CN108849927A - 含有安全剂的农药组合物及其应用 - Google Patents
含有安全剂的农药组合物及其应用 Download PDFInfo
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- CN108849927A CN108849927A CN201710329630.7A CN201710329630A CN108849927A CN 108849927 A CN108849927 A CN 108849927A CN 201710329630 A CN201710329630 A CN 201710329630A CN 108849927 A CN108849927 A CN 108849927A
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- Prior art keywords
- ether
- agent
- herbicidal composition
- polyoxyethylene
- sodium
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- OYIKARCXOQLFHF-UHFFFAOYSA-N isoxaflutole Chemical compound CS(=O)(=O)C1=CC(C(F)(F)F)=CC=C1C(=O)C1=C(C2CC2)ON=C1 OYIKARCXOQLFHF-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000005571 Isoxaflutole Substances 0.000 claims abstract description 28
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- COYBRKAVBMYYSF-UHFFFAOYSA-N heptan-2-yl [(5-chloroquinolin-8-yl)oxy]acetate Chemical group C1=CN=C2C(OCC(=O)OC(C)CCCCC)=CC=C(Cl)C2=C1 COYBRKAVBMYYSF-UHFFFAOYSA-N 0.000 claims abstract description 4
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- ARIWANIATODDMH-UHFFFAOYSA-N rac-1-monolauroylglycerol Chemical compound CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
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- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 5
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- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical group OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims description 4
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical group CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
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- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 claims description 4
- 229940068939 glyceryl monolaurate Drugs 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
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- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明提供了一种除草剂组合物及其应用，所述除草剂组合物的活性成分包括异恶唑草酮和高效异丙甲草胺、异丙甲草胺、异丙草胺、中的一种或多种。本发明组合物中还添加了安全剂，所述安全剂为解草酮、解毒喹、解草唑、解草啶、解草安、肟草安、呋喃解草唑、双苯恶唑酸、吡唑解草酯中的一种或几种。本发明还提供了所述除草剂组合物在防治玉米田一年生及多年生阔叶杂草和禾本科杂草中的应用。本发明的除草剂组合物，较其单剂的除草效果显著提高，表现出极好的增效作用，降低了药剂使用量，在减少农民用药成本的同时，降低对环境的影响。
Description
技术领域
本发明涉及农用除草剂领域，具体地说，涉及一种以异恶唑草酮和高效异丙甲草胺、异丙甲草胺、异丙草胺中的一种或多种为活性成分的除草剂组合物及其应用。
背景技术
异恶唑草酮是由罗纳·普朗克公司开发的异噁唑类除草剂。化学名称为：5-环丙基-1,2-噁唑-4-基(α，α，α，-三氟甲基-2-甲磺酰基对甲苯基)酮，其分子式为C15H12F3NO4S，分子量为359.4，结构式为：
异恶唑草酮是羟基苯基丙酮酸酯双氧化酶抑制剂，即HPPD抑制剂。其作用特点是具有广谱的除草活性、苗前苗后均可使用、杂草出现白化后死亡。虽其症状与类胡萝卜素生物合成抑制剂的作用症状极其相似，但其化学结构特点如极性和电离度与已知的类胡萝卜素生物合成抑制剂等有明显的不同。异恶唑草酮主要经由杂草幼根吸收传导而起作用，敏感杂草吸收了此药以后通过抑制对羟基苯基丙酮酸酯双氧化酶的合成，导致酪氨酸的积累，使质体琨和生育酚的生物合成受阻，进而影响到类胡萝卜素的生物合成。
高效异丙甲草胺是由Syngenta公司开发的氯乙酰胺类除草剂。化学名称为：(aRS,1R)-2-氯-6’-乙基-N-(2-甲氧基-1-甲基乙基)乙酰邻甲苯胺或(aRS,1S)-2-氯-6’-乙基-N-(2-甲氧基-1-甲基乙基)乙酰邻甲苯胺，其分子式为C15H22ClNO2，分子量为283.8，结构式为：
高效异丙甲草胺主要是通过阻碍蛋白质的合成而抑制细胞的生长。通过植物的幼芽即单子叶植物的胚芽鞘、双子叶植物的下胚轴吸收向上传导，种子和根也吸收传导，但吸收量较少，传导速度慢。出苗后主要靠根吸收向上传导，抑制幼芽与根的生长。敏感杂草在发芽后出土前或者刚刚出土立即中毒死亡，表现为牙鞘紧包着生长点，稍变粗，胚根细而弯曲，无须根，生长点逐渐变褐色、黑色烂掉。
异丙甲草胺是由Syngenta公司开发的氯乙酰胺类除草剂。化学名称为：(aRS,1RS)-2-氯-6’-乙基-N-(2-甲氧基-1-甲基乙基)乙酰邻甲苯胺.其分子式为C15H22ClNO2，分子量为283.8，结构式为：
异丙甲草胺主要是通过阻碍蛋白质的合成而抑制细胞的生长。通过植物的幼芽即单子叶植物的胚芽鞘、双子叶植物的下胚轴吸收向上传导，种子和根也吸收传导，但吸收量较少，传导速度慢。出苗后主要靠根吸收向上传导，抑制幼芽与根的生长。敏感杂草在发芽后出土前或者刚刚出土立即中毒死亡，表现为牙鞘紧包着生长点，稍变粗，胚根细而弯曲，无须根，生长点逐渐变褐色、黑色烂掉。
异丙草胺是由匈牙利氮化股份公司开发的氯代乙酰胺类除草剂。化学名称为：2-氯-6’-乙基-N-异丙氧甲基乙酰邻甲苯胺.其分子式为C15H22ClNO2，分子量为283.8，结构式为：
异丙草胺主要是通过阻碍蛋白质的合成而抑制细胞的生长。药剂通过植物幼芽吸收，进入植物体内抑制蛋白酶合成，芽和根停止生长，不定根无法形成。单子叶植物通过胚芽鞘，双子叶植物则经下胚轴吸收，然后向上传导，种子和根也吸收传导，但吸收量较少，传导速度慢，出苗后要靠根吸收向上传导。如果土壤水分适宜杂草幼芽期不出土即被杀死。
解草酮属氯代酰胺类除草剂安全剂由诺华(现Syngenta公司)开发的除草剂解毒剂。化学名称为：(RS)-4-二氯乙酰基-3,4-二氢-3-甲基-2H-1,4-苯并噁嗪.其分子式为C11H11Cl2NO2，分子量为260.1，结构式为：
解毒喹由诺华(现Syngenta公司)开发的除草剂解毒剂。化学名称为：(5-氯喹啉-8-基氧基)乙酸(1-甲基己)酯。其分子式为C18H22ClNO3，分子量为335.8，结构式为：
解草唑由Hoechst AG(现为安万特公司)开发的除草剂解毒剂。化学名称为：1-(2,4-二氯苯基)-5-三氯甲基-1H-1,2,4-三唑-3-羧酸乙酯。其酸分子式为C10H4Cl5N3O2，分子量为375.4，其乙酯分子式为C12H8Cl5N3O2，分子量为375.4，结构式为：
解草啶由由诺华(现Syngenta公司)开发的除草剂解毒剂。化学名称为：4,6-二氯-2-苯基嘧啶。其分子式为C10H6Cl2N2，分子量,225.1，结构式为：
解草安属噻唑羧酸类除草剂安全剂，由孟山都公司开发的除草剂解毒剂。化学名称为：2-氯-4-三氟甲基-1,3-噻唑-5-羧酸苄酯或2-氯-4-三氟甲基噻唑-5-羧酸苄酯.其分子式为C12H7ClF3NO2S，分子量为321.7，结构式为：
肟草安属肟醚类除草剂安全剂，由诺华(现Syngenta公司)开发的除草剂解毒剂。化学名称为：4'-氯-2,2,2-三氟乙酰苯O-1,3-二噁戊环-2-基甲基肟.其分子式为C12H11ClF3NO3，分子量为309.7，结构式为：
呋喃解草唑由Monsanto公司开发的除草剂解毒剂。化学名称为：(RS)-3-二氯乙酰基-5-(2-呋喃基)-2,2-二甲基噁唑烷。其分子式为C11H13Cl2NO3，分子量,278.1，结构式为：
双苯恶唑酸属异噁唑类除草剂安全剂，由安万特公司开发的异噁唑类安全剂。化学名称为：4,5-二氢-5,5-二苯基-1,2-噁唑-3-羧酸.其分子式为C16H13NO3，分子量为267.28，结构式为：
吡唑解草酯由安万特公司开发的除草剂解毒剂。化学名称为：(RS)-1-(2,4-二氯苯基)-5-甲基-2-吡唑啉-3,5-二羧酸二乙酯。其分子式为C16H18Cl2N2O4，分子量为373.2，结构式为：
发明内容
本发明的目的在于提供一种杀草谱广、对阔叶杂草及禾本科杂草具有显著防除效果的除草剂组合物以及所述除草剂组合物的应用。
本发明提供一种除草剂组合物，包括组分A和组分B，其中组分A为异恶唑草酮或高效异丙甲草胺中的一种或多种，组分B为异丙甲草胺、异丙草胺中的一种或多种；
所述组分A和组分B的重量比为1～99：99～1，优选为1～20：20～1；
所述除草剂组合物还包括安全剂，所述安全剂为解草酮、解毒喹、解草唑、解草啶、解草安、肟草安、呋喃解草唑、双苯恶唑酸、吡唑解草酯中的一种或几种。所述安全剂的重量比为0.1％～5％。
本发明的除草剂组合物，还含有至少两种载体，并且其中至少一种为表面活性剂。所述表面活性剂包括乳化剂、分散剂和润湿剂中的一种或几种。
所述乳化剂为苯乙基酚聚氧乙烯聚氧丙稀醚、甘油单月桂酸酯聚氧乙烯醚、苯乙烯基苯酚聚氧乙烯醚、蓖麻油聚氧乙烯醚、乙氧基蓖麻油聚氧乙烯醚、烷基酚聚氧丙烯聚氧乙烯醚、苯乙烯基苯基聚氧乙烯醚、仲辛基酚聚氧乙烯醚、壬基酚聚氧乙烯醚、烷基-二乙二醇醚-磺酸钠、脂肪酸聚乙二醇酯、快渗剂T、苯乙烯基苯酚甲醛树脂聚氧乙烯-聚氧丙烯嵌段型聚醚、失水山梨醇脂肪酸酯聚氧乙烯基醚、脂肪醇聚氧乙烯醚磺酸盐、聚氧乙烯烷基酚甲醛缩合物、十二烷基磺酸钙、癸醇聚氧乙烯醚磺基琥珀酸钠、烷基酚聚氧乙烯醚、甘油三月桂酸酯聚氧乙烯醚、二卞联苯基聚氧乙烯醚、油酸聚乙二醇400酯或脂肪醇聚氧乙烯醚、烷基酚聚氧乙烯醚甲醛缩合物硫酸钠、烷基酚聚氧乙烯醚丁二酸单酯磺酸盐、烷基酚聚氧乙烯磷酸酯、烷基酚聚氧乙烯醚磺化琥珀酸酯、聚氧乙烯脂肪酸脂、聚丙烯酸甲酯、聚氧乙烯脂肪氨、乙氧基蓖麻油、脂肪酸聚氧乙烯醚、聚氧乙烯脂肪醇醚、烷基芳基聚氧乙烯聚氧丙烯醚中的一种或几种；
所述分散剂为亚甲基双萘磺酸钠、亚甲基双甲基萘磺酸钠、聚乙烯吡咯烷酮、木质素磺酸钠、亚甲基二萘磺酸钠(分散剂NNO)、烷酰胺基牛磺酸盐、木质素磺酸钙、聚丙烯酸钠、烷基萘磺酸缩聚物的钠盐和亚甲基双萘磺酸钠甲醛缩合物中的一种或几种；
所述湿润剂为烷基萘磺酸钠、脂肪醇聚氧乙烯醚、仲烷基硫酸钠、十二烷基硫酸钠、十二烷基苯磺酸钠，脂肪醇聚乙二醇醚硫酸盐、壬基酚聚氧乙烯醚、失水山梨醇脂肪酸酯聚氧乙烯醚、烷基萘甲醛缩合物、烷基萘磺酸盐和阴离子润湿剂的混合物。
本发明的除草剂组合物，其还含有除草剂领域常用的制剂用助剂，如溶剂、助溶剂、助悬剂、增稠剂、防冻剂、消泡剂中的一种或几种。
其中，所述溶剂包括有机溶剂、植物油、矿物油、溶剂油或水中的一种或几种；具体地说，所述有机溶剂包括N-甲基吡咯烷酮、四氢呋喃、二甲基亚砜、N,N-二甲基癸酰胺、N,N-二甲基甲酰胺、四氢糠醇、磷酸三丁酯、二甲苯、1，4-二氧六环或环己酮等；所述植物油为环氧大豆油、大豆油、花生油、菜籽油、蓖麻油、玉米油或松籽油等；所述矿物油为液蜡、机油、煤油或润滑油等；所述溶剂油为溶剂油100号、150号、180号或200号等。
上述溶剂也可以作为助溶剂使用。
所述防冻剂包括乙二醇、1,2-丙二醇、硫酸铵、甘油或尿素等。
所述增稠剂包括黄原胶、聚乙烯醇、聚乙二醇、白炭黑、海藻酸钠、硅酸铝镁、硅酸铝钠、羧甲基纤维素、硅藻土、高岭土或有机膨润土。
所述助悬剂为胶体二氧化硅、羧甲基纤维素(CMC)、海藻酸钠或羧甲基纤维素钠等。
所述消泡剂为有机硅氧烷、磷酸三丁酯或硅酮等。
本发明的除草剂组合物的剂型为乳油、水乳剂、浓乳剂、可湿性粉剂、油悬浮剂。上述剂型均可由本领域的常规方法制备。
所述乳油按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂0.5％～30％、助溶剂0％～30％、溶剂补充至100％；
制备方法为：将活性成分、安全剂、乳化剂、助溶剂及溶剂混合，使其成为均匀油相。
所述水乳剂按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂0.5～30％、助溶剂0％～30％、溶剂1％～30％、防冻剂0％～20％、增稠剂0.1％～5％、水补充至100％；
制备方法为：将活性成分、安全剂、乳化剂、助溶剂和溶剂混合，使其成为均匀油相；将水、防冻剂、增稠剂等混合，使其成均匀水相。在高速搅拌下，将水相加入到油相或将油相加入到水相，形成分散性良好的水乳剂。
所述油悬浮剂按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂0.1％～30％、增稠剂0.01％～30％、油补足至100％；
制备方法为：以油为介质，将活性成分、安全剂、表面活性剂和增稠剂等加入砂磨釜中研细，制成油悬浮剂。
所述浓乳剂按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂1％～20％、助溶剂1％～30％、防冻剂1％～20％、增稠剂0.01％～5％，水补充至100％；
本发明的除草组合物的制备方法为：将活性成分、安全剂、助溶剂、乳化剂混合成均匀油相，加入水、防冻剂、增稠剂经高剪切乳化机高速剪切即得浓乳剂。
本发明的除草组合物可以以成品制剂形式提供，即组合物中各物质已经混合；也可以以单独制剂形式提供，使用前在桶或罐中自行混合，其浓缩物通常与水混合得到所需活性物质的浓度。
本发明的除草剂组合物应用于防除玉米田一年生及多年生阔叶杂草、禾本科杂草。
本发明的除草剂组合物，其施用场所为玉米、甜菜、甘蔗、高粱田等作物田地除草，或果园除草等。
本发明的组合物还可以与其它具有除草、杀虫或杀菌性能的化合物特别是茎叶处理的除草剂混合使用，也可与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合使用。
本发明的除草剂组合物使用方法简单，在杂草萌发之前或萌发之后，向作物及作物生长的场所按常规方法施用，如拌土、喷雾、喷射、浇注等，其施用量根据气候条件或作物状态而定，一般在5-200g(a.i.)/亩。本发明的除草剂组合物，其除草效果通常与组合物中单个化合物的含量有关，也与外界因素例如气候有关，但通过使用适当的剂型可以减缓气候的影响。
本发明的除草组合物具有以下优点：
1、异恶唑草酮和高效异丙甲草胺、异丙甲草胺、异丙草胺中的一种或多种组合除草剂在一定配比范围内复配表现出极好的增效作用，与单剂相比明显提高了除草效果，从而降低了使用量，在减少农民用药成本的同时，降低了对环境的影响；
2、扩大了杀草谱，使得一种药剂能同时防治多种杂草，提供了一种极其方便有效的防治手段，对玉米、甜菜、甘蔗等作物田及果园等的阔叶杂草及禾本科杂草均有良好的防除效果；
具体实施方式
以下结合实施例对本发明的技术方案作进一步地详细介绍，需要说明的是，实施例仅用于进一步解释本发明内容，方便本技术领域技术人员理解，并不限制本发明的保护范围，相关人员对本发明显而易见的改变，仍然在本发明要求的保护范围之内。
实施例1含0.2％活性成分的乳油
将异恶唑草酮0.1g、高效异丙甲草胺1.9g、解草酮0.05g、蓖麻油聚氧乙烯醚5g、二卞联苯基聚氧乙烯醚15g、N-甲基吡咯烷酮补至1kg，混合成均匀油相，即得到含0.2％活性成分的乳油。
实施例2含0.2％活性成分的乳油
将异恶唑草酮1.9g、高效异丙甲草胺0.1g、解草喹0.1g、N-甲基吡咯烷酮50g、脂肪酸聚氧乙烯醚50g、聚氧乙烯烷基酚甲醛缩合物50g、无水甲醇补至1kg，混合成均匀油相，即得到含有0.2％活性成分的乳油。
实施例3含50％活性成分的乳油
将异恶唑草酮200g、异丙甲草胺300g、解草唑50g、溶剂油180#200g、甘油三月桂酸酯聚氧乙烯醚50g、乙氧基蓖麻油聚氧乙烯醚50g、甲苯补至1kg，混合成均匀油相，即得到含有50％活性成分的乳油。
实施例4含50％活性成分的乳油
将异恶唑草酮300g、异丙甲草胺200g、解草啶30g、四氢糠醇100g、烷基酚聚氧乙烯醚甲醛缩合物硫酸钠50g、聚氧乙烯脂肪酸脂50g、二甲基甲酰胺补至1kg，混合成均匀油相，即得到含有50％活性成分的乳油剂。
实施例5含1％活性成分的水乳剂
配方：异恶唑草酮0.5g、异丙草胺9.5g、解草安9.5g、溶剂油200号50g、苯乙基酚聚氧乙烯聚氧丙稀醚50g，苯乙烯基苯酚甲醛树脂聚氧乙烯-聚氧丙烯嵌段型聚醚50g、丙二醇80g、白炭黑30g、水补足至1kg。
制备方法：将上述异恶唑草酮、异丙草胺、解草安、溶剂油200号、苯乙基酚聚氧乙烯聚氧丙稀醚、苯乙烯基苯酚甲醛树脂聚氧乙烯-聚氧丙烯嵌段型聚醚混合成均匀油相；水、丙二醇、白炭黑混合成均一水相；在高速搅拌下，将水相加入到油相中，形成分散性良好的含1％活性成分的水乳剂。
实施例6含1％活性成分的水乳剂
配方：异恶唑草酮9.5g、异丙草胺0.5g、肟草安0.5g、N-甲基吡咯烷酮50g、仲辛基酚聚氧乙烯醚30g、脂肪醇聚氧乙烯醚20g、丙三醇50g、黄原胶3g、水补足至1kg。
制备方法：将上述异恶唑草酮、异丙草胺、肟草安、N-甲基吡咯烷酮、仲辛基酚聚氧乙烯醚、脂肪醇聚氧乙烯醚混合成均匀油相；水、丙三醇、黄原胶混合成均一水相；在高速搅拌下，将油相加入到水相中，形成分散性良好的含1％活性成分的水乳剂。
实施例7含35％活性成分的水乳剂
配方：异恶唑草酮175g、高效异丙甲草胺175g、呋喃解草唑100g、1,4-二氧六环180g、花生油10g、失水山梨醇脂肪酸酯聚氧乙烯基醚100g、乙氧基蓖麻油聚氧乙烯醚50g、黄原胶3g、尿素50g、水补足至1kg。
制备方法：将上述异恶唑草酮、高效异丙甲草胺、呋喃解草唑、花生油、失水山梨醇脂肪酸酯聚氧乙烯基醚、乙氧基蓖麻油聚氧乙烯醚混合成均匀油相；水、黄原胶、尿素混合成均一水相；在高速搅拌下，将油相加入到水相中，形成分散性良好的含45％活性成分的水乳剂。
实施例8含60％活性成分的水乳剂
配方：异恶唑草酮5g、高效异丙甲草胺595g、双苯恶唑酸100g、油酸聚乙二醇400酯或脂肪醇聚氧乙烯醚30g、甘油单月桂酸酯聚氧乙烯醚40g、N-甲基吡咯烷酮150g、黄原胶5g、尿素50g、水补足至1kg。
制备方法：将上述异恶唑草酮、高效异丙甲草胺、双苯恶唑酸、油酸聚乙二醇400酯或脂肪醇聚氧乙烯醚、甘油单月桂酸酯聚氧乙烯醚、N-甲基吡咯烷酮混合成均匀油相；水、黄原胶、尿素混合成均一水相；在高速搅拌下，将水相加入到油相中，形成分散性良好的含60％活性成分的水乳剂。
实施例9含10.8％活性成分的油悬浮剂
配方：异恶唑草酮80g、异丙甲草胺28g、吡唑解草酯100g、烷基芳基聚氧乙烯聚氧丙烯醚75g、脂肪醇聚氧乙烯醚50g、白炭黑10g、大豆油补至1kg。
制备方法：以大豆油为介质，将上述异恶唑草酮、异丙甲草胺、吡唑解草酯、烷基芳基聚氧乙烯聚氧丙烯醚、脂肪醇聚氧乙烯醚、白炭黑加入砂磨釜中研细，即得到10.8％活性成分的油悬浮剂。
实施例10含10.8％活性成分的油悬浮剂
配方：异恶唑草酮8g、异丙草胺100g、解草安10g、脂肪醇聚氧乙烯醚100g、苯乙烯基苯基聚氧乙烯醚50g、有机膨润土30g、油酸甲酯补至1kg。
制备方法：以油酸甲酯为介质，将上述异恶唑草酮、异丙草胺、解草安、脂肪醇聚氧乙烯醚、苯乙烯基苯基聚氧乙烯醚、有机膨润土加入砂磨釜中研细，即得到10.8％活性成分的油悬浮剂。
实施例11含50％活性成分的浓乳剂
配方：将异恶唑草酮100g、精异丙甲草胺400g、解草唑50g、1,4-二氧六环100g、环己酮200g、乙氧基蓖麻油50g、失水山梨醇脂肪酸酯聚氧乙烯基醚200g、1,2-丙二醇100g、聚乙烯醇80g、水补足1000g。
制备方法：以水为介质，将上述异恶唑草酮、精异丙甲草胺、解草唑、1,4-二氧六环、环己酮、乙氧基蓖麻油、失水山梨醇脂肪酸酯聚氧乙烯基醚混合制成均匀油相，加入水、1,2-丙二醇、聚乙烯醇经高剪切乳化机高速剪切即得含50％活性成分的浓乳剂。
以下通过实施例产品与单剂的除草效果对比试验，进一步说明本发明。
试验例1本发明的除草剂组合物在温室的除草效果与单剂的对比试验
在温室内采用盆栽的方法测定实验例1-11的除草剂组合物产品对阔叶杂草及禾本科杂草的防除效果，并与单剂进行对比。
试验方法：试验采用温室盆栽法，在一次性纸杯中播种定量的杂草种子，随机分为异恶唑草酮组、酰胺类除草剂组以及试验组，待杂草出土后1.5～2叶期时进行间苗，每个纸杯选留5株长势较为一致的杂草植株进行培养，并定期浇灌N、P、K复合肥的水溶液，待阔叶杂草长至4～6叶期、禾本科杂草长至2～5叶期时用履带式作物喷雾机进行茎叶喷雾处理，异恶唑草酮组喷施异恶唑草酮单剂、酰胺类除草剂组喷施酰胺类除草剂单剂、试验组喷施试验例1-11的除草剂组合物产品，喷雾处理后继续培养观察，20天后调查各组的除草效果。结果如表1所示。
表1单剂及实施例组合物对阔叶杂草及禾本科杂草的防除效果
由表1可以看出，异恶唑草酮与精异丙甲草胺、异丙甲草胺、异丙草胺复配后，与单剂相比对杂草特别是阔叶类杂草如鸭趾草、大戟、马齿苋等的防除效果有明显的提高；对禾本科类杂草如稗草、牛筋草也有明显的增效作用，达到同时防除阔叶杂草和禾本科杂草的目的。
Claims (10)
1.一种除草剂组合物，其特征在于，所述除草剂组合物包括组分A和组分B，其中组分A为异恶唑草酮或高效异丙甲草胺中的一种或多种，组分B为异丙甲草胺、异丙草胺中的一种或多种；
所述组分A和组分B的重量比为1～99：99～1，优选为1～20：20～1；
所述除草剂组合物还包括安全剂，所述安全剂为解草酮、解毒喹、解草唑、解草啶、解草安、肟草安、呋喃解草唑、双苯恶唑酸、吡唑解草酯中的一种或几种。
2.根据权利要1所述的除草剂组合物，其特征在于，所述安全剂的重量比为0.1％～5％。
3.根据权利要1所述的除草剂组合物，其特征在于，所述除草剂组合物还添加了表面活性剂，所述表面活性剂包括乳化剂、分散剂和润湿剂中的一种或几种。
4.根据权利要求3所述的除草剂组合物，其特征在于，所述乳化剂为苯乙基酚聚氧乙烯聚氧丙稀醚、甘油单月桂酸酯聚氧乙烯醚、苯乙烯基苯酚聚氧乙烯醚、蓖麻油聚氧乙烯醚、乙氧基蓖麻油聚氧乙烯醚、烷基酚聚氧丙烯聚氧乙烯醚、苯乙烯基苯基聚氧乙烯醚、仲辛基酚聚氧乙烯醚、壬基酚聚氧乙烯醚、烷基-二乙二醇醚-磺酸钠、脂肪酸聚乙二醇酯、快渗剂T、苯乙烯基苯酚甲醛树脂聚氧乙烯-聚氧丙烯嵌段型聚醚、失水山梨醇脂肪酸酯聚氧乙烯基醚、脂肪醇聚氧乙烯醚磺酸盐、聚氧乙烯烷基酚甲醛缩合物、十二烷基磺酸钙、癸醇聚氧乙烯醚磺基琥珀酸钠、烷基酚聚氧乙烯醚、甘油三月桂酸酯聚氧乙烯醚、二卞联苯基聚氧乙烯醚、油酸聚乙二醇400酯或脂肪醇聚氧乙烯醚、烷基酚聚氧乙烯醚甲醛缩合物硫酸钠、烷基酚聚氧乙烯醚丁二酸单酯磺酸盐、烷基酚聚氧乙烯磷酸酯、烷基酚聚氧乙烯醚磺化琥珀酸酯、聚氧乙烯脂肪酸脂、聚丙烯酸甲酯、聚氧乙烯脂肪氨、乙氧基蓖麻油、脂肪酸聚氧乙烯醚、聚氧乙烯脂肪醇醚、烷基芳基聚氧乙烯聚氧丙烯醚中的一种或几种；
所述分散剂为亚甲基双萘磺酸钠、亚甲基双甲基萘磺酸钠、聚乙烯吡咯烷酮、木质素磺酸钠、亚甲基二萘磺酸钠(分散剂NNO)、烷酰胺基牛磺酸盐、木质素磺酸钙、聚丙烯酸钠、烷基萘磺酸缩聚物的钠盐和亚甲基双萘磺酸钠甲醛缩合物中的一种或几种；
所述湿润剂为烷基萘磺酸钠、脂肪醇聚氧乙烯醚、仲烷基硫酸钠、十二烷基硫酸钠、十二烷基苯磺酸钠，脂肪醇聚乙二醇醚硫酸盐、壬基酚聚氧乙烯醚、失水山梨醇脂肪酸酯聚氧乙烯醚、烷基萘甲醛缩合物、烷基萘磺酸盐和阴离子润湿剂的混合物。
5.根据权利要求3所述的除草剂组合物，其特征在于，所述除草剂组合物还含有制剂用助剂；所述助剂包括溶剂、助溶剂、助悬剂、增稠剂、消泡剂、渗透剂中的一种或几种。
6.根据权利要求1-5任意一项权利要求所述的除草剂组合物，其特征在于，所述除草剂组合物的剂型为乳油、水乳剂、浓乳剂、油悬浮剂。
7.根据权利要求6所述的除草剂组合物，其特征在于，所述乳油按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂0.5％～30％、助溶剂0％～30％、溶剂补充至100％；
所述水乳剂按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂0.5～30％、助溶剂0％～30％、溶剂1％～30％、防冻剂0％～20％、增稠剂0.1％～5％、水补充至100％；
所述浓乳剂按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂1％～20％、助溶剂1％～30％、防冻剂1％～20％、增稠剂0.01％～5％、水补充至100％；
所述油悬浮剂按重量百分数的组成为：活性成分0.1％～95％、安全剂0.1％～95％、乳化剂0.1％～30％、增稠剂0.01％～30％、油补足至100％。
8.根据权利要求1-5任一权利要求所述的除草剂组合物，其特征在于所述组合物可以以成品制剂形式提供，即组合物中各物质已经混合；也可以以单独制剂形式提供，使用前在桶或罐中自行混合，其浓缩物通常与水混合得到所需活性物质的浓度。
9.根据权利要求1-7任一权利要求所述的除草剂组合物，其特征在于所述组合物用于防除玉米田一年生及多年生阔叶杂草、禾本科杂草。
10.根据权利要求9所述的除草剂组合物，其特征在于所述玉米田一年生及多年生阔叶杂草和禾本科杂草的杂草为：苘麻、苍耳、地肤、繁缕、龙葵、婆婆纳、曼陀罗、猪毛菜、柳叶刺蓼、春蓼、鬼针草、反枝苋、马齿苋、铁苋菜、稗草、牛筋草、荠菜、辣子草、藜、小藜、鼠尾看麦娘、宝盖草、马唐、秋稷、稷、千金子、狗尾草、大狗尾巴草等。
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1131379A (zh) * | 1994-08-01 | 1996-09-18 | 罗纳-普朗克农业有限公司 | 新颖的除草剂组合物 |
| WO1997034486A1 (en) * | 1996-03-15 | 1997-09-25 | Rhone-Poulenc Agrochimie | Herbicidal compositions |
| CN1213272A (zh) * | 1996-03-15 | 1999-04-07 | 诺瓦提斯公司 | 增效除草组合物以及防治杂草的方法 |
| CN1332608A (zh) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | 除草剂组合物 |
| CN101115389A (zh) * | 2005-02-04 | 2008-01-30 | 辛根塔参与股份公司 | 控制稻中不需要的植物生长的方法 |
| CN104322527A (zh) * | 2014-09-28 | 2015-02-04 | 青岛康和食品有限公司 | 一种玉米田除草剂组合物 |
| CN105394051A (zh) * | 2015-12-19 | 2016-03-16 | 青岛奥迪斯生物科技有限公司 | 一种含有异恶唑草酮的除草组合物 |
| CN105410001A (zh) * | 2015-12-28 | 2016-03-23 | 青岛海益诚管理技术有限公司 | 一种玉米田除草剂 |
| CN105451557A (zh) * | 2013-08-05 | 2016-03-30 | 先正达参股股份有限公司 | 吡唑基吡咯啉酮及其作为除草剂的用途 |
-
2017
- 2017-05-11 CN CN201710329630.7A patent/CN108849927A/zh active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1131379A (zh) * | 1994-08-01 | 1996-09-18 | 罗纳-普朗克农业有限公司 | 新颖的除草剂组合物 |
| WO1997034486A1 (en) * | 1996-03-15 | 1997-09-25 | Rhone-Poulenc Agrochimie | Herbicidal compositions |
| CN1213272A (zh) * | 1996-03-15 | 1999-04-07 | 诺瓦提斯公司 | 增效除草组合物以及防治杂草的方法 |
| CN1332608A (zh) * | 1998-11-10 | 2002-01-23 | 辛根塔参与股份公司 | 除草剂组合物 |
| CN101115389A (zh) * | 2005-02-04 | 2008-01-30 | 辛根塔参与股份公司 | 控制稻中不需要的植物生长的方法 |
| CN105451557A (zh) * | 2013-08-05 | 2016-03-30 | 先正达参股股份有限公司 | 吡唑基吡咯啉酮及其作为除草剂的用途 |
| CN104322527A (zh) * | 2014-09-28 | 2015-02-04 | 青岛康和食品有限公司 | 一种玉米田除草剂组合物 |
| CN105394051A (zh) * | 2015-12-19 | 2016-03-16 | 青岛奥迪斯生物科技有限公司 | 一种含有异恶唑草酮的除草组合物 |
| CN105410001A (zh) * | 2015-12-28 | 2016-03-23 | 青岛海益诚管理技术有限公司 | 一种玉米田除草剂 |
Non-Patent Citations (3)
| Title |
|---|
| GEIER, PATRICK W.等: "EXP 31130A efficacy and corn (Zea mays) response in western Kansas", 《WEED TECHNOLOGY》 * |
| LUSCOMBE, B M等: "RPA 201772: A novel herbicide for broad leaf and grass weed control in maize and sugar cane", 《BRIGHTON CROP PROTECTION CONFERENCE--WEEDS》 * |
| SPRAGUE, CHRISTY L.等: "Weed control and corn (Zea mays) tolerance from soil-applied RPA 201772", 《WEED TECHNOLOGY 》 * |
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