CN108300606A - Liquid detergent - Google Patents
Liquid detergent Download PDFInfo
- Publication number
- CN108300606A CN108300606A CN201810232185.7A CN201810232185A CN108300606A CN 108300606 A CN108300606 A CN 108300606A CN 201810232185 A CN201810232185 A CN 201810232185A CN 108300606 A CN108300606 A CN 108300606A
- Authority
- CN
- China
- Prior art keywords
- parts
- liquid detergent
- quaternary ammonium
- ammonium salt
- cosolvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000003599 detergent Substances 0.000 title claims abstract description 74
- 239000007788 liquid Substances 0.000 title claims abstract description 74
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 39
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 34
- 102000004190 Enzymes Human genes 0.000 claims abstract description 31
- 108090000790 Enzymes Proteins 0.000 claims abstract description 31
- 229940088598 enzyme Drugs 0.000 claims abstract description 31
- 229920001661 Chitosan Polymers 0.000 claims abstract description 29
- 108010059892 Cellulase Proteins 0.000 claims abstract description 27
- 229940106157 cellulase Drugs 0.000 claims abstract description 26
- 239000006184 cosolvent Substances 0.000 claims abstract description 26
- 239000003381 stabilizer Substances 0.000 claims abstract description 26
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000008367 deionised water Substances 0.000 claims abstract description 22
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 22
- 108091005804 Peptidases Proteins 0.000 claims description 19
- 239000004365 Protease Substances 0.000 claims description 19
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 19
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 12
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 12
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 12
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 239000001110 calcium chloride Substances 0.000 claims description 10
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 10
- 239000001509 sodium citrate Substances 0.000 claims description 10
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 10
- JOLVYUIAMRUBRK-UHFFFAOYSA-N 11',12',14',15'-Tetradehydro(Z,Z-)-3-(8-Pentadecenyl)phenol Natural products OC1=CC=CC(CCCCCCCC=CCC=CCC=C)=C1 JOLVYUIAMRUBRK-UHFFFAOYSA-N 0.000 claims description 9
- YLKVIMNNMLKUGJ-UHFFFAOYSA-N 3-Delta8-pentadecenylphenol Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1 YLKVIMNNMLKUGJ-UHFFFAOYSA-N 0.000 claims description 9
- JOLVYUIAMRUBRK-UTOQUPLUSA-N Cardanol Chemical compound OC1=CC=CC(CCCCCCC\C=C/C\C=C/CC=C)=C1 JOLVYUIAMRUBRK-UTOQUPLUSA-N 0.000 claims description 9
- FAYVLNWNMNHXGA-UHFFFAOYSA-N Cardanoldiene Natural products CCCC=CCC=CCCCCCCCC1=CC=CC(O)=C1 FAYVLNWNMNHXGA-UHFFFAOYSA-N 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- PTFIPECGHSYQNR-UHFFFAOYSA-N cardanol Natural products CCCCCCCCCCCCCCCC1=CC=CC(O)=C1 PTFIPECGHSYQNR-UHFFFAOYSA-N 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 8
- 239000000758 substrate Substances 0.000 claims description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- PKDCQJMRWCHQOH-UHFFFAOYSA-N triethoxysilicon Chemical compound CCO[Si](OCC)OCC PKDCQJMRWCHQOH-UHFFFAOYSA-N 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 235000019270 ammonium chloride Nutrition 0.000 claims description 4
- 238000005282 brightening Methods 0.000 claims description 4
- 235000019441 ethanol Nutrition 0.000 claims description 4
- 239000003755 preservative agent Substances 0.000 claims description 4
- 230000002335 preservative effect Effects 0.000 claims description 4
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims description 4
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004280 Sodium formate Substances 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 229940071118 cumenesulfonate Drugs 0.000 claims description 3
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000686 essence Substances 0.000 claims description 3
- 229940031098 ethanolamine Drugs 0.000 claims description 3
- -1 ethoxy compound Chemical class 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000011083 sodium citrates Nutrition 0.000 claims description 3
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 3
- 235000019254 sodium formate Nutrition 0.000 claims description 3
- 229940045944 sodium lauroyl glutamate Drugs 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 claims description 3
- 229950004288 tosilate Drugs 0.000 claims description 3
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical compound CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- XKXHCNPAFAXVRZ-UHFFFAOYSA-N benzylazanium;chloride Chemical compound [Cl-].[NH3+]CC1=CC=CC=C1 XKXHCNPAFAXVRZ-UHFFFAOYSA-N 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- PFKRTWCFCOUBHS-UHFFFAOYSA-N dimethyl(octadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[NH+](C)C PFKRTWCFCOUBHS-UHFFFAOYSA-N 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 21
- 238000004140 cleaning Methods 0.000 abstract description 7
- 230000002401 inhibitory effect Effects 0.000 abstract description 7
- 238000005406 washing Methods 0.000 abstract description 6
- 206010011409 Cross infection Diseases 0.000 abstract description 4
- 206010029803 Nosocomial infection Diseases 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 12
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 230000003213 activating effect Effects 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000002191 fatty alcohols Chemical class 0.000 description 6
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 5
- 230000035699 permeability Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- LLDFSHBCVFHQIV-UHFFFAOYSA-M dimethyl-octadecyl-propylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCC LLDFSHBCVFHQIV-UHFFFAOYSA-M 0.000 description 4
- 150000004676 glycans Chemical class 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 210000002421 cell wall Anatomy 0.000 description 3
- 239000005515 coenzyme Substances 0.000 description 3
- 238000005202 decontamination Methods 0.000 description 3
- 230000003588 decontaminative effect Effects 0.000 description 3
- 230000001408 fungistatic effect Effects 0.000 description 3
- 231100000518 lethal Toxicity 0.000 description 3
- 230000001665 lethal effect Effects 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 230000029058 respiratory gaseous exchange Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 101710112457 Exoglucanase Proteins 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229960005150 glycerol Drugs 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000002503 metabolic effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 229940071104 xylenesulfonate Drugs 0.000 description 2
- BXQNSPXDWSNUKE-UHFFFAOYSA-N 1,3-benzothiazole 1-oxide Chemical compound C1=CC=C2S(=O)C=NC2=C1 BXQNSPXDWSNUKE-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 208000005623 Carcinogenesis Diseases 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000192125 Firmicutes Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241000235342 Saccharomycetes Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 230000036952 cancer formation Effects 0.000 description 1
- 231100000504 carcinogenesis Toxicity 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000003916 ethylene diamine group Chemical group 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000028993 immune response Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 150000004804 polysaccharides Polymers 0.000 description 1
- 238000004313 potentiometry Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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Abstract
The present invention discloses a kind of liquid detergent, and by weight, which includes：5 10 parts of anion surfactant；10 20 parts of nonionic surfactant；0.5 2.0 parts of cellulase；2.0 parts of proteinase-10 .5；0.01 1.5 parts of enzyme stabilizers；0.1 1.0 parts of organosilicon quaternary ammonium salt；0.1 1.0 parts of chitosan；2.0 5.0 parts of cosolvent；30 70 parts of deionized water.The liquid detergent that technical solution of the present invention provides not only has preferable cleaning function, moreover it is possible to effectively play inhibiting effect to the bacterium on clothing, cross-infection occurs for various bacteriums when so as to avoid machine washing on each part clothing.
Description
Technical field
The present invention relates to daily-use chemical industry technical field, more particularly to a kind of liquid detergent.
Background technology
With the continuous improvement of living standards, people wash clothing by the way of machine washing more and more.It is doing washing
In the process, all it is often to wash the immersion of more than one piece clothing together, the various bacteriums on every clothing in this way are easy to happen
Cross-infection, and liquid detergent on the market generally all only has the functions such as clean or skin care at present, it cannot be very well to thin on clothing
Bacterium reaches inhibiting effect.
Invention content
The main object of the present invention is to propose that a kind of liquid detergent, the liquid detergent can reach effectively the bacterium on clothing
Inhibiting effect.
To achieve the above object, the present invention proposes a kind of liquid detergent, and by weight, which includes：
5-10 parts of anion surfactant；
10-20 parts of nonionic surfactant；
0.5-2.0 parts of cellulase；
.5-2.0 parts of proteinase-10；
0.01-1.5 parts of enzyme stabilizers；
0.1-1.0 parts of organosilicon quaternary ammonium salt；
0.1-1.0 parts of chitosan；
2.0-5.0 parts of cosolvent；
30-70 parts of deionized water.
Preferably, by weight percentage, the liquid detergent includes：
5-10 parts of anion surfactant；
10-15 parts of nonionic surfactant；
1.0-1.5 parts of cellulase；
1.0-1.5 parts of protease；
0.01-1.5 parts of enzyme stabilizers；
0.5-1.0 parts of organosilicon quaternary ammonium salt；
0.5-1.0 parts of chitosan；
2.0-5.0 parts of cosolvent；
30-70 parts of deionized water.
Preferably, the organosilicon quaternary ammonium salt include 3- (trimethoxy silicon substrate) propyl octadecyldimethyls ammonium chloride,
Any one in 3- (triethoxy silicon substrate) propyl octadecyldimethyls ammonium chloride, dodecyl benzyl dimethyl ammonium chloride
Or a variety of composition.
Preferably, the anion surfactant includes sodium sulfate of polyethenoxy ether of fatty alcohol, fatty acid methyl ester ethoxy
In glycolylate sodium sulfonate, methyl sodiosul foaliphatate and sodium lauroyl glutamate any one or combinations thereof object.
Preferably, the nonionic surfactant includes fatty alcohol polyoxyethylene ether, cardanol polyoxyethylene ether, fat
In sour methyl esters ethoxy compound any one or combinations thereof object.
Preferably, the enzyme stabilizers include calcium chloride, sodium tetraborate, propylene glycol, sodium formate, sodium citrate, ethanol amine
In the composition of any one or more.
Preferably, the cosolvent includes tosilate, xylenesulfonate, cumene sulfonate, glycerine, second
The composition of any one or more in alcohol, isopropanol.
Preferably, the liquid detergent further includes additive, and the parts by weight of the additive are 0.1-5.0 parts, described to add
It includes the composition of any one or more in brightening agent, preservative, essence to add agent.
The liquid detergent that technical solution of the present invention provides not only has preferable cleaning function, moreover it is possible to effectively on clothing
Bacterium play inhibiting effect, cross-infection occurs for various bacteriums when so as to avoid machine washing on each part clothing.It is specific and
Spot is resolved into that volume is smaller, is easily removed by the way that cellulase and protease is added by speech, liquid detergent of the invention
Ingredient achievees the effect that decontamination, to improving the cleaning function of liquid detergent；Meanwhile liquid detergent of the invention is by using shell
The relatively strong thermophilic film property of glycan changes the permeability of bacterium, causes its content to leak and causes its death；Utilize organosilicone quaternary ammonium
Salt is forcefully adsorbed in the surface of bacterium, changes the permeability of bacteria cell wall, keeps endobacillary enzyme, coenzyme and metabolism intermediate
Product overflows, and causes microorganism to cease breathing function and lethal, to reach the inhibiting effect to bacterium.
Specific implementation mode
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is general
The every other embodiment that logical technical staff is obtained without creative efforts belongs to what the present invention protected
Range.
In addition, the technical solution between each embodiment can be combined with each other, but must be with ordinary skill
Personnel can be implemented as basis, will be understood that this technical side when the combination of technical solution appearance is conflicting or cannot achieve
The combination of case is not present, also not the present invention claims protection domain within.
The present invention proposes a kind of liquid detergent, not only has preferable cleaning function, moreover it is possible to effectively to thin on clothing
Bacterium plays inhibiting effect, and cross-infection occurs for various bacteriums when so as to avoid machine washing on each part clothing.
Liquid detergent proposed by the present invention, by weight, including：5-10 parts of anion surfactant；Non-ionic surface
10-20 parts of activating agent；0.5-2.0 parts of cellulase；.5-2.0 parts of proteinase-10；0.01-1.5 parts of enzyme stabilizers；Organosilicone quaternary ammonium
0.1-1.0 parts of salt；0.1-1.0 parts of chitosan；2.0-5.0 parts of cosolvent；30-70 parts of deionized water.
Preferably, by weight percentage, the liquid detergent includes：5-10 parts of anion surfactant；Non-ionic surface
10-15 parts of activating agent；1.0-1.5 parts of cellulase；1.0-1.5 parts of protease；0.01-1.5 parts of enzyme stabilizers；Organosilicone quaternary ammonium
0.5-1.0 parts of salt；0.5-1.0 parts of chitosan；2.0-5.0 parts of cosolvent；30-70 parts of deionized water.
In general, in order to improve washing effect, frequently with anion surfactant and nonionic surfactant into
Row compounding, anion surfactant is conducive to remove fine dust particles, and nonionic surface active agent then contributes to clearly
Except grease type dirt.Wherein, the anion surfactant includes sodium sulfate of polyethenoxy ether of fatty alcohol, fatty acid methyl ester second
In oxygroup compound sodium sulfonate, methyl sodiosul foaliphatate and sodium lauroyl glutamate any one or combinations thereof object.It is described
Nonionic surfactant includes fatty alcohol polyoxyethylene ether, cardanol polyoxyethylene ether, fatty acid methyl ester ethoxy compound
In any one or combinations thereof object.
Enzyme is added in liquid detergent and assists in removing spot and dust, it is dirty by such as bloodstain, careless stain and meat soup spot
Stain resolves into the ingredient that volume is smaller, is easily removed to achieve the effect that decontamination.Wherein, the detergency mechanism of cellulase is interior
It cuts with exoglucanase collective effect in cellulose, endoglucanase acts on the amorphous region of cellulose fibre, will be fine
The plain macromolecular of dimension truncates, and generates new polysaccharide chain end；Exoglucanase act on fibrination sugar chain reduction or it is non-also
Former end, cuts cellulose, generates cellobiose and glucose.The detergency mechanism of protease is to be hydrolyzed to protein
Peptide chain and amino acid easy to dissolve or be scattered in detergent solution.
Further include enzyme stabilizers to make the property temperature of various enzymes, the liquid detergent.Wherein, the enzyme stabilizers include
The composition of any one or more in calcium chloride, sodium tetraborate, propylene glycol, sodium formate, sodium citrate, ethanol amine.
In addition, in order to improve the solubility of surfactant component, the liquid detergent of stable transparent is made, the liquid detergent is also
Including cosolvent.Specifically, the cosolvent include tosilate, xylenesulfonate, cumene sulfonate, glycerine,
The composition of any one or more in ethyl alcohol, isopropanol.
Organosilicon quaternary ammonium salt and chitosan are added in liquid detergent, then can improve the antibacterial effect of the liquid detergent.Shell is poly-
Sugared (CS) is alkaline polysaccharide existing for nature, has superior biocompatibility, a biodegradability, and catabolite without
Poison, without immune response, non-carcinogenesis, there is broad-spectrum antibacterial action, especially to gram-positive bacterium significant effect.To cause of disease
Microorganism has very strong thermophilic film property, adsorbs, merges with membranous structure, changes its permeability, its content is caused to leak and cause it
It is dead；Have broad-spectrum antiseptic, antiviral activity, pathogenic microorganism is not easy to generate drug resistance to it.
Organosilicon quaternary ammonium salt is a kind of Novel Cationic Surfactants, it has high temperature resistant, water-fastness, lasting effect
Fruit, scope of restraining fungi are wide, can effectively inhibit gram-positive bacteria, Gram-negative bacteria, saccharomycete and fungi.Its sterilization mechanism
It is：Using organosilicon as medium, ammonium cation group with bactericidal property is forcefully adsorbed in the surface of bacterium, is changed
The permeability of bacteria cell wall makes endobacillary enzyme, coenzyme and metabolic intermediate overflow, and microorganism is caused to cease breathing function
And it is lethal, to have the function that sterilization, it is antibacterial.In the present embodiment, the organosilicon quaternary ammonium salt includes 3- (trimethoxy silicon
Base) propyl octadecyldimethyl ammonium chloride, 3- (triethoxy silicon substrate) propyl octadecyldimethyls ammonium chloride, dodecyl
The composition of any one or more in dimethyl benzyl ammonium chloride.
It is to be appreciated that the liquid detergent of the present invention changes the penetrating of bacterium by using the relatively strong thermophilic film property of chitosan
Property, cause its content to leak and causes its death；It is forcefully adsorbed in the surface of bacterium using organosilicon quaternary ammonium salt, changes thin
The permeability of bacterium cell wall makes endobacillary enzyme, coenzyme and metabolic intermediate overflow, cause microorganism cease breathing function and
It is lethal, the inhibiting effect to bacterium is reached with this.
Further, the liquid detergent further includes additive, and the parts by weight of the additive are 0.1-5.0 parts, described
Additive includes the composition of any one or more in brightening agent, preservative, essence.Wherein, brightening agent is ethylenediamine tetraacetic
Sodium acetate, preservative are benzothiazolinone, and essence is water-soluble essence.
The present invention also provides a kind of preparation methods of liquid detergent, are used to prepare above-mentioned liquid detergent.The preparation method includes
Following steps：
Deionized water is added in reaction kettle according to mass fraction, anionic surface is then added into reaction kettle again lives
Property agent, nonionic surfactant, cosolvent, are stirred at a temperature of 50-60 DEG C；Wait for that each raw material is completely dissolved and is uniformly mixed
Afterwards, 30-40 DEG C is cooled the temperature to, then chitosan and organosilicon quaternary ammonium salt are added into reaction kettle, continues to stir 10min；Then
Cellulase and protease are added, is filtered after stirring evenly, you can obtain liquid detergent.
Wherein, the mass fraction of above-mentioned main component is as follows：5-10 parts of anion surfactant；Non-ionic surface active
10-20 parts of agent；0.5-2.0 parts of cellulase；.5-2.0 parts of proteinase-10；0.01-1.5 parts of enzyme stabilizers；Organosilicon quaternary ammonium salt
0.1-1.0 parts；0.1-1.0 parts of chitosan；2.0-5.0 parts of cosolvent；30-70 parts of deionized water.
Technical scheme of the present invention is further elaborated below in conjunction with specific embodiment.
Embodiment 1：
A kind of liquid detergent, by weight, including：5 parts of anion surfactant；10 parts of nonionic surfactant；
0.5 part of cellulase；.5 parts of proteinase-10；0.01 part of enzyme stabilizers；1.0 parts of organosilicon quaternary ammonium salt；0.1 part of chitosan；Cosolvent
2.0 part；30 parts of deionized water.
Wherein, the anion surfactant is sodium sulfate of polyethenoxy ether of fatty alcohol, the non-ionic surface active
Agent is fatty alcohol polyoxyethylene ether, and the enzyme stabilizers are calcium chloride and sodium citrate, and the organosilicon quaternary ammonium salt is 3- (front threes
Oxygroup silicon substrate) propyl octadecyldimethyl ammonium chloride.
The preparation method of the liquid detergent：Deionized water is added in reaction kettle according to mass fraction, then again to reaction
Anion surfactant, nonionic surfactant, cosolvent are added in kettle, is stirred at a temperature of 50-60 DEG C；Wait for each raw material
It is completely dissolved and after mixing, cools the temperature to 30-40 DEG C, then chitosan and organosilicon quaternary ammonium salt are added into reaction kettle,
Continue to stir 10min；Then cellulase and protease are added, is filtered after stirring evenly, you can obtain liquid detergent.
Embodiment 2：
A kind of liquid detergent, by weight, including：8.0 parts of anion surfactant；Nonionic surfactant 15
Part；1.0 parts of cellulase；1.0 parts of protease；0.1 part of enzyme stabilizers；0.1 part of organosilicon quaternary ammonium salt；1.0 parts of chitosan；Hydrotropy
3.0 parts of agent；60 parts of deionized water.
Wherein, the anion surfactant is fatty acid methyl ester ethoxylate sodium sulfonate, the non-ionic surface
Activating agent is cardanol polyoxyethylene ether, and the enzyme stabilizers are calcium chloride and sodium citrate, and the organosilicon quaternary ammonium salt is 3-
(triethoxy silicon substrate) propyl octadecyldimethyl ammonium chloride.
The preparation method of the liquid detergent：Deionized water is added in reaction kettle according to mass fraction, then again to reaction
Anion surfactant, nonionic surfactant, cosolvent are added in kettle, is stirred at a temperature of 50-60 DEG C；Wait for each raw material
It is completely dissolved and after mixing, cools the temperature to 30-40 DEG C, then chitosan and organosilicon quaternary ammonium salt are added into reaction kettle,
Continue to stir 10min；Then cellulase and protease are added, is filtered after stirring evenly, you can obtain liquid detergent.
Embodiment 3：
A kind of liquid detergent, by weight, including：9 parts of anion surfactant；20 parts of nonionic surfactant；
1.5 parts of cellulase；1.5 parts of protease；1.0 parts of enzyme stabilizers；0.5 part of organosilicon quaternary ammonium salt；0.5 part of chitosan；Cosolvent
5.0 part；70 parts of deionized water.
Wherein, the anion surfactant is fatty acid methyl ester ethoxylate sodium sulfonate, the non-ionic surface
Activating agent is cardanol polyoxyethylene ether, and the enzyme stabilizers are calcium chloride and sodium citrate, and the organosilicon quaternary ammonium salt is ten
Dialkyl dimethyl benzyl ammonium chloride.
The preparation method of the liquid detergent：Deionized water is added in reaction kettle according to mass fraction, then again to reaction
Anion surfactant, nonionic surfactant, cosolvent are added in kettle, is stirred at a temperature of 50-60 DEG C；Wait for each raw material
It is completely dissolved and after mixing, cools the temperature to 30-40 DEG C, then chitosan and organosilicon quaternary ammonium salt are added into reaction kettle,
Continue to stir 10min；Then cellulase and protease are added, is filtered after stirring evenly, you can obtain liquid detergent.
Embodiment 4：
A kind of liquid detergent, by weight, including：10 parts of anion surfactant；20 parts of nonionic surfactant；
2.0 parts of cellulase；2.0 parts of protease；1.5 parts of enzyme stabilizers；1.0 parts of organosilicon quaternary ammonium salt；1.0 parts of chitosan；Cosolvent
5.0 part；40 parts of deionized water.
Wherein, the anion surfactant is fatty acid methyl ester ethoxylate sodium sulfonate, the non-ionic surface
Activating agent is cardanol polyoxyethylene ether, and the enzyme stabilizers are calcium chloride and sodium citrate, and the organosilicon quaternary ammonium salt is ten
Dialkyl dimethyl benzyl ammonium chloride.
The preparation method of the liquid detergent：Deionized water is added in reaction kettle according to mass fraction, then again to reaction
Anion surfactant, nonionic surfactant, cosolvent are added in kettle, is stirred at a temperature of 50-60 DEG C；Wait for each raw material
It is completely dissolved and after mixing, cools the temperature to 30-40 DEG C, then chitosan and organosilicon quaternary ammonium salt are added into reaction kettle,
Continue to stir 10min；Then cellulase and protease are added, is filtered after stirring evenly, you can obtain liquid detergent.
Comparative example 1：
A kind of liquid detergent, by weight, including：10 parts of anion surfactant；20 parts of nonionic surfactant；
2.0 parts of cellulase；2.0 parts of protease；1.5 parts of enzyme stabilizers；1.0 parts of chitosan；5.0 parts of cosolvent；40 parts of deionized water.
Wherein, the anion surfactant is fatty acid methyl ester ethoxylate sodium sulfonate, the non-ionic surface
Activating agent is cardanol polyoxyethylene ether, and the enzyme stabilizers are calcium chloride and sodium citrate, and the organosilicon quaternary ammonium salt is ten
Dialkyl dimethyl benzyl ammonium chloride.
The preparation method of the liquid detergent：Deionized water is added in reaction kettle according to mass fraction, then again to reaction
Anion surfactant, nonionic surfactant, cosolvent are added in kettle, is stirred at a temperature of 50-60 DEG C；Wait for each raw material
It is completely dissolved and after mixing, cools the temperature to 30-40 DEG C, then chitosan is added into reaction kettle, continue to stir 10min；
Then cellulase and protease are added, is filtered after stirring evenly, you can obtain liquid detergent.
Comparative example 2：
A kind of liquid detergent, by weight, including：10 parts of anion surfactant；20 parts of nonionic surfactant；
2.0 parts of cellulase；2.0 parts of protease；1.5 parts of enzyme stabilizers；1.0 parts of organosilicon quaternary ammonium salt；5.0 parts of cosolvent；Deionization
40 parts of water.
Wherein, the anion surfactant is fatty acid methyl ester ethoxylate sodium sulfonate, the non-ionic surface
Activating agent is cardanol polyoxyethylene ether, and the enzyme stabilizers are calcium chloride and sodium citrate, and the organosilicon quaternary ammonium salt is ten
Dialkyl dimethyl benzyl ammonium chloride.
The preparation method of the liquid detergent：Deionized water is added in reaction kettle according to mass fraction, then again to reaction
Anion surfactant, nonionic surfactant, cosolvent are added in kettle, is stirred at a temperature of 50-60 DEG C；Wait for each raw material
It is completely dissolved and after mixing, cools the temperature to 30-40 DEG C, then organosilicon quaternary ammonium salt is added into reaction kettle, continue to stir
10min；Then cellulase and protease are added, is filtered after stirring evenly, you can obtain liquid detergent.
Comparative example 3：
A kind of liquid detergent, by weight, including：10 parts of anion surfactant；20 parts of nonionic surfactant；
2.0 parts of protease；1.5 parts of enzyme stabilizers；1.0 parts of organosilicon quaternary ammonium salt；1.0 parts of chitosan；5.0 parts of cosolvent；Deionized water
40 parts.
Wherein, the anion surfactant is fatty acid methyl ester ethoxylate sodium sulfonate, the non-ionic surface
Activating agent is cardanol polyoxyethylene ether, and the enzyme stabilizers are calcium chloride and sodium citrate, and the organosilicon quaternary ammonium salt is 3-
(triethoxy silicon substrate) propyl octadecyldimethyl ammonium chloride.
The preparation method of the liquid detergent：Deionized water is added in reaction kettle according to mass fraction, then again to reaction
Anion surfactant, nonionic surfactant, cosolvent are added in kettle, is stirred at a temperature of 50-60 DEG C；Wait for each raw material
It is completely dissolved and after mixing, cools the temperature to 30-40 DEG C, then chitosan and organosilicon quaternary ammonium salt are added into reaction kettle,
Continue to stir 10min；Then add protease again, filtered after stirring evenly, you can obtain liquid detergent.
It is right to aforementioned four embodiment and three in order to verify the clean performance and anti-microbial property of liquid detergent of the present invention
The performance of liquid detergent in ratio is tested.It is specific as follows：
(1) detergency test
According to QB/T 1224-2012《Dress material washes agent by liquid》Defined method, to embodiment 1 to embodiment 4,
And the liquid detergent (0.2% aqueous solution) of comparison 1 to comparative example 3 carries out detergency test.
1 detergency test table of table
As shown in Table 1, the decontamination force value for the liquid detergent that the embodiment of the present invention 1 is prepared to embodiment 4 is larger, illustrates this hair
Bright liquid detergent has preferable cleaning ability.Also, embodiment 1 to embodiment 4 is added to chitosan and organosilicon quaternary ammonium salt,
And comparative example 1 is without addition organosilicon quaternary ammonium salt, the no addition chitosan of comparative example 2, it can thus be seen that addition organosilicon season
Ammonium salt and chitosan can further increase the cleaning ability of liquid detergent.
(2) anti-microbial property test
According to QB/T 2738-2012《The evaluation method of daily chemical products antibacterial bacteriostatic effect》, to embodiment 1 to embodiment
4, and comparison 1 to comparative example 3 liquid detergent (0.2% aqueous solution) carry out fungistatic effect test, as a result as shown in table 2 below.
2 fungistatic effect of table tests table
According to QB/T 2738-2012《The evaluation method of daily chemical products antibacterial bacteriostatic effect》Regulation, product bacteriostasis rate >=
50% -90% is to have bacteriostasis, and product bacteriostasis rate >=90% is to have stronger bacteriostasis.As shown in Table 2, embodiment 1,
2,3,4 all have stronger fungistatic effect.Also, the embodiment of the present invention 1 to embodiment 4 is added to chitosan and organosilicon season
Ammonium salt, and comparative example 1 is without addition organosilicon quaternary ammonium salt, the no addition chitosan of comparative example 2, it follows that adding shell simultaneously
Glycan and organosilicon quaternary ammonium salt are conducive to the antibacterial effect for improving the liquid detergent.Meanwhile it is poly- to be added to shell in comparative example 3 simultaneously
Sugar and organosilicon quaternary ammonium salt, but without addition cellulase, it follows that addition cellulase is also beneficial to improve liquid detergent
Antibacterial effect also illustrates that cellulase, chitosan, which have the antibacterial effect for improving liquid detergent with organosilicon quaternary ammonium salt, to be cooperateed with
Effect.
(3) pH value is tested
According to GB/T 6368《The measurement potentiometry of aqueous surfactant solution pH value》Regulation, to embodiment 1 to implementation
Example 4, and the liquid detergent of comparison 1 to comparative example 3 carry out pH value test respectively.
According to table 2 it is found that the pH value range of liquid detergent prepared by the embodiment of the present invention 1 to embodiment 4 is 6.8~7.5, it is in
It is neutral；And the pH value of comparative example 3 is all higher than 9, alkalinity is stronger.Therefore it can obtain, when the pH value of the liquid detergent is 6.8~7.5
When, which has preferable cleaning function, and can also effectively inhibit the bacterial growth on clothing.
The foregoing is merely the preferred embodiment of the present invention, are not intended to limit the scope of the invention, every at this
Under the inventive concept of invention, using equivalent structure transformation made by present specification, or directly/it is used in other indirectly
Relevant technical field is included in the scope of patent protection of the present invention.
Claims (8)
1. a kind of liquid detergent, which is characterized in that by weight, which includes：
5-10 parts of anion surfactant；
10-20 parts of nonionic surfactant；
0.5-2.0 parts of cellulase；
.5-2.0 parts of proteinase-10；
0.01-1.5 parts of enzyme stabilizers；
0.1-1.0 parts of organosilicon quaternary ammonium salt；
0.1-1.0 parts of chitosan；
2.0-5.0 parts of cosolvent；
30-70 parts of deionized water.
2. liquid detergent as described in claim 1, which is characterized in that by weight percentage, the liquid detergent includes：
5-10 parts of anion surfactant；
10-15 parts of nonionic surfactant；
1.0-1.5 parts of cellulase；
1.0-1.5 parts of protease；
0.01-1.5 parts of enzyme stabilizers；
0.5-1.0 parts of organosilicon quaternary ammonium salt；
0.5-1.0 parts of chitosan；
2.0-5.0 parts of cosolvent；
30-70 parts of deionized water.
3. the liquid detergent stated such as claim 2, which is characterized in that the organosilicon quaternary ammonium salt includes 3- (trimethoxy silicon substrate) third
Base octadecyldimethyl ammonium chloride, 3- (triethoxy silicon substrate) propyl octadecyldimethyls ammonium chloride, dimethyl
The composition of any one or more in base benzyl ammonium chloride.
4. the liquid detergent stated such as claim 2, which is characterized in that the anion surfactant includes aliphatic alcohol polyethenoxy
Appointing in ether sodium sulfate, fatty acid methyl ester ethoxylate sodium sulfonate, methyl sodiosul foaliphatate and sodium lauroyl glutamate
One kind of anticipating or combinations thereof object.
5. the liquid detergent stated such as claim 2, which is characterized in that the nonionic surfactant includes aliphatic alcohol polyethenoxy
In ether, cardanol polyoxyethylene ether, fatty acid methyl ester ethoxy compound any one or combinations thereof object.
6. the liquid detergent stated such as claim 2, which is characterized in that the enzyme stabilizers include calcium chloride, sodium tetraborate, the third two
The composition of any one or more in alcohol, sodium formate, sodium citrate, ethanol amine.
7. the liquid detergent stated such as claim 2, which is characterized in that the cosolvent includes tosilate, xylene monosulfonic acid
The composition of any one or more in salt, cumene sulfonate, glycerine, ethyl alcohol, isopropanol.
8. the liquid detergent stated such as claim 1, which is characterized in that the liquid detergent further includes additive, the weight of the additive
It is 0.1-5.0 parts to measure number, and the additive includes the composition of any one or more in brightening agent, preservative, essence.
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Application publication date: 20180720 |