CN1035115C - Compound additive for gasoline - Google Patents
Compound additive for gasoline Download PDFInfo
- Publication number
- CN1035115C CN1035115C CN 94117669 CN94117669A CN1035115C CN 1035115 C CN1035115 C CN 1035115C CN 94117669 CN94117669 CN 94117669 CN 94117669 A CN94117669 A CN 94117669A CN 1035115 C CN1035115 C CN 1035115C
- Authority
- CN
- China
- Prior art keywords
- gasoline
- composite additive
- kinds
- additive
- following formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003502 gasoline Substances 0.000 title claims abstract description 70
- 239000000654 additive Substances 0.000 title claims abstract description 40
- 230000000996 additive effect Effects 0.000 title claims abstract description 39
- 150000001875 compounds Chemical class 0.000 title abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 15
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 alkenyl succinimide Chemical compound 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 21
- 239000004480 active ingredient Substances 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 150000004867 thiadiazoles Chemical class 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003208 petroleum Substances 0.000 abstract description 4
- 241001597008 Nomeidae Species 0.000 abstract 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012964 benzotriazole Substances 0.000 abstract 1
- 239000006184 cosolvent Substances 0.000 abstract 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N dihydromaleimide Natural products O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 abstract 1
- 229960002317 succinimide Drugs 0.000 abstract 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 16
- 239000003921 oil Substances 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- 239000000446 fuel Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000003348 petrochemical agent Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000003749 cleanliness Effects 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 230000001939 inductive effect Effects 0.000 description 3
- 238000007689 inspection Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241001085205 Prenanthella exigua Species 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 229960004756 ethanol Drugs 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 229920002552 poly(isobornyl acrylate) polymer Polymers 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- CAMMWOIMMVZFIC-UHFFFAOYSA-N [N].C1=COC=N1 Chemical class [N].C1=COC=N1 CAMMWOIMMVZFIC-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000007171 acid catalysis Methods 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 238000005691 oxidative coupling reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The present invention discloses a compound additive for gasoline and a preparation method thereof. The compound additive is prepared by that active components of alkenyl succinimide, alkylphenol, a benzotriazole derivant and a thiadiazole derivant are dissolved in low molecular alcohol cosolvent and petroleum light fraction solvent. The additive can improve the cleanness and the stability of the gasoline.
Description
The present invention relates to a kind of oil light fraction fuel with additive and preparation method thereof, more particularly, the present invention relates to a kind of gasoline dope and preparation method thereof, be used to improve quality of gasoline, particularly improve the detergency and the package stability of gasoline.
As everyone knows, reduce environmental pollution and save energy two big global social concerns and constantly exert pressure, and promoted developing of automobile industry to automotive industry.Accordingly, automotive industry reduces exhaust pollution and these two targets of fuel saving for realizing engine, and gasoline is had higher requirement.
For rotating speed and the volume power that improves petrol motor, particularly under the air rarefaction condition, carburettor is inapplicable.The fifties, the U.S. at first adopted gasoline electric-controlled injection oil supply on military aircraft, began the sixties to popularize the microminiaturization of electronic technology in addition to civilian, digitizing, promoted parameter acquisition, the reliability of operating mode control, thus realized that computer is from seeking optimized operation under the full working condition of engine.EFI fuel feeding and carburettor ratio, noxious emission descend 20%, and oil consumption 15% power that descends increases about 10%.U.S.'s beginning in 1976 is used on car, and is very universal at automatically controlled fuel feeding automobiles of developed country such as the U.S., Japan, Europe now.
The electronic gasoline injection car that enters China at present reaches 60,000, adds putting on market of China's self-generated electricity controlled jetting car of be about to going into operation, and the demand of electric-controlled injection gasoline will be the subject matter that the human consumer faces.One of quality characteristic of electric-controlled gasoline requires to have higher detergency exactly, and to keep the cleaning of oil-feed system, this will rely on, and the adding additive solves in the gasoline.
In order to control the settling in the engine, purificant was just recommended to use by the U.S. in 1954, recommended with anti-deposition agent (Depusit ControlAdditive) in 1970.In order to reach the requirement of federal uncontaminated air amendment of nineteen ninety,, stipulate that the whole gasoline of the U.S. must add purification agent since January nineteen ninety-five.The effect of purification agent generally is to prevent that the settling of engine parts from generating, and anti-deposition agent mainly is to remove the settling that has generated, specifically can be divided three classes:
(1) the lower molecular weight amine is mainly used in carburetor engine, and typical commercial is the LZ8166 additive of Lubrizol company, and consumption is 70～80ppm.
(2) compound such as succimide is mainly used in the electrospray engine, and typical commercial is the Lz8136 additive of Lubrizol company, and consumption is 150～250ppm.
(3) PIBA (PIBA) and polyesteramine (PEA) are mainly used in intake valve, and typical commercial is the LZ8195 additive of Lubrizol company, and consumption is 600～1000ppm.
The object of the invention provides composite additive, stability and the detergency to improve gasoline that a kind of light fraction fuel, particularly gasoline are used.It is applicable to electric-controlled injection fuel feeding engine, also is applicable to the gasifier oil turbine.The present invention simultaneously also provides the method for this composite additive of preparation, and this additive is in the using method of gasoline and contain the gasoline composition of this gasoline dope.
Gasoline composite additive of the present invention is the composition concentrate of amine-nitrogen azoles-thiazole-phenol.
Gasoline composite additive of the present invention is to make solvent with light hydrocarbon, and low mass molecule alcohol is made solubility promoter, and it is formulated to add dispersion agent, metal passivator and oxidation inhibitor by a certain percentage.Wherein said varsol generally adopts white gasoline or No. 200 solvent oils.
The used dispersion agent of gasoline composite additive of the present invention is the allyl butyrate imide shown in the following formula A:
R represents polyisobutenyl in the formula, and molecular weight is 800～1800, is preferably 1100～1300.
Compound shown in the formula A is to make enetutanedioic acid anhydride with the low-molecular-weight polyisobutylene of molecular weight 800～1800 and maleic anhydride through addition reaction, makes with the tetraethylene pentamine reaction then, and this preparation method is well known in the art.Compound shown in the formula A can have been bought from petrochemicals sales department.
The used oxidation inhibitor of gasoline composite additive of the present invention is the alkylphenol shown in the following formula B:
R1 represents 4-8 carbon alkyl among the formula B.
Compound shown in the formula B is to carry out alkylated reaction with p-cresol and iso-butylene under sulphuric acid catalysis, forms with the crystallization of ethanol alkaline solution neutralized crude, separation, washing, filtration and recrystallize are refining again.This preparation method is well known in the art.
Compound shown in the formula B can have been bought from petrochemicals sales department.
The used metal passivator of gasoline composite additive of the present invention is a kind of nitrogen oxazole derivatives shown in the following formula C that is:
R2 is an alkyl among the formula C, preferably C8～C20 alkyl.
This derivative is made through association reaction by 124 Triazole, formaldehyde, organic amine.Its preparation method is well known in the art.Product shown in the formula C can have been bought from petrochemicals sales department.
The used another kind of metal passivator of the present invention is the thiadiazoles derivative shown in the following formula D:
R3 is C3～C16 alkyl among the formula D, and X is an integer 1,2,3:
This derivative is to be made through processes such as acidifying and oxidative couplings by 2,5 disulfide group thiadiazoles (DMTD).Its preparation method is well known in the art, and product shown in the formula D can have been bought from petrochemicals sales department.
The part by weight of the four kinds of active ingredients (hereinafter to be referred as A, B, C, D) shown in gasoline composite additive Chinese style A of the present invention, B, C, the D closes:
A: B: C: D is 70～80%: 4～10%: 4～10%: 5～20%, and total amount is 100%.
Above-mentioned four kinds of components are dissolved in solubility promoter and the solvent by desired amount can be mixed with additive of the present invention.The used solubility promoter of the present invention is a monohydroxy-alcohol, is preferably dehydrated alcohol: solvent is a light hydrocarbon, is preferably solvent oil No. 200.The ratio of gasoline dope active ingredient of the present invention and solubility promoter and solvent is generally 1: 0.5: 10～20, is preferably 1: 0.5: 13.
The preparation method of gasoline dope of the present invention has two kinds: a kind of method is under agitation, at 20～60 ℃, preferred 25～40 ℃, with active component A, B, C, four kinds of independent components of D are dissolved in a small amount of solubility promoter or the solvent respectively separately in required ratio, add balance solvent then or solubility promoter mixes it, promptly get required gasoline composite additive, another kind method is under above-mentioned condition, with A, B, C, four kinds of components of D add in a small amount of same solubility promoter or the solvent in desired ratio and priority, and dissolving adds balance solvent afterwards and solubility promoter promptly gets required gasoline composite additive.
Gasoline dope of the present invention is a weak yellow liquid.
Gasoline dope of the present invention can be widely used in the extensive stock gasoline, and it is best to be used for the non-lead gasoline for car effect.Gasoline of the present invention can be added in amounts (with the total amount of four kinds of active ingredients) the adding gasoline in PMT (Per metric ton) gasoline adding 80～260 grams mixing during application, can obtain good security, the peace and quiet gasoline that cleanliness is high.This additive breakdown time is not less than 600 minutes, and air inlet and exhaust system cleanliness factor improve greatly during use.
With embodiment the present invention is further specified below, but the present invention is not limited to this.
Embodiment 1-3 illustrates the preparation of gasoline composite additive of the present invention.
Under 25 ℃, one side stir one side with market bought through check satisfactory A, B, four kinds of components of C, D with meet No. 200 paint industries that SH0005 standard Tianjin first petroleum chemical plant produces use solvent oil and ethanol by table 1 routine mixed, be mixed with gasoline composite additive of the present invention, its character is shown in the table 2.Table 1 additive preparation example
Table 2 additive physico-chemical property
| Project | Quality index | Test method |
| 20 ℃ of g/CM3 of density | 0.75～0.85 | GB/T1884 |
| Copper corrosion, 50 ℃ of 3H of level | 1 | GB/T5096 |
| Ammonia content % (m/m) | 0.25～0.35 | SH/T0224 |
Embodiment 4
The gasoline composite additive of embodiment 1 is joined in the 90# white gasoline of Tianjin first petroleum chemical plant production, and add-on is measured inductive phase by the total of active ingredient with the GB/T8018 method, the results are shown in table 3.By the data of table 3 as can be seen: add additive and can prolong induction period of gasoline, it is best, most economical wherein to add 130 gram additive effects with PMT (Per metric ton).Table 3 adds the inductive phase of agent oil
| The total add-on g/T of A+B+C+D active ingredient | Inductive phase min |
| 0 | 960 |
| 80 | 1032 |
| 130 | ＞1000 |
| 260 | ＞1000 |
Embodiment 5
The gasoline composite additive of embodiment 1 is joined in the 90# white gasoline of Tianjin one petroleum chemical plant, PMT (Per metric ton) adds 130 grams (by active ingredient), the same gasoline that will not add agent simultaneously and add U.S. PA 748 additives is made testing of engine as a comparison.The significant parameter of used engine is:
Model: 4920-A type
Work discharge capacity: 2.4451
Compression ratio: 6.6: 1
Peak power: 51KW/3600r/min
Peak torque: 170N.m/2200r/min
Draw the visual observation of table 4 through 130 minutes detergency tests, observe from material object and photo, as fuel oil fitering element, vapor pipe and sparking plug, carburettor etc., with No. 2 (adding U.S.'s additive), No. 3 (adding gasoline composite additive of the present invention) gasoline cleanliness is good, and fuel oil fitering element is bright, cleaning, basic contamination-free, and color is pure whiter, vapor pipe, spark plug fouling are less, and carbon is thinner.In kind and photo demonstration does not have pollution with No. 1 gasoline of purification agent to piece surface, does not have peace and quiet effect.The peace and quiet situation of table 4 detergency test in 130 minutes back range estimation part
| Part name | Detergency | ||
| No. 1 gasoline | No. 2 gasoline | No. 3 gasoline | |
| Fuel oil fitering element | Color has dirt more deeply. | Bright white, no dirt. | Bright white, no dirt. |
| Vapor pipe | The more thick-skinned look of carbon is more black. | The thin carbon distribution of carbon is few. | The thin carbon distribution of carbon is few. |
| Sparking plug | The visible carbon distribution is arranged. | It is dark-coloured that no visible carbon distribution shows slightly. | No visible carbon distribution Lu Bense. |
| The carburetor bowl flange. | Peace and quiet pollution-free butterfly color is darker. | Peace and quiet pollution-free butterfly color light. | Peace and quiet pollution-free butterfly color light. |
Embodiment 6
The gasoline composite additive of embodiment 1 is joined in the commercially available 93# gasoline, and PMT (Per metric ton) adds 130 grams (by amount of active ingredients), and the same gasoline that will not add agent simultaneously carries out actual service test as a comparison.Used car is a Guangzhou beautiful 505SW8 type car, and its main technical details is:
Engine model: KN1A carburetor type
Cylinder diameter. stroke: 88.81mm
Compression ratio: 8: 1
Ignition order: 1-3-4-2
Idle running: 900r/min
Discharge capacity: 1971cm
3
Use the gasoline test-results of additive of the present invention as follows:
But 1, per 100 km fuel-economizing 0.66L (seeing Table 5), rate of economizing gasoline is-5.2%:
2, tail gas pollution (the seeing Table 6.7) hydrocarbon that obviously descends reduces 22.9～43.8%, and carbon monoxide reduces 20.2～32.5%.
3, carburetor detergency obviously improves, and the stain that adds agent oil obviously reduces.Table 5 regular gasoline with add agent oil oil consumption contrast
Table 6 fixed point tail gas inspection results
Table 7 tunnel inspection tail gas inspection results
| Running time | Mileage KM | Gasoline consumption L | Fuel consumption per hundred kilometers L | Rate of economizing gasoline % |
| 94.3.14～ 4.12 | 3004 | Conventional oil 326.07 | 10.85 | |
| 4.12～5.21 | 3006 | Add agent oil 314.72 | 10.47 | On average-5.2 |
| 5.21～6.18 | 3199 | Add agent oil 323.09 | 10.10 |
| When regular gasoline travels 2600KM | HC178ppm | CO 4％ |
| When adding agent gasoline and travelling 2000KM | HC100ppm | CO 2.7％ |
| Reduce % | -43.8 | -32.5 |
| Regular gasoline | HC 468 ppm | CO 5.85％ |
| Add agent gasoline | HC 361 ppm | CO 4.67％ |
| The minimizing value | HC 107 ppm | CO 1.18％ |
| ％ | -22.9 | -20.2 |
Claims (3)
1, a kind of gasoline composite additive is characterized in that this components of additives and content thereof (weight) are as follows:
(1) active ingredient:
A. the allyl butyrate imide represented of following formula, 70～80%
R represents polyisobutenyl in the formula, and molecular weight is 800～1800;
B. the alkylphenol represented of following formula, 4～10%
R1 represents the alkyl of 4～8 carbon atoms in the formula;
C. the benzotriazole derivative represented of following formula, 4～10%
R2 is C8～C20 alkyl;
D. the thiadiazoles derivative represented of following formula, 5～20%
R3 is C3～C16 alkyl; X is an integer 1,2,3;
The total amount of four kinds of activeconstituentss of A.B.C.D is 100%;
(2) solubility promoter: dehydrated alcohol;
(3) solvent: boiling point is not higher than the oil lighting end of 250C;
Wherein (1); (2); (3) ratio is 1: 0.5: 10～20.
2, a kind of gasoline composition is characterized in that this gasoline PMT (Per metric ton) contains the gasoline composite additive (by the gross activity component) of 100～300 gram claims 1.
3, a kind of preparation method of gasoline composite additive, it is characterized in that four kinds of active ingredients in the claim 1 under normal temperature, normal pressure, stirring condition, ratio on demand is dissolved in respectively in solubility promoter and the solvent, and then with four kinds of mixtures mixing, perhaps four kinds of active ingredients are dissolved in solubility promoter and the solvent simultaneously in the lump, promptly get required gasoline composite additive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94117669 CN1035115C (en) | 1994-11-01 | 1994-11-01 | Compound additive for gasoline |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 94117669 CN1035115C (en) | 1994-11-01 | 1994-11-01 | Compound additive for gasoline |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1108683A CN1108683A (en) | 1995-09-20 |
| CN1035115C true CN1035115C (en) | 1997-06-11 |
Family
ID=5038457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 94117669 Expired - Lifetime CN1035115C (en) | 1994-11-01 | 1994-11-01 | Compound additive for gasoline |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1035115C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062591C (en) * | 1998-01-08 | 2001-02-28 | 北京市朝阳区高科应用技术研究所 | Anti-knock additive for lead-free gasoline and its preparation |
| CN1063216C (en) * | 1997-08-29 | 2001-03-14 | 深圳市日研科技有限公司 | Liquid fuel additive |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1046131C (en) * | 1997-03-13 | 1999-11-03 | 陈祥科 | Multifunctional gasoline additive composition |
| CN1054626C (en) * | 1998-03-04 | 2000-07-19 | 北京市艾实华标准技术公司 | High-clean gasoline additive and its preparing process and application |
| US6074992A (en) * | 1999-02-02 | 2000-06-13 | Union Carbide Chemicals & Plastics Technology Corporation | Functional fluid compositions |
| CN1081224C (en) * | 1999-02-09 | 2002-03-20 | 北京艾木科技发展有限公司 | Multi-effect composite additive for gasoline/diesel oil and its preparation method |
| US8231695B2 (en) * | 2006-08-09 | 2012-07-31 | Afton Chemical Corporation | Fuel compositions comprising hydrocarbon oil carriers and methods for using the same |
| CN101586048B (en) * | 2008-05-23 | 2013-11-20 | 杨道保 | Gasoline detergent additive |
| CN104004553B (en) * | 2014-06-04 | 2015-04-08 | 山东吉利达能源科技有限公司 | Gasoline quality improver applicable to national IV-level gasoline |
-
1994
- 1994-11-01 CN CN 94117669 patent/CN1035115C/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063216C (en) * | 1997-08-29 | 2001-03-14 | 深圳市日研科技有限公司 | Liquid fuel additive |
| CN1062591C (en) * | 1998-01-08 | 2001-02-28 | 北京市朝阳区高科应用技术研究所 | Anti-knock additive for lead-free gasoline and its preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1108683A (en) | 1995-09-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5266082A (en) | Fuel additive | |
| US4073626A (en) | Hydrocarbon fuel additive and process of improving hydrocarbon fuel combustion | |
| CN1035115C (en) | Compound additive for gasoline | |
| CN109468148B (en) | A kind of harmless automobile fuel-saving composition and preparation method thereof | |
| CN1583977A (en) | Clean alcohol fuel | |
| CN1081224C (en) | Multi-effect composite additive for gasoline/diesel oil and its preparation method | |
| CN102041115B (en) | Ethanol-diesel compound additive and preparation method thereof | |
| US3707362A (en) | Method and composition for optimizing air-fuel ratio distribution in internal combustion engines | |
| CN1281724C (en) | Highly efficient fuel accelerant and method for preparing the same | |
| CN114164027A (en) | Clean environment-friendly diesel oil and preparation method thereof | |
| CN1611582A (en) | Multifunctional efficent composite fuel additive for engine and preparing method thereof | |
| CN111394141A (en) | Environment-friendly energy-saving automobile detergent and preparation method thereof | |
| CN101180384B (en) | General additives for lubricating oils and fuel oils, fuel oils/schemes/ for internal combustion engines containing general additives, diesel oils/schemes/ and ignition fuels for combustion furnaces and metal smelters in thermal power stations | |
| CN101824341A (en) | High-clean gasoline additive | |
| CN117603742A (en) | A highly active green detergent and its preparation method and application | |
| CN1063216C (en) | Liquid fuel additive | |
| CN103361134A (en) | Additive for reducing PM2.5 emission of diesel engines and application of additive | |
| CN1891795B (en) | Petrol additive | |
| CN101497830A (en) | Efficient environment-friendly energy-saving diesel fuel additive | |
| US20070044373A1 (en) | Fuel additive | |
| CN1928033A (en) | Methanol modifier and application thereof | |
| CN1508234A (en) | Vehicular clean environmental-protection methanol gasoline | |
| CN112920866B (en) | Composite detergent for automotive gasoline and preparation method thereof | |
| CN1033458C (en) | Gasoline saving agent for vehicle fuel | |
| CN1730621A (en) | Catalytic detersive of diesel fuel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: CHINA PETROCHEMICAL GROUP SALES CO., LTD. Free format text: FORMER NAME OR ADDRESS: CHINA PETRO-CHEMICAL PRODUCTS SALES CORP. |
|
| CP03 | Change of name, title or address |
Address after: 100029, Beijing, Chaoyang District, a new East Street, No. 6 Petrochemical Sales Company Patentee after: Sinopec Group Sales Industry Co., Ltd. Address before: 100032 No. 10, Tokyo, Xicheng District, Beijing Patentee before: China Petro-Chemical Products Sales Corp. |
|
| C56 | Change in the name or address of the patentee | ||
| CP02 | Change in the address of a patent holder |
Address after: 100728, Beijing Chaoyang District Chaoyangmen 22 North Street, 18 floor, Sinopec Sales Co., Ltd. Patentee after: Sinopec Group Sales Industry Co., Ltd. Address before: 100029, Beijing, Chaoyang District, a new East Street, No. 6 Petrochemical Sales Company Wu Yang Patentee before: Sinopec Group Sales Industry Co., Ltd. |
|
| C17 | Cessation of patent right | ||
| CX01 | Expiry of patent term |
Expiration termination date: 20141101 Granted publication date: 19970611 |