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CN106866026A - A kind of high tenacity construction material and preparation method thereof - Google Patents

A kind of high tenacity construction material and preparation method thereof Download PDF

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Publication number
CN106866026A
CN106866026A CN201710186650.3A CN201710186650A CN106866026A CN 106866026 A CN106866026 A CN 106866026A CN 201710186650 A CN201710186650 A CN 201710186650A CN 106866026 A CN106866026 A CN 106866026A
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China
Prior art keywords
parts
high tenacity
preparation
construction material
rice husk
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Pending
Application number
CN201710186650.3A
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Chinese (zh)
Inventor
不公告发明人
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Hefei Wisdom Longtuteng Intellectual Property Co Ltd
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Hefei Wisdom Longtuteng Intellectual Property Co Ltd
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Priority to CN201710186650.3A priority Critical patent/CN106866026A/en
Publication of CN106866026A publication Critical patent/CN106866026A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of high tenacity construction material and preparation method thereof, including following parts by weight raw material:12 28 parts of polyacrylonitrile fibre, 22 38 parts of diatomite, 4 11 parts of chitin, 10 23 parts of Barley Greeg, 15 30 parts of alfalfa meal, 15 29 parts of PA 66,7 13 parts of lignin, 7 11 parts of propyl benzene nano core-shell emulsion, 8 15 parts of mica powder, 5 18 parts of polyvinylpyrrolidone, 25 parts of core shell rubbers, 25 parts of propilolic alcohol, 28 parts of black earth, 37 parts of Amprolium Hydrochloride, 70 130 parts of rice husk extract solution.High tenacity construction material of the invention, is compounded by raw material and plays synergy, with preferable toughness, improves the action of crack arrest of material, and intensity is higher, can be prevented effectively from generation cracking and is broken;Preparation method is simple, and range of application is wider.

Description

A kind of high tenacity construction material and preparation method thereof
Technical field
The present invention relates to a kind of construction material, specifically a kind of high tenacity construction material and preparation method thereof.
Background technology
Construction material (Building materials, referred to as:Building materials) refer to the total of various materials for civil engineering Claim, structural material, ornament materials and some proprietary materials can be divided into.Structural material includes timber, bamboo wood, stone material, cement, coagulation Soil, metal, brick and tile, ceramics, glass, engineering plastics, composite etc.;Ornament materials includes various coating, paint, coating, patch Face, assorted ceramic tile, the glass with special-effect etc.;Proprietary material refer to for waterproof, protection against the tide, anti-corrosion, fire prevention, fire-retardant, sound insulation, Heat-insulated, insulation, sealing etc..Traditional concrete has low tensile strength, poor toughness and fracture width is difficult to control to after cracking Shortcoming.In the market occurs in that some composite architectural materials, but because preparation cost is higher, usage amount is larger, causes economy It is poor, therefore can not tackle the problem at its root.
The content of the invention
It is an object of the invention to provide a kind of high tenacity construction material and preparation method thereof, to solve above-mentioned background technology The problem of middle proposition.
To achieve the above object, the present invention provides following technical scheme:
A kind of high tenacity construction material, including following parts by weight raw material:Polyacrylonitrile fibre 12-28 parts, diatomite 22-38 parts, chitin 4-11 parts, Barley Greeg 10-23 parts, alfalfa meal 15-30 parts, PA 66 15-29 parts, it is wooden Plain 7-13 parts, 7-11 parts of propyl- benzene nano core-shell emulsion, mica powder 8-15 parts, polyvinylpyrrolidone 5-18 parts, core shell rubbers 2- 5 parts, propilolic alcohol 2-5 parts, black earth 2-8 parts, Amprolium Hydrochloride 3-7 parts, 70-130 parts of rice husk extract solution.
As further scheme of the invention:Raw material including following parts by weight:21 parts of polyacrylonitrile fibre, diatomite 35 parts, 7 parts of chitin, 18 parts of Barley Greeg, 24 parts of alfalfa meal, 20 parts of PA 66,9 parts of lignin, propyl- benzene nanometer 8 parts of core-shell emulsion, 12 parts of mica powder, 6 parts of polyvinylpyrrolidone, 3 parts of core shell rubbers, 2 parts of propilolic alcohol, 4 parts of black earth, hydrochloric acid peace 4 parts of general sieve ammonium, 98 parts of rice husk extract solution.
As further scheme of the invention:The preparation method of the rice husk extract solution is:By rice husk, 60 parts are put into 100 parts In distilled water, 8-10g sodium potassium tartrate tetrahydrates are added, 20-35min are boiled with high heat, then simmer in water 1-1.5h, filters to get filtrate, Obtain final product rice husk extract solution.
A kind of preparation method of high tenacity construction material, concretely comprises the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is standby;
(2) crushed by pulverizer after alfalfa meal is dried, obtain powder;
(3) upper step gained mixed-powder is put into homogenizer with diatomite, mica powder, black earth, rice husk extract solution, is mixed Close 80-95 degrees Celsius of temperature, mixing speed 150-180r/min, stirring mixing 8-15min;
(4) by polyacrylonitrile fibre, chitin, Barley Greeg, polyvinylpyrrolidone, core shell rubbers, lignin in 115- 18-25min is mixed under 130 degree celsius temperatures;
(5) step (3) gains, propyl- benzene nano core-shell emulsion, Amprolium Hydrochloride are sequentially added into step (4) gained In thing, 135-150 degrees Celsius, stirring mixing 30-38min are warming up to;
(6) will be walked in PA 66, propilolic alcohol addition in gains, be cooled to 122-130 degrees Celsius, stirring is mixed 40-55min is closed, is suppressed after cooling, got product.
As further scheme of the invention:The step (3) by upper step gained mixed-powder and diatomite, mica powder, Black earth, rice husk extract solution are put into homogenizer, 88 degrees Celsius of mixing temperature, mixing speed 168r/min, stirring mixing 11min。
As further scheme of the invention:The step (4) is by polyacrylonitrile fibre, chitin, Barley Greeg, polyethylene Pyrrolidones, core shell rubbers, lignin mix 20min under 122 degree celsius temperatures.
As further scheme of the invention:The step (5) by step (3) gains, propyl- benzene nano core-shell emulsion, Amprolium Hydrochloride is sequentially added in step (4) gains, is warming up to 148 degrees Celsius, stirring mixing 32min.
As further scheme of the invention:PA 66, propilolic alcohol are added and walk gained by the step (6) In thing, 125 degrees Celsius are cooled to, stirring mixing 48min is suppressed after cooling, is got product.
Compared with prior art, the beneficial effects of the invention are as follows:
High tenacity construction material of the invention, is compounded by raw material and plays synergy, with preferable toughness, is improve The action of crack arrest of material, and intensity is higher, can be prevented effectively from generation cracking and be broken;Preparation method is simple, and range of application is wider.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of high tenacity construction material, including following parts by weight raw material:12 parts of polyacrylonitrile fibre, diatomite 22 Part, 4 parts of chitin, 10 parts of Barley Greeg, 15 parts of alfalfa meal, 15 parts of PA 66,7 parts of lignin, propyl- benzene nanometer core 7 parts of shell emulsion, 8 parts of mica powder, 5 parts of polyvinylpyrrolidone, 2 parts of core shell rubbers, 2 parts of propilolic alcohol, black earth 2-8 parts, hydrochloric acid peace 3-7 parts of general sieve ammonium, 70-130 parts of rice husk extract solution.The preparation method of the rice husk extract solution is:By rice husk, 60 parts are put into 100 parts In distilled water, 8-10g sodium potassium tartrate tetrahydrates are added, 20-35min are boiled with high heat, then simmer in water 1-1.5h, filters to get filtrate, Obtain final product rice husk extract solution.
A kind of preparation method of high tenacity construction material, concretely comprises the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is standby;
(2) crushed by pulverizer after alfalfa meal is dried, obtain powder;
(3) upper step gained mixed-powder is put into homogenizer with diatomite, mica powder, black earth, rice husk extract solution, is mixed Close 80-95 degrees Celsius of temperature, mixing speed 150-180r/min, stirring mixing 8-15min;
(4) by polyacrylonitrile fibre, chitin, Barley Greeg, polyvinylpyrrolidone, core shell rubbers, lignin in 115- 18-25min is mixed under 130 degree celsius temperatures;
(5) step (3) gains, propyl- benzene nano core-shell emulsion, Amprolium Hydrochloride are sequentially added into step (4) gained In thing, 135-150 degrees Celsius, stirring mixing 30-38min are warming up to;
(6) will be walked in PA 66, propilolic alcohol addition in gains, be cooled to 122-130 degrees Celsius, stirring is mixed 40-55min is closed, is suppressed after cooling, got product.
Embodiment 2
A kind of high tenacity construction material, including following parts by weight raw material:Polyacrylonitrile fibre 12-28 parts, diatomite 22-38 parts, chitin 4-11 parts, Barley Greeg 10-23 parts, alfalfa meal 15-30 parts, PA 66 15-29 parts, it is wooden Plain 7-13 parts, 7-11 parts of propyl- benzene nano core-shell emulsion, mica powder 8-15 parts, polyvinylpyrrolidone 5-18 parts, core shell rubbers 2- 5 parts, propilolic alcohol 2-5 parts, black earth 2-8 parts, Amprolium Hydrochloride 3-7 parts, 70-130 parts of rice husk extract solution.The rice husk extract solution Preparation method be:By rice husk, 60 parts are put into 100 parts of distilled water, add 8-10g sodium potassium tartrate tetrahydrates, and 20- is boiled with high heat 35min, then simmer in water 1-1.5h, filters to get filtrate, and obtains final product rice husk extract solution.
A kind of preparation method of high tenacity construction material, concretely comprises the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is standby;
(2) crushed by pulverizer after alfalfa meal is dried, obtain powder;
(3) upper step gained mixed-powder is put into homogenizer with diatomite, mica powder, black earth, rice husk extract solution, is mixed Close 80-95 degrees Celsius of temperature, mixing speed 150-180r/min, stirring mixing 8-15min;
(4) by polyacrylonitrile fibre, chitin, Barley Greeg, polyvinylpyrrolidone, core shell rubbers, lignin in 115- 18-25min is mixed under 130 degree celsius temperatures;
(5) step (3) gains, propyl- benzene nano core-shell emulsion, Amprolium Hydrochloride are sequentially added into step (4) gained In thing, 135-150 degrees Celsius, stirring mixing 30-38min are warming up to;
(6) will be walked in PA 66, propilolic alcohol addition in gains, be cooled to 122-130 degrees Celsius, stirring is mixed 40-55min is closed, is suppressed after cooling, got product.
Embodiment 3
A kind of high tenacity construction material, including following parts by weight raw material:21 parts of polyacrylonitrile fibre, diatomite 35 Part, 7 parts of chitin, 18 parts of Barley Greeg, 24 parts of alfalfa meal, 20 parts of PA 66,9 parts of lignin, propyl- benzene nanometer core 8 parts of shell emulsion, 12 parts of mica powder, 6 parts of polyvinylpyrrolidone, 3 parts of core shell rubbers, 2 parts of propilolic alcohol, 4 parts of black earth, hydrochloric acid peace are general 4 parts of sieve ammonium, 98 parts of rice husk extract solution.The preparation method of the rice husk extract solution is:By rice husk, 60 parts are put into 100 parts of distilled water In, 8-10g sodium potassium tartrate tetrahydrates are added, 20-35min is boiled with high heat, then simmer in water 1-1.5h, filters to get filtrate, and obtains final product rice Shell extract solution.
A kind of preparation method of high tenacity construction material, concretely comprises the following steps:
(1) each raw material is weighed according to above-mentioned formula, it is standby;
(2) crushed by pulverizer after alfalfa meal is dried, obtain powder;
(3) upper step gained mixed-powder is put into homogenizer with diatomite, mica powder, black earth, rice husk extract solution, is mixed Close 88 degrees Celsius of temperature, mixing speed 168r/min, stirring mixing 11min;
(4) polyacrylonitrile fibre, chitin, Barley Greeg, polyvinylpyrrolidone, core shell rubbers, lignin are taken the photograph 122 20min is mixed at a temperature of family name's degree;
(5) step (3) gains, propyl- benzene nano core-shell emulsion, Amprolium Hydrochloride are sequentially added into step (4) gained In thing, 148 degrees Celsius, stirring mixing 32min are warming up to;
(6) will be walked in PA 66, propilolic alcohol addition in gains, be cooled to 125 degrees Celsius, stirring mixing 48min, suppresses after cooling, gets product.
High tenacity construction material of the invention, is compounded by raw material and plays synergy, with preferable toughness, is improve The action of crack arrest of material, and intensity is higher, can be prevented effectively from generation cracking and be broken;Preparation method is simple, and range of application is wider.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from Make a variety of changes.

Claims (8)

1. a kind of high tenacity construction material, it is characterised in that the raw material including following parts by weight:Polyacrylonitrile fibre 12-28 Part, diatomite 22-38 parts, chitin 4-11 parts, Barley Greeg 10-23 parts, alfalfa meal 15-30 parts, PA 66 15- 29 parts, lignin 7-13 parts, 7-11 parts of propyl- benzene nano core-shell emulsion, mica powder 8-15 parts, polyvinylpyrrolidone 5-18 parts, Core shell rubbers 2-5 parts, propilolic alcohol 2-5 parts, black earth 2-8 parts, Amprolium Hydrochloride 3-7 parts, 70-130 parts of rice husk extract solution.
2. high tenacity construction material according to claim 1, it is characterised in that the raw material including following parts by weight:It is poly- 21 parts of Dralon, 35 parts of diatomite, 7 parts of chitin, 18 parts of Barley Greeg, 24 parts of alfalfa meal, PA 66 20 Part, 9 parts of lignin, 8 parts of propyl- benzene nano core-shell emulsion, 12 parts of mica powder, 6 parts of polyvinylpyrrolidone, 3 parts of core shell rubbers, third 2 parts of alkynol, 4 parts of black earth, 4 parts of Amprolium Hydrochloride, 98 parts of rice husk extract solution.
3. according to any described high tenacity construction materials of claim 1-2, it is characterised in that the preparation of the rice husk extract solution Method is:By rice husk, 60 parts are put into 100 parts of distilled water, add 8-10g sodium potassium tartrate tetrahydrates, 20-35min are boiled with high heat, then Simmer in water 1-1.5h, filters to get filtrate, and obtains final product rice husk extract solution.
4. a kind of preparation method of high tenacity construction material as described in claim 1-2 is any, it is characterised in that specific steps For:
(1) each raw material is weighed according to above-mentioned formula, it is standby;
(2) crushed by pulverizer after alfalfa meal is dried, obtain powder;
(3) upper step gained mixed-powder and diatomite, mica powder, black earth, rice husk extract solution are put into homogenizer, mixing temperature 80-95 degrees Celsius of degree, mixing speed 150-180r/min, stirring mixing 8-15min;
(4) polyacrylonitrile fibre, chitin, Barley Greeg, polyvinylpyrrolidone, core shell rubbers, lignin are taken the photograph in 115-130 18-25min is mixed at a temperature of family name's degree;
(5) in step (3) gains, propyl- benzene nano core-shell emulsion, Amprolium Hydrochloride being sequentially added into step (4) gains, It is warming up to 135-150 degrees Celsius, stirring mixing 30-38min;
(6) will be walked in PA 66, propilolic alcohol addition in gains, be cooled to 122-130 degrees Celsius, stirring mixing 40-55min, suppresses after cooling, gets product.
5. the preparation method of high tenacity construction material according to claim 4, it is characterised in that the step (3) will be upper Step gained mixed-powder and diatomite, mica powder, black earth, rice husk extract solution are put into homogenizer, 88 degrees Celsius of mixing temperature, Mixing speed 168r/min, stirring mixing 11min.
6. the preparation method of high tenacity construction material according to claim 4, it is characterised in that the step (4) will be poly- Dralon, chitin, Barley Greeg, polyvinylpyrrolidone, core shell rubbers, lignin mix under 122 degree celsius temperatures Stirring 20min.
7. the preparation method of high tenacity construction material according to claim 4, it is characterised in that the step (5) will walk Suddenly during (3) gains, propyl- benzene nano core-shell emulsion, Amprolium Hydrochloride sequentially add step (4) gains, 148 are warming up to and are taken the photograph Family name's degree, stirring mixing 32min.
8. the preparation method of high tenacity construction material according to claim 4, it is characterised in that the step (6) will be poly- Hexamethylene diamine adipate, propilolic alcohol are added in step gains, are cooled to 125 degrees Celsius, and stirring mixing 48min is suppressed after cooling, Get product.
CN201710186650.3A 2017-03-27 2017-03-27 A kind of high tenacity construction material and preparation method thereof Pending CN106866026A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108439913A (en) * 2018-05-16 2018-08-24 合肥欧克斯新型建材有限公司 A kind of lower shrinkage high tenacity construction material and preparation method thereof
CN108623217A (en) * 2018-05-24 2018-10-09 合肥永泰新型建材有限公司 A kind of cracking resistance heat insulation floor and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1568293A (en) * 2000-10-04 2005-01-19 詹姆斯·哈迪研究有限公司 Fiber cement composites using cellulose fibers loaded with inorganic and/or organic substances
CN101456698A (en) * 2008-10-24 2009-06-17 北京崇高纳米科技有限公司 Rapid forming high intensity and high functional diatomite composition and method for making the same
CN103496916A (en) * 2013-09-18 2014-01-08 长白朝鲜族自治县广森元硅藻土科技有限公司 Diatom ooze wall material with high content of diatomite and preparation method thereof
CN104556894A (en) * 2014-12-11 2015-04-29 昆山市悦硕建筑材料有限公司 High-toughness building material
CN105565743A (en) * 2016-01-11 2016-05-11 郑州工业应用技术学院 High toughness construction material
CN106277967A (en) * 2016-08-08 2017-01-04 凡音环保科技(苏州)有限公司 A kind of environment protecting thermal insulating construction material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1568293A (en) * 2000-10-04 2005-01-19 詹姆斯·哈迪研究有限公司 Fiber cement composites using cellulose fibers loaded with inorganic and/or organic substances
CN101456698A (en) * 2008-10-24 2009-06-17 北京崇高纳米科技有限公司 Rapid forming high intensity and high functional diatomite composition and method for making the same
CN103496916A (en) * 2013-09-18 2014-01-08 长白朝鲜族自治县广森元硅藻土科技有限公司 Diatom ooze wall material with high content of diatomite and preparation method thereof
CN104556894A (en) * 2014-12-11 2015-04-29 昆山市悦硕建筑材料有限公司 High-toughness building material
CN105565743A (en) * 2016-01-11 2016-05-11 郑州工业应用技术学院 High toughness construction material
CN106277967A (en) * 2016-08-08 2017-01-04 凡音环保科技(苏州)有限公司 A kind of environment protecting thermal insulating construction material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108439913A (en) * 2018-05-16 2018-08-24 合肥欧克斯新型建材有限公司 A kind of lower shrinkage high tenacity construction material and preparation method thereof
CN108623217A (en) * 2018-05-24 2018-10-09 合肥永泰新型建材有限公司 A kind of cracking resistance heat insulation floor and preparation method thereof

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Application publication date: 20170620