CN1308861A - Benzoylphenyl carbamides insecticides - Google Patents
Benzoylphenyl carbamides insecticides Download PDFInfo
- Publication number
- CN1308861A CN1308861A CN 00101299 CN00101299A CN1308861A CN 1308861 A CN1308861 A CN 1308861A CN 00101299 CN00101299 CN 00101299 CN 00101299 A CN00101299 A CN 00101299A CN 1308861 A CN1308861 A CN 1308861A
- Authority
- CN
- China
- Prior art keywords
- carbamides
- benzoylphenyl
- filler
- avermectin
- insecticides
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000013877 carbamide Nutrition 0.000 title claims abstract description 27
- 239000002917 insecticide Substances 0.000 title claims abstract description 22
- -1 Benzoylphenyl carbamides Chemical class 0.000 title claims abstract description 21
- 235000013311 vegetables Nutrition 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 4
- 239000005660 Abamectin Substances 0.000 claims description 22
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 14
- 239000000945 filler Substances 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 239000004202 carbamide Substances 0.000 claims description 9
- 239000005893 Diflubenzuron Substances 0.000 claims description 8
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical group FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 claims description 8
- 229940019503 diflubenzuron Drugs 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- XYFMGGWVGACNEC-UHFFFAOYSA-N n-carbamoyl-n-phenylbenzamide Chemical compound C=1C=CC=CC=1N(C(=O)N)C(=O)C1=CC=CC=C1 XYFMGGWVGACNEC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000005942 Triflumuron Substances 0.000 claims description 3
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000000375 suspending agent Substances 0.000 claims description 3
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 229960000892 attapulgite Drugs 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000006184 cosolvent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000012764 mineral filler Substances 0.000 claims description 2
- 229910052625 palygorskite Inorganic materials 0.000 claims description 2
- 229910052903 pyrophyllite Inorganic materials 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 235000012222 talc Nutrition 0.000 claims description 2
- 241000607479 Yersinia pestis Species 0.000 abstract description 6
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract description 2
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 2
- 241000209140 Triticum Species 0.000 abstract description 2
- 235000021307 Triticum Nutrition 0.000 abstract description 2
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 235000009566 rice Nutrition 0.000 abstract description 2
- 241000219146 Gossypium Species 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000004495 emulsifiable concentrate Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000725 suspension Substances 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- 230000000749 insecticidal effect Effects 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 210000000481 breast Anatomy 0.000 description 6
- 238000009313 farming Methods 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical group O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YPSCQJTUAKNUNF-UHFFFAOYSA-N 2-chloro-n-[(4-chlorophenyl)carbamoyl]benzamide Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl YPSCQJTUAKNUNF-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 101000989653 Homo sapiens Membrane frizzled-related protein Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 102000003960 Ligases Human genes 0.000 description 1
- 108090000364 Ligases Proteins 0.000 description 1
- 102100029357 Membrane frizzled-related protein Human genes 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000187747 Streptomyces Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- PXZAWHSJYIECNQ-UHFFFAOYSA-N apholate Chemical compound C1CN1P1(N2CC2)=NP(N2CC2)(N2CC2)=NP(N2CC2)(N2CC2)=N1 PXZAWHSJYIECNQ-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A benzoylphenyl carbamides insecticide for controlling the pests of vegetables, fruit tree, cotton, wheat, rice, etc is prepared from different two insecticides. Its advantages are different forms including suspension, emulsifiable concentrate, wettable powder, particles and emulsion, high effect and no environmental pollution.
Description
The invention belongs to the composite processing technique field of agricultural insecticide formulation.
Benzoyl phenyl urea insecticide is the steroids insect growth regulator, IGR of the exploitation seventies, can suppress the formation of insect chitin synthetase, disturbs the deposition of chitin in epidermis, causes insect normally not cast off a skin and death.Have efficient, low toxicity, low-residual, characteristics such as long and high selectivity of lasting period.Target insect had tag and stomach poison function.It is influential that adult pest is laid eggs, and can be used as the apholate of insect.Non-target insect is not had injury, and free from environmental pollution to people, animal safety, killed natural enemies except that lepidoptera pest is had the special efficacy, does not have good preventive effect to diptera and coleopteran pest yet.
The insecticide of benzoyl phenyl ureas; China succeeds in developing in the eighties to the nineties and has carried out large-area applying, and principal item has the young urea (chlorbenzuron) that goes out, diflubenzuron (diflubenzuron), kills bell urea (triflumuron), fluorine bell urea (hexaflumuron) four strains.Because it is slower that this class medicament is knocked down the speed of killing worm, numerous users are not easy to accept, and owing to large tracts of land, long-term, the independent use, are easy to make insect to produce resistance again.
Avermectin (Avermectin) is a kind of macrolide antibiotic class insecticidal/acaricidal agent, and by Japanese scientist big village intelligence and the cooperative development of U.S. Merck company, through explained hereafter such as fermented extracted, its main active ingredient is Avermectin B
1(abamectin).China introduce to separate Avermectin from the end of the eighties and produces plain bacterial classification (Streptomyces avermitills), and through carrying out the research of aspects such as mutation breeding, zymotechnique, extraction is refining, technology is mature on the whole.Avermectin can effectively be prevented and treated various pests and evil mite, is a kind of antibiotics harmless boilogical agricultural chemicals of efficient, wide spectrum.
Avermectin has begun large scale application in China, because manufacturing cost is higher, price is higher at present, causes the peasant to use other high toxicant in use instead owing to the expenses for prevention and control of unit are is excessive, and the popularization of this agent is restricted; Large tracts of land, long-term, use separately also make insect produce resistance easily.
The objective of the invention is the deficiency in order to overcome above-mentioned two kinds of insecticides and to use separately; the composite insecticidal preparation of benzoyl phenyl ureas and Avermectin has been proposed; two kinds of dissimilar insecticides mix according to a certain percentage, and its insecticidal effect can general performance be synergy, addition or antagonism generally.And the mixed preparation of benzoyl phenyl ureas and Avermectin shows as synergy or summation action, has improved insecticidal effect in the use, has reduced use cost, stops and delayed the development of resistance, has enlarged the scope of application.
The present invention is according to different purposes, using method and controlling object, select to add different auxiliary agent or filler, can be processed into suspending agent (SC), missible oil (EC), wetting powder (WP), suspended emulsion (SE), water dispersible granules (WG) to this mix preparation.
Complex preparation of the present invention, its formula range is:
Active ingredient (benzoyl phenyl ureas and Avermectin total amount) 0.15～40%
Auxiliary agent, filler 98.85～60%
In complex preparation of the present invention, the amount ranges of benzoyl phenyl ureas and Avermectin is respectively 0.1～30% and 0.05～10%.
In the preparation of the present invention, the used kind of benzoyl phenyl ureas mainly adopts that China produces voluntarily and belongs to kind efficiently, and they are respectively diflubenzurons (diflubenzuron), kill bell urea (triflumuron), fluorine bell urea (hexaflumuron).
Used auxiliary agent has solvent, cosolvent, surfactant, sticker, dispersant, stabilizing agent, safener, synergist etc. in the preparation, and commonly used have dimethylbenzene, dimethyl formamide, a farming breast 2201
#, farming breast 100
#, farming breast 500
#, farming breast 602
#, farming breast 603
#, farming breast 1600
#, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, neopelex, NNO, Sopa etc.; Used filler has vegetable filler, mineral filler, chemical earthfill rockfill concrete riprap RCC, and filler commonly used mainly contains following several: diatomite, talcum and pyrophyllite, crystallite Argilla, kaolin, Emathlite, bentonite, CaCO
3, NaHCO
3, attapulgite, white carbon, compounded mix.
Various auxiliary agents and filler can be published referring to pesticide processing book series " insecticides adjuvant " 1994 chemical industry publishing houses.
Various auxiliary agents and filler be available wherein one or more in the different dosage form of said preparation, and various auxiliary agents can use separately or compound use, decide according to concrete formulation content and purposes.
A kind of embodiment below is provided, but is not limited thereto:
Embodiment 1: diflubenzuron 15%, and Avermectin 0.5%, NNO 2.5%, calcium lignosulfonate (sodium) 2.5%, white carbon 3%, 2201 emulsifier 2.0%, ethylene glycol 5%, water complements to 100%, makes 15.5% suspending agent.
Embodiment 2: diflubenzuron 18.8%, and Avermectin 0.2%, NNO 4%, lauryl sodium sulfate 3%, white carbon 10%, diatomite complements to 100%, makes 20% wetting powder.
Embodiment 3: diflubenzuron 4.8%, and Avermectin 0.2%, dimethyl formamide 30%, 2201 compound emulsifying agent such as grade 15%, dimethylbenzene complements to 100%, makes 5% missible oil.
Embodiment 4: fluorine bell urea 3%, and Avermectin 0.5%, dimethyl formamide 30%, 2201 compound emulsifying agent such as grade 12%, dimethylbenzene complements to 100%, makes 3.5% missible oil.
Embodiment 5; Kill bell urea 15%, Avermectin 0.5%, compound emulsifying agent (0207+2201) 8%, NNO2%, from carbon black+CMC 2.5%, ethylene glycol 5%, water complements to 100%, makes 15.5% suspended emulsion.
The present invention shows through field control effectiveness test, uses the composite insecticidal preparation control diamond-back moth of benzoyl phenyl urea insecticide and Avermectin, has significant synergies.
The composite insecticidal preparation of benzoyl phenyl urea insecticide and Avermectin, two kinds of active ingredients are public nuisance-free agricultural chemicals, and the application of said preparation helps the production of pollution-free vegetable, also is one of main means that prolong two kinds of single agent service lifes.
The composite insecticidal preparation of benzoyl phenyl urea insecticide and Avermectin is mainly used in insect pests such as control vegetables, fruit tree, cotton, wheat, paddy rice.
Claims (7)
1, a kind of Benzoylphenyl carbamides insecticides is characterized in that active ingredient is made up of benzoyl phenyl urea insecticide and Avermectin (Avermectin), and all the other are auxiliary agent, filler.
2, Benzoylphenyl carbamides insecticides according to claim 1 is characterized in that formula range is as follows:
Active ingredient (benzoyl phenyl ureas and Avermectin total amount) 0.15～40%
Auxiliary agent, filler 98.85～60%
3, Benzoylphenyl carbamides insecticides according to claim 1 and 2 is characterized in that benzoyl phenyl ureas amount ranges is 0.1～30%.
4, Benzoylphenyl carbamides insecticides according to claim 1 and 2, the amount ranges that it is characterized in that Avermectin is 0.05～10%.
5, Benzoylphenyl carbamides insecticides according to claim 1 and 2 is characterized in that said preparation is suspending agent, missible oil, wetting powder, water dispersible granules, suspended emulsion.
6, Benzoylphenyl carbamides insecticides according to claim 1 and 2 is characterized in that benzoyl phenyl urea insecticide is diflubenzuron (diflubenzuron), fluorine bell urea (hexaflumuron), kills a kind of in the bell urea (triflumuron).
7, Benzoylphenyl carbamides insecticides according to claim 1 and 2 is characterized in that auxiliary agent used in the preparation has solvent, cosolvent, surfactant, sticker, dispersant, stabilizing agent, safener, synergist etc.; Used filler has vegetable filler, mineral filler, chemical earthfill rockfill concrete riprap RCC, and filler commonly used mainly contains following several: diatomite, talcum and pyrophyllite, crystallite Argilla, kaolin, Emathlite, bentonite, CaCO
3, NaHCO
3, attapulgite, white carbon, compounded mix.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00101299 CN1308861A (en) | 2000-02-16 | 2000-02-16 | Benzoylphenyl carbamides insecticides |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00101299 CN1308861A (en) | 2000-02-16 | 2000-02-16 | Benzoylphenyl carbamides insecticides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1308861A true CN1308861A (en) | 2001-08-22 |
Family
ID=4575862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00101299 Pending CN1308861A (en) | 2000-02-16 | 2000-02-16 | Benzoylphenyl carbamides insecticides |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1308861A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101185436B (en) * | 2007-11-21 | 2010-12-01 | 张少武 | Chlorbenzuron water-dispersing granules preparation |
| CN102037954A (en) * | 2010-12-23 | 2011-05-04 | 海南正业中农高科股份有限公司 | Hexaflumuron suspended emulsion |
| CN101658166B (en) * | 2008-08-27 | 2013-02-20 | 北京广源益农化学有限责任公司 | Triflumuron water dispersible granule and method for preparing same |
| CN101530086B (en) * | 2008-03-14 | 2013-03-13 | 北京绿色农华植保科技有限责任公司 | Chlorbenzuron suspending agent and preparation method thereof |
| CN105707101A (en) * | 2016-04-13 | 2016-06-29 | 南通清安健无水印染研究所（普通合伙） | Preparation method of microencapsulated powder for controlling root-knot nematodes of vegetables in greenhouses |
| CN106035356A (en) * | 2016-06-06 | 2016-10-26 | 南通伟德动力电池研究所（普通合伙） | Preparation method for trunk injecting microcapsule pesticide for controlling Bursaphelenchus xylophilus |
| US9730453B2 (en) | 2008-12-31 | 2017-08-15 | Makhteshim Chemical Works Ltd. | Method for controlling insects in plants |
| WO2019005700A1 (en) * | 2017-06-26 | 2019-01-03 | Merial, Inc. | Dual active parasiticidal granule compositions, methods and uses thereof |
-
2000
- 2000-02-16 CN CN 00101299 patent/CN1308861A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101185436B (en) * | 2007-11-21 | 2010-12-01 | 张少武 | Chlorbenzuron water-dispersing granules preparation |
| CN101530086B (en) * | 2008-03-14 | 2013-03-13 | 北京绿色农华植保科技有限责任公司 | Chlorbenzuron suspending agent and preparation method thereof |
| CN101658166B (en) * | 2008-08-27 | 2013-02-20 | 北京广源益农化学有限责任公司 | Triflumuron water dispersible granule and method for preparing same |
| US9730453B2 (en) | 2008-12-31 | 2017-08-15 | Makhteshim Chemical Works Ltd. | Method for controlling insects in plants |
| CN102037954A (en) * | 2010-12-23 | 2011-05-04 | 海南正业中农高科股份有限公司 | Hexaflumuron suspended emulsion |
| CN102037954B (en) * | 2010-12-23 | 2013-07-10 | 海南正业中农高科股份有限公司 | Hexaflumuron suspended emulsion |
| CN105707101A (en) * | 2016-04-13 | 2016-06-29 | 南通清安健无水印染研究所（普通合伙） | Preparation method of microencapsulated powder for controlling root-knot nematodes of vegetables in greenhouses |
| CN106035356A (en) * | 2016-06-06 | 2016-10-26 | 南通伟德动力电池研究所（普通合伙） | Preparation method for trunk injecting microcapsule pesticide for controlling Bursaphelenchus xylophilus |
| WO2019005700A1 (en) * | 2017-06-26 | 2019-01-03 | Merial, Inc. | Dual active parasiticidal granule compositions, methods and uses thereof |
| US11147273B2 (en) | 2017-06-26 | 2021-10-19 | Boehringer Ingelheim Animal Health USA Inc. | Dual active parasiticidal granule compositions, methods and uses thereof |
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