CN106242815A - A kind of liquid fertilizer and preparation method thereof - Google Patents
A kind of liquid fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN106242815A CN106242815A CN201610692616.9A CN201610692616A CN106242815A CN 106242815 A CN106242815 A CN 106242815A CN 201610692616 A CN201610692616 A CN 201610692616A CN 106242815 A CN106242815 A CN 106242815A
- Authority
- CN
- China
- Prior art keywords
- liquid
- sulfate
- liquid fertilizer
- fertilizer
- potassium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000007788 liquid Substances 0.000 title claims abstract description 55
- 239000003337 fertilizer Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 235000001014 amino acid Nutrition 0.000 claims abstract description 30
- 150000001413 amino acids Chemical class 0.000 claims abstract description 30
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002131 composite material Substances 0.000 claims abstract description 15
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims abstract description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 8
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- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 8
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- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000004323 potassium nitrate Substances 0.000 claims abstract description 6
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- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 5
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- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- 239000001103 potassium chloride Substances 0.000 claims abstract description 3
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- 229910052939 potassium sulfate Inorganic materials 0.000 claims abstract description 3
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- 229940024606 amino acid Drugs 0.000 claims description 27
- 238000003756 stirring Methods 0.000 claims description 20
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 14
- 239000000052 vinegar Substances 0.000 claims description 14
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- 239000002028 Biomass Substances 0.000 claims description 10
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- 239000000080 wetting agent Substances 0.000 claims description 7
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- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 6
- 229920000053 polysorbate 80 Polymers 0.000 claims description 6
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 6
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- -1 alkyl sodium sulfate Chemical compound 0.000 claims description 5
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- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 4
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- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
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- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical group [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 4
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- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 claims description 2
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- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 2
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- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims 2
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- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of liquid fertilizer and preparation method thereof, its Main Components and percentage by weight thereof are as follows: carbamide ammonium nitrate solution 20% 45%, liquid APP 10% 40%, potash fertilizer 10% 20%, boric acid 0.6% 1%, composite aminoacid chelating microelement 4% 8%, synergist 0.1% 1%, remaining be water.Described potash fertilizer is one or more in potassium nitrate, potassium chloride, potassium sulfate, potassium pyrophosphate and potassium dihydrogen phosphate；Described composite aminoacid chelating microelement is to be prepared by chelatropic reaction with sulfate by chelates of composite amino acid.Each raw material not only environmental protection in described liquid fertilizer is easy to get, and can effectively provide multiple nutrient necessary to plant；Substantially increase plant recovery of nutrient and the production efficiency of liquid fertilizer simultaneously, there is the several functions such as improvement soil.
Description
Technical field
The present invention relates to new-type fertilizer technical field, particularly relate to a kind of liquid fertilizer and preparation method thereof.
Background technology
" file " of central authorities' appearance in 2016, does not require nothing more than enforcement chemical fertilizer zero growth rate action, simultaneously fertilizer to be ensured
Material is efficient, environmental protection.While not increasing current the problems of agricultural environment burden, moreover it is possible to improve soil quality.Liquid fertilizer has
The features such as safe efficient, energy-saving and environmental protection, can effectively alleviate or solve current agricultural environment problem encountered.
It is known that in plant growth and development process, need constantly to absorb from soil nutrient, denitrogenate, phosphorus, potassium a large amount of
Outside element, middle and trace element is also requisite, and they affect the photosynthesis of plant, Repiration, simultaneously participate in and plant
Multiple metabolic process in object.But in common liq fertilizer, a great number of elements and trace element all mix with saturated aqueous solution, secondary
Reaction easily occurs, and as formed water-fast precipitation, reduces fertilizer efficiency, uses chelated microelements can solve this and asks
Topic.The most conventional chelating agen has EDTA, humic acids and aminoacid etc., and wherein, EDTA is expensive, applicable pH range is narrow, certainly
Body can not be degraded, the most easily the heavy metal in complexation soil, utilization absorbed by crops, thus threatens food safety；Humic acids
The nutrient content of chelate is low, poor stability, and production cost is high, is difficult to directly be absorbed by crop；Amino-acid chelate
Not only good stability, absorption efficiency height, the aminoacid after simultaneously decomposing is the nutrient substance of plant growth equally, can promote photosynthetic
Effect, improve chlorophyllous content, promote bud differentiation and full seed, raising crop anti-adversity, more environmental protection excellent
Gesture.
Common liq fertilizer is except providing nutrient necessary to plant growing, and plant recovery of nutrient only compares conventional compound fertilizer
Improve about 30%.Improve the plant recovery of nutrient of liquid fertilizer the most further, the most also there are other functions such as improvement soil,
It is the difficult problem faced at present, therefore, it is necessary to develop the liquid fertilizer of a kind of high-efficiency environment friendly and preparation method thereof.
Summary of the invention
The technical problem to be solved is to provide a kind of liquid fertilizer and preparation method thereof, in described liquid fertilizer
The not only environmental protection of each raw material be easy to get, and can effectively provide multiple nutrient necessary to plant；Substantially increase Liquid Fertilizer simultaneously
The plant recovery of nutrient of material and production efficiency, have the several functions such as improvement soil.
The present invention solves that above-mentioned technical problem employed technical scheme comprise that a kind of liquid fertilizer of offer, its Main Components
And percentage by weight is as follows: carbamide ammonium nitrate solution 20%-45%, liquid APP 10%-40%, potash fertilizer 10%-20%,
Boric acid 0.6%-1%, composite aminoacid chelating microelement 4%-8%, synergist 0.1%-1%, remaining be water.
Further, the one during described potash fertilizer is potassium nitrate, potassium chloride, potassium sulfate, potassium pyrophosphate and potassium dihydrogen phosphate
Or it is several.
Further, described composite aminoacid chelating microelement is to be passed through chela by chelates of composite amino acid and sulfate
Conjunction reaction prepares.
Further, described chelates of composite amino acid contains glycine, alanine, leucine, isoleucine, figured silk fabrics ammonia
Acid, cystine, cysteine, methionine, threonine, serine, phenylalanine, tyrosine, tryptophan, proline, hydroxyl dried meat
Propylhomoserin, glutamic acid and aspartic acid.
Further, described sulfate is ferrous sulfate, manganese sulfate, zinc sulfate and copper sulfate.
Further, in described composite aminoacid chelating microelement building-up process, it is added with antioxidant；Described antioxygen
Agent is one or more in tea polyphenols, propylgallate, phytic acid, preferably propylgallate.
Further, described synergist be mainly composed of biomass vinegar liquid, surfactant and water conservation wetting agent.
Further, described biomass vinegar liquid is one or more in Bamboo vinegar solution, wood vinegar, CAOSU liquid；Described surface
Activating agent is one or more in alkyl sodium sulfate, benzene sulfonamide acid amide, polysorbate60, Tween 80, triethanolamine, preferably tells
Temperature 80；Described water conservation wetting agent is one or more in polyglutamic acid, hydroscopic high-molecular resin, polyacrylamide, is preferably
Polyglutamic acid.
The present invention solves above-mentioned technical problem and another technical scheme used is to provide a kind of aforesaid liquid fertilizer
Preparation method, comprises the steps of: (1) adds water and the aminoacids complex solid of scheduled volume in reactor, be heated to 40 DEG C-
80 DEG C, stirring is to being completely dissolved；(2) add in the solution that described step (1) obtains the ferrous sulfate of scheduled volume, manganese sulfate,
Zinc sulfate, copper sulfate and antioxidant, regulate pH scope 4-6, and stir 30min-60min；(3) treat that described step (2) obtains
Solution be cooled to room temperature after, add carbamide ammonium nitrate solution, liquid APP, potash fertilizer, boric acid to it, stirring is until the most molten
Solve；(4) in the solution that described step (3) obtains, biomass vinegar liquid, surfactant, water conservation wetting agent it are sequentially added into, stirring
Until being completely dissolved, obtain liquid fertilizer.
Further, also comprise the steps: that (5) pack after the solution bubble that described step (4) obtains eliminates.
A kind of high-efficiency environment friendly liquid fertilizer that the present invention provides and preparation method thereof, contrast prior art has the most useful
Effect: the biomass vinegar liquid, the Organic substance such as aminoacid that 1, add in liquid fertilizer are to carry the waste material after agricultural production is processed
Take, turn waste into wealth and economize on resources, meet the requirement of Current Agricultural Development environmental protection；2, surfactant and water conservation wetting agent are multiple
There is after joining synergism, substantially increase liquid fertilizer fertilizer efficiency；When 3, preparing composite aminoacid chelating microelement, select multiple
Conjunction aminoacid, as chelating agen, can be that plant provides more fully nutrition relative to single amino acid, promote plant robust growth；
4, in composite aminoacid chelating microelement preparation process, aminoacids complex is not to react one by one with metal sulfate, but choosing
Select suitable reaction condition, make aminoacids complex chelating Tong Bu with several metal sulfates, thus simplify production technology, improve effect
Rate；5, in composite aminoacid chelating microelement preparation process, by add antioxidant, substantially increase aminoacids complex and
The chelation percent of trace element；6, propylgallate is a kind of efficient natural antioxidant, and when being used in combination with synergist, it resists
More preferably, consumption is few, effect is notable for Oxidation；7, Tween 80 is a kind of nonionic surfactant, has stronger hydrophilic
Property and not dissociative chemically, have the function of stable liquid fertilizer simultaneously；8, after polyglutamic acid is used in natural environment
Slowly degraded, and then the nutrient making it be chelated progressively discharges, and crop can be made to obtain lasting nutrient supply over a period to come,
Reach the purpose of fertilizer slow release.
Detailed description of the invention
Below in conjunction with example, the present invention is described further, but should not be understood as limitation of the present invention.
Embodiment 1
(1) as a example by producing 1000kg Liquid Fertilizer, in reactor, add the water of 270kg, then add 28kg compounded amino
Acid solid, is heated to 40 DEG C, and stirring is to being completely dissolved；(2) 5kg ferrous sulfate monohydrate, 5kg manganese sulfate monohydrate, 5kg seven water are weighed
Zinc sulfate, 5kg copper sulphate pentahydrate and 0.2kg propylgallate are added simultaneously in the solution described in step (1), adjust pH to arrive
6, constant temperature 40 DEG C, stirs 60min；(3), after the solution obtained until step (2) is cooled to room temperature, it is added thereto to 320kg carbamide nitre
Ammonium salt solution, 200kg liquid APP, 90kg potassium nitrate, 60kg potassium dihydrogen phosphate, 6kg boric acid, stirring is until being completely dissolved；
(4) in the solution described in step (3), add 5kg biomass vinegar liquid, 0.5kg Tween 80 and 0.3kg polyglutamic acid, stirring until
It is completely dissolved；(5) treat that the solution bubble that step (4) obtains eliminates, after packaging, i.e. obtain the liquid fertilizer of a kind of high-efficiency environment friendly.
Embodiment 2
(1) as a example by producing 1000kg Liquid Fertilizer, in reactor, add the water of 227kg, then add 35kg compounded amino
Acid solid, is heated to 60 DEG C, and stirring is to being completely dissolved；(2) 5kg ferrous sulfate monohydrate, 6kg manganese sulfate monohydrate, 6kg seven water are weighed
Zinc sulfate, 6kg copper sulphate pentahydrate and 0.2kg propylgallate are added simultaneously in the solution described in step (1), constant temperature 60
DEG C, regulate pH to 5, stir 50min；(3), after the solution obtained until step (2) is cooled to room temperature, 400kg carbamide nitre is added to it
Ammonium salt solution, 200kg liquid APP, 80kg potassium nitrate, 20kg potassium pyrophosphate, 8kg boric acid, stirring is until being completely dissolved；(4)
Adding 6kg biomass vinegar liquid, 0.5kg Tween 80 and 0.3kg polyglutamic acid in solution described in the most backward step (3), stirring is straight
To being completely dissolved；(5) treat that the solution bubble that step (4) obtains eliminates, after packaging, i.e. obtain the liquid fertilizer of a kind of high-efficiency environment friendly.
Embodiment 3
(1) as a example by producing 1000kg Liquid Fertilizer, in reactor, add 203kg water, add 42kg aminoacids complex
Solid, is heated to 80 DEG C, and stirring is to being completely dissolved；(2) 8kg ferrous sulfate monohydrate, 8kg manganese sulfate monohydrate, 8kg seven water sulfur are weighed
Acid zinc, 8kg copper sulphate pentahydrate and 0.2kg propylgallate are added simultaneously in the solution described in step (1), constant temperature 80
DEG C, regulate pH to 4, stir 30min；(3), after the solution obtained until step (2) is cooled to room temperature, 450kg carbamide nitre is added to it
Ammonium salt solution, 140kg liquid APP, 75kg potassium nitrate, 40kg potassium dihydrogen phosphate, 8kg boric acid, keep 80 DEG C, stirring until
It is completely dissolved；(4) solution described in the most backward step (3) adds 9kg biomass vinegar liquid, 0.5kg Tween 80 and the poly-paddy of 0.3kg
Propylhomoserin, stirring is until being completely dissolved；(5) treat that the solution bubble that step (4) obtains eliminates, after packaging, i.e. obtain a kind of high-efficiency environment friendly
Liquid fertilizer.
Although the present invention discloses as above with preferred embodiment, so it is not limited to the present invention, any this area skill
Art personnel, without departing from the spirit and scope of the present invention, when making a little amendment and perfect, the therefore protection model of the present invention
Enclose when with being as the criterion that claims are defined.
Claims (10)
1. a liquid fertilizer, it is characterised in that its Main Components and percentage by weight thereof are as follows: carbamide ammonium nitrate solution 20%-
45%, liquid APP 10%-40%, potash fertilizer 10%-20%, boric acid 0.6%-1%, composite aminoacid chelating microelement
4%-8%, synergist 0.1%-1%, remaining be water.
2. liquid fertilizer as claimed in claim 1, it is characterised in that described potash fertilizer is potassium nitrate, potassium chloride, potassium sulfate, Jiao
One or more in potassium phosphate and potassium dihydrogen phosphate.
3. liquid fertilizer as claimed in claim 1, it is characterised in that described composite aminoacid chelating microelement is by being combined
Amino-acid chelate is prepared by chelatropic reaction with sulfate.
4. liquid fertilizer as claimed in claim 3, it is characterised in that described chelates of composite amino acid contain glycine, third
Propylhomoserin, leucine, isoleucine, valine, cystine, cysteine, methionine, threonine, serine, phenylalanine,
Tyrosine, tryptophan, proline, hydroxyproline, glutamic acid and aspartic acid.
5. liquid fertilizer as claimed in claim 3, it is characterised in that described sulfate is ferrous sulfate, manganese sulfate, zinc sulfate
And copper sulfate.
6. liquid fertilizer as claimed in claim 3, it is characterised in that described composite aminoacid chelating microelement building-up process
In, it is added with antioxidant；Described antioxidant is one or more in tea polyphenols, propylgallate, phytic acid.
7. liquid fertilizer as claimed in claim 1, it is characterised in that described synergist be mainly composed of biomass vinegar liquid,
Surfactant and water conservation wetting agent.
8. liquid fertilizer as claimed in claim 7, it is characterised in that described biomass vinegar liquid is Bamboo vinegar solution, wood vinegar, CAOSU
One or more in liquid；Described surfactant is alkyl sodium sulfate, benzene sulfonamide acid amide, polysorbate60, Tween 80, three ethanol
One or more in amine；Described water conservation wetting agent be the one in polyglutamic acid, hydroscopic high-molecular resin, polyacrylamide or
Several.
9. the preparation method of liquid fertilizer described in an any one of claim 1-8, it is characterised in that comprise the steps of:
(1) adding water and the aminoacids complex solid of scheduled volume in reactor, be heated to 40 DEG C-80 DEG C, stirring is to the most molten
Solve；
(2) in the solution that described step (1) obtains, add the ferrous sulfate of scheduled volume, manganese sulfate, zinc sulfate, copper sulfate and resist
Oxidant, regulates pH scope 4-6, and stirs 30min-60min；
(3) after the solution obtained until described step (2) is cooled to room temperature, to its add carbamide ammonium nitrate solution, liquid APP,
Potash fertilizer, boric acid, stirring is until being completely dissolved；
(4) in the solution that described step (3) obtains, biomass vinegar liquid, surfactant, water conservation wetting agent it are sequentially added into, stirring
Until being completely dissolved, obtain liquid fertilizer.
10. preparation method as claimed in claim 9, it is characterised in that also comprise the steps: that (5) treat that described step (4) obtains
To solution bubble eliminate after pack.
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Cited By (8)
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| CN106748380A (en) * | 2016-12-23 | 2017-05-31 | 贵州大学 | A kind of paddy rice dedicated liquid fertilizer containing MTI-446 suspending agent and preparation method thereof |
| CN107417387A (en) * | 2017-07-21 | 2017-12-01 | 华中农业大学 | Micro- fertilizer of balance type multifunctional ecological containing organic active substance and preparation method thereof |
| CN107445683A (en) * | 2017-07-21 | 2017-12-08 | 华中农业大学 | High micro- fertilizer of phosphorous multifunctional ecological containing organic active substance and preparation method thereof |
| CN107960170A (en) * | 2017-12-08 | 2018-04-27 | 佛山科学技术学院 | A kind of method for improving continuous cropping obstacle |
| CN108419636A (en) * | 2018-03-14 | 2018-08-21 | 佛山市三水区嘉信农业技术研究院（普通合伙） | A kind of hyacinth bean implantation methods rich in various trace elements |
| CN108516888A (en) * | 2018-04-23 | 2018-09-11 | 中国科学院沈阳应用生态研究所 | A kind of ammonium polyphosphate Water soluble fertilizer and preparation method thereof suitable for the synergy of greenhouse booth vegetable-growing area |
| CN109851432A (en) * | 2018-07-19 | 2019-06-07 | 华中农业大学 | Multi-functional clear liquid type liquid fertilizer of high potassium containing amino acid and preparation method thereof |
| CN111732489A (en) * | 2020-07-08 | 2020-10-02 | 郑州郑氏化工产品有限公司 | Clear liquid type organic high-potassium fertilizer and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106748380A (en) * | 2016-12-23 | 2017-05-31 | 贵州大学 | A kind of paddy rice dedicated liquid fertilizer containing MTI-446 suspending agent and preparation method thereof |
| CN107417387A (en) * | 2017-07-21 | 2017-12-01 | 华中农业大学 | Micro- fertilizer of balance type multifunctional ecological containing organic active substance and preparation method thereof |
| CN107445683A (en) * | 2017-07-21 | 2017-12-08 | 华中农业大学 | High micro- fertilizer of phosphorous multifunctional ecological containing organic active substance and preparation method thereof |
| CN107960170A (en) * | 2017-12-08 | 2018-04-27 | 佛山科学技术学院 | A kind of method for improving continuous cropping obstacle |
| CN108419636A (en) * | 2018-03-14 | 2018-08-21 | 佛山市三水区嘉信农业技术研究院（普通合伙） | A kind of hyacinth bean implantation methods rich in various trace elements |
| CN108516888A (en) * | 2018-04-23 | 2018-09-11 | 中国科学院沈阳应用生态研究所 | A kind of ammonium polyphosphate Water soluble fertilizer and preparation method thereof suitable for the synergy of greenhouse booth vegetable-growing area |
| CN109851432A (en) * | 2018-07-19 | 2019-06-07 | 华中农业大学 | Multi-functional clear liquid type liquid fertilizer of high potassium containing amino acid and preparation method thereof |
| CN111732489A (en) * | 2020-07-08 | 2020-10-02 | 郑州郑氏化工产品有限公司 | Clear liquid type organic high-potassium fertilizer and preparation method thereof |
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Address after: 200333 room 306, 3 building, 879 Zhongjiang Road, Putuo District, Shanghai. Applicant after: SHANGHAI WINTONG ECOLOGICAL ENGINEERING CO.,LTD. Address before: 200333 room 306, 3 building, 879 Zhongjiang Road, Putuo District, Shanghai. Applicant before: SHANGHAI WINTONG CHEMICALS CO.,LTD. |
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Application publication date: 20161221 |