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CN102017800A - Organic el display panel - Google Patents

Organic el display panel Download PDF

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CN102017800A
CN102017800A CN2010800014216A CN201080001421A CN102017800A CN 102017800 A CN102017800 A CN 102017800A CN 2010800014216 A CN2010800014216 A CN 2010800014216A CN 201080001421 A CN201080001421 A CN 201080001421A CN 102017800 A CN102017800 A CN 102017800A
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organic
pixel
substrate
functional layer
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CN102017800B (en
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吉田英博
奥本健二
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Magno Bolan Co ltd
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Matsushita Electric Industrial Co Ltd
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00Electroluminescent light sources
    • H05B33/10Apparatus or processes specially adapted to the manufacture of electroluminescent light sources
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30Devices specially adapted for multicolour light emission
    • H10K59/35Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • H10K59/122Pixel-defining structures or layers, e.g. banks
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/17Passive-matrix OLED displays
    • H10K59/173Passive-matrix OLED displays comprising banks or shadow masks

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electroluminescent Light Sources (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Abstract

Disclosed is an organic EL display panel that has: a substrate having at least two line-shaped color-producing regions; and at least two subpixels arranged in one row in the color-producing regions. The color-producing regions include a color-producing region in which red-light-emitting subpixels are arranged, a color-producing region in which green-light-emitting subpixels are arranged, and a color-producing region in which blue-light-emitting subpixels are arranged. Each subpixel has: a pixel electrode; an organic functional layer formed as a coating on top of the pixel electrode; an opposing electrode disposed on top of the organic functional layer; and a forward-tapered bank that constitutes the wall of the region in which the organic functional layer is formed. Letting the angle of inclination of the surface of said wall on the side of the edge of the substrate be a, and letting the angle of inclination of the surface of said wall on the side of the center of the substrate be ss, a is less than ss for subpixels X arranged in color-producing regions X located on the edge of the substrate.

Description

有机电致发光显示面板 Organic Electroluminescent Display Panel

技术领域technical field

本发明涉及有机EL(Electroluminescent:电致发光)显示面板。The present invention relates to an organic EL (Electroluminescent: electroluminescence) display panel.

背景技术Background technique

有机EL显示面板是具有发光元件(有机EL元件)的显示面板,所述发光元件利用了有机化合物的电致发光现象。The organic EL display panel is a display panel having light-emitting elements (organic EL elements) that utilize the electroluminescence phenomenon of organic compounds.

在基板上矩阵状地配置RGB三色的子像素(有机EL元件)而制造有机EL显示面板。RGB三色的有机EL元件构成一个像素。通过在基板上层叠像素电极(例如,阳极)、有机发光层、对向电极(例如,阴极),制造各个有机EL元件。另外,有时也层叠电子输入层、电子输送层、空穴输送层或空穴输入层等功能层。An organic EL display panel is manufactured by arranging RGB sub-pixels (organic EL elements) in a matrix on a substrate. Organic EL elements of three colors of RGB constitute one pixel. Each organic EL element is manufactured by laminating a pixel electrode (eg, anode), an organic light-emitting layer, and a counter electrode (eg, cathode) on a substrate. In addition, functional layers such as an electron input layer, an electron transport layer, a hole transport layer, or a hole input layer are sometimes laminated.

有机发光元件可以分类为:发出红色光的有机发光元件R、发出绿色光的有机发光元件G以及发出蓝色光的有机发光元件B。有时作为使各个有机发光元件所包含的有机发光层都发出白色光的有机发光层,通过彩色滤色片对白色光进行着色,但也可以对每个有机发光元件,配置发出红色光的有机发光层,发出绿色光的有机发光层或发出蓝色光的有机发光层。Organic light emitting elements can be classified into organic light emitting elements R that emit red light, organic light emitting elements G that emit green light, and organic light emitting elements B that emit blue light. In some cases, as an organic light-emitting layer that makes the organic light-emitting layer included in each organic light-emitting element emit white light, white light is colored by a color filter, but it is also possible to arrange an organic light-emitting layer that emits red light for each organic light-emitting element. layer, an organic light-emitting layer that emits green light or an organic light-emitting layer that emits blue light.

例如,通过在基板上涂覆功能层的材料液并使其干燥而形成有机发光层、空穴输入层、或空穴输送层等功能层。更具体而言,通过由树脂等构成的隔堤对每个RGB规定形成功能层的区域,在由隔堤规定的区域内,涂覆功能层的材料液并使其干燥,从而形成功能层。For example, a functional layer such as an organic light-emitting layer, a hole input layer, or a hole transport layer is formed by coating a material solution for the functional layer on a substrate and drying it. More specifically, a functional layer formation area is defined for each RGB by a bank made of resin or the like, and a functional layer material liquid is applied and dried in the area defined by the bank to form a functional layer.

这样,在通过涂覆法形成功能层时,有时在面板的端部的形成区域(形成功能层的区域)和面板的中央部的形成区域,功能层的材料液的干燥速度不同。材料液的干燥速度对干燥后的功能层的形状造成影响。因此,若材料液的干燥速度不同,则所形成的功能层形状轮廓(profile)和膜厚也不同。像素间的功能层的膜厚不均造成显示器中的亮度不均。In this way, when the functional layer is formed by the coating method, the drying speed of the material liquid of the functional layer may differ between the formation region at the edge of the panel (the region where the functional layer is formed) and the formation region at the center of the panel. The drying speed of the material liquid affects the shape of the dried functional layer. Therefore, if the drying speed of the material liquid is different, the shape profile and film thickness of the formed functional layer will also be different. The uneven film thickness of the functional layer between pixels causes uneven luminance in the display.

为了解决这样的问题,提出了在使面板的端部的形成区域(形成功能层的空间)大于面板的中央部的形成区域的技术(例如,参照专利文献1)。在专利文献1中,使面板的端部的形成区域大于面板的中央部的形成区域,并且根据形成区域的大小而增加功能层的材料液,由此对在面板的中央部和面板的端部之间产生的材料液的干燥速度不均进行校正。In order to solve such a problem, it has been proposed to make the formation area (space where the functional layer is formed) at the edge of the panel larger than the formation area at the center of the panel (for example, refer to Patent Document 1). In Patent Document 1, the formation area of the edge portion of the panel is made larger than the formation area of the central portion of the panel, and the material liquid of the functional layer is increased according to the size of the formation area, so that the formation area of the central portion of the panel and the edge portion of the panel are aligned. The unevenness in the drying speed of the material liquid that occurs between them is corrected.

另外,也提出了下述技术,即,通过使涂覆在面板的端部的形成区域的材料液所包含的溶剂的量多于涂覆在面板中央部的形成区域的材料液所包含的溶剂的量,对在面板的中央部和面板的端部之间产生的材料液的干燥速度不均进行校正(例如,参照专利文献2)。In addition, a technique has also been proposed in which the amount of solvent contained in the material liquid applied to the forming region at the edge of the panel is larger than the amount of solvent contained in the material liquid applied to the forming region at the center of the panel. The unevenness in the drying speed of the material liquid that occurs between the center of the panel and the edge of the panel is corrected (for example, refer to Patent Document 2).

另外,也提出了下述技术,即,为了防止因面板的中央部和面板的端部之间的干燥速度不均造成的显示器的亮度不均,在矩阵状地配置了像素的发色区域的外周部设置没有像素电极的形成区域(空(dummy)区域)(例如参照专利文献3至专利文献6)。In addition, a technique has been proposed in which, in order to prevent uneven luminance of a display caused by uneven drying speed between the center portion of the panel and the edge portions of the panel, a technology is proposed in which pixels are arranged in a matrix in color-emitting regions. A region (dummy region) where no pixel electrode is formed is provided on the outer peripheral portion (for example, refer to Patent Document 3 to Patent Document 6).

这样若在发光区域的外周部设置空的区域,并且在空区域也涂覆材料液,则在非发光区域的空区域形成膜厚不均匀的功能层,但是降低面板中央的发光区域的材料液的干燥速度的偏差,从而在像素间功能层的膜厚变得均匀。因此,能够降低显示器的亮度不均。In this way, if an empty area is provided on the outer periphery of the light-emitting area, and the material liquid is also applied to the empty area, a functional layer with uneven film thickness will be formed in the empty area of the non-light-emitting area, but the material liquid in the light-emitting area in the center of the panel will be reduced. The deviation of the drying speed, so that the film thickness of the functional layer between the pixels becomes uniform. Therefore, uneven brightness of the display can be reduced.

另外,涂覆形成的功能层的形状轮廓因溶液的溶质或溶剂的种类以及它们的含有比例而不同。例如,在要涂覆形成有机发光元件的各色的彩色滤色膜时,对于每种颜色,涂覆的溶液的溶质不同。因此,隔堤(bank)的高度或锥角的角度相同时,对于每种颜色,彩色滤色膜的形状也容易不同。因此,报告了下述技术,即,对每个彩色滤色膜的颜色,变更隔堤的高度或锥角的角度,提高彩色滤色膜的膜厚均匀性(例如参照专利文献7)。In addition, the shape profile of the functional layer formed by coating differs depending on the type of solute or solvent of the solution and their content ratio. For example, when coating color filters of various colors that form an organic light-emitting element, the solute of the solution to be coated is different for each color. Therefore, when the height of the bank or the angle of the taper angle is the same, the shape of the color filter is likely to be different for each color. Therefore, a technology has been reported to improve the film thickness uniformity of the color filter by changing the height of the bank or the angle of the taper angle for each color of the color filter (for example, refer to Patent Document 7).

另外,已知有下述技术,即,为了提高从有机EL元件的光的取出效率,将像素电极或对向电极中的一方设定为透明电极而且将另一方设定为反射电极,在反射电极和有机发光层之间通过溅射法等配置透明导电膜(例如参照专利文献8)。进而,通过配置在反射电极和有机发光层之间的透明导电膜来调整从有机发光层至反射电极为止的光学距离,由反射电极反射后朝向透明电极的光和直接朝向透明电极的光相互增强,从而能够提高光的取出效率。In addition, there is known a technique in which one of the pixel electrode or the counter electrode is set as a transparent electrode and the other is set as a reflective electrode in order to improve the light extraction efficiency from the organic EL element. A transparent conductive film is disposed between the electrodes and the organic light-emitting layer by sputtering or the like (for example, refer to Patent Document 8). Furthermore, the optical distance from the organic light-emitting layer to the reflective electrode is adjusted by the transparent conductive film arranged between the reflective electrode and the organic light-emitting layer, and the light reflected by the reflective electrode and directed to the transparent electrode and the light directly directed to the transparent electrode are mutually enhanced. , so that the light extraction efficiency can be improved.

专利文献patent documents

专利文献1:(日本)特开2008-16205号公报Patent Document 1: (Japanese) Unexamined Patent Publication No. 2008-16205

专利文献2:(日本)特开2006-260779号公报Patent Document 2: (Japanese) Unexamined Patent Publication No. 2006-260779

专利文献3:(日本)特开2007-103349号公报Patent Document 3: (Japanese) Unexamined Patent Publication No. 2007-103349

专利文献4:(日本)特开2006-3870号公报Patent Document 4: (Japanese) Unexamined Patent Publication No. 2006-3870

专利文献5:美国专利申请公开第2007/0052199号说明书Patent Document 5: Specification of US Patent Application Publication No. 2007/0052199

专利文献6:美国专利第7459177号专利说明书Patent Document 6: US Patent No. 7459177 Patent Specification

专利文献7:(日本)特开2007-310156号公报Patent Document 7: (Japanese) Unexamined Patent Publication No. 2007-310156

专利文献8:(日本)特开2003-272855号公报Patent Document 8: (Japanese) Unexamined Patent Publication No. 2003-272855

但是,如专利文献1或专利文献2公开的技术那样,即使在有机EL显示器的端部和中央部对干燥速度的不均进行校正,也无法消除像素间功能层的形状偏差的问题。这样,若功能层的形状在像素间存在偏差,则有机EL显示面板的亮度存在偏差。However, as in the techniques disclosed in Patent Document 1 or Patent Document 2, even if the unevenness in the drying speed is corrected at the edge and center of the organic EL display, the problem of shape variation of the functional layer between pixels cannot be eliminated. In this way, if the shape of the functional layer varies between pixels, the luminance of the organic EL display panel varies.

以下,参照图1至图D说明像素间功能层的形状存在偏差的机理。Hereinafter, the mechanism of the variation in the shape of the functional layer between pixels will be described with reference to FIGS. 1 to 1D .

图1A是形成功能层之前的有机EL显示面板的剖面图。图1A所示的有机EL显示面板具有排列在基板110上的子像素(有机EL元件)130R、130G、130B。各个子像素具有配置在基板110上的隔堤170。子像素130R是发出红色光的子像素,子像素130G是发出绿色光的子像素,子像素130B是发出蓝色光的子像素。有机EL显示面板包括:配置在面板的端部的子像素130RX和配置在面板的中央部的子像素130RY。FIG. 1A is a cross-sectional view of an organic EL display panel before forming a functional layer. The organic EL display panel shown in FIG. 1A has sub-pixels (organic EL elements) 130R, 130G, and 130B arranged on a substrate 110 . Each sub-pixel has a bank 170 disposed on the substrate 110 . The sub-pixel 130R is a sub-pixel that emits red light, the sub-pixel 130G is a sub-pixel that emits green light, and the sub-pixel 130B is a sub-pixel that emits blue light. The organic EL display panel includes sub-pixels 130RX arranged at the ends of the panel and sub-pixels 130RY arranged at the center of the panel.

图1B表示在由隔堤170规定的区域涂覆功能层的材料液140的情形,图1C表示在由隔堤170规定的区域内的功能层的材料液140干燥的情形。在有机EL显示面板的端部,材料液140的溶剂的蒸气浓度较低,所以能够促进功能层的材料液140的干燥。涂覆后的材料液140朝干燥速度快的一方对流,所以子像素130RX内的功能层180的材料液140被拉向面板的端部侧。FIG. 1B shows a state in which the functional layer material solution 140 is coated on the area defined by the bank 170 , and FIG. 1C shows a state in which the functional layer material liquid 140 is dried in the area defined by the bank 170 . At the edge of the organic EL display panel, the solvent vapor concentration of the material liquid 140 is low, so drying of the material liquid 140 of the functional layer can be accelerated. Since the applied material liquid 140 convects toward the side with a faster drying speed, the material liquid 140 of the functional layer 180 in the sub-pixel 130RX is pulled toward the edge of the panel.

图1D表示形成功能层180的形状。另外,图2A是图1D所示的子像素130RX的放大图,图2B是图1D所示的子像素的130RY的放大图。如上所述,在材料液140的干燥中,子像素130RX内的材料液140被拉向面板的端部侧,所以形成子像素130RX的功能层180的基板的端部侧的边缘181较高,而基板中央部侧的边缘182较低。这样在通过涂覆法形成了功能层时,配置在基板的端部的子像素的功能层偏向基板的端部侧。因此,子像素130RX的功能层180的膜厚T也比子像素130RY的功能层180的膜厚T’薄。FIG. 1D shows the shape of the functional layer 180 . In addition, FIG. 2A is an enlarged view of the sub-pixel 130RX shown in FIG. 1D , and FIG. 2B is an enlarged view of the sub-pixel 130RY shown in FIG. 1D . As described above, during the drying of the material liquid 140, the material liquid 140 in the sub-pixel 130RX is pulled toward the end side of the panel, so the edge 181 of the end side of the substrate forming the functional layer 180 of the sub-pixel 130RX is higher, On the other hand, the edge 182 on the central side of the substrate is lower. In this way, when the functional layer is formed by the coating method, the functional layer of the sub-pixel arranged at the edge of the substrate is shifted toward the edge of the substrate. Therefore, the film thickness T of the functional layer 180 of the sub-pixel 130RX is also thinner than the film thickness T' of the functional layer 180 of the sub-pixel 130RY.

发明内容Contents of the invention

本发明的目的在于,提供使显示面板内的功能层的形状一样的方法,而且提供没有亮度不均的有机EL显示面板。An object of the present invention is to provide a method for making the shapes of functional layers in a display panel uniform, and to provide an organic EL display panel free from uneven brightness.

发现在基板的端部的子像素中,通过调节由隔堤规定的涂覆区域的壁面的倾斜角度,能够对像素间的有机功能层的形状和膜厚的偏差进行校正,并且进一步研究而完成本发明。It was found that in the sub-pixels at the end of the substrate, by adjusting the inclination angle of the wall surface of the coating region defined by the bank, it is possible to correct the deviation in the shape and film thickness of the organic functional layer between pixels, and further studies have been completed. this invention.

也就是说,本发明涉及以下所述的有机EL显示面板。That is, the present invention relates to the organic EL display panel described below.

[1]、有机EL显示面板包括:基板,其具有平行的两个以上的线状的发色区域;以及两个以上的子像素,其一列地排列在所述发色区域,所述发色区域包含:排列了发出红色光的子像素的发色区域、排列了发出绿色光的子像素的发色区域以及排列了发出蓝色光的子像素的发色区域,所述子像素分别具有:像素电极,其配置在所述基板上;有机功能层,其涂覆形成在所述像素电极上;对向电极,其配置在所述有机功能层上;以及正锥形的隔堤,其构成用于形成所述有机功能层的区域的壁面,在将形成所述有机功能层的区域的壁面中的、所述基板的端部侧的壁面的倾斜角度设定为倾斜角度α,并且将形成所述有机功能层的区域的壁面中的、所述基板的中央侧的壁面的倾斜角度设定为倾斜角度β时,在排列在位于所述基板的端部的发色区域X的子像素X中,所述倾斜角度α小于所述倾斜角度β。[1] An organic EL display panel includes: a substrate having more than two parallel linear color-emitting areas; and two or more sub-pixels arranged in a row in the color-emitting areas, and the color-emitting areas The area includes: a color-emitting area in which sub-pixels emitting red light are arranged, a color-emitting area in which sub-pixels emitting green light are arranged, and a color-emitting area in which sub-pixels emitting blue light are arranged, and the sub-pixels respectively have: An electrode, which is arranged on the substrate; an organic functional layer, which is coated and formed on the pixel electrode; an opposite electrode, which is arranged on the organic functional layer; In the wall surface of the region where the organic functional layer is formed, the inclination angle of the wall surface on the end portion side of the substrate is set as an inclination angle α in the wall surface of the region where the organic functional layer is formed, and the Among the wall surfaces of the region of the organic functional layer, when the inclination angle of the wall surface on the central side of the substrate is set to an inclination angle β, in the sub-pixels X arranged in the color-emitting region X located at the end of the substrate , the inclination angle α is smaller than the inclination angle β.

[2]、如[1]所述的有机EL显示面板,所述子像素X中的所述倾斜角度α与所述倾斜角度β之差大于与所述子像素X发出同色的光且排列在位于所述基板的中央部的发色区域Y的子像素Y中的所述倾斜角度α与所述倾斜角度β之差。[2] In the organic EL display panel as described in [1], the difference between the inclination angle α and the inclination angle β in the sub-pixel X is greater than the light of the same color as that emitted by the sub-pixel X and is arranged in the The difference between the inclination angle α and the inclination angle β in the sub-pixel Y of the color-emitting region Y located in the central portion of the substrate.

[3]、如[1]或[2]中记载的有机EL显示面板,形成各个所述子像素具有的所述有机功能层的区域在四周由所述隔堤包围。[3] In the organic EL display panel described in [1] or [2], a region where the organic functional layer of each of the sub-pixels is formed is surrounded by the banks.

[4]、如[1]或[2]中记载的有机EL显示面板,形成一列地排列在所述发色区域内的两个以上的子像素具有的所述有机功能层的区域构成为由所述隔堤规定的、一个线状的区域。[4] In the organic EL display panel as described in [1] or [2], the region where the organic functional layer of the two or more sub-pixels arranged in a row in the color-emitting region is formed is composed of A linear area defined by the bank.

[5]、如[4]所述的有机EL显示面板,在一个所述线状的发色区域中,形成位于所述线方向的中央部的子像素具有的所述有机功能层的区域的壁面的倾斜角度大于形成位于所述线方向的端部的子像素具有的所述有机功能层的区域的壁面的倾斜角度。[5] In the organic EL display panel according to [4], in one of the linear color-emitting regions, the region of the organic functional layer of the sub-pixel located in the center of the linear direction is formed The inclination angle of the wall surface is larger than the inclination angle of the wall surface in a region where the sub-pixel located at the end in the line direction has the organic functional layer.

[6]、如[1]至[5]中任一个所述的有机EL显示面板,所述有机功能层包含有机发光层和空穴输送层。[6] The organic EL display panel according to any one of [1] to [5], wherein the organic functional layer includes an organic light emitting layer and a hole transport layer.

根据本发明,防止在基板端部的子像素中有机功能层偏向基板端部侧,从而能够使像素间有机功能层的形状和膜厚一样,并且能够提供亮度均匀的有机EL显示面板。According to the present invention, the organic functional layer is prevented from being biased toward the substrate end in sub-pixels at the substrate end, so that the shape and film thickness of the organic functional layer between pixels can be made uniform, and an organic EL display panel with uniform brightness can be provided.

附图说明Description of drawings

图1A至图1D是表示在通过涂覆法形成了功能层时的功能层的材料液的变化的图。1A to 1D are diagrams showing changes in a material solution of a functional layer when the functional layer is formed by a coating method.

图2A和图2B是表示通过涂覆法形成的功能层的图。2A and 2B are diagrams showing functional layers formed by a coating method.

图3A和图3B是表示实施方式1的有机EL显示面板的的图。3A and 3B are diagrams showing an organic EL display panel according to Embodiment 1. FIG.

图4A和图4B是实施方式1的有机EL显示面板所包含的子像素的剖面图。4A and 4B are cross-sectional views of sub-pixels included in the organic EL display panel of Embodiment 1. FIG.

图5A至图5D是表示隔堤的形成方法的图。5A to 5D are diagrams showing a method of forming a bank.

图6A至图6C是表示干燥过程中的有机功能层的材料液的变化的图。6A to 6C are diagrams showing changes in the material liquid of the organic functional layer during the drying process.

图7A至图7E是表示干燥过程中的有机功能层的材料液的变化的图。7A to 7E are diagrams showing changes in the material liquid of the organic functional layer during the drying process.

图8A和图8B是表示干燥中心点的图。8A and 8B are diagrams showing drying center points.

图9A和图9B是表示实施方式2的有机EL显示面板的图。9A and 9B are diagrams showing an organic EL display panel according to Embodiment 2. FIG.

图10A和图10B是实施方式2的有机EL显示面板所包含的线状涂覆区域的剖面图。10A and 10B are cross-sectional views of linear coating regions included in the organic EL display panel according to the second embodiment.

图11A和图11B是表示实施方式3的有机EL显示面板的图。11A and 11B are diagrams showing an organic EL display panel according to Embodiment 3. FIG.

图12A和图12B是实施方式3的有机EL显示面板所包含的子像素的剖面图。12A and 12B are cross-sectional views of sub-pixels included in the organic EL display panel according to Embodiment 3. FIG.

附图标记的说明Explanation of reference signs

100、101、102、103、104、105、106、107、108、200、300有机EL显示面板100, 101, 102, 103, 104, 105, 106, 107, 108, 200, 300 organic EL display panels

110基板110 substrate

120发色区域120 hair color areas

130子像素130 sub-pixels

140有机功能层的材料液140 Material solutions for organic functional layers

141液滴的端部141 The tip of the droplet

150、450像素电极150, 450 pixel electrodes

160金属氧化物膜160 metal oxide film

170格子状隔堤170 lattice dikes

171光敏性树脂膜171 photosensitive resin film

173线状隔堤173 linear dike

175、176涂敷区域175, 176 coating area

180有机功能层180 organic functional layers

181有机功能层的基板端部侧的边缘181 The edge of the substrate end side of the organic functional layer

182有机功能层的基板中央部侧的边缘182 The edge of the substrate center side of the organic functional layer

190半色调掩膜190 halftone masks

具体实施方式Detailed ways

本发明的有机EL显示面板包括基板和配置在基板上的多个子像素(有机EL元件)。The organic EL display panel of the present invention includes a substrate and a plurality of sub-pixels (organic EL elements) arranged on the substrate.

[基板][substrate]

基板具有相互平行的多个线状的发色区域。这里所谓发色区域是指红(R)、绿(G)、蓝(B)中的任一子像素排成一列的区域。也就是说在基板上相互平行地配置三种发色区域(R、G、B)。例如,在红色发色区域的旁边配置绿色发色区域,在绿色发色区域的旁边配置蓝色发色区域,在蓝色发色区域的旁边配置红色发色区域。The substrate has a plurality of linear color-producing regions parallel to each other. Here, the color-emitting area refers to an area in which sub-pixels of red (R), green (G), and blue (B) are arranged in a row. That is to say, three kinds of color-emitting regions (R, G, B) are arranged parallel to each other on the substrate. For example, a green-colored area is arranged next to the red-colored area, a blue-colored area is arranged next to the green-colored area, and a red-colored area is arranged next to the blue-colored area.

另外,在本发明中,将位于基板的端部的发色区域称为“发色区域X”,将位于基板的中央部且排列了与排列在发色区域X的子像素发出同色光的子像素的发色区域称为“发色区域Y”。这里所谓“基板的端部”并不是仅指基板的周围边缘部,也指对于“基板的中央部”相对位于外侧的区域。同样,所谓“基板的中央部”并不是仅指基板的中央,也指对于“基板的端部”相对位于中央侧的区域。也就是说,“基板的端部”和“基板的中央部”确定比较对象的两个区域的相对位置关系。In addition, in the present invention, the color-emitting region located at the end of the substrate is called "color-emitting region X", and the sub-pixels arranged in the center of the substrate and emitting the same color light as the sub-pixels arranged in the color-emitting region X are called "color-emitting region X". The color-emitting area of the pixel is referred to as "color-emitting area Y". Here, the "end portion of the substrate" does not refer only to the peripheral edge portion of the substrate, but also refers to a region located relatively outside of the "central portion of the substrate". Similarly, "the center of the substrate" does not mean only the center of the substrate, but also refers to a region located relatively to the center of the "edges of the substrate". That is, "the edge of the substrate" and "the center of the substrate" determine the relative positional relationship between the two regions to be compared.

根据本发明的有机EL显示面板是底部发光型还是顶部发光型,基板的材料不同。在本发明的有机EL显示面板是底部发光型时,只要基板的材料透明且是绝缘体就不特别限定。作为这样的材料的例子,包括玻璃或透明树脂等。另一方面,在本发明的有机EL显示面板是顶部发光型时,只要基板的材料是绝缘体就不特别限定。基板的大小及厚度根据要制造的有机EL显示面板的大小或基板的材料等,进行适宜的设定即可。Whether the organic EL display panel of the present invention is a bottom emission type or a top emission type depends on the material of the substrate. When the organic EL display panel of the present invention is a bottom emission type, the material of the substrate is not particularly limited as long as it is transparent and an insulator. Examples of such materials include glass, transparent resin, and the like. On the other hand, when the organic EL display panel of the present invention is a top emission type, the material of the substrate is not particularly limited as long as it is an insulator. The size and thickness of the substrate may be appropriately set according to the size of the organic EL display panel to be manufactured, the material of the substrate, and the like.

基板也可以具有用于驱动有机EL元件的薄膜晶体管(驱动TFT)。TFT的源电极或漏电极被连接到后述的像素电极。The substrate may also have a thin film transistor (driving TFT) for driving the organic EL element. A source electrode or a drain electrode of the TFT is connected to a pixel electrode described later.

[子像素][subpixel]

如上所述,子像素(有机EL元件)包含发出红色光的子像素、发出绿色光的子像素以及发出蓝色光的子像素。发出这些三种颜色(RGB)的子像素构成一个像素。As described above, the subpixels (organic EL elements) include subpixels that emit red light, subpixels that emit green light, and subpixels that emit blue light. Sub-pixels emitting these three colors (RGB) constitute one pixel.

另外,在本发明中,将排列在位于基板的端部的发色区域X的子像素称为“子像素X”,将排列在基板的中央部的发色区域Y的子像素称为“子像素Y”。子像素X和子像素Y发出同色光。In addition, in the present invention, the sub-pixels arranged in the color-emitting region X located at the edge of the substrate are referred to as “sub-pixel X”, and the sub-pixels arranged in the color-emitting region Y in the center of the substrate are referred to as “sub-pixels”. Pixel Y". Sub-pixel X and sub-pixel Y emit light of the same color.

配置在基板上的子像素分别包括:1)像素电极、2)隔堤、3)有机功能层以及4)对向电极。以下,说明各个构成部件。The sub-pixels arranged on the substrate respectively include: 1) a pixel electrode, 2) a bank, 3) an organic functional layer, and 4) a counter electrode. Hereinafter, each component will be described.

1)像素电极1) Pixel electrode

像素电极是配置在基板上的导电性部件。像素电极通常作为阳极而起作用,但也可以作为阴极而起作用。另外,也可以在像素电极的表面形成由过渡金属的氧化物构成的膜(例如,氧化钨或氧化钼等)。像素电极的表面上的过渡金属的氧化物膜作为空穴输入层而起作用。The pixel electrode is a conductive member arranged on the substrate. The pixel electrode normally functions as an anode, but may also function as a cathode. In addition, a film made of transition metal oxide (for example, tungsten oxide, molybdenum oxide, etc.) may be formed on the surface of the pixel electrode. The transition metal oxide film on the surface of the pixel electrode functions as a hole input layer.

根据本发明的有机EL显示屏是底部发光型还是顶部发光型,像素电极的材料不同。在本发明的有机EL显示面板是底部发光型时,只要像素电极的材料透明且是导电体,就不特别限定。作为这样的材料的例子包括ITO(氧化铟锡)、IZO(氧化铟锌)或ZnO(氧化锌)等。另一方面,在本发明的有机EL显示面板是顶部发光型时,只要像素电极的材料具有光反射性且是导电体,就不特别限定。作为这样的材料的例子包括:含银的合金,更具体而言为银-钯-铜合金(APC)、银-钌-金合金(ARA)、MoCr(钼铬)、NiCr(镍铬)、铝-钕合金(Al-Nd)等。另外,也可以在具有光反射性的像素电极的表面形成ITO膜或IZO膜。According to whether the organic EL display panel of the present invention is a bottom emission type or a top emission type, the material of the pixel electrode is different. When the organic EL display panel of the present invention is a bottom emission type, the material of the pixel electrodes is not particularly limited as long as it is transparent and a conductor. Examples of such materials include ITO (indium tin oxide), IZO (indium zinc oxide), ZnO (zinc oxide), and the like. On the other hand, when the organic EL display panel of the present invention is a top emission type, the material of the pixel electrodes is not particularly limited as long as it has light reflectivity and is a conductor. Examples of such materials include: silver-containing alloys, more specifically silver-palladium-copper alloy (APC), silver-ruthenium-gold alloy (ARA), MoCr (molybdenum chromium), NiCr (nickel chromium), Aluminum-Neodymium alloy (Al-Nd), etc. In addition, an ITO film or an IZO film may be formed on the surface of the light reflective pixel electrode.

2)隔堤2) Dike

隔堤构成用于涂覆形成有机功能层的区域(以下也称为“涂覆区域”)的壁面,并规定涂覆区域。在本发明中,隔堤可以矩阵状地规定涂覆区域,也可以线状地规定涂覆区域。The bank constitutes a wall surface of a region where the organic functional layer is formed by coating (hereinafter also referred to as “coating region”), and defines the coating region. In the present invention, the banks may define the coating area in a matrix or linearly.

在隔堤矩阵状地规定涂覆区域时,有机EL显示面板具有格子状的隔堤(参照图3A),各个子像素具有的涂覆区域在四周由隔堤包围。另一方面,在隔堤规定线状的涂覆区域时,有机EL显示面板具有多个线状隔堤,在发色区域内排成一列的多个子像素具有的涂覆区域构成由线状的隔堤规定的一个线状的涂覆区域(参照图9A)。When the banks define the coating area in a matrix, the organic EL display panel has grid-like banks (see FIG. 3A ), and the coating area of each sub-pixel is surrounded by the banks. On the other hand, when the banks define a linear coating area, the organic EL display panel has a plurality of linear banks, and the coating area of a plurality of sub-pixels arranged in a row in the color-emitting area constitutes a linear coating area. A linear coating area defined by the bank (see FIG. 9A ).

优选的是,隔堤的自基板的表面的高度是0.1~3μm,特别优选,其高度是0.8μm~1.2μm。在隔堤的高度为3μm以上时,有可能使后述的所有有机EL元件共享的一个对向电极的阶梯被覆性(step coverage)降低。另外,在隔堤的高度为不足0.1μm时,涂敷在由隔堤规定的涂覆区域内的墨有可能从隔堤漏出。The height of the bank from the surface of the substrate is preferably 0.1 to 3 μm, particularly preferably 0.8 μm to 1.2 μm. When the height of the bank is 3 μm or more, the step coverage of one counter electrode shared by all the organic EL elements described later may be reduced. In addition, when the height of the bank is less than 0.1 μm, the ink coated in the coating area defined by the bank may leak from the bank.

此外,优选的是,隔堤的形状是正锥形。所谓正锥形,指的是隔堤的侧面倾斜且隔堤的底面的面积大于隔堤的上表面的面积的形状。优选的是,隔堤的锥角的角度为80°以下。在隔堤的锥角的角度为超过80°时,后述的对向电极的阶梯被覆性降低。Furthermore, it is preferable that the shape of the bank is a forward taper. The normal taper shape refers to a shape in which the side of the bank is inclined and the area of the bottom surface of the bank is larger than the area of the upper surface of the bank. Preferably, the taper angle of the bank is 80° or less. When the taper angle of the bank exceeds 80°, the step coverage of the counter electrode described later decreases.

作为隔堤的材料的例子包括:聚酰亚胺等绝缘性树脂。优选的是,隔堤的表面的亲水性较低(例如,呈防水性)。为了使隔堤的表面的亲水性较低,例如,将隔堤的材料设为含有氟素化合物的含氟树脂,或通过氟类气体等离子体对隔堤的表面进行氟化处理即可。Examples of the material of the banks include insulating resins such as polyimide. Preferably, the surface of the bank is less hydrophilic (for example, waterproof). In order to make the surface of the bank less hydrophilic, for example, the material of the bank may be a fluorine-containing resin containing a fluorine compound, or the surface of the bank may be fluorinated by fluorine-based gas plasma.

作为包含有含氟树脂的氟素化合物的例子包括:偏氟乙烯(Vinylidene fluoride)、氟乙烯(vinyl fluoride)、三氟乙烯(trifluoroethylene)、以及其共聚物等氟化树脂等。另外,作为包含有含氟树脂的树脂的例子包括:酚醛树脂(phenol-novolac resins)、聚乙烯基苯酚树脂(polyvinylphenol resins)、丙烯酯树脂(acrylate resins)、甲基丙烯酸酯树脂(methacrylate resins)、以及其组合。Examples of fluorine compounds containing fluorine-containing resins include fluorinated resins such as vinylidene fluoride, vinyl fluoride, trifluoroethylene, and copolymers thereof. In addition, examples of resins containing fluorine-containing resins include phenol-novolac resins, polyvinylphenol resins, acrylate resins, and methacrylate resins. , and combinations thereof.

作为含氟树脂的更为具体的例子包括:例如特表2002-543469号公报中记载的含氟聚合物(氟乙烯)和乙烯基醚的共聚物即LUMIFLON(旭硝子株式会社的登录商标)等。More specific examples of fluorine-containing resins include, for example, LUMIFLON (a registered trademark of Asahi Glass Co., Ltd.), which is a copolymer of a fluorine-containing polymer (fluoroethylene) and vinyl ether described in Japanese Patent Application Publication No. 2002-543469.

隔堤例如通过光刻法形成。通过光刻法形成隔堤的方法例如包括以下步骤:i)在基板上形成光敏性树脂膜;ii)对形成后的光敏性树脂膜进行曝光;iii)对曝光后的光敏性树脂膜进行显像而进行图案化;以及iv)对图案化后的树脂膜进行烘焙,将树脂膜固定在基板上(参照图5A至图5D)。The banks are formed by, for example, photolithography. The method for forming a bank by photolithography, for example, includes the following steps: i) forming a photosensitive resin film on a substrate; ii) exposing the formed photosensitive resin film; iii) developing the exposed photosensitive resin film. and iv) baking the patterned resin film to fix the resin film on the substrate (see FIGS. 5A to 5D ).

本发明的特征在于,位于基板端部的发色区域X内的子像素X具有的涂覆区域的壁面的倾斜角度。在本发明中,“涂覆区域的壁面”是指涂覆区域的壁面中的、与发光区域的线方向平行的壁面。另外,在本发明中,将与发色区域的线方向平行的壁面中的、基板端部侧的壁面称为“壁面W1”,将基板中央部侧的壁面称为“壁面W2”。另外,将壁面W1的倾斜角度称为“倾斜角度α”,将壁面W2的倾斜角度称为“倾斜角度β”。The present invention is characterized by the inclination angle of the wall surface of the coating region of the sub-pixel X located in the color-emitting region X located at the edge of the substrate. In the present invention, "the wall surface of the coating region" refers to the wall surface parallel to the line direction of the light emitting region among the wall surfaces of the coating region. In the present invention, among the wall surfaces parallel to the linear direction of the color-producing region, the wall surface on the substrate end side is referred to as "wall surface W1", and the wall surface on the substrate center side is referred to as "wall surface W2". In addition, the inclination angle of the wall surface W1 is called "inclination angle α", and the inclination angle of the wall surface W2 is called "inclination angle β".

另外,所谓“子像素具有的涂覆区域”是指,在各个子像素具有其四周由隔堤包围的涂覆区域时,由隔堤包围了四周的各个涂覆区域(参照图3A);而在发色区域内的多个子像素具有的涂覆区域构成一个线状的涂覆区域时,将线状的涂覆区域以排列在发色区域内的子像素的数进行等分割后的各个区域(参照图9A)。In addition, the so-called "coating area of a sub-pixel" means that when each sub-pixel has a coating area surrounded by banks, each coating area is surrounded by banks (see FIG. 3A); When the coating area of a plurality of sub-pixels in the color-emitting area constitutes a linear coating area, each area obtained by dividing the linear coating area equally by the number of sub-pixels arranged in the color-emitting area (Refer to FIG. 9A).

具体而言,本发明的特征在于,在子像素X中壁面W1倾斜角度α小于壁面W2的倾斜角度β。子像素X中的倾斜角度α为20°~60°,壁面W2的倾斜角度β为40°~70°。另外,在子像素X中,倾斜角度α和倾斜角度β之差的最大值为10°~50°。Specifically, the present invention is characterized in that in the sub-pixel X, the inclination angle α of the wall surface W1 is smaller than the inclination angle β of the wall surface W2. The inclination angle α in the sub-pixel X is 20° to 60°, and the inclination angle β of the wall surface W2 is 40° to 70°. In addition, in the sub-pixel X, the maximum value of the difference between the inclination angle α and the inclination angle β is 10° to 50°.

另外,本发明的特征在于,根据发色区域的位置,调节子像素的涂覆区域的壁面的倾斜角度。具体而言,位于基板的中央部的发色区域Y内的子像素Y中倾斜角度α以及倾斜角度β为40°~70°。也就是说,在子像素X中倾斜角度α和倾斜角度β之差大,但在子像素Y中倾斜角度α和倾斜角度β之差小或没有差距。In addition, the present invention is characterized in that the inclination angle of the wall surface of the coating region of the sub-pixel is adjusted according to the position of the color emitting region. Specifically, the inclination angle α and the inclination angle β of the sub-pixel Y located in the color-emitting region Y at the center of the substrate are 40° to 70°. That is, the difference between the inclination angle α and the inclination angle β is large in the sub-pixel X, but the difference between the inclination angle α and the inclination angle β is small or has no difference in the sub-pixel Y.

这样,为了调节涂敷区域的壁面的倾斜角度,调节构成涂敷区域的壁面的隔堤的锥角角度即可。为了调节隔堤的锥角角度,在对光敏性树脂膜进行曝光时,调节曝光强度即可。例如,将光敏性树脂膜的材料设为光硬化性树脂,并以通过了多阶掩膜(灰阶掩膜或半色调掩膜)的弱光对希望使锥角的角度较小的区域进行曝光即可(参照图5B)。In this way, in order to adjust the inclination angle of the wall surface of the application area, it is only necessary to adjust the taper angle of the banks constituting the wall surface of the application area. In order to adjust the taper angle of the banks, it is sufficient to adjust the exposure intensity when exposing the photosensitive resin film. For example, the material of the photosensitive resin film is set to photocurable resin, and the area where the angle of the taper angle is expected to be smaller is processed with the weak light that has passed through the multi-level mask (grayscale mask or halftone mask). Just exposure (refer to FIG. 5B ).

这样,通过调整子像素具有的涂覆区域的壁面的倾斜角度,对因干燥不均产生的像素间的有机功能层的形状和膜厚的偏差进行校正。在实施方式1,参照附图详细地说明对有机功能层的形状和膜厚的偏差进行校正的机理。In this way, by adjusting the inclination angle of the wall surface of the coating region of the sub-pixel, the variation in the shape and film thickness of the organic functional layer between pixels caused by uneven drying is corrected. In Embodiment 1, a mechanism for correcting variations in shape and film thickness of an organic functional layer will be described in detail with reference to the drawings.

3)有机功能层3) Organic functional layer

有机功能层是配置在像素电极上的、至少包含有机发光层的层。在本发明中,有机功能层是通过在由隔堤规定的涂覆区域涂覆有机功能层的材料液而形成的。例如,能够通过涂覆法(例如,喷墨法)涂覆有机功能层的材料液(使有机功能层的材料溶解于苯甲醚或环己基苯等有机溶剂后所得到的溶液)并使其干燥,由此形成有机功能层。有机功能层的厚度并不特别限定,但例如为50nm~200nm左右即可。The organic functional layer is a layer that is disposed on the pixel electrode and includes at least an organic light emitting layer. In the present invention, the organic functional layer is formed by coating the material liquid of the organic functional layer in the coating area defined by the bank. For example, it is possible to apply a material solution (a solution obtained by dissolving the material of the organic functional layer in an organic solvent such as anisole or cyclohexylbenzene) by a coating method (for example, an inkjet method) and make it dried, thereby forming an organic functional layer. The thickness of the organic functional layer is not particularly limited, but may be, for example, about 50 nm to 200 nm.

根据子像素(有机EL元件)发出的光的颜色(RGB),对各个子像素适当地选择有机功能层具有的有机发光层所含有的有机EL材料。有机EL材料可以是高分子有机EL材料和低分子有机EL材料中的任一材料,但从通过涂覆法来形成的观点出发,优选为高分子有机EL材料。其理由在于,通过使用高分子有机EL材料,能够容易地形成有机发光层而不会对其他部件造成损伤。作为高分子有机EL材料的例子包括:聚苯亚乙烯以及其衍生物、聚乙炔(Polyacetylene)以及其衍生物、聚苯(Polyphenylene(PP))以及其衍生物、聚对苯乙烯(Polyparaphenylene ethylene)以及其衍生物、聚3-己基噻吩(Poly-3-hexyl thiophene(P3HT))以及其衍生物、聚芴(polyfluorene(PF))以及其衍生物等。作为低分子有机EL材料的例子包含三(8-羟基喹啉)铝(tris(8-quinolinolate)aluminum)等。The organic EL material contained in the organic light-emitting layer of the organic functional layer is appropriately selected for each sub-pixel according to the color (RGB) of light emitted by the sub-pixel (organic EL element). The organic EL material may be either a high-molecular organic EL material or a low-molecular organic EL material, but is preferably a high-molecular organic EL material from the viewpoint of being formed by a coating method. The reason for this is that by using a polymeric organic EL material, an organic light-emitting layer can be easily formed without damaging other components. Examples of polymer organic EL materials include: polyphenylene vinylene and its derivatives, polyacetylene and its derivatives, polyphenylene (PP) and its derivatives, polyparaphenylene ethylene And its derivatives, poly-3-hexyl thiophene (Poly-3-hexyl thiophene (P3HT)) and its derivatives, polyfluorene (polyfluorene (PF)) and its derivatives, etc. Examples of low-molecular-weight organic EL materials include tris(8-quinolinolate)aluminum ( tris(8-quinolinolate)aluminum ) and the like.

有机功能层除了具有有机发光层以外,也可以具有空穴输入层、空穴输送层(中间层:interlayer)、电子输入层或电子输送层等。The organic functional layer may have a hole input layer, a hole transport layer (interlayer), an electron input layer or an electron transport layer, etc. in addition to the organic light emitting layer.

空穴输入层包括例如掺杂了聚苯乙烯磺酸盐的聚(3、4-亚乙基二氧噻吩)(称为PEDOT-PSS)或其衍生物(共聚物等)。这样的空穴输入层是通过例如在像素电极上涂覆空穴输入层的材料液(含有PEDOT-PSS和水的墨)来形成的。The hole input layer includes, for example, poly(3,4-ethylenedioxythiophene) doped with polystyrene sulfonate (referred to as PEDOT-PSS) or derivatives thereof (copolymer, etc.). Such a hole input layer is formed by, for example, coating a material liquid (ink containing PEDOT-PSS and water) for the hole input layer on the pixel electrode.

在像素电极(或空穴输入层)和有机发光层之间配置空穴输送层。空穴输送层具有将空穴高效率地运送到有机发光层的功能,并且具有阻止电子侵入像素电极(或空穴输入层)的功能。空穴输送层的材料优选是聚芴和三苯胺衍生物的共聚物。A hole transport layer is disposed between the pixel electrode (or hole input layer) and the organic light emitting layer. The hole transport layer has a function of efficiently transporting holes to the organic light-emitting layer, and has a function of preventing electrons from entering the pixel electrode (or the hole input layer). The material of the hole transport layer is preferably a copolymer of polyfluorene and a triphenylamine derivative.

空穴输送层可以通过在像素电极(或空穴输入层)上涂覆空穴输送层的材料液(例如,使空穴输送层的材料溶解于苯甲醚或苯环等有机溶剂后所得到的溶液)来形成。空穴输送层的厚度并不特别限定,但例如为10nm~40nm左右即可。The hole transport layer can be obtained by coating the material solution of the hole transport layer (for example, dissolving the material of the hole transport layer in an organic solvent such as anisole or benzene ring) on the pixel electrode (or hole input layer). solution) to form. The thickness of the hole transport layer is not particularly limited, but may be, for example, about 10 nm to 40 nm.

在有机功能层具有空穴输入层或空穴输送层等时,可以将像素电极设为反射电极,通过涂覆形成的空穴输入层或空穴输送层来调节有机发光层和反射阳极即像素电极之间的光学距离。特别是空穴输送层即使稍微增加减少其厚度,对有机EL元件的发光特性也不会造成大影响,所以优选其作为调整光学距离用的层。通过涂覆形成后的空穴输入层和空穴输送层等来调整光学距离,由此能够提高有机EL元件的光的取出效率。在通过空穴输入层或空穴输送层调节光学距离时,由于最合适的光学距离因光的波长而不同,所以对于各个RGB,空穴输入层或空穴输送层的膜厚不同,对于各个RGB,有机功能层的膜厚不同。When the organic functional layer has a hole input layer or a hole transport layer, etc., the pixel electrode can be set as a reflective electrode, and the organic light-emitting layer and the reflective anode, that is, the pixel, can be adjusted by coating the formed hole input layer or hole transport layer. Optical distance between electrodes. In particular, even if the thickness of the hole transport layer is slightly increased or decreased, the light-emitting characteristics of the organic EL device will not be greatly affected, so it is preferably used as a layer for adjusting the optical distance. By coating the formed hole input layer, hole transport layer, etc. to adjust the optical distance, the light extraction efficiency of the organic EL element can be improved. When the optical distance is adjusted by the hole input layer or the hole transport layer, since the optimum optical distance differs depending on the wavelength of light, the film thickness of the hole input layer or the hole transport layer is different for each RGB, and for each RGB, the film thickness of the organic functional layer is different.

另一方面,优选的是,发出同色的子像素的有机功能层的膜厚均匀。这是因为,若发出同色的光的子像素的有机功能层的膜厚存在偏差,则有机EL显示面板产生亮度不均。特别是在如上所述通过有机功能层调节了光学距离时,若发出同色的子像素的有机功能层的膜厚存在偏差,则在子像素间产生光学距离被适当调整的子像素和光学距离未被适当调整的子像素,有机EL显示面板的亮度不均特别明显。On the other hand, it is preferable that the thickness of the organic functional layer of the sub-pixels emitting the same color be uniform. This is because if the film thickness of the organic functional layers of sub-pixels that emit light of the same color varies, unevenness in luminance occurs in the organic EL display panel. Especially when the optical distance is adjusted by the organic functional layer as described above, if the film thickness of the organic functional layer of the sub-pixels emitting the same color varies, a sub-pixel whose optical distance is appropriately adjusted and an optical distance difference between sub-pixels will occur. With properly adjusted sub-pixels, the brightness unevenness of the organic EL display panel is particularly obvious.

这里,所谓“有机功能层的厚度”是指各个子像素具有的有机功能层中的最薄之处的膜厚(参照图4A和图4B)。Here, the "thickness of the organic functional layer" refers to the thickness of the thinnest part of the organic functional layer of each sub-pixel (see FIGS. 4A and 4B ).

4)对向电极4) Counter electrode

对向电极是配置在有机功能层上的导电部件。对向电极通常作为阴极而起作用,但也可以作为阳极而起作用。多个子像素可以共享一个对向电极。例如,在有机EL显示面板为有源矩阵型时,一枚面板所包含的所有子像素可以共享一个对向电极。The counter electrode is a conductive component arranged on the organic functional layer. The counter electrode usually functions as a cathode, but may also function as an anode. A plurality of sub-pixels may share one counter electrode. For example, when the organic EL display panel is an active matrix type, all sub-pixels included in one panel may share one counter electrode.

根据本发明的有机EL显示面板是底部发光型还是顶部发光型,对向电极的材料不同。在本发明的有机EL显示面板是顶部发光型时,只要对向电极的材料透明且是导电体,就不特别限定。作为这样的材料的例子,包括ITO、IZO或ZnO等。另一方面,在本发明的有机EL显示面板是底部发光型时,只要像素电极的材料是导电体,就不特别限定。作为这样的材料的例子,包括钡、氧化钡或铝等。Depending on whether the organic EL display panel of the present invention is a bottom emission type or a top emission type, the material of the counter electrode is different. When the organic EL display panel of the present invention is a top emission type, the material of the counter electrode is not particularly limited as long as it is transparent and a conductor. Examples of such materials include ITO, IZO, ZnO, and the like. On the other hand, when the organic EL display panel of the present invention is a bottom emission type, the material of the pixel electrode is not particularly limited as long as it is a conductor. Examples of such materials include barium, barium oxide, or aluminum.

在对向电极上也还可以配置密封膜。密封膜具有保护有机功能层或像素电极等免受水分、热或冲击等的影响的功能。作为密封膜的材料的例子包括氮化硅或氮氧化硅等。A sealing film may also be arranged on the counter electrode. The sealing film has a function of protecting organic functional layers, pixel electrodes, and the like from moisture, heat, shock, and the like. Examples of the material of the sealing film include silicon nitride, silicon oxynitride, and the like.

以下,参照附图说明本发明的有机EL显示面板的实施方式。但是,本发明并不由这些实施方式限定。Hereinafter, embodiments of the organic EL display panel of the present invention will be described with reference to the drawings. However, the present invention is not limited by these embodiments.

(实施方式1)(Embodiment 1)

图3A是本发明实施方式1的有机EL显示面板100的平面图。另外,图3B是实施方式1的有机EL显示面板100的AA线处的剖面图。3A is a plan view of organic EL display panel 100 according to Embodiment 1 of the present invention. In addition, FIG. 3B is a cross-sectional view of the organic EL display panel 100 according to Embodiment 1 along line AA.

如图3A和图3B所示,有机显示面板100包括:基板110,其具有多个相互平行的线状的发色区域120;以及多个子像素(有机EL元件)130,其在发色区域120内排成一列。As shown in FIG. 3A and FIG. 3B , the organic display panel 100 includes: a substrate 110 having a plurality of color-emitting regions 120 parallel to each other; in a row.

发色区域120包含排列了发出红色光的子像素130R的发色区域120R、排列了发出绿色光的子像素130G的发色区域120G以及排列了发出蓝色光的子像素130B的发色区域120B。由子像素130R、子像素130G以及子像素130B构成一个像素。The color-emitting region 120 includes a color-emitting region 120R in which sub-pixels 130R emitting red light are arranged, a color-emitting region 120G in which sub-pixels 130G emitting green light are arranged, and a color-emitting region 120B in which sub-pixels 130B emitting blue light are arranged. One pixel is constituted by the sub-pixel 130R, the sub-pixel 130G, and the sub-pixel 130B.

另外,在发色区域120包含位于基板110的端部的发色区域120X(120RX、120GX、120BX)和位于基板110的中央部的发色区域120Y(120RY、120GY、120BY)。在发色区域120X排列子像素130X(130RX、130GX、130BX),在发色区域120Y排列子像素130Y(130RY、130GY、130BY)(参照图3B)。In addition, the color-emitting regions 120 include color-emitting regions 120X (120RX, 120GX, 120BX) located at the ends of the substrate 110 and color-emitting regions 120Y (120RY, 120GY, 120BY) located at the center of the substrate 110 . Sub-pixels 130X (130RX, 130GX, 130BX) are arranged in the color-emitting region 120X, and sub-pixels 130Y (130RY, 130GY, 130BY) are arranged in the color-emitting region 120Y (see FIG. 3B ).

如图3B所示,各个子像素130包括:配置在基板110上的像素电极150、配置在像素电极上的金属氧化物膜160、规定涂覆区域175的隔堤170、形成在涂覆区域175内的有机功能层180以及配置在有机功能层180上的对向电极190(未图示)。有机功能层180配置在金属氧化物膜160上。As shown in FIG. 3B , each sub-pixel 130 includes: a pixel electrode 150 disposed on the substrate 110 , a metal oxide film 160 disposed on the pixel electrode, a bank 170 defining a coating region 175 , and a bank 170 formed on the coating region 175 . The inner organic functional layer 180 and the counter electrode 190 (not shown) disposed on the organic functional layer 180 . The organic functional layer 180 is disposed on the metal oxide film 160 .

由隔堤170的侧面构成涂敷区域175的壁面。另外,在本实施方式中,隔堤170形成为格子状,各个子像素130具有四周由隔堤170包围的涂覆区域175。The wall surface of the coating region 175 is formed by the side surfaces of the bank 170 . In addition, in the present embodiment, the banks 170 are formed in a lattice shape, and each sub-pixel 130 has a coating region 175 surrounded by the banks 170 .

金属氧化物膜160例如是氧化钨,并作为空穴输入层而起作用。The metal oxide film 160 is, for example, tungsten oxide, and functions as a hole input layer.

子像素130R具有的有机功能层180R包含发出红色光的有机发光层;子像素130G具有的有机功能层180G包含发出绿色光的有机发光层;子像素130B具有的有机功能层180B包含发出蓝色光的有机发光层。The organic functional layer 180R of the sub-pixel 130R includes an organic light-emitting layer emitting red light; the organic functional layer 180G of the sub-pixel 130G includes an organic light-emitting layer emitting green light; organic light-emitting layer.

图4A是图3B所示的子像素130RX的放大图,图4B是图3B所示的子像素的130RY的放大图。FIG. 4A is an enlarged view of the sub-pixel 130RX shown in FIG. 3B , and FIG. 4B is an enlarged view of the sub-pixel 130RY shown in FIG. 3B .

如图4A所示,子像素130RX中,壁面W1的倾斜角度α小于壁面W2的倾斜角度β。另一方面,如图4B所示,子像素130RY中,壁面W1的倾斜角度α与壁面W2的倾斜角度β大致相同。As shown in FIG. 4A , in the sub-pixel 130RX, the inclination angle α of the wall W1 is smaller than the inclination angle β of the wall W2 . On the other hand, as shown in FIG. 4B , in the sub-pixel 130RY, the inclination angle α of the wall surface W1 is substantially the same as the inclination angle β of the wall surface W2 .

因此,子像素130RX中的倾斜角度α与倾斜角度β之差大于子像素130RY中的倾斜角度α与倾斜角度β之差。Therefore, the difference between the tilt angle α and the tilt angle β in the sub-pixel 130RX is greater than the difference between the tilt angle α and the tilt angle β in the sub-pixel 130RY.

接着,参照附图,说明通过光刻法形成用于构成涂覆区域175的壁面的隔堤170的方法。图5A至图5D表示配置在基板110的端部的子像素130RX的隔堤170的形成方法的步骤。Next, a method of forming bank 170 constituting the wall surface of coating region 175 by photolithography will be described with reference to the drawings. 5A to 5D show the steps of a method of forming the bank 170 of the sub-pixel 130RX arranged at the end of the substrate 110 .

如图5A至图5D所示,隔堤170的形成方法包括:1)第一步骤,在基板110上形成光敏性树脂膜171(图5A);2)第二步骤,对光敏性树脂膜171进行曝光;3)第三步骤,对曝光后的光敏性树脂膜171进行显像,并对光敏性树脂膜171进行图案化(图5C);以及4)第四步骤,对图案化后的树脂膜171进行烘焙,将其固定在基板110上(图5D)。As shown in FIGS. 5A to 5D , the forming method of the bank 170 includes: 1) a first step, forming a photosensitive resin film 171 on the substrate 110 ( FIG. 5A ); 2) a second step, forming a photosensitive resin film 171 on the substrate 110; Expose; 3) the third step, developing the exposed photosensitive resin film 171, and patterning the photosensitive resin film 171 (FIG. 5C); and 4) the fourth step, patterning the patterned resin The film 171 is baked, fixing it on the substrate 110 (FIG. 5D).

1)图5A表示第一步骤。如图5A所示,在第一步骤中,在配置了由金属氧化物膜160覆盖的像素电极150的基板110上形成光敏性树脂膜171。在本实施方式中,说明光敏性树脂为光硬化性树脂(负型的光致抗蚀剂)的例子,但光敏性树脂也可以是正型的光致抗蚀剂。1) Figure 5A shows the first step. As shown in FIG. 5A , in a first step, a photosensitive resin film 171 is formed on the substrate 110 on which the pixel electrode 150 covered with the metal oxide film 160 is disposed. In this embodiment, an example in which the photosensitive resin is a photocurable resin (negative photoresist) is described, but the photosensitive resin may be a positive photoresist.

为了在基板110上形成光敏性树脂膜171,通过旋涂(spin-coating)、模压涂层法、狭缝涂敷等将光敏性树脂组合物涂敷在基板110上,预烘焙涂敷后的膜即可。并不特别限定预烘焙条件,在80℃~100℃(例如100℃)放置2分钟至3分钟即可。In order to form the photosensitive resin film 171 on the substrate 110, the photosensitive resin composition is coated on the substrate 110 by spin coating (spin-coating), die coating method, slit coating, etc., and pre-baking the coated film. film. The pre-baking conditions are not particularly limited, and it can be placed at 80° C. to 100° C. (for example, 100° C.) for 2 minutes to 3 minutes.

2)图5B表示第二步骤。如图5B所示在第二步骤中,对光敏性树脂膜171进行曝光。更具体而言,对光敏性树脂膜171中的、成为隔堤170的区域照射光。在本实施方式中,对成为隔堤170的光敏性树脂膜171的区域中的构成壁面W1的区域171a照射通过了半色调掩膜190的弱光,对除此以外的区域171b不经由掩膜而照射强光。2) Figure 5B shows the second step. In the second step, as shown in FIG. 5B, the photosensitive resin film 171 is exposed to light. More specifically, light is irradiated to the region to be the bank 170 in the photosensitive resin film 171 . In the present embodiment, the weak light passing through the halftone mask 190 is irradiated to the region 171a constituting the wall surface W1 in the region of the photosensitive resin film 171 serving as the bank 170, and the other regions 171b are not masked. And shine bright light.

通过光照射,光敏性树脂被硬化,光敏性树脂的弹性和玻璃转移温度上升。硬化的程度取决于照射的光的强度,所以在照射了弱光的区域171a的树脂中,硬化的程度较小,在照射了强光的区域171b的树脂中,硬化的程度较大。The photosensitive resin is hardened by light irradiation, and the elasticity and glass transition temperature of the photosensitive resin rise. The degree of hardening depends on the intensity of the irradiated light, so the resin in the area 171a irradiated with weak light is less hardened, and the resin in the area 171b irradiated with strong light is more hardened.

3)图5C表示第三步骤。如图5C所示,在第三步骤中,对曝光后的光敏性树脂膜171进行显像。为了对光敏性树脂膜171进行显像,将配置了曝光后的光敏性树脂膜171的基板110例如浸泡在0.2%TMAH(四甲基氢氧化铵)液中60钞,此后用纯水冲洗60秒即可。3) Figure 5C shows the third step. As shown in FIG. 5C, in the third step, the exposed photosensitive resin film 171 is developed. In order to develop the photosensitive resin film 171, the substrate 110 on which the exposed photosensitive resin film 171 is disposed is soaked in 0.2% TMAH (tetramethylammonium hydroxide) solution for 60 minutes, and then rinsed with pure water for 60 minutes. seconds.

如上所述,在照射了弱光的区域171a中,硬化的程度较小,所以在显像步骤中,树脂膜171的边缘被削去,树脂膜171的侧面的倾斜角度α变小。另一方面,在照射了强光的区域171b中,硬化的程度大,所以在显像步骤中,树脂膜171的边缘难以被削去,树脂膜171的侧面的倾斜角度β变得较大。As described above, in the region 171a irradiated with weak light, the degree of hardening is small, so in the developing step, the edge of the resin film 171 is chipped, and the inclination angle α of the side surface of the resin film 171 becomes small. On the other hand, in the region 171b irradiated with strong light, the degree of hardening is large, so the edge of the resin film 171 is difficult to be chipped in the developing step, and the inclination angle β of the side surface of the resin film 171 becomes large.

4)图5D表示第四步骤。如图5D所示,在第四步骤中,对图案化后的树脂膜171进行锻烧(后烘焙),将其固定在基板110上。并不特别限定后烘焙的条件,但例如温度约为200度(例如为220度)以上,时间约为1小时。通过对图案化后的树脂膜171进行后烘焙,去除树脂膜171内的溶剂和水分,提高树脂膜171与基板的密接性,树脂膜171被固定在基板110上。固定在基板110上的树脂膜171构成隔堤170。4) Figure 5D shows the fourth step. As shown in FIG. 5D , in the fourth step, the patterned resin film 171 is fired (post-baked) to be fixed on the substrate 110 . The post-baking conditions are not particularly limited, but for example, the temperature is about 200 degrees (for example, 220 degrees) or higher, and the time is about 1 hour. By post-baking the patterned resin film 171 , the solvent and moisture in the resin film 171 are removed, and the adhesiveness between the resin film 171 and the substrate is improved, and the resin film 171 is fixed on the substrate 110 . The resin film 171 fixed on the substrate 110 constitutes the bank 170 .

这样,在通过光刻法形成隔堤170时,通过局部地调节曝光条件,能够调节隔堤170的锥角的角度,并调节涂覆区域175的壁面的倾斜角度。Thus, by locally adjusting exposure conditions when forming bank 170 by photolithography, it is possible to adjust the taper angle of bank 170 and adjust the inclination angle of the wall surface of coating region 175 .

这样,在子像素130X中,通过使倾斜角度α小于倾斜角度β,能够对子像素130X具有的有机功能层180X的偏差进行校正。其结果,能够使配置在基板110的端部的子像素130X具有的有机功能层180的膜厚均匀,并能够对有机功能层180的膜厚的在像素间的偏差进行校正。In this way, in the sub-pixel 130X, by making the inclination angle α smaller than the inclination angle β, it is possible to correct the variation of the organic functional layer 180X included in the sub-pixel 130X. As a result, the film thickness of the organic functional layer 180 included in the sub-pixel 130X arranged at the end of the substrate 110 can be made uniform, and the variation in the film thickness of the organic functional layer 180 between pixels can be corrected.

以下,说明在由隔堤所规定的涂覆区域内涂覆的有机功能层的材料液在干燥过程中所表现出的变化,而且说明通过调节涂覆区域的壁面的倾斜角度而能够使有机功能层的膜厚均匀的机理。In the following, the change of the material liquid of the organic functional layer coated in the coating area defined by the bank during the drying process is described, and the organic functional layer can be adjusted by adjusting the inclination angle of the wall surface of the coating area. The mechanism by which the film thickness of the layer is uniform.

图6A至图6C以及图7A至图7E是材料液在干燥过程中所表现出的基本的变化的示意图。FIGS. 6A to 6C and FIGS. 7A to 7E are schematic diagrams showing basic changes of the material liquid during the drying process.

图6A是表示在由隔堤170规定的涂覆区域175内刚涂覆完有机功能层的材料液140后的状态的示意图。如图6A所示,材料液140从涂覆区域175溢出而被涂覆到隔堤170的上表面。刚涂覆完之后,由于液滴端部141中的表面张力的均衡,液滴端部141的接触角为θ。FIG. 6A is a schematic diagram showing a state immediately after the material solution 140 for the organic functional layer is coated in the coating area 175 defined by the bank 170 . As shown in FIG. 6A , the material liquid 140 overflows from the coating area 175 to be coated on the upper surface of the bank 170 . Immediately after coating, the contact angle of the droplet end 141 is θ due to the equalization of surface tension in the droplet end 141 .

材料液140开始干燥后,在保持表面张力的均衡的期间,如图6B所示,在液滴端部141被固定后的状态下,由于溶剂的蒸发,抵触角从θ减少到后退角θR为止。这种干燥形式由于液滴的直径一定,所以将其称为CCR(Constant Contact Radius:恒定接触半径)模式。After the material liquid 140 starts to dry, while maintaining the equilibrium of the surface tension, as shown in FIG. 6B , in the state where the droplet end 141 is fixed, the angle of collision decreases from θ to the receding angle θ R due to the evaporation of the solvent. until. This drying mode is called a CCR (Constant Contact Radius: Constant Contact Radius) mode because the diameter of the droplet is constant.

另外,后退角θR根据材料液的性质(粘度等)或隔堤表面的物理性能(表面自由能等)而变化。In addition, the receding angle θ R varies depending on the properties of the material liquid (viscosity, etc.) or the physical properties of the bank surface (surface free energy, etc.).

液滴端部141的抵触角减少到后退接触角θR后,液滴端部141中的表面张力的均衡崩溃,产生将材料液140吸入内部的力。其结果,如图6C所示,在接触角θR被固定后的状态下,由于溶剂的蒸发,液滴端部141向内侧移动,液滴的直径减少。这种干燥形式由于相对于隔堤170的上表面的接触角一定,所以将其称为CCA(Constant Contact Angle:恒定接触角)模式。该液滴的直径的减少一直持续到液滴端部141到达隔堤170的角上(隔堤的上表面与壁面之间的边界线)为止。When the contact angle of the droplet end 141 decreases to the receding contact angle θ R , the equilibrium of the surface tension in the droplet end 141 collapses, and a force for sucking the material liquid 140 inside is generated. As a result, as shown in FIG. 6C , in the state where the contact angle θ R is fixed, the droplet end 141 moves inward due to the evaporation of the solvent, and the diameter of the droplet decreases. This drying mode is called a CCA (Constant Contact Angle: Constant Contact Angle) mode because the contact angle with the upper surface of the bank 170 is constant. The droplet diameter decreases until the droplet end 141 reaches the corner of the bank 170 (the boundary line between the upper surface of the bank and the wall surface).

液滴端部141到达隔堤170的角后,如图7A所示,接触角的基准面由隔堤的上表面变为隔堤的侧面(涂覆区域的壁面),所以接触角增大为θ’。由此,由于抵触角大于后退接触角,所以液滴端部141的表面张力再次均衡。其结果,如图7B所示,在液滴端部141被固定在隔堤170的角上的状态下,由于溶剂的的蒸发,抵触角从θ’减少到后退接触角θR’为止(CCR模式)。After the droplet end 141 reaches the corner of the bank 170, as shown in Figure 7A, the reference plane of the contact angle changes from the upper surface of the bank to the side of the bank (the wall surface of the coating area), so the contact angle increases as θ'. Thereby, since the collision angle is larger than the receding contact angle, the surface tension of the droplet end 141 is equalized again. As a result, as shown in FIG. 7B , in the state where the droplet tip 141 is fixed on the corner of the bank 170, due to the evaporation of the solvent, the collision angle decreases from θ' to the receding contact angle θ R ' (CCR model).

接触角减少到后退接触角θR’时,如图7C所示,在抵触角θR’被固定后的状态下,由于溶剂的蒸发,液滴端部141移动而液滴的体积减少(CCA模式)。When the contact angle decreases to the receding contact angle θ R ', as shown in FIG. 7C , in the state after the contact angle θ R ' is fixed, due to the evaporation of the solvent, the droplet tip 141 moves and the volume of the droplet decreases (CCA model).

由于干燥而使液滴端部141附近的溶质的浓度达到临界浓度时,如图7D所示,材料液140胶凝化(gelled),液滴端部141被固定在涂覆区域的壁面上。将这样的液滴端部的位置确定称为“锁定”(pinning)。特别是,将由于材料液的浓度的上升(粘度的上升)而产生的锁定称为“自锁定”(self pinning)。自锁定之后,如图7E所示,液滴端部141在被固定了的状态下继续干燥,形成有机功能层180。When the solute concentration near the droplet end 141 reaches a critical concentration due to drying, the material solution 140 is gelled as shown in FIG. 7D , and the droplet end 141 is fixed on the wall surface of the coating region. Such determination of the position of the droplet tip is referred to as "pinning". In particular, pinning caused by an increase in the concentration (increase in viscosity) of the material liquid is called "self pinning". After being locked, as shown in FIG. 7E , the droplet end 141 continues to dry in a fixed state to form an organic functional layer 180 .

如上所述,在涂敷区域内,溶液的干燥在交替重复CCR模式和CCA模式中持续进行。As mentioned above, in the application area, the drying of the solution continues in the alternating repetition of the CCR mode and the CCA mode.

这里,在使涂敷区域的壁面的倾斜角度小时,在以壁面为基准面时液滴端部141的抵触角变小。因此,溶剂蒸发后液滴端部141的抵触角立刻达到后退接触角θR’,液滴端部141移动,液滴的体积减少(CCA模式干燥)的时间变长。在CCA模式下,干燥的时间较长时,直至液滴端部141附近的溶质的浓度达到临界浓度为止,液滴端部141移动到涂敷区域的壁面的更下部。其结果,液滴端部141被固定在涂敷区域的壁面上的位置的高度(有机功能层的边缘的高度)变低。Here, when the inclination angle of the wall surface of the application region is made small, the collision angle of the droplet end 141 becomes small when the wall surface is used as a reference plane. Therefore, immediately after the solvent evaporates, the contact angle of the droplet end 141 reaches the receding contact angle θ R ', the droplet end 141 moves, and the time for the volume of the droplet to decrease (CCA mode drying) becomes longer. In the CCA mode, when the drying time is long, the droplet end 141 moves to the lower part of the wall surface of the coating area until the solute concentration near the droplet end 141 reaches the critical concentration. As a result, the height of the position where the droplet end 141 is fixed on the wall surface of the coating region (the height of the edge of the organic functional layer) becomes low.

如上所述,在配置在基板110的端部的子像素130X中,由于干燥速度的不均,有机功能层180X的在基板110的端部侧的边缘变高,有机功能层180X偏向于基板110的端部侧(参照图2)。As described above, in the sub-pixel 130X arranged at the end of the substrate 110, the edge of the organic functional layer 180X on the edge of the substrate 110 becomes higher due to uneven drying speed, and the organic functional layer 180X is biased toward the substrate 110. side of the end (refer to Figure 2).

但是,如本实施方式那样,通过在子像素130X中使倾斜角度α小于倾斜角度β,能够降低涂敷区域的壁面W1上的有机功能层180X的边缘的高度,能够对有机功能层180X的偏向进行校正(参照图4A)。However, as in the present embodiment, by making the inclination angle α smaller than the inclination angle β in the sub-pixel 130X, the height of the edge of the organic functional layer 180X on the wall surface W1 of the coating region can be reduced, and the deflection of the organic functional layer 180X can be adjusted. Calibrate (see Figure 4A).

另一方面,在基板中央部的子像素130Y中,由于有机功能层不存在偏向,所以即使倾斜角度α和倾斜角度β相同,也能够获得具有均匀膜厚的有机功能层180(参照图4B)。其结果,子像素130RX具有的有机功能层180X的膜厚T与子像素130RY具有的有机功能层180Y的膜厚T’一样(参照图4A和图4B)。On the other hand, in the sub-pixel 130Y at the center of the substrate, since the organic functional layer is not deflected, even if the inclination angle α and the inclination angle β are the same, an organic functional layer 180 having a uniform film thickness can be obtained (see FIG. 4B ). . As a result, the film thickness T of the organic functional layer 180X included in the sub-pixel 130RX is the same as the film thickness T' of the organic functional layer 180Y included in the sub-pixel 130RY (see FIGS. 4A and 4B ).

这样,根据本实施方式,通过调节子像素的涂敷区域的壁面的倾斜角度,能够对在位于基板的端部的子像素产生的有机功能层的偏向进行校正,从而能够使位于基板的端部的子像素的有机功能层的膜厚均匀。其结果,能够对有机功能层的膜厚的在像素间的偏差进行校正。由此,能够提供像素间膜厚相同的有机EL显示面板。In this way, according to this embodiment, by adjusting the inclination angle of the wall surface of the coating region of the sub-pixel, the deviation of the organic functional layer generated in the sub-pixel located at the end of the substrate can be corrected, so that the sub-pixel located at the end of the substrate can be corrected. The film thickness of the organic functional layer of the sub-pixel is uniform. As a result, variations in the film thickness of the organic functional layer between pixels can be corrected. Accordingly, it is possible to provide an organic EL display panel having the same film thickness between pixels.

另外,在本实施方式中,子像素中的倾斜角度α和倾斜角度β之差(以下,也简称为“角度差”)优选朝向干燥中心点逐渐地变小。这里,所谓“干燥中心点”是指在有机EL显示面板的制造步骤中,涂覆后的有机功能层的干燥速度最慢的假想上的点。干燥中心点有时在面板内,但有时在面板外。In addition, in the present embodiment, it is preferable that the difference between the inclination angle α and the inclination angle β (hereinafter, simply referred to as “angle difference”) in the sub-pixel gradually decreases toward the dry center point. Here, the "drying center point" refers to a virtual point at which the drying rate of the coated organic functional layer is the slowest in the manufacturing steps of the organic EL display panel. Sometimes the dry center point is inside the panel, but sometimes it is outside the panel.

例如,如图8A所示,在从一个基板110制造一个有机EL显示面板100时,干燥中心点C位于有机EL显示面板100的中央。此时,配置在有机EL显示面板100的四周的端部(100a、100b、100c、100d)的子像素中的角度差最大,随着接近干燥中心点C,子像素中的角度差逐渐变小。For example, as shown in FIG. 8A , when one organic EL display panel 100 is manufactured from one substrate 110 , the drying center point C is located at the center of the organic EL display panel 100 . At this time, the angular difference among the sub-pixels arranged at the peripheral ends (100a, 100b, 100c, and 100d) of the organic EL display panel 100 is the largest, and the angular difference among the sub-pixels gradually decreases as the dry center point C approaches. .

另一方面,如图8B所示,在从一个基板110制造多个(例如八个)有机EL显示面板(101~108)时,干燥中心点C有时位于有机EL显示面板之外。此时,例如着眼于有机EL显示面板101,配置在有机EL显示面板101的四周的端部(101a、100b、101c、101d)中的101a和101d的子像素中的角度差最大,随着接近干燥中心点C,子像素中的角度差逐渐变小。即使在这样的情况下,配置在面板的端部101a和101d的子像素中的角度差大于配置在面板101的中央部且发出同色的光的子像素中的角度差。On the other hand, as shown in FIG. 8B , when a plurality of (for example, eight) organic EL display panels ( 101 to 108 ) are manufactured from one substrate 110 , the drying center point C may be located outside the organic EL display panels. At this time, for example, focusing on the organic EL display panel 101, the angular difference between the sub-pixels 101a and 101d arranged at the peripheral edges (101a, 100b, 101c, and 101d) of the organic EL display panel 101 is the largest. As the center point C dries, the angle difference among the sub-pixels gradually becomes smaller. Even in such a case, the angular difference between the sub-pixels arranged at the edge portions 101 a and 101 d of the panel is larger than the angular difference between the sub-pixels arranged at the center of the panel 101 and emitting light of the same color.

(实施方式2)(Embodiment 2)

在实施方式1中,说明了隔堤矩阵状地规定涂敷区域的方式。在实施方式2中,说明隔堤规定线状的涂敷区域的方式。In Embodiment 1, the mode in which the banks define the application area in a matrix has been described. In Embodiment 2, a mode in which the banks define the linear application region will be described.

图9A是实施方式2的有机EL显示面板200的平面图。图9B是图9A所示的有机EL显示面板200的AA线处的剖面图。对与有机EL显示面板100相同的构成要素标注相同附图标记,并省略其说明。如图9A和图9B所示,有机EL显示面板200具有多个相互平行的线状的隔堤173来替代具有格子状的隔堤。9A is a plan view of an organic EL display panel 200 according to Embodiment 2. FIG. FIG. 9B is a cross-sectional view along line AA of the organic EL display panel 200 shown in FIG. 9A. The same reference numerals are attached to the same constituent elements as those of the organic EL display panel 100 , and description thereof will be omitted. As shown in FIGS. 9A and 9B , the organic EL display panel 200 has a plurality of linear banks 173 parallel to each other instead of the grid-shaped banks.

线状隔堤173规定线状的涂敷区域176。由排列在发色区域120的多个子像素130共享线状隔堤173所规定的线状的涂敷区域176。另外,在由线状隔堤173规定的线状涂敷区域176,线状地形成有机功能层180。因此,排列后的多个子像素130共享一个线状的有机功能层180。The linear bank 173 defines a linear coating area 176 . The linear coating area 176 defined by the linear bank 173 is shared by the plurality of sub-pixels 130 arranged in the color emitting area 120 . In addition, the organic functional layer 180 is linearly formed in the linear application region 176 defined by the linear bank 173 . Therefore, the arranged sub-pixels 130 share one linear organic functional layer 180 .

如图9B所示,在有机EL显示面板200中,也与有机EL显示面板100同样,在子像素130X中,倾斜角度α小于倾斜角度β。另外,子像素130X中的倾斜角度α与倾斜角度β之差大于子像素130Y中的倾斜角度α与倾斜角度β之差。这样,通过根据子像素的配置位置来调节涂敷区域的壁面的倾斜角度,能够对在配置于基板的端部的子像素产生的有机功能层的偏向进行校正,从而能够对有机功能层的膜厚的在像素间的偏差进行校正。As shown in FIG. 9B , also in the organic EL display panel 200 , as in the organic EL display panel 100 , in the sub-pixel 130X, the inclination angle α is smaller than the inclination angle β. In addition, the difference between the tilt angle α and the tilt angle β in the sub-pixel 130X is larger than the difference between the tilt angle α and the tilt angle β in the sub-pixel 130Y. In this way, by adjusting the inclination angle of the wall surface of the coating region according to the arrangement position of the sub-pixel, the deviation of the organic functional layer generated in the sub-pixel arranged at the edge of the substrate can be corrected, and the film of the organic functional layer can be corrected. Thick deviations between pixels are corrected.

图10A是图9A所示的线状涂敷区域176a的AA线处的剖面图。图10B是图9A所示的线状涂敷区域176a的BB线处的剖面图。FIG. 10A is a cross-sectional view along line AA of the linear application region 176a shown in FIG. 9A. FIG. 10B is a cross-sectional view along line BB of the linear coating region 176 a shown in FIG. 9A .

如图10A和图10B所示,在本实施方式中,其特征在于,在一个线状的发色区域120内涂覆区域176的壁面的倾斜角度发生变化。具体而言,在发色区域120的线方向的中央部的子像素130中,壁面的倾斜角度的锥角的角度大(参照图10A),在涂敷区域176的线方向的端部的子像素130中,壁面的倾斜角度的锥角的角度小(参照图10B)。As shown in FIGS. 10A and 10B , this embodiment is characterized in that the inclination angle of the wall surface of the coating region 176 changes within one linear color developing region 120 . Specifically, in the sub-pixel 130 in the center of the color-forming region 120 in the line direction, the taper angle of the inclination angle of the wall surface is large (see FIG. In the pixel 130, the taper angle of the inclination angle of the wall surface is small (see FIG. 10B ).

在由线状隔堤规定的线状的涂敷区域内涂覆有机功能层的材料液,形成线状的有机功能层时,在材料液干燥的过程中,有时材料液被拉向涂敷区域的线方向的端部,有机功能层的线方向的膜厚不均匀。但是,如本实施方式那样,在一个线状的涂敷区域中,通过使线方向端部的壁面的倾斜角度也小于线方向中央部的壁面的倾斜角度,能够防止材料液被拉向涂敷区域的线方向的端部。When the material liquid of the organic functional layer is coated in the linear coating area defined by the linear bank to form a linear organic functional layer, the material liquid is sometimes pulled toward the coating area during the drying process of the material liquid. At the end of the linear direction, the film thickness of the organic functional layer in the linear direction is not uniform. However, as in the present embodiment, by making the inclination angle of the wall surface at the end portion in the line direction smaller than the inclination angle of the wall surface at the center portion in the line direction in one linear application region, it is possible to prevent the material liquid from being pulled toward the application area. The end of the line direction of the region.

因此,根据本实施方式,即使在线状的涂覆区域内涂覆有机功能层的材料液而形成线状的有机功能层时,也能够对有机功能层的线方向的膜厚的偏差进行校正,从而获得沿线方向上具有均匀膜厚的有机功能层。Therefore, according to this embodiment, even when the material liquid of the organic functional layer is coated in the linear coating region to form the linear organic functional layer, the deviation of the film thickness in the linear direction of the organic functional layer can be corrected, Thus, an organic functional layer having a uniform film thickness along the line direction is obtained.

(实施方式3)(Embodiment 3)

在实施方式3中,说明根据子像素的位置,像素电极的剖面形状不同的本发明的有机EL显示面板。In Embodiment 3, the organic EL display panel of the present invention in which the cross-sectional shape of the pixel electrode differs according to the positions of the sub-pixels will be described.

图11A是实施方式3的有机EL显示面板300的平面图。图11B是图11A所示的有机EL显示面板300的AA线处的剖面图。11A is a plan view of an organic EL display panel 300 according to Embodiment 3. FIG. FIG. 11B is a cross-sectional view along line AA of the organic EL display panel 300 shown in FIG. 11A .

实施方式3的有机EL显示面板300除了发出同色的光的子像素具有的涂覆区域的壁面的倾斜角度相同而发出同色的光的子像素具有的像素电极的剖面形状不同以外,其他与实施方式1的有机EL显示面板100相同。对与有机EL显示面板100相同的构成要素标注相同附图标记,并省略其说明。The organic EL display panel 300 of the third embodiment is the same as the embodiment 3 except that the inclination angles of the walls of the coating regions of the sub-pixels emitting the same-color light are the same and the cross-sectional shapes of the pixel electrodes of the sub-pixels emitting the same-color light are different. 1 organic EL display panel 100 is the same. The same reference numerals are attached to the same constituent elements as those of the organic EL display panel 100 , and description thereof will be omitted.

如图11B所示,在实施方式3的有机EL显示面板300中,各个子像素130具有凹曲状的像素电极450。这里所谓“像素电极为凹曲状”是指,像素电极的功能层侧的表面是曲面,中央部向基板侧凹陷。As shown in FIG. 11B , in the organic EL display panel 300 of Embodiment 3, each sub-pixel 130 has a concavely curved pixel electrode 450 . Here, "the pixel electrode is concavely curved" means that the surface of the pixel electrode on the functional layer side is a curved surface, and the central part is concave toward the substrate side.

通常在像素电极上涂敷形成的有机功能层的表面(与对向电极相对的面)呈凹曲状(参照图2)。因此,若有机功能层的底面(与基板相对的面)是平坦的,则子像素内的有机功能层的膜厚不均匀。另一方面,如本实施方式那样,如果使像素电极450为凹曲状,则能够使涂敷形成在像素电极450上的有机功能层180的底面的形状为凹曲状。由此,能够使有机功能层的表面的形状与底面的形状匹配,从而能够使子像素内的有机功能层的膜厚均匀。Usually, the surface (the surface opposite to the counter electrode) of the organic functional layer formed by coating on the pixel electrode has a concave shape (see FIG. 2 ). Therefore, if the bottom surface (the surface facing the substrate) of the organic functional layer is flat, the film thickness of the organic functional layer in the sub-pixel will be uneven. On the other hand, if the pixel electrode 450 is concavely curved as in the present embodiment, the shape of the bottom surface of the organic functional layer 180 coated and formed on the pixel electrode 450 can be concavely curved. Thereby, the shape of the surface of the organic functional layer can be matched with the shape of the bottom surface, and the film thickness of the organic functional layer in the sub-pixel can be made uniform.

为了使像素电极450为凹曲状,例如在基板110上形成凹曲部,在凹曲部上形成像素电极450即可。为了在基板110上形成凹曲部,也可以对基板110直接进行湿法蚀刻或干法蚀刻,也可以在形成凹曲部的面上配置光敏性树脂层,对光敏性树脂层进行曝光,进行显像并对凹曲部进行图案化。In order to form the pixel electrode 450 into a concave shape, for example, a concave portion is formed on the substrate 110 and the pixel electrode 450 may be formed on the concave portion. In order to form the concave portion on the substrate 110, the substrate 110 may also be wet-etched or dry-etched directly, or a photosensitive resin layer may be disposed on the surface where the concave portion is formed, and the photosensitive resin layer may be exposed to light. Develop and pattern the concavities.

在本实施方式中,其特征在于,根据子像素的配置位置,像素电极的剖面形状不同。更具体而言,各个子像素130具有与各个子像素130具有的有机功能层180的形状匹配的截面形状的像素电极450。例如,在有机功能层180偏向基板110的端部侧的子像素130X中,像素电极450也具有与有机功能层180同样偏向的形状。另一方面,在有机功能层180不偏向基板110的端部侧的子像素130Y中,像素电极450的形状也不偏向。以下,参照附图,说明像素电极450的具体形状。The present embodiment is characterized in that the cross-sectional shape of the pixel electrode differs depending on the arrangement positions of the sub-pixels. More specifically, each sub-pixel 130 has a pixel electrode 450 having a cross-sectional shape matching the shape of the organic functional layer 180 that each sub-pixel 130 has. For example, in the sub-pixel 130X where the organic functional layer 180 is oriented toward the end of the substrate 110 , the pixel electrode 450 also has a shape oriented similarly to that of the organic functional layer 180 . On the other hand, in the sub-pixel 130Y where the organic functional layer 180 is not deviated toward the end side of the substrate 110 , the shape of the pixel electrode 450 is also not deviated. Hereinafter, a specific shape of the pixel electrode 450 will be described with reference to the drawings.

图12A是图11B所示的子像素130RX的放大图,图12B是图11B所示的子像素的130RY的放大图。如图12A所示,子像素130RX具有的像素电极450X的底点Z比像素电极450X的中心S位于基板110的中心侧。这样,通过将像素电极450X的底点偏移至基板110的中心侧,由此即使有机功能层180RX偏向基板110的端部侧,也能够使有机功能层180RX的膜厚均匀。其结果,子像素130RX具有的有机功能层180RX的膜厚T与子像素130RY具有的有机功能层180RY的膜厚T’一样。FIG. 12A is an enlarged view of sub-pixel 130RX shown in FIG. 11B , and FIG. 12B is an enlarged view of sub-pixel 130RY shown in FIG. 11B . As shown in FIG. 12A , the bottom point Z of the pixel electrode 450X of the sub-pixel 130RX is located on the center side of the substrate 110 relative to the center S of the pixel electrode 450X. In this way, by shifting the bottom point of the pixel electrode 450X to the center of the substrate 110 , even if the organic functional layer 180RX is biased toward the end of the substrate 110 , the film thickness of the organic functional layer 180RX can be made uniform. As a result, the film thickness T of the organic functional layer 180RX included in the sub-pixel 130RX is the same as the film thickness T' of the organic functional layer 180RY included in the sub-pixel 130RY.

另一方面,如图12B所示,子像素130RY具有的像素电极450Y中,像素电极450Y的底点Z’位于像素电极450Y的中心。这样,在本实施方式中,子像素130X的像素电极450X的底点Z比像素电极150X的中心S位于基板110的中心侧,像素电极450X的底点Z与像素电极450X的中心S之间的间隔大于子像素130Y的像素电极450Y的底点Z’与像素电极450Y的中心S’之间的间隔。On the other hand, as shown in FIG. 12B , in the pixel electrode 450Y included in the sub-pixel 130RY, the bottom point Z' of the pixel electrode 450Y is located at the center of the pixel electrode 450Y. In this way, in this embodiment, the bottom point Z of the pixel electrode 450X of the sub-pixel 130X is located on the center side of the substrate 110 than the center S of the pixel electrode 150X, and the distance between the bottom point Z of the pixel electrode 450X and the center S of the pixel electrode 450X is The interval is greater than the interval between the bottom point Z′ of the pixel electrode 450Y and the center S′ of the pixel electrode 450Y of the sub-pixel 130Y.

这样,通过使像素电极的截面形状与有机功能层的形状匹配,能够使基板的端部的子像素的有机功能层的膜厚均匀。其结果,能够对通过涂覆法形成的有机功能层180的在像素间的偏差进行校正。In this way, by matching the cross-sectional shape of the pixel electrode to the shape of the organic functional layer, the film thickness of the organic functional layer of the sub-pixels at the edge of the substrate can be made uniform. As a result, it is possible to correct the variation between pixels of the organic functional layer 180 formed by the coating method.

另外,在本实施方式中与与实施方式1相同,发出同色的光的子像素具有的像素电极的底点与中心点之间的距离优选随着从基板的端部朝向干燥中心点逐渐变小。Also, in this embodiment, as in Embodiment 1, it is preferable that the distance between the bottom point and the center point of the pixel electrode of the sub-pixel emitting light of the same color gradually decreases from the edge of the substrate toward the dry center point. .

本申请主张基于2009年6月29日提交的特愿第2009-154240号的优先权。该申请说明书中所记载的内容,全部被本申请说明书引用。This application claims priority based on Japanese Patent Application No. 2009-154240 filed on June 29, 2009. All the content described in this application specification is referred by this application specification.

工业实用性Industrial Applicability

根据本发明,能够提供亮度高的有机EL显示面板。According to the present invention, it is possible to provide an organic EL display panel with high brightness.

Claims (6)

1. organic EL display panel comprises:
Substrate, it has the color development zone of parallel plural wire; And
Plural sub-pixel is arranged in described color development zone the one row,
Described color development zone comprises: arranged the color development zone of the sub-pixel that sends red light, the color development zone of having arranged the sub-pixel that sends green light and the color development zone of having arranged the sub-pixel that sends blue light,
Described sub-pixel has respectively: pixel electrode, and it is configured on the described substrate; Organic function layer, its coating are formed on the described pixel electrode; Counter electrode, it is configured on the described organic function layer; And the separation levee of positive taper, it is configured for forming the wall in the zone of described organic function layer,
The angle of inclination of the wall of end side in the wall in the zone that will form described organic function layer, described substrate is set at tilt angle alpha, and when the angle of inclination that will form the wall of center side in the wall in zone of described organic function layer, described substrate is set at inclination angle beta, at the sub-pixel X of the color development zone X that is arranged in the end that is arranged in described substrate, described tilt angle alpha is less than described inclination angle beta.
2. organic EL display panel as claimed in claim 1,
The described tilt angle alpha among the described sub-pixel X and the difference of described inclination angle beta are greater than sending whole-colored light with described sub-pixel X and being arranged in the described tilt angle alpha of sub-pixel Y of color development zone Y of the central portion that is arranged in described substrate and described inclination angle beta poor.
3. organic EL display panel as claimed in claim 1,
The zone that forms the described organic function layer that each described sub-pixel has around surround by described separation levee.
4. organic EL display panel as claimed in claim 1 forms the zone that a row ground is arranged in the described organic function layer that the plural sub-pixel in the described color development zone has and constitutes by described separation levee zone that stipulate, a wire.
5. organic EL display panel as claimed in claim 4,
In the color development zone of a described wire, the angle of inclination of wall that forms the zone of the described organic function layer that the sub-pixel of the central portion be positioned at described line direction has is positioned at the angle of inclination of wall in the zone of the described organic function layer that the sub-pixel of the end of described line direction has greater than formation.
6. organic EL display panel as claimed in claim 1,
Described organic function layer comprises organic luminous layer and hole transporting layer.
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