CN1067653C - Process for preparing high purity nitrogen by deep purification fo coarse nitrogen and technological flow - Google Patents
Process for preparing high purity nitrogen by deep purification fo coarse nitrogen and technological flow Download PDFInfo
- Publication number
- CN1067653C CN1067653C CN96119471A CN96119471A CN1067653C CN 1067653 C CN1067653 C CN 1067653C CN 96119471 A CN96119471 A CN 96119471A CN 96119471 A CN96119471 A CN 96119471A CN 1067653 C CN1067653 C CN 1067653C
- Authority
- CN
- China
- Prior art keywords
- nitrogen
- hydrogen
- high purity
- thick
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 164
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 82
- 238000000746 purification Methods 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title description 7
- 239000001257 hydrogen Substances 0.000 claims abstract description 35
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 35
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000003054 catalyst Substances 0.000 claims abstract description 29
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 26
- 239000001301 oxygen Substances 0.000 claims abstract description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 25
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 22
- 230000008569 process Effects 0.000 claims abstract description 15
- 239000010970 precious metal Substances 0.000 claims description 18
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 16
- 230000001105 regulatory effect Effects 0.000 claims description 12
- 238000005984 hydrogenation reaction Methods 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 9
- 230000008929 regeneration Effects 0.000 claims description 7
- 238000011069 regeneration method Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000010926 purge Methods 0.000 claims description 2
- -1 nitrogen hydrogen Chemical class 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 abstract description 6
- 229910000510 noble metal Inorganic materials 0.000 abstract 2
- 239000011261 inert gas Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 4
- 239000002808 molecular sieve Substances 0.000 description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 206010058490 Hyperoxia Diseases 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229960004643 cupric oxide Drugs 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 230000000222 hyperoxic effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- DOTMOQHOJINYBL-UHFFFAOYSA-N molecular nitrogen;molecular oxygen Chemical compound N#N.O=O DOTMOQHOJINYBL-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000012492 regenerant Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
Abstract
粗氮气深度净化制取高纯氮气的方法和工艺流程是根据氮中氧含量，加入超过计量比约200～500ppm的氢气，通过第一级净化器，在含贵金属Pd和/或Pt脱氧催化剂的作用下，将粗氮中的氧气净化到1ppm以下，净化后氮气中的残余氢，再经过第二级净化器，在含贵金属Pd/氧化锰调变催化剂的作用下，脱除到1ppm以下，得到O2、H2含量均低于1ppm的高纯氮。该工艺方法特别适合于变压吸附氮等具有高氧含量(～0.5%)的粗氮或惰性气体的净化。
The method and process flow of deep purification of crude nitrogen to produce high-purity nitrogen is based on the oxygen content in nitrogen, adding hydrogen with a metering ratio of about 200-500ppm, passing through the first-stage purifier, and containing noble metal Pd and/or Pt deoxidation catalyst. Under the action, the oxygen in the crude nitrogen is purified to below 1ppm, and the residual hydrogen in the purified nitrogen is removed to below 1ppm under the action of the noble metal Pd/manganese oxide modulation catalyst through the second-stage purifier. High-purity nitrogen with O 2 and H 2 contents lower than 1 ppm can be obtained. This process is especially suitable for the purification of crude nitrogen or inert gas with high oxygen content (~0.5%), such as pressure swing adsorption nitrogen.
Description
The present invention relates to a kind of method and technical process of producing high purity nitrogen from the thick nitrogen deep purifying that contains hyperoxia amount (～0.5%).Specifically, the thick nitrogen of the first step is excessive hydrogenation earlier, under the effect that contains precious metals pd and/or Pt dehydrogenation catalyst, removes oxygen in the nitrogen, and the nitrogen that contains excessive hydrogen then contains precious metals pd/manganese oxide regulating catalyst through second section, and excessive hydrogen is removed, and obtains O
2, H
2The high purity nitrogen of＜1ppm.
The high pure nitrogen body is widely used in the production process of petrochemical complex, chemical industry, electronic industry, metallurgical industry and building materials industry as the shielding gas in producing.The preparation of high purity nitrogen in the past adopts the empty method of dividing of deep cooling to produce usually, but huge for the investment of deep cooling air separation plant, and the energy consumption height only is suitable for the production (＞10000M of large-scale high purity nitrogen
3/ hr), the purity nitrogen production of centering, hour scale is non-remunerative economically.
The carbonaceous molecular sieve making nitrogen by pressure swing adsorption is the seventies new developing technology, compares with molten cold nitrogen production by air separation method, and this technology is simple with its equipment, less investment, simple to operate, low power consumption and other advantages, the nitrogen production of centering, hour scale is more reasonable economically, is popular in users.Unique shortcoming of making nitrogen by pressure swing adsorption is that nitrogen gas purity is not too high, generally at 99.5% (0.5%O
2), in most cases, need further to purify, can be used for production process.At present, thick nitrogen deoxidation is mainly catforming, promptly adds excessive 0.2～5.0% hydrogen in smart nitrogen, under the effect of catalyzer such as palladium/aluminum oxide, residual oxygen in the nitrogen is removed.With the purifying method of above-mentioned catalyst removal oxygen, the oxygen level of its finished product gas is 0.2～10ppm, and the hydrogen residual volume surpasses 0.2% in the nitrogen, is high purity nitrogen so be far from being, and can only be used for the industry that thermal treatment etc. needs hydrogen.
Thick nitrogen purifies the general oxide compound absorption process of appraising at the current rate that adopts of the another kind of method that removes oxygen, and carbon burning consumes method.Absorption process reductor commonly used has manganese oxide (MnOx), silver suboxide (Ag
2O), cupric oxide (CuOx) (referring to Wu Yanmin " purification for gas " 23,1983, National Defense Industry Press).5～15 milliliters of the former general every gram reductor deoxidations, because thick nitrogen oxygen level height, so need a large amount of reductors, treating plant is huge, and is more uneconomical economically.Though latter's deoxidation is great, belongs to expendable, and 320～900 ℃ of uses, and produce new impurity CO and CO
2Up to now, the purification that contains the thick nitrogen of hyperoxia amount is the difficult problem in the gas sweetening, and Shang Weiyou rational technology is economically solved.
The purpose of this invention is to provide a kind of economy, be suitable for extensive use, is method for gas purification and the technical process that unstripped gas is produced high purity nitrogen with thick nitrogen.
Adopt in the present invention the applicant's early development contain precious metals pd and/or Pt dehydrogenation catalyst (number of patent application 96115578.7) but and not only can inhale hydrogen but also oxygen uptake contain precious metals pd/manganese oxide regulating catalyst and technical process (seeing accompanying drawing 1), dividing two sections is high purity nitrogen with thick nitrogen deep purifying.In first section cleaner, the thick excessive hydrogenation of nitrogen, under the effect that contains precious metals pd and/or Pt dehydrogenation catalyst, the hydrogen-oxygen catalyzed reaction generates water and removes deoxidation.Remaining hydrogen in the nitrogen after first section purification by second section cleaner adsorbing and removing that contains Pd/ manganese oxide regulating catalyst, obtains H
2, O
2The high pure nitrogen of＜1ppm.Second section cleaner contains precious metals pd/manganese oxide purification reactor by two and forms, switch to use, i.e. and reactor hydrogen in inhaling hydrogen purification nitrogen, another reactor is then logical to contain the thick nitrogen oxidation regeneration of oxygen, hockets operate continuously.If high purity nitrogen requires the control moisture content, then need add conventional 5A molecular sieve purification process in the technical process and be dewatered.The condition of its scavenging process is: first section cleaner temperature of reaction is normal temperature～200 ℃, air speed 4000～8000hr
-1, oxygen level 0.05～3.0% in the nitrogen, and than excessive 200～500ppm, method of hydrotreating adopts pure hydrogen source or ammonia cracking hydrogen source to the hydrogenation amount by the metering of oxygen level in the thick nitrogen in the thick nitrogen.The dehydrogenation working temperature of second section cleaner is 100～150 ℃, contains the regeneration of precious metals pd/manganese oxide regulating catalyst and carries out 100～250 ℃ of regeneration temperatures containing under the oxygen-nitrogen atmosphere.Purge gas pressure is 0.1～3MPa.
Accompanying drawing 1 is the technical process of the thick nitrogen system High Purity Hydrogen of the present invention.
Among the figure:
The 1:506HO regulating catalyst is regenerated with thick nitrogen variable valve; 2: smart nitrogen variable valve; 3: join the hydrogen variable valve; 4～12:506HO modulation catalyst converter switching valve; 13: high purity nitrogen displacement valve; 14: the regenerant flow meter; 15. smart nitrogen under meter; 16: join the hydrogen under meter; 17: the first sections cleaners; 18 and 19 are respectively two reactors of second section cleaner; 20:5A molecular sieve dehydration system.
Below by embodiment invention is described further:
Example 1: the preparation (0.25%Pt+0.25%Pd/TiO that contains precious metals pd and/or Pt dehydrogenation catalyst
2+ Al
2O
3)
Get 100 milliliters of (0.025 gram Pd/ milliliter) aqueous solution+(the 0.025 gram Pt/ milliliter) aqueous solution 100 milliliters+60 ml waters and mix, again with 1000 gram column (TiO
2+ Al
2O
3) carrier pours in the above-mentioned solution, floods 4 hours, 80～120 ℃ of oven dry were got 100 milliliters of reduction of hydrazine hydrate of 50% 12 hours, and deionized water wash is to there not being Cl
-, pH=7 places 80～120 ℃ of baking ovens dry, places in the tube furnace under 500～750 ℃ of nitrogen atmosphere thermal treatment again 1～4 hour, is cooled to the logical nitrogen row hydrogen taking-up of chamber, chamber naturally.
Example 2: the performance of dehydrogenation catalyst
Because oxygen level is widely different in the various thick nitrogen, on φ 25mm continuous flow reaction unit, restrains and contain precious metals pd and/or the Pt dehydrogenation catalyst carries out the quantitative hydrogenation deoxidation evaluation of various oxygen concns with 80.Be equipped with metering in the nitrogen than electrolysis hydrogen, oxygen, air speed 5000br
-1, temperature of reaction is a normal temperature, follows the tracks of with the Nanjing GH-3 of analytical instrument factory type oxygen analyzer and detects, the results are shown in Table 1 for it.
Table 1 contains precious metals pd and/or the quantitative hydrogenation deoxidation performance of the smart nitrogen of Pt dehydrogenation catalyst
| Oxygen level (ppm) | Hydrogenation amount (ppm) | Use temperature (℃) | Residual hydrogen amount (ppm) |
| 2000 | 4000 | 25 | ＜0.3 |
| 5000 | 10000 | 25 | ＜0.3 |
| 30000 | 60000 | 25 | ＜0.3 |
As can be seen from Table 1, during different oxygen, hydrogen, oxygen level are for measuring than under the condition, and this catalyzer also has the very high effect that removes oxygen.
Example 3: nitrogen advanced purification process method
Accompanying drawing 1 is the process flow sheet that thick nitrogen is produced high purity nitrogen, with the refining plant of this process design is that the first section cleaner that contains 18 kilograms of precious metals pd and/or Pt dehydrogenation catalysts is housed, with the second section cleaner that contains 37.5 kilograms of precious metals pd/manganese oxide regulating catalysts (Dalian Inst of Chemicophysics, Chinese Academy of Sciences produces 506HO type commercial catalyst), thick nitrogen (making nitrogen by pressure swing adsorption) flow is 60M
3/ hr.Carry out the commerical test of smart nitrogen hydrogenation deoxidation with this device, the results are shown in Table 2 for it.The working temperature of first section cleaner is a normal temperature, and pressure 0.5MPa uses air speed 4000hr
-1, detecting instrument is the Nanjing DH-3 of an analytical instrument factory type oxygen analyzer.
Table 2 contains precious metals pd and/or Pt dehydrogenation catalyst industry use properties
| Nitrogen source | Oxygen level (ppm) | Hydrogenation amount (ppm) | Residual hydrogen amount (ppm) |
| Making nitrogen by pressure swing adsorption | 0.5 | 10.2～1.05 | ＜1 |
As can be seen from Table 2, contain precious metals pd and/or Pt dehydrogenation catalyst under the big air speed working conditions of industry, effect is still fine.
On said apparatus, nitrogen after the deoxidation carries out hydrogen with the 506HO regulating catalyst and absorbs, the working temperature of second section cleaner is 100～150 ℃, pressure 0.6MPa, hydrogen before and after absorbing is followed the tracks of detection with the OHW-01 type and the CD-HY type hydrogen detector of Dalian Inst of Chemicophysics, Chinese Academy of Sciences's system, and the results are shown in Table 3 for it.
Table 3 506HO regulating catalyst dehydrogenation
| Hydrogen richness (ppm) | Use temperature (℃) | Applying pressure (MPa) | Residual hydrogen amount (ppm) |
| 200～500 | 100～150 | 0.6 | ＜1 |
As can be seen from Table 3, after the 506HO regulating catalyst was inhaled hydrogen, hydrogen was residual heavy less than 1ppm, and transformation is adsorbed thick nitrogen after above second cleaner purifies, and hydrogen, oxygen all become high purity nitrogen less than 1ppm.
The continuous flow reaction unit is adopted in above-mentioned technical process, catalyzer successive reaction and regeneration, its process stream trend is: the transformation adsorption of nitrogen through valve, under meter to mixing tank; Hydrogen or ammonia cracking hydrogen mix with nitrogen to mixing tank through valve, under meter, and mixed gas enters first section cleaner 17, under the effect that contains precious metals pd and/or Pt dehydrogenation catalyst, and the normal temperature deoxidation.Nitrogen after the deoxidation enters second section cleaner, one of them 506HO reactor 18, and under the effect of 506HO regulating catalyst, the absorbing and removing excessive hydrogen.Nitrogen after the dehydrogenation enters next stage and carries out conventional 5A molecular sieve dehydration, thereby obtains high purity nitrogen.In one second section reactor 18 dehydrogenations, to another second section 506HO reactor 19,, after having regenerated, replace with high purity nitrogen with the oxygenous oxidation regeneration that carries out of transformation absorption, use in order to switching.
It is 60M that the thick nitrogen of above-mentioned reaction unit carries out tolerance
3/ hr
-1, pressure 0.6MPa, first section cleaner working temperature is normal temperature～200 ℃, the 506HO regulating catalyst inhales hydrogen and regeneration temperature is 100～250 ℃, O in the high purity nitrogen
2, H
2＜1ppm.
Claims (1)
1. one kind is used for the method that thick nitrogen deep purifying is produced high purity nitrogen, it is characterized in that: the thick excessive hydrogenation 200～500ppm of nitrogen, by containing precious metals pd and/or Pt dehydrogenation catalyst, oxyhydrogen reaction removes in the denitrification oxygen to 1ppm, reaction conditions is normal temperature～200 ℃, air speed 4000～8000h
-1, oxygen level 0.05～3.0% in the nitrogen; Nitrogen contains precious metals pd/manganese oxide regulating catalyst except that residual hydrogen in the denitrification through the second stage then, its process is to contain precious metals pd/manganese oxide purification reactor by two to finish, one is used for removing nitrogen hydrogen, another then logical thick nitrogen oxidation regeneration, alternately switch and carry out, operate continuously, reaction conditions is 100～150 ℃, purge gas pressure 0.1～3.0MPa obtains O
2, H
2The high purity nitrogen of＜1ppm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119471A CN1067653C (en) | 1996-10-09 | 1996-10-09 | Process for preparing high purity nitrogen by deep purification fo coarse nitrogen and technological flow |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96119471A CN1067653C (en) | 1996-10-09 | 1996-10-09 | Process for preparing high purity nitrogen by deep purification fo coarse nitrogen and technological flow |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1178768A CN1178768A (en) | 1998-04-15 |
| CN1067653C true CN1067653C (en) | 2001-06-27 |
Family
ID=5125724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96119471A Expired - Fee Related CN1067653C (en) | 1996-10-09 | 1996-10-09 | Process for preparing high purity nitrogen by deep purification fo coarse nitrogen and technological flow |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1067653C (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515119A (en) * | 2011-12-05 | 2012-06-27 | 西安康本材料有限公司 | Method for regulating hydrogen content in high-pure nitrogen production process |
| CN104030257A (en) * | 2014-06-12 | 2014-09-10 | 鞍钢股份有限公司 | Control method of nitrogen purification system |
| CN104528665A (en) * | 2014-12-22 | 2015-04-22 | 本钢板材股份有限公司 | Method of purifying nitrogen |
| CN110980662A (en) * | 2019-12-28 | 2020-04-10 | 南京宝雅气体有限公司 | Catalytic deoxidation process for producing high-purity nitrogen |
| CN112279222B (en) * | 2020-11-12 | 2022-04-26 | 杭州汉德空分设备有限公司 | Pressure swing adsorption nitrogen making equipment |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85102710A (en) * | 1985-04-01 | 1986-09-17 | 中国科学院大连化学物理研究所 | Platinum, Pd/TiO 2 deoxygenationcatalyst |
| CN1048684A (en) * | 1989-05-12 | 1991-01-23 | 联合碳化工业气体技术公司 | A kind of method of improved production dry high purity nitrogen and system thereof |
| CN1061161A (en) * | 1990-10-25 | 1992-05-20 | 联合碳化工业气体技术公司 | Duplex adsorption process |
-
1996
- 1996-10-09 CN CN96119471A patent/CN1067653C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85102710A (en) * | 1985-04-01 | 1986-09-17 | 中国科学院大连化学物理研究所 | Platinum, Pd/TiO 2 deoxygenationcatalyst |
| CN1048684A (en) * | 1989-05-12 | 1991-01-23 | 联合碳化工业气体技术公司 | A kind of method of improved production dry high purity nitrogen and system thereof |
| CN1061161A (en) * | 1990-10-25 | 1992-05-20 | 联合碳化工业气体技术公司 | Duplex adsorption process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1178768A (en) | 1998-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI460003B (en) | Gas purifying method and gas purifying device | |
| CN100453447C (en) | A process for purifying hydrogen from a hydrogen-rich source | |
| CN1600686A (en) | High recovery carbon monoxide production process | |
| JP2003500323A (en) | Nitrous oxide purification method | |
| CN113830734B (en) | System and method for purifying hydrogen for fuel cell | |
| WO1994025142A1 (en) | Process for reducing the content of metal carbonyls in gas streams | |
| CN114950424A (en) | Circulating gas two-stage type desulfurization catalyst, preparation method and application thereof | |
| CN1067653C (en) | Process for preparing high purity nitrogen by deep purification fo coarse nitrogen and technological flow | |
| KR20080031780A (en) | Inert gas treatment method and purification method and gas treatment tank | |
| CN1054765A (en) | Continuous process for synthesizing oxalate by gas phase catalysis | |
| CN102389697A (en) | Method for removing arsenic hydride in tail gas of iron making blast furnace by wet process | |
| US5662873A (en) | Process for the elimination of impurities contained in a gaseous compound | |
| CN1030895C (en) | Palladium/manganese oxide deoxidizer | |
| CN1074448C (en) | Pressure swing adsorption process for concentration and purification of carbon monooxide in blast furnace gas | |
| CN112408579B (en) | Membrane module for ozone catalytic oxidation wastewater treatment and preparation method thereof | |
| CN1175478A (en) | High-strength, high heat-resistance and poisoning-resistance deoxidation catalyst | |
| CN112844006A (en) | Yellow phosphorus tail gas purification method | |
| CN101773777B (en) | Method for removing phosphine by wet catalytic oxidation | |
| CN118767867A (en) | Adsorbent and preparation method thereof, and method for removing oxygen-containing impurities from propylene oxide | |
| CN1203187A (en) | Process for preparing high-purity hydrogen by converting methanol aqueous vapour | |
| CN1013658B (en) | Method for purifying nitrogen for refining aluminium melt | |
| CN1048195C (en) | Methanation catalyst for purifying gas as raw material for synthesis of ammonia | |
| CN210786828U (en) | Impurity removal system for argon-oxygen-containing tail gas | |
| RU1816734C (en) | Process for cleaning inert gas of hydrogen impurity | |
| RU2855817C1 (en) | Process for purifying hydrogen from oxygen microimpurities using aluminium-nickel catalyst |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |