CN102456903A - Method for preparing hydrogen by utilizing formic acid electrolysis - Google Patents
Method for preparing hydrogen by utilizing formic acid electrolysis Download PDFInfo
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- CN102456903A CN102456903A CN2010105229057A CN201010522905A CN102456903A CN 102456903 A CN102456903 A CN 102456903A CN 2010105229057 A CN2010105229057 A CN 2010105229057A CN 201010522905 A CN201010522905 A CN 201010522905A CN 102456903 A CN102456903 A CN 102456903A
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- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 239000001257 hydrogen Substances 0.000 title claims abstract description 75
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 75
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 73
- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 62
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 235000019253 formic acid Nutrition 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims description 16
- 239000000446 fuel Substances 0.000 claims abstract description 36
- 239000012528 membrane Substances 0.000 claims abstract description 21
- 239000003792 electrolyte Substances 0.000 claims abstract description 7
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 238000007731 hot pressing Methods 0.000 claims abstract description 3
- 238000009792 diffusion process Methods 0.000 claims description 21
- 239000003054 catalyst Substances 0.000 claims description 17
- 238000000354 decomposition reaction Methods 0.000 claims description 13
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 7
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 7
- 238000006555 catalytic reaction Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 230000008878 coupling Effects 0.000 claims description 4
- 238000010168 coupling process Methods 0.000 claims description 4
- 238000005859 coupling reaction Methods 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910000510 noble metal Inorganic materials 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 101100135888 Mus musculus Pdia5 gene Proteins 0.000 claims description 2
- 229910021132 PdIr Inorganic materials 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 239000004744 fabric Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 20
- 238000005265 energy consumption Methods 0.000 abstract description 5
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000005518 polymer electrolyte Substances 0.000 abstract 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000013459 approach Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000012267 brine Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
本发明提供一种利用甲酸电解制取氢气的方法：以甲酸水溶液为燃料，以聚合物电解质膜电解器来电解制取氢气。将阳极、电解质膜和阴极依次叠放在一起，经热压后，构成电解电极，并将其夹紧于双极板之间构成聚合物电解质膜电解器。在电解器的阳极侧通入甲酸水溶液，于阴、阳两极间施加电压，使甲酸在阳极发生电催化氧化反应，在阴极侧产生氢气。本发明是一种便捷、快速及灵活的小规模现场制氢方法，具有电解电压低、能耗小、制氢效率高等优点。
The invention provides a method for producing hydrogen by using formic acid electrolysis: using formic acid aqueous solution as fuel and using a polymer electrolyte membrane electrolyzer to electrolyze and produce hydrogen. The anode, the electrolyte membrane and the cathode are stacked together in turn, and after hot pressing, the electrolysis electrode is formed, and it is clamped between the bipolar plates to form the polymer electrolyte membrane electrolyzer. The formic acid aqueous solution is fed into the anode side of the electrolyzer, and a voltage is applied between the cathode and the anode, so that the formic acid undergoes an electrocatalytic oxidation reaction at the anode, and hydrogen gas is generated at the cathode side. The invention is a convenient, fast and flexible small-scale on-site hydrogen production method, which has the advantages of low electrolysis voltage, low energy consumption, high hydrogen production efficiency and the like.
Description
Technical field
The present invention relates to a kind of hydrogen method of producing based on the solid polymer dielectric film electrolyzer.With the aqueous formic acid is anode electrolysis fuel, applies certain voltage in the cathode and anode both sides, makes formic acid generation electrocatalysis oxidation reaction; The proton that anode-side produces conducts to cathode side through film, and combines to generate hydrogen again in electronics.
Background technology
It is abundant that Hydrogen Energy has the source, and the characteristics of clean and effective are might be at the secondary energy sources of the very important effect of performance on the 21 century world energy sources stage.And be that Proton Exchange Membrane Fuel Cells (PEMFC) technology of fuel has obtained significant progress in recent years with hydrogen.Fuel cell might solve " energy " and " environmental protection " this two big worlds difficult problem, and will be significant for human social.Yet, how to realize economy, to produce hydrogen efficiently most important to the Hydrogen Energy expanding economy.
At present, the method for small-scale hydrogen manufacturing commonly used mainly contains methyl alcohol/gas renormalizing hydrogen manufacturing and water electrolysis hydrogen producing dual mode.Wherein, the course of reaction of reformation hydrogen production is complicated, and system is huge, and is poor to equipment requirements height and mobility; And electrolytic hydrogen production has that device is simple, equipment moulding, the characteristics that are easy to use, is highly suitable for on-the-spot hydrogen manufacturing and application on a small scale.
The electrolysis unit that is used for electrolytic hydrogen production mainly contains two types.A kind of is the alkaline electrolysis device, promptly in electrolytic cell, adds a certain amount of alkali or salt to strengthen conductivity, obtains hydrogen and oxygen respectively in anode and cathode, utilizes this electrolysis unit brine electrolysis to produce hydrogen and still has high, the less economical problem of energy consumption; The another kind of electrolyzer (Solid-PEM electrolyzer) that just is based on the solid electrolyte film type.This device has simple to operate, and anode and cathode separately and can keep certain partial pressure avoids the use of advantage such as alkali lye and in industry, is used widely.
Because water electrolysis hydrogen production, its theoretical decomposition voltage is 1.23V, and in the actual electrolytic hydrogen production process, owing to there is certain loss, its decomposition voltage is up to more than the 1.4-1.5V; And high energy consumption is to realize the very big obstacle of extensive water electrolysis hydrogen producing.Formic acid is as liquid fuel and hydrogen source, have to be easy to carry, hydrogen content high (4.3%), advantages of environment protection, and the most important thing is its theoretical decomposition voltage low (have only-0.02V).These characteristics make formic acid electrolytic hydrogen production required voltage be significantly less than the water electrolysis hydrogen producing required voltage, save the consumption of electric energy greatly, also for the on-the-spot hydrogen manufacturing of small-scale new approaches are provided.
Summary of the invention
The object of the present invention is to provide a kind of energy-conservation, efficiently, the on-the-spot method of producing hydrogen easily.
For realizing above-mentioned purpose, the technical scheme that the present invention adopts is:
With the aqueous formic acid is fuel, adopts the electrolyzer of solid polymer dielectric film to produce hydrogen;
Specifically may further comprise the steps: between electrolysis electrode anode and negative electrode, apply decomposition voltage, and, make formic acid at anode generation electrocatalysis oxidation reaction in the aqueous formic acid of the anode-side feeding>=2M of electrolysis electrode, the electric current that produces electrolysis, current density is 50-350mA/cm
2, produce hydrogen at cathode side; The electrolyzer temperature is controlled between 20-70 ℃.
The solid polymer dielectric film electrolyzer comprises plate, cathode plate and places the electrolysis electrode between pole plate; Electrolysis electrode is clamped in formation polymer dielectric film electrolyzer between two pole plates, and pole plate is provided with the flow field near electrolysis electrode one side.
The preparation of electrolysis electrode: after electrolysis electrode was superimposed together by cathode diffusion layer, cathode catalysis layer, dielectric film, anode catalyst layer, anode diffusion layer successively, hot pressing 1-5min under 1000-2000 pound pressure formed electrolysis electrode.
On cathode diffusion layer, scribble Pt/C or Pd/C catalyst, form cathode catalysis layer, and constitute the negative electrode of electrolysis electrode with cathode diffusion layer; Cathode catalysis layer noble metal carrying capacity is 1-2mg/cm
2
On anode diffusion layer, scribble Pd/C, PdAu/C, PdSn/C, a kind of catalyst among the PdIr/C or two or more catalyst combination form anode catalyst layer, and constitute the anode of electrolysis electrode with anode diffusion layer.Anode catalyst layer noble metal carrying capacity is 2-5mg/cm
2
Electrolyte membrane
Series film or
in a modified membrane.
The cathode and anode diffusion layer of electrode is carbon paper, carbon cloth or the carbon felt that adopts the PTFE hydrophobic to handle, and wherein PTFE quality percentage composition is 10-30%.
During electrolysis, negative electrode can feed the N of 20-40sccm
2, hydrogen is taken out of, or is not fed gas (the hydrogen self-diffusion goes out negative electrode).The charging flow velocity of electrolyte formic acid is 1-5ml/min.
The concentration optimum of electrolyte formic acid is 6-10M.The decomposition voltage that applies between the anode of electrolysis electrode and negative electrode is generally 0.3-1V.
Its hydrogen that is produced by negative electrode adopts drainage to collect or the use that directly acts as a fuel;
Directly act as a fuel when using; With formic acid is fuel; Hydrogen that the polymer dielectric film electrolyzer is produced and Proton Exchange Membrane Fuel Cells coupling; The hydrogen that makes collects and directly feeds the anode of Proton Exchange Membrane Fuel Cells (PEMFC) through self-diffusion, as anode reaction fuel, produce electric energy.
The formic acid that utilizes according to the invention is electrolysis fuel, comes electrolysis to produce the method for hydrogen with the polymer dielectric film electrolyzer.Comparing with traditional reformation hydrogen production is a kind of simple, convenient, hydrogen production process fast and flexibly; Compare with other electrolysis fuel electrolytic hydrogen productions such as utilizing water or methyl alcohol, have the advantage that decomposition voltage is low, energy consumption is little, hydrogen production efficiency is high.This method of producing hydrogen can combine with primary energy such as solar energy, wind energies; Utilize primary energy cheap and easy to get that electric power is provided; With formic acid is fuel, and hydrogen is produced in on-the-spot electrolysis, and small-sized removable power-supply device such as fueling battery car uses or stores.The present invention also for the on-the-spot hydrogen manufacturing of small-scale provides new approaches and approach, helps further promoting the Hydrogen Energy expanding economy to realize with final when reducing the electrolytic hydrogen production energy consumption.
Description of drawings
Fig. 1 formic acid electrolysis hydrogen production device sketch map.
Wherein, a is the anode-side of electrolyzer; B is the cathode side of electrolyzer; C is a dielectric film; D is a DC power supply.
Fig. 2 is 60 ℃, under the 1V decomposition voltage, and during different aqueous formic acid concentration charging, the variation relation of Faradaic current and hydrogen-producing speed.
Fig. 3 is 60 ℃, during the charging of 6M aqueous formic acid, and the variation tendency of the Faradaic current under the different decomposition voltages.
Fig. 4 is for to produce hydrogen and Proton Exchange Membrane Fuel Cells (PEMFC) coupling sketch map with formic acid for the fuel electrolysis.
Wherein, 1 is No. 5 batteries of a joint, rated voltage 1.5V; 2 is the anode of electrolyzer; 3 is the negative electrode of electrolyzer; 4 is dielectric film; 5 is the anode of Proton Exchange Membrane Fuel Cells; 6 is the negative electrode of Proton Exchange Membrane Fuel Cells; 7 is small fan; 8 is hydrogen pipeline; Circuit connection is represented with single solid line.
Embodiment
Assemble the polymer dielectric film electrolyzer by Fig. 1, the carbon paper (Toray-060) that its cathode and anode diffusion layer adopts the PTFE hydrophobic to handle, wherein anode PTFE quality percentage composition is 15%, negative electrode PTFE quality percentage composition is 30%.Anode catalyst is Pd/C, is sprayed on the anode diffusion layer, and loading is 2mg/cm
2Cathod catalyst is Pt/C, is sprayed on the cathode diffusion layer, and carrying capacity is 1mg/cm
2Dielectric film does
-115 films, electrode effective area are 4cm
2The formic acid solution of 2-10M is fed the anode of electrolyzer with the flow velocity of 1ml/min, and negative electrode feeds nitrogen, and its flow velocity is 20sccm.Use PAR273A electrochemical workstation (potentiostat/galvanostat; The Princeton application study) as DC power supply; Apply 0.3-1V voltage at the electrolytic cell two ends; The electrolytic cell temperature is controlled at makes formic acid generation electrocatalysis oxidation reaction under 60 ℃, negative electrode adopts drainage to collect hydrogen, and calculates hydrogen-producing speed.
Fig. 2 is 60 ℃, under the 1V decomposition voltage, and during different aqueous formic acid concentration charging, the variation relation of Faradaic current and hydrogen-producing speed.Can find out that Faradaic current and hydrogen-producing speed are the trend that raises and reduce earlier with formic acid concn; Wherein when aqueous formic acid concentration was 8M, current density reached 314mA/cm
2, hydrogen-producing speed is 9.5ml/min.
Fig. 3 is 60 ℃, during the charging of 6M formic acid, and the variation tendency of the Faradaic current under the different decomposition voltages.Raise with decomposition voltage, electrolysis performance (electric current) also increases.When 0.6V, current density reaches 110mA/cm
2
Embodiment 2:
Fig. 4 produces hydrogen and Proton Exchange Membrane Fuel Cells (PEMFC) coupling instance for being fuel with the aqueous formic acid with the electrolysis of polymer dielectric film electrolyzer.
Electrolysis power is joint No. 5 batteries (rated voltage 1.5V) among the figure; Electrolyzer is that two electrolysis electrodes are in series, and constitutes with bipolar plates.Owing to there is ohmic loss, the voltage of surveying two series connection electrolysis electrodes is all in the 0.65-0.68V scope.
The anode catalyst of electrolysis electrode is Pd/C, and loading is 3mg/cm
2, cathod catalyst is Pt/C, loading is 1mg/cm
2, electrode area is 16cm altogether
2
Proton Exchange Membrane Fuel Cells among the figure (PEMFC) cathode and anode catalyst is Pt/C, and loading is 0.4mg/cm
2, and negative electrode adopts air from breathing pattern, and electrode area is 8cm
2
The anode formic acid feed cavity volume of electrolyzer is 20ml among the figure, and aqueous formic acid concentration is 8M, and the hydrogen that negative electrode produces is through the anode-side of pipeline self-diffusion to Proton Exchange Membrane Fuel Cells, as the anode reaction fuel of Proton Exchange Membrane Fuel Cells.
During test, the whole system circuit is connected, the anode generation formic acid electrocatalysis oxidation reaction of electrolyzer produces hydrogen at cathode side.The hydrogen that produces is accumulative total in the negative electrode cavity of electrolyzer, and diffuse in the anode cavities of Proton Exchange Membrane Fuel Cells, as its anode reaction fuel.Produce electric energy under the common reaction of the oxygen of Proton Exchange Membrane Fuel Cells in anode hydrogen gas, cathode air, driven small fan work.
Claims (10)
1. a method of utilizing the formic acid electrolysis to produce hydrogen is characterized in that, is fuel with the aqueous formic acid, adopts the electrolyzer of solid polymer dielectric film to produce hydrogen;
Specifically may further comprise the steps: between electrolysis electrode anode and negative electrode, apply decomposition voltage, and in the aqueous formic acid of the anode-side feeding >=2M of electrolysis electrode, make formic acid at anode generation electrocatalysis oxidation reaction, the electric current that produces electrolysis produces hydrogen at cathode side; The electrolyzer temperature is controlled between 20-70 ℃.
2. utilize the formic acid electrolysis to produce the method for hydrogen according to claim 1, it is characterized in that:
The solid polymer dielectric film electrolyzer comprises plate, cathode plate and places the electrolysis electrode between pole plate; Electrolysis electrode is clamped in formation polymer dielectric film electrolyzer between two pole plates, and pole plate is provided with the flow field near electrolysis electrode one side.
3. like the said method of utilizing the formic acid electrolysis to produce hydrogen of claim 2, it is characterized in that:
The preparation of electrolysis electrode: after electrolysis electrode was superimposed together by cathode diffusion layer, cathode catalysis layer, dielectric film, anode catalyst layer, anode diffusion layer successively, hot pressing 1-5min under 1000-2000 pound pressure formed electrolysis electrode.
4. like the said method of utilizing the formic acid electrolysis to produce hydrogen of claim 3, it is characterized in that: on cathode diffusion layer, scribble Pt/C or Pd/C catalyst, form cathode catalysis layer, and constitute the negative electrode of electrolysis electrode with cathode diffusion layer; Cathode catalysis layer noble metal carrying capacity is 1-2mg/cm
2On anode diffusion layer, scribble Pd/C, PdAu/C, PdSn/C, a kind of catalyst among the PdIr/C or two or more catalyst combination form anode catalyst layer, and constitute the anode of electrolysis electrode with anode diffusion layer.Anode catalyst layer noble metal carrying capacity is 2-5mg/cm
2
Electrolyte membrane
series film or
modified membrane in one.
5. like claim 3 or the 4 said methods of utilizing the formic acid electrolysis to produce hydrogen, it is characterized in that: the cathode and anode diffusion layer of electrode is carbon paper, carbon cloth or the carbon felt that adopts the PTFE hydrophobic to handle, and wherein PTFE quality percentage composition is 10-30%.
6. utilize the preparation method of formic acid electrolysis hydrogen according to claim 1, it is characterized in that: during electrolysis, negative electrode feeds the N of 20-40sccm
2
7. utilize the formic acid electrolysis to produce the method for hydrogen according to claim 1, it is characterized in that: the charging flow velocity of electrolyte formic acid is 1-5ml/min.
8. utilize the formic acid electrolysis to produce the method for hydrogen according to claim 1, it is characterized in that: the optimum 6-10M of being of the concentration of electrolyte formic acid.
9. utilize the formic acid electrolysis to produce the method for hydrogen according to claim 1, it is characterized in that: the decomposition voltage that applies between electrolysis electrode anode and negative electrode is 0.3-1V.
10. utilize the formic acid electrolysis to produce the method for hydrogen according to claim 1, it is characterized in that: its hydrogen that is produced by negative electrode adopts drainage to collect or the use that directly acts as a fuel;
Directly act as a fuel when using; With formic acid is fuel, hydrogen that the polymer dielectric film electrolyzer is produced and Proton Exchange Membrane Fuel Cells coupling, and the hydrogen that makes collects and directly feeds the anode of Proton Exchange Membrane Fuel Cells PEMFC through self-diffusion; As anode reaction fuel, produce electric energy.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014045049A1 (en) * | 2012-09-21 | 2014-03-27 | Ucl Business Plc | Electrolysis electrocatalyst |
| JP2021130600A (en) * | 2020-02-21 | 2021-09-09 | 株式会社カレントダイナミックス | High-pressure hydrogen production method |
| CN114481164A (en) * | 2021-02-25 | 2022-05-13 | 四川大学 | Non-pure aqueous solution electrolytic hydrogen production device, system and method based on liquid phase moisture absorption |
| CN116121788A (en) * | 2023-02-24 | 2023-05-16 | 兰州大学 | A device for preparing formic acid and hydrogen |
| CN118343675A (en) * | 2024-05-15 | 2024-07-16 | 北京理工大学 | A flat tube type methane steam catalytic reforming hydrogen production device based on proton membrane reactor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1896317A (en) * | 2006-06-22 | 2007-01-17 | 上海交通大学 | Hydrogen maker for electrolyzing organic solution with polymer electrolyte film |
| CN101239277A (en) * | 2007-11-27 | 2008-08-13 | 江苏雷石新能源科技有限公司 | Electrochemical treatment method and special device for direct liquid fuel cell exhaust gas |
-
2010
- 2010-10-27 CN CN2010105229057A patent/CN102456903A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1896317A (en) * | 2006-06-22 | 2007-01-17 | 上海交通大学 | Hydrogen maker for electrolyzing organic solution with polymer electrolyte film |
| CN101239277A (en) * | 2007-11-27 | 2008-08-13 | 江苏雷石新能源科技有限公司 | Electrochemical treatment method and special device for direct liquid fuel cell exhaust gas |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014045049A1 (en) * | 2012-09-21 | 2014-03-27 | Ucl Business Plc | Electrolysis electrocatalyst |
| CN104797742A (en) * | 2012-09-21 | 2015-07-22 | Ucl商业有限公司 | electrolytic electrocatalyst |
| JP2021130600A (en) * | 2020-02-21 | 2021-09-09 | 株式会社カレントダイナミックス | High-pressure hydrogen production method |
| JP7435953B2 (en) | 2020-02-21 | 2024-02-21 | 株式会社カレントダイナミックス | High pressure hydrogen generation method |
| CN114481164A (en) * | 2021-02-25 | 2022-05-13 | 四川大学 | Non-pure aqueous solution electrolytic hydrogen production device, system and method based on liquid phase moisture absorption |
| CN116121788A (en) * | 2023-02-24 | 2023-05-16 | 兰州大学 | A device for preparing formic acid and hydrogen |
| CN116121788B (en) * | 2023-02-24 | 2023-08-18 | 兰州大学 | A device for preparing formic acid and hydrogen |
| CN118343675A (en) * | 2024-05-15 | 2024-07-16 | 北京理工大学 | A flat tube type methane steam catalytic reforming hydrogen production device based on proton membrane reactor |
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Application publication date: 20120516 |