CN1032280A - A kind of agriculture chemical compounding formulation - Google Patents
A kind of agriculture chemical compounding formulation Download PDFInfo
- Publication number
- CN1032280A CN1032280A CN 87101390 CN87101390A CN1032280A CN 1032280 A CN1032280 A CN 1032280A CN 87101390 CN87101390 CN 87101390 CN 87101390 A CN87101390 A CN 87101390A CN 1032280 A CN1032280 A CN 1032280A
- Authority
- CN
- China
- Prior art keywords
- belmark
- isocarbophos
- agriculture chemical
- chemical compounding
- compounding formulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009472 formulation Methods 0.000 title claims abstract description 17
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000000126 substance Substances 0.000 title claims description 16
- 238000013329 compounding Methods 0.000 title claims description 15
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims abstract description 20
- YFVOXLJXJBQDEF-UHFFFAOYSA-N isocarbophos Chemical compound COP(N)(=S)OC1=CC=CC=C1C(=O)OC(C)C YFVOXLJXJBQDEF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 6
- 230000002195 synergetic effect Effects 0.000 claims abstract description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000002728 pyrethroid Substances 0.000 claims description 5
- 239000003986 organophosphate insecticide Substances 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 230000002708 enhancing effect Effects 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 abstract description 10
- 239000004480 active ingredient Substances 0.000 abstract description 8
- 241001124076 Aphididae Species 0.000 abstract description 7
- 230000000749 insecticidal effect Effects 0.000 abstract description 6
- 241001347511 Carposina sasakii Species 0.000 abstract description 5
- 238000005507 spraying Methods 0.000 abstract description 5
- 150000002148 esters Chemical class 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 4
- 241000723353 Chrysanthemum Species 0.000 abstract 2
- 235000007516 Chrysanthemum Nutrition 0.000 abstract 2
- 239000003814 drug Substances 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 7
- 239000006071 cream Substances 0.000 description 7
- 239000010779 crude oil Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000003905 agrochemical Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 241001454293 Tetranychus urticae Species 0.000 description 2
- 240000008866 Ziziphus nummularia Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 235000009917 Crataegus X brevipes Nutrition 0.000 description 1
- 235000013204 Crataegus X haemacarpa Nutrition 0.000 description 1
- 235000009685 Crataegus X maligna Nutrition 0.000 description 1
- 235000009444 Crataegus X rubrocarnea Nutrition 0.000 description 1
- 235000009486 Crataegus bullatus Nutrition 0.000 description 1
- 235000017181 Crataegus chrysocarpa Nutrition 0.000 description 1
- 235000009682 Crataegus limnophila Nutrition 0.000 description 1
- 235000004423 Crataegus monogyna Nutrition 0.000 description 1
- 240000000171 Crataegus monogyna Species 0.000 description 1
- 235000002313 Crataegus paludosa Nutrition 0.000 description 1
- 235000009840 Crataegus x incaedua Nutrition 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 241000255129 Phlebotominae Species 0.000 description 1
- 241000488533 Tetranychus viennensis Species 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N Valeric acid Natural products CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003129 miticidal effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention for a kind of be active ingredient with Belmark and isocarbophos, be equipped with suitable emulsifier and solvent the modulation the composite synergistic complex formulation that makes, be mainly used in the control Carposina niponensis in fruit trees, aphid and mite class.This complex agent type has not only that chrysanthemum ester class is efficient, the characteristics of wide spectrum, the characteristic that also has the organophosphorus insecticidal mite, and its price is cheap more than the chrysanthemum ester, use cost only is single with 40～60% of Belmark, because its insecticidal spectrum is wide, can reduce spraying times again, the saving of labor, save time, thereby reduced agriculture use cost, improved economic benefit.
Description
The invention belongs to pesticide processing formulation field, a kind of pyrethroid and organophosphorus insecticide complex agent type that mainly is suitable for fruit tree of saying so in more detail.
Organophosphorus insecticide is that a kind of insecticidal spectrum is wide, but the not only desinsection but also the agricultural chemicals that can kill mite.But in recent years along with increase its service time, particularly inappropriate medication causes pest resistance to increase, and drug effect descends, and consumption obviously improves.Pyrethroid insecticides is a kind of emerging agricultural chemicals type, because of its low toxicity, efficient, consumption is few receives praises from customers.But it costs an arm and a leg, and the control efficiency to the mite class is not good, especially because improper use, within a short period of time, insect such as cotten aphid have just produced stronger resistance to it, cause in some resistance district and lose use value, produce in order to delay pest resistance, keep the efficient characteristics of above-mentioned agricultural chemicals, increase the service life, be necessary to carry out the development of complex preparation.Though have Multiple Pesticides complex agent type supply the market at present both at home and abroad, up to now, it is the agriculture chemical compounding formulation of main component that valeric acid Cyano chrysanthemate and isocarbophos are not arranged as yet.
The object of the present invention is to provide a kind of be mainly used in the control fruit tree pest insect be the agriculture chemical compounding formulation of active ingredient with Belmark and isocarbophos, its price and use cost are far below independent use Belmark, and insecticidal effect is suitable with it, and has good acaricidal action and than obvious synergistic effect.
Agriculture chemical compounding formulation of the present invention is that a kind of pyrethroid and organophosphorus insecticides are the agriculture chemical compounding formulation of main active ingredient.Having it is characterized in that selecting for use Belmark and the isocarbophos in the organophosphorus insecticides in the pyrethroid insecticides is main active ingredient, and be equipped with suitable emulsifier and solvent carry out composite, but make a kind of not only desinsection of control fruit tree pest insect but also comparatively cheap novel agrochemical complex agent type of price that can kill mite of being mainly used in.
Relative scale scope in the agriculture chemical compounding formulation active ingredient of the present invention between Belmark and the isocarbophos is 1: (1～3), its concrete ratio can take all factors into consideration price and controlling object is determined.Composite between Belmark and the isocarbophos, the effect of learning from other's strong points to offset one's weaknesses is mutually not only arranged, and have certain synergistic effect, through Toxicity Determination, filtering out best enhancing proportions scope is 1: (2.2～3), its co-toxicity coefficient can reach 130～190 in this scope.
Employed solvent can be selected benzene, toluene or dimethylbenzene etc. for use in this agriculture chemical compounding formulation.Emulsifier can be selected the mixed type of nonionic and anionic for use, and its HLB value can slightly adjust according to active ingredient ratio and solvent situation, to obtain the optimum emulsification effect.
Consider composite processing technology, packing, storing and many-sided factor such as easy to use, active ingredient is controlled at 30～40% in this agriculture chemical compounding formulation, and the proportion between active ingredient, emulsifier and the solvent three is (30～40): (5～12): (50～65).
The processing process figure of this complex agent type is as follows:
This complex agent type is mainly used in the control fruit tree pest insect, as the peach fruit borer of apple, hawthorn, jujube etc., two spotted spider mite, aphid etc., also can be used for preventing and treating cotton sandfly worm, cotten aphid, two-spotted spider mite and other crop pest.
This complex agent type is a missible oil, and its outward appearance is faint yellow, as clear as crystal single-phase oily liquids, and its stability meets GB1603-79 agricultural-chemical emulsion stability criterion.
When using this complex agent type, generally need thin up to spray for 3000～5000 times, its lasting period is 7～15 days, and in 1 year, general dispenser can comprehensive Pest Control endanger for 2～3 times.
The insecticidal effect of this complex agent type is equivalent to or a little more than using Belmark separately, miticidal effect is particularly evident, and its control efficiency sees following each table for details.
Table 1 control apple peach fruit borer effect contrast table
| Medicament | Use multiple | Spraying times | Wormed fruit rate (%) |
| 20% Belmark missible oil | 3000 | 2 | 0.6 |
| 40% cream of isocarbophos | 1500 | 2 | 2.7 |
| 30% complex agent type of the present invention | 3000 | 2 | 0.6 |
Table 2 control jujube peach fruit borer contrast table
| Medicament | Use multiple | Spraying times | Wormed fruit rate (%) |
| 40% cream of isocarbophos | 1500 | 2 | 6.57 |
| 20% Belmark missible oil | 5000 | 2 | 0.53 |
| 30% compounded cream of the present invention | 5000 | 2 | 0.54 |
Table 3 control apple yellow aphid effect contrast table
| Medicament | Use multiple | Spraying times | Control efficiency (%) |
| 20% Belmark missible oil | 5000 | 1 | 84.25 |
| 40% cream of isocarbophos | 1000 | 1 | 31.18 |
| 30% compounded cream of the present invention | 5000 | 1 | 100.0 |
Table 4 control apple hawthorn spider mite effect contrast table
| Medicament | Use multiple | Spraying times | Control efficiency (%) |
| 20% Belmark missible oil | 6000 | 1 | 76.9 |
| 40% cream of isocarbophos | 1500 | 1 | 90.0 |
| 30% compounded cream of the present invention | 6000 | 1 | 98.7 |
The price of agriculture chemical compounding formulation of the present invention and use cost only are to use 40～60% of Belmark separately, because its insecticidal spectrum is wide, doublely control mite again, spray the medicine number of times so can reduce, obtain the effect of saving of work and time, thereby remarkable economic efficiency and social benefit are arranged.
60 kilograms of embodiment 1. Belmark crude oil, 60 kilograms of isocarbophos crude oils, 50 kilograms of emulsifier, 230 kilograms of benzene compositely are modulated into 400 kilograms of complex agent types of the present invention, are used to prevent and treat Carposina niponensis in fruit trees.Dilute 5000 times, spray medicine 2 times, control efficiency can reach more than 95%, and its use cost is single with 60% of pentyl ester cyanogen ether-ether.
30 kilograms of embodiment 2. pentyl ester cyanogen ether-ether crude oil, 60 kilograms of isocarbophos crude oils, 20 kilograms of emulsifier, 190 kilograms of modulation of dimethylbenzene are re-dubbed 300 kilograms of complex agent types of the present invention.Be used to prevent and treat fruit tree budworm, aphid, mite, dilute 5000 times, dispenser 2 times, control efficiency can reach more than 95%, and use cost is single with 50% of Belmark.
Embodiment 3,30 kilograms of Belmark crude oil, and 90 kilograms of isocarbophos crude oils, 30 kilograms of emulsifier, 150 kilograms of toluene are modulated the composite 300 kilograms of complex agent types of the present invention that get.Prevent and treat fruit tree budworm, aphid, mite with it, dilute 5000 times, spray medicine 2 times, control efficiency can reach more than 95%, and use cost is single with 40% of Belmark.
(above crude oil is all by 100% cubage).
Claims (6)
1, a kind of pyrethroid and organophosphorus insecticide complex agent type is characterized in that with Belmark and isocarbophos be effective ingredient, are equipped with suitable emulsifier and solvent, but the composite novel synergistic farm chemical complex agent type that makes a kind of not only desinsection but also can kill mite.
2, agriculture chemical compounding formulation as claimed in claim 1 is characterized in that the relative scale scope between the Belmark and isocarbophos is 1 in the said effective ingredient: (1～3).
3,, it is characterized in that the best enhancing proportions scope between the Belmark and isocarbophos is 1 in the said effective ingredient: (2.2～3) as claim 1 and 2 described agriculture chemical compounding formulations.
4, agriculture chemical compounding formulation as claimed in claim 1 is characterized in that selected emulsifier is the mixed emulsifier of nonionic and anionic.
5, agriculture chemical compounding formulation as claimed in claim 1 is characterized in that selected solvent is benzene, toluene or dimethylbenzene.
6, agriculture chemical compounding formulation as claimed in claim 1 is characterized in that wherein the part by weight of effective ingredient, emulsifier and solvent is: (30～40): (5～12): (50～65).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87101390 CN1032280A (en) | 1987-09-30 | 1987-09-30 | A kind of agriculture chemical compounding formulation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 87101390 CN1032280A (en) | 1987-09-30 | 1987-09-30 | A kind of agriculture chemical compounding formulation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1032280A true CN1032280A (en) | 1989-04-12 |
Family
ID=4813382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 87101390 Pending CN1032280A (en) | 1987-09-30 | 1987-09-30 | A kind of agriculture chemical compounding formulation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1032280A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119867094A (en) * | 2025-03-26 | 2025-04-25 | 山东百农思达生物科技有限公司 | Compound emulsifiable concentrate pesticide for pest control and preparation method thereof |
-
1987
- 1987-09-30 CN CN 87101390 patent/CN1032280A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119867094A (en) * | 2025-03-26 | 2025-04-25 | 山东百农思达生物科技有限公司 | Compound emulsifiable concentrate pesticide for pest control and preparation method thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |