CN108231816A - Imaging sensor and the method for forming imaging sensor - Google Patents
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Abstract
本公开涉及一种图像传感器,其包括:第一光电二极管,用于转换第一波段的光,所述第一光电二极管的第一部分由第一半导体材料形成,所述第一光电二极管的第二部分由第二半导体材料形成;以及第二光电二极管,用于转换第二波段的光,所述第二光电二极管由第二半导体材料形成,其中,所述第一波段的至少部分波长大于所述第二波段的波长,所述第一半导体材料的能带隙小于所述第二半导体材料的能带隙。本公开还涉及一种形成图像传感器的方法。本公开能够提高量子效率以及减少光的串扰。
The present disclosure relates to an image sensor, which includes: a first photodiode for converting light in a first wavelength band, a first part of the first photodiode is formed of a first semiconductor material, a second part of the first photodiode formed in part of a second semiconductor material; and a second photodiode for converting light in a second wavelength band, the second photodiode formed of a second semiconductor material, wherein at least a portion of the first wavelength band has a wavelength greater than that of the For the wavelength of the second band, the energy band gap of the first semiconductor material is smaller than the energy band gap of the second semiconductor material. The present disclosure also relates to a method of forming an image sensor. The present disclosure can improve quantum efficiency and reduce crosstalk of light.
Description
技术领域technical field
本公开涉及半导体技术领域,具体来说,涉及一种图像传感器及形成图像传感器的方法。The present disclosure relates to the technical field of semiconductors, and in particular, to an image sensor and a method for forming the image sensor.
背景技术Background technique
入射光在图像传感器的光电二极管中有可能未被完全吸收,存在一部分光会穿透光电二极管。这会造成量子效率降低,并且穿透光电二极管的这部分光有可能会进入其他的光电二极管而造成光的串扰。The incident light may not be completely absorbed in the photodiode of the image sensor, and some light may pass through the photodiode. This will cause a decrease in quantum efficiency, and the part of the light that penetrates the photodiode may enter other photodiodes and cause light crosstalk.
因此,存在对新技术的需求。Therefore, there is a need for new technology.
发明内容Contents of the invention
本公开的一个目的是提供一种新型的图像传感器及形成图像传感器的方法。An object of the present disclosure is to provide a novel image sensor and a method of forming the image sensor.
根据本公开的第一方面,提供了一种图像传感器,包括:第一光电二极管,用于转换第一波段的光,所述第一光电二极管的第一部分由第一半导体材料形成,所述第一光电二极管的第二部分由第二半导体材料形成;以及第二光电二极管,用于转换第二波段的光,所述第二光电二极管由第二半导体材料形成,其中,所述第一波段的至少部分波长大于所述第二波段的波长,所述第一半导体材料的能带隙小于所述第二半导体材料的能带隙。According to a first aspect of the present disclosure, there is provided an image sensor, including: a first photodiode for converting light in a first wavelength band, a first part of the first photodiode is formed of a first semiconductor material, and the first photodiode A second portion of a photodiode is formed of a second semiconductor material; and a second photodiode for converting light in a second wavelength band, the second photodiode is formed of a second semiconductor material, wherein the light of the first wavelength band At least some of the wavelengths are greater than the wavelengths of the second band, and the energy band gap of the first semiconductor material is smaller than the energy band gap of the second semiconductor material.
根据本公开的第二方面,提供了一种形成图像传感器的方法,包括:在半导体衬底中形成第一光电二极管的第二部分和第二光电二极管,其中,所述第一光电二极管用于转换第一波段的光,所述第二光电二极管用于转换第二波段的光,所述半导体衬底由第二半导体材料形成;以及在所述第二部分之上形成覆盖所述第二部分的所述第一光电二极管的第一部分,其中,所述第一部分由第一半导体材料形成,其中,所述第一波段的至少部分波长大于所述第二波段的波长,所述第一半导体材料的能带隙小于所述第二半导体材料的能带隙。According to a second aspect of the present disclosure, there is provided a method of forming an image sensor, comprising: forming a second portion of a first photodiode and a second photodiode in a semiconductor substrate, wherein the first photodiode is used for converting light of a first wavelength band, the second photodiode is used for converting light of a second wavelength band, the semiconductor substrate is formed of a second semiconductor material; The first portion of the first photodiode, wherein the first portion is formed of a first semiconductor material, wherein at least part of the wavelength of the first wavelength band is greater than the wavelength of the second wavelength band, and the first semiconductor material The energy band gap is smaller than the energy band gap of the second semiconductor material.
通过以下参照附图对本公开的示例性实施例的详细描述,本公开的其它特征及其优点将会变得清楚。Other features of the present disclosure and advantages thereof will become apparent through the following detailed description of exemplary embodiments of the present disclosure with reference to the accompanying drawings.
附图说明Description of drawings
构成说明书的一部分的附图描述了本公开的实施例,并且连同说明书一起用于解释本公开的原理。The accompanying drawings, which constitute a part of this specification, illustrate the embodiments of the disclosure and together with the description serve to explain the principles of the disclosure.
参照附图,根据下面的详细描述,可以更加清楚地理解本公开,其中:The present disclosure can be more clearly understood from the following detailed description with reference to the accompanying drawings, in which:
图1是示意性地示出根据本公开的一个实施例的图像传感器的结构的示意图。FIG. 1 is a schematic diagram schematically showing the structure of an image sensor according to one embodiment of the present disclosure.
图2至5分别是示意性地示出根据本公开的一个实施例的图像传感器中的第一光电二极管的结构的示意图。2 to 5 are diagrams schematically showing the structure of a first photodiode in an image sensor according to an embodiment of the present disclosure, respectively.
图6是示意性地示出根据本公开的一个实施例的图像传感器的结构的示意图。FIG. 6 is a diagram schematically showing the structure of an image sensor according to one embodiment of the present disclosure.
图7至10是分别示出了在根据本公开一个示例性实施例来形成图像传感器的一个方法示例的各个步骤处的图像传感器的截面的示意图。7 to 10 are schematic diagrams respectively showing cross sections of an image sensor at respective steps of an example of a method of forming an image sensor according to an exemplary embodiment of the present disclosure.
图11是示意性地示出根据本公开的一个实施例的图像传感器的结构的示意图。FIG. 11 is a schematic diagram schematically showing the structure of an image sensor according to one embodiment of the present disclosure.
图12至14是分别示出了在根据本公开一个示例性实施例来形成图像传感器的一个方法示例的各个步骤处的图像传感器的截面的示意图。12 to 14 are schematic diagrams each showing a cross-section of an image sensor at respective steps of an example of a method of forming an image sensor according to an exemplary embodiment of the present disclosure.
注意,在以下说明的实施方式中,有时在不同的附图之间共同使用同一附图标记来表示相同部分或具有相同功能的部分,而省略其重复说明。在本说明书中,使用相似的标号和字母表示类似项,因此,一旦某一项在一个附图中被定义,则在随后的附图中不需要对其进行进一步讨论。Note that in the embodiments described below, the same reference numerals may be used in common between different drawings to denote the same parts or parts having the same functions, and repeated descriptions thereof will be omitted. In this specification, similar reference numerals and letters are used to refer to similar items, therefore, once an item is defined in one figure, it does not require further discussion in subsequent figures.
为了便于理解,在附图等中所示的各结构的位置、尺寸及范围等有时不表示实际的位置、尺寸及范围等。因此,所公开的发明并不限于附图等所公开的位置、尺寸及范围等。In order to facilitate understanding, the position, size, range, etc. of each structure shown in the drawings and the like may not represent the actual position, size, range, and the like. Therefore, the disclosed invention is not limited to the positions, dimensions, ranges, etc. disclosed in the drawings and the like.
具体实施方式Detailed ways
现在将参照附图来详细描述本公开的各种示例性实施例。应注意到:除非另外具体说明,否则在这些实施例中阐述的部件和步骤的相对布置、数字表达式和数值不限制本公开的范围。Various exemplary embodiments of the present disclosure will now be described in detail with reference to the accompanying drawings. It should be noted that relative arrangements of components and steps, numerical expressions and numerical values set forth in these embodiments do not limit the scope of the present disclosure unless specifically stated otherwise.
以下对至少一个示例性实施例的描述实际上仅仅是说明性的,决不作为对本公开及其应用或使用的任何限制。The following description of at least one exemplary embodiment is merely illustrative in nature and in no way intended as any limitation of the disclosure, its application or uses.
对于相关领域普通技术人员已知的技术、方法和设备可能不作详细讨论,但在适当情况下,所述技术、方法和设备应当被视为授权说明书的一部分。Techniques, methods and devices known to those of ordinary skill in the relevant art may not be discussed in detail, but where appropriate, such techniques, methods and devices should be considered part of the Authorized Specification.
在这里示出和讨论的所有示例中,任何具体值应被解释为仅仅是示例性的,而不是作为限制。因此,示例性实施例的其它示例可以具有不同的值。In all examples shown and discussed herein, any specific values should be construed as illustrative only, and not as limiting. Therefore, other examples of the exemplary embodiment may have different values.
在本公开中,对“一个实施例”、“一些实施例”的提及意味着结合该实施例描述的特征、结构或特性包含在本公开的至少一个实施例、至少一些实施例中。因此,短语“在一个实施例中”、“在一些实施例中”在本公开的各处的出现未必是指同一个或同一些实施例。此外,在一个或多个实施例中,可以任何合适的组合和/或子组合来组合特征、结构或特性。In the present disclosure, reference to "one embodiment" or "some embodiments" means that a feature, structure, or characteristic described in connection with the embodiment is included in at least one embodiment, at least some embodiments of the present disclosure. Thus, appearances of the phrase "in one embodiment" and "in some embodiments" in various places in this disclosure are not necessarily referring to the same embodiment or embodiments. Furthermore, features, structures or characteristics may be combined in any suitable combination and/or subcombination in one or more embodiments.
如图1所示,本公开的图像传感器包括第一光电二极管10和第二光电二极管20。其中,第一光电二极管10用于转换第一波段的光,第二光电二极管20用于转换第二波段的光。第一光电二极管10的第一部分11由第一半导体材料形成,其第二部分12由第二半导体材料形成。第二光电二极管20由第二半导体材料形成。其中,第一波段的至少部分波长大于第二波段的波长,第一半导体材料的能带隙(energy bandgap)小于第二半导体材料的能带隙。As shown in FIG. 1 , the image sensor of the present disclosure includes a first photodiode 10 and a second photodiode 20 . Wherein, the first photodiode 10 is used for converting the light of the first wavelength band, and the second photodiode 20 is used for converting the light of the second wavelength band. A first part 11 of the first photodiode 10 is formed from a first semiconductor material and a second part 12 thereof is formed from a second semiconductor material. The second photodiode 20 is formed of a second semiconductor material. Wherein, at least part of the wavelengths of the first waveband is greater than the wavelength of the second waveband, and the energy bandgap of the first semiconductor material is smaller than the energy bandgap of the second semiconductor material.
具有更小的能带隙的半导体材料,其中的电子由价带被激发到导带(conductionband)所必须获得的最低能量更小,即越容易被激发,因此也越容易吸收进入其中的光。同样厚度的半导体材料,具有更小的能带隙的半导体材料通常能够吸收比具有更大的能带隙的半导体材料更多的光。由于波长越长的光越难被吸收,所以完全吸收波长较长的光通常需要比完全吸收波长较短的光更厚的光电二极管。因此在根据这些实施例的图像传感器中,用于吸收波长较长的光的光电二极管中的一部分由能带隙较小的半导体材料形成,从而使得在不增加(或不过于增加)光电二极管的厚度的情况下,波长较长的光也能够被完全吸收。In a semiconductor material with a smaller energy band gap, the minimum energy that electrons must obtain to be excited from the valence band to the conduction band is smaller, that is, the easier it is to be excited, and therefore the easier it is to absorb light entering it. For the same thickness of semiconductor material, a semiconductor material with a smaller energy band gap can generally absorb more light than a semiconductor material with a larger energy band gap. Since longer wavelength light is harder to absorb, fully absorbing longer wavelength light typically requires a thicker photodiode than shorter wavelength light. Therefore, in the image sensor according to these embodiments, a part of the photodiode for absorbing light with a longer wavelength is formed of a semiconductor material with a smaller energy bandgap, so that the photodiode is not increased (or is not increased too much) In the case of thickness, light with a longer wavelength can also be completely absorbed.
在根据这些实施例的图像传感器中,在一些例子里,第一光电二极管10用于转换的第一波段的光可以是红光,第二光电二极管20用于转换的第二波段的光可以是绿光和/或蓝光;在另一些例子里,第一光电二极管10用于转换的第一波段的光可以是红外光,第二光电二极管20用于转换的第二波段的光可以是红光、绿光和/或蓝光;在又一些例子里,第一光电二极管10用于转换的第一波段的光可以是红光和红外光,第二光电二极管20用于转换的第二波段的光可以是绿光和/或蓝光;在又一些例子里,第一光电二极管10用于转换的第一波段的光可以是红外光、红光、绿光和/或蓝光,第二光电二极管20用于转换的第二波段的光可以是紫外光。本领域技术人员可以理解,以上例子只是示例性的并不是限制性的也不是穷举性的,只要满足第一波段的全部或部分波长大于第二波段的波长即可。In the image sensor according to these embodiments, in some examples, the light of the first wavelength band converted by the first photodiode 10 may be red light, and the light of the second wavelength band used by the second photodiode 20 may be Green light and/or blue light; in some other examples, the light of the first wavelength band used for conversion by the first photodiode 10 may be infrared light, and the light of the second wavelength band used for conversion by the second photodiode 20 may be red light , green light and/or blue light; in still some examples, the light of the first waveband that the first photodiode 10 is used for conversion can be red light and infrared light, and the light of the second waveband that the second photodiode 20 is used for conversion Can be green light and/or blue light; In still some examples, the light of the first waveband that the first photodiode 10 is used for conversion can be infrared light, red light, green light and/or blue light, and the second photodiode 20 uses The light of the converted second wavelength band may be ultraviolet light. Those skilled in the art can understand that the above examples are only illustrative and not restrictive nor exhaustive, as long as all or part of the wavelengths in the first waveband are greater than the wavelengths in the second waveband.
在一些实施例中,第一半导体材料为锗硅(SiGe),第二半导体材料为硅(Si)。本领域技术人员可以理解,第一半导体材料可以包含SiGe、GaAs、Pbs、PbSe、PbTe、GaSb、InN等、或任两种及以上的组合的半导体材料。本领域技术人员还可以理解,任何III族(硼族)元素(B、Al、Ga、In、Tl)、IV族(碳族)元素(C、Si、Ge、Sn、Pb)、V族(氮族)元素(N、P、As、Sb、Bi)或类似物都可用于形成第一半导体材料。In some embodiments, the first semiconductor material is silicon germanium (SiGe), and the second semiconductor material is silicon (Si). Those skilled in the art can understand that the first semiconductor material may include SiGe, GaAs, Pbs, PbSe, PbTe, GaSb, InN, etc., or any combination of two or more semiconductor materials. Those skilled in the art can also understand that any III group (boron group) element (B, Al, Ga, In, Tl), IV group (carbon group) element (C, Si, Ge, Sn, Pb), V group ( Nitrogen) elements (N, P, As, Sb, Bi) or the like can be used to form the first semiconductor material.
在一些实施例中,如图1所示,第一光电二极管10的第一部分11比第二部分12更靠近图像传感器的用于接收光的表面。图像传感器的用于接收光的表面可以是图像传感器的正面(例如,前照射式图像传感器),也可以是图像传感器的背面(例如,背照射式图像传感器)。In some embodiments, as shown in FIG. 1 , the first portion 11 of the first photodiode 10 is closer to the surface of the image sensor for receiving light than the second portion 12 . The surface of the image sensor for receiving light may be the front side of the image sensor (for example, a front-illuminated image sensor) or the back side of the image sensor (for example, a back-illuminated image sensor).
在一些实施例中,第一光电二极管的结构可以如图2至5所示。其中,第一光电二极管由第一半导体材料S1和第二半导体材料S2形成。其中,第二半导体材料S2(即形成第一光电二极管的第二部分的材料)是第一导电类型的,第一半导体材料S1(即形成第一光电二极管的第一部分的材料)可以是与第二半导体材料S2相同掺杂为第一导电类型的,也可以是未掺杂的半导体材料。In some embodiments, the structure of the first photodiode may be as shown in FIGS. 2 to 5 . Wherein, the first photodiode is formed by the first semiconductor material S1 and the second semiconductor material S2. Wherein, the second semiconductor material S2 (that is, the material that forms the second part of the first photodiode) is of the first conductivity type, and the first semiconductor material S1 (that is, the material that forms the first part of the first photodiode) can be the same as the first semiconductor material S1. The two semiconductor materials S2 are identically doped to the first conductivity type, or may be undoped semiconductor materials.
在第一半导体材料S1和/或第二半导体材料S2中形成有第二导电类型的区域30。例如,第二导电类型的区域30可以仅形成在第一半导体材料S1中(如图2所示,这种情况下第一半导体材料S1需要掺杂为第一导电类型的),也可以仅形成在第二半导体材料S2中(如图4所示),还可以同时形成在第一半导体材料S1和第二半导体材料S2中(如图3、5所示)。例如,第二导电类型的区域30可以是从上表面形成的,如图2、3所示,也可以是从下表面形成的,如图4、5所示。虽然未在附图中示出,但本领域技术人员可以理解,第二导电类型的区域30的边界也可以正好在第一半导体材料S1和第二半导体材料S2的交界处。A region 30 of the second conductivity type is formed in the first semiconductor material S1 and/or the second semiconductor material S2 . For example, the region 30 of the second conductivity type can be formed only in the first semiconductor material S1 (as shown in FIG. In the second semiconductor material S2 (as shown in FIG. 4 ), it can also be formed in the first semiconductor material S1 and the second semiconductor material S2 (as shown in FIGS. 3 and 5 ) at the same time. For example, the region 30 of the second conductivity type may be formed from the upper surface, as shown in FIGS. 2 and 3 , or may be formed from the lower surface, as shown in FIGS. 4 and 5 . Although not shown in the drawings, those skilled in the art can understand that the boundary of the region 30 of the second conductivity type can also be just at the junction of the first semiconductor material S1 and the second semiconductor material S2 .
在一些实施例中,第一导电类型为P型,第二导电类型为N型,即在P型的半导体材料中形成N型区域从而形成光电二极管。本领域技术人员可以理解,第一导电类型也可以为N型,第二导电类型也可以为P型,即在N型的半导体材料中形成P型区域从而形成光电二极管。In some embodiments, the first conductivity type is P-type, and the second conductivity type is N-type, that is, an N-type region is formed in a P-type semiconductor material to form a photodiode. Those skilled in the art can understand that the first conductivity type can also be N-type, and the second conductivity type can also be P-type, that is, a P-type region is formed in an N-type semiconductor material to form a photodiode.
在一些实施例中,如图6所示,图像传感器包括第一光电二极管PD1、第二光电二极管PD2、和第三光电二极管PD3。其中,第一光电二极管PD1用于转换第一波段的光,第二光电二极管PD2用于转换第二波段的光,第三光电二极管PD3用于转换第三波段的光。第一光电二极管PD1的第一部分由第一半导体材料SEM形成,第一光电二极管PD1的第二部分由第二半导体材料(在半导体衬底SUB中的部分)形成。第二光电二极管PD2和第三光电二极管PD3均由第二半导体材料(在半导体衬底SUB中)形成。其中,第一波段的至少部分波长大于第二波段的波长,第二波段的至少部分波长大于第三波段的波长,第一半导体材料的能带隙小于第二半导体材料的能带隙。In some embodiments, as shown in FIG. 6 , the image sensor includes a first photodiode PD1 , a second photodiode PD2 , and a third photodiode PD3 . Wherein, the first photodiode PD1 is used for converting the light of the first wavelength band, the second photodiode PD2 is used for converting the light of the second wavelength band, and the third photodiode PD3 is used for converting the light of the third wavelength band. A first portion of the first photodiode PD1 is formed of a first semiconductor material SEM, and a second portion of the first photodiode PD1 is formed of a second semiconductor material (the portion in the semiconductor substrate SUB). Both the second photodiode PD2 and the third photodiode PD3 are formed of the second semiconductor material (in the semiconductor substrate SUB). Wherein, at least part of the wavelength of the first waveband is greater than the wavelength of the second waveband, at least part of the wavelength of the second waveband is greater than the wavelength of the third waveband, and the energy bandgap of the first semiconductor material is smaller than the energy bandgap of the second semiconductor material.
在一些实施例中,图像传感器的色彩空间为RGB空间,第一光电二极管PD1、第二光电二极管PD2、和第三光电二极管PD3分别用于转换红光、绿光、和蓝光。In some embodiments, the color space of the image sensor is an RGB space, and the first photodiode PD1, the second photodiode PD2, and the third photodiode PD3 are used to convert red light, green light, and blue light, respectively.
在一些实施例中,图像传感器还包括分别位于第一光电二极管PD1、第二光电二极管PD2、和第三光电二极管PD3之上并分别覆盖第一光电二极管PD1、第二光电二极管PD2、和第三光电二极管PD3的第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3。其中,第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3分别用于透过红光、绿光、和蓝光。In some embodiments, the image sensor further includes a photodiode located above the first photodiode PD1, the second photodiode PD2, and the third photodiode PD3 and covering the first photodiode PD1, the second photodiode PD2, and the third photodiode respectively. The first color filter CF1, the second color filter CF2, and the third color filter CF3 of the photodiode PD3. Wherein, the first color filter CF1, the second color filter CF2, and the third color filter CF3 are respectively used to transmit red light, green light, and blue light.
下面结合图7至10来描述根据本公开一个实施例的形成图像传感器的方法。A method of forming an image sensor according to an embodiment of the present disclosure will be described below with reference to FIGS. 7 to 10 .
如图7所示,在由第二半导体材料形成的半导体衬底SUB中形成第一光电二极管的第二部分、第二光电二极管、和第三光电二极管。可以通过在第一导电类型的半导体衬底SUB中形成第二导电类型的区域来形成各光电二极管。例如,在第一导电类型的半导体衬底SUB中形成第二导电类型的第一区域REG1来形成第一光电二极管的第二部分,在第一导电类型的半导体衬底SUB中形成第二导电类型的第二区域REG2来形成第二光电二极管,以及在第一导电类型的半导体衬底SUB中形成第二导电类型的第三区域REG3来形成第三光电二极管。As shown in FIG. 7, the second portion of the first photodiode, the second photodiode, and the third photodiode are formed in the semiconductor substrate SUB formed of the second semiconductor material. Each photodiode may be formed by forming a region of the second conductivity type in the semiconductor substrate SUB of the first conductivity type. For example, the first region REG1 of the second conductivity type is formed in the semiconductor substrate SUB of the first conductivity type to form the second part of the first photodiode, and the second portion of the first photodiode is formed in the semiconductor substrate SUB of the first conductivity type. The second region REG2 of the second conductive type is formed to form a second photodiode, and the third region REG3 of the second conductive type is formed in the semiconductor substrate SUB of the first conductive type to form a third photodiode.
接下来,在第一光电二极管的第二部分之上形成覆盖第一光电二极管的第二部分的第一光电二极管的第一部分,其中,第一光电二极管的第一部分由第一半导体材料形成,并且第一半导体材料的能带隙小于第二半导体材料的能带隙。Next, forming a first portion of the first photodiode covering the second portion of the first photodiode over a second portion of the first photodiode, wherein the first portion of the first photodiode is formed of a first semiconductor material, and The energy bandgap of the first semiconductor material is smaller than the energy bandgap of the second semiconductor material.
具体地,如图7所示,先在半导体衬底SUB之上形成电介质材料层L1。电介质材料层L1可以是由氧化硅形成,也可以是由其他的电介质材料例如氮化硅而形成。电介质材料层L1可以通过化学气相沉积(CVD)处理、原子层沉积(ALD)处理、热氧化处理或其他适合的手段而形成。Specifically, as shown in FIG. 7 , firstly, a dielectric material layer L1 is formed on the semiconductor substrate SUB. The dielectric material layer L1 may be formed of silicon oxide, or may be formed of other dielectric materials such as silicon nitride. The dielectric material layer L1 can be formed by chemical vapor deposition (CVD), atomic layer deposition (ALD), thermal oxidation or other suitable means.
如图8所示,去除电介质材料层L1的覆盖第一光电二极管的第二部分的部分,以在电介质材料层L1中形成如图8所示的缺口,并在该缺口中暴露出第一光电二极管的第二部分,即暴露出半导体衬底SUB。可以通过光刻加刻蚀的处理来形成该缺口,也可以通过其他手段例如硬掩膜加刻蚀的处理来形成该缺口。As shown in FIG. 8, the part of the dielectric material layer L1 covering the second part of the first photodiode is removed to form a gap as shown in FIG. 8 in the dielectric material layer L1, and the first photodiode is exposed in the gap. The second part of the diode exposes the semiconductor substrate SUB. The gap can be formed by photolithography plus etching, or by other means such as hard mask plus etching.
如图9所示,在形成的如图8所示的缺口中填充第一半导体材料SEM,从而在暴露出的第一光电二极管的第二部分上形成第一光电二极管的第一部分,以最终形成整个第一光电二极管。其中,第一半导体材料的能带隙小于第二半导体材料的能带隙。可以通过化学气相沉积处理、原子层沉积处理、或分子束外延(MBE)处理等形成第一光电二极管的第一部分。优选地,形成第一部分的处理温度低于500℃,更优地为低于450℃,这样可以避免对已经形成的器件、金属互连层等产生影响。As shown in FIG. 9, the first semiconductor material SEM is filled in the formed gap as shown in FIG. across the first photodiode. Wherein, the energy band gap of the first semiconductor material is smaller than the energy band gap of the second semiconductor material. The first portion of the first photodiode may be formed through a chemical vapor deposition process, an atomic layer deposition process, or a molecular beam epitaxy (MBE) process, or the like. Preferably, the processing temperature for forming the first part is lower than 500° C., more preferably lower than 450° C., so as to avoid affecting the already formed devices, metal interconnection layers and the like.
然后可以在各光电二极管的周围,形成全部或部分围绕该光电二极管以用于将该光电二极管与邻近的光电二极管隔离开的隔离结构I1、I2,例如深槽隔离(DTI)结构、或者浅槽隔离(STI)结构等,如图10所示。之后可以在电介质材料层L1之上先形成由电介质材料形成的填充层L2(例如可以是抗反射层、高介电常数层、平坦化层、间隔层等任何合适的功能层),再在填充层L2上形成滤色器,例如分别用于第一光电二极管、第二光电二极管、和第三光电二极管的第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3。其中,第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3。分别位于第一光电二极管、第二光电二极管、和第三光电二极管之上并分别覆盖第一光电二极管、第二光电二极管、和第三光电二极管。各滤色器之间还间隔有光隔离结构I3、I4。之后,在各滤色器之上还分别形成分别覆盖第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3的第一微透镜ML1、第二微透镜ML2、和第三微透镜ML3,从而形成如图6所示的图像传感器。Around each photodiode, isolation structures I1, I2, such as deep trench isolation (DTI) structures, or shallow trenches, may then be formed surrounding the photodiode in whole or in part for isolating the photodiode from adjacent photodiodes. Isolation (STI) structure, etc., as shown in Figure 10. Afterwards, a filling layer L2 (for example, any suitable functional layer such as an anti-reflection layer, a high dielectric constant layer, a planarization layer, a spacer layer, etc.) formed by a dielectric material can be formed on the dielectric material layer L1, and then the filling layer L2 can be formed on the dielectric material layer L1. Color filters are formed on the layer L2, such as a first color filter CF1, a second color filter CF2, and a third color filter CF3 for the first photodiode, the second photodiode, and the third photodiode, respectively. Among them, the first color filter CF1, the second color filter CF2, and the third color filter CF3. are respectively located on the first photodiode, the second photodiode, and the third photodiode and respectively cover the first photodiode, the second photodiode, and the third photodiode. There are also light isolation structures I3 and I4 between the color filters. After that, the first microlens ML1, the second microlens ML2, and the second microlens ML1 covering the first color filter CF1, the second color filter CF2, and the third color filter CF3 are respectively formed on each color filter. Three microlenses ML3, thereby forming an image sensor as shown in FIG. 6 .
适当选择各滤色器的材料,以使得第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3分别用于透过第一波段的光、第二波段的光、和第三波段的光。从而使得第一光电二极管用于转换第一波段的光,第二光电二极管用于转换第二波段的光,第三光电二极管用于转换第三波段的光。其中,第一波段的至少部分波长大于第二波段的波长,第二波段的至少部分波长大于第三波段的波长。在一些例子里,图像传感器的色彩空间为RGB空间,第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3分别用于透过红光、绿光、和蓝光,第一光电二极管、第二光电二极管、和第三光电二极管分别用于转换红光、绿光、和蓝光。The material of each color filter is appropriately selected so that the first color filter CF1, the second color filter CF2, and the third color filter CF3 are respectively used to transmit the light of the first waveband, the light of the second waveband, and the light of the second waveband. Light of the third band. Therefore, the first photodiode is used to convert the light of the first wavelength band, the second photodiode is used to convert the light of the second wavelength band, and the third photodiode is used to convert the light of the third wavelength band. Wherein, at least part of the wavelength of the first wave band is greater than the wavelength of the second wave band, and at least part of the wavelength of the second wave band is greater than the wavelength of the third wave band. In some examples, the color space of the image sensor is the RGB space, the first color filter CF1, the second color filter CF2, and the third color filter CF3 are used to transmit red light, green light, and blue light respectively, and the A photodiode, a second photodiode, and a third photodiode are used to convert red light, green light, and blue light, respectively.
本领域技术人员可以理解,也可以在形成电介质材料层L1之前形成用于将光电二极管与邻近的光电二极管隔离开的隔离结构I1、I2,例如,形成如图11所示的图像传感器。Those skilled in the art can understand that the isolation structures I1 and I2 for isolating photodiodes from adjacent photodiodes can also be formed before forming the dielectric material layer L1 , for example, to form an image sensor as shown in FIG. 11 .
如图12所示,在由第二半导体材料形成的半导体衬底SUB中形成第一光电二极管的第二部分、第二光电二极管、和第三光电二极管。然后在各光电二极管的周围,形成全部或部分围绕该光电二极管以用于将该光电二极管与邻近的光电二极管隔离开的隔离结构I1、I2,例如深槽隔离(DTI)结构、或者浅槽隔离(STI)结构等,如图12所示。接下来,在半导体衬底SUB之上形成电介质材料层L1。然后,去除电介质材料层L1的覆盖第一光电二极管的第二部分的部分,以在电介质材料层L1中形成如图13所示的缺口,并在该缺口中暴露出第一光电二极管的第二部分,即暴露出半导体衬底SUB。如图14所示,在形成的如图13所示的缺口中填充第一半导体材料SEM,从而在暴露出的第一光电二极管的第二部分上形成第一光电二极管的第一部分,以最终形成整个第一光电二极管。其中,第一半导体材料的能带隙小于第二半导体材料的能带隙。之后可以在电介质材料层L1之上先形成由电介质材料形成的填充层L2,再在填充层L2上形成分别用于第一光电二极管、第二光电二极管、和第三光电二极管的第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3,以及第一微透镜ML1、第二微透镜ML2、和第三微透镜ML3,从而形成如图11所示的图像传感器。As shown in FIG. 12, the second portion of the first photodiode, the second photodiode, and the third photodiode are formed in the semiconductor substrate SUB formed of the second semiconductor material. Then around each photodiode, an isolation structure I1, I2 is formed wholly or partially surrounding the photodiode for isolating the photodiode from adjacent photodiodes, such as a deep trench isolation (DTI) structure, or a shallow trench isolation (STI) structure, etc., as shown in Figure 12. Next, a dielectric material layer L1 is formed over the semiconductor substrate SUB. Then, the part of the dielectric material layer L1 covering the second part of the first photodiode is removed to form a gap as shown in FIG. 13 in the dielectric material layer L1, and the second part of the first photodiode is exposed in the gap. Part, that is, the semiconductor substrate SUB is exposed. As shown in FIG. 14, the first semiconductor material SEM is filled in the formed gap as shown in FIG. across the first photodiode. Wherein, the energy band gap of the first semiconductor material is smaller than the energy band gap of the second semiconductor material. Afterwards, a filling layer L2 formed of a dielectric material may be first formed on the dielectric material layer L1, and then the first color filters for the first photodiode, the second photodiode, and the third photodiode are formed on the filling layer L2. Filter CF1, second color filter CF2, and third color filter CF3, and first microlens ML1, second microlens ML2, and third microlens ML3, thereby forming an image sensor as shown in FIG. 11 .
适当选择各滤色器的材料,以使得第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3分别用于透过第一波段的光、第二波段的光、和第三波段的光。从而使得第一光电二极管用于转换第一波段的光,第二光电二极管用于转换第二波段的光,第三光电二极管用于转换第三波段的光。其中,第一波段的至少部分波长大于第二波段的波长,第二波段的至少部分波长大于第三波段的波长。在一些例子里,图像传感器的色彩空间为RGB空间,第一滤色器CF1、第二滤色器CF2、和第三滤色器CF3分别用于透过红光、绿光、和蓝光,第一光电二极管、第二光电二极管、和第三光电二极管分别用于转换红光、绿光、和蓝光。The material of each color filter is appropriately selected so that the first color filter CF1, the second color filter CF2, and the third color filter CF3 are respectively used to transmit the light of the first waveband, the light of the second waveband, and the light of the second waveband. Light of the third band. Therefore, the first photodiode is used to convert the light of the first wavelength band, the second photodiode is used to convert the light of the second wavelength band, and the third photodiode is used to convert the light of the third wavelength band. Wherein, at least part of the wavelength of the first wave band is greater than the wavelength of the second wave band, and at least part of the wavelength of the second wave band is greater than the wavelength of the third wave band. In some examples, the color space of the image sensor is an RGB space, the first color filter CF1, the second color filter CF2, and the third color filter CF3 are used to transmit red light, green light, and blue light respectively, and the A photodiode, a second photodiode, and a third photodiode are used to convert red light, green light, and blue light, respectively.
虽然以上仅结合图7至10描述了形成如图6所示的图像传感器的方法,以及结合图12至14描述了形成如图11所示的图像传感器的方法,但本领域技术人员可以得到形成本公开所描述的所有图像传感器的方法。Although the method for forming the image sensor shown in FIG. 6 is described above only in conjunction with FIGS. 7 to 10, and the method for forming the image sensor shown in FIG. 11 is described in conjunction with FIGS. 12 to 14, those skilled in the art can obtain the formation All image sensor methods described in this disclosure.
虽然本公开的附图中仅以截面图的形式示意性地示出了像素区的图像传感器的结构,本领域技术人员基于本公开记载的内容能够得到本公开所涉及的图像传感器整体的结构和形成方法。Although the drawings of the present disclosure only schematically show the structure of the image sensor in the pixel area in the form of a cross-sectional view, those skilled in the art can obtain the overall structure and structure of the image sensor involved in the present disclosure based on the contents of the present disclosure. form method.
在说明书及权利要求中的词语“A或B”包括“A和B”以及“A或B”,而不是排他地仅包括“A”或者仅包括“B”,除非另有特别说明。The word "A or B" in the specification and claims includes "A and B" and "A or B", and does not exclusively include only "A" or only "B", unless specifically stated otherwise.
在说明书及权利要求中的词语“前”、“后”、“顶”、“底”、“之上”、“之下”等,如果存在的话,用于描述性的目的而并不一定用于描述不变的相对位置。应当理解,这样使用的词语在适当的情况下是可互换的,使得在此所描述的本公开的实施例,例如,能够在与在此所示出的或另外描述的那些取向不同的其他取向上操作。In the specification and claims, the words "front", "rear", "top", "bottom", "above", "under", etc., if present, are used for descriptive purposes and not necessarily to describe a constant relative position. It is to be understood that the terms so used are interchangeable under appropriate circumstances such that the embodiments of the disclosure described herein are, for example, capable of operation in other orientations than those illustrated or otherwise described herein. Orientation operation.
如在此所使用的,词语“示例性的”意指“用作示例、实例或说明”,而不是作为将被精确复制的“模型”。在此示例性描述的任意实现方式并不一定要被解释为比其它实现方式优选的或有利的。而且,本公开不受在上述技术领域、背景技术、发明内容或具体实施方式中所给出的任何所表述的或所暗示的理论所限定。As used herein, the word "exemplary" means "serving as an example, instance, or illustration" rather than as a "model" to be exactly reproduced. Any implementation described illustratively herein is not necessarily to be construed as preferred or advantageous over other implementations. Furthermore, the disclosure is not to be bound by any expressed or implied theory presented in the preceding technical field, background, brief summary or detailed description.
如在此所使用的,词语“基本上”意指包含由设计或制造的缺陷、器件或元件的容差、环境影响和/或其它因素所致的任意微小的变化。词语“基本上”还允许由寄生效应、噪音以及可能存在于实际的实现方式中的其它实际考虑因素所致的与完美的或理想的情形之间的差异。As used herein, the word "substantially" is meant to include any minor variations due to defects in design or manufacturing, device or component tolerances, environmental influences, and/or other factors. The word "substantially" also allows for differences from a perfect or ideal situation due to parasitic effects, noise, and other practical considerations that may exist in an actual implementation.
上述描述可以指示被“连接”或“耦合”在一起的元件或节点或特征。如在此所使用的,除非另外明确说明,“连接”意指一个元件/节点/特征与另一种元件/节点/特征在电学上、机械上、逻辑上或以其它方式直接地连接(或者直接通信)。类似地,除非另外明确说明,“耦合”意指一个元件/节点/特征可以与另一元件/节点/特征以直接的或间接的方式在机械上、电学上、逻辑上或以其它方式连结以允许相互作用,即使这两个特征可能并没有直接连接也是如此。也就是说,“耦合”意图包含元件或其它特征的直接连结和间接连结,包括利用一个或多个中间元件的连接。The above description may refer to elements or nodes or features being "connected" or "coupled" together. As used herein, unless expressly stated otherwise, "connected" means that one element/node/feature is directly connected (or electrically, mechanically, logically, or otherwise) to another element/node/feature. direct communication). Similarly, unless expressly stated otherwise, "coupled" means that one element/node/feature can be directly or indirectly mechanically, electrically, logically or otherwise connected to another element/node/feature to Interactions are allowed even though the two features may not be directly connected. That is, "coupled" is intended to encompass both direct and indirect couplings of elements or other features, including connections utilizing one or more intervening elements.
另外,仅仅为了参考的目的,还可以在下面描述中使用某种术语,并且因而并非意图限定。例如,除非上下文明确指出,否则涉及结构或元件的词语“第一”、“第二”和其它此类数字词语并没有暗示顺序或次序。In addition, certain terms may also be used in the following description for reference purposes only, and thus are not intended to be limiting. For example, the words "first," "second," and other such numerical terms referring to structures or elements do not imply a sequence or order unless clearly indicated by the context.
还应理解,“包括/包含”一词在本文中使用时,说明存在所指出的特征、整体、步骤、操作、单元和/或组件,但是并不排除存在或增加一个或多个其它特征、整体、步骤、操作、单元和/或组件以及/或者它们的组合。It should also be understood that when the word "comprises/comprises" is used herein, it indicates the presence of indicated features, integers, steps, operations, units and/or components, but does not exclude the presence or addition of one or more other features, whole, steps, operations, units and/or components and/or combinations thereof.
在本公开中,术语“提供”从广义上用于涵盖获得对象的所有方式,因此“提供某对象”包括但不限于“购买”、“制备/制造”、“布置/设置”、“安装/装配”、和/或“订购”对象等。In this disclosure, the term "provide" is used broadly to cover all ways of obtaining an object, thus "provide something" includes, but is not limited to, "purchase", "preparation/manufacture", "arrangement/setup", "installation/ Assembly", and/or "Order" objects, etc.
本领域技术人员应当意识到,在上述操作之间的边界仅仅是说明性的。多个操作可以结合成单个操作,单个操作可以分布于附加的操作中,并且操作可以在时间上至少部分重叠地执行。而且,另选的实施例可以包括特定操作的多个实例,并且在其他各种实施例中可以改变操作顺序。但是,其它的修改、变化和替换同样是可能的。因此,本说明书和附图应当被看作是说明性的,而非限制性的。Those skilled in the art will appreciate that the boundaries between the above-described operations are merely illustrative. Multiple operations may be combined into a single operation, a single operation may be distributed among additional operations, and operations may be performed with at least partial overlap in time. Also, alternative embodiments may include multiple instances of a particular operation, and the order of operations may be altered in other various embodiments. However, other modifications, changes and substitutions are also possible. Accordingly, the specification and drawings are to be regarded as illustrative rather than restrictive.
另外,本公开的实施方式还可以包括以下示例:In addition, implementations of the present disclosure may also include the following examples:
1.一种图像传感器,其特征在于,包括:1. An image sensor, characterized in that, comprising:
第一光电二极管,用于转换第一波段的光,所述第一光电二极管的第一部分由第一半导体材料形成,所述第一光电二极管的第二部分由第二半导体材料形成;以及a first photodiode for converting light in a first wavelength band, a first portion of the first photodiode is formed of a first semiconductor material, and a second portion of the first photodiode is formed of a second semiconductor material; and
第二光电二极管,用于转换第二波段的光,所述第二光电二极管由第二半导体材料形成,a second photodiode for converting light in a second wavelength band, the second photodiode is formed of a second semiconductor material,
其中,所述第一波段的至少部分波长大于所述第二波段的波长,所述第一半导体材料的能带隙小于所述第二半导体材料的能带隙。Wherein, at least part of the wavelengths of the first waveband are greater than the wavelengths of the second waveband, and the energy bandgap of the first semiconductor material is smaller than the energy bandgap of the second semiconductor material.
2.根据1所述的图像传感器,其特征在于,所述第一部分比所述第二部分更靠近所述图像传感器的用于接收光的表面。2. The image sensor according to 1, wherein the first portion is closer to a surface for receiving light of the image sensor than the second portion.
3.根据1所述的图像传感器,其特征在于,还包括:3. The image sensor according to 1, further comprising:
第三光电二极管,用于转换第三波段的光,所述第三光电二极管由第二半导体材料形成,a third photodiode for converting light in a third wavelength band, the third photodiode is formed of a second semiconductor material,
其中,所述第二波段的至少部分波长大于所述第三波段的波长。Wherein, at least part of the wavelengths of the second waveband are greater than the wavelengths of the third waveband.
4.根据3所述的图像传感器,其特征在于,所述第一、第二、和第三光电二极管分别用于转换红光、绿光、和蓝光。4. The image sensor according to 3, wherein the first, second, and third photodiodes are used to convert red light, green light, and blue light, respectively.
5.根据3所述的图像传感器,其特征在于,还包括:5. The image sensor according to 3, further comprising:
分别位于所述第一、第二、和第三光电二极管之上并分别覆盖所述第一、第二、和第三光电二极管的第一、第二、和第三滤色器,first, second, and third color filters overlying and covering the first, second, and third photodiodes, respectively,
其中,所述第一、第二、和第三滤色器分别用于透过红光、绿光、和蓝光。Wherein, the first, second, and third color filters are respectively used to transmit red light, green light, and blue light.
6.根据1所述的图像传感器,其特征在于,所述第一部分和所述第二部分均为第一导电类型的,并且所述第一部分和/或所述第二部分中形成有第二导电类型的区域。6. The image sensor according to 1, wherein both the first part and the second part are of the first conductivity type, and a second conductive type is formed in the first part and/or the second part. area of conductivity type.
7.根据6所述的图像传感器,其特征在于,所述第一导电类型为P型,所述第二导电类型为N型。7. The image sensor according to 6, wherein the first conductivity type is P-type, and the second conductivity type is N-type.
8.根据1所述的图像传感器,其特征在于,所述第一半导体材料为锗硅,所述第二半导体材料为硅。8. The image sensor according to 1, wherein the first semiconductor material is silicon germanium, and the second semiconductor material is silicon.
9.一种形成图像传感器的方法,其特征在于,包括:9. A method of forming an image sensor, comprising:
在半导体衬底中形成第一光电二极管的第二部分和第二光电二极管,其中,所述第一光电二极管用于转换第一波段的光,所述第二光电二极管用于转换第二波段的光,所述半导体衬底由第二半导体材料形成;以及A second part of the first photodiode and a second photodiode are formed in the semiconductor substrate, wherein the first photodiode is used to convert light of a first wavelength band, and the second photodiode is used to convert light of a second wavelength band light, the semiconductor substrate is formed from a second semiconductor material; and
在所述第二部分之上形成覆盖所述第二部分的所述第一光电二极管的第一部分,其中,所述第一部分由第一半导体材料形成,forming a first portion of the first photodiode covering the second portion over the second portion, wherein the first portion is formed from a first semiconductor material,
其中,所述第一波段的至少部分波长大于所述第二波段的波长,所述第一半导体材料的能带隙小于所述第二半导体材料的能带隙。Wherein, at least part of the wavelengths of the first waveband are greater than the wavelengths of the second waveband, and the energy bandgap of the first semiconductor material is smaller than the energy bandgap of the second semiconductor material.
10.根据9所述的方法,其特征在于,在所述第二部分之上形成所述第一部分包括:10. The method according to 9, wherein forming the first portion over the second portion comprises:
在所述半导体衬底之上形成电介质材料层;forming a layer of dielectric material over the semiconductor substrate;
去除所述电介质材料层的覆盖所述第二部分的部分,以暴露出所述第二部分;以及removing a portion of the layer of dielectric material overlying the second portion to expose the second portion; and
在暴露出的所述第二部分上形成所述第一部分。The first portion is formed on the exposed second portion.
11.根据9所述的方法,其特征在于,通过化学气相沉积处理、原子层沉积处理、或分子束外延处理形成所述第一部分。11. The method according to 9, wherein the first portion is formed by chemical vapor deposition, atomic layer deposition, or molecular beam epitaxy.
12.根据11所述的方法,其特征在于,形成所述第一部分的处理温度低于500℃。12. The method according to 11, characterized in that the processing temperature for forming the first part is lower than 500°C.
13.根据11所述的方法,其特征在于,形成所述第一部分的处理温度低于450℃。13. The method according to 11, characterized in that the processing temperature for forming the first portion is lower than 450°C.
14.根据9所述的方法,其特征在于,还包括:14. The method according to 9, further comprising:
在半导体衬底中形成第三光电二极管,其中,所述第三光电二极管用于转换第三波段的光,所述半导体衬底由第二半导体材料形成,forming a third photodiode in a semiconductor substrate, wherein the third photodiode is used to convert light of a third wavelength band, the semiconductor substrate is formed of a second semiconductor material,
其中,所述第二波段的至少部分波长大于所述第三波段的波长。Wherein, at least part of the wavelengths of the second waveband are greater than the wavelengths of the third waveband.
15.根据14所述的方法,其特征在于,所述第一、第二、和第三光电二极管分别用于转换红光、绿光、和蓝光。15. The method of 14, wherein the first, second, and third photodiodes are used to convert red, green, and blue light, respectively.
16.根据14所述的方法,其特征在于,还包括:16. The method according to 14, further comprising:
在所述第一、第二、和第三光电二极管之上形成分别覆盖所述第一、第二、和第三光电二极管的第一、第二、和第三滤色器,forming first, second, and third color filters covering the first, second, and third photodiodes, respectively, over the first, second, and third photodiodes,
其中,所述第一、第二、和第三滤色器分别用于透过红光、绿光、和蓝光。Wherein, the first, second, and third color filters are respectively used to transmit red light, green light, and blue light.
17.根据9所述的方法,其特征在于,所述第一部分和所述第二部分均为第一导电类型的,并且所述第一部分和/或所述第二部分中形成有第二导电类型的区域。17. The method according to 9, wherein both the first part and the second part are of the first conductivity type, and the first part and/or the second part are formed with a second conductive type. type of area.
18.根据17所述的方法,其特征在于,所述第一导电类型为P型,所述第二导电类型为N型。18. The method according to 17, wherein the first conductivity type is P-type, and the second conductivity type is N-type.
19.根据9所述的方法,其特征在于,所述第一半导体材料为锗硅,所述第二半导体材料为硅。19. The method according to 9, wherein the first semiconductor material is silicon germanium, and the second semiconductor material is silicon.
虽然已经通过示例对本公开的一些特定实施例进行了详细说明,但是本领域的技术人员应该理解,以上示例仅是为了进行说明,而不是为了限制本公开的范围。在此公开的各实施例可以任意组合,而不脱离本公开的精神和范围。本领域的技术人员还应理解,可以对实施例进行多种修改而不脱离本公开的范围和精神。本公开的范围由所附权利要求来限定。Although some specific embodiments of the present disclosure have been described in detail through examples, those skilled in the art should understand that the above examples are for illustration only, rather than limiting the scope of the present disclosure. The various embodiments disclosed herein can be combined arbitrarily without departing from the spirit and scope of the present disclosure. Those skilled in the art will also appreciate that various modifications may be made to the embodiments without departing from the scope and spirit of the present disclosure. The scope of the present disclosure is defined by the appended claims.
Claims (10)
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