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CN100419845C - Printer and method of manufacturing electronic circuit and display - Google Patents

Printer and method of manufacturing electronic circuit and display Download PDF

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Publication number
CN100419845C
CN100419845C CNB03821069XA CN03821069A CN100419845C CN 100419845 C CN100419845 C CN 100419845C CN B03821069X A CNB03821069X A CN B03821069XA CN 03821069 A CN03821069 A CN 03821069A CN 100419845 C CN100419845 C CN 100419845C
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layer
display
printing
field
make
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CN1679079A (en
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约翰·丹尼尔斯
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/14Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base
    • G03G15/16Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer
    • G03G15/1625Apparatus for electrographic processes using a charge pattern for transferring a pattern to a second base of a toner pattern, e.g. a powder pattern, e.g. magnetic transfer on a base other than paper
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00Electroluminescent light sources
    • H05B33/10Apparatus or processes specially adapted to the manufacture of electroluminescent light sources
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/06Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09GARRANGEMENTS OR CIRCUITS FOR CONTROL OF INDICATING DEVICES USING STATIC MEANS TO PRESENT VARIABLE INFORMATION
    • G09G5/00Control arrangements or circuits for visual indicators common to cathode-ray tube indicators and other visual indicators
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • H10K71/12Deposition of organic active material using liquid deposition, e.g. spin coating
    • H10K71/13Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Theoretical Computer Science (AREA)
  • Printers Or Recording Devices Using Electromagnetic And Radiation Means (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Electroluminescent Light Sources (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)

Abstract

制成一种显示薄片(224),包括用于显示信息的发光像素,它是通过印制导电聚合物微囊(218)制成。通本发明的打印方法在离散位置提供电激活微囊(218)制成电子器件。本发明打印方法制作的电池薄片(212)提供电能给显示元件。利用本发明打印方法,可以在柔性基片(210)上制作薄型、轻质、柔性、明亮、无线显示器。用户输入薄片(222)接收用户输入并产生用户输入信号。

A display sheet (224) is made, including light-emitting pixels for displaying information, which is made by printing conductive polymer microcapsules (218). The electronic device is made by providing electrically activated microcapsules (218) at discrete locations through the printing method of the present invention. The battery sheet (212) made by the printing method of the present invention provides electrical energy to the display element. Using the printing method of the present invention, a thin, lightweight, flexible, bright, wireless display can be made on a flexible substrate (210). The user input sheet (222) receives user input and generates user input signals.

Description

打印机以及制造电子电路和显示器的方法 Printer and method of manufacturing electronic circuits and displays

技术领域 technical field

本发明涉及打印机以及制造电子电路和显示器的方法。更具体地说,本发明涉及能够利用微囊封装材料制成各种电子电路元件和显示装置的打印机,以及利用场吸引微囊制作电子电路和显示器的方法。The invention relates to printers and methods of making electronic circuits and displays. More specifically, the present invention relates to a printer capable of fabricating various electronic circuit elements and display devices using microcapsule encapsulation materials, and a method of fabricating electronic circuits and displays using field-attracting microcapsules.

背景技术 Background technique

最近以来,人们一直在开发利用场致发光材料像素的薄型、柔性显示器,例如,有机发光二极管(OLED)。这种显示器不需要任何的背面照明,因为每个像素元产生它自己的光。典型的是,利用旋转涂敷或蒸发技术沉积有机材料。发给May的US Patent No.6,395,328公开一种有机发光彩色显示器,其中通过沉积和形成图形的发光材料层,制成多色器件。发给Friend et al.的US Patent No.5,965,979公开一种制作发光器件的方法,通过叠层两个自支承元件,其中至少一个元件有发光层。发给Strum et al.的US Patent No.6,087,196公开一种利用喷墨打印制成有机半导体器件的制造方法。发给Towna et al.的US Patent No.6,416,885公开一种场致发光器件,其中有机发光层与电荷注入层之间的导电聚合物层抵挡电荷载流子的横向扩散以改进显示特性。发给Yamazaki et al.的US Patent No.6,48,300B1公开一种利用凸版印刷或丝网印刷法制造电光器件的方法。发给Pichler et al.的USPatent No.6,402,579公开一种有机发光器件,其中利用DC磁控管溅射制成多层结构。发给Jacobson的US Patent No.6,50,687B1公开一种电子可寻址微囊封装的墨粉和显示器。More recently, thin, flexible displays utilizing pixels of electroluminescent materials, such as organic light emitting diodes (OLEDs), have been developed. Such displays do not require any backlighting, since each pixel generates its own light. Typically, the organic material is deposited using spin-coating or evaporation techniques. US Patent No. 6,395,328 to May discloses an organic light emitting color display in which a multicolor device is made by depositing and patterning layers of light emitting material. US Patent No. 5,965,979 to Friend et al. discloses a method of making a light emitting device by laminating two self-supporting elements, at least one of which has a light emitting layer. US Patent No. 6,087,196 to Strum et al. discloses a method of fabricating organic semiconductor devices using inkjet printing. US Patent No. 6,416,885 to Towna et al. discloses an electroluminescent device in which a conductive polymer layer between an organic light emitting layer and a charge injection layer resists lateral diffusion of charge carriers to improve display characteristics. US Patent No. 6,48,300 B1 to Yamazaki et al. discloses a method of manufacturing electro-optic devices using letterpress printing or screen printing. US Patent No. 6,402,579 to Pichler et al. discloses an organic light emitting device in which a multilayer structure is made by DC magnetron sputtering. US Patent No. 6,50,687 B1 to Jacobson discloses an electronically addressable microencapsulated toner and display.

现有技术指出,利用各种制造技术,有机发光像素可以制成显示器。例如,′196专利说明利用喷墨打印机可以制造OLED。′687专利说明利用微囊封装的电激活材料可以制成各种电子电路元件。The prior art indicates that organic light-emitting pixels can be fabricated into displays using various fabrication techniques. For example, the '196 patent teaches that OLEDs can be fabricated using an inkjet printer. The '687 patent teaches that a variety of electronic circuit components can be fabricated using microencapsulated electro-active materials.

现有技术的专利内容说明,可以制造一种薄型、轻质、柔性、明亮显示器,其中利用包括喷墨打印技术的各种方法制成OLED像素。然而,没有一种现有技术涉及制造包含用户输入机构的这种显示器的实际要求。此外,没有一种现有技术确认需要格式化和发射诸如HTML页面的内容,因此,它不需要基本的板上数据处理可以显示该内容。诸如微处理器的数据处理元件消耗功率,是相对地昂贵,很难制造和要求复杂的电路。因此,有基本机上处理能力的薄型、明亮、无线显示器严重限制显示器的有效性。此外,没有一种现有技术提供这样的显示器,它能够同时接收两个或多个显示信息信号,例如,可以同时观看电视节目和显示网页。所以,需要一种制造薄型、轻质、柔性、明亮、无线显示器的方法,该显示器有实用的用户输入机构,其结构可以使功率密度最大化和机载电池的高效率功率消耗,且至少部分地可以利用打印方法制造。The prior art patent claims that it is possible to manufacture a thin, lightweight, flexible, bright display in which OLED pixels are made using various methods including inkjet printing techniques. However, none of the prior art addresses the practical requirements of making such displays that incorporate user input mechanisms. Furthermore, none of the prior art recognizes the need to format and transmit content such as HTML pages so that it can be displayed without basic on-board data processing. Data processing elements such as microprocessors consume power, are relatively expensive, are difficult to manufacture and require complex circuitry. Therefore, thin, bright, wireless displays with basic on-board processing power severely limit the effectiveness of the display. Furthermore, none of the prior art provides a display capable of simultaneously receiving two or more display information signals, for example, viewing a television program and displaying a web page simultaneously. Therefore, there is a need for a method of fabricating a thin, lightweight, flexible, bright, wireless display with a practical user input mechanism that is structured to maximize power density and efficient power dissipation from an on-board battery while at least partially The ground can be fabricated using printing methods.

发明内容 Contents of the invention

本发明克服现有技术中的缺点。本发明的一个目的是提供一种利用微囊封装电激活材料制作电子器件的打印机。本发明的另一个目的是提供一种制造薄型、轻质、明亮、无线显示器的方法。The present invention overcomes the disadvantages of the prior art. It is an object of the present invention to provide a printer for fabricating electronic devices using microencapsulated electroactive materials. Another object of the present invention is to provide a method of manufacturing a thin, lightweight, bright, wireless display.

按照本发明,提供一种局部可变的吸引场元件,用于有选择地吸引场吸引微囊。控制局部可变的吸引场元件,使它有选择地加吸引场到可以制成场吸引微囊层的各个位置。场吸引微囊包含电激活材料,用于吸引到所述吸引场元件的吸引场位置。可以根据场吸引微囊层的成分和尺寸制作预定的电子电路元件。局部可变的吸引场元件有形成的光电和/或光磁涂层,用于响应入射到涂层上的光而产生吸引场。涂层可以蚀刻成像素。In accordance with the present invention, a locally variable attractive field element is provided for selectively attracting field-attracting microcapsules. The locally variable attracting field element is controlled to selectively apply the attracting field to various locations where the field attracting microcapsule layer can be formed. The field-attracting microcapsules contain electroactive materials for attracting to the attracting field sites of the attracting field elements. Depending on the composition and size of the field-attracting microcapsule layer, predetermined electronic circuit components can be fabricated. Locally variable attractive field elements have optoelectronic and/or optomagnetic coatings formed for generating an attractive field in response to light incident on the coating. The coating can be etched into pixels.

可以引导光束入射到涂层上以产生磁场和/或静电场,为的是在局部可变吸引场元件的对应离散位置上形成各自的吸引场。引导装置可以包括:多个光纤光波导。引导装置还可以包括:产生光束的光束源和在至少一个光电涂层或光磁涂层上扫描光束的扫描装置,用于产生吸引场,为的是在至少一个光电涂层或光磁涂层的对应离散位置上形成各自的吸引场。局部可变的吸引场元件还包括:基片上产生光的发光涂层,产生的光入射到至少一个光电涂层或光磁涂层上以产生至少一个静电吸引或磁吸引场。场吸引微囊可以是磁吸引微囊,其中局部可变的吸引场元件还包括:加磁场装置,用于加每个局部吸引场作为磁吸引场。场吸引微囊可以是静电吸引微囊,其中局部可变的吸引场元件还包括:加静电场装置,用于加每个局部吸引场作为静电吸引场。至少一些场吸引微囊可以包含至少一个热膨胀成分或热可熔化成分。这能使制作的器件有可选择的密度和尺寸,它影响制作电子器件的所需电气特性。Light beams may be directed to be incident on the coating to generate magnetic and/or electrostatic fields in order to form respective attractive fields at corresponding discrete locations of the locally variable attractive field elements. The guiding means may comprise: a plurality of fiber optic waveguides. The guiding means may further comprise: a beam source for generating a light beam and a scanning device for scanning the light beam on at least one optoelectronic coating or optomagnetic coating for generating an attractive field for Attractive fields are formed on the corresponding discrete positions of . The locally variable attractive field element also includes: a luminescent coating on the substrate that generates light incident on at least one optoelectronic coating or optomagnetic coating to generate at least one electrostatic or magnetic attraction field. The field-attracting microcapsules may be magnetically-attracting microcapsules, wherein the locally variable attracting field element further includes: a magnetic field applying device for applying each local attracting field as a magnetic attracting field. The field-attracting microcapsules may be electrostatically-attracting microcapsules, wherein the locally variable attracting field element further includes: an electrostatic field-applying device for applying each local attracting field as an electrostatic attracting field. At least some of the field-attracting microcapsules may contain at least one thermally expandable or thermally meltable component. This enables the fabrication of devices with selectable densities and dimensions, which affect the desired electrical characteristics of fabricated electronic devices.

按照本发明,提供一种制作显示器的方法,它有利用打印方法能制造的元件。提供一种作为支承结构的支承基片,利用微囊打印方法可以在该基片上制作元件。制成的显示层包含显示信息的发光像素。通过印制发光导电聚合物微囊的像素图形,可以制作发光像素。在支承基片上的离散位置上印制电激活微囊图形,制成包含电子器件的电子电路层。制成的用户输入层用于接收用户输入并产生用户输入信号,用户输入层的制作是通过印制导电元的网格。在磁场穿过导电元时,每个导电元产生可检测的电信号。制成的电池层提供电能给电子电路层元件,用户输入层元件和显示层元件。电池层可以包含第一电流收集层。阳极层印制在第一电流收集层上。电解质层印制在阳极层上,和阴极层印制在电解质层上。第二电流收集层印制在阴极层上。According to the present invention, there is provided a method of manufacturing a display having elements manufacturable by printing methods. A support substrate is provided as a support structure on which elements can be fabricated using a microcapsule printing method. The resulting display layer contains light-emitting pixels that display information. Light-emitting pixels can be fabricated by printing pixel patterns of light-emitting conductive polymer microcapsules. A pattern of electroactive microcapsules is printed at discrete locations on a support substrate to form an electronic circuit layer containing electronic devices. The fabricated user input layer is used to receive user input and generate user input signals, and the user input layer is fabricated by printing a grid of conductive elements. Each conductive element generates a detectable electrical signal when a magnetic field passes through the conductive elements. The resulting battery layer provides power to the electronic circuit layer elements, user input layer elements and display layer elements. The battery layer may comprise a first current collection layer. An anode layer is printed on the first current collecting layer. An electrolyte layer is printed on the anode layer, and a cathode layer is printed on the electrolyte layer. A second current collecting layer is printed on the cathode layer.

显示层包含与每个发光像素连接的印制导电引线,在显示驱动元件的控制下,有选择地加电能到每个发光像素。发光像素是这样制成的,提供绝缘层,在绝缘层上印制包含导电材料线的y电极层,在y电极层上印制发光导电聚合物区的像素层,和在像素层上印制包含透明导电材料线的x电极层。The display layer includes printed conductive leads connected to each luminous pixel, and under the control of the display driving element, selectively supplies power to each luminous pixel. Light-emitting pixels are made by providing an insulating layer, printing a y-electrode layer containing lines of conductive material on the insulating layer, printing a pixel layer of light-emitting conductive polymer regions on the y-electrode layer, and printing An x-electrode layer comprising lines of transparent conductive material.

电子电路层可以包含信号接收元件,它包括:第一射频接收元件,用于接收第一射频上承载第一显示信息的第一显示信号;和第二射频接收元件,用于接收第二射频上承载第二显示信息的第二显示信号。显示驱动元件包括:信号处理元件,用于接收第一显示信号和第二显示信号并产生显示驱动信号。因此,本发明显示器能够同时在显示薄片的第一位置显示第一显示信息和在显示薄片的第二位置显示第二显示信息。电池薄片,显示薄片,用户输入薄片和电子电路薄片中至少一些元件是通过印制电激活材料以制成电路元件,它包括:电阻器,电容器,电感器,天线,导体和半导体器件。可以安装其他常规方法制造的电路元件到印制的导电区,例如,通过焊接或利用导电粘合剂。The electronic circuit layer may contain a signal receiving element, which includes: a first radio frequency receiving element, used to receive the first display signal carrying the first display information on the first radio frequency; and a second radio frequency receiving element, used to receive the first display signal on the second radio frequency A second display signal carrying second display information. The display driving component includes: a signal processing component for receiving the first display signal and the second display signal and generating a display driving signal. Therefore, the display of the present invention can simultaneously display the first display information at the first position where the sheet is displayed and the second display information at the second position where the sheet is displayed. Battery wafers, display wafers, user input wafers and electronic circuit wafers at least some of which are printed with electroactive materials to form circuit elements, including: resistors, capacitors, inductors, antennas, conductors and semiconductor devices. Circuit elements fabricated by other conventional methods may be mounted to the printed conductive areas, for example, by soldering or using conductive adhesives.

按照本发明的方法,提供作为支承结构有上表面的基片,利用微囊打印方法可以在该基片上制作元件。场吸引微囊层被吸引到基片的离散位置。场吸引微囊包含电激活材料。因此,可以制成预定的电子电路元件,它与场吸引微囊层的成分和尺寸有关。电激活材料有电子元件的电气性质,例如,导体,绝缘体,电阻器,半导体,电感器,磁性材料,压电材料,光电材料,或热电材料。场吸引微囊层可以有多个层次微囊堆积以形成所需的三维形状。本发明方法制作的电子电路元件有这样的电气性质,它与多个层次堆积的微囊层成分和三维形状的尺寸有关。According to the method of the invention, a substrate is provided as a support structure with an upper surface, on which substrate components can be produced by means of a microcapsule printing method. The field-attracting microcapsule layer is attracted to discrete locations on the substrate. Field-attracting microcapsules contain electroactive materials. Thus, predetermined electronic circuit components can be fabricated, depending on the composition and size of the field-attracting microcapsule layer. Electroactive materials have the electrical properties of electronic components, for example, conductors, insulators, resistors, semiconductors, inductors, magnetic materials, piezoelectric materials, photovoltaic materials, or pyroelectric materials. The field-attracting microcapsule layer can have multiple layers of microcapsules stacked to form a desired three-dimensional shape. The electronic circuit element produced by the method of the present invention has such electrical properties, which are related to the composition of the multi-layered microcapsule layer and the size of the three-dimensional shape.

附图说明 Description of drawings

图1是按照本发明打印机的示意图;Fig. 1 is the schematic diagram according to the printer of the present invention;

图2(a)是另一个微囊供应装置的剖面图,在制成电子电路成型微囊层之前有包含装置和分散在液体中的微囊;Figure 2(a) is a cross-sectional view of another microcapsule supply device, which has containment means and microcapsules dispersed in a liquid before making an electronic circuit forming microcapsule layer;

图2(b)是在制成电子电路成型微囊层之后图2(a)所示另一个微囊供应装置的剖面图;Fig. 2 (b) is the sectional view of another microcapsule supply device shown in Fig. 2 (a) after making the electronic circuit molding microcapsule layer;

图3(a)是有平坦微囊层的局部可变吸引场平板的剖面图;Fig. 3 (a) is the sectional view of the locally variable attraction field flat plate with flat microcapsule layer;

图3(b)是在局部可变吸引场平板工作面的平坦微囊层上堆积三微结构电子电路成型微囊的示意图;Fig. 3 (b) is the schematic diagram of stacking three microstructure electronic circuit molding microcapsules on the flat microcapsule layer of the flat plate working surface of the local variable attraction field;

图3(c)是在局部可变吸引场平板上显影和固化的三微电子电路的剖面图;Figure 3(c) is a cross-sectional view of three microelectronic circuits developed and cured on a locally variable attractive field plate;

图4(a)是电子电路元件成型微囊的示意图;Fig. 4 (a) is the schematic diagram of electronic circuit element forming microcapsule;

图4(b)是电子电路元件成型微囊的示意图,它包含有导电聚合物壳层的电解质内相和有导电聚合物壳层的金属内相;Fig. 4 (b) is the schematic diagram of the electronic circuit element molding microcapsule, and it comprises the electrolytic inner phase that has conductive polymer shell and the metallic inner phase that has conductive polymer shell;

图4(c)是无涂层电子电路元件成型微囊和显影剂微囊的示意图;Fig. 4 (c) is the schematic diagram of uncoated electronic circuit element forming microcapsule and developer microcapsule;

图4(d)是热可熔微囊的示意图;Fig. 4 (d) is the schematic diagram of thermofusible microcapsule;

图5(a)是局部可变吸引场平板部分的透视图,其中展示有相对弱附加场的像素,有相对强附加场的像素,以及有均匀场或无附加场的像素;Figure 5(a) is a perspective view of a portion of a locally variable attractive field slab, showing pixels with a relatively weak additional field, pixels with a relatively strong additional field, and pixels with a uniform field or no additional field;

图5(b)是图5(a)所示局部可变吸引场平板部分的正视图,其中展示有不同附加场强度的像素;Figure 5(b) is a front view of the part of the local variable attraction field shown in Figure 5(a), wherein pixels with different additional field strengths are shown;

图5(c)是局部可变吸引场平板部分的正视图,其中展示被吸引到不同附加场强度的三维结构微囊堆积;Figure 5(c) is a front view of a portion of a locally variable attraction field slab, showing the accumulation of three-dimensionally structured microcapsules attracted to different additional field strengths;

图6(a)是三维结构吸引微囊堆积的示意图;Figure 6(a) is a schematic diagram of the three-dimensional structure attracting microcapsules to accumulate;

图6(b)是三维结构热膨胀微囊堆积的示意图;Figure 6(b) is a schematic diagram of the stacking of thermally expandable microcapsules with a three-dimensional structure;

图7是同时显示三个接收显示信号的本发明薄型、轻质、柔性、明亮、无线显示器的示意图;Fig. 7 is a schematic diagram showing three thin, lightweight, flexible, bright and wireless displays of the present invention simultaneously displaying display signals;

图8是本发明薄型、轻质、柔性、明亮、无线显示器各薄片的示意图;Fig. 8 is a schematic diagram of each sheet of the thin, light, flexible, bright and wireless display of the present invention;

图9(a)是利用微囊打印机制作本发明薄型、轻质、柔性、明亮、无线显示器的实施例;Fig. 9(a) is an embodiment of making a thin, light, flexible, bright and wireless display of the present invention by using a microcapsule printer;

图9(b)表示导电线圈的网格,它是本发明薄型、轻质、柔性、明亮、无线显示器的部分用户输入薄片;Figure 9(b) shows a grid of conductive coils, which is part of the user input sheet for the thin, lightweight, flexible, bright, wireless display of the present invention;

图9(c)是利用本发明磁笔在磁检测网格上形成的磁笔划;Fig. 9 (c) is the magnetic stroke that utilizes the magnetic pen of the present invention to form on the magnetic detection grid;

图9(d)是导电线圈的分解图;Figure 9(d) is an exploded view of the conductive coil;

图9(e)是导电线圈的组装图;Figure 9(e) is an assembly diagram of the conductive coil;

图9(f)是两个导电线圈的剖面图;Figure 9(f) is a cross-sectional view of two conductive coils;

图9(g)是按照本发明所用柔性可充电电池支承片的放大剖面图;Figure 9(g) is an enlarged cross-sectional view of a flexible rechargeable battery support used in accordance with the present invention;

图9(h)是图9(g)所示本发明可充电电池结构制成的多单元支承片的剖面图;Figure 9(h) is a cross-sectional view of the multi-unit supporting sheet made of the rechargeable battery structure of the present invention shown in Figure 9(g);

图10(a)是吸引场元件实施例的侧视图,其中展示光纤光引导器,它引导光入射到透明基片上的光磁涂层;Figure 10(a) is a side view of an embodiment of an attracting field element showing a fiber optic light guide directing light incident on a optomagnetic coating on a transparent substrate;

图10(b)是图10(a)所示实施例的侧视图,其中吸引场元件还包含荧光涂层;Figure 10(b) is a side view of the embodiment shown in Figure 10(a), wherein the attracting field element also includes a fluorescent coating;

图10(c)是图10(b)所示实施例的侧视图,其中还包含光屏蔽层;Figure 10(c) is a side view of the embodiment shown in Figure 10(b), which also includes a light shielding layer;

图11(a)是吸引场元件的侧视图,它吸引有平坦结构的均匀微囊层;Figure 11 (a) is a side view of an attracting field element, which attracts a uniform microcapsule layer with a flat structure;

图11(b)是吸引场元件的侧视图,它吸引有变化结构的非均匀微囊层;Figure 11(b) is a side view of an attracting field element, which attracts a layer of heterogeneous microcapsules with varying structures;

图12(a)是吸引场元件实施例的侧视图,说明扫描激光用于写入信息到光磁涂层上;Figure 12(a) is a side view of an embodiment of an attracting field element illustrating a scanning laser for writing information onto a magneto-optical coating;

图12(b)是吸引场元件实施例,说明扫描电子枪用于写入信息到荧光涂层上;Figure 12(b) is an embodiment of an attracting field element, illustrating that a scanning electron gun is used to write information onto a fluorescent coating;

图12(c)是吸引场元件实施例的侧视图,它有LCD矩阵或二极管激光器矩阵,用于写入信息到光磁涂层上;Figure 12(c) is a side view of an embodiment of an attracting field element with an LCD matrix or a matrix of diode lasers for writing information onto a magneto-optical coating;

图12(d)是图12(c)所示吸引场元件的正视图;Figure 12(d) is a front view of the attracting field element shown in Figure 12(c);

图13是电流扫描仪用于扫描激光束到吸引场元件上的实施例;Figure 13 is an embodiment of a current scanner used to scan a laser beam onto an attracting field element;

图14是配置成转鼓的吸引场元件实施例;Figure 14 is an embodiment of an attractive field element configured as a rotating drum;

图15(a)是吸引场发生光源设置在空转鼓内部的实施例透视图;Figure 15(a) is a perspective view of an embodiment in which the light source for generating the attractive field is arranged inside the idle drum;

图15(b)是图15(a)所示实施例的侧视图,它展示微囊被吸引和影像曝光到转鼓上;Figure 15(b) is a side view of the embodiment shown in Figure 15(a), showing microcapsules being attracted and image-wise exposed onto the drum;

图16(a)是配置成LED或二极管激光器矩阵的光源图;Figure 16(a) is a diagram of a light source configured as a matrix of LED or diode lasers;

图16(b)是配置成液晶光阀的光源图;Figure 16(b) is a diagram of a light source configured as a liquid crystal light valve;

图16(c)是配置成阴极射线管的光源图;和Figure 16(c) is a diagram of a light source configured as a cathode ray tube; and

图16(d)是配置成光纤光缆末端的光源图。Figure 16(d) is a diagram of a light source configured at the end of a fiber optic cable.

具体实施方式 Detailed ways

为了便于理解本发明的原理,参照附图中所描述的实施例,并利用特定的语言给予描述。然而,应当明白,本发明的范围不受此限制,对于专业人员而言,应用此处所公开的本发明原理,对所描述的装置作各种变化和改动是可以可以设想的。To facilitate an understanding of the principles of the invention, reference has been made to the embodiments illustrated in the drawings, and specific language has been used for the description. It should be understood, however, that the scope of the invention is not so limited and that variations and modifications to the described apparatus may be envisioned by those skilled in the art applying the principles of the invention disclosed herein.

参照图1,图1表示本发明实施例的打印机10。本发明打印机10是用于制作电子电路,例如,薄型、明亮、轻质和柔性显示器,借助于电激活微囊层的堆积和固化。以下详细地讨论电激活微囊的成分。Referring to FIG. 1, FIG. 1 shows a printer 10 according to an embodiment of the present invention. The printer 10 of the present invention is used to fabricate electronic circuits, such as thin, bright, lightweight and flexible displays, by means of deposition and curing of electroactive microcapsule layers. The components of the electroactive microcapsules are discussed in detail below.

图1所示的本发明微囊打印机10包括:图像接收装置12,用于接收电激活微囊层的电子电路预制件。在微囊层固化或显影之后,电子电路预制件变成电子电路。图像接收装置12包含局部可变的吸引场平板14。电子电路预制件可以是完全的电子电路形式,包括诸如布线,显示像素,离散电子元件等的单元。例如,微囊有选择地可以包含导电,绝缘,半导体或电阻性内相。通过形成多个离散电路元件的电子电路,每个元件是由具有合适电气特性的微囊印制成,利用以下描述的打印方法可以构造一种电子电路,例如,薄型、轻质、柔性显示器。The microcapsule printer 10 of the present invention shown in FIG. 1 includes an image receiving device 12 for receiving an electronic circuit preform of an electroactive microcapsule layer. After the microcapsule layer is cured or developed, the electronic circuit pre-form becomes an electronic circuit. The image receiving device 12 includes a locally variable field of attraction plate 14 . An electronic circuit preform may be in the form of a complete electronic circuit, including elements such as wiring, display pixels, discrete electronic components, and the like. For example, microcapsules may optionally contain a conductive, insulating, semiconducting or resistive internal phase. By forming an electronic circuit of a plurality of discrete circuit elements, each of which is printed from microcapsules with suitable electrical properties, an electronic circuit, such as a thin, lightweight, flexible display, can be constructed using the printing methods described below.

图像接收装置12还包括:控制装置,用于控制局部可变的吸引场平板14,从而在局部可变吸引场平板14的对应离散位置有选择地改变各自局部吸引场。在图1所示的实施例中,控制装置包含输入装置16,例如,计算机,数字化仪,用于数字化从原型反射的电子电路或电子元件图像,或可以提供输入信号给处理器18的任何其他输入装置。处理器18处理从输入装置16输入的信号并产生与此有关的对应图像接收信号。这个图像接收信号被控制器20接收,通过有选择地改变局部可变吸引场平板14对应离散位置的各自局部吸引场,可以控制局部可变的吸引场平板14。The image receiving device 12 further comprises: a control device for controlling the locally variable attracting field plates 14 to selectively change respective local attracting fields at corresponding discrete positions of the locally variable attracting field plates 14 . In the embodiment shown in FIG. 1, the control means comprises an input means 16, such as a computer, a digitizer, for digitizing images of electronic circuits or electronic components reflected from a prototype, or any other device that can provide an input signal to a processor 18. input device. Processor 18 processes the input signal from input device 16 and generates a corresponding image reception signal thereon. The image receiving signal is received by the controller 20, and the locally variable attracting field plate 14 can be controlled by selectively changing the respective local attracting fields corresponding to the discrete positions of the locally variable attracting field plate 14.

在操作时,三维结构的场吸引微囊24可以构造在电子电路成型微囊层30上,为的是形成有峰和谷的三维结构,如以下详细描述的。因此,按照本发明,可以制成包含具体结构三维电子电路元件的三维电子电路元件。此外,可以构造包含通孔和连接各层布线的电路层。In operation, the three-dimensionally structured field-attracting microcapsules 24 may be constructed on the electronic circuit forming microcapsule layer 30 in order to form a three-dimensional structure with peaks and valleys, as described in detail below. Therefore, according to the present invention, a three-dimensional electronic circuit element including a specifically structured three-dimensional electronic circuit element can be produced. In addition, it is possible to construct circuit layers including vias and wiring connecting layers.

本发明的打印机10还包括:微囊供应装置22,用于提供被吸引的多个场吸引微囊24到局部可变吸引场平板14的离散位置,它与每个局部吸引场有关。因此,制成这样的场吸引微囊24层,其厚度与局部可变吸引场平板14上每个离散位置的对应吸引场强度有关。这种局部可控的微囊厚度能够有效地制作复杂的电子电路,其中电子元件有各种电气性质。如图1所示,微囊源26提供多个场吸引微囊24,如在这个实施例中所示,允许这些场吸引微囊级联在微囊源与收集器28之间。由于在局部可变吸引场平板14的离散位置存在吸引场,这些级联场吸引微囊24中的一些微囊被吸引到局部可变吸引场平板14上。按照本发明的打印机10,为了形成均匀的场吸引微囊24层,局部可变吸引场平板14在每个离散位置加均匀的对应吸引场。因此,可以形成均匀层30,利用它产生有精确控制的机械,电气和化学属性的基片。The printer 10 of the present invention also includes a microcapsule supply 22 for supplying attracted plurality of field-attracting microcapsules 24 to discrete locations on the locally variable field-of-attraction plate 14, which is associated with each local field-attracting field. Thus, a layer of field-attracting microcapsules 24 is made whose thickness is related to the corresponding attractive field strength at each discrete location on the locally variable attractive-field plate 14 . This locally controllable microcapsule thickness enables efficient fabrication of complex electronic circuits in which electronic components have various electrical properties. As shown in FIG. 1 , a microcapsule source 26 provides a plurality of field-attracting microcapsules 24 , allowing these field-attracting microcapsules to be cascaded between the microcapsule source and collector 28 as shown in this embodiment. Some of these cascaded field-attracting microcapsules 24 are attracted to the locally variable field-attracting field plate 14 due to the presence of attractive fields at discrete locations on the locally variable field-attracting field plate 14 . According to the printer 10 of the present invention, in order to form a uniform layer of field-attracting microcapsules 24, the locally variable field-of-attraction plate 14 applies a uniform corresponding field of attraction at each discrete location. Thus, a uniform layer 30 can be formed which yields a substrate with precisely controlled mechanical, electrical and chemical properties.

在图1所示的实施例中,收集器28包括:可控变化的吸引场源,它可以吸引至少一些场吸引微囊24,这些微囊不足以被吸引到局部可变的吸引场平板14作为电子电路成型微囊层30或形成三维结构。与使用的微囊类型有关,收集器28可以提供磁吸引场或静电吸引场。此外,如图1中实线框所示,屏幕32至少包含微囊源26,微囊收集器28和二者之间的空间。这个屏幕32可以减小级联场吸引微囊24的过量损耗。应当注意,这个屏幕32可以包含提供排斥力的装置,促使场吸引微囊24到达局部可变吸引场平板14或收集器28,并可以包含分离涂层,例如,Teflon等,防止场吸引微囊24粘贴到屏幕32。与常规的静电吸引微囊或打印机墨粉比较,按照本发明利用磁吸引微囊,由于纸片尘埃或粉末的污染对收集器中收集的微囊重复使用影响较小,因为纸片尘埃和粉末不会被磁性吸引到磁吸引场平板14上。In the embodiment shown in FIG. 1 , the collector 28 includes a source of a controllably variable attractive field capable of attracting at least some of the field-attracting microcapsules 24 that are insufficiently attracted to the locally variable attractive field plate 14 The microcapsule layer 30 is molded as an electronic circuit or formed into a three-dimensional structure. Depending on the type of microcapsule used, collector 28 can provide a magnetic or electrostatic attraction field. In addition, as shown by the solid line box in FIG. 1, the screen 32 includes at least the microcapsule source 26, the microcapsule collector 28 and the space between them. This screen 32 can reduce excess wear of the cascaded field-attracting microcapsules 24 . It should be noted that this screen 32 may contain means to provide a repulsive force, urging the field-attracting microcapsules 24 to reach the locally variable field-attracting field plate 14 or collector 28, and may contain a separation coating, e.g., Teflon, etc., to prevent the field-attracting microcapsules 24 Paste to screen 32. Compared with conventional electrostatically attracted microcapsules or printer toner, utilizing magnetically attracted microcapsules according to the present invention, the pollution of paper dust or powder has less influence on the reuse of microcapsules collected in the collector, because paper dust and powder Will not be magnetically attracted to the flat plate 14 of the magnetic attraction field.

本发明打印机还包括:成像装置34,在需要形成电子电路潜像36时,用于影像曝光电激活微囊层。例如,可以利用光固化微囊成分以制成精确的电子元件。局部吸引场可以吸引所需微囊块到特定位置。微囊的光固化成分能使微囊块精确地固化以得到制造电子电路元件的所需电气特性。在图1所示的实施例中,成像装置34包含辐射源38,提供载像辐射40,可以影像曝光电激活微囊层。这个载像辐射40最好包含不同的电磁辐射波长,根据对应电子电路元件成型的微囊混合,每种波长可以有选择地形成特定的电子电路元件。利用这种成影像曝光,通过有选择地释放和混合有不同电气性质的电激活材料,可以制成电子电路。利用包含电阻性材料的微囊,例如,碳,可以制成电阻器的阻抗部分,而利用包含导电性材料的微囊,例如,导电聚合物或金属,可以制成电阻器的导电部分(引线)。The printer of the present invention also includes: an imaging device 34 for image exposure of the electroactive microcapsule layer when the latent image 36 of the electronic circuit needs to be formed. For example, light can be used to cure microcapsule components to make precise electronic components. A local attraction field can attract the desired mass of microcapsules to a specific location. The photocurable composition of the microcapsules enables precise curing of the mass of microcapsules to obtain the desired electrical properties for the fabrication of electronic circuit components. In the embodiment shown in FIG. 1, the imaging device 34 includes a radiation source 38 that provides image-bearing radiation 40 to imagewise expose the electroactive microcapsule layer. This image-bearing radiation 40 preferably contains different wavelengths of electromagnetic radiation, each of which can be selectively formed into a particular electronic circuit component, depending on the mix of microcapsules shaped corresponding to the electronic circuit component. Using this image-wise exposure, electronic circuits can be fabricated by selectively releasing and mixing electroactive materials having different electrical properties. The resistive portion of the resistor can be made using microcapsules containing a resistive material, such as carbon, while the conductive portion (leads) of the resistor can be made using microcapsules containing a conductive material, such as a conductive polymer or metal. ).

在图1所示的实施例中,成像装置34包括:电子电路成型控制装置(它可以利用一个或多个相同的元件作为控制装置)。提供输入装置16′,例如,计算机,或任何其他的装置,它可以产生对应于电子电路的输入信号。输入信号被处理器18′接收,例如,计算机微处理器,可以确定相关的电子电路成型信号。这些电子电路成型信号被控制器20′接收,可以控制辐射源,从而有选择地影像曝光电激活微囊层,并在其中产生电子电路潜像36。辐射源38可以是CRT,LCD,LED,激光器,或其他的电子电路辐射源,还包括反射型辐射源,其中光从原型反射并被聚焦,为的是影像曝光电激活微囊层。此外,光纤面板CRT可用于影像曝光电激活微囊层。光纤面板是有利的,因为在曝光微囊时,可以清晰地聚焦电子电路。发给Yamada的US PatentNo.4,978,978公开一种光纤面板的例子。In the embodiment shown in FIG. 1, the imaging device 34 includes an electronic circuit forming control (which may utilize one or more of the same components as the control). An input device 16' is provided, such as a computer, or any other device, which can generate an input signal corresponding to an electronic circuit. The input signal is received by a processor 18', such as a computer microprocessor, which can determine an associated electronic circuit forming signal. These electronic circuit forming signals are received by the controller 20' which controls the radiation source to selectively image-expose the electroactive microcapsule layer and produce a latent electronic circuit image 36 therein. Radiation source 38 can be a CRT, LCD, LED, laser, or other electronic circuit radiation source, and also includes reflective radiation sources where light is reflected from the prototype and focused for imagewise exposure of the electroactive microcapsule layer. In addition, fiber-optic faceplate CRTs can be used to image-expose electroactive microcapsule layers. Fiber optic faceplates are advantageous because the electronic circuitry can be sharply focused when exposing the microcapsules. US Patent No. 4,978,978 to Yamada discloses an example of a fiber optic panel.

本发明微囊打印机10还包括:图像显影装置42,用于显影电子电路潜像36以制成功能电子电路44。在本发明的实施例中,图像显影装置42包含热源46。这个热源46可以热破裂电激活微囊成型电子电路潜像36,因此,可以释放微囊中的电激活材料,并显影成功能电子电路。或者,图像显影装置42可以包含压力辊46′,通过破坏性压力使电激活微囊破裂。如以下要详细讨论的,本发明打印机10可用于制成有三维结构的电子电路,在这种情况下,最好是利用热源使微囊破裂以制成功能电子电路。我们设想,显影剂可以存在于微囊形式的记录薄片上。或者,可以利用喷射,浸渍等方法加显影剂,或利用与现有技术一致的其他方法加显影剂。The microcapsule printer 10 of the present invention further includes: an image developing device 42 for developing the electronic circuit latent image 36 to form a functional electronic circuit 44 . In an embodiment of the invention, image developing device 42 includes heat source 46 . This heat source 46 can thermally rupture the latent image 36 of the electroactive microcapsule formed electronic circuit, thereby releasing the electroactive material in the microcapsule and developing a functional electronic circuit. Alternatively, the image developing device 42 may include a pressure roller 46' to rupture the electroactive microcapsules by destructive pressure. As discussed in detail below, the printer 10 of the present invention can be used to form electronic circuits having three-dimensional structures, in which case it is preferable to rupture the microcapsules using a heat source to form a functional electronic circuit. It is envisioned that the imaging agent could be present on the recording sheet in the form of microcapsules. Alternatively, the developer can be added by means of spraying, dipping, etc., or by other methods consistent with the prior art.

在图1所示的本发明打印机实施例中,提供记录薄片供应装置48,可以给图像接收装置12供应记录薄片48′。记录薄片48′用于支承电激活微囊层和局部吸引场微囊24层。因此,可以是纸片,合成纸片,塑料或其他合适介质的记录薄片48′首先放置在局部可变吸引场平板14的工作面50上。然后,控制装置控制局部可变吸引场平板14。控制装置包括改变装置,当场吸引微囊从微囊源26喷流时,可以有选择地改变局部吸引场平板的对应离散位置上各自局部吸引场。因此,可以制成电子电路成型微囊层30。In the embodiment of the printer of the present invention shown in FIG. 1, a recording sheet supply means 48 is provided which can supply the image receiving means 12 with a recording sheet 48'. The recording sheet 48' is used to support the electroactive microcapsule layer and the local attraction field microcapsule 24 layer. Thus, a recording sheet 48 ′, which may be a sheet of paper, synthetic paper, plastic or other suitable medium, is first placed on the working surface 50 of the locally variable field of attraction plate 14 . Then, the control device controls the local variable attraction field plate 14 . The control means includes varying means for selectively varying the respective local attraction fields at corresponding discrete locations on the local attraction field plate as the field attraction microcapsules are jetted from the microcapsule source 26 . Therefore, the electronic circuit molding microcapsule layer 30 can be produced.

或者,在记录薄片48′放置在与局部可变吸引场平板14邻近之前,在记录薄片48′上可以提供电子电路成型微囊层30。然后,通过改变局部可变吸引场平板14的离散位置上吸引场,可以在电子电路成型微囊层30的选取位置上提供附加的场吸引微囊24层。例如,电子电路成型微囊层可以包含显影的微囊层。在该层上可以形成均匀(二维)或非均匀(三维)的电激活微囊层,然后影像曝光以形成电子电路潜像。利用加压力,加热等方法,释放微囊封装的显影剂和微囊封装的电激活材料并把它们混合在一起,从电子电路潜像得到显影的功能电子电路。Alternatively, the electronic circuit forming microcapsule layer 30 may be provided on the recording sheet 48' before the recording sheet 48' is placed adjacent to the locally variable field of attraction plate 14. Additional layers of field-attracting microcapsules 24 can then be provided at selected locations of the electronic circuit-forming microcapsule layer 30 by varying the attractive field at discrete locations of the locally variable field-attracting field plate 14 . For example, the electronic circuit forming microcapsule layer may comprise a developed microcapsule layer. A uniform (two-dimensional) or non-uniform (three-dimensional) layer of electro-active microcapsules can be formed on this layer and then imagewise exposed to form a latent image of the electronic circuit. Using pressure, heating and other methods to release the microencapsulated developer and the microencapsulated electroactive material and mix them together to obtain a developed functional electronic circuit from the latent image of the electronic circuit.

或者,通过加均匀的吸引场,例如,均匀的静电场,可以提供电子电路成型微囊层30到与局部可变吸引场平板14邻近的静电吸引装置70的表面上,然后,通过改变局部吸引场,附加的微囊可以分布到离散的位置。例如,通过静电吸引力,可以提供均匀的电子电路成型微囊层30,而通过局部可变吸引场平板14选取离散位置上的磁吸引力,可以提供附加的场吸引微囊层24,其厚度随不同的位置而变化。Or, by adding a uniform attraction field, for example, a uniform electrostatic field, the electronic circuit forming microcapsule layer 30 can be provided on the surface of the electrostatic attraction device 70 adjacent to the local variable attraction field plate 14, and then, by changing the local attraction field, additional microcapsules can be distributed to discrete locations. For example, a uniform electronic circuit molding microcapsule layer 30 can be provided by electrostatic attraction, and an additional field-attracting microcapsule layer 24, whose thickness Varies with different locations.

本发明打印机10还包括:附加的打印装置52,例如,另一个打印机,它可以在局部可变吸引场平板14设置在记录薄片48′之前或之后提供,利用图像接收装置12和成像装置14形成与这些电子电路附加的电子电路。例如,这另一个打印机可以是激光打印机,另一个微囊型打印机,击打式打印机,感热式打印机,喷墨打印机,或任何其他合适的打印机。因此,在单个记录薄片48′上可以提供各种类型印制电子电路的组合。例如,我们设想,利用喷墨打印机可以在记录薄片48′上印制轻质、明亮、柔性显示器的基片和OLED部分,以及其他的电路器件,例如,利用此处描述的图像接收装置12和成像装置14,包含电极的电池部分,两个电极之间有电解质,可以印制在相同的记录薄片48′上。The printer 10 of the present invention also includes an additional printing device 52, e.g., another printer, which may be provided before or after the locally variable field of attraction plate 14 is disposed on the recording sheet 48', formed using the image receiving device 12 and the imaging device 14. Electronic circuits attached to these electronic circuits. For example, the other printer may be a laser printer, another capsule printer, an impact printer, a thermal printer, an inkjet printer, or any other suitable printer. Thus, combinations of various types of printed electronic circuits can be provided on a single recording sheet 48'. For example, it is contemplated that substrates and OLED portions of lightweight, bright, flexible displays, as well as other circuit components, may be printed on recording sheet 48' using an inkjet printer, for example, using the image receiving device 12 and The imaging device 14, the battery portion comprising the electrodes with the electrolyte between them, can be printed on the same recording sheet 48'.

现在参照图2(a)和2(b),它表示另一个实施例的微囊供应装置22。在这个实施例中,微囊供应装置22包括:微囊包含装置80,在与局部可变吸引场平板14相邻的位置包含多个场吸引微囊24,因此,多个场吸引微囊24中至少一些微囊被吸引到局部可变吸引场平板14的离散位置,为的是形成场吸引微囊24层。场吸引微囊24可以是没有分布在分散液82中的干式,或分布在分散液82中的湿式。此外,液压泵(未画出)可以搅拌分散液82,使其中分散的微囊保持均匀的统计分布。Referring now to Figures 2(a) and 2(b), another embodiment of the microcapsule supply device 22 is shown. In this embodiment, the microcapsule supply means 22 includes: a microcapsule containing means 80 which contains a plurality of field-attracting microcapsules 24 adjacent to the locally variable field of attraction plate 14, whereby the plurality of field-attracting microcapsules 24 At least some of the microcapsules are attracted to discrete locations on the locally variable field of attraction plate 14 in order to form a layer of field-attracting microcapsules 24. The field-attracting microcapsules 24 may be of a dry type not distributed in the dispersion liquid 82 , or of a wet type distributed in the dispersion liquid 82 . Additionally, a hydraulic pump (not shown) can agitate the dispersion 82 to maintain a uniform statistical distribution of microcapsules dispersed therein.

如图2(b)所示,在加均匀的吸引场(例如,均匀的磁场或均匀的静电场)之后,电子电路成型微囊层30制成在局部可变吸引场平板14的工作面50上。在加非均匀的吸引场之后,制成局部吸引的吸引场微囊24的微囊层(它可以包含形成电子电路的电激活微囊)。As shown in Figure 2 (b), after adding a uniform attraction field (for example, a uniform magnetic field or a uniform electrostatic field), the electronic circuit molding microcapsule layer 30 is made on the working surface 50 of the local variable attraction field plate 14 superior. After applying the non-uniform attracting field, a microcapsule layer of locally attracting attracting field microcapsules 24 (which may contain electrically active microcapsules forming electronic circuits) is formed.

参照图3(a)至图3(c),它表示一种制成三维结构电子线路方法的示意图。应当注意,按照本发明,可以利用实现所需结果的各种其他方法,以下描述其中的一些方法。然而,还应当注意,如这些附图中所示和以下的描述,利用本发明得到所需电子电路的方法说明本发明范围内各种元件可能的组合。Referring to Fig. 3(a) to Fig. 3(c), it shows a schematic diagram of a method for making a three-dimensional structure electronic circuit. It should be noted that various other methods of achieving the desired results can be utilized in accordance with the present invention, some of which are described below. However, it should also be noted that, as shown in these figures and described below, the method by which the invention is used to obtain the desired electronic circuit illustrates the possible combinations of various elements within the scope of the invention.

图3(a)表示局部可变吸引场平板14的侧视图,在其上面制成平坦的微囊层30。这个平坦的微囊层可以制成在记录片48′上(如图1所示),或可以直接制成在局部可变吸引场平板14的工作面50上,并作为制成电子电路基片。在这种情况下,在固化之后,若选取合适的微囊成分,则可以制成固化和显影微囊的自支承结构,它可以转移到支承片上或依靠自身支承。通过加均匀的静电场或均匀的磁场以吸引微囊,可以制成这种平坦的微囊层30,也可能不需要加电场或磁场,它与应用有关。Figure 3(a) shows a side view of a locally variable attractive field plate 14 on which a flat microcapsule layer 30 is formed. This flat microcapsule layer can be formed on the recording sheet 48' (as shown in FIG. 1), or can be directly formed on the working surface 50 of the locally variable attractive field plate 14, and used as an electronic circuit substrate. In this case, after curing, if the microcapsule composition is chosen appropriately, a self-supporting structure of the cured and developed microcapsules can be made which can be transferred to a support sheet or supported on its own. This flat microcapsule layer 30 can be made by applying a uniform electrostatic field or a uniform magnetic field to attract the microcapsules, or it may not need to apply an electric field or a magnetic field, which is related to the application.

如图3(b)所示,三维结构电子电路成型微囊的堆积包含峰和谷,它可以制成引线,天线,RF接收元件,RF发射元件,光反应和激活电路元件,电阻器,电容器,电感器,和诸如晶体管的半导体器件。图3(b)还表示辐照源38,它利用载像辐射40辐照三维结构的电子电路成型微囊,按照载像辐射的成影像曝光有选择地曝光微囊。图3(c)表示在显影和固化之后的三维结构电子电路成型微囊。制成的电子电路可以包含电容器,电阻器,布线,线圈,多层电池,和按照本发明利用微囊材料制成的任何其他电路元件。As shown in Figure 3(b), the accumulation of three-dimensional structure electronic circuit molding microcapsules contains peaks and valleys, which can be made into leads, antennas, RF receiving elements, RF emitting elements, photoresponsive and active circuit elements, resistors, capacitors , inductors, and semiconductor devices such as transistors. Figure 3(b) also shows an irradiation source 38 for irradiating the three-dimensionally structured electronic circuit-forming microcapsules with image-bearing radiation 40 to selectively expose the microcapsules according to the image-wise exposure of the image-bearing radiation. Figure 3(c) shows the three-dimensional structured electronic circuit forming microcapsules after development and curing. The resulting electronic circuits may contain capacitors, resistors, wiring, coils, multilayer batteries, and any other circuit elements made using microencapsulated materials in accordance with the present invention.

参照图4(a)至图4(d),它表示本发明利用的各种微囊成分。应当注意,这些具体的成分仅仅是说明性的,并不限制可能的微囊成分。按照本发明的实施例,提供几种类型的微囊,它包含可用于制成电子电路元件的成分。与微囊内相或壳层的成分有关,它们是静电场吸引和/或磁场吸引微囊。因此,这些微囊可以用于本发明打印机,利用本发明打印方法制作电子电路。Referring to Figure 4(a) to Figure 4(d), it shows various microcapsule components utilized in the present invention. It should be noted that these specific components are illustrative only and do not limit the possible microcapsule components. According to embodiments of the present invention, several types of microcapsules are provided which contain components useful for making electronic circuit components. Depending on the composition of the microcapsule inner phase or shell, they are electrostatically and/or magnetically attracted to the microcapsules. Therefore, these microcapsules can be used in the printers of the invention to make electronic circuits using the printing method of the invention.

例如,微囊的内相可以包含诸如金属或导电聚合物的导电材料,诸如碳的电阻性材料,诸如非导电聚合物的绝缘材料,和/或半导体材料。微囊可以包含仅有一种电气性质的材料,或可以包含材料的混合物或有组合电气性质的一种材料。此外,微囊壳层本身的电气或机械特性还可以对最终制成的电子电路起作用。例如,微囊壳层可以包含坚硬或可硬化物质,它对按照本发明制成印制物品的所需支承强度起作用。与电子器件中喷墨打印所用的电激活微囊比较,本发明的微囊和打印方法及设备可以更有效地产生功能电子电路。按照本发明,如此处详细描述的,按照所需三维形状有选择地吸引场吸引微囊,可以快速地制成多种电子元件。在制作电子元件的喷墨打印方法中,完成墨粉的相继传输和喷射,缓慢地堆积所需厚度的电反应材料。这个过程与本发明方法比较是缓慢的,其中局部吸引场强度在所需位置的增大可以导致相对大量微囊被吸引以堆积所需的三维结构,因此,利用本发明打印方法制成工作电子电路的功能元件。For example, the internal phase of the microcapsules may comprise conductive materials such as metals or conductive polymers, resistive materials such as carbon, insulating materials such as non-conductive polymers, and/or semiconducting materials. Microcapsules may contain a material of only one electrical property, or may contain a mixture of materials or one material with combined electrical properties. In addition, the electrical or mechanical properties of the microcapsule shell itself can also contribute to the final electronic circuit. For example, the microcapsule shell may comprise a hard or hardenable substance which contributes to the desired support strength of printed articles made according to the invention. The microcapsules and printing methods and apparatus of the present invention can produce functional electronic circuits more efficiently than electroactive microcapsules used for inkjet printing in electronic devices. According to the present invention, a variety of electronic components can be rapidly fabricated by selectively attracting field-attracting microcapsules according to a desired three-dimensional shape, as described in detail herein. In the inkjet printing method for making electronic components, the sequential delivery and ejection of toner powder is done to slowly build up the electro-reactive material to a desired thickness. This process is slow compared to the method of the present invention, where an increase in the strength of the local attractive field at the desired location can result in a relatively large number of microcapsules being attracted to pack the desired three-dimensional structure, therefore, the printing method of the present invention is used to make working electronic A functional element of a circuit.

这种微囊的成分可以包含静电吸引的材料,因此,可以利用本发明打印机实施例的静电吸引元件。微囊的壳层可以是热可熔物质,在固化功能电子电路之后,它至少形成半刚性的强力整体结构。The composition of such microcapsules may contain electrostatically attractive materials, and thus, the electrostatically attractive elements of printer embodiments of the present invention may be utilized. The shell of the microcapsule may be a heat-fusible substance which, after curing the functional electronic circuit, forms at least a semi-rigid strong monolithic structure.

在图4(b)中,它表示形成电池或电容器的微囊成分。电池通常包括阳极部分和阴极部分以及夹在两个电极之间的电解质。按照本发明,利用本发明场吸引微囊打印方法,可以制造电能储存装置。在这种情况下,微囊可以包含微囊壁和内相。微囊壁可以有包含金属成分M的成分,或内相可以有包含金属成分M的成分(或微囊壁和内相都可以有包含金属的成分,例如,镍,锂,铅等)。聚合物壳层(它可以是导电聚合物)中封装的电解质是用微囊E表示。微囊封装电解质作为场吸引微囊中的内相,利用本发明打印方法可以容易地制成有所需厚度的电解质层。In Fig. 4(b), it represents the microcapsule components forming a battery or capacitor. Batteries generally include an anode portion and a cathode portion with an electrolyte sandwiched between the two electrodes. According to the present invention, the electric energy storage device can be manufactured by using the field-attracted microcapsule printing method of the present invention. In this case, the microcapsule can comprise a microcapsule wall and an internal phase. The microcapsule wall can have a composition comprising the metal component M, or the internal phase can have a composition comprising the metal component M (or both the microcapsule wall and the internal phase can have a metal-containing composition, e.g., nickel, lithium, lead, etc.). The electrolyte encapsulated in the polymer shell (which may be a conducting polymer) is represented by microcapsule E. The electrolyte encapsulated in the microcapsule is used as the internal phase in the field-attracted microcapsule, and the electrolyte layer with the required thickness can be easily produced by using the printing method of the present invention.

按照本发明,薄型、轻质、明亮显示器包含柔性电池,所需电容器,电阻器,天线,电感器,绕组,线圈,引线,全色OLED基显示元件,以及所有其他的元件,它们都可以利用本发明场吸引微囊打印方法制成。In accordance with the present invention, a thin, lightweight, bright display containing flexible batteries, required capacitors, resistors, antennas, inductors, windings, coils, leads, full-color OLED-based display elements, and all other components can utilize The field suction microcapsule printing method of the present invention is made.

例如,提供柔性基片作为耐用的绝缘和保护基底,在该基片上制成各种电池层,输入层,显示层和电子电路层。例如,柔性基片可以是包括尼龙,聚乙烯,或其他合适材料的塑料片。柔性电池制成在柔性基片上。柔性基片的大表面积允许制成有合适储能容量和很薄的电池。通过制作组成功能电池元件的微囊电激活材料层,可以制成本发明的电池。通过制作第一阴极微囊层制成阴极部分。微囊封装的阴极材料(在图4(b)中用微囊M表示)可以由聚合物壳层内包含的高纯度二氧化锰(MnO2)内相M构成。利用本发明打印方法印制电极片,可以制成第一电池引线。第一电池引线(电极片)制成在第一阴极微囊层上,而第二阴极微囊层制成在这个电池引线的顶部。通过制作第一阳极微囊层,可以制成阳极部分。微囊封装的阳极材料可以是聚合物壳层内包含的含锂材料内相。第二电池引线(同样,利用导电微囊封装材料和本发明打印方法制成片电极)制作在第一阳极微囊层邻近。第二阳极微囊层制作在这个电池引线的顶部。阳极部分与阴极部分之间是电解质层。电解质层可以是聚合母体中的高导电性电解质。在场吸引微囊壳层内微囊封装液态电解质内相,可以制成电解质层。For example, flexible substrates are provided as durable insulating and protective bases upon which various battery layers, input layers, display layers and electronic circuit layers are fabricated. For example, the flexible substrate can be a plastic sheet comprising nylon, polyethylene, or other suitable material. Flexible batteries are fabricated on flexible substrates. The large surface area of the flexible substrate allows the fabrication of batteries with suitable energy storage capacity and thinness. The batteries of the present invention can be made by making layers of microencapsulated electroactive materials that make up the functional battery components. The cathode portion is made by making a first cathode microcapsule layer. The microencapsulated cathode material (represented by microcapsule M in Figure 4(b)) may consist of an internal phase M of high purity manganese dioxide ( MnO2 ) contained within a polymer shell. Using the printing method of the present invention to print the electrode sheet can make the first battery lead. A first battery lead (electrode sheet) is made on the first cathode microcapsule layer and a second cathode microcapsule layer is made on top of this battery lead. By making the first anode microcapsule layer, the anode portion can be made. The microencapsulated anode material may be an internal phase of a lithium-containing material contained within a polymer shell. The second battery lead (similarly, using the conductive microcapsule packaging material and the printing method of the present invention to make a sheet electrode) is made adjacent to the first anode microcapsule layer. A second anode microcapsule layer was fabricated on top of this cell lead. Between the anode part and the cathode part is an electrolyte layer. The electrolyte layer may be a highly conductive electrolyte in a polymeric matrix. The liquid electrolyte inner phase is encapsulated by the microcapsules in the shell layer of the field-attracted microcapsules, and the electrolyte layer can be made.

如图4(c)所示,其他的场吸引微囊配方可用于产生其他的电子电路元件。例如,本发明磁网格可以包含印制绕组内放置的铁芯(事实上,绕组可以制成围绕铁芯的三维螺旋线)。利用本发明打印方法,含铁质材料的微囊F可用于制成铁芯。此外,利用本发明打印机和打印方法,微囊封装和印制非铁材料(微囊nF),例如,铝,可以制作非磁性反应或准磁性反应的电子元件。As shown in Figure 4(c), other field-attracting microcapsule formulations can be used to create other electronic circuit components. For example, the magnetic grid of the present invention may comprise an iron core placed within a printed winding (in fact, the winding may be formed as a three-dimensional helix around the iron core). Using the printing method of the present invention, the microcapsules F containing iron materials can be used to make iron cores. In addition, by using the printer and printing method of the present invention, non-ferrous materials (microcapsule nF), such as aluminum, can be encapsulated and printed in microcapsules, and electronic components with non-magnetic or quasi-magnetic responses can be produced.

图4(d)表示热可熔微囊84,其中有不同波长的红外线可以成影像辐射使微囊曝光,利用加热代替压力有选择地固化和破裂微囊。在US Patent No.4,916,042中公开这种微囊成分。此外,应当注意,本发明设想可以热熔化其他的微囊成分使它破裂。例如,微囊壁可以由这样的材料组成,它在特定温度下加热可以均匀地熔化。因此,显影装置42可以包含提供这种温度的热源46,它使微囊破裂并按照电子电路潜像产生功能电子电路而不需要加压力。显影剂(它可以作为催化剂,从微囊封装的母体材料中形成某些电子电路材料)可以包含在微囊形式中并随电激活微囊一起破裂。此外,可以提供诸如激光器的光源,用于加特定波长的电磁辐射,它可以被热可熔微囊84吸收而产生热量。Figure 4(d) shows heat fusible microcapsules 84 in which image-forming radiation of different wavelengths of infrared light can expose the microcapsules to selectively solidify and rupture the microcapsules using heat instead of pressure. Such microencapsulated compositions are disclosed in US Patent No. 4,916,042. In addition, it should be noted that the present invention contemplates that other microcapsule components can be thermally melted to rupture it. For example, the microcapsule wall can be composed of a material that melts uniformly when heated at a specific temperature. Thus, the development device 42 may contain a heat source 46 that provides the temperature that ruptures the microcapsules and produces a functional electronic circuit in accordance with the latent image of the electronic circuit without the need for applied pressure. A developer (which can act as a catalyst to form certain electronic circuit materials from a microencapsulated matrix material) can be contained in the microencapsulated form and rupture with the electroactive microcapsules. Additionally, a light source, such as a laser, may be provided for applying electromagnetic radiation of a specific wavelength, which may be absorbed by the heat-fusible microcapsules 84 to generate heat.

现在参照图5(a)至图5(c),它表示部分的局部可变吸引场平板14,其中每个磁可变像素包含每个分别可控电磁源62铁芯64的上表面。应当指出,这个结构仅仅用于说明,它也可以是静电可变像素和分别可控的静电源(在这种情况下,结构中不包含铁芯,但提供多个分别可控的吸引场源)。如图5(a)至图5(c)所示,局部可变吸引场平板14有包含多个分别可控吸引场源的工作面50,每个吸引场源与工作面50的对应离散位置相联系。在图5(a)至图5(c)所示的实施例中,分别可控电磁源62的铁芯顶部作为磁可变像素。Referring now to FIGS. 5( a ) to 5 ( c ), there is shown a portion of the locally variable field of attraction plate 14 in which each magnetically variable pixel comprises the upper surface of each individually controllable electromagnetic source 62 core 64 . It should be noted that this structure is for illustration only, it could also be electrostatically variable pixels and individually controllable electrostatic sources (in this case the structure does not contain an iron core but provides multiple individually controllable sources of attractive fields ). As shown in Fig. 5 (a) to Fig. 5 (c), the locally variable attraction field plate 14 has a working surface 50 comprising a plurality of respectively controllable attraction field sources, and each attraction field source corresponds to a discrete position of the work surface 50 related. In the embodiments shown in FIG. 5( a ) to FIG. 5( c ), the iron core tops of the respectively controllable electromagnetic sources 62 are used as magnetically variable pixels.

这些磁可变像素是等间隔的,以及分别可控的电磁源62可以封闭在磁绝缘材料内,因此,每个磁像素的影响局限于磁末端效应对其相邻磁像素的影响。从图5(b)中可以更清楚地看出,一些磁可变像素有均匀或没有磁场86。其他的磁可变像素有相对弱的附加磁场88,而另一些磁可变像素有相对强的附加磁场90。应当注意,可以控制每个磁像素使它有任意大小的磁场强度,当一个极性的最大电流加到分别可控的电磁源62时,它有最大的正磁场;当没有电流加到分别可控的电磁源62时,它有零磁场;而当相反极性的最大电流加到分别可控的电磁源62时,它有最大的负磁场。在普通的术语中,磁场可以描述成北极或南极。These magnetically variable pixels are equally spaced, and the individually controllable electromagnetic sources 62 can be enclosed in magnetically insulating material, so that the effect of each magnetic pixel is limited to the effect of magnetic end effects on its adjacent magnetic pixels. As can be seen more clearly in FIG. 5( b ), some magnetically variable pixels have either a uniform or no magnetic field 86 . Other magnetically variable pixels have a relatively weak additional magnetic field 88 , while other magnetically variable pixels have a relatively strong additional magnetic field 90 . It should be noted that each magnetic pixel can be controlled so that it has a magnetic field strength of any size. When the maximum current of a polarity is added to the respectively controllable electromagnetic source 62, it has the maximum positive magnetic field; When the electromagnetic source 62 is controllable, it has a zero magnetic field; and when the maximum current of the opposite polarity is applied to the respectively controllable electromagnetic source 62, it has a maximum negative magnetic field. In common terms, a magnetic field can be described as either a north pole or a south pole.

如图5(c)所示,当均匀磁场加到磁可变像素时,制成均匀电子电路成型微囊层30。或者,如参照其他附图所讨论的,这个均匀电子电路成型微囊层30可以通过静电吸引力产生。有相对弱附加磁场88的像素形成三维结构微囊的堆积,它们被吸引到相对弱的磁场。这种三维微囊堆积能有效地制成各种电子电路元件。制成电子电路元件的电气性质取决于被吸引微囊的成分和三维结构。有相对强附加磁场90的像素有三维结构微囊的堆积,它们被吸引到相对强的磁场。按照本发明,微囊堆积的数目以及微囊堆积形成三维结构的最终尺寸取决于通过每个磁可变像素所加的磁场强度。此外,利用静电可变像素可以提供相同的结构,或按照熟知的方式,利用激光打印机在转鼓或平板的表面上建立静电吸引力变化。按照本发明,激光打印机通过提供墨粉成分可用于印制电子电路元件,其中墨粉成分包含合适的电激活成分。在这种情况下,可以选取多个墨粉源并被吸引到静电吸引平板或转鼓,其中每个墨粉源有合适的墨粉成分以形成所需的电子电路元件。As shown in FIG. 5(c), when a uniform magnetic field is applied to the magnetically variable pixel, a uniform electronic circuit-forming microcapsule layer 30 is formed. Alternatively, this uniform electronic circuit forming microcapsule layer 30 can be created by electrostatic attraction, as discussed with reference to the other figures. Pixels with a relatively weak additional magnetic field 88 form an accumulation of three-dimensional structured microcapsules that are attracted to the relatively weak magnetic field. This three-dimensional microcapsule accumulation can be effectively fabricated into various electronic circuit components. The electrical properties of fabricated electronic circuit components depend on the composition and three-dimensional structure of the attracted microcapsules. Pixels with a relatively strong additional magnetic field 90 have accumulations of three-dimensional structured microcapsules that are attracted to the relatively strong magnetic field. According to the present invention, the number of microcapsule stacks and the final size of the three-dimensional structure formed by microcapsule stacking depend on the strength of the magnetic field applied through each magnetically variable pixel. Alternatively, the same structure can be provided using electrostatically variable pixels, or in a well-known manner, using a laser printer to create electrostatic attraction variations on the surface of a drum or plate. According to the present invention, laser printers can be used to print electronic circuit components by providing a toner composition which contains suitable electroactive components. In this case, multiple toner sources can be taken and attracted to an electrostatic attraction plate or drum, where each toner source has the appropriate toner composition to form the desired electronic circuit elements.

参照图6(a)和6(b),它表示按照本发明制作有三维结构电子电路元件的方法。微囊138的结构堆积到局部可变的吸引场平板14上以形成这样的结构,例如,三维结构微囊140被吸引到有相对弱附加磁场的分别可变像素,和三维结构微囊142被吸引到有相对强附加磁场的分别可变像素。在这个实施例中,微囊是热膨胀的并可以通过加热发生热膨胀。微囊的热膨胀可以导致固化,和减小制作电子器件内所含微囊封装电反应材料的密度。这种控制器件密度的方法有利于形成各种电路元件,例如,有所需电气特性的电阻器,电容器等。Referring to Figures 6(a) and 6(b), it shows a method of fabricating an electronic circuit element with a three-dimensional structure according to the present invention. The structure of the microcapsules 138 is stacked onto the locally variable attraction field plate 14 to form such a structure, for example, the three-dimensional structure microcapsules 140 are attracted to the respective variable pixels with a relatively weak additional magnetic field, and the three-dimensional structure microcapsules 142 are attracted to attracted to individually variable pixels with relatively strong additional magnetic fields. In this embodiment, the microcapsules are thermally expandable and can be thermally expanded by heating. Thermal expansion of the microcapsules can result in solidification and a reduction in the density of the microencapsulated electrically reactive material contained within the fabricated electronic device. This method of controlling device density facilitates the formation of various circuit elements, such as resistors, capacitors, etc., with desired electrical characteristics.

图7表示本发明的薄型、轻质、柔性、明亮、无线显示器的示意图,它可以同时显示三个接收的显示信号。本发明的薄型、轻质、柔性、明亮、无线显示器包含提供支承结构的柔性基片,利用打印方法可以在该基片上制造元件。如在共有人同时申请的US PatentApplication中所描述的,其标题为“A Thin,Lightweight,Flexible,Bright,Wireless Display”,发射显示信息到单个或多个显示器的唯一和有效方法能使这种显示器不必有很大的机载存储容量和处理能力,全文合并在此供参考。按照本发明的这个特征,可以避免与这种装置通常有关的能量消耗,体积,重量和成本,并可增大显示器的耐用性和方便性。此外,如图7所示,可以同时接收和显示多个显示信息流。例如,在显示器的第一部分可以显示诸如电视节目的广播视频内容,在第二部分可以显示诸如可视电话交谈的个人化视频内容,和在第三部分可以显示包含映射超链接内容的网页。大部分的处理操作,联网,信号调谐,数据存储等建立这组显示内容流不是由本发明无线显示器完成的。诸如集中式计算机,A/V或网关装置的其他装置可以完成这些功能,因此,本发明显示器有巨大的移动性和方便性。Figure 7 shows a schematic diagram of the thin, lightweight, flexible, bright, wireless display of the present invention, which can simultaneously display three received display signals. The thin, lightweight, flexible, bright, wireless displays of the present invention comprise a flexible substrate providing a support structure on which elements can be fabricated using printing methods. As described in co-owner's co-applied US Patent Application entitled "A Thin, Lightweight, Flexible, Bright, Wireless Display", a unique and efficient method of transmitting display information to a single or multiple displays enables such displays It is not necessary to have significant on-board storage capacity and processing power, the full text of which is hereby incorporated by reference. In accordance with this feature of the invention, the power consumption, bulk, weight and cost normally associated with such devices can be avoided and the durability and convenience of the display can be increased. Furthermore, as shown in FIG. 7, multiple streams of display information may be received and displayed simultaneously. For example, broadcast video content such as a television program may be displayed on a first portion of the display, personalized video content such as a videophone conversation may be displayed on a second portion, and a web page containing mapped hyperlinked content may be displayed on a third portion. Most of the processing operations, networking, signal tuning, data storage, etc. to create this set of display content streams are not performed by the wireless display of the present invention. Other devices such as centralized computers, A/V or gateway devices can perform these functions, therefore, the display of the present invention has great mobility and convenience.

图8表示形成本发明薄型、轻质、柔性、明亮、无线显示器中的一些层。柔性基片210提供耐用、绝缘和保护基底,在该基片上制成各种电池层,输入层,显示层和电子电路层。例如,柔性基片210可以是包括尼龙,聚乙烯的塑料片,或其他合适的材料。柔性电池212制成在柔性基片210上。柔性基片210的大表面积可以形成有合适储能容量和很薄的电池。如此处所描述的,利用本发明微囊打印方法可以制成柔性电池212,或把各个元件片叠层在一起以形成支承片,可以制成柔性基片和电池支承片,在支承片上制成显示器和电子电路。一般地说,按照本发明的柔性电池包括:阴极层214,它可以由阴极薄膜构成。阴极层214可以由高纯度二氧化锰(MnO2)材料制成。与阴极层214相邻的电流收集器216是由金属铂或屏或网格制成。这个电流收集器216形成电池的正引线。阳极层217是由阳极薄膜构成,它有相邻的电流收集器216。阳极层217可以由含锂材料制成。电流收集器216形成电池的负引线。在阳极层217与阴极层214之间是电解质层。电解质层218可以是包含聚合母体中高导电性电解质的微囊。在聚合物内灌输液态电解质,或利用本发明打印方法,在场吸引微囊壳层内微囊封装液态电解质内相,可以制成电解质层218。Figure 8 shows some of the layers that form the thin, lightweight, flexible, bright, wireless display of the present invention. The flexible substrate 210 provides a durable, insulating and protective base upon which the various battery layers, input layers, display layers and electronic circuit layers are formed. For example, flexible substrate 210 may be a plastic sheet including nylon, polyethylene, or other suitable material. A flexible battery 212 is fabricated on a flexible substrate 210 . The large surface area of the flexible substrate 210 can form batteries with suitable energy storage capacity and thinness. As described herein, the microcapsule printing method of the present invention can be used to make a flexible battery 212, or the individual element sheets can be laminated together to form a support sheet, a flexible substrate and a battery support sheet can be made, and a display can be made on the support sheet and electronic circuits. In general, a flexible battery according to the invention includes a cathode layer 214, which may consist of a cathode film. Cathode layer 214 may be made of high purity manganese dioxide (MnO 2 ) material. The current collector 216 adjacent to the cathode layer 214 is made of metallic platinum or a screen or grid. This current collector 216 forms the positive lead of the battery. The anode layer 217 is formed by an anode film, which has the current collector 216 adjacent thereto. The anode layer 217 may be made of a lithium-containing material. Current collector 216 forms the negative lead of the battery. Between the anode layer 217 and the cathode layer 214 is an electrolyte layer. Electrolyte layer 218 may be microcapsules containing a highly conductive electrolyte in a polymeric matrix. The electrolyte layer 218 can be made by infusing the liquid electrolyte in the polymer, or using the printing method of the present invention to microencapsulate the liquid electrolyte inner phase in the field-attracted microcapsule shell.

图8是本发明薄型、轻质、柔性、明亮、无线显示器中各薄片的示意图。本发明显示器制造成本低廉,且耐用和高效。柔性基片210提供形成显示器中各薄片的结构,并使显示器有高度柔软性和耐用性。例如,柔性基片210可以是塑料,纸片或铜版纸,或其他合适的材料。Figure 8 is a schematic illustration of the sheets in the thin, lightweight, flexible, bright, wireless display of the present invention. The displays of the present invention are inexpensive to manufacture, durable and efficient. The flexible substrate 210 provides the structure that forms the sheets in the display and makes the display highly flexible and durable. For example, the flexible substrate 210 can be plastic, paper or coated paper, or other suitable materials.

电池薄片212提供电能给电子电路薄片220元件,用户输入薄片222元件和显示薄片224元件。电池薄片212可以包括:柔性绝缘基片上印制的第一电流收集器216,该基片可以是柔性基片210。一个阳极层217或阴极层214印制在第一电流收集器216层。微囊封装的电解质层218印制在阳极层217或阴极层214。另一个阳极层217或阴极层214印制在电解质层218,而第二电流收集器216印制在这个阳极层217或阴极层214。电池薄片212的尺寸基本上可以是无线显示器的整个表面积。因此,可以制成非常有效和薄型的电池。由于电池产生信号屏蔽效应,理想的是利用小于总的表面积制成电池,并放置可以从多个方向接收信号的天线。或者,有利的是利用屏蔽和信号反射能力以建立接收和/或发射信号的定向性。此外,电池薄片212可以包含多层,用于增大储存密度和改变电池的电气特性。The battery sheet 212 provides power to the electronic circuit sheet 220 components, the user input sheet 222 component and the display sheet 224 component. The battery sheet 212 may include a first current collector 216 printed on a flexible insulating substrate, which may be the flexible substrate 210 . An anode layer 217 or cathode layer 214 is printed on the first current collector 216 layer. The microencapsulated electrolyte layer 218 is printed on the anode layer 217 or the cathode layer 214 . Another anode layer 217 or cathode layer 214 is printed on the electrolyte layer 218 and a second current collector 216 is printed on this anode layer 217 or cathode layer 214 . The size of the battery sheet 212 can be substantially the entire surface area of the wireless display. Therefore, very efficient and thin batteries can be made. Due to the signal shielding effect of the battery, it is ideal to make the battery with less than the total surface area and place an antenna that can receive signals from multiple directions. Alternatively, it may be advantageous to utilize shielding and signal reflection capabilities to establish directionality of received and/or transmitted signals. Additionally, the battery sheet 212 may contain multiple layers for increasing storage density and changing the electrical characteristics of the battery.

本发明的无线显示器还包含电子电路薄片220。利用打印方法可以制成电子电路薄片220的元件,或可以利用其他的技术制成,例如,表面安装电路组件或组合,它与电子元件和电路设计有关。电子电路薄片220包含用于发射用户输入信号的信号发射元件226。这些用户输入信号用于控制远程装置,例如,计算机,A/V设备,可视电话装置,电器,家庭照明等。用户输入信号可以直接发射到被控制的装置,如此处所描述的,或可以被中央计算机装置接收,于是,该计算机用于控制该装置。The wireless display of the present invention also includes an electronic circuit sheet 220 . The components of electronic circuit wafer 220 may be fabricated using printing methods, or may be fabricated using other techniques, such as surface mount circuit assemblies or combinations, which relate to electronic components and circuit designs. The electronic circuit sheet 220 includes signal transmitting elements 226 for transmitting user input signals. These user input signals are used to control remote devices such as computers, A/V equipment, videotelephony devices, appliances, home lighting, and the like. User input signals may be transmitted directly to the device being controlled, as described herein, or may be received by a central computer device, which is then used to control the device.

本发明的重要特征是能够提供薄型、轻质、明亮、无线显示装置,它有低成本和容易制造。典型的是,移动显示装置,例如,膝上型计算机或webpad,需要基本的机载处理能力,它可以接收与互联网连接的无线调制解调器信号和显示网页。本发明的一个目的是在显示器上完全避免需要这种处理能力,从而降低成本,尺寸,电池消耗并增大耐用性和有效性。所以,按照本发明,信号接收元件228包含在接收显示信息的电子电路薄片220内,而显示驱动元件230按照接收的显示信息驱动显示层。如此处所描述的,信号接收元件228是由RF天线和接收电路构成,利用本发明微囊打印方法,可以制成电子元件电路中的大部分或全部元件。An important feature of the present invention is the ability to provide a thin, lightweight, bright, wireless display device that is low cost and easy to manufacture. Typically, mobile display devices, such as laptop computers or webpads, require substantial on-board processing power to receive wireless modem signals connected to the Internet and display web pages. It is an object of the present invention to completely obviate the need for such processing power on the display, thereby reducing cost, size, battery consumption and increasing durability and availability. Therefore, according to the present invention, the signal receiving element 228 is included in the electronic circuit sheet 220 for receiving display information, and the display driving element 230 drives the display layer according to the received display information. As described here, the signal receiving component 228 is composed of an RF antenna and a receiving circuit, and most or all components in the electronic component circuit can be made by using the microcapsule printing method of the present invention.

本发明的薄型、轻质、明亮、无线显示器还包括:用户输入薄片222,用于接收用户输入并产生用户输入信号。用户输入薄片222可以是导电线圈232的网格,它可以利用打印方法制成,通过打印诸如导电聚合物的导电材料。The thin, lightweight, bright, wireless display of the present invention also includes a user input sheet 222 for receiving user input and generating user input signals. The user input sheet 222 may be a grid of conductive coils 232, which may be made using a printing method by printing a conductive material such as a conductive polymer.

在磁场穿过线圈时,导电线圈232中可以产生电流。检测电路(未画出)检测感应电流的位置(如在常规的触摸屏输入装置中),从而定位用户输入。A current may be induced in the conductive coil 232 as a magnetic field passes through the coil. A detection circuit (not shown) detects the location of the induced current (as in a conventional touch screen input device), thereby locating the user input.

用户输入薄片222可以包含绝缘层234上印制的导电元网格。导电元诱发可检测的电信号以响应运动的磁场。例如,磁笔尖通过本发明无线显示器的表面,可以建立运动的磁场。有诱发磁场的导电元位置能使用户输入发生映射。这个映射的输入可以发射到中央计算机装置(如此处所描述的),它能超链路接入互联网基内容,手写体识别,绘图,高亮度文本等。User input sheet 222 may comprise a grid of conductive elements printed on insulating layer 234 . Conductive elements induce detectable electrical signals in response to moving magnetic fields. For example, a magnetic pen tip passing through the surface of the wireless display of the present invention can create a moving magnetic field. The location of conductive elements with induced magnetic fields enables user input to be mapped. This mapped input can be transmitted to a central computer device (as described herein), which can hyperlink to Internet-based content, handwriting recognition, graphics, highlighted text, and the like.

再参照图8,包含用于显示信息的发光像素240的显示薄片224是由基片支承。最好是,按照共有人申请的美国专利申请所述方法制造显示薄片224,其标题为“A Thin,Lightweight,Flexible,Bright,Wireless Display”,全文合并在此供参考。显示薄片224可以形成在本发明无线显示器的其他各层上。利用打印制造方法可以制成这些其他的各层,或利用其他方法制成。例如,把合适材料的片叠层在一起,可以制成此处所描述电池薄片212中的全部或部分,例如,阳极层,阴极层,电荷收集层和电解质层。Referring again to FIG. 8, a display sheet 224 including light-emitting pixels 240 for displaying information is supported by a substrate. Preferably, the display sheet 224 is manufactured as described in co-owned U.S. Patent Application, entitled "A Thin, Lightweight, Flexible, Bright, Wireless Display," which is hereby incorporated by reference in its entirety. Display sheet 224 may be formed on other layers of the wireless display of the present invention. These other layers can be produced using printing manufacturing methods, or using other methods. For example, all or part of the battery sheet 212 described herein can be made by laminating together sheets of suitable materials, eg, anode layers, cathode layers, charge collection layers, and electrolyte layers.

通过提供绝缘层234,例如,在本发明显示层上叠层或印制的聚合物片材料的一个片,可以制成显示薄片224中的发光像素240。包括导电材料线路的x或y电极层242制成在绝缘层上,最好是,通过印制导电聚合物到绝缘层234。发光导电聚合物区240的像素层印制在y电极层242上。包含透明导电材料线的y或x电极层244制成在像素层上。Light emitting pixels 240 in display sheet 224 may be made by providing insulating layer 234, eg, a sheet of polymer sheet material laminated or printed on top of the display layer of the present invention. An x or y electrode layer 242 comprising lines of conductive material is formed on the insulating layer, preferably by printing a conductive polymer onto the insulating layer 234 . A pixel layer of light emitting conductive polymer region 240 is printed on y electrode layer 242 . A y or x electrode layer 244 comprising lines of transparent conductive material is formed on the pixel layer.

显示薄片224可以包含与每个发光像素连接的印制导电引线,在显示驱动元件的控制下,可以有选择地加电能到每个发光像素。信号接收元件228可以包括:第一射频接收元件,用于接收第一射频上承载第一显示信息的第一显示信号,和第二射频接收元件,用于接收第二射频上承载第二显示信息的第二显示信号。显示驱动元件230还可以包括:信号处理元件,例如,DSP,用于接收第一显示信号和第二显示信号并产生显示驱动信号,可以同时在显示薄片224的第一位置上显示第一显示信息和在显示薄片224的第二位置上显示第二显示信息。利用这种结构,例如,可以从屋子的一个房间中放置的计算机接收一个显示信号,和从该屋子的另一个房间中放置的电视机顶盒接收第二显示信号。可以同时显示两个显示信号中承载的信息,例如,能够在本发明无线显示器上同时网浏览和电视观看。此外,本发明无线显示器可以构造成这样,能够同时接收和显示三个或更多个这种信号。The display sheet 224 may include printed conductive leads connected to each light-emitting pixel, and under the control of the display driving element, power can be selectively applied to each light-emitting pixel. The signal receiving element 228 may include: a first radio frequency receiving element, configured to receive the first display signal carrying the first display information on the first radio frequency, and a second radio frequency receiving element, configured to receive the second display information carried on the second radio frequency of the second display signal. The display driving component 230 may also include: a signal processing component, such as a DSP, for receiving the first display signal and the second display signal and generating a display driving signal, which can simultaneously display the first display information on the first position of the display sheet 224 And the second display information is displayed on the second position of the display sheet 224 . With this configuration, for example, it is possible to receive one display signal from a computer placed in one room of the house, and receive a second display signal from a television set-top box placed in another room of the house. Information carried in two display signals can be displayed simultaneously, for example, enabling simultaneous web browsing and TV viewing on the wireless display of the present invention. In addition, the wireless display of the present invention may be constructed so as to be able to receive and display three or more such signals simultaneously.

可以制成这样的显示薄片224,其中三层像素元是一层叠加到另一层上。包含OLED像素240的每层产生彩色光(如同普通彩色电视中的像素240)。通过控制每个像素240的开关状态和/或光强,可以得到全色显示。在显示薄片224上可以制成透明的保护基片246,例如,保护基片246可以是清澈、耐用的柔性聚合物。A display sheet 224 can be made in which three layers of pixels are superimposed one on top of the other. Each layer including OLED pixels 240 produces colored light (like pixels 240 in a normal color television). By controlling the on-off state and/or light intensity of each pixel 240, a full-color display can be obtained. A transparent protective substrate 246 can be formed over the display sheet 224, for example, the protective substrate 246 can be a clear, durable flexible polymer.

按照本发明,电子电路薄片220中至少一些元件是通过印制电激活材料以制成电路元件,其中包括:电阻器,电容器,电感器,天线,导体和半导体器件。这就可以实现非常适用,高效率和有效的制造过程,并能使本发明器件有低的制造成本。According to the present invention, at least some components of the electronic circuit sheet 220 are printed with electroactive materials to form circuit elements, including: resistors, capacitors, inductors, antennas, conductors and semiconductor devices. This allows for a very adaptable, efficient and effective manufacturing process and enables low manufacturing costs for the devices of the invention.

图9是利用微囊打印机制作本发明薄型、柔性、轻质、明亮、无线显示器的实施例。该图描绘圆形微囊元代表的微囊层堆积。当然,实际上,这些微囊层被显影,并使微囊破裂。在激光墨粉的情况下,微囊被熔化和破裂。在微囊打印机的情况下,最可能是借助于压力或加热量微囊破裂。或者,一些微囊不需要任何的显影,而是有这样的成分,未破裂或未显影的微囊变成部分的制成电子元件。Fig. 9 is an embodiment of making a thin, flexible, lightweight, bright, wireless display of the present invention by using a microcapsule printer. The figure depicts the packing of microcapsule layers represented by circular microcapsule elements. In practice, of course, these microcapsule layers are developed, and the microcapsules are ruptured. In the case of laser toners, the microcapsules are melted and ruptured. In the case of a microcapsule printer, the microcapsules are most likely ruptured by means of pressure or heat. Alternatively, some microcapsules do not require any development, but instead have such a composition that the unruptured or undeveloped microcapsules become part of the finished electronic component.

按照本发明,可以得到薄型、柔性、轻质、明亮、无线显示器,它有能够利用打印方法制作的元件。柔性基片210提供支承结构,利用打印方法可以在此基片上制作元件。提供包含发光像素的显示薄片224用于显示信息。通过印制发光导电聚合物的像素层240,可以制成发光像素。显示薄片224包含与每个发光像素相联系的印制导电引线242,244,在显示驱动元件的控制下,有选择地加电能到每个发光像素,发光像素是这样制成的,提供绝缘层234,在绝缘层234上印制包含导电材料线的y电极层242,在y电极层242上印制发光导电聚合物区240的像素层,和在像素层240上印制包含透明导电材料线的x电极层244。According to the present invention, a thin, flexible, light weight, bright, wireless display can be obtained, which has elements that can be fabricated using printing methods. The flexible substrate 210 provides the support structure on which components can be fabricated using printing methods. A display sheet 224 comprising light emitting pixels is provided for displaying information. By printing a pixel layer 240 of a light emitting conductive polymer, a light emitting pixel can be made. The display sheet 224 includes printed conductive leads 242, 244 associated with each light-emitting pixel. Under the control of the display drive element, power is selectively applied to each light-emitting pixel. The light-emitting pixels are made in such a way that an insulating layer is provided. 234, print the y-electrode layer 242 comprising the conductive material line on the insulating layer 234, print the pixel layer of the light-emitting conductive polymer region 240 on the y-electrode layer 242, and print the transparent conductive material line on the pixel layer 240 The x-electrode layer 244.

电子电路薄片220包含用户输入映射元件,用于接收用户输入信号并确定显示器上接收用户输入信号的物理位置。用户输入映射元件产生映射的用户输入信号。例如,可以利用电极信号检测电路的元件,例如,触摸屏装置所用元件,检测和映射接收的用户输入信号以响应磁笔尖在输入网格上的运动。信号发射元件从本发明无线显示装置中发射映射的用户输入信号作为无线信息信号。信号接收元件接收显示信息。信号接收元件可以包括:第一射频接收元件,用于接收第一射频承载第一显示信息的第一显示信号,和第二射频接收元件,用于接收第二射频承载第二显示信息的第二显示信号。显示驱动元件包括:信号处理元件,用于接收第一显示信号和第二显示信号并产生显示驱动信号,可以同时在显示薄片224的第一位置上显示第一显示信息和在显示薄片224的第二位置上显示第二显示信息。The electronic circuit sheet 220 contains user input mapping elements for receiving user input signals and determining the physical location on the display at which the user input signals are received. A user input mapping element generates a mapped user input signal. For example, elements of an electrode signal detection circuit, such as those used in a touch screen device, may be utilized to detect and map received user input signals in response to movement of a magnetic pen tip across an input grid. The signal transmitting element transmits the mapped user input signal from the wireless display device of the present invention as a wireless information signal. The signal receiving element receives display information. The signal receiving element may include: a first radio frequency receiving element, configured to receive a first display signal carried by a first radio frequency carrying first display information, and a second radio frequency receiving element, configured to receive a second radio frequency signal carrying a second display information. Show signal. The display driving component includes: a signal processing component, used for receiving the first display signal and the second display signal and generating the display driving signal, which can simultaneously display the first display information on the first position of the display sheet 224 and the first display information on the first position of the display sheet 224 The second display information is displayed on the second position.

信号发射元件和信号接收元件包含熟知的电子电路元件,例如,天线,电阻器,电感器,电容器,和电子元件227代表的其他RF电路器件。利用本发明打印机和打印方法,可以直接制作这种器件中的至少一些器件以及本发明无线显示器其他薄片中的元件。显示驱动元件根据接收的显示信息驱动显示层。这些显示驱动元件是由熟知的电路构成,例如,普通LCD屏的驱动电路。然而,普通LCD屏利用包含液晶光阀的像素使背面照明有选择地通过。按照本发明,有机发光元件用作图像元。由于每个像素在受到驱动时由自身发射光,就不需要背面照明,与LCD技术比较,可以降低整个电路复杂性,成本和重量。The signal transmitting element and the signal receiving element comprise well-known electronic circuit elements such as antennas, resistors, inductors, capacitors, and other RF circuit devices represented by electronic element 227 . Using the printers and printing methods of the invention, at least some of these devices, as well as elements in other sheets of the wireless displays of the invention, can be directly fabricated. The display driving element drives the display layer according to the received display information. These display driving elements are formed by well-known circuits, for example, driving circuits of common LCD screens. Conventional LCD panels, however, use pixels containing liquid crystal light valves to selectively pass backside illumination. According to the invention, an organic light-emitting element is used as a picture element. Since each pixel emits light by itself when driven, no backlighting is required, reducing overall circuit complexity, cost and weight compared to LCD technology.

用户输入薄片222接收用户输入并产生用户输入信号。用户输入薄片222包含绝缘层上印制的导电元232的网格,所述导电元232诱发可检测的电信号以响应运动的磁场。The user input sheet 222 receives user input and generates user input signals. The user input sheet 222 contains a grid of conductive elements 232 printed on an insulating layer that induce a detectable electrical signal in response to a moving magnetic field.

电池薄片212提供电能给电子电路薄片220元件,输入薄片222元件和显示薄片224元件。电池薄片212包括:柔性绝缘基片上印制的第一电流收集层216,该基片可以是柔性基片210。阳极层217印制在第一电流收集层上。电解质层218印制在阳极层217上。阴极层214印制在电解质层218上,而第二电流收集层216印制在阴极层214上。按照本发明,本发明无线显示器中的许多元件是这样制成的,通过印制电激活材料以制成电路元件,它包括:电阻器,电容器,电感器,天线,导体和半导体器件。The battery sheet 212 provides power to the electronic circuit sheet 220 components, input sheet 222 components and display sheet 224 components. The battery sheet 212 includes a first current collecting layer 216 printed on a flexible insulating substrate, which may be the flexible substrate 210 . An anode layer 217 is printed on the first current collecting layer. An electrolyte layer 218 is printed on the anode layer 217 . The cathode layer 214 is printed on the electrolyte layer 218 and the second current collecting layer 216 is printed on the cathode layer 214 . In accordance with the present invention, many components of the wireless display of the present invention are made by printing electro-active materials to form circuit elements including: resistors, capacitors, inductors, antennas, conductors and semiconductor devices.

具体地说,关于电池薄片212,柔性基片210的大表面积可以制成有合适储能容量和很薄的电池。如此处所描述的,把各种元件片叠层在一起以制成支承片,可以制成柔性基片和电池支承片,在此支承片上制作显示器和电子电路。按照本发明的这个特征,利用本发明的场吸引微囊打印方法,可以制成柔性电池。然而,应当注意,按照本发明柔性电池的制作,也可以利用其他的打印方法,例如,喷墨打印。在喷墨打印的情况下,包含本发明电池组成部分的微囊散布在液体内并喷射到喷墨打印方法中的柔性基片210上。按照本发明,通过形成微囊封装的电激活材料层,该材料层构成功能电池的元件,可以制成电池。通过形成第一阴极微囊层制成阴极部分。微囊封装的阴极材料可以由聚合物壳层内包含的高纯度二氧化锰(MnO2)内相构成。在第一阴极微囊层邻近,制作由金属箔或网格等制成的第一电池引线。第二阴极微囊层制成在这个电池引线的上部。阳极部分是通过形成第一阳极微囊层制成的。微囊封装的阳极材料可以由聚合物壳层内的含锂材料内相构成。在第一阳极微囊层邻近,制作金属箔或网格等制成的第二电池引线。第二阳极微囊层制成在这个电池引线的上部。在阳极部分与阴极部分之间是电解质层。电解质层可以是聚合母体中的高导电性电解质。在场吸引微囊壳层内微囊封装液态电解质内相,可以制成电解质层。在每层的制成步骤期间,特别是在压力或加热可破裂微囊的情况下,可以固化或破裂每个微囊层,在形成顶层之后,电池元件微囊层可以全部固化或破裂。利用这个方法,利用本发明微囊打印方法制成薄型、柔性、轻质功率源。类似于此处描述的结构,利用包含合适树脂,聚合物或其他合适物质以增大强度和防止柔性电池元件叠层分离的场吸引微囊,可以制成充满通孔的结构材料。此外,需要制成这样的电池,电解质封装在电绝缘外壳内,且在诸如加压破裂的显影之后需要产生电能时才激活。因此,诸如RF接头或无线显示器的器件可以有长的存放寿命,通过破裂电解质微囊使器件激活后使用。In particular, with respect to battery sheet 212, the large surface area of flexible substrate 210 allows for suitable energy storage capacity and very thin batteries. As described herein, various component sheets are laminated together to form a support sheet, which can be used to form flexible substrates and battery support sheets on which displays and electronic circuits are fabricated. According to this feature of the present invention, flexible batteries can be made by using the field-attracted microcapsule printing method of the present invention. However, it should be noted that other printing methods, such as inkjet printing, can also be utilized in the fabrication of flexible batteries according to the present invention. In the case of inkjet printing, the microcapsules containing the battery components of the present invention are dispersed in a liquid and ejected onto the flexible substrate 210 in the inkjet printing process. According to the present invention, a battery can be made by forming a microencapsulated layer of electroactive material which constitutes an element of a functional battery. The cathode portion is made by forming a first cathode microcapsule layer. The microencapsulated cathode material may consist of an internal phase of high purity manganese dioxide ( MnO2 ) contained within a polymer shell. Adjacent to the first cathode microcapsule layer, a first cell lead made of metal foil or mesh or the like is fabricated. A second cathode microcapsule layer is formed on top of this cell lead. The anode portion is made by forming a first anode microcapsule layer. The microencapsulated anode material may consist of an internal phase of lithium-containing material within a polymer shell. Adjacent to the first anode microcapsule layer, a second battery lead made of metal foil or mesh is fabricated. A second anode microcapsule layer is formed on top of this cell lead. Between the anode part and the cathode part is an electrolyte layer. The electrolyte layer may be a highly conductive electrolyte in a polymeric matrix. The liquid electrolyte inner phase is encapsulated by the microcapsules in the shell layer of the field-attracted microcapsules, and the electrolyte layer can be made. Each layer of microcapsules can be cured or ruptured during the step of making each layer, especially in the case of pressure or heat rupturable microcapsules, and after the formation of the top layer, the battery element microcapsule layers can all be cured or ruptured. Using this method, the microcapsule printing method of the present invention is used to make a thin, flexible and lightweight power source. Similar to the structures described here, via-filled structural materials can be made using field-attracting microcapsules containing suitable resins, polymers, or other suitable substances to increase strength and prevent separation of flexible battery element stacks. In addition, there is a need to make batteries where the electrolyte is encapsulated within an electrically insulating casing and activated only when power is required to be generated after development such as pressurization. Thus, devices such as RF connectors or wireless displays can have a long shelf life by rupturing the electrolyte microcapsules to activate the device for use.

图9(a)是按照此处描述的本发明印制电子电路方法所用柔性可充电电池支承片248的放大剖面图。按照本发明的一个特征,利用柔性可充电电池支承片248作为支承片,在此支承片上可以制作薄型、轻质、明亮、和柔性彩色显示器。可充电电池元件可以包括:可充电塑料锂离子电池。电池元件包含塑料件250,它是利用液态电解质灌输塑料制成。形成的塑料电解质件250通常约含50%液体,但不能泄漏。塑料电解质件250夹在铝网格254熔接的正塑料电极252(它可以包含氧化锂锰)与铜网格258熔接的负塑料电极256(它可以包含碳)之间。按照本发明,结构支承基片260放置成与可充电电池元件的至少一侧相邻。结构壳层基片260可以是耐用和柔性材料,例如,玻璃纤维,塑料或其他合适的材料。因此,按照本发明,柔性可充电电池支承片248可用于提供自给式功率源,给电路元件和此处描述的薄型、轻质、明亮、和柔性彩色显示器中显示元件提供能量。在这种情况下,提供柔性可充电电池支承片48作为基片,在此基片上制作本发明显示器的其余部分。如同此处所描述的,利用本发明微囊打印方法,可以制作构成柔性可充电电池中的全部元件或一些元件。在这种情况下,利用相同的本发明打印技术,可以制作本发明柔性可充电显示器的能源,以及本发明薄型、轻质、明亮和柔性彩色显示器的一些或全部其他电子和显示元件。制成的显示器有非常高的效率,因为显示器的支承元件也用于储存驱动电子和显示元件所需的电能,从而大大节省重量并使空间最大化。提供所需的电极区和导电通孔(未画出),可以使电池与其余的电子元件连接。Figure 9(a) is an enlarged cross-sectional view of a flexible rechargeable battery support sheet 248 for use in the method of printing electronic circuits according to the invention described herein. According to a feature of the present invention, flexible rechargeable battery support sheet 248 is utilized as a support sheet on which a thin, lightweight, bright, and flexible color display can be fabricated. Rechargeable battery elements may include: rechargeable plastic lithium-ion batteries. The battery element comprises a plastic part 250 which is made by impregnating the plastic with a liquid electrolyte. The formed plastic electrolyte member 250 is typically about 50% liquid, but must not leak. The plastic electrolyte member 250 is sandwiched between a positive plastic electrode 252 (which may contain lithium manganese oxide) fused to an aluminum grid 254 and a negative plastic electrode 256 (which may contain carbon) fused to a copper grid 258 . In accordance with the present invention, structural support substrate 260 is positioned adjacent at least one side of the rechargeable battery element. Structural shell substrate 260 may be a durable and flexible material such as fiberglass, plastic or other suitable material. Thus, in accordance with the present invention, flexible rechargeable battery support sheet 248 can be used to provide a self-contained power source to power circuit components and display elements in the thin, lightweight, bright, and flexible color displays described herein. In this case, a flexible rechargeable battery support sheet 48 is provided as the substrate upon which the remainder of the display of the invention is fabricated. As described herein, all or some of the components that make up a flexible rechargeable battery can be fabricated using the microcapsule printing method of the present invention. In this case, using the same inventive printing technique, it is possible to fabricate the energy source for the inventive flexible rechargeable display, as well as some or all of the other electronic and display elements for the inventive thin, lightweight, bright and flexible color display. The resulting displays are very efficient because the display's support elements are also used to store the electrical energy needed to drive the electronics and display elements, resulting in significant weight savings and space maximization. Providing the required electrode areas and conductive vias (not shown) allows the battery to be connected to the rest of the electronics.

图9(b)表示导电线圈的网格,它是本发明薄型、轻质、柔性、明亮、无线显示器的部分用户输入薄片。用户输入薄片可以由导电元的网格构成,每个导电元诱发可检测的电信号以响应运动的磁场。或者,用户输入薄片可以包括触摸屏,它是在绝缘层上印制压敏或电容敏感元件制成。在任何情况下,确定用户输入的物理位置和基于确定的物理位置产生控制信号并发射到远程装置。通过映射本发明无线显示器上显示的超链路位置,并把该位置与中央计算机映射的超链路相联系(若改变无线显示器的布局,例如,移动显示器特定屏上的位置,如网页,则可以发射布局信息到显示信息发射装置,从而使网关系统是可行的,其中单个服务器可以提供互联网,音频和视频内容到许多无线装置)。Figure 9(b) shows a grid of conductive coils that is part of the user input sheet for the thin, lightweight, flexible, bright, wireless display of the present invention. The user input sheet may consist of a grid of conductive elements, each of which induces a detectable electrical signal in response to a moving magnetic field. Alternatively, the user input sheet may comprise a touch screen made by printing pressure sensitive or capacitive sensitive elements on an insulating layer. In any event, the physical location of the user input is determined and a control signal is generated and transmitted to the remote device based on the determined physical location. By mapping the hyperlink position displayed on the wireless display of the present invention, and linking this position with the hyperlink mapped by the central computer (if the layout of the wireless display is changed, for example, the position on the specific screen of the mobile display, such as a web page, then Layout information can be transmitted to display information transmitting devices, making a gateway system feasible where a single server can provide Internet, audio and video content to many wireless devices).

图9(c)是按照本发明磁检测网格上形成的磁笔划。如图9(c)所示,检测磁笔划作为用户输入薄片线圈内感应的电流。这种检测的磁笔尖运动能够确定用户输入的位置。无线发射有关磁笔划映射和跟踪的信息到远程计算机,其中发生手写体识别,超链路映射和其他有用的处理操作。此外,通过控制显示器,本发明无线显示器或远程计算机可以利用这个检测的笔划给用户提供反馈,从而产生笔划运动的视觉表示。Fig. 9(c) is a magnetic stroke formed on a magnetic detection grid according to the present invention. As shown in Figure 9(c), the magnetic stroke is detected as a user input current induced in the foil coil. This detected magnetic tip movement enables the location of user input to be determined. Information about magnetic stroke mapping and tracking is wirelessly transmitted to a remote computer where handwriting recognition, hyperlink mapping and other useful processing operations occur. Additionally, by controlling the display, the wireless display or remote computer of the present invention can use this detected stroke to provide feedback to the user, thereby producing a visual representation of the stroke motion.

各种打印方法适合于制成本发明无线显示器中的元件,其中包括喷墨打印技术,或本发明激光、微囊等打印技术。当磁场穿过线圈时,导电线圈中可以产生电流。检测电路(未画出)检测感应电流的位置(如同在普通的触摸屏输入装置中),从而可以定位用户输入。用户输入薄片可以包括绝缘层上印制的导电元网格。导电元诱发可检测的电信号以响应运动的磁场。例如,磁笔尖通过本发明无线显示器的表面,可以产生运动的磁场。有感应磁场的导电元位置能使用户输入发生映射。发射这个映射的输入到中央计算机装置(如此处所描述的),就能够超链路接入互联网基内容,手写体识别,绘图,高亮度文本等。图9(d)是导电线圈的分解图。图9(e)是导电线圈的组合图;和图9(f)是两个导电线圈的剖面图。每个导电元可以制成这样的形状,线圈的终端是x电极和y电极端,这种线圈的网格包含用户输入薄片。本发明打印方法制成线圈网格需要在绝缘支承片上堆积导电线圈结构,该支承结构可以是薄片或印制的绝缘层。如图10所示,绝缘材料可以印制在线圈的导电部分之间以建立平坦的上表面,在此表面上加另一个绝缘层(或印制的绝缘片)。在这个绝缘层的上面,制成顶部电极层以完成线圈网格。绝缘层中的通孔可以使顶部电极与印制线圈形成电连接。Various printing methods are suitable for making components in the wireless display of the present invention, including inkjet printing technology, or printing technology such as laser and microcapsules of the present invention. When a magnetic field passes through the coil, a current can be induced in the conductive coil. A detection circuit (not shown) detects the position of the induced current (as in a common touch screen input device), so that the user input can be located. The user input sheet may comprise a grid of conductive elements printed on an insulating layer. Conductive elements induce detectable electrical signals in response to moving magnetic fields. For example, a magnetic pen tip passing through the surface of the wireless display of the present invention can generate a moving magnetic field. The location of conductive elements with induced magnetic fields enables user input to be mapped. Transmitting this mapped input to a central computer device (as described herein) enables hyperlink access to Internet-based content, handwriting recognition, graphics, highlighted text, and the like. Figure 9(d) is an exploded view of the conductive coil. Figure 9(e) is an assembled view of the conductive coil; and Figure 9(f) is a cross-sectional view of two conductive coils. Each conductive element may be shaped such that the coil terminates at the x- and y-electrode terminals, the grid of such coils containing the user input slice. The printing method of the present invention to form a coil grid requires the deposition of a conductive coil structure on an insulating support sheet, which can be a thin sheet or a printed insulating layer. As shown in Figure 10, insulating material can be printed between the conductive parts of the coil to create a flat upper surface on which another insulating layer (or printed insulating sheet) is added. On top of this insulating layer, a top electrode layer is made to complete the coil grid. Vias in the insulating layer allow electrical connection of the top electrode to the printed coil.

图9(h)是按照图9(g)所示本发明可充电电池结构制成的多单元支承片的剖面图。柔性电池元件262的叠层夹在内支承基片264与外支承基片266之间。这些支承基片给显示器元件提供耐久性和保护,以及电池元件与其他电子电路元件之间的电绝缘。每个相邻的柔性电池元件叠层件与它的相邻部分分享铜或铝网格。填充通孔268的结构材料增大强度并防止柔性电池元件叠层262的分离。例如,结构材料可以是树脂,聚合物,或其他的合适物质。Fig. 9(h) is a cross-sectional view of a multi-unit support sheet made according to the structure of the rechargeable battery of the present invention shown in Fig. 9(g). The stack of flexible battery elements 262 is sandwiched between an inner support substrate 264 and an outer support substrate 266 . These support substrates provide durability and protection to the display components, as well as electrical isolation between the battery components and other electronic circuit components. Each adjacent stack of flexible battery elements shares the copper or aluminum mesh with its neighbors. The structural material filling the vias 268 increases strength and prevents separation of the flexible battery element stack 262 . For example, the structural material may be a resin, polymer, or other suitable substance.

现在描述微囊层中制成电子电路的本发明打印机的另一个实施例。如图10(a)所示,提供一个图像接收装置,用于接收场吸引微囊24层中电子电路。图像接收装置包括局部可变的吸引场元件,它包含在其上面有光磁涂层146的玻璃板基片144。信息光源包括:例如,一束光纤光缆148用于传输光信息,每个光纤光缆形成单个光纤像素。各个光纤的末端可以熔接在一起以形成玻璃板基片,或建立由玻璃板基片144支承的结构。此外,光磁涂层146也可以是光电涂层146,它产生均匀或变化的静电场以吸引静电吸引微囊24。通过改变指向光纤光缆束的光信息空间关系和强度,光磁涂层或光电涂层146变成吸引的,因此,它能够吸引场吸引微囊24到吸引场元件的选取部分。按照本发明,控制装置与信息光源连接,用于控制局部可变吸引场元件,可以有选择地加吸引场到局部可变吸引场元件的位置,因此,通过有选择地加局部可变吸引场元件,可以制成场吸引微囊24层。Another embodiment of the printer of the present invention in which electronic circuits are formed in the microcapsule layer will now be described. As shown in FIG. 10( a ), an image receiving device is provided for receiving the electric circuit in the field-attracting microcapsule 24 layer. The image receiving device includes a locally variable attractive field element comprising a glass plate substrate 144 having an optomagnetic coating 146 thereon. The information light source includes, for example, a bundle of fiber optic cables 148 for transmitting optical information, each fiber optic cable forming a single fiber optic pixel. The ends of the individual fibers may be fused together to form the glass plate substrate, or to create a structure supported by the glass plate substrate 144 . In addition, the opto-magnetic coating 146 can also be an opto-electronic coating 146 that generates a uniform or varying electrostatic field to attract the electrostatically attracted microcapsules 24 . By changing the spatial relationship and intensity of the optical information directed to the fiber optic cable bundle, the opto-magnetic coating or optoelectronic coating 146 becomes attractive so that it is capable of attracting the microcapsules 24 to selected portions of the attracting field element. According to the present invention, the control device is connected with the information light source for controlling the locally variable attracting field element, and can selectively add the attracting field to the position of the locally variable attracting field element, therefore, by selectively adding the locally variable attracting field Components can be made into 24 layers of field-attracting microcapsules.

在图10(a)至10(c)所示的实施例中,控制装置包含光纤束的末端,并通过加入射到光磁涂层146选取位置的光信息,可以控制吸引场元件的吸引强度,使吸引场加到吸引场元件的位置。在被入射光激励时,光磁涂层变成磁可吸引的,从而使磁吸引微囊到达吸引场元件。In the embodiment shown in Figures 10(a) to 10(c), the control means comprises the end of the optical fiber bundle, and by adding light information to the selected position of the optical magnetic coating 146, the attraction strength of the attraction field element can be controlled , so that the attractive field is added to the location of the attractive field element. When excited by incident light, the optomagnetic coating becomes magnetically attractable, thereby magnetically attracting the microcapsules to the attracting field element.

如图10(a)至10(c)所示,光束被引导通过一段光纤,使它入射到光电和/或光磁涂层146以产生磁场和/或静电场,为的是在光电和/或光磁涂层146的对应离散位置加各自的吸引场。光电和/或光磁涂层146可以是这样加的,例如,有选择地静电吸引和磁吸引有不同成分的微囊24以产生多个效应。As shown in Figures 10(a) to 10(c), the light beam is guided through a section of optical fiber, making it incident on the optoelectronic and/or optomagnetic coating 146 to generate a magnetic field and/or an electrostatic field, in order to Or corresponding discrete positions of the magneto-optical coating 146 plus respective attractive fields. The optoelectronic and/or optomagnetic coating 146 may be applied, for example, to selectively electrostatically and magnetically attract microcapsules 24 of different compositions to produce multiple effects.

光信息源可以是荧光涂层150,它发射光以响应入射的电子束。荧光涂层150可以包括黑白荧光屏以形成高对比度和灰色调,从而改变光磁和光电效应。彩色荧光屏可用于给出有不同效应的彩色信息,它与光电和光磁涂层146的属性有关。The source of optical information may be a fluorescent coating 150 that emits light in response to an incident electron beam. The phosphor coating 150 may include a black and white phosphor screen to create high contrast and gray tones, thereby altering the magneto-optical and electro-optical effects. Color phosphor screens can be used to give color information with different effects, depending on the properties of the optoelectronic and optomagnetic coating 146 .

在图10(c)所示的实施例中,光信息用于控制吸引场元件的吸引强度,光屏蔽层152可用于防止微囊24的多余曝光。或者,微囊24的光磁层和电激活材料可以对光的不同波长起反应,从而防止电激活材料的过早曝光。In the embodiment shown in FIG. 10( c ), the light information is used to control the attraction strength of the field element, and the light shielding layer 152 can be used to prevent unwanted exposure of the microcapsules 24 . Alternatively, the optomagnetic layer and electro-active material of microcapsule 24 may respond to different wavelengths of light, thereby preventing premature exposure of the electro-active material.

现在参照图11(a),可以加均匀的强度和/或波长入射到光磁涂层146上以形成均匀磁场,它导致有平坦结构的均匀微囊24层。此外,为了产生各种效应,例如,电子电路设置在记录薄片上的离散位置,而同时使记录薄片的其余部分保持空白,形成三维电子电路,或堆积复合的电子电路到记录薄片上,在一系列电子电路成型步骤中的各个离散位置上有选择地形成电子电路,可以加变化强度和/或波长的光入射到光磁涂层146上,为的是形成非均匀的磁场,它导致有变化结构的非均匀微囊24层。Referring now to FIG. 11(a), a uniform intensity and/or wavelength may be incident on the magneto-optical coating 146 to form a uniform magnetic field, which results in a uniform microcapsule 24 layer with a planar structure. Furthermore, in order to produce various effects such as placing electronic circuits at discrete positions on the recording sheet while leaving the rest of the recording sheet blank, forming a three-dimensional electronic circuit, or stacking composite electronic circuits onto the recording sheet, in a To selectively form electronic circuits at discrete locations in a series of electronic circuit forming steps, light of varying intensities and/or wavelengths may be incident on the magneto-optical coating 146 in order to form a non-uniform magnetic field that results in varying Structure of heterogeneous microcapsules with 24 layers.

如图12(a)所示,来自激光源156的扫描激光可用于写入信息到玻璃基片144的光磁涂层146上。可以脉冲调制扫描激光,从而有选择地写入信息到光磁涂层146上的选取离散位置。如图12(b)所示,扫描电子枪158可用于写入信息到荧光涂层150上。在这种情况下,利用常规的磁场操作技术,例如,普通阴极射线管所采用的技术,可以使扫描电子枪158扫描。因此,荧光屏产生光的发射,它入射到光磁或光电涂层146上并在吸引场元件的选取离散位置产生光磁和/或静电效应,为的是制成吸引微囊24的所需未曝光电子电路成型潜像层。Scanning laser light from a laser source 156 can be used to write information onto the opto-magnetic coating 146 of the glass substrate 144 as shown in FIG. 12( a ). The scanning laser may be pulsed to selectively write information to selected discrete locations on the magneto-optical coating 146 . As shown in FIG. 12( b ), a scanning electron gun 158 may be used to write information onto the fluorescent coating 150 . In this case, scanning electron gun 158 may be caused to scan using conventional magnetic field manipulation techniques, such as those employed in conventional cathode ray tubes. Accordingly, the phosphor screen produces an emission of light which is incident on the optomagnetic or optoelectronic coating 146 and which produces optomagnetic and/or electrostatic effects at selected discrete locations of the attracting field elements in order to create the desired undesired properties of the attracting microcapsules 24. Expose the electronic circuit to form the latent image layer.

如图12(c)和12(d)所示,LCD矩阵160,或发光二极管或二极管激光器矩阵,可用于写入信息到光磁和/或光电涂层146上。在LCD矩阵160的情况下,可以提供由LCD矩阵160光阀效应空间调制的背面照明。利用制成这种器件的已知技术,可以制成LCD矩阵160或二极管激光器(或LED)矩阵。As shown in FIGS. 12( c ) and 12 ( d ), an LCD matrix 160 , or a matrix of light emitting diodes or diode lasers, can be used to write information onto the optomagnetic and/or optoelectronic coating 146 . In the case of an LCD matrix 160, backside illumination spatially modulated by the LCD matrix 160 light valve effect may be provided. An LCD matrix 160 or a diode laser (or LED) matrix can be fabricated using known techniques for fabricating such devices.

图13表示激光源156产生激光束的另一个实施例,其中利用电流扫描仪162使激光束在吸引场元件的光磁和/或光电涂层146上扫描。为了提高对比度,并使吸引场元件上的离散位置(即,像素)之间有间隔,光磁和/或光电涂层146可以形成像素。把涂层146蚀刻成离散的像素,可以使每个像素的各自感应场更集中在分开像素的区域内,为的是减小每个像素中感应的场对相邻像素的影响。利用已知的掩模/选择性蚀刻技术,例如,印刷电路制造中采用的那些技术,可以完成涂层的蚀刻。可以脉冲调制激光束以传送电子电路信息。电流扫描仪162用于引导这个脉冲调制激光束到吸引场元件的位置以形成电子电路潜像。因此,可以制成局部可变的吸引场,被吸引的微囊24形成有平坦结构的均匀层或有变化结构的非均匀层。通过控制激光束的扫描,可以制作产生吸引场的电子电路潜像。FIG. 13 shows another embodiment of laser source 156 generating a laser beam that is scanned across optomagnetic and/or optoelectronic coating 146 of an attracting field element using galvano scanner 162 . To improve contrast and provide spacing between discrete locations (ie, pixels) on the field element, optomagnetic and/or optoelectronic coatings 146 may form pixels. Etching the coating 146 into discrete pixels allows each pixel's respective sensing field to be more concentrated in the area separating the pixels in order to reduce the effect of the field induced in each pixel on adjacent pixels. Etching of the coating can be accomplished using known masking/selective etching techniques, such as those employed in printed circuit fabrication. Laser beams can be pulsed to convey electronic circuit information. A galvano scanner 162 is used to direct this pulse modulated laser beam to the location of the attractive field element to form a latent image of the electronic circuit. Thus, a locally variable attraction field can be made, and the attracted microcapsules 24 form a uniform layer with a flat structure or a non-uniform layer with a variable structure. By controlling the scanning of the laser beam, latent images of electronic circuits that generate attractive fields can be made.

图14表示吸引场元件配置成转鼓164的一个实施例。转鼓164的工作面上涂敷光电和/或光磁涂层146,而一个或多个激光束在转鼓164的整个表面上一次扫描一条或多条线以形成吸引场。在多个激光束的情况下,可以加空间光信息以调制不同的光束。此外,一条或多条光纤光缆148可用于引导光到转鼓164上。或者,电子束可用于产生变化的吸引场。FIG. 14 shows an embodiment in which the attractive field elements are configured as a rotating drum 164 . The working surface of the drum 164 is coated with an optoelectronic and/or magneto-optical coating 146, and one or more laser beams are scanned across the entire surface of the drum 164 one or more lines at a time to form an attractive field. In the case of multiple laser beams, spatial optical information can be added to modulate the different beams. Additionally, one or more fiber optic cables 148 may be used to direct light onto the drum 164 . Alternatively, electron beams can be used to generate varying attractive fields.

如图15(a)所示,吸引场元件配置成转鼓164,它也可以是空鼓,并包含透明基片144。载信息光源,例如,一条或多条光纤光缆148,阴极射线管,液晶光阀(或其他的空间光调制器)矩阵,LED或二极管激光器矩阵,或其他的载信息光源,放置在空鼓164内部的某个位置,它可以辐射到空转鼓164上设置的光电和/或光磁涂层146。光信息传输通过透明鼓164基片144,并使光电和/或光磁涂层146变成局部可变的吸引涂层。As shown in FIG. 15( a ), the attractive field element is configured as a rotating drum 164 , which may also be hollow, and contains a transparent substrate 144 . An information-carrying light source, such as one or more fiber optic cables 148, a cathode ray tube, a matrix of liquid crystal light valves (or other spatial light modulators), a matrix of LED or diode lasers, or other information-carrying light sources, is placed in the hollow drum 164 Somewhere inside, it may radiate to the optoelectronic and/or optomagnetic coating 146 provided on the idler drum 164 . Optical information is transmitted through the transparent drum 164 to the substrate 144 and causes the optoelectronic and/or optomagnetic coating 146 to become a locally variable attractive coating.

如图15(b)所示,空转鼓164内部设置信息光源的光信息使光电,光磁涂层146在转鼓164的表面产生吸引场。来自微囊源26的微囊24被吸引到转鼓164的表面(或转鼓164上放置的记录薄片表面)。当转鼓164转动时,微囊24层变成面向另一个信息光源165(它可以配置成如参照转鼓164内部信息光源所描述的光源)。这个信息光源165影像曝光微囊24层以产生电子电路潜像。然后,使电子电路潜像显影(未画出)。此外,消除装置167可用于恢复光电,光磁涂层146的磁场或静电场。As shown in FIG. 15( b ), the optical information of the information light source is set inside the idle drum 164 to make the optoelectronic, and the optomagnetic coating 146 generate an attractive field on the surface of the drum 164 . The microcapsules 24 from the microcapsule source 26 are attracted to the surface of the drum 164 (or the surface of the recording sheet placed on the drum 164). As the drum 164 rotates, the layer of microcapsules 24 becomes facing another information light source 165 (which may be configured as a light source as described with reference to the information light source inside the drum 164). This information light source 165 imagewise exposes the microcapsule 24 layer to produce a latent image of the electronic circuit. Then, the latent image of the electronic circuit is developed (not shown). Additionally, the canceling device 167 may be used to restore the magnetic or electrostatic field of the opto-electronic, opto-magnetic coating 146 .

图16(a)至16(d)表示信息光源的各种配置。图16(a)表示配置成LED或二极管激光器矩阵166的信息光源;图16(b)表示配置成有背面照明168的液晶光阀160的信息光源;图16(c)表示配置成阴极射线管170的信息光源;和图16(d)表示配置成光纤光缆末端172阵列的信息光源。为了便于说明,阵列或矩阵中每个单元174的尺寸是放大的。实际的尺寸可以随成本,所需分辨率,空间等因素而变化。16(a) to 16(d) show various arrangements of information light sources. Fig. 16 (a) represents the information light source configured as LED or diode laser matrix 166; Fig. 16 (b) represents the information light source configured as liquid crystal light valve 160 with backside illumination 168; Fig. 16 (c) represents the configuration as cathode ray tube 170; and FIG. 16(d) shows an information light source configured as an array of fiber optic cable ends 172. The size of each cell 174 in the array or matrix is exaggerated for ease of illustration. Actual dimensions may vary with cost, required resolution, space, etc.

Claims (38)

1. one kind is utilized micro-capsule to encapsulate the printer that electric active material is made electron device, it is characterized in that:
The attraction field element of locally variable;
Control the control device that locally variable attracts an element, be used for adding selectively the attraction field and arrive each position that locally variable attracts an element, so can make a field attraction microcapsule layer,
The field attracts the micro-capsule feeding mechanism of micro-capsule, and described attracts micro-capsule to comprise electric active material, is used to be attracted to the described position, attraction field that attracts the field element;
Thereby can attract the composition of microcapsule layer and size to make predetermined electronic circuit component according to the field.
2. make the printer of electron device according to claim 1, wherein the attraction field element of locally variable also comprises: at least one the photoelectricity coating or the optomagnetic coating that form on substrate are used to respond and incide the light at least one photoelectricity coating or the optomagnetic coating and produce and attract.
3. make the printer of electron device according to claim 2, wherein at least one photoelectricity coating or optomagnetic coating are etched into pixel.
4. make the printer of electron device according to claim 2, also comprise: lead beam incides the guiding device of a few photoelectricity coating or optomagnetic coating, be used to produce at least one magnetic field or electrostatic field, in order that on the corresponding discrete location of at least one photoelectricity coating or optomagnetic coating, form attraction field separately.
5. make the printer of electron device according to claim 4, wherein guiding device comprises: a plurality of fiber optical waveguides.
6. make the printer of electron device according to claim 4, wherein guiding device also comprises: produce the light beam source of light beam and the scanister of scanning light beam at least one photoelectricity coating or optomagnetic coating, be used for producing the attraction field, in order that on the corresponding discrete location of at least one photoelectricity coating or optomagnetic coating, form attraction field separately.
7. make the printer of electron device according to claim 2, wherein the attraction field element of locally variable also comprises: produce the luminescent coating of light on the substrate, the light of generation incides at least one photoelectricity coating or the optomagnetic coating to produce at least one electrostatic attraction field or magnetic attachment field.
8. make the printer of electron device according to claim 1, it is the magnetic attachment micro-capsule that its midfield attracts micro-capsule; And the attraction field element of locally variable also comprises: add magnetic field device, be used to add each local attraction field as the magnetic attachment field.
9. make the printer of electron device according to claim 1, it is the electrostatic attraction micro-capsule that its midfield attracts micro-capsule; And the attraction field element of locally variable also comprises: add static field device, be used to add each local attraction field as the electrostatic attraction field.
10. make the printer of electron device according to claim 1, wherein at least some attract micro-capsule to comprise a thermal expansion composition or hot fusible composition at least.
11. a method of making display, it has the element that utilizes Method of printing to make, and its feature may further comprise the steps: the bearing substrate of supporting structure is provided, utilizes Method of printing to make element on this bearing substrate; Making comprises the display layer of light emitting pixel, is used for display message, and light emitting pixel is to make by the pixel graphics of printing the luminous current-conducting polymer microcapsule; Making comprises the electronic circuit layer of electron device, and it is to print electricity activation micro-capsule figure to make on the discrete location of bearing substrate; Make the user's input layer that receives user's input and produce user input signal, make user's input layer by printing the conductive element grid, when passing conductive element in magnetic field, each conductive element produces detectable electric signal; With the making battery layers, be used to provide electric energy to the electronic circuit layer elements, user's input layer element and display layer element.
12. according to the method that claim 11 is made display, wherein battery layers comprises: first current collection layer; In anode layer of on first current collection layer, printing and the cathode layer one; The dielectric substrate of printing on described one in anode layer and cathode layer; With another and described second current collection layer of printing on another in anode layer and cathode layer in anode layer of on dielectric substrate, printing and the cathode layer.
13. make the method for display according to claim 11, wherein display layer comprises the conductive lead wire that is connected with each light emitting pixel, under the control of display driver element, add electric energy selectively to each light emitting pixel, light emitting pixel is made like this, and insulation course is provided, and prints the y electrode layer that comprises the conductive material line on insulation course, on the y electrode layer, print the pixel layer of luminous current-conducting polyidal field and on pixel layer, print the x electrode layer that comprises the transparent conductive material line.
14. make the method for display according to claim 11, wherein the electronic circuit layer comprises signal receiving element, it comprises: the first radio frequency receiving element, be used to receive first shows signal with first display message of on first radio frequency, carrying, with the second radio frequency receiving element, be used to receive second shows signal with second display message of on second radio frequency, carrying, with the display driver element that comprises the signal processor element, be used to receive first shows signal and second shows signal and produce display drive signals, can show demonstration second display message on first display message and the second place on the primary importance of display layer simultaneously at display layer.
15. the method for making display according to claim 11, battery layers wherein, display layer, at least some elements are by printing electric active material to make circuit component in user's input layer and the electronic circuit layer, and it comprises: resistor, capacitor, inductor, antenna, conductor and semiconductor devices.
16. one kind is utilized micro-capsule to encapsulate the method that electric active material is made electron device, its feature may further comprise the steps: the substrate that upper surface is arranged as supporting structure is provided, utilizes the micro-capsule Method of printing to make element on this substrate; Attract the discrete location of an attraction microcapsule layer to substrate, an attraction micro-capsule comprises electric active material, thereby can attract the composition of microcapsule layer and size to make predetermined electronic circuit component according to the field.
17. according to the method that claim 16 is made electron device, wherein electric active material has conductor, insulator, resistor, semiconductor, inductor, magnetic material, piezoelectric, photoelectric material, or at least a electrical properties in the thermoelectric material.
18. make the method for electron device according to claim 16, its midfield attracts microcapsule layer the many levels micro-capsule to be arranged to form desired three dimensional shape, therefore, electronic circuit component have with pile up microcapsule layer in the composition electrical properties relevant of many levels with the 3D shape size.
19. a display, it has the element that utilizes Method of printing to make, and it is characterized in that: as supporting structure the flexible substrate of upper surface is arranged, utilize Method of printing to make element on this substrate; Comprise the display layer of light emitting pixel, be used for display message, light emitting pixel is to make by the pixel layer of printing the luminous current-conducting polymkeric substance; The electronic circuit layer, it comprises: the signal radiated element, be used to launch the display message that user input signal is launched from the shows signal generating means with control to the shows signal generating means, signal receiving element, be used to receive display message from the emission of shows signal generating means, with the display driver element, drive display layer according to the display message that receives; User's input layer is used to receive user's input and produces user input signal; Battery layers is used to provide electric energy to the electronic circuit layer elements, user's input layer element and display layer element.
20. according to the display of claim 19, wherein battery layers comprises: first current collection layer; Anode layer; Dielectric substrate, it comprises liquid electric conductivity electrolysis matter and forms the polymkeric substance of leakproof dielectric substrate; The cathode layer and second current collection layer, wherein said battery layers basically forms the entire upper surface at flexible substrate.
21. according to the display of claim 19, wherein user's input layer comprises: conductive element grid, each conductive element are used to bring out the magnetic field of detectable electric signal with responsive movement.
22. according to the display of claim 19, wherein user's input layer comprises: touch-screen, it is to print pressure-sensitive on insulation course or the capacitance-sensitive element is made.
23. according to the display of claim 19, wherein display layer comprises: the conductive lead wire that is connected with each light emitting pixel under the control of display driver element, adds electric energy selectively to each light emitting pixel.
24. display according to claim 19, wherein signal receiving element comprises: the first radio frequency receiving element, be used to receive first shows signal of carrying first display message on first radio frequency, with the second radio frequency receiving element, be used to receive second shows signal of carrying second display message on second radio frequency, and wherein the display driver element comprises: Signal Processing Element, be used to receive first shows signal and second shows signal and produce display drive signals, can show demonstration second display message on first display message and the second place on the primary importance of display layer simultaneously at display layer.
25. according to the display of claim 19, battery layers wherein, display layer, at least some elements are by printing electric active material to make circuit component in user's input layer and the electronic circuit layer, and it comprises: resistor, capacitor, inductor, antenna, conductor and semiconductor devices.
26. a display, the element that it has the Method of printing system of utilization to make is characterized in that: as supporting structure the flexible substrate of upper surface is arranged, utilize Method of printing can make element on flexible substrate; The display layer that comprises light emitting pixel, be used for display message, light emitting pixel is made like this, insulation course is provided, on insulation course, print the y electrode layer that comprises the conductive material line, on the y electrode layer, print the pixel layer of luminous current-conducting polyidal field and on pixel layer, print the x electrode layer that comprises the transparent conductive material line; The electronic circuit layer comprises: the signal radiated element, be used to launch user input signal, and signal receiving element is used to receive display message and display driver element, drives display layer according to the display message that receives; User's input layer is used to receive user's input and produces user input signal; Battery layers is used to provide electric energy to the electronic circuit layer elements, user's input layer element and display layer element.
27. according to the display of claim 26, wherein battery layers comprises: first current collection layer of on the flexible insulation substrate, printing; In anode layer of on first current collection layer, printing and the cathode layer one; The micro-capsule encapsulation dielectric substrate of printing on described in anode layer and cathode layer; With in anode layer of on dielectric substrate, printing and the cathode layer another; With described second current collection layer of printing on another in anode layer and cathode layer; Wherein said battery layers basically forms the entire upper surface at flexible substrate.
28. according to the display of claim 26, wherein user's input layer comprises: printed conductive unit grid on the insulation course, described conductive element is used to bring out the magnetic field of detectable electric signal with responsive movement.
29. according to the display of claim 28, wherein each described conductive element is made coil shape.
30. according to the display of claim 26, wherein display layer comprises: the printing conductive lead wire that is connected with each light emitting pixel under the control of display driver element, adds electric energy selectively to each light emitting pixel.
31. display according to claim 26, wherein signal receiving element comprises: the first radio frequency receiving element, be used to receive first shows signal of carrying first display message on first radio frequency, with the second radio frequency receiving element, be used to receive second shows signal of carrying second display message on second radio frequency, and wherein the display driver element comprises: Signal Processing Element, be used to receive first shows signal and second shows signal and produce display drive signals, can show demonstration second display message on first display message and the second place on the primary importance of display layer simultaneously at display layer.
32. according to the display of claim 26, battery layers wherein, display layer, at least some elements are by printing electric active material to make circuit component in user's input layer and the electronic circuit layer, and it comprises: resistor, capacitor, inductor, antenna, conductor and semiconductor devices.
33. a display, it has the element that utilizes Method of printing to make, and it is characterized in that: the flexible substrate as supporting structure is provided, utilizes Method of printing to make element on this substrate; Comprise the display layer of light emitting pixel, be used for display message, light emitting pixel is to make by the pixel layer of printing the luminous current-conducting polymkeric substance; Comprise the electronic circuit layer that the user imports the mapping element, be used to receive user input signal and determine to receive on the display physical location of user input signal and the user input signal of generation mapping; The signal radiated element is used to launch the user input signal of mapping; Signal receiving element is used to receive display message; With the display driver element, drive display layer according to the display message that receives; User's input layer is used to receive user's input and produces user input signal; Battery layers is used to provide electric energy to the electronic circuit layer elements, user's input layer element and display layer element.
34. according to the display of claim 33, wherein battery layers comprises: first current collection layer of on the flexible insulation substrate, printing; In anode layer of on first current collection layer, printing and the cathode layer one; The dielectric substrate of printing on described one in anode layer and cathode layer; With in anode layer of on dielectric substrate, printing and the cathode layer another; With described second current collection layer of printing on another in anode layer and cathode layer.
35. according to the display of claim 33, wherein user's input layer comprises: printed conductive unit grid on the insulation course, described conductive element is used to bring out the magnetic field of detectable electric signal with responsive movement.
36. display according to claim 33, wherein display layer comprises: the printing conductive lead wire that is connected with each light emitting pixel, under the control of display driver element, add electric energy selectively to each light emitting pixel, light emitting pixel is made like this, and insulation course is provided, and prints the y electrode layer that comprises the conductive material line on insulation course, on the y electrode layer, print the pixel layer of luminous current-conducting polyidal field and on pixel layer, print the x electrode layer that comprises the transparent conductive material line.
37. display according to claim 33, wherein signal receiving element comprises: the first radio frequency receiving element, be used to receive first shows signal of carrying first display message on first radio frequency, with the second radio frequency receiving element, be used to receive second shows signal of carrying second display message on second radio frequency, and wherein the display driver element comprises: Signal Processing Element, be used to receive first shows signal and second shows signal and produce display drive signals, can show demonstration second display message on first display message and the second place on the primary importance of display layer simultaneously at display layer.
38. according to the display of claim 37, battery layers wherein, display layer, at least some elements are by printing electric active material to make circuit component in user's input layer and the electronic circuit layer, and it comprises: resistor, capacitor, inductor, antenna, conductor and semiconductor devices.
CNB03821069XA 2002-09-04 2003-09-02 Printer and method of manufacturing electronic circuit and display Expired - Fee Related CN100419845C (en)

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US10/234,301 US20040043139A1 (en) 2002-09-04 2002-09-04 Printer and method for manufacturing electronic circuits and displays
US10/234,302 US7161590B2 (en) 2002-09-04 2002-09-04 Thin, lightweight, flexible, bright, wireless display
US10/234,301 2002-09-04

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KR20050057192A (en) 2005-06-16
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AU2003270067A8 (en) 2004-03-29

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