CN101803801B - Humectant for smoke - Google Patents
Humectant for smoke Download PDFInfo
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- CN101803801B CN101803801B CN 201010142981 CN201010142981A CN101803801B CN 101803801 B CN101803801 B CN 101803801B CN 201010142981 CN201010142981 CN 201010142981 CN 201010142981 A CN201010142981 A CN 201010142981A CN 101803801 B CN101803801 B CN 101803801B
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- humectant
- pure water
- smoke
- carbon fatty
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- 239000003906 humectant Substances 0.000 title claims abstract description 48
- 239000000779 smoke Substances 0.000 title claims abstract description 29
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 62
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 235000011187 glycerol Nutrition 0.000 claims abstract description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 16
- 229930195729 fatty acid Natural products 0.000 claims abstract description 16
- 239000000194 fatty acid Substances 0.000 claims abstract description 16
- -1 carbon fatty alcohols Chemical class 0.000 claims description 34
- 229910052799 carbon Inorganic materials 0.000 claims description 30
- 241000208125 Nicotiana Species 0.000 claims description 22
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 20
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 18
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 10
- 239000005643 Pelargonic acid Substances 0.000 claims description 8
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000008213 purified water Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 10
- 239000002253 acid Substances 0.000 description 6
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 6
- 230000003020 moisturizing effect Effects 0.000 description 4
- 235000019504 cigarettes Nutrition 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical class OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 150000001323 aldoses Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a humectant for smoke, which contains the following ingredients in parts by weight in the formula thereof: 1-17 parts of purified water, 1-27 parts of glycerin, 28-65 parts of polycarbon aliphatic alcohol and 15-85 parts of polycarbon fatty acid. The humectant for smoke according to the invention can not only preserve moisture, but can also preserve humidity.
Description
Technical field
The present invention relates to a kind of humectant for smoke, this humectant is for keeping tobacco elasticity, improve the anti-breaking capacity of pipe tobacco, belonging to the additive of tobacco business.
Background technology
Humectant is in the cigarette manufacture process, in order to strengthen the anti-processability of tobacco, reduces rough broken, the loss that adds man-hour, keeps simultaneously toughness and moisture content, and a kind of additive that adds.The main component of tradition humectant is generally the polyhydroxy substances such as glycerine and propane diols, the main purpose of this type of humectant is to keep the moisture content of pipe tobacco in process, improve the anti-processability of pipe tobacco, it is mainly to reach the purpose of pipe tobacco moisturizing according to the affinity of Semi-polarity group and hydrone.Yet, this adhesion a little less than, can not bring into play good humectation effect.And to keeping of finished cigarettes moisture content, suck comfort level to improve effect also not ideal.In addition, these humectants mainly come tobacco is produced the humectation effect by its hygroscopicity, but without moisture-proof role.In addition, the glycerine price is not only relatively high, and main is that its use amount can not be excessive, otherwise can have a strong impact on the mouthfeel of sucking.The relatively poor xylitol of effect, the humectant of glucitols have precipitation when long storage time, easily solidify when temperature is low, therefore are not easy to production and application.
Desirable humectant should have moisturizing and moistureproof two kinds of effects concurrently, makes cigarette remain metastable moisture content.The compound humectants of Novel tobacco such as some tobacco sealers, bionical humectant (FSB), sucrose ester by forming oil isolated from water double sublayer diaphragm on tobacco surface, thereby have played the humectation effect.Therefore, the exploitation of humectant needs to carry out from hydrophily water conservation material and hydrophobicity water proof material two aspects.Hydrophobicity water proof substance forms one deck water-separating film at tobacco leaf surface, thereby plays the effect of damp proof insulation, and polyhydric aliphatic acid has a great impact the formation of water-separating film, and the chain length of aliphatic acid is to affect the film formed main cause of water proof.
The disclosed humectant of publication number CN1204482 is comprised of aldose, alkyl polyols, pentose etc., and this humectant belongs to traditional humectant, does not fundamentally solve the effect of humectation; The disclosed humectant of publication number CN1985687 is the humectation effect that realizes by the aqueous solution that adds pyrrolidone carboxylic acid salt, yet its raw materials used costliness is difficult for obtaining.
Therefore, the tobacco business urgent need is a kind of at present has better moisturizing humectation and has good fixation effect and cost humectant low, easy to use.
Summary of the invention
In order to solve the defective that exists in prior art, the invention provides a kind of humectant for smoke, comprise pure water, glycerine, many carbon fatty alcohols and many carbon fatty acids.
Wherein, pure water content is the 1-17 weight portion, and glycerol content is the 1-27 weight portion, and many carbon fatty alcohols content is the 28-65 weight portion, and many carbon fatty acids content is the 15-85 weight portion.
Choosing is more arranged, and pure water content is the 3-15 weight portion, and glycerol content is the 3-25 weight portion, and many carbon fatty alcohols content is the 32-60 weight portion, and many carbon fatty acids content is the 20-80 weight portion.
Most preferably, pure water content is 5 weight portions, and glycerol content is 10 weight portions, and many carbon fatty alcohols content is 50 weight portions, and many carbon fatty acids content is 35 weight portions.
Wherein, described many carbon fatty alcohols are C
5-12Fatty alcohol, be preferably selected from hexanol, enanthol, nonyl alcohol or decyl alcohol; Described many carbon fatty acids are C
5-12Aliphatic acid, be preferably selected from pelargonic acid or hendecoic acid.
Humectant for smoke of the present invention is to use conventional method to be prepared, specifically comprise the steps: the described component except pure water is positioned in closed container, at the temperature of 35-55 ℃ uniform stirring 1-5 hour, add afterwards pure water, at the temperature of 25-30 ℃ uniform stirring 1-5 hour.
Humectant for smoke of the present invention is to carry out using method according to conventional method, namely evenly is sprayed on tobacco leaf in the leaves moisting operation.
The specific embodiment
The invention will be further described below in conjunction with preferred embodiment, it should be understood that these embodiment only are used for the purpose of illustration, never limit protection scope of the present invention.
Humectant for smoke of the present invention comprises pure water, glycerine, many carbon fatty alcohols and many carbon fatty acids.
Wherein, pure water content is the 1-17 weight portion, and glycerol content is the 1-27 weight portion, and many carbon fatty alcohols content is the 28-65 weight portion, and many carbon fatty acids content is the 15-85 weight portion.
Choosing is more arranged, and pure water content is the 3-15 weight portion, and glycerol content is the 3-25 weight portion, and many carbon fatty alcohols content is the 32-60 weight portion, and many carbon fatty acids content is the 20-80 weight portion.
Most preferably, pure water content is 5 weight portions, and glycerol content is 10 weight portions, and many carbon fatty alcohols content is 50 weight portions, and many carbon fatty acids content is 35 weight portions.
Wherein, described many carbon fatty alcohols are C
5-12Fatty alcohol, be preferably selected from hexanol, enanthol, nonyl alcohol or decyl alcohol; Described many carbon fatty acids are C
5-12Aliphatic acid, be preferably selected from pelargonic acid or hendecoic acid.
Humectant for smoke of the present invention adopts conventional method to be prepared, be specially: the described component except pure water is positioned in closed container, at the temperature of 35-55 ℃ uniform stirring 1-5 hour, add afterwards pure water, at the temperature of 25-30 ℃ uniform stirring 1-5 hour.
Embodiment 1
Pure water content is 5 weight portions, and glycerol content is 15 weight portions, and hexanol content is 50 weight portions, and n-nonanoic acid content is 30 weight portions.Described component except pure water is positioned in closed container, and uniform stirring is 2.5 hours at the temperature of 35 ℃, adds afterwards pure water, and uniform stirring is 3 hours at the temperature of 30 ℃, obtains humectant for smoke 1.
Embodiment 2
Pure water content is 10 weight portions, and glycerol content is 10 weight portions, and nonyl alcohol content is 55 weight portions, and undecanoic acid content is 30 weight portions.Described component except pure water is positioned in closed container, and uniform stirring is 2 hours at the temperature of 40 ℃, adds afterwards pure water, and uniform stirring is 4 hours at the temperature of 30 ℃, obtains humectant for smoke 2.
Embodiment 3
Pure water content is 5 weight portions, and glycerol content is 10 weight portions, and decyl alcohol content is 50 weight portions, and pelargonic acid content is 35 weight portions.Described component except pure water is positioned in closed container, and uniform stirring is 2 hours at the temperature of 35 ℃, adds afterwards pure water, and uniform stirring is 4 hours at the temperature of 30 ℃, obtains humectant for smoke 3.
Embodiment 4
Pure water content is 1 weight portion, and glycerol content is 1 weight portion, and enanthol content is 28 weight portions, and pelargonic acid content is 15 weight portions.Described component except pure water is positioned in closed container, and uniform stirring is 2 hours at the temperature of 35 ℃, adds afterwards pure water, and uniform stirring is 4 hours at the temperature of 30 ℃, obtains humectant for smoke 4.
Embodiment 5
Pure water content is 17 weight portions, and glycerol content is 27 weight portions, and enanthol content is 65 weight portions, and pelargonic acid content is 85 weight portions.Described component except pure water is positioned in closed container, and uniform stirring is 2 hours at the temperature of 35 ℃, adds afterwards pure water, and uniform stirring is 4 hours at the temperature of 30 ℃, obtains humectant for smoke 5.
Embodiment 6
Pure water content is 3 weight portions, and glycerol content is 3 weight portions, and enanthol content is 32 weight portions, and pelargonic acid content is 20 weight portions.Described component except pure water is positioned in closed container, and uniform stirring is 2 hours at the temperature of 35 ℃, adds afterwards pure water, and uniform stirring is 4 hours at the temperature of 30 ℃, obtains humectant for smoke 6.
Embodiment 7
Pure water content is 15 weight portions, and glycerol content is 25 weight portions, and decyl alcohol content is 60 weight portions, and pelargonic acid content is 80 weight portions.Described component except pure water is positioned in closed container, and uniform stirring is 2 hours at the temperature of 35 ℃, adds afterwards pure water, and uniform stirring is 4 hours at the temperature of 30 ℃, obtains humectant for smoke 7.
The using method of humectant for smoke of the present invention be first with humectant with after other feed liquid is evenly mixed, utilize existing atomising device, be sprayed on uniformly tobacco leaf and get final product.
Comparative Examples 1
Compared to traditional humectant (as glycerine, propane diols), use the humectant for smoke 1-7 of embodiment 1-7, the anti-breaking capacity of pipe tobacco improves 3-5 and doubly (measures according to YC/T 1782003), obviously improve the dry sensation of flue gas, the amplitude of variation of moisture in cut tobacco is the 25-30% (Hunan C3F tobacco leaf measured value under 35% and 75% relative humidity) of traditional humectant.
Comparative Examples 2
The humectant for smoke 3 that will have humectant for smoke (according to the CN1204482 formulated) and embodiment 3 now compares, find to use humectant of the present invention, the anti-breaking capacity of pipe tobacco improves 3-5 doubly (to be measured according to YC/T 178 2003), and the amplitude of variation of moisture in cut tobacco is the 10-20% (Hunan C3F tobacco leaf measured value under 35% and 75% relative humidity) of existing humectant for smoke.
Above experiment shows, humectant for smoke of the present invention more can moisturizing and humectation than prior art.
The above is only preferred embodiment of the present invention, is only illustrative for the purpose of the present invention, and nonrestrictive.Those skilled in the art is understood, and can carry out many changes to it in the spirit and scope that claim of the present invention limits, revise, and even equivalence, but all will fall within the scope of protection of the present invention.
Claims (5)
1. a humectant for smoke, is characterized in that, comprises pure water, glycerine, many carbon fatty alcohols and many carbon fatty acids;
Wherein, described many carbon fatty alcohols are selected from enanthol, nonyl alcohol or decyl alcohol; Described many carbon fatty acids are pelargonic acid or hendecanoic acid;
The method for preparing described humectant for smoke, comprise the steps: the described component except pure water is positioned in closed container, at the temperature of 35-55 ℃ uniform stirring 1-5 hour, add afterwards pure water, at the temperature of 25-30 ℃ uniform stirring 1-5 hour.
2. humectant for smoke as claimed in claim 1, is characterized in that, pure water content is the 1-17 weight portion, and glycerol content is the 1-27 weight portion, and many carbon fatty alcohols content is the 28-65 weight portion, and many carbon fatty acids content is the 15-85 weight portion.
3. humectant for smoke as claimed in claim 1, is characterized in that, pure water content is the 3-15 weight portion, and glycerol content is the 3-25 weight portion, and many carbon fatty alcohols content is the 32-60 weight portion, and many carbon fatty acids content is the 20-80 weight portion.
4. humectant for smoke as claimed in claim 1, is characterized in that, pure water content is 5 weight portions, and glycerol content is 10 weight portions, and many carbon fatty alcohols content is 50 weight portions, and many carbon fatty acids content is 35 weight portions.
5. the using method of the described humectant for smoke of any one in claim 1-4, is characterized in that: be evenly to be sprayed on tobacco leaf in the leaves moisting operation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010142981 CN101803801B (en) | 2010-04-07 | 2010-04-07 | Humectant for smoke |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010142981 CN101803801B (en) | 2010-04-07 | 2010-04-07 | Humectant for smoke |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101803801A CN101803801A (en) | 2010-08-18 |
| CN101803801B true CN101803801B (en) | 2013-05-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010142981 Active CN101803801B (en) | 2010-04-07 | 2010-04-07 | Humectant for smoke |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796146B (en) * | 2012-08-02 | 2014-05-14 | 河南中烟工业有限责任公司 | Humectant for cigarettes and preparation method thereof |
| CN103844347B (en) * | 2014-03-26 | 2016-02-24 | 安徽中烟工业有限责任公司 | A kind of preparation method of degradable starch tobacco humectant of different degree of hydrolysis mixing |
| CN105167176B (en) * | 2015-08-18 | 2017-05-10 | 浙江中烟工业有限责任公司 | A kind of composite tobacco humectant and its preparation method and application |
| CN106235395A (en) * | 2016-08-09 | 2016-12-21 | 广西中烟工业有限责任公司 | A kind of tobacco humectant and its preparation method and application |
| CN106490676A (en) * | 2016-12-11 | 2017-03-15 | 钦州学院 | A kind of starchiness humectant for smoke and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051290A (en) * | 1989-10-31 | 1991-05-15 | 沃纳-兰伯特公司 | Encapsulated sweetener-flavor delivery system and method for its preparation |
| CN1066384A (en) * | 1991-05-04 | 1992-11-25 | 普罗格特-甘布尔公司 | cosmetic composition |
| CN1266656A (en) * | 1999-03-13 | 2000-09-20 | 坦恩－帕皮尔有限公司 | Cigarette |
| CN1649565A (en) * | 2002-04-26 | 2005-08-03 | 宝洁公司 | Fragrance delivery agent |
| CN101171976A (en) * | 2007-11-02 | 2008-05-07 | 云南瑞升烟草技术（集团）有限公司 | A moisturizing and flavoring additive and its preparation method |
-
2010
- 2010-04-07 CN CN 201010142981 patent/CN101803801B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051290A (en) * | 1989-10-31 | 1991-05-15 | 沃纳-兰伯特公司 | Encapsulated sweetener-flavor delivery system and method for its preparation |
| CN1066384A (en) * | 1991-05-04 | 1992-11-25 | 普罗格特-甘布尔公司 | cosmetic composition |
| CN1266656A (en) * | 1999-03-13 | 2000-09-20 | 坦恩－帕皮尔有限公司 | Cigarette |
| CN1649565A (en) * | 2002-04-26 | 2005-08-03 | 宝洁公司 | Fragrance delivery agent |
| CN101171976A (en) * | 2007-11-02 | 2008-05-07 | 云南瑞升烟草技术（集团）有限公司 | A moisturizing and flavoring additive and its preparation method |
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| CN101803801A (en) | 2010-08-18 |
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Inventor after: An Yi Inventor after: Chen Jianjun Inventor after: Ma Changli Inventor after: Wang Wei Inventor after: Zhang Li Inventor before: An Yi |
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