CN103098817B - The composition pesticide of biguanides three octyl benzene sulfonate and tpn - Google Patents
The composition pesticide of biguanides three octyl benzene sulfonate and tpn Download PDFInfo
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- CN103098817B CN103098817B CN201210583624.1A CN201210583624A CN103098817B CN 103098817 B CN103098817 B CN 103098817B CN 201210583624 A CN201210583624 A CN 201210583624A CN 103098817 B CN103098817 B CN 103098817B
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- biguanides
- benzene sulfonate
- tpn
- octyl benzene
- composition pesticide
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- 229940123208 Biguanide Drugs 0.000 title claims abstract description 50
- GVMDZMPQYYHMSV-UHFFFAOYSA-N octyl benzenesulfonate Chemical compound CCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVMDZMPQYYHMSV-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 150000004283 biguanides Chemical class 0.000 title claims abstract description 45
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 239000000575 pesticide Substances 0.000 title claims abstract description 16
- 244000052769 pathogen Species 0.000 claims abstract description 7
- 230000001717 pathogenic effect Effects 0.000 claims abstract description 7
- 241000235349 Ascomycota Species 0.000 claims abstract description 6
- 241000233866 Fungi Species 0.000 claims abstract description 6
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 4
- 238000009472 formulation Methods 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims 1
- 239000005747 Chlorothalonil Substances 0.000 abstract description 11
- -1 chlorothalonil compound Chemical class 0.000 abstract description 7
- 239000003814 drug Substances 0.000 abstract description 5
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 230000009977 dual effect Effects 0.000 abstract description 3
- 230000000474 nursing effect Effects 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 229940079593 drug Drugs 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 229920001732 Lignosulfonate Polymers 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical group NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 description 4
- 240000008067 Cucumis sativus Species 0.000 description 4
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 241000213004 Alternaria solani Species 0.000 description 3
- 241000198596 Alternaria tomatophila Species 0.000 description 3
- 241000221785 Erysiphales Species 0.000 description 3
- 238000003556 assay Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- XDQUZFWEORJPTA-UHFFFAOYSA-N C(CCCCCCC)C1=C(C2=C(N=C(N2)S(=O)(=O)O)C=C1)C1=CC=CC=C1 Chemical class C(CCCCCCC)C1=C(C2=C(N=C(N2)S(=O)(=O)O)C=C1)C1=CC=CC=C1 XDQUZFWEORJPTA-UHFFFAOYSA-N 0.000 description 1
- 241000227653 Lycopersicon Species 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the composition pesticide of a kind of biguanides three octyl benzene sulfonate and tpn, the ratio of weight and number of biguanides three octyl benzene sulfonate and tpn is 15:1 ~ 1:20, preferred weight portion rate is 5:1 ~ 1:9, and biguanides three octyl benzene sulfonate and the percentage by weight of tpn weight summation in composition pesticide are 30 ~ 80%.Have obvious synergistic effect after biguanides three octyl benzene sulfonate and chlorothalonil compound, compound drug effective ingredient consumption ratio is used alone obvious minimizing, effectively can protect crop, treat dual nursing.Be applicable to prevent and treat the crop pest caused by pathogen sac fungi, imperfect fungus.
Description
Technical field
The composition pesticide that the present invention relates to, be with biguanides three octyl benzene sulfonate and tpn for active ingredient, be applicable to prevent and treat the crop pest caused by pathogen sac fungi, imperfect fungus.
Background technology
Biguanides three octyl benzene sulfonate, chemical name: 1,1-octyl group methylene biguanides three octyl phenylbenzimidazole sulfonic acid salt.Biguanides three octyl benzene sulfonate is wide spectrum, low toxicity bactericide, and suppress the biosynthesis of germ quasi-grease compound, local permeability is strong, has very high growth inhibitory activity to pathogen sac fungi, imperfect fungus.
Tpn, chloro-1, the 3-dicyanobenzenes of chemical name: 2,4,5,6-tetra-.Tpn is protective fungicide, does not have Inner to inhale conduction, has good control efficiency to multiple by the fungus-caused plant disease of pathogen.
The same with other bactericide, there is resistance risk in long-term single use tpn or biguanides three octyl benzene sulfonate.
Have no the report of biguanides three octyl benzene sulfonate and chlorothalonil compound at present.
Summary of the invention
The object of this invention is to provide a kind of efficient, low toxicity, low-residual, to the composition pesticide that Environmental compatibility is good, cost is lower, active ingredient is biguanides three octyl benzene sulfonate and tpn.
Technical scheme of the present invention: the composition pesticide of a kind of biguanides three octyl benzene sulfonate and tpn, the ratio of weight and number of biguanides three octyl benzene sulfonate and tpn is 15:1 ~ 1:20, preferred weight portion rate is 5:1 ~ 1:9, and biguanides three octyl benzene sulfonate and the percentage by weight of tpn weight summation in composition pesticide are 30 ~ 80%.
Composition pesticide of the present invention according to well known to a person skilled in the art method, can be selected known pesticidal preparations auxiliary element, being mixed with Multiple Pesticides formulation.In the present invention, water dispersible granules, wetting powder or suspending agent is preferably mixed with.
The pesticidal preparations auxiliary element used in composition pesticide of the present invention comprise solvent, dispersant, stabilizing agent, emulsifier, antifreezing agent, thickener etc. and other to be of value to active ingredient stable and play the known substance of drug effect in the formulation, all various compositions that are conventional in pesticidal preparations or permission use, be not particularly limited, concrete composition and consumption are determined by test according to recipe requirements.
Advantage of the present invention is: the composition pesticide of biguanides three octyl benzene sulfonate and chlorothalonil compound; good preventive effect is had to the crop pest caused by pathogen sac fungi, imperfect fungus; there is provided protection to crop, treat dual nursing; and drug-fast generation can be delayed, the lasting period is long, decreases dosage and access times; cost-saving; easy to use, time and labour saving, environmentally friendly.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
example of formulations 1: 40% biguanides three octyl benzene sulfonate tpn suspending agent.
Biguanides three octyl benzene sulfonate 15%, tpn 25%, lignosulfonates (sodium, calcium) 5%, calcium dodecyl benzene sulfonate 3%, xanthan gum 0.1%, empgen BB 5%, glycerine 5%, gum Arabic 0.1%.Deionized water complements to 100%.Above-mentioned formula is pulverized in proportion in advance, then adds in sand mill and grind, the obtained 40% biguanides three octyl benzene sulfonate tpn suspending agent of allotment after high shear mixing.
example of formulations 2: 20% biguanides three octyl benzene sulfonate tpn suspending agent.
Biguanides three octyl benzene sulfonate 8%, tpn 12%, lignosulfonates (sodium, calcium) 5%, calcium dodecyl benzene sulfonate 3%, xanthan gum 0.1%, empgen BB 5%, glycerine 5%, gum Arabic 0.1%.Deionized water complements to 100%.Above-mentioned formula is pulverized in proportion in advance, then adds in sand mill and grind, the obtained 20% biguanides three octyl benzene sulfonate tpn suspending agent of allotment after high shear mixing.
example of formulations 3: 60% biguanides three octyl benzene sulfonate chlorothalonil water dispersible granule.
Biguanides three octyl benzene sulfonate 15%, tpn 45%, lauryl sodium sulfate 6%, dispersant lignosulfonates (sodium, calcium) 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stable meltable starch 3%, kaolin complements to 100%.By above-mentioned formula, 60% biguanides three octyl benzene sulfonate chlorothalonil water dispersible granule is made and is obtained in dry pulverization process, granulation, drying, screening in proportion.
example of formulations 4: 50% biguanides three octyl benzene sulfonate chlorothalonil water dispersible granule.
Biguanides three octyl benzene sulfonate 10%, tpn 40%, lauryl sodium sulfate 6%, dispersant lignosulfonates (sodium, calcium) 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stable meltable starch 3%, kaolin complements to 100%.By above-mentioned formula, 50% biguanides three octyl benzene sulfonate chlorothalonil water dispersible granule is made and is obtained in dry pulverization process, granulation, drying, screening in proportion.
example of formulations 5: 50% biguanides three octyl benzene sulfonate tpn wetting powder.
Biguanides three octyl benzene sulfonate 10%, tpn 40%, pulls open powder 3%, and lignosulfonates (sodium, calcium) 6%, talcum powder 15%, kaolin complements to 100%.Mix entering in blender after above-mentioned formula in proportion coarse crushing, more namely obtain 50% biguanides three octyl benzene sulfonate tpn wetting powder after air-flow crushing.
example of formulations 6: 60% biguanides three octyl benzene sulfonate tpn wetting powder.
Biguanides three octyl benzene sulfonate 18%, tpn 42%, pulls open powder 3%, and lignosulfonates (sodium, calcium) 6%, talcum powder 15%, kaolin complements to 100%.Mix entering in blender after above-mentioned formula in proportion coarse crushing, more namely obtain 60% biguanides three octyl benzene sulfonate tpn wetting powder after air-flow crushing.
assays Example 1:biguanides three octyl benzene sulfonate tpn is to the Toxicity Determination of alternaria solani sorauer.
Table 1, biguanides three octyl benzene sulfonate tpn are to the Toxicity Determination result of alternaria solani sorauer.
As shown in Table 1, the bactericidal composition of biguanides three octyl benzene sulfonate of the present invention and chlorothalonil compound has and has higher synergistic effect to alternaria solani sorauer, biguanides three octyl benzene sulfonate and tpn 5:1,3:1,1:1,1:4,1:9 synergistic effect obvious, co-toxicity coefficient is greater than 140, and other proportionings all show synergistic effect in various degree.
assays Example 2: to the field control effectiveness test of powdery mildew of cucumber.
In March, 2012 this test moon carries out in Feitian town, Boluo County of Dong Sheng Huizhou City, is watered 45kg carries out even spraying by every mu, altogether dispenser 1 time, and after medicine, 7 days control efficiency are in table 2.
Table 2, biguanides three octyl benzene sulfonate tpn are to the field control effectiveness test result of powdery mildew of cucumber.
As can be seen from Table 2, the bactericidal composition of biguanides three octyl benzene sulfonate chlorothalonil compound of the present invention has good control efficiency to powdery mildew of cucumber, finds in test, and said composition, to cucumber safety, can reach desirable control efficiency in after medicine 7 days.
assays Example 3:to the field control effectiveness test of early blight of tomato.
This is tested and carries out in Liang Zhuan town, Yue Dai district, Tai'an, Shandong Province in May, 2012, is watered 45kg carries out even spraying by every mu, altogether dispenser 1 time, and after medicine, 7 days control efficiency are in table 3.
Table 3, biguanides three octyl benzene sulfonate tpn are to the field control effectiveness test result of early blight of tomato.
As can be seen from Table 3, biguanides three octyl benzene sulfonate of the present invention and chlorothalonil compound composition have good control efficiency to early blight of tomato, find in test, and said composition, to tomato safety, can reach desirable preventive effect in after medicine 7 days.
In sum; the composition of biguanides three octyl benzene sulfonate and chlorothalonil compound has good preventive effect to the plant disease caused by pathogen sac fungi, imperfect fungus; to crop, there is protection, treat dual nursing role, to crop safety safety, environmentally friendly.Compared with single dose, reduce times for spraying, save cost.Therefore R&D and promotion of the present invention is significant.
Claims (3)
1. the composition pesticide of a biguanides three octyl benzene sulfonate and tpn, it is characterized in that: active ingredient is biguanides three octyl benzene sulfonate and tpn, the ratio of weight and number of biguanides three octyl benzene sulfonate and tpn is 15:1 ~ 1:9, and biguanides three octyl benzene sulfonate
Be 30 ~ 80% with the percentage by weight of tpn weight summation in composition pesticide.
2. the agricultural chemicals of biguanides three octyl benzene sulfonate according to claim 1 and tpn
Composition, is characterized in that: the formulation of described composition pesticide is water dispersible granules, wetting powder or suspending agent.
3. the composition pesticide of biguanides three octyl benzene sulfonate according to claim 1 and tpn is preventing and treating the application in the crop pest caused by pathogen sac fungi, imperfect fungus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210583624.1A CN103098817B (en) | 2012-12-30 | 2012-12-30 | The composition pesticide of biguanides three octyl benzene sulfonate and tpn |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210583624.1A CN103098817B (en) | 2012-12-30 | 2012-12-30 | The composition pesticide of biguanides three octyl benzene sulfonate and tpn |
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| Publication Number | Publication Date |
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| CN103098817A CN103098817A (en) | 2013-05-15 |
| CN103098817B true CN103098817B (en) | 2016-01-06 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN115956573A (en) * | 2022-12-15 | 2023-04-14 | 江苏维尤纳特精细化工有限公司 | Novel bactericidal composition containing chlorothalonil |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101560A (en) * | 1984-02-24 | 1987-01-24 | 大日本油墨化学工业株式会社 | Guanidine-type (fungus) fungicide for agriculture and gardening and its production process |
| CN1287473A (en) * | 1998-11-02 | 2001-03-14 | 大日本油墨化学工业株式会社 | Bacteriocide compositions for agricultural and horticultural use |
| CN1312681A (en) * | 1998-06-12 | 2001-09-12 | 明治制果株式会社 | Agricultural or horticultural bacterial disease control agent |
| US20100197741A1 (en) * | 2007-09-26 | 2010-08-05 | Basf Se | Ternary Fungicidal Compositions Comprising Boscalid and Chlorothalonil |
| CN102258047A (en) * | 2011-05-25 | 2011-11-30 | 江苏龙灯化学有限公司 | Germicide composition |
-
2012
- 2012-12-30 CN CN201210583624.1A patent/CN103098817B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101560A (en) * | 1984-02-24 | 1987-01-24 | 大日本油墨化学工业株式会社 | Guanidine-type (fungus) fungicide for agriculture and gardening and its production process |
| CN1312681A (en) * | 1998-06-12 | 2001-09-12 | 明治制果株式会社 | Agricultural or horticultural bacterial disease control agent |
| CN1287473A (en) * | 1998-11-02 | 2001-03-14 | 大日本油墨化学工业株式会社 | Bacteriocide compositions for agricultural and horticultural use |
| US20100197741A1 (en) * | 2007-09-26 | 2010-08-05 | Basf Se | Ternary Fungicidal Compositions Comprising Boscalid and Chlorothalonil |
| CN102258047A (en) * | 2011-05-25 | 2011-11-30 | 江苏龙灯化学有限公司 | Germicide composition |
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