CN1076032C - Fine denier and super-fine denier polypropylene alloy fibre and its prodn. method - Google Patents
Fine denier and super-fine denier polypropylene alloy fibre and its prodn. method Download PDFInfo
- Publication number
- CN1076032C CN1076032C CN95119564A CN95119564A CN1076032C CN 1076032 C CN1076032 C CN 1076032C CN 95119564 A CN95119564 A CN 95119564A CN 95119564 A CN95119564 A CN 95119564A CN 1076032 C CN1076032 C CN 1076032C
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- Prior art keywords
- denier
- fine
- polypropylene
- spinning
- polypropylene resin
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 52
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 48
- -1 polypropylene Polymers 0.000 title claims abstract description 48
- 239000000835 fiber Substances 0.000 title claims abstract description 23
- 239000000956 alloy Substances 0.000 title claims description 11
- 229910045601 alloy Inorganic materials 0.000 title claims description 11
- 238000000034 method Methods 0.000 title abstract description 11
- 238000009987 spinning Methods 0.000 claims abstract description 28
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 238000002144 chemical decomposition reaction Methods 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000002074 melt spinning Methods 0.000 claims abstract description 7
- 239000011342 resin composition Substances 0.000 claims abstract description 4
- 229920013716 polyethylene resin Polymers 0.000 claims abstract 3
- 239000000155 melt Substances 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims 2
- 238000005275 alloying Methods 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 7
- 239000012752 auxiliary agent Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000000805 composite resin Substances 0.000 description 6
- 229920000915 polyvinyl chloride Polymers 0.000 description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 4
- 235000013539 calcium stearate Nutrition 0.000 description 4
- 239000008116 calcium stearate Substances 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a method for manufacturing a thin denier polypropylene fiber and a super thin denier polypropylene fiber through an alloying polypropylene resin composition. An alloying polypropylene resin composition composed of polymerization grade polypropylene resin with low fluidity, chemical degradation polypropylene resin with high fluidity, one kind or a plurality of kinds of polyethylene resin and a processing auxiliary agent is used as a special spinning material. Melt spinning is carried out on universal spinning equipment to obtain a thin denier polypropylene fiber and a super thin denier polypropylene fiber which have the monofilament size which is from 0.5 to 2.0 denier. Tensile strength is from 2.5 to 6 gram/denier; breaking elongation is from 20 to 140%; spinning stability is good; the disadvantage that a head is broken during the spinning is reduced.
Description
The present invention relates to a kind of manufacture method of polypropylene fibre, specially refer to the manufacture method of a kind of thin dawn and superfine denier polypropylene fibers.
Traditional theory is thought, make thin dawn and superfine denier polypropylene fibers, require its material resin to have good fluidity of molten, lower molecular weight and narrow molecular weight distribution, it is very difficult poor with stability of spinning process that practice shows with the acrylic resin reduction filament number of above-mentioned characteristic, USP.4 in 1981,296,022 has reported acrylic resin with different molecular weight mix by a certain percentage after, can be used for making polypropylene fibre, the Chinese patent patent No.: 91104649.6 have set forth polymer grade polypropylene resin and the thin dawn of chemical degradation of polypropylene resin composition manufacturing of high workability and the method for superfine denier polypropylene fibers that adopts low flow.
It is poor that the present invention has overcome stability of spinning process, reduce the shortcoming of filament number difficulty, and the method for a kind of usefulness " alloying " polypropylene resin composite thin dawn of manufacturing and superfine denier polypropylene fibers is provided on the basis of the Chinese patent patent No. 91104649.6 patented technologies.
The used spinning PP Pipe Compound of method that the present invention makes thin dawn and superfine denier polypropylene fibers is the polymer grade polypropylene resin by low flow, the chemical degradation of polypropylene resin of high workability, a kind of " alloying " polypropylene resin composite that one or more polyvinyl resins and processing aid combine, the melt flow index MFI of said composition is 20-90 gram/10 minutes, preferable melt flow index is 25-75 gram/10 minutes, the melt flow index MFI of polymer grade polypropylene resin is that the 0.5-10 gram (was pressed ASTM D1238 in/10 minutes in the above-mentioned composition, 230 ℃, 2.16 kilogram), the melt flow index MFI of above-mentioned chemical degradation of polypropylene resin is 15-100 gram/10 minutes, and its molecular weight distributing index Q is 1.2-1.7.(measuring method of Q value is seen polymer communication, 1983,3,234), the melt flow index MFI of above-mentioned polyvinyl resin are 5-55 gram/10 minutes, and above-mentioned processing aid comprises stablizer, FLOW IMPROVERS, tinting material, static inhibitor and dyeing auxiliaries.The manufacture method of thin dawn of the present invention and superfine denier polypropylene fibers is to adopt above-mentioned spinning PP Pipe Compound to carry out melt-spinning on general spinning equipment, spinning temperature is 220-280 ℃, preferable spinning temperature is 240-270 ℃, spinning speed be 500-3500 rice/minute, but make well behaved undrawn yarn of drawing-off or pre-oriented yarn, its cross section is circle or triangle profile, with undrawn yarn or pre-oriented yarn carries out hot drawing-off or hot drawing-off adds bullet, drafting multiple is 1.5-4.0 times, and making filament number is thin dawn and the superfine denier polypropylene multifilament or the low stretch yarn at 0.5-2.0 dawn.
Adopt manufacture method stability of spinning process of the present invention good, reduced broken end, waft the silk shortcoming, the filament number of making is the 0.5-2.0 dawn, its tensile strength is the 2.5-6 gram/dawn, its elongation at break is 20-140%.
Context of the present invention can be with the further additional explanation of the following example, but can not think that the present invention only only limits to these embodiment.
Embodiment 1:
Select " alloying " polypropylene resin composite of following prescription (seeing Table 1) for use, said composition melt flow index MFI is 38 grams/10 minutes, carries out melt-spinning.Spinning speed is 650 meters/minute, spinning temperature is 248 ℃ must arrive the undrawn yarn that the cross section is a trilobal, through drawing temperature is that 120 ℃ and drafting multiple are 3.2 to carry out drawing-off, and obtaining filament number was 1.3 dawn, tensile strength be 4.0 grams but and elongation be 51% fine denier filament.
1,010 0.2 parts of table 1,0.2 part of 0.2 part of Irganox of 0.1 part of 2,6 di tert butyl 4 methyl phenol of calcium stearate of 95 parts of polyvinyl resins of 5 parts of chemical degradation modified polypropenes of spinning formula of special material polymer grade polypropylene (MFI=18 gram/10 minutes)
Embodiment 2:
Select " alloying " polypropylene resin composite of following prescription (seeing Table 2) for use, said composition melt flow index MFI is 37 grams/10 minutes, carries out melt-spinning.Spinning speed is 900 meters/minute, spinning temperature is 248 ℃ must arrive the undrawn yarn that the cross section is a trilobal, through drawing temperature is that 100 ℃ and drafting multiple are 3.2 to carry out drawing-off, and obtaining filament number was 0.8 dawn, and tensile strength is that 5.5 gram/dawn and elongation are 23% fine denier filament.
Table 2,2 parts of 1,010 0.2 parts of embodiment 3 of 0.2 part of Irganox of 0.1 part of 2,6 di tert butyl 4 methyl phenol of calcium stearate of 95 parts of polyvinyl resins of 5 parts of chemical degradation modified polypropenes of spinning formula of special material polymer grade polypropylene (MFI=18 gram/10 minutes):
The alloying polypropylene resin composite that makes by table 3, the melt flow index of said composition is 51 grams/10 minutes, carry out melt-spinning, spinning speed is 1000 meters/minute, spinning temperature is 260 ℃, must arrive the cross section and be circular undrawn yarn, is that 100 ℃ and drafting multiple are 2.5 to carry out drawing-off through drawing temperature, obtaining filament number was 0.9 dawn, and tensile strength is that 3.1 gram/dawn and elongation are 140% fine denier filament.
1,010 0.2 parts of table 3,10 parts of 0.2 part of Irganox of 0.1 part of 2,6 di tert butyl 4 methyl phenol of calcium stearate of 90 parts of polyvinyl resins of 5 parts of chemical degradation modified polypropenes of spinning formula of special material polymer grade polypropylene (MFI=18 gram/10 minutes)
Embodiment 4:
The melt flow index of the alloying polypropylene resin composite said composition that makes by table 3 is 42 grams/10 minutes, carry out melt-spinning, spinning speed is 3200 meters/minute, spinning temperature is 264 ℃, must arrive the cross section is circular pre-oriented yarn, through drawing temperature is that 130 ℃ and drafting multiple are 2.4 to carry out drawing-off, and obtaining filament number was 1.1 dawn, and tensile strength is that 4.3 gram/dawn and elongation are 54% fine denier filament.
1,010 0.2 parts of table 4,2 parts of 0.2 part of Irganox of 0.1 part of 2,6 di tert butyl 4 methyl phenol of calcium stearate of 95 parts of polyvinyl resins of 5 parts of chemical degradation modified polypropenes of spinning formula of special material polymer grade polypropylene (MFI=50 gram/10 minutes)
Four [β-(3,5-di-tert-butyl-4-hydroxyl-phenyl) propionic acid] tetramethylolmethane that above-mentioned Irganox 1010 produces for Beijing Chemical Factory No. 3.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95119564A CN1076032C (en) | 1995-11-24 | 1995-11-24 | Fine denier and super-fine denier polypropylene alloy fibre and its prodn. method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95119564A CN1076032C (en) | 1995-11-24 | 1995-11-24 | Fine denier and super-fine denier polypropylene alloy fibre and its prodn. method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1151410A CN1151410A (en) | 1997-06-11 |
| CN1076032C true CN1076032C (en) | 2001-12-12 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95119564A Expired - Fee Related CN1076032C (en) | 1995-11-24 | 1995-11-24 | Fine denier and super-fine denier polypropylene alloy fibre and its prodn. method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1076032C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1086367C (en) * | 1998-07-17 | 2002-06-19 | 中国科学院化学研究所 | Fine PP fiber reinforced cement based composite material, and use thereof |
| CN1123595C (en) * | 1998-08-31 | 2003-10-08 | 中国科学院化学研究所 | High-flowability polypropylene resin composition and its preparing process and usage |
| CN1116241C (en) * | 2000-04-26 | 2003-07-30 | 中国纺织大学化纤科技开发部 | Modified polypropene staple for concrete and mortar |
| US20110052913A1 (en) | 2008-01-21 | 2011-03-03 | Mcamish Larry | Monofilament fibers comprising at least one filler, and processes for their production |
| CN107513814B (en) * | 2017-07-04 | 2021-08-06 | 马鞍山市鑫程纳米新材料科技有限公司 | Preparation method for improving elasticity of spun-bonded polypropylene non-woven fabric |
| CN109535546A (en) * | 2018-10-26 | 2019-03-29 | 弓立（厦门）医疗用品有限公司 | A kind of antibacterial bacteriostatic nonwoven fabric formula |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4296022A (en) * | 1980-06-04 | 1981-10-20 | Chevron Research | Polypropylene blend compositions |
| CN1068603A (en) * | 1991-07-13 | 1993-02-03 | 中国科学院化学研究所 | Process for the manufacture of fine and ultrafine denier polypropylene fibers |
-
1995
- 1995-11-24 CN CN95119564A patent/CN1076032C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4296022A (en) * | 1980-06-04 | 1981-10-20 | Chevron Research | Polypropylene blend compositions |
| CN1068603A (en) * | 1991-07-13 | 1993-02-03 | 中国科学院化学研究所 | Process for the manufacture of fine and ultrafine denier polypropylene fibers |
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| Publication number | Publication date |
|---|---|
| CN1151410A (en) | 1997-06-11 |
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