CN107711877A - 含有壬酸的除草组合物 - Google Patents
含有壬酸的除草组合物 Download PDFInfo
- Publication number
- CN107711877A CN107711877A CN201710901855.5A CN201710901855A CN107711877A CN 107711877 A CN107711877 A CN 107711877A CN 201710901855 A CN201710901855 A CN 201710901855A CN 107711877 A CN107711877 A CN 107711877A
- Authority
- CN
- China
- Prior art keywords
- nonanoic acid
- mcpa
- mcp
- ammonium
- herbicidal combinations
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 title claims abstract description 112
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 41
- 239000011734 sodium Substances 0.000 claims abstract description 40
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 40
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 39
- 239000005574 MCPA Substances 0.000 claims abstract description 38
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 claims abstract description 37
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 claims abstract description 34
- 241000196324 Embryophyta Species 0.000 claims abstract description 26
- 239000000375 suspending agent Substances 0.000 claims abstract description 10
- 239000004563 wettable powder Substances 0.000 claims abstract description 9
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 7
- 238000009472 formulation Methods 0.000 claims abstract description 6
- 239000002671 adjuvant Substances 0.000 claims abstract description 3
- 239000002917 insecticide Substances 0.000 claims abstract description 3
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 claims abstract 5
- 244000025254 Cannabis sativa Species 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 12
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims 6
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 13
- 244000237956 Amaranthus retroflexus Species 0.000 abstract description 10
- 235000013479 Amaranthus retroflexus Nutrition 0.000 abstract description 10
- 241000192043 Echinochloa Species 0.000 abstract description 7
- 239000000575 pesticide Substances 0.000 abstract description 7
- ZBMRKNMTMPPMMK-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid;azane Chemical compound [NH4+].CP(O)(=O)CCC(N)C([O-])=O ZBMRKNMTMPPMMK-UHFFFAOYSA-N 0.000 description 29
- 239000004009 herbicide Substances 0.000 description 19
- -1 carboxylic acids Compound Chemical class 0.000 description 14
- 239000000463 material Substances 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000005864 Sulphur Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000004083 survival effect Effects 0.000 description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- RMFGNMMNUZWCRZ-UHFFFAOYSA-N Humulone Natural products CC(C)CC(=O)C1=C(O)C(O)(CC=C(C)C)C(O)=C(CC=C(C)C)C1=O RMFGNMMNUZWCRZ-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- VMSLCPKYRPDHLN-NRFANRHFSA-N humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)[C@@](O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-NRFANRHFSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 6
- 229940124530 sulfonamide Drugs 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- QHTQREMOGMZHJV-UHFFFAOYSA-N Thiobencarb Chemical compound CCN(CC)C(=O)SCC1=CC=C(Cl)C=C1 QHTQREMOGMZHJV-UHFFFAOYSA-N 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000003851 azoles Chemical class 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000000080 wetting agent Substances 0.000 description 4
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 244000058871 Echinochloa crus-galli Species 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
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- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
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- 229910000278 bentonite Inorganic materials 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
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- 150000002148 esters Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 description 3
- 150000007523 nucleic acids Chemical class 0.000 description 3
- 102000039446 nucleic acids Human genes 0.000 description 3
- 108020004707 nucleic acids Proteins 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
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- 238000001228 spectrum Methods 0.000 description 3
- 238000009333 weeding Methods 0.000 description 3
- OVXMBIVWNJDDSM-UHFFFAOYSA-N (benzhydrylideneamino) 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoate Chemical compound COC1=CC(OC)=NC(OC=2C(=C(OC=3N=C(OC)C=C(OC)N=3)C=CC=2)C(=O)ON=C(C=2C=CC=CC=2)C=2C=CC=CC=2)=N1 OVXMBIVWNJDDSM-UHFFFAOYSA-N 0.000 description 2
- DHYXNIKICPUXJI-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-n-(2,4-difluorophenyl)-5-oxo-n-propan-2-yl-1,2,4-triazole-4-carboxamide Chemical compound C=1C=C(F)C=C(F)C=1N(C(C)C)C(=O)N(C1=O)C=NN1C1=CC=C(Cl)C=C1Cl DHYXNIKICPUXJI-UHFFFAOYSA-N 0.000 description 2
- IXWKBUKANTXHJH-UHFFFAOYSA-N 1-[5-chloro-2-methyl-4-(5-methyl-5,6-dihydro-1,4,2-dioxazin-3-yl)pyrazol-3-yl]sulfonyl-3-(4,6-dimethoxypyrimidin-2-yl)urea Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=C(Cl)C=2C=2OC(C)CON=2)C)=N1 IXWKBUKANTXHJH-UHFFFAOYSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- YOYAIZYFCNQIRF-UHFFFAOYSA-N 2,6-dichlorobenzonitrile Chemical compound ClC1=CC=CC(Cl)=C1C#N YOYAIZYFCNQIRF-UHFFFAOYSA-N 0.000 description 2
- NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 description 2
- YUVKUEAFAVKILW-UHFFFAOYSA-N 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 YUVKUEAFAVKILW-UHFFFAOYSA-N 0.000 description 2
- MAYMYMXYWIVVOK-UHFFFAOYSA-N 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-4-(methanesulfonamidomethyl)benzoic acid Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(CNS(C)(=O)=O)C=2)C(O)=O)=N1 MAYMYMXYWIVVOK-UHFFFAOYSA-N 0.000 description 2
- KRQUFUKTQHISJB-YYADALCUSA-N 2-[(E)-N-[2-(4-chlorophenoxy)propoxy]-C-propylcarbonimidoyl]-3-hydroxy-5-(thian-3-yl)cyclohex-2-en-1-one Chemical compound CCC\C(=N/OCC(C)OC1=CC=C(Cl)C=C1)C1=C(O)CC(CC1=O)C1CCCSC1 KRQUFUKTQHISJB-YYADALCUSA-N 0.000 description 2
- SVOAUHHKPGKPQK-UHFFFAOYSA-N 2-chloro-9-hydroxyfluorene-9-carboxylic acid Chemical compound C1=C(Cl)C=C2C(C(=O)O)(O)C3=CC=CC=C3C2=C1 SVOAUHHKPGKPQK-UHFFFAOYSA-N 0.000 description 2
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 2
- CTSLUCNDVMMDHG-UHFFFAOYSA-N 5-bromo-3-(butan-2-yl)-6-methylpyrimidine-2,4(1H,3H)-dione Chemical compound CCC(C)N1C(=O)NC(C)=C(Br)C1=O CTSLUCNDVMMDHG-UHFFFAOYSA-N 0.000 description 2
- PVSGXWMWNRGTKE-UHFFFAOYSA-N 5-methyl-2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]pyridine-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=C(C)C=C1C(O)=O PVSGXWMWNRGTKE-UHFFFAOYSA-N 0.000 description 2
- DVOODWOZJVJKQR-UHFFFAOYSA-N 5-tert-butyl-3-(2,4-dichloro-5-prop-2-ynoxyphenyl)-1,3,4-oxadiazol-2-one Chemical group O=C1OC(C(C)(C)C)=NN1C1=CC(OCC#C)=C(Cl)C=C1Cl DVOODWOZJVJKQR-UHFFFAOYSA-N 0.000 description 2
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- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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Abstract
本发明公开了含有壬酸的除草组合物，该除草组合物含有活性成分壬酸、草铵膦、二甲四氯钠；组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:1～30:1～5，优选比例5:5～20:1～5；该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量占组合物总质量的5％～80％，其余为农药助剂，它的剂型是可分散油悬浮剂、水分散粒剂、可湿性粉剂中的一种；可应用于防除非耕地杂草。本发明除草组合物因对稗草、反枝苋具有协同增效作用，进而降低农药使用量。
Description
技术领域
本发明属于植物源农药与化学农药组合的农药组合物领域，具体涉及一种含有活性成分壬酸、草铵膦、二甲四氯钠的协同增效除草组合物。
背景技术
壬酸(Nonanoic acid)，是牻牛儿苗科若干植物的天然产物，属于脂肪酸或羧酸类化合物，具有良好的除草活性，毒性低、对环境友好，杀草谱广，可广泛应用于无公害克有机农业生产中；钱振官、沈国辉等对壬酸防除非耕地杂草进行过相关研究(上海农业科技，2008年第6期，植物源除草剂30％壬酸EW防除非耕地杂草试验研究)。
草铵膦(glufosinate-ammonium)，化学名称：(RS)-2-氨基-4-(羟基甲基氧瞵基)丁酸铵，属瞵酸类除草剂，是谷氨酰胺合成抑制剂，具有部分内吸作用的非选择性触杀除草剂。施药后短时间内，植物体内铵代谢陷于紊乱，细胞毒剂铵离子在植物体内累积，与此同时，光合作用被严重抑制，达到除草目的。
2甲4氯(MCPA)，化学名称：2-甲基-4-氯苯氧乙酸，2甲4氯是以酸及各种盐的形式存在，其中有2甲4氯酸、2甲4氯钠盐、2甲4氯二甲胺盐、2甲4氯异辛酯。2甲4氯具有内吸传导性，主要用于苗后茎叶处理，穿过角质层和细胞膜，最后传导到各部分。在不同部位对核酸和蛋白质的合成产生不同影响，在植物顶端抑制核酸代谢和蛋白质的合成，使生长点停止生长，幼嫩叶片不能伸展，抑制光合作用的正常进行，传导到植株下部的药剂，使植物茎部组织的核酸和蛋白质的合成增加，促进细胞异常分裂，根尖膨大，丧失吸收能力，造成茎秆扭曲、畸形，筛管堵塞，韧皮部破坏，有机物运输受阻，从而破坏植物正常的生活能力，最终导致植物死亡。
农业杂草草相复杂，种类繁多，施用化学药剂是防除农业杂草最有效的化学手段之一；用没有交互抗性的新农药来防除农业杂草是一个良好的解决方法；但是，目前开发一个新农药需要筛选上万个化合物，耗资1.2-1.5亿美元，开发周期为5-10年，很难赶的上杂草产生抗药性的速度；其他的方法如作物布局调整、不同农药轮换等，在实际操作过程中，很难起到明显的效果。
合理的化学除草剂复配或混配具有扩大杀草谱，提高防治效果、延长施药时期、减少用药量、降低药害风险、减少残留、延缓杂草耐药性和抗药性的发生与发展等优点，所以选择合适的除草剂复配或混配是解决上述问题的最为有效和经济的方法之一。
开发新品除草剂价格昂贵、周期长，而相比之下，开发与研究高效、低毒、低残留的复配与混配具有投资小、研制周期短而受到国内外的重视，纷纷加大研制力度。
草铵膦、壬酸、二甲四氯钠三元组合物未见报道。
发明内容
本发明提供一种含有草铵膦、壬酸、二甲四氯钠的三元协同增效除草组合物，用于防除非耕地杂草。
本发明通过以下技术方案实现：
一种除草组合物，含有活性成分壬酸、草铵膦、二甲四氯钠，壬酸、草铵膦、二甲四氯钠三者之间的质量份数比例为5:1～30:1～5，进一步的优选壬酸、草铵膦、二甲四氯钠三者之间的质量份数比例为5:5～20:1～5，具体的特定比例的壬酸、草铵膦、二甲四氯钠三者之间的质量份数比例为5:20:5、5:20:3、5:10:5、5:10:2、5:30:5；
该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量占组合物总质量的5％～80％，其余为农药助剂；
该组合物的剂型可以可分散油悬浮剂、水分散粒剂、可湿性粉剂中的一种；
所述除草组合物，在防除非耕地杂草上的应用。
合理的化学除草剂复配或混配具有扩大杀草谱，提高防治效果、延长施药时期、减少用药量、降低药害风险、减少残留、延缓杂草耐药性和抗药性的发生与发展等优点，所以选择合适的除草剂复配或混配是解决上述问题的最为有效和经济的方法之一。
本发明具有如下有益效果：
1、所述除草组合物对稗草具有协同增效作用；
2、所述除草组合物对反枝苋具有协同增效作用；
3、所述除草组合物因对稗草、反枝苋具有协同增效作用，进而降低农药使用量。
具体实施方式
为了使本发明的目的、技术方案及优点更加简洁明了，本发明用以下具体实施例进行说明，但本发明绝非仅限于这些例子。以下所述仅为本发明较好的实施例，仅仅用于描述本发明，不能理解为对本发明的范围的限制。应当指出的是，凡在本发明的精神和原则之内所做的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。
本发明的协同性混合物可与一种或更多种其它除草剂联合施用以防治更广种类的不期望的植被。当与其它除草剂联合使用时，所述组合物可与其它一种或多种除草剂配制，与其它一种或多种除草剂进行罐混合或与其它一种或多种除草剂先后施用。可与本发明的协同增效组合物联合使用的一些除草剂包括：刈草胺(acetochlor)、三氟羧草醚(acifluorfen)、苯草醚(aclonifen)、AE0172747、草不绿(alachlor)、磺氨磺隆(amidosulfuron)、氨基三唑(aminotriazole)、硫氰酸铵(ammonium thiocyanate)、莎稗磷(anilofos)、莠去津(atrazine)、AVH301、四唑磺隆(azimsulfuron)、呋草磺(benfuresate)、苯达松(bentazone)、杀草丹(benthiocarb)、苯并双环酮(benzobicyclon)、治草醚(bifenox)、双草醚(bispyribac-sodium)、除草定(bromacil)、溴苯腈(bromoxynil)、丁草胺(butachlor)、氟丙嘧草酯(butafenacil)、地乐胺(butralin)、唑草胺(cafenstrole)、长杀草(carbetamide)、唑草酮(carfentrazone-ethyl)、双唑草酮、氯甲丹(chlorflurenol)、氯苯胺灵(chlorpropham)、烯草酮(clethodim)、异噁草酮(clomazone)、氯酯磺草胺(cloransulam-methyl)、噻草酮(cycloxydim)、麦草畏(dicamba)、敌草腈(dichlobenil)、精2,4-滴丙酸(dichlorprop-P)、唑嘧磺胺(diclosulam)、吡氟酰草胺(diflufenican)、二氟吡隆(diflufenzopyr)、二甲吩草胺(dimethenamid)、精二甲吩草胺(dimethenamid-p)、敌草快(diquat)、氟硫草定(dithiopyr)、敌草隆(diuron)、EK2612、茵草敌(EPTC)、禾草畏(esprocarb)、ET-751、乙氧嘧磺隆(ethoxysulfuron)、ethbenzanid、F7967、噁唑禾草灵(fenoxaprop)、噁唑禾草灵(fenoxaprop-ethyl)、噁唑禾草灵(fenoxaprop-ethyl)+双苯噁唑酸乙酯(isoxadifen-ethyl)、四唑草胺(fentrazamide)、氟酮磺草胺、啶嘧磺隆(flazasulfuron)、双氟磺草胺(florasulam)、吡氟甲禾灵(fluazifop)、精吡氟禾草灵(fluazifop-P-butyl)、氟噻草胺(flufenacet)、氟哒嗪草酯(flufenpyr-ethyl)、氟唑啶草(flumetsulam)、氟烯草酸(flumiclorac-pentyl)、丙炔氟草胺(flumioxazin)、伏草隆(fluometuron)、氟啶磺隆(flupyrsulfuron)、氟磺胺草醚(fomesafen)、甲酰胺磺隆(foramsulfuron)、fumiclorac、草甘膦(glyphosate)、氟吡甲禾灵(haloxyfop-methyl)、精氟吡禾灵(haloxyfop-R)、咪草酯(imazamethabenz)、咪草啶酸(imazamox)、甲咪唑烟酸(imazapic)、灭草喹(imazaquin)、咪草烟(imazethapyr)、啶咪磺隆(imazosulfuron)、茚草酮(indanofan)、三嗪茚草胺(indaziflam)、碘磺隆(iodosulfuron)、碘苯腈(ioxynil)、ipfencarbazone(HOK-201)、IR5790,异丙隆(isoproturon)、异噁酰草胺(isoxaben)、异噁氟草酮(isoxaflutole)、KUH-071、乳氟禾草灵(lactofen)、利谷隆(linuron)、2甲4氯(MCPA)、MCPA酯&胺、精2甲4氯丙酸(mecoprop-P)、苯噻酰草胺(mefenacet)、甲基二磺隆(mesosulfuron)、甲基磺草酮(mesotrione)、双醚氯吡嘧磺隆(metazosulfuron,NC-620)、异丙甲草胺(metolachlor)、唑草磺胺(metosulam)、噁嗪草酮(oxaziclomefone)、嗪草酮(metribuzin)、甲磺隆(metsulfuron)、草达灭(molinate)、甲胂一钠(MSMA)、敌草胺(napropamide)、烟嘧磺隆(nicosulfuron)、达草灭(norflurazon)、OK-9701、黄草消(oryzalin)、丙炔噁草酮(oxadiargyl)、噁草酮(oxadiazon)、oxazichlomefone、乙氧氟草醚(oxyfluorfen)、乙羧氟草醚(Fluoroglycofen)、百草枯(paraquat)、胺硝草(pendimethalin)、五氟磺草胺(penoxsulam)、戊噁唑草(pentoxazone)、烯草胺(pethoxamid)、哌草磷(piperophos)、丙草胺(pretilachlor)、氟嘧磺隆(primisulfuron)、环苯草酮(profoxydim)、毒草安(propachlor)、敌稗(propanil)、propyrisulfuron(TH-547)、炔苯酰草胺(propyzamide)、苄草丹(prosulfocarb)、氟丙磺隆(prosulfuron)、双唑草腈(pyraclonil)、pyrazogyl、嘧苯草肟(pyribenzoxim,LGC-40863)、环酯草醚(pyriftalid)、嘧草醚(pyriminobac-methyl)、氟嘧啶草醚、pyrimisulfan(KUH-021)、甲氧磺草胺(pyroxsulam)、pyroxasulfone(KIH-485)、quizalofop-ethyl-D、S-3252、稀禾定(sethoxydim)、SL-0401、SL-0402、精异丙甲草胺(S-metolachlor)、磺草酮(sulcotrione)、环磺酮(Tembotrione)、三唑磺草酮、磺胺草唑(sulfentrazone)、草硫膦(sulfosate)、丁唑隆(tebuthiuron)、tefuryltrione(AVH-301)、特草定(terbacil)、噻草啶(thiazopyr)、禾草丹(thiobencarb)、绿草定(triclopyr)、氟乐灵(trifluralin)和三氟甲磺隆(tritosulfuron)、二氯喹啉酸(quinclorac)、苯吡唑草酮(Topramezone)、氟吡草酮(bicyclopyrone)。
所述的除草组合物通过一定的技术手段可赋型为悬浮剂、可分散油悬浮剂、水分散粒剂、可湿性粉剂等。
实施例1
所述可分散油悬浮剂剂型按质量百分数组成为：壬酸0.1～5％，草铵膦0.1～30％，二甲四氯钠0.1～5％、分散剂0.1～11％、湿润剂0.1～7％、增稠剂0.1～3％，液体载体补足至100％。具体生产步骤为：将有效成分和其它助剂混合，经高速剪切分散、砂磨机中砂磨后，在非水系介质中形成高分散、稳定的悬浮体系，制得相应质量百分含量的可分散油悬浮剂，可分散油悬浮剂总活性成分含量不高于40％。
实施例2
所述水分散粒剂剂型按质量百分数组成为：壬酸0.1～10％，草铵膦0.1～60％，二甲四氯钠0.1～10％、分散剂0.1～9％、湿润剂0.1～4％、崩解剂0.1～6％，固体载体补足至100％。具体生产步骤为：将有效成分和其它助剂混合均匀，用超微气流粉碎机粉碎，经捏合，然后加入流化床造粒干燥机中进行造粒、干燥、筛分，制得相应质量百分含量的水分散粒剂，水分散粒剂总活性成分含量不高于80％。
实施例3
所述可湿性粉剂剂型按质量百分数组成为：壬酸0.1～10％，草铵膦0.1～60％，二甲四氯钠0.1～10％、分散剂0.1～10％、湿润剂0.1～8％，固体载体补足至100％。具体生产步骤为：将有效成分和其它助剂混合，机械粉碎后再经气流粉碎，混合均匀，制得相应质量百分含量的可湿性粉剂，可湿性粉剂总活性成分含量不高于80％。
所述的防冻剂可以是甘油、丙二醇、二甘醇、尿素、甘油-乙醚双甘醇、无机盐等中一种或几种。
所述的湿润剂可以是十二烷基硫酸钠、十二烷基苯磺酸钠、丁基萘磺酸钠、烷基磺酸钠、茶枯粉、皂角粉、无患子粉、缩合磷酸盐、硫酸盐、磷酸盐等中的一种或几种。
所述的分散剂可以是烷基酚聚氧乙烯醚甲醛缩合物、萘磺酸盐甲醛缩合物、对甲氧基脂肪酰胺基苯磺酸、木质素磺酸盐、聚羧酸盐、烷基酚聚氧乙烯醚硫酸盐、烷基苯磺酸钙盐、脂肪酸酯硫酸盐、烷基酚聚氧乙烯醚、脂肪醇聚氧乙烯醚、聚氧乙烯聚氧丙烯基醚嵌段共聚物等中的一种或几种。
所述的崩解剂可以是羧甲基淀粉钠、低取代羟丙基纤维素、交联羧甲基纤维素钠、交联聚维酮、壳聚糖、海藻酸钠碳酸氢钠、氯化镁、氯化铝、氯化钠、尿素、硫酸铵、膨润土等中的一种或几种。
所述的增稠剂可以是聚乙酸乙烯酯、黄原胶、明胶、阿拉伯树胶、硅酸镁铝、酚醛树脂、羟甲基纤维素、海藻酸钠等中的一种或几种。
所述的固体载体可以是轻质碳酸钙、陶土、高岭土、硅藻土、膨润土、白炭黑、粘土、凹凸棒土、滑石粉、石英沙等中的一种或几种。
所述的液体载体可以是精致大豆油、玉米油、菜籽油、松节油、油酸甲酯、椰子油、棕榈油、花生油、葵花油等中的一种或几种。
本发明组合物的施用频率和施用量随农作物、杂草、天气情况变化而有小量变化，可以通过使用适当的剂量达到有效防治的目的。
实施例4室内毒力实施例
根据Colby公式，参见S.R.Colby，“Calculating Synergistic and AntagonisticResponses of Herbicide combinations”Weeds 1967,15,20-22)：
A以某剂量单用时对靶标杂草的存活率或鲜重残存率(％)；
B以某剂量单用时对靶标杂草的存活率或鲜重残存率(％)；
C以某剂量单用时对靶标杂草的存活率或鲜重残存率(％)；
评价标准：存活率观测值小于理论值时具有协同作用(增效作用)
壬酸、草铵膦、二甲四氯钠及其复配对稗草(Echinochloa crusgalli)、反枝苋(Amaranthus retroflexus)的室内毒力测定。
Obs-观测的防治百分数。
Exp-Colby等式所预期的防治百分数。
g a.i./ha-克活性成分/公顷。
杂草为人工培养，草龄为2叶到3叶，施药方法为茎叶喷雾，每公顷用水量675升。
表1壬酸、草铵膦、二甲四氯钠及其复配对稗草(Echinochloa crusgalli)的室内毒力测定结果
根据Colby法评价除草剂联合方式，表1记载的数据结果表明，草铵膦、壬酸、二甲四氯钠三元组合对稗草(Echinochloa crusgalli)增效作用显著，E0-E值均大于20％，其中10+5+2、10+5+5、20+5+3、20+5+5、30+5+5的E0-E值均大于30％。
表2壬酸、草铵膦、二甲四氯钠及其复配对反枝苋(Amaranthus retroflexus)的室内毒力测定结果
根据Colby法评价除草剂联合方式，表1记载的数据结果表明，草铵膦、壬酸、二甲四氯钠三元组合对反枝苋(Amaranthus retroflexus)增效作用显著，E0-E值均大于20％，其中10+5+2、10+5+5、20+5+3、20+5+5、30+5+5的E0-E值均大于30％。
实施例5制剂实施例
5％壬酸30％草铵膦5％二甲四氯钠水分散粒剂
壬酸5％、草铵膦30％、二甲四氯钠5％、聚羧酸盐类5％、玉米粉7％、木质素磺酸钠7％、硅藻土至100％；将上述物料一起加入锥形混合机中混合均匀，后经气流粉碎机粉碎，粉碎后的物料再经锥形混合机混合，混合后的物料细度98％通过600目标准筛，加入捏合机中捏合成可塑性物料，最后将此物料放入挤压造粒机中挤压造粒，造粒后经干燥、筛分后即制得40％壬酸·草铵膦·二甲四氯钠水分散粒剂。
10％壬酸40％草铵膦10％二甲四氯钠可湿性粉剂
壬酸10％、草铵膦40％、二甲四氯钠10％、十二烷基硫酸钠18％、硅藻土5％、高岭土至100％；将上述物料一起加入锥形混合机中混合均匀，后经气流粉碎机粉碎，粉碎后的物料再经锥形混合机混合，混合后的物料细度98％通过600目标准筛，60％壬酸·草铵膦·二甲四氯钠可湿性粉剂。
5％壬酸20％草铵膦3％二甲四氯钠可分散油悬浮剂
壬酸5％、草铵膦20％、二甲四氯钠3％、苯乙苯酚聚氧乙烯醚8％、、油酸甲酯15％、聚氧乙烯聚氧丙烯醚嵌段共聚物7％、膨润土3％、玉米油至100％；将上述物料(有机膨润土除外)一起加入到反应釜混合机中，搅拌2小时，打开釜底入料阀，将物料注入多级砂磨机中研磨，研磨后的物料细度98％通过1-5um后出料，物料再与事先溶解好的有机膨润土一起放入高剪切乳化釜中，乳化后即可制成流到性良好的28％壬酸·草铵膦·二甲四氯钠可分散油悬浮剂。
实施例6应用实施例
壬酸、草铵膦、二甲四氯钠组合物防除水稻田一年生杂草田间药效试验
表3壬酸、草铵膦、二甲四氯钠对防除水稻田一年生禾本科杂草田间药效试验，田间优势禾本科杂草为稗草、反枝苋、碎米莎草、小飞蓬，防治方法为茎叶喷雾，每亩用水30千克。
药效计算公式如下：
Claims (10)
1.一种含有壬酸的除草组合物，其特征在于：含有活性成分壬酸、草铵膦、二甲四氯钠，该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:1～30:1～5。
2.根据权利要求1所述的含有壬酸的除草组合物，其特征在于：该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:5～20:1～5。
3.根据权利要求1所述的含有壬酸的除草组合物，其特征在于：该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:20:5。
4.根据权利要求1所述的含有壬酸的除草组合物，其特征在于：该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:20:3。
5.根据权利要求1所述的含有壬酸的除草组合物，其特征在于：该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:10:5。
6.根据权利要求1所述的含有壬酸的除草组合物，其特征在于：该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:10:2。
7.根据权利要求1所述的含有壬酸的除草组合物，其特征在于：该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量比例为5:30:5。
8.根据权利要求1～7所述的含有壬酸的除草组合物，其特征在于：该组合物中壬酸、草铵膦、二甲四氯钠三者之间的质量占组合物总质量的5％～80％，其余为农药助剂。
9.根据权利要求8所述的含有壬酸的除草组合物，其特征在于：所述除草组合物的剂型是可分散油悬浮剂、水分散粒剂或可湿性粉剂。
10.权利要求1所述的含有壬酸的除草组合物在防治非耕地杂草上的应用。
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