CN1092246C - 对含铝金属材料进行表面处理的聚合物组合物及方法 - Google Patents
对含铝金属材料进行表面处理的聚合物组合物及方法 Download PDFInfo
- Publication number
- CN1092246C CN1092246C CN95103820A CN95103820A CN1092246C CN 1092246 C CN1092246 C CN 1092246C CN 95103820 A CN95103820 A CN 95103820A CN 95103820 A CN95103820 A CN 95103820A CN 1092246 C CN1092246 C CN 1092246C
- Authority
- CN
- China
- Prior art keywords
- surface treatment
- water
- phosphate ion
- containing metal
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007769 metal material Substances 0.000 title claims description 56
- 229910052782 aluminium Inorganic materials 0.000 title claims description 53
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims description 49
- 239000000203 mixture Substances 0.000 title claims description 46
- 238000000034 method Methods 0.000 title claims description 35
- 229920000642 polymer Polymers 0.000 title abstract description 41
- 238000004381 surface treatment Methods 0.000 claims abstract description 104
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 59
- 229940085991 phosphate ion Drugs 0.000 claims abstract description 43
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 43
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 15
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 15
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 13
- 238000001035 drying Methods 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims description 71
- 239000011248 coating agent Substances 0.000 claims description 68
- 239000000243 solution Substances 0.000 claims description 63
- 239000007864 aqueous solution Substances 0.000 claims description 59
- 229920005989 resin Polymers 0.000 claims description 55
- 239000011347 resin Substances 0.000 claims description 55
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 40
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 20
- -1 phosphate anion Chemical class 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 11
- 238000005507 spraying Methods 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 239000010452 phosphate Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- 239000004254 Ammonium phosphate Substances 0.000 claims description 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 238000006068 polycondensation reaction Methods 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 6
- 238000006424 Flood reaction Methods 0.000 claims 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 229920000137 polyphosphoric acid Polymers 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 15
- 125000000217 alkyl group Chemical group 0.000 abstract description 9
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- 150000002500 ions Chemical class 0.000 description 27
- 229910000838 Al alloy Inorganic materials 0.000 description 20
- 125000001424 substituent group Chemical group 0.000 description 20
- 238000005260 corrosion Methods 0.000 description 19
- 239000007787 solid Substances 0.000 description 14
- 238000007739 conversion coating Methods 0.000 description 13
- 238000006116 polymerization reaction Methods 0.000 description 13
- 230000007797 corrosion Effects 0.000 description 12
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 11
- 229940048086 sodium pyrophosphate Drugs 0.000 description 11
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 11
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 11
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 239000003973 paint Substances 0.000 description 9
- 238000006467 substitution reaction Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000005530 etching Methods 0.000 description 6
- 235000021317 phosphate Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000002738 chelating agent Substances 0.000 description 4
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- WMYWOWFOOVUPFY-UHFFFAOYSA-L dihydroxy(dioxo)chromium;phosphoric acid Chemical compound OP(O)(O)=O.O[Cr](O)(=O)=O WMYWOWFOOVUPFY-UHFFFAOYSA-L 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000013256 coordination polymer Substances 0.000 description 3
- 229920001795 coordination polymer Polymers 0.000 description 3
- KHEMNHQQEMAABL-UHFFFAOYSA-J dihydroxy(dioxo)chromium Chemical compound O[Cr](O)(=O)=O.O[Cr](O)(=O)=O KHEMNHQQEMAABL-UHFFFAOYSA-J 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 229910000914 Mn alloy Inorganic materials 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000009924 canning Methods 0.000 description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 229940048084 pyrophosphate Drugs 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000012756 surface treatment agent Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- XFNGYPLLARFULH-UHFFFAOYSA-N 1,2,4-oxadiazetidin-3-one Chemical compound O=C1NON1 XFNGYPLLARFULH-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 150000001555 benzenes Chemical group 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229910000151 chromium(III) phosphate Inorganic materials 0.000 description 1
- IKZBVTPSNGOVRJ-UHFFFAOYSA-K chromium(iii) phosphate Chemical compound [Cr+3].[O-]P([O-])([O-])=O IKZBVTPSNGOVRJ-UHFFFAOYSA-K 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000013527 degreasing agent Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920001523 phosphate polymer Polymers 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
- C23C22/23—Condensed phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6077219A JP2771110B2 (ja) | 1994-04-15 | 1994-04-15 | アルミニウム含有金属材料用表面処理組成物および表面処理方法 |
| JP77219/94 | 1994-04-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1112166A CN1112166A (zh) | 1995-11-22 |
| CN1092246C true CN1092246C (zh) | 2002-10-09 |
Family
ID=13627747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95103820A Expired - Fee Related CN1092246C (zh) | 1994-04-15 | 1995-04-14 | 对含铝金属材料进行表面处理的聚合物组合物及方法 |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0757725B1 (pt) |
| JP (1) | JP2771110B2 (pt) |
| KR (1) | KR0179685B1 (pt) |
| CN (1) | CN1092246C (pt) |
| AT (1) | ATE184331T1 (pt) |
| BR (1) | BR9507365A (pt) |
| CA (1) | CA2187795A1 (pt) |
| DE (1) | DE69512049T2 (pt) |
| ES (1) | ES2136844T3 (pt) |
| MY (1) | MY113052A (pt) |
| TW (1) | TW404975B (pt) |
| WO (1) | WO1995028509A1 (pt) |
| ZA (1) | ZA953031B (pt) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2226524A1 (en) * | 1995-07-10 | 1997-01-30 | Toshiaki Shimakura | Metal surface treatment agent and method and metallic materials treated with the same |
| JP3620893B2 (ja) * | 1995-07-21 | 2005-02-16 | 日本パーカライジング株式会社 | アルミニウム含有金属用表面処理組成物及び表面処理方法 |
| US6059896A (en) * | 1995-07-21 | 2000-05-09 | Henkel Corporation | Composition and process for treating the surface of aluminiferous metals |
| JP3544761B2 (ja) * | 1995-10-13 | 2004-07-21 | 日本パーカライジング株式会社 | アルミニウム含有金属材料用表面処理組成物および表面処理方法 |
| DE19621184A1 (de) * | 1996-05-28 | 1997-12-04 | Henkel Kgaa | Zinkphosphatierung mit integrierter Nachpassivierung |
| JPH101782A (ja) * | 1996-06-13 | 1998-01-06 | Nippon Paint Co Ltd | 金属表面処理剤、処理方法及び表面処理された金属材料 |
| JPH1046101A (ja) * | 1996-08-01 | 1998-02-17 | Nippon Parkerizing Co Ltd | 金属材料の表面にフィルムラミネート用下地皮膜を形成させた被覆金属材料、およびその製造方法 |
| JPH10182916A (ja) * | 1996-10-21 | 1998-07-07 | Nippon Paint Co Ltd | Ｎ複素環を含むアクリル樹脂含有金属表面処理組成物、処理方法及び処理金属材料 |
| FR2769325B1 (fr) * | 1997-10-08 | 1999-12-03 | Cfpi Ind | Bain acide pour la phosphatation au zinc de substrats metalliques, concentre pour la preparation du bain et procede de phosphatation le mettant en oeuvre |
| JPWO2002061175A1 (ja) * | 2001-01-31 | 2004-06-03 | 日本パーカライジング株式会社 | 金属材料用表面処理剤および表面処理方法 |
| JP2004076024A (ja) * | 2002-08-09 | 2004-03-11 | Nippon Paint Co Ltd | アルミニウム系基材の処理方法及び製品 |
| JP2010013677A (ja) | 2008-07-01 | 2010-01-21 | Nippon Parkerizing Co Ltd | 金属構造物用化成処理液および表面処理方法 |
| CN102983419A (zh) * | 2011-09-07 | 2013-03-20 | 崔骥 | 一种接地器件以及接地方法 |
| CN106591817B (zh) * | 2016-11-08 | 2019-01-29 | 高林 | 无重金属物排放钢铁表面处理液及其制备方法 |
| TWI802600B (zh) * | 2017-10-12 | 2023-05-21 | 日商日本帕卡瀨精股份有限公司 | 表面處理劑、具有表面處理覆膜的罐用鋁合金材料的製造方法以及用其所製的鋁合金罐體及罐蓋 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4433015A (en) * | 1982-04-07 | 1984-02-21 | Parker Chemical Company | Treatment of metal with derivative of poly-4-vinylphenol |
| US4795506A (en) * | 1986-07-26 | 1989-01-03 | Detrex Corporation | Process for after-treatment of metals using 2,2-bis(4-hydroxyphenyl)alkyl poly derivatives |
| JPH03207766A (ja) * | 1990-01-10 | 1991-09-11 | Nippon Parkerizing Co Ltd | ぶりきｄｉ缶の表面処理方法 |
| ATE116694T1 (de) * | 1990-06-19 | 1995-01-15 | Henkel Corp | Behandlungsverfahren von aluminium- oder blechdosen zur erhöhung der korrosionsbeständigkeit und zur verringerung des reibungskoeffizienten und zusammensetzung der behandlungsflüssigkeit. |
| JPH04187782A (ja) * | 1990-11-21 | 1992-07-06 | Nippon Parkerizing Co Ltd | ぶりきｄｉ缶用表面処理液 |
-
1994
- 1994-04-15 JP JP6077219A patent/JP2771110B2/ja not_active Expired - Lifetime
-
1995
- 1995-04-07 EP EP95915455A patent/EP0757725B1/en not_active Expired - Lifetime
- 1995-04-07 ES ES95915455T patent/ES2136844T3/es not_active Expired - Lifetime
- 1995-04-07 CA CA002187795A patent/CA2187795A1/en not_active Abandoned
- 1995-04-07 WO PCT/US1995/003933 patent/WO1995028509A1/en not_active Ceased
- 1995-04-07 DE DE69512049T patent/DE69512049T2/de not_active Expired - Fee Related
- 1995-04-07 AT AT95915455T patent/ATE184331T1/de not_active IP Right Cessation
- 1995-04-07 BR BR9507365A patent/BR9507365A/pt not_active IP Right Cessation
- 1995-04-12 TW TW084103586A patent/TW404975B/zh not_active IP Right Cessation
- 1995-04-12 ZA ZA953031A patent/ZA953031B/xx unknown
- 1995-04-12 MY MYPI95000943A patent/MY113052A/en unknown
- 1995-04-14 CN CN95103820A patent/CN1092246C/zh not_active Expired - Fee Related
- 1995-04-15 KR KR1019950008908A patent/KR0179685B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| TW404975B (en) | 2000-09-11 |
| AU685938B2 (en) | 1998-01-29 |
| DE69512049T2 (de) | 2000-04-27 |
| AU2232995A (en) | 1995-11-10 |
| CN1112166A (zh) | 1995-11-22 |
| JPH07278836A (ja) | 1995-10-24 |
| KR950029375A (ko) | 1995-11-22 |
| JP2771110B2 (ja) | 1998-07-02 |
| EP0757725B1 (en) | 1999-09-08 |
| EP0757725A4 (en) | 1997-07-30 |
| WO1995028509A1 (en) | 1995-10-26 |
| DE69512049D1 (de) | 1999-10-14 |
| ES2136844T3 (es) | 1999-12-01 |
| ATE184331T1 (de) | 1999-09-15 |
| ZA953031B (en) | 1995-12-21 |
| EP0757725A1 (en) | 1997-02-12 |
| CA2187795A1 (en) | 1995-10-26 |
| BR9507365A (pt) | 1997-10-07 |
| KR0179685B1 (ko) | 1999-02-18 |
| MY113052A (en) | 2001-11-30 |
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