CN1098850A - Crops missible oil insecticide - Google Patents
Crops missible oil insecticide Download PDFInfo
- Publication number
- CN1098850A CN1098850A CN 93109797 CN93109797A CN1098850A CN 1098850 A CN1098850 A CN 1098850A CN 93109797 CN93109797 CN 93109797 CN 93109797 A CN93109797 A CN 93109797A CN 1098850 A CN1098850 A CN 1098850A
- Authority
- CN
- China
- Prior art keywords
- crops
- missible oil
- solubilizer
- emulsifier
- insecticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000002917 insecticide Substances 0.000 title claims abstract description 16
- 239000000575 pesticide Substances 0.000 claims abstract description 23
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 15
- 239000002904 solvent Substances 0.000 claims abstract description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003905 agrochemical Substances 0.000 claims abstract description 12
- 239000003960 organic solvent Substances 0.000 claims abstract description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229930193529 cinerin Natural products 0.000 claims abstract description 7
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 6
- 150000003851 azoles Chemical class 0.000 claims abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011574 phosphorus Substances 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 5
- 210000000481 breast Anatomy 0.000 claims abstract description 4
- 238000009313 farming Methods 0.000 claims abstract description 4
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims abstract description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims abstract description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000002728 pyrethroid Substances 0.000 claims description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 241000723353 Chrysanthemum Species 0.000 claims description 6
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000005946 Cypermethrin Substances 0.000 claims description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 3
- 229960005424 cypermethrin Drugs 0.000 claims description 3
- RLLPVAHGXHCWKJ-IEBWSBKVSA-N (3-phenoxyphenyl)methyl (1s,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-IEBWSBKVSA-N 0.000 claims description 2
- 239000005949 Malathion Substances 0.000 claims description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims description 2
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 2
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 claims description 2
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 claims description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims description 2
- -1 flolimat Chemical compound 0.000 claims description 2
- 229960000453 malathion Drugs 0.000 claims description 2
- 239000012046 mixed solvent Substances 0.000 claims description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 2
- 229950001664 phoxim Drugs 0.000 claims description 2
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 abstract description 16
- 241000255967 Helicoverpa zea Species 0.000 abstract description 12
- 241000238631 Hexapoda Species 0.000 abstract description 6
- 241000721451 Pectinophora gossypiella Species 0.000 abstract description 3
- 241001414989 Thysanoptera Species 0.000 abstract description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 2
- 241000425037 Toona sinensis Species 0.000 abstract description 2
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 230000000857 drug effect Effects 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 3
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 3
- 229950001327 dichlorvos Drugs 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 2
- 241001454293 Tetranychus urticae Species 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000003986 organophosphate insecticide Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 1
- 241001600407 Aphis <genus> Species 0.000 description 1
- 241001600408 Aphis gossypii Species 0.000 description 1
- 241000012249 Dendrolimus spectabilis Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000005461 organic phosphorous group Chemical group 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of crops missible oil insecticide, be applicable to that mainly control has drug-fast cotton cotton bollworm, pink bollworm, thrips, educates insects such as Chinese toon tin, Ye Mang.It has added emulsifier and solubilizer, its proportioning: organophosphorous pesticide: 5-20%; Cinerins agricultural chemicals: 0.2-20%; Emulsifier: 3-10%; Solubilizer: 0.2-18%; All the other are organic solvent: add to 100%.Emulsifier is selected farming breast respectively for use No. 500, peregal, dodecyl sodium sulfate or straight chain dodecyl sodium sulfate etc.Solubilizer is selected ethanol, formyl, isopropyl alcohol, metallic stearate, Ah azoles, synergy phosphorus or sodium sulfosuccinate etc. respectively for use.
Description
The present invention relates to a kind of crops missible oil insecticide, be applicable to that mainly control has drug-fast cotton cotton bollworm, pink bollworm, thrips, educates insects such as Chinese toon tin, Ye Mang.
Existing crops pesticide, as China patent 91105692.0(CN 1060387A) " oxychloride emulsion as pesticide ", this patent proposes a kind of Recompounded pesticide oxychloride emulsion as pesticide that dichlorvos, flolimat and beta-cypermethrin are formed as active ingredient that contains, increase and joined a kind of synergist, each components contents is by weight: concentration is 90% dichlorvos 10-40%, concentration is 65% flolimat 9-38%, and concentration is 5% beta-cypermethrin 15-45%, synergist 30-50%.This agricultural chemicals oxychloride emulsion as pesticide has strengthened insecticidal effect, is mainly used in insects such as control antibiosis cotton aphid, cotton bollworm, pink bollworm, fruit tree budworm, fruit tree two spotted spider mite, little green aphid and cabbage caterpillar.Its weak point is that dichlorvos toxicity is bigger, and its drug effect of antagonism property of medicine cotton bollworm is not ideal enough.Cotton bollworm is serious to the harm of cotton, usually causes the cotton underproduction sometimes, even total crop failure.The control of cotton bollworm is imminent, and the bollworm resistance of China is very strong, needs to use the agricultural chemicals of high-efficiency low-toxicity to prevent and treat.
The purpose of this invention is to provide the strong interpolation emulsifier of a kind of pesticide resistance and the insecticide of solubilizer.
The object of the present invention is achieved like this: adopt organophosphorous pesticide and pyrethroid composite, and add the drug-fast emulsifier of elimination and solubilizer and organic solvent, through assembly, make cotton boll and kill the missible oil crops pesticide.
Advantage of the present invention is: 1. organophosphorous pesticide has and tags and interior absorption; Pyrethroid has very strong contact toxicity, and dosage is few, and environmental pollution is light; The present invention has had both the advantage of above-mentioned two kinds of agricultural chemicals, and having overcome chrysanthemum ester class does not have interior absorption shortcoming.2. after adding the drug-fast New-type emulsifier of elimination, strengthen the medicine infiltration, insecticidal effect is better.3. cotton boll kills missible oil has extremely strong control efficiency to crop pests, and the drug effect phase is long, and its toxicity environmental pollution is little.
It is by organophosphorous pesticide and pyrethroid pesticide that cotton boll of the present invention kills missible oil, and adds emulsifier, solubilizer and organic solvent is composite forms.
Cotton boll of the present invention kills missible oil and mainly forms:
1. organophosphorous pesticide is selected Rogor, flolimat, malathion, phoxim, 1605 or 1059 etc. respectively for use, and the independent use of these agricultural chemicals does not all have insecticidal effect preferably.
2. pyrethroid is selected for use respectively and is killed chrysanthemum ester, Chinese and Western chrysanthemum ester, cyhalothrin, sumicidin, cypermethrin, Permanone or decis etc., they are broad spectrum insecticides, has strong contact toxicity, and stomach toxicity is arranged, kill ovum, food refusal and repellent action, and dosage is few, environmental pollution is little, and the drug effect phase is moderate.But cost is higher, and inhales and fumigation action in not having, thereby is subjected to certain influence in the control of insect.
3. emulsifier select farming breast respectively for use No. 500, the polyvinyl chloride-based ether of nonyl phenol (OP-10, OP-7, OP-5), peregal, dodecyl sodium sulfate (ABS), straight chain dodecyl sodium sulfate (LAS), Myri45, Emcoleo-50 or Ninol etc., emulsifier can make the organophosphorous pesticide of oiliness and pyrethroid emulsification water-soluble, becoming small emulsion particle is dispersed in the water, has good plate-out ability simultaneously, be sprayed on leaf, stem and the insect of plant, make it have adhesiveness, and certain permeability is arranged.
4. solubilizer is selected ethanol, methyl alcohol, isopropyl alcohol, metallic stearate, Ah azoles (AZ), synergy phosphorus or sodium sulfosuccinate etc. respectively for use, solubilizer can increase dissolubility, emulsibility, stability, the permeability of agricultural chemicals, can give full play to the effect of agricultural chemicals, prolong the drug effect phase, and be subjected to climatic effect less.
5. organic solvent is selected benzene,toluene,xylene or acetone etc. respectively for use, and their mixed solvent.
Above-mentioned each form to choose percentage by weight as follows:
1. organophosphorous pesticide: 5-20%
2. cinerins agricultural chemicals: 0.2-20%
3. emulsifier: 3-10%
4. solubilizer: 0.2-18%
5. organic solvent: all the other add to 100% with organic solvent
Adding water to 45 public very heavy with every mu of cotton field 50-100 milliliter below is example, its proportioning:
1. organophosphorous pesticide is selected the flolimat of content 65%: 10-20% for use
2. the cinerins agricultural chemicals is selected cypermethrin for use: 0.5-8%
3. emulsifier is selected farming breast No. 500 or OP-10:3-10% for use
4. solubilizer is selected the compound of ethanol, isopropyl alcohol and Ah azoles, synergy phosphorus: 0.2-18% for use
5. organic solvent is selected toluene for use: add to 100%
Other each proportioning of forming and roughly the same above-mentioned.Configuration back dilution 4000-8000 doubly, and is promptly sprayable.
This cream pesticide can dispose under 30-100 ℃ of temperature, as long as cream pesticide is placed in the container heats slightly, helps like this mixing during operation.
The present invention will have the organophosphorus insecticide of interior absorption and pyrethroid pesticide and carry out compositely, can remedy the deficiency of absorption in the cinerins medicament, can improve the organic phosphorous insecticide control efficiency again, reduce the pyrethroid pesticide price simultaneously.
The present invention has studied the composite and consumption test of a series of cinerins agricultural chemicals and organophosphorus insecticide and emulsifier, organic solvent, through the control test of sub-district, cotton land for growing field crops second-generation cotton bollworm, prove that it is respond well (for details see attached table: Hebei province on the 16th Nangong City cotton boll killed missible oil and prevented and treated the resistance second-generation cotton bollworm and prevent and treat application form as a result July in 1993).Cotton boll kills the missible oil cost and reduces by 8.3% than chrysanthemum ester class, and cotton boll kills missible oil and is mainly used in except that preventing and treating the pesticide resistance cotton bollworm, also to vegetables, fruit tree, wheat, pine tree anti-ly eliminate aphis, insects such as two spotted spider mite, pine caterpillars also have the better prevention effect.
This cotton boll kills the oily liquids that missible oil is yellowish-brown or light brown red, and is soluble in water, can prepare the even milky white liquid of any multiple.
It is a kind of high-efficiency low-toxicity broad spectrum insecticide that cotton boll kills missible oil, and absorption is strong and the power of tagging is strong in having concurrently, thereby drug effect is for a long time special rapidly, once sprays medicine, and the efficacy of a drug can keep 5 days.Process has the control test of the cotton bollworm of resistance to the area, Hebei, its effect has reached more than 90%.
Subordinate list: Nangong City, Hebei province cotton boll kills EC resistance second-generation cotton bollworm and prevents and treats as a result application form on July 16th, 1993
Claims (6)
1, a kind of crops missible oil insecticide includes machine phosphorus insecticide, cinerins agricultural chemicals, emulsifier, organic solvent, it is characterized in that having added in the insecticide solubilizer, and its proportioning is as follows: organophosphorous pesticide: 5-20%; Cinerins agricultural chemicals: 0.2-20%; Emulsifier: 3-10%; Solubilizer: 0.2-18%; All the other are organic solvent: add to 100%.
2, crops missible oil insecticide according to claim 1 is characterized in that above-mentioned organophosphorous pesticide selects Rogor, flolimat, malathion, phoxim, 1605 or 1059 respectively for use.
3, crops missible oil insecticide according to claim 1 is characterized in that above-mentioned pyrethroid is selected for use respectively to kill chrysanthemum ester, Chinese and Western chrysanthemum ester, cyhalothrin, sumicidin, cypermethrin, Permanone or decis.
4, crops missible oil insecticide according to claim 1 is characterized in that above-mentioned emulsifier select farming breast respectively for use No. 500, the polyvinyl chloride-based ether of nonyl phenol (OP-10, OP-7, OP-5), peregal, dodecyl sodium sulfate (ABS), straight chain dodecyl sodium sulfate (LAS), Myri45, Emcoleo-50 or Ninol.
5, crops missible oil insecticide according to claim 1 is characterized in that above-mentioned solubilizer selects ethanol, methyl alcohol, isopropyl alcohol, metallic stearate, Ah azoles (AZ), synergy phosphorus or sodium sulfosuccinate respectively for use.
6, crops missible oil insecticide according to claim 1 is characterized in that above-mentioned organic solvent selects benzene,toluene,xylene or acetone respectively for use, and their mixed solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93109797 CN1098850A (en) | 1993-08-20 | 1993-08-20 | Crops missible oil insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93109797 CN1098850A (en) | 1993-08-20 | 1993-08-20 | Crops missible oil insecticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1098850A true CN1098850A (en) | 1995-02-22 |
Family
ID=4987798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93109797 Withdrawn CN1098850A (en) | 1993-08-20 | 1993-08-20 | Crops missible oil insecticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1098850A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109662104A (en) * | 2017-10-13 | 2019-04-23 | 黄俊华 | A kind of contact insecticide |
| CN119867094A (en) * | 2025-03-26 | 2025-04-25 | 山东百农思达生物科技有限公司 | Compound emulsifiable concentrate pesticide for pest control and preparation method thereof |
-
1993
- 1993-08-20 CN CN 93109797 patent/CN1098850A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109662104A (en) * | 2017-10-13 | 2019-04-23 | 黄俊华 | A kind of contact insecticide |
| CN119867094A (en) * | 2025-03-26 | 2025-04-25 | 山东百农思达生物科技有限公司 | Compound emulsifiable concentrate pesticide for pest control and preparation method thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C03 | Withdrawal of patent application (patent law 1993) | ||
| WW01 | Invention patent application withdrawn after publication |