly fungal disease, its kind is many, causes harm serious.The gray mold that Botrytis cinerea can cause various plants, causes the underproduction.
For a long time, chemical control is to prevent and treat the main effective means of crop pest.But, due to single drug and not Scientific Usage of Drugs for a long time, cause pathogen to produce resistance to the agricultural chemicals of current use, using dosage and medication number of times increase the development that is still difficult to effectively control disease year by year, the harm of ecotope is also being increased, meanwhile, also difficult secure to the safety of crop.
Fenhexamid is mainly the synthetic of check melanin and promotes the generation of plant antibiotic, is mainly used in rice field control rice blast, various gray mold and relevant stalk break, black spot etc.Gray mold is had to special efficacy.
Fluazinam belongs to 2, 6-dinitroanilines, for methionine biosynthesis inhibitor, there is protection, treatment, blade penetrates and root systemic activity, product are to interlink spore genus, Botrytis, Phytophthora, Plasmopara, Sclerotinia and black to cultivate Pseudomonas bacterium very effective, Botrytis cinerea to anti-benzimidazole type and dicarboximide class biocide agent also has good result, resistance of rainwater washing against, lasting period is long, have the effect of good planting property of control food mite class concurrently, crucifer club root is also had to remarkable preventive effect, to also having good preventive effect by the microbial paddy rice damping off of head mold.
The mixture of different pesticide species is common methods of the agriculture resistance disease of control.Screening by formulation of pesticide, filter out rational formula, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the generation of disease drug resistance, is the important means of the disease comprehensive regulation.Fenhexamid and fluazinam mixture have obvious synergistic effect.
Summary of the invention
The technical problem that the present invention need solve is: overcome that in prior art, dosage is large, cost is high, large to ecotope harm, to shortcomings such as crop safety are low, provide a kind of efficient, safety, low toxicity and lasting period long, be conducive to the composition pesticide that contains fenhexamid and fluazinam of comprehensive regulation crop grey mold disease.
For addressing the above problem, the technical solution adopted in the present invention is: a kind of composition pesticide that contains fenhexamid and fluazinam, comprise usual auxiliaries, fenhexamid and fluazinam, and the ratio of weight and number of fenhexamid and fluazinam is 15:1-1:15.
Composition pesticide of the present invention can, according to well known to a person skilled in the art method, be mixed with the application forms of the applicable agricultural uses such as suspending agent, water dispersible granules, wetting powder.
Composition pesticide of the present invention also contains the usual auxiliaries of pesticidal preparations, comprise one or more mixing in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, defoamer, antifreezing agent, disintegrant, binding agent, filler, filler, medium etc., be known substance, various auxiliary agents conventional in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
Composition pesticide of the present invention, for preventing and treating the plant disease in agricultural, is particularly useful for preventing and treating gray mold.
, in the time of application, should there is early stage or the use of disease initial stage of origination in disease in composition pesticide of the present invention.
Composition pesticide of the present invention, adopts the method for spraying to use conventionally, also can adopt as required other operation techniques of the upper application of agricultural.
Composition pesticide provided by the invention has following beneficial effect:
1, composition pesticide provided by the invention, in certain ratio range, show obvious synergistic effect, the control efficiency of composition is significantly improved than single dose, has reduced the using dosage of agricultural chemicals, reduce drug cost, reduced the adverse effect of agricultural chemicals to ecotope;
2, the combination of two kinds of bactericide of the present invention, has expanded fungicidal spectrum;
3, two of composition pesticide provided by the invention kinds of effective ingredient mechanism of action are different, can overcome the long-term single shortcoming that makes with medicament easily produce resistance, extend the service life of medicament, to the comprehensive regulation important in inhibiting of disease.
Brief description of the drawings
Fig. 1 is the synergy actual measurement to Botrytis cinerea of fenhexamid and fluazinam and theoretical equivalent line chart (fenhexamid and the fluazinam mixture equivalent line to Botrytis cinerea, series 1 is mixture equivalent line, serial 2 is theoretical equivalent line).
embodiment
In order to understand better essence of the present invention, be described further by following examples, but the present invention is not limited to these embodiment.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
Example of formulations 1:(40% fenhexamid fluazinam suspending agent)
Following material is all weight percentage: fenhexamid 20%, fluazinam 20%, lignosulfonates 3%, calcium dodecyl benzene sulfonate 3%, xanthan gum 0.1%, empgen BB 5%, fatty alcohol-polyoxyethylene ether 5%, glycerine 5%, gum Arabic 0.1%, deionized water complements to 100%, and above-mentioned formula is pulverized in proportion in advance, add in sand mill and grind again, after high shear mixing, allotment makes 40% fenhexamid fluazinam suspending agent.
Example of formulations 2:(30% fenhexamid fluazinam suspending agent)
Following material is all weight percentage: fenhexamid 24%, fluazinam 6%, lignosulfonates 3%, calcium dodecyl benzene sulfonate 3%, xanthan gum 0.1%, empgen BB 5%, fatty alcohol-polyoxyethylene ether 5%, glycerine 5%, gum Arabic 0.1%, deionized water complements to 100%, and above-mentioned formula is pulverized in proportion in advance, add in sand mill and grind again, after high shear mixing, allotment makes 30% fenhexamid fluazinam suspending agent.
Example of formulations 3:(60% fenhexamid fluazinam water dispersible granules)
Following material is all weight percentage: fenhexamid 15%, fluazinam 45%, lauryl sodium sulfate 6%, dispersant lignosulfonates 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stable meltable starch 3%, kaolin complements to 100%, and by above-mentioned formula, 60% fenhexamid fluazinam water dispersible granules is made and obtained in dry pulverization process, granulation, dry, screening in proportion.
Example of formulations 4:(50% fenhexamid fluazinam water dispersible granules)
Following material is all weight percentage: fenhexamid 13%, fluazinam 37%, lauryl sodium sulfate 6%, dispersant lignosulfonates 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stable meltable starch 3%, kaolin complements to 100%, and by above-mentioned formula, 50% fenhexamid fluazinam water dispersible granules is made and obtained in dry pulverization process, granulation, dry, screening in proportion.
Example of formulations 5:(50% fenhexamid fluazinam wetting powder)
Following material is all weight percentage: fenhexamid 20%, and fluazinam 30%, pulls open powder 3%, lignosulfonates 6%, talcum powder 15%, kaolin complements to 100%.Above-mentioned formula is entered in blender after coarse crushing and mixed in proportion, then after air-flow crushing, make 50% fenhexamid fluazinam wetting powder.
Example of formulations 6:(40% fenhexamid fluazinam wetting powder)
Following material is all weight percentage: fenhexamid 12%, and fluazinam 28%, pulls open powder 3%, lignosulfonates 6%, talcum powder 15%, kaolin complements to 100%.Above-mentioned formula is entered in blender after coarse crushing and mixed in proportion, then after air-flow crushing, make 40% fenhexamid fluazinam wetting powder.
Biologicall test embodiment 1: Toxicity Determination test
For further understanding fenhexamid and the virulence of fluazinam mixture to Rhizoctonia solani Kuhn, the inventor has carried out a large amount of formulation screening tests to fenhexamid and fluazinam mixture.
Table 1, fenhexamid and fluazinam and mixture thereof the Toxicity Determination result to Botrytis cinerea
See Fig. 1, fenhexamid and fluazinam synergy actual measurement and the theoretical equivalent line (Fig. 1 data come from table 1) to Botrytis cinerea.
As shown in Figure 1, actual measurement equivalent line series 1 is under theoretical equivalent line series 2, and fluazinam and fenhexamid are composite shows obvious synergistic effect to Botrytis cinerea.
Biologicall test embodiment 2: the field control effectiveness test of control graw mold of tomato.
Reagent agent and dispenser dosage:
(1) 40% fenhexamid fluazinam suspending agent (fenhexamid 20%: fluazinam 20%), mu 25 grams, preparation (1#)
(2) 50% fenhexamid fluazinam water dispersible granules ((fenhexamid 13%: fluazinam 37%), mu 20 grams, preparation (2#);
Contrast medicament and dispenser dosage:
(1) 50% fenhexamid suspending agent, mu 30 grams, preparation (3#);
(2) 50% fluazinam suspending agents, mu 35 grams, preparation (4#).
Spraying time and application method: graw mold of tomato their early stage, is watered even spraying.
Result of the test: in table 1, as can be seen from the test results: after dispenser 14 days, fluazinam of the present invention and fenhexamid mixture composition to graw mold of tomato preventive effect all more than 90%, significantly better than the single dose of contrast; After dispenser 21 days, fluazinam of the present invention and fenhexamid mixture composition to graw mold of tomato preventive effect all more than 93%, also significantly better than the single dose of contrast; In process of the test, each medicament is showed no poisoning generation.Illustrate that fluazinam of the present invention and fenhexamid mixture composition are better than single dose, improve actual control efficiency, reduce dosage, reduce costs, reduce the adverse effect of medicament to environment, delay the generation of disease drug resistance, agricultural synthesis is administered and had great significance.
The field control effectiveness test result of table 2, control graw mold of tomato.
Claims (2)
1. a composition pesticide that contains fenhexamid and fluazinam, is characterized in that: active ingredient is fenhexamid and fluazinam, and the part by weight of fenhexamid and fluazinam is 15:1～1:15.
2. a kind of composition pesticide that contains fenhexamid and fluazinam according to claim 1, is characterized in that: be applicable to prevent and treat crop pest, be particularly useful for preventing and treating crop gray mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310634440.8A CN103828811A (en) | 2013-11-28 | 2013-11-28 | Pesticide composition containing fenhexamid and fluazinam |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310634440.8A CN103828811A (en) | 2013-11-28 | 2013-11-28 | Pesticide composition containing fenhexamid and fluazinam |
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| Publication Number | Publication Date |
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| CN103828811A true CN103828811A (en) | 2014-06-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310634440.8A Pending CN103828811A (en) | 2013-11-28 | 2013-11-28 | Pesticide composition containing fenhexamid and fluazinam |
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| Country | Link |
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| CN (1) | CN103828811A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016203154A1 (en) * | 2015-06-19 | 2016-12-22 | Phyteurop S.A. | Process for treating perennial plant wood diseases |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094221A (en) * | 1993-04-28 | 1994-11-02 | 拜尔公司 | Composition of fungicidally active compounds |
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2013
- 2013-11-28 CN CN201310634440.8A patent/CN103828811A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1094221A (en) * | 1993-04-28 | 1994-11-02 | 拜尔公司 | Composition of fungicidally active compounds |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016203154A1 (en) * | 2015-06-19 | 2016-12-22 | Phyteurop S.A. | Process for treating perennial plant wood diseases |
| FR3037479A1 (en) * | 2015-06-19 | 2016-12-23 | Phyteurop S A | PROCESS FOR TREATING WOOD DISEASES OF PERENNIAL PLANTS |
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Application publication date: 20140604 |