CN108697603A - Emusification cosmetic material - Google Patents
Emusification cosmetic material Download PDFInfo
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- CN108697603A CN108697603A CN201780012480.5A CN201780012480A CN108697603A CN 108697603 A CN108697603 A CN 108697603A CN 201780012480 A CN201780012480 A CN 201780012480A CN 108697603 A CN108697603 A CN 108697603A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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Abstract
The present invention relates to a kind of Emusification cosmetic materials, it contains following compositions A, following compositions B, following compositions C, following compositions D and following compositions E, the content of mentioned component A is 0.2 mass of mass %~3.5 %, the content of mentioned component B is 0.2 mass of mass %~2.0 %, the content of mentioned component D is 0.3 mass % or less, mentioned component C is 0.03~0.35 relative to the mass ratio (C/A) of mentioned component A, and mentioned component D is 0.045 or more relative to the mass ratio (D/A) of mentioned component A;Ingredient A:Starch ocentyl succinic aluminium, ingredient B:Single Compritol 888 ATO, ingredient C:Xanthans, ingredient D:Carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl and ingredient E:Water.The Emusification cosmetic material of the present invention can be used as cosmetic preparations such as lotion or the emulsifiable pastes that can assign elastic sensation and heavy feeling to skin.
Description
Technical field
The present invention relates to Emusification cosmetic materials.
Background technology
Highly concentrated sense of touch can be brought to user when the cosmetic preparation and the coating that assign elastic sensation (Ha リ senses) to skin
The cosmetic preparation of (hereinafter referred to " heavy feeling (sense of U Network) ") can make user feel certain comfort, and can show height
Grade sense, it can be said that being one of the type of cosmetic preparation that user is pursued.All the time, elastic sensation is assigned as to skin
Emusification cosmetic material, it is known that mixture polyethylene glycol (PEG), higher alcohol Emusification cosmetic material (patent document 1,2).
Existing technical literature
Patent document
Patent document 1:Japanese Unexamined Patent Publication 2012-197253 bulletins
Patent document 2:Japanese Unexamined Patent Publication 2005-53879 bulletins
Invention content
Problems to be solved by the invention
But using PEG, it is easy to pour off from skin, the imparting of elastic sensation is insufficient;Using higher alcohol
In the case of, preparation through when viscosify, it is known that the storage stability of preparation is bad.
The issue of the present invention is to provide a kind of while assigning elastic sensation and heavy feeling, the breast of excellent storage stability
Change cosmetic preparation.
Means for solving the problems
That is, the present invention relates to a kind of Emusification cosmetic material, contain following compositions A, following compositions B, following compositions C, following
Ingredient D and following compositions E,
The content that the content of mentioned component A is 0.2 mass %~3.5 mass %, mentioned component B is 0.2 mass %~2.0
The content of quality %, mentioned component D are 0.3 mass % hereinafter, mentioned component C is relative to the mass ratio (C/A) of mentioned component A
0.03~0.35, mentioned component D are 0.045 or more relative to the mass ratio (D/A) of mentioned component A.
Ingredient A:Starch ocentyl succinic aluminium
Ingredient B:Single Compritol 888 ATO
Ingredient C:Xanthans
Ingredient D:Carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl
Ingredient E:Water
The effect of invention
According to the present invention it is possible to provide a kind of while assigning elastic sensation and heavy feeling, the breast of excellent storage stability
Change cosmetic preparation.It should be noted that above-mentioned " elastic sensation " refers to the sense of touch that skin is extended out.In addition, above-mentioned " heavy feeling " is
Refer to the sense of touch as being coated with highly concentrated preparation when being coated with.
Specific implementation mode
The Emusification cosmetic material of the present invention is the Emusification cosmetic material containing ingredient A~E.
The inventors discovered that the starch ocentyl succinic aluminium by using ingredient A with hydration status, can manufacture imparting
The Emusification cosmetic material of elastic sensation.It, can but if the Emusification cosmetic material containing ingredient A is preserved under low temperature (5 DEG C or less)
Know that the elasticity of Emusification cosmetic material increases, forms gluey, stability reduction.Speculate that the phenomenon is caused by the aging of starch
's.Therefore, the present inventor in cosmetic preparation field in workable diversified ingredient by single behenyl acid glycerol of ingredient B
The carboxyl vinyl polymer (or alkyl-modified carboxyl group polyvinyl) of ester, the xanthans of ingredient C and ingredient D is applied to breast
Change cosmetic preparation, it is found that while the low-temperature stability in Emusification cosmetic material obtains improving, additionally it is possible to assign heavy feeling to skin.It protects
It deposits the mechanism that stability is improved not yet to determine, but is presumably due to, gel network is formd by the application of the ingredient
(interlayer, intercalation), thus, it is possible to inhibit the hydrogen bond generated between starch molecule, as a result, it is possible to inhibit under low temperature
Structure change.
Ingredient A is " starch ocentyl succinic aluminium ".Following effects are played by ingredient A:To being coated with emulsification makeup
The skin of material assigns elastic sensation.The mechanism that can obtain elastic sensation not yet determines, but is presumably due to, in coating Emusification cosmetic material
Water evaporation afterwards, the on the skin film of forming component A.
In the Emusification cosmetic material of the present invention, ingredient A exists with hydration status.As make ingredient A be hydration status method,
For example, the method for heating starch ocentyl succinic aluminium together with water can be enumerated.By being heated together with water,
The structure of ingredient A changes, and hydrophobic powder becomes hydrophily, becomes hydration status.Temperature in above-mentioned heating is preferred
It is 60 DEG C or more, more preferably 65 DEG C~90 DEG C, further preferably 70 DEG C~85 DEG C.
Starch ocentyl succinic aluminium be by starch with it is octenyl succinated and attached aluminium salt starch derive
Object.As the starch for constituting starch ocentyl succinic aluminium, cornstarch etc. can be enumerated.As ingredient A, corn can be enumerated
Starch ocentyl succinic aluminium.As ingredient A, commercially available product can be used.As the commercially available product of ingredient A, " DRY- can be enumerated
FLO PURE " (manufacture of AKZONOBEL companies), " DRY-FLO PC " (NATIONAL STARCH AND CHEMICAL corporations
Make), " Octie " (manufacture of Dian chemical companies).
About the content of the ingredient A in the 100 mass % of Emusification cosmetic material of the present invention, from the side for assigning elastic sensation to skin
Face is set out, and is 0.2 mass % or more, preferably 0.3 mass % or more, more preferably 0.5 mass % or more, is applied to from inhibition
The aspect that coating residue when on skin generates is set out, and is 3.5 mass % or less, preferably 3.0 mass % or less, is more preferably
2.5 mass % or less.It should be noted that the whole components A for including in Emusification cosmetic material of the content of ingredient A for the present invention
Total amount.
Ingredient B is " single Compritol 888 ATO ".Ingredient B plays following effects:It is assigned in the coating of Emusification cosmetic material
Heavy feeling, or in turn high-temperature stability is assigned to Emusification cosmetic material.
About the content of the ingredient B in the 100 mass % of Emusification cosmetic material of the present invention, the imparting and high temperature from heavy feeling are steady
Qualitatively aspect is set out, and is 0.2 mass % or more, preferably 0.5 mass % or more, more preferably 0.8 mass % or more;It is another
Aspect is 2.0 mass % or less, preferably 1.8 mass % or less, more preferably 1.5 matter from high-temperature stability aspect
Measure % or less.
Ingredient C is " xanthans ".Ingredient C is played steady to Emusification cosmetic material imparting low temperature by being shared with ingredient D
Qualitative effect.Xanthans refers to the chain being made of the repetitive unit of 2 molecule of glucose, 2 molecule of mannose, glucuronic acid
Polysaccharide.
As ingredient C, commercially available product can be used.As the commercially available product of ingredient C, for example, " ECHO GUM T " can be enumerated
(DSP GOKYO FOOD&CHEMICAL CO., LTD. manufacture), " NOMCORT ZZ " (Nissin Oillio Group corporations
Make) etc..
About the content of the ingredient C in the 100 mass % of Emusification cosmetic material of the present invention, go out in terms of low-temperature stability
Hair, preferably 0.01 mass % or more, more preferably 0.02 mass % or more, further preferably 0.03 mass % or more;From
The aspect that coating residue when inhibiting tacky and being applied to skin generates is set out, and preferably 0.5 mass % or less is preferably, more
Preferably 0.3 mass % or less, further preferably 0.2 mass % or less.
About mass ratioes (C/A) of the ingredient C relative to ingredient A in the Emusification cosmetic material of the present invention, from preventing low temperature steady
It is qualitative reduce, Emusification cosmetic material with gluey high resiliency in terms of set out, be 0.03 or more, preferably 0.035 or more, more preferably
It is 0.04 or more;From preventing Emusification cosmetic material from becoming non-uniform state, (gel piece is crushed the state of (モ ロ モ ロ):High resiliency
Partial hybrid state), coating sense of touch reduce aspect set out, be 0.35 or less, preferably 0.3 or less.
Ingredient D is " carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl ".That is, ingredient D is carboxyl
One or both of polyvinyl and alkyl-modified carboxyl group polyvinyl.Ingredient D with ingredient C by being closed
With, play to Emusification cosmetic material assign low-temperature stability effect.
Carboxyl vinyl polymer is mainly the polymer of acrylic acid, and alkyl-modified carboxyl group polyvinyl is mainly third
The copolymer of olefin(e) acid and alkyl methacrylate.One kind can be used only in ingredient D, can also use two or more.
Carboxyl vinyl polymer and alkyl-modified carboxyl group polyvinyl can be readily available as commercially available product.Make
For the preferred commercially available product of carboxyl vinyl polymer, for example, can enumerate " Carbopol 934 ", " Carbopol 940 ",
"Carbopol 941","Carbopol 980","Carbopol 981","Carbopol 1342","Carbopol 2984",
" Carbopol Ultrez 10 ", " Carbopol ETD 2050 " (being Japanese Lu Borun Co., Ltd.);"AQUPEC HV-
501 ", " AQUPEC HV-504 ", " AQUPEC HV-505 ", " HIVISWAKO 104 ", " HIVISWAKO 105 " (are and light
Chun Yao Industrial Co., Ltd) etc..As the preferred commercially available product of alkyl-modified carboxyl group polyvinyl, for example, can enumerate
" PEMULEN TR-1 ", " PEMULEN TR-2 ", " Carbopol ETD 2020 ", " Carbopol ULTREZ 20 " (are day
Ben Lubo moistens Co., Ltd.) etc..
About the content of the ingredient D in the 100 mass % of Emusification cosmetic material of the present invention, go out in terms of low-temperature stability
Hair, preferably 0.05 mass % or more, more preferably 0.06 mass % or more, further preferably 0.08 mass % or more;Separately
On the one hand, become non-uniform state (the broken state of gel piece from inhibition Emusification cosmetic material:The shape of elastomeric partial hybrid
State), coating sense of touch reduce aspect set out, be 0.3 mass % or less, preferably 0.25 mass % or less.It should be noted that
The total amount for the whole components D that the content of ingredient D includes in the Emusification cosmetic material for the present invention.
Mass ratio (D/A) about the ingredient D in the Emusification cosmetic material of the present invention relative to ingredient A, from low-temperature stability
Aspect set out, be 0.045 or more, preferably 0.05 or more, more preferably 0.08 or more;From coating sense of touch aspect,
Preferably 0.5 or less.
Ingredient E is " water ".Ingredient E has the function of the medium as the Emusification cosmetic material for being used to form emulsifying systems.It is logical
Crossing makes cosmetic preparation be emulsion type, and it is hydration status that can make ingredient A, and that plays that ingredient A brings assigns elastic sensation to skin
Effect.
The present invention 100 mass % of Emusification cosmetic material in ingredient E content be preferably 40.0 mass % or more, more preferably
For 50.0 mass % or more, further preferably 60.0 mass % or more;From containing other compositions aspect, preferably
95.0 mass % or less, more preferably 90.0 mass % or less.
The Emusification cosmetic material of the present invention can further contain " phosphatide " and be used as ingredient F.By using ingredient F, not only may be used
To promote emulsification, but also heavy feeling can be assigned to user, soft sense of touch, therefore the emulsification of the present invention are assigned to skin
Cosmetic preparation preferably further contains ingredient F.
Ingredient F is the complex lipid comprising phosphate moiety, can enumerate natural phospholipid, synthetic phospholipid, be made naturally using hydrogen
The hydrogenated phospholipid etc. of the unsaturated carbon chains saturation of the phosphatide in source.As above-mentioned phosphatide, for example, can enumerate phosphatidyl choline,
Phosphatidyl-ethanolamine, phosphatidylserine, phosphatidylinositols, lysophosphatidyl choline, sphingomyelins, egg yolk lecithin, soybean ovum
The natural phospholipids such as phosphatide;Dilauroyl Phosphatidylcholine, dimyristoyl phosphatidyl choline, dipalmitoylphosphatidylcholine, two
The synthetic phospholipids such as stearoylphosphatidylcholine, Dioleoyl Phosphatidylcholine, Palmitoyl Phosphatidylcholine;Hydrogenated soybean lecithin
Hydrogenated phospholipids such as fat, hydrogenated yolk lecithin, Phosphatidylcholine Hydrogenated, hydrogenated phospholipid acyl serine etc..Wherein, stablize from preservation
The excellent aspect of property is set out, preferably hydrogenated phospholipid, more preferably hydrogenated soy phosphatidyl choline.One kind can be used only in ingredient F,
It can use two or more.
As ingredient F, commercially available product can be used.As the commercially available product of hydrogenated soy phosphatidyl choline, for example, can enumerate
" COATSOME NC-61 " (manufacture of You companies), " NIKKOL Retinol S-10 " (Nikko Chemical Company manufacture), " BASIS
LP-20H " (manufacture of Nissin Oillio Group companies) etc..
About the content of the ingredient F in the 100 mass % of Emusification cosmetic material of the present invention, go out in terms of improving coating sense of touch
Hair, preferably 0.1 mass % or more, more preferably 0.3 mass % or more, further preferably 0.5 mass % or more;From inhibition
Through when discoloration, the aspect that generates of peculiar smell set out, preferably 5.0 mass % or less, more preferably 3.5 mass % or less, into one
Step is preferably 2.5 mass % or less.It should be noted that include in Emusification cosmetic material of the content of ingredient F for the present invention is complete
The total amount of portion ingredient F.
The Emusification cosmetic material of the present invention can further contain " glycerin monostearate and/or monostearate D-sorbite
Acid anhydride " is used as ingredient G.That is, ingredient G is one or both of glycerin monostearate and monostearate sorbitan.Pass through
Using ingredient G, the heavy feeling of Emusification cosmetic material can be improved, therefore it is preferred that.In addition, by sharing ingredient G and ingredient F,
The emulsification that ingredient F is brought can be made more to stablize, therefore it is preferred that.
About the content of the ingredient G in the 100 mass % of Emusification cosmetic material of the present invention, emulsified from improving heavy feeling and improving
It sets out in terms of stability, preferably 0.1 mass % or more, more preferably 0.2 mass % or more;In terms of raising use feeling
It sets out, preferably 3.0 mass % or less, more preferably 2.5 mass % or less, further preferably 2.0 mass % or less.It needs
Illustrate, the content of ingredient G is the total amount for the whole components G for including in Emusification cosmetic material of the invention.
In order to make dosage form be emulsion type, Emusification cosmetic material of the invention also contains finish other than mentioned component A~G.
Above-mentioned finish is not particularly limited, for example, higher alcohol, higher fatty acids, grease, hydrocarbon ils, ester oil, silicone oil, wax etc. can be enumerated.
As the concrete example of above-mentioned finish, can enumerate:Laruyl alcohol, myristyl alcohol, cetanol, stearyl alcohol, oleyl alcohol, wool
The higher alcohols such as lipidol, docosyl alcohol, cetostearyl alcohol;Lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, 11
The higher fatty acids such as carbon enoic acid, lanoceric acid, isostearic acid;Cocounut oil, palm oil, hydrogenated palm oil, avocado oil, sesame oil, olive
Olive oil, Hawaii drupe oil, grapefruit, safflower oil, apricot kernel oil, corn oil, cottonseed oil, sunflower oil, grape seed oil, fibert
The greases such as oil, macadimia nut oil, white awns flower seed oil oil, rose hip oil;Olefin oligomer, lightweight flowing isoparaffin, saualane,
The hydrocarbon ils such as atoleine, flowing isoparaffin, vaseline;Ethyl oleate, isopropyl myristate, isopropyl palmitate, Pork and beans
Cool acid myristin, cetyl palmitate, oleyl oleate, myristic acid octyldodecyl, oleic acid octyldodecyl
Base ester, isostearic acid ethyl ester, isopropyl isostearate, 2 ethyl hexanoic acid cetyl, 2 ethyl hexanoic acid cetearyl alcohol ester, three 2- second
Base caproin, three (caprylic/capric) glyceride, three different tripalmitins, four 2 ethyl hexanoic acid pentaerythritol esters, octanoic acid
Isohexadecane base ester, the different stearyl ester of octanoic acid, isostearic acid isohexadecane base ester, isostearic acid octyldodecyl, dimethyl
The ester oils such as sad octyldodecyl, isostearic acid propylene glycol ester;Dimethicone, methyl polysiloxane, high polymeric MAO
Polysiloxanes, methyl phenyl silicone, octamethyltrisiloxane, decamethyl tetrasiloxane, octamethylcy-clotetrasiloxane, ten first
Base cyclopentasiloxane, ten diformazan basic rings, six siloxanes, octamethylpolysiloxane, alcohol modified silicone, alkyl-modified silicone, amino change
The silicone oil such as property silicone, epoxy-modified silicone;Waxes such as jojoba oil, beeswax etc..One kind can be used only in finish, can also use two
Kind or more.
The content of finish in the 100 mass % of Emusification cosmetic material of the present invention is not particularly limited, is imitated from moisturizing is assigned
It sets out in terms of fruit, preferably 2.0 mass % or more, more preferably 3.0 mass % or more.On the other hand, tacky from inhibition
Aspect is set out, as above-mentioned content, preferably 30.0 mass % or less, more preferably 20.0 mass % or less.It needs to illustrate
It is that the content of finish is the total amount for the whole finishes for including in Emusification cosmetic material of the invention.
Mass ratio (oil/B) about the finish in Emusification cosmetic material relative to ingredient B, goes out in terms of assigning heavy feeling
Hair, preferably 3.0 or more, more preferably 3.25 or more, and preferably 30.0 or less, more preferably 20.0 or less.
The Emusification cosmetic material of the present invention can contain the emulsifier (referred to as " other emulsifiers ") other than ingredient F.As
Other above-mentioned emulsifiers, are not particularly limited, preferably nonionic emulsifier.One kind can be used only in " other emulsifiers ",
It can also use two or more.
As above-mentioned " other emulsifiers ", sorbitan aliphatic ester, fatty acid glyceride, castor oil, hydrogen can be enumerated
Change castor oil and their alkylene oxide adducts, Polyoxyethylene Sorbitan acid esters, polyglyceryl fatty acid ester, polyoxy
Change allylic alkylation ether, polyoxyalkylene fatty acid ester, polyoxyalkylene alkylphenol, polyoxyethylene sorbitol aliphatic ester, polyoxy second
Allylic alkylation phenyl formaldehyde condensation products, polyoxyethylene sterol and its derivative, Wool wax alcohols,ethoxylated and its derivative, polyoxyethylene
The nonionic emulsifier such as beeswax derivatives, sugar esters;Higher fatty acids soap, alkyl sulfate salt, alkylphosphonic, polyoxy second
Allylic alkylation ether sulfate, polyoxyethylene alkylphenyl ether sulfate salt, alkyl ether phosphate, alkyl ether carboxy acid salt, sulfonylmethyl ox
Sulfonate, N- acyl-N-methyls-Beta-alanine salt, N- acylglycines salt, N- acyl glutamates, polyxyethylated carboxylic
Hydrochlorate, alkyl phenyl ether sulfonate, alkyl sulfosuccinate and its salt, N- acyl groups sarcosine and its salt, polyoxyethylene cocounut oil fat
The anionic emulsifiers such as fat acid single ethanol amide sulfate;The amine such as alkylamine salt, fatty acid amide amine salt, ester-containing tertiary ammonium salt
Alkyl quaternary ammonium salts, the alkane such as salt, monoalkyl type quaternary ammonium salt, dioxane fundamental mode quaternary ammonium salt, trialkyl type quaternary ammonium salt, zephiran type quaternary ammonium salt
Cationic emulsifiers such as the ring types such as yl pyridines salt quaternary ammonium salt, benzethonium chloride etc..Wherein, preferably nonionic emulsifier,
Preferably Crodaret, polyglyceryl fatty acid ester, Polyoxyethylene Sorbitan acid esters, polyglycereol
Aliphatic ester.
The content of " other emulsifiers " in the 100 mass % of Emusification cosmetic material of the present invention be preferably 0.05 mass % with
Upper, more preferably 0.1 mass % or more, preferably 5.0 mass % or less, more preferably 3.0 mass % or less.It needs to illustrate
It is that nonionic emulsifier preferably satisfies above range.It should be noted that the content of " other emulsifiers " is the breast of the present invention
Change the total amount for the whole " other emulsifiers " for including in cosmetic preparation.
The Emusification cosmetic material of the present invention can further contain any ingredient other than the above.As above-mentioned any ingredient,
It is not particularly limited, for example, lower alcohol can be enumerated;The polyalcohols such as glycerine, 1,3 butylene glycol;Ultra-violet absorber;Powder;It is anti-
Oxidant;The preservatives such as methyl p-hydroxybenzoate;Fragrance;Colorant;Chelating agent;Freshener;Thickener;Vitamins;In
And agent;Amino acid;PH adjusting agent;Whitening agent;Anti-inflammatory agent;Deodorant;Animal and plant extracts;The sodium salt etc. of ethylenediamine tetra-acetic acid
Additives such as chelating agent etc..One kind can be used only in other compositions, can also use two or more.
The Emusification cosmetic material of the present invention preferably contains substantially no " the straight-chain aliphatic unitary that carbon atom number is 12~22
Alcohol ".Containing above-mentioned aliphatic alcohol, Emusification cosmetic material sometimes through when be hardened.Herein, emulsification of the invention makeup
Expect the content preferably 0.1 mass % or less of " the straight-chain aliphatic monohydric alcohol that carbon atom number is 12~22 " in 100 mass %
(that is, 0~0.1 mass %), more preferably 0.05 mass % or less, further preferably 0.01 mass % or less.In particular,
In the case that the Emusification cosmetic material of the present invention is lotion, above range is preferably satisfied.
As the concrete example of " carbon atom number be 12~22 straight-chain aliphatic monohydric alcohol ", for example, can enumerate cetanol,
Docosyl alcohol, stearyl alcohol, cetostearyl alcohol etc..Existing " the straight-chain aliphatic monohydric alcohol that carbon atom number is 12~22 " is only a kind of
Situation, also there are two types of above situations.
In the present invention, the content of the electrolyte in Emusification cosmetic material is fewer, then storage stability is higher, therefore it is preferred that.About
The content of electrolyte in the 100 mass % of Emusification cosmetic material of the present invention, from storage stability aspect, preferably less than
0.3 mass % (that is, 0 mass % is less than 0.3 mass %), more preferably 0.1 mass % or less.It should be noted that
The total amount for whole electrolyte that the content of electrolyte includes in the Emusification cosmetic material for the present invention.
Mentioned component A~G is not included in " electrolyte " in this specification.As electrolyte, for example, monovalence can be enumerated
Metal salt, multivalent metal salt etc. more than divalent.Above-mentioned metal salt can be inorganic salts, or organic salt.In addition, making
For above-mentioned metal salt, sodium salt, sylvite, calcium salt, magnesium salts, zinc salt, ammonium salt, aluminium salt etc. can be enumerated.Specifically, can example go out pair
Zinc phenolsulfonate, sodium chloride, potassium chloride, calcium chloride, magnesium chloride, magnesium sulfate, alum, sodium carbonate, sodium bicarbonate, saleratus,
Ammonium chloride, sodium phosphate, disodium hydrogen phosphate, sodium dihydrogen phosphate, sodium citrate (trisodium citrate), disodium ethylene diamine tetraacetate, sulphur
Sour aluminium potassium etc..In addition, also including benzalkonium chloride and chlorination hydroxyl aluminium in electrolyte.
The pH of the Emusification cosmetic material of the present invention is not particularly limited, for example, being preferably 5.0~7.5 at 25 DEG C, more excellent
It is selected as 5.5~7.0.
The viscosity of the Emusification cosmetic material of the present invention is not particularly limited, for example, the viscosity at 25 DEG C is preferably
500mPas~80000mPas, more preferably 1500mPas~25000mPas.Viscosimetric analysis using Brookfield viscometer,
Implemented with being suitble to rotor, the rotating speed of viscosity.It should be noted that above-mentioned viscosity is the feelings of 500mPas~25000mPas
Under condition, Emusification cosmetic material of the invention is emulsion form.
The dosage form of Emusification cosmetic material as the present invention, is not particularly limited, for example, emulsifiable paste, lotion etc. can be enumerated.Its
In, preferred emulsion.
It as the Emusification cosmetic material of the present invention, is not particularly limited, for example, moisturizing cosmetic preparation, whitening makeup can be enumerated
The skin nursings such as material, acne nursing cosmetic preparation, anti-aging cosmetic preparation (for example, for the purpose of inhibiting wrinkle, inhibition relaxation etc.)
Cosmetic preparation etc..The Emusification cosmetic material of the present invention is preferably used as skin cosmetic.The Emusification cosmetic material of the present invention for example can be to change
Any one of cosmetic, quasi drug, drug, groceries.
The position of Emusification cosmetic material as the application present invention, is not particularly limited, can enumerate face (for example, forehead, eye
Eyeball, canthus, cheek, mouth etc.), arm, ancon, the back of the hand, finger tip, foot, knee, heel, neck, oxter, back etc..
In the Emusification cosmetic material of the present invention, ingredient A preferably includes with hydration status.It plays as a result, and carrys out bullet to skin tape
Sexy effect.In order to make ingredient A be hydration status, in the manufacturing process of the Emusification cosmetic material of the present invention, preferably by ingredient A
At least heated together with water.That is, this specification also includes following inventions.
This specification includes a kind of manufacturing method of Emusification cosmetic material, for by ingredient A, ingredient B, ingredient C, ingredient D and
The manufacturing method of the Emusification cosmetic material of ingredient E mixing, the manufacturing method be characterized in that, the content of ingredient A be 0.2 mass %~
The content that the content of 3.5 mass %, ingredient B are 0.2 mass %~2.0 mass %, ingredient D is 0.3 mass % hereinafter, ingredient C
Relative to ingredient A mass ratio (C/A) be 0.03~0.35, ingredient D relative to ingredient A mass ratio (D/A) be 0.045 with
On, including ingredient A is at least heated to 60 DEG C or more process.In above-mentioned manufacturing method, preferably by ingredient A be heated to 65 DEG C~
90 DEG C, be further preferably heated to 70 DEG C~85 DEG C.As the mode of above-mentioned manufacturing method, for example, following manner can be enumerated:
By water composition (for example, ingredient A, ingredient C, ingredient D, ingredient E, electrolyte etc.) and oil components (ingredient B, ingredient F, ingredient
G, finish etc.) respectively heat after, by two-component mix and manufacture Emusification cosmetic material.It should be noted that before above-mentioned heating at
It is preferably the state of hydrophobicity powder to divide A.
Embodiment
In the following, based on embodiment, the present invention will be described in more detail, but the present invention is not limited to these embodiments.
It should be noted that blend amount and content are to be converted into the amount of pure ingredient, indicated as long as not special declaration " quality % ".
Embodiment 1~14 and comparative example 1~11 (preparation of Emusification cosmetic material)
It is following to prepare embodiment 1~14 and comparative example 1~11 according to the composition described in table 1A, table 1B, table 2A and table 2B
Each Emusification cosmetic material.
As water phase, by ingredient A, ingredient C, ingredient D, ingredient E, potassium hydroxide, glycerine, 1,3-BDO, EDTA-2Na,
Methyl p-hydroxybenzoate is mixed and heated to 85 DEG C.In addition, as oil phase, by ingredient B, ingredient F, ingredient G, other emulsifications
Agent, finish are mixed and heated to 85 DEG C.Next, above-mentioned water phase and above-mentioned oil phase are mixed, using homomixer with rotating speed
6000rpm, the stirring of 5 minutes conditions, are emulsified, are cooled to 35 DEG C, prepare Emusification cosmetic material.
The Emusification cosmetic material of embodiment 1 is about 6.5 in 25 DEG C of pH, and 25 DEG C of viscosity is 9260mPas.In addition, other
The Emusification cosmetic material of embodiment is about 6.5 in 25 DEG C of pH, and 25 DEG C of viscosity is the model of 3280mPas~42470mPas
It encloses.It should be noted that the Emusification cosmetic material of embodiment 9 is emulsifiable paste shape, other embodiment is emulsion form.
Test example 1:The storage stability (low-temperature stability, high-temperature stability) of Emusification cosmetic material
(low-temperature stability)
By the Emusification cosmetic material of each embodiment and comparative example to be preserved 28 days under conditions of -3 DEG C in thermostat.It will preserve
It is steady to the low temperature of each Emusification cosmetic material using following methods after each Emusification cosmetic material afterwards is placed 4 hours under conditions of 25 DEG C
It is qualitative to be evaluated.Specifically, each Emusification cosmetic material is thinly applied on glass plate, coating state is observed.In addition, closing
In the Emusification cosmetic material of emulsion form, mobility is observed;About the pasta Emusification cosmetic material of breast, shape of observation when finger allocation
State.It will be uniform coating state, and there is mobility in the case of emulsion form, be easy allocation in the case of emulsifiable paste shape
The case where to be evaluated as low-temperature stability good (zero);It will be non-uniform coating state, and not have in the case of emulsion form
Have that mobility, that elasticity is high in the case of emulsifiable paste shape, situation of allocation difficulty is evaluated as low-temperature stability is bad (×).
(high-temperature stability)
By the Emusification cosmetic material of each embodiment and comparative example to be preserved 28 days under conditions of 40 DEG C in thermostat.It will preserve
It is steady to the low temperature of each Emusification cosmetic material using following methods after each Emusification cosmetic material afterwards is placed 4 hours under conditions of 25 DEG C
It is qualitative to be evaluated.Specifically, observing the appearance of each Emusification cosmetic material.In addition, the Emusification cosmetic material about emulsion form, observation
Mobility;About the pasta Emusification cosmetic material of breast, state of observation when finger allocation.It will be without separation and apparent viscosity drop
It is good (zero) that low situation is evaluated as high-temperature stability;It is steady that the case where there will be separation or apparent viscosity reduce is evaluated as high temperature
Qualitative bad (×).
As a result in A shown in table 1, table 1B, table 2A and table 2B.
Test example 2:The coating sense of touch (elastic sensation, heavy feeling) of Emusification cosmetic material
The Emusification cosmetic material obtained in each embodiment and each comparative example is applied on the inside of forethiga by 3 professional judging panels, right
Sense of touch when coating, is compared with the lotion of following standard recipes, is evaluated according to following benchmark.
<Standard recipe (lotion) >
Xanthans:0.05 mass %
Carboxyl vinyl polymer:0.1 mass %
Hydrolecithin:1.0 mass %
Monostearate POE-20 sorbitans:0.5 mass %
Glycerin monostearate:0.5 mass %
Potassium hydroxide:0.05 mass %
Atoleine:2.0 mass %
Dimethicone:0.5 mass %
Isostearic acid PG:2.0 mass %
Glycerine:5.0 mass %
1,3 butylene glycol:5.0 mass %
EDTA-2Na:0.08 mass %
Methyl p-hydroxybenzoate:0.2 mass %
Water:Remainder
<The Ping Jiajizhun > of elastic sensation;
◎ (excellent):It is very excellent with standard recipe resilience in comparison sense.
Zero (good):Elastic sensation is clearly felt that compared with standard recipe.
× (bad):Apparent elastic sensation difference is not felt compared with standard recipe.<The Ping Jiajizhun > of heavy feeling;
◎ (excellent):Heavy feeling is very excellent compared with standard recipe.
Zero (good):Heavy feeling is clearly felt that compared with standard recipe.
× (bad):Apparent heavy feeling difference is not felt compared with standard recipe.[Table 1A]
Table 1A
The value of each ingredient is quality %.
[Table 1B]
Table 1B
The value of each ingredient is quality %.
[Table 2A]
Table 2A
The value of each ingredient is quality %.
[Table 2B]
Table 2B
The value of each ingredient is quality %.
It should be noted that the details of each ingredient is as described below.
Cornstarch ocentyl succinic Al:The manufacture of AKZONOBEL companies, trade name " DRY-FLO PURE ", corn form sediment
Powder ocentyl succinic aluminium
Xanthans:DSP GOKYO FOOD&CHEMICAL CO., LTD. manufacture, trade name " ECHO GUM T "
Carboxyl vinyl polymer:Lubrizol Corp.'s manufacture, trade name " Carbopol 980 "
Alkyl-modified carboxyl group polyvinyl:Lubrizol Corp.'s manufacture, trade name " PEMULEN TR-1 "
Hydrolecithin:Nikko Chemical Company manufacture, trade name " Retinol S-10 "
Monostearate POE-20 sorbitans:KAO. Corp. SA's manufacture, trade name " RHEODOL TW-S120V "
Atoleine:The manufacture of SONNEBORN companies, trade name " CARNATION#70 "
Dimethicone:The manufacture of Dow Corning Toray companies, trade name " SH200C 10CS-JASU "
Isostearic acid PG:The manufacture of green wood oil fat industrial group, trade name " isostearic acid PG ", propylene glycol isostearate
The following contents known to above-mentioned table 1A, table 1B, table 2A and table 2B.
In the example (comparative example 1 and 10) that D/A values are not up to prescribed limit, low-temperature stability is poor.It is super in the amount of ingredient D
It crosses in the example (comparative example 2,3 and 11) of prescribed limit, product is the state that non-uniform gel piece is crushed, hence it is evident that can not conduct
Emulsification composition processing, therefore do not evaluated.It is more than prescribed limit to be not up to prescribed limit and C/A values in the amount of ingredient A
In example (comparative example 4), elastic sensation is poor.It is more than the example that prescribed limit and C/A values are not up to prescribed limit in the amount of ingredient A
In (comparative example 5), low-temperature stability is poor, and coating residue is will produce when being applied to skin.Model is not up to provided in the amount of ingredient B
In the example (comparative example 6) enclosed, high-temperature stability and heavy feeling are poor, and product is separated into two layers.It is more than regulation model in the amount of ingredient B
In the example (comparative example 7) enclosed, poor high temperature stability, product viscosity reduces.It is not up to the example (ratio of prescribed limit in C/A values
Compared with example 8) in, low-temperature stability is poor.In the example (comparative example 9) that C/A values are more than prescribed limit, heavy feeling is poor, is being applied to
Glutinous soapy feeling is felt when skin.
On the other hand, for the content containing ingredient A~E, ingredient A, ingredient B and ingredient D in prescribed limit, C/A
For the Emusification cosmetic material (embodiment 1~14) of the present invention of value and D/A values in prescribed limit, it is known that under low temperature and high temperature
Excellent storage stability, and elastic sensation and heavy feeling are also excellent.
Formulation Example 1 (lotion)
Formulation Example 2 (emulsifiable paste)
Industrial applicibility
The Emusification cosmetic material of the present invention can be as lotion or the emulsifiable paste etc. that can assign elastic sensation and heavy feeling to skin
Cosmetic preparation uses.
Claims (7)
1. a kind of Emusification cosmetic material contains following compositions A, following compositions B, following compositions C, following compositions D and following compositions
E,
The content that the content of the ingredient A is 0.2 mass of mass %~3.5 %, the ingredient B is 0.2 matter of mass %~2.0
% is measured, the content of the ingredient D is 0.3 mass % hereinafter, the ingredient C relative to the mass ratio C/A of the ingredient A is 0.03
~0.35, the ingredient D are 0.045 or more relative to the mass ratio D/A of the ingredient A,
Ingredient A:Starch ocentyl succinic aluminium;
Ingredient B:Single Compritol 888 ATO;
Ingredient C:Xanthans;
Ingredient D:Carboxyl vinyl polymer and/or alkyl-modified carboxyl group polyvinyl;
Ingredient E:Water.
2. Emusification cosmetic material as described in claim 1 further contains following compositions F,
Ingredient F:Phosphatide.
3. Emusification cosmetic material as claimed in claim 1 or 2 further contains following compositions G,
Ingredient G:Glycerin monostearate and/or monostearate sorbitan.
4. Emusification cosmetic material according to any one of claims 1 to 3,25 DEG C of viscosity be 500mPas~
80000mPa·s。
5. Emusification cosmetic material as described in any one of claims 1 to 4, it is 12~22 to contain substantially no carbon atom number
Straight-chain aliphatic monohydric alcohol.
6. such as Emusification cosmetic material according to any one of claims 1 to 5, wherein the content of electrolyte is less than 0.3 mass %.
7. it is skin cosmetic such as Emusification cosmetic material according to any one of claims 1 to 6.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016-191576 | 2016-09-29 | ||
| JP2016191576 | 2016-09-29 | ||
| PCT/JP2017/033655 WO2018061855A1 (en) | 2016-09-29 | 2017-09-19 | Emulsified cosmetic |
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| Publication Number | Publication Date |
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| CN108697603A true CN108697603A (en) | 2018-10-23 |
| CN108697603B CN108697603B (en) | 2021-04-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201780012480.5A Active CN108697603B (en) | 2016-09-29 | 2017-09-19 | Emulsified cosmetic |
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| Country | Link |
|---|---|
| JP (1) | JP6747763B2 (en) |
| KR (1) | KR102104095B1 (en) |
| CN (1) | CN108697603B (en) |
| WO (1) | WO2018061855A1 (en) |
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| WO2021100666A1 (en) * | 2019-11-19 | 2021-05-27 | 株式会社マンダム | Cosmetic composition |
| WO2021259663A1 (en) * | 2020-06-23 | 2021-12-30 | Unilever Ip Holdings B.V. | Cosmetic composition for improving appearance of skin |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020094341A1 (en) * | 1998-11-03 | 2002-07-18 | Lise W. Jorgensen | Skin moisturizer compositions containing a sebum control agent |
| JP2003238356A (en) * | 2002-02-15 | 2003-08-27 | Kose Corp | Cosmetic |
| US20070280977A1 (en) * | 2004-08-06 | 2007-12-06 | Macian Karla A | Multiple Emulsion Excipient for Cosmetic Actives |
| JP2011201799A (en) * | 2010-03-25 | 2011-10-13 | Mandom Corp | Emulsified composition for skin |
| JP2013018751A (en) * | 2011-07-13 | 2013-01-31 | Shiseido Co Ltd | Oil-in-water emulsion cosmetic |
| CN105250189A (en) * | 2015-11-24 | 2016-01-20 | 广州市花安堂生物科技有限公司 | Acne treatment essence cream and preparing method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005053879A (en) | 2003-08-07 | 2005-03-03 | Kose Corp | Emulsion cosmetic |
| TW200744663A (en) * | 2005-07-27 | 2007-12-16 | Showa Denko Kk | Emulsified skin external preparation and method for stabilizing the skin external preparation |
| JP5601951B2 (en) * | 2010-09-27 | 2014-10-08 | 株式会社マンダム | Liposome-containing composition, and water-soluble cosmetic for skin comprising the composition |
| JP5790054B2 (en) | 2011-03-22 | 2015-10-07 | 日油株式会社 | Skin cosmetics |
-
2017
- 2017-09-19 WO PCT/JP2017/033655 patent/WO2018061855A1/en not_active Ceased
- 2017-09-19 KR KR1020187022602A patent/KR102104095B1/en active Active
- 2017-09-19 JP JP2018542416A patent/JP6747763B2/en active Active
- 2017-09-19 CN CN201780012480.5A patent/CN108697603B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020094341A1 (en) * | 1998-11-03 | 2002-07-18 | Lise W. Jorgensen | Skin moisturizer compositions containing a sebum control agent |
| JP2003238356A (en) * | 2002-02-15 | 2003-08-27 | Kose Corp | Cosmetic |
| US20070280977A1 (en) * | 2004-08-06 | 2007-12-06 | Macian Karla A | Multiple Emulsion Excipient for Cosmetic Actives |
| JP2011201799A (en) * | 2010-03-25 | 2011-10-13 | Mandom Corp | Emulsified composition for skin |
| JP2013018751A (en) * | 2011-07-13 | 2013-01-31 | Shiseido Co Ltd | Oil-in-water emulsion cosmetic |
| CN105250189A (en) * | 2015-11-24 | 2016-01-20 | 广州市花安堂生物科技有限公司 | Acne treatment essence cream and preparing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6747763B2 (en) | 2020-08-26 |
| KR102104095B1 (en) | 2020-04-23 |
| CN108697603B (en) | 2021-04-23 |
| WO2018061855A1 (en) | 2018-04-05 |
| KR20180100640A (en) | 2018-09-11 |
| JPWO2018061855A1 (en) | 2018-11-01 |
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