CN1074653A - Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant - Google Patents
Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant Download PDFInfo
- Publication number
- CN1074653A CN1074653A CN 92100417 CN92100417A CN1074653A CN 1074653 A CN1074653 A CN 1074653A CN 92100417 CN92100417 CN 92100417 CN 92100417 A CN92100417 A CN 92100417A CN 1074653 A CN1074653 A CN 1074653A
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- Prior art keywords
- rubber
- composite slab
- equipment
- glue
- slab rubber
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 42
- 239000002131 composite material Substances 0.000 title claims abstract description 19
- 229920005549 butyl rubber Polymers 0.000 title claims abstract description 14
- 238000005260 corrosion Methods 0.000 title claims description 14
- 230000007797 corrosion Effects 0.000 title claims description 14
- 238000004073 vulcanization Methods 0.000 title description 8
- 239000003292 glue Substances 0.000 claims abstract description 21
- 238000005987 sulfurization reaction Methods 0.000 claims abstract description 9
- 229920001206 natural gum Polymers 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 6
- 239000004568 cement Substances 0.000 claims abstract description 6
- 229920005556 chlorobutyl Polymers 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 6
- 238000010276 construction Methods 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 12
- 238000001035 drying Methods 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000011787 zinc oxide Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000010057 rubber processing Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920001368 Crepe rubber Polymers 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 235000012550 Pimpinella anisum Nutrition 0.000 description 1
- 240000004760 Pimpinella anisum Species 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000010892 electric spark Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The invention provides a kind of presulfurization composite slab rubber, be the butyl rubber that will vulcanizate or chlorobutyl rubber as outer layer glue, adopt material sulfuration back such as natural gum cis-butadiene cement as the internal layer bonded adhesives, two kinds of composite slab rubber materials that offset plate is fitted and is pressed into.This composite slab rubber, decay resistance and adhesive property are preferably arranged, use the lining technology of this composite slab rubber, do not need refrigerating equipment, the energy is saved in easy construction, is convenient to repair, be suitable for adopting in the equipment of seriously corroded under different condition and the container, the equipment that is specially adapted to is big, the anticorrosion benefit glue of large-scale groove, jar, crossbeam of transportation inconvenience, sulfuration difficulty.
Description
The present invention relates to a kind of corrosion-resistant composite slab rubber material and manufacture method thereof.
At chemical industry, metallurgical, electric power, in the production process of industries such as light industry, the rubber lining of equipment is etch-proof effective ways commonly used, this method requires the densification of lining rubber material structure, to acid, alkali, salt medium has corrosion resistance preferably, with the equipment matrix good adhesive property is arranged, but for a long time, anticorrosion line with rubber plate is the way that adopts first line with rubber after cure, or adopt individual layer pre-vulcanized butyl rubber lining technology, the rubber-lining method of lining after cure earlier, cure time is long, what use is anti-impact force and the relatively poor hard rubber of resistant and oscillation resistant power, its service life is short, the body sulfuration is dangerous, large chemical equipment, the crossbeam that particularly needs line with rubber, groove, jar inconvenience sulfuration, though and the individual layer pre-vulcanized butyl rubber is a kind of corrosion resistance, temperature tolerance, air-tightness is lining material preferably, but its offset plate and metallic object bond properties are relatively poor, delamination easily, and service life is short, the conduction accident appears when the spark test instrument detects easily, therefore, equipment line with rubber technology is subjected to vulcanizing tank volume and sulfuration process, particularly the high steam heat cure can not make the development of line with rubber equipment also be subjected to certain restriction in the restriction of rubber liner on-site construction.
The invention provides a kind of corrosion resistance, anti-impact force, resistant and oscillation resistant power, resistance to tearing and viscosity all are much higher than the double-deck pre-vulcanized butyl rubber composite slab rubber of lining after cure earlier or individual layer pre-vulcanized butyl rubber, it is characterized in that the butyl rubber that will vulcanizate or chlorobutyl rubber are as corrosion-resistant outer layer glue, adopt natural gum, materials such as cis-butadiene cement sulfuration back is as the internal layer bonded adhesives, two kinds of offset plates are fitted and are pressed into the composite slab rubber material, warehouse-in is deposited, ready access upon use, make this composite slab rubber, decay resistance and adhesive property are preferably arranged, use the lining technology of this composite slab rubber, do not need refrigerating equipment, the energy is saved in easy construction, is convenient to repair, be suitable for adopting in the equipment of seriously corroded under different condition and the container, the equipment that is specially adapted to is big, transportation inconvenience, the large-scale groove of sulfuration difficulty, jar, the anticorrosion line with rubber of crossbeam.
The Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant manufacturing comprise compounding ingredient processing, rubber processing, rubber plasticate, cooperate mixing, add technologies (seeing Figure of description) such as sulphur heat refining, four roller slices, applying, compression molding, compression molding.
Below in conjunction with an embodiment, the Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant manufacturing process is illustrated it in detail.
One, factory formula:
Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant outer layer glue prescription
1
#Natural gum 6.000 (gram)
HT10-68 chlorinated butyl rubber 14.000 (gram)
Sulphur 0.140 (gram)
M promoter 0.200 (gram)
Zinc oxide 1.000 (gram)
Stearic acid 0.400 (gram)
D age resistor 0.300 (gram)
HAF carbon black 10.000 (gram)
2402 resins 0.600 (gram)
Rosin 0.200 (gram)
Add up to 32.840 (grams)
Gum content 61 (%)
Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant hose lining prescription
1
#Natural gum 9.000 (gram)
Cis-butadiene cement 6.000 (gram)
Sulphur 0.030 (gram)
TT promoter 0.300 (gram)
DM promoter 0.120 (gram)
Zinc oxide 0.750 (gram)
Stearic acid 0.225 (gram)
Paraffin 0.100 (gram)
A age resistor 0.150 (gram)
D age resistor 0.150 (gram)
Potter's clay 3.750 (gram)
Barium sulfate 6.000 (gram)
Talcum powder 9.750 (gram)
High-voltage device oil 0.750 (gram)
Add up to 37.075 (grams)
Gum content 41 (%)
Two, manufacturing process:
1, compounding ingredient processing:
(1) drying: just determine criteria thus the drying time according to the raw material moisture content, can put into production after up to standard.
Technological standards
| The raw material title | Drying temperature | Should reach standard after the processing |
| Promote M.TT.DM | Below 90 ℃ | Moisture content is no more than 0.2% |
| Zinc oxide | Below 150 ℃ | Moisture content is no more than 0.2% |
| Potter's clay | Below 105 ℃ | Moisture content is no more than 0.5% |
| Barium sulfate | Below 105 ℃ | Moisture content is no more than 1.5% |
(2) screening: transposing is when sieving medicinal powder, former kind powder should be removed totally, and when idling up to no former medicinal powder, can add another kind of medicinal powder and screen; Sieve was checked fineness once every one hour when making, as had a question and answer parking checking.
Technological standards
| The raw material title | Machine sieve mesh/inch | Manual sieve mesh/inch | Reach standard behind the sieve |
| Sulphur | 80～120 | The full no-sundries of crossing | |
| Promoter | 40 | The full no-sundries of crossing | |
| Zinc oxide | 80 | The full no-sundries of crossing | |
| Antioxidant D | 40 | The full no-sundries of crossing | |
| Potter's clay | 100 | The full no-sundries of crossing | |
| Barium sulfate | 80 | The full no-sundries of crossing |
(3) pulverize: should note removal of contamination during pulverizing.
Technological standards
| The raw material title | Processing mode | Reach standard after the processing |
| Hard ester acid, paraffin | Smash by hand | The grain sheet heavily is not more than 10 grams |
| Antioxidant A | Smash by hand | The grain sheet heavily is not more than 10 grams |
2, rubber processing:
(1) drying glue: use the drying room drying glue, 45 ℃-55 ℃ of drying glue temperature-summers, 55 ℃-75 ℃ of winters.
Working stamndard:
1. natural gum should be removed foreign material such as the sand on surface, these bits, the end of a thread and totally can send drying room to.
2. natural gum is sent drying room to and is wanted the strict grade of distinguishing.
3. rubber polymer is forbidden to be exposed to the sun under daylight, and three days before use winter, palpus was deposited in indoor warehouse.
4. under the temperature normal condition, rubber drying glue in the winter time is no more than 48 hours.
5. the rubber grade is constant does not generally allow upgrading to use.
(2) cut glue: use vertical electric hilted broadsword bale splitter.
Technological standards:
1. smoke sheet rubber, crepe rubber blob of viscose are not more than 80～100 millimeters, and weight is not more than 15 kilograms.
2. become the particle natural glue of piece, cut glue according to refining glue weighing needs size.
3. synthetic blob of viscose is cut glue according to refining glue weighing size.
3, rubber is plasticated: use 16 * 40 " opening rubber mixing machines.
Working stamndard:
1. roll temperature: preliminary roller 45-55 ℃, back roller 55-65 ℃.
2. roll spacing: 0.8～1.2 millimeter.
3. weight is no more than 30 kilograms, per car plastic cement allowable error: ± 0.2 kilogram.
4. after each pillow bag is got off, answer pound accurately.
4, cooperate: use the platform scale metering.
| The platform scale specification | The raw material title | Allowable error |
| 1-5 kilogram platform balance | Sulphur, promoter, single amount small powder | ± 5 grams |
| 5-10 kilogram platform balance | Expect in the zinc oxide | ± 10 grams |
| 50-150 kilogram platform balance | Aniseed such as carbon black | ± 200 grams |
| 50-150 kilogram platform balance | Rubber, broken-down rubber | ± 200 grams |
5, mixing: as to use mixing roll.
Mixing rule (time in proper order)
| Project | Time | Project | Time |
| Rubber bag roller is plasticated softening | The 4-6 branch | The triangle bag | The 3-4 branch |
| Material in the zinc oxide etc. | 1 minute | Thin-pass | 2 minutes |
| Carbon black+filler+oil | The 6-8 branch | Slice | 2 minutes |
| Promoter | 1 minute | Add up to | The 20-25 branch |
| Sulphur | The 3-4 branch |
6, heat refining: use the open warm-up mill of 400 * 100mm
Process conditions
| Before roll temperature ℃ | 40－45 |
| Back roll temperature ℃ | 50－55 |
| Slice thickness mm | 5－8 |
7, compressing tablet: use four-roll calender
Technological standards
Technological standards
| Last roll temperature ℃ | 80 |
| In roll temperature ℃ | 90 |
| Lower roll thickness ℃ | 50 |
| The glue kind | Thickness | Error |
| Interior glue | 1mm | ±0.2 |
| Outer glue | 1mm | 0-0.1 |
| Outer glue | 3mm | 0-0.2 |
8, applying roll extrusion: use roller press
Film is forbidden to land, and forbids colour band inhomogeneous, remove bubble, exogenous impurity or dead glue pimple; During applying, if cold glue must be earlier with gasoline or rubber cement brushing binding face, waiting can fit after the volatilization send roller press; Can vulcanize after the assay was approved.
9, sulfuration: use 1.2 * 2.5M vulcanizing press
Conditions of vulcanization
| Steam pressure Mpa | End the cure time branch | The operating time branch | Total time branch |
| 0.35 | 45 | 15 | 60 |
10, test package warehouse-in:
Electric spark inspection after the depanning, defective work must in time be repaired to qualified, then the packing warehouse-in.
The use of Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant has solved the problem of the on-the-spot line with rubber of main equipment, has promoted the development of equipment line with rubber technology and line with rubber equipment.
Claims (2)
1, a kind of equipment line with rubber, the corrosion-resistant composite slab rubber of presulfurization particularly, it is characterized in that the composite slab rubber that forms is suppressed in natural gum, the applying of cis-butadiene cement internal layer offset plate after the butyl rubber after vulcanizing or outer offset plate of chlorinated butyl rubber and the sulfuration, have excellent corrosion resisting performance and adhesive property.
2, composite slab rubber according to claim 1 is characterized in that the outer layer glue factory formula is:
The hose lining factory formula is:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92100417 CN1074653A (en) | 1992-01-21 | 1992-01-21 | Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92100417 CN1074653A (en) | 1992-01-21 | 1992-01-21 | Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1074653A true CN1074653A (en) | 1993-07-28 |
Family
ID=4938572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92100417 Pending CN1074653A (en) | 1992-01-21 | 1992-01-21 | Butylrubber composite rubber plate of pre-vulcanization and corrosion resistant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1074653A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051783C (en) * | 1995-07-03 | 2000-04-26 | 张庆虎 | Room temp. self-sulfurizing rubber-isobutylene lining |
| CN101247955B (en) * | 2005-08-25 | 2011-07-20 | 东燃化学株式会社 | Polyethylene multilayer microporous film, battery separator and battery using same |
| CN101104711B (en) * | 2007-08-10 | 2011-07-20 | 王崇高 | Factory formula for aging-resistant rubber strip |
| CN102806622A (en) * | 2012-09-12 | 2012-12-05 | 中橡集团沈阳橡胶研究设计院 | Manufacturing method for matte rubber plate and adhesive tape |
| CN103694509A (en) * | 2013-10-28 | 2014-04-02 | 北京天山新材料技术股份有限公司 | Conveyer belt damage repairing strip with reinforcing layer and preparation method thereof |
| CN112280492A (en) * | 2020-10-22 | 2021-01-29 | 武汉华利浦防腐工程有限公司 | Double-layer composite pre-vulcanized butyl rubber plate |
-
1992
- 1992-01-21 CN CN 92100417 patent/CN1074653A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1051783C (en) * | 1995-07-03 | 2000-04-26 | 张庆虎 | Room temp. self-sulfurizing rubber-isobutylene lining |
| CN101247955B (en) * | 2005-08-25 | 2011-07-20 | 东燃化学株式会社 | Polyethylene multilayer microporous film, battery separator and battery using same |
| CN101104711B (en) * | 2007-08-10 | 2011-07-20 | 王崇高 | Factory formula for aging-resistant rubber strip |
| CN102806622A (en) * | 2012-09-12 | 2012-12-05 | 中橡集团沈阳橡胶研究设计院 | Manufacturing method for matte rubber plate and adhesive tape |
| CN103694509A (en) * | 2013-10-28 | 2014-04-02 | 北京天山新材料技术股份有限公司 | Conveyer belt damage repairing strip with reinforcing layer and preparation method thereof |
| CN103694509B (en) * | 2013-10-28 | 2015-09-23 | 北京天山新材料技术有限公司 | A kind of band enhancement Layer damages of conveyor belt repairs bar and preparation method thereof |
| CN112280492A (en) * | 2020-10-22 | 2021-01-29 | 武汉华利浦防腐工程有限公司 | Double-layer composite pre-vulcanized butyl rubber plate |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |