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CN106479600A - A kind of lube oil additive and the lubricating oil containing this additive - Google Patents

A kind of lube oil additive and the lubricating oil containing this additive Download PDF

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Publication number
CN106479600A
CN106479600A CN201610891033.9A CN201610891033A CN106479600A CN 106479600 A CN106479600 A CN 106479600A CN 201610891033 A CN201610891033 A CN 201610891033A CN 106479600 A CN106479600 A CN 106479600A
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China
Prior art keywords
parts
calcite
powder
additive
lube oil
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Pending
Application number
CN201610891033.9A
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Chinese (zh)
Inventor
陈秋霞
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Individual
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Individual
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Priority to CN201610891033.9A priority Critical patent/CN106479600A/en
Publication of CN106479600A publication Critical patent/CN106479600A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/10Metal oxides, hydroxides, carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10Compounds containing silicon
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of lube oil additive and the lubricating oil containing this additive, lube oil additive is grouped into by the group of following weight portion:Nano magnesia, 30 50 parts;Nano silicon, 20 40 parts;Modified calcite in powder, 15 25 parts;The particle diameter of each component is 20 80 nanometers;Described modification calcite in powder preparation method be:Calcite is pulverized and calcines 3 5h in calcining furnace under 500 600 DEG C of temperature conditionss, then take out, cool down, soaking through formic acid, filtering, clear water adds the mercaptoethanol of calcite in powder weight 2 4%, 3 5% polyvinyl alcohol after washing, after being ground to required particle diameter, 40 60 DEG C of oven drying at low temperatures obtain final product.A kind of lubricating oil for antiwear and antifriction, lube oil additive addition in lubricating oil accounts for the 10 20% of lubrication weight of oil.The lube oil additive that the present invention provides can significantly improve the antiwear and antifriction ability of lubricating oil.

Description

A kind of lube oil additive and the lubricating oil containing this additive
Technical field
The present invention relates to lubricating oil is and in particular to a kind of lube oil additive and the lubricating oil containing this additive.
Background technology
Lubricating oil is used in all kinds automobile, in plant equipment to reduce friction, the liquid of protection machinery and workpiece Or semisolid lubricants, act primarily as lubrication, supplement heat rejecter, antirust, cleaning, sealing and buffering etc. effect.
Lubricating oil-as be made up of base oil and additive two parts.Base oil is the main component of lubricating oil, decides profit The fundamental property of lubricating oil, additive then can make up and improve the deficiency of base oil aspect of performance, gives some new performances, is profit The important component part of lubricating oil.Lube base oil mainly divides mineral base oil, synthetic base oil and biological basis oil three big Class.
Additive is the marrow of modern age senior lubricant, and correct selection rationally adds, and can improve its physicochemical properties, right Lubricating oil gives new property, or strengthens certain performance that its original has, and meets higher requirement.Will according to lubricating oil The quality asked and performance, the meticulous selection to additive, carefully balance, carry out rational allocation, be to ensure that the pass of quality of lubrication oil Key.- as conventional additive have:Viscosity index improver, pour-point depressant, antioxidant, detergent-dispersant additive, friction relaxes Agent, oiliness improver, EP agent, foam reducing composition, matal deactivator, emulsifying agent, anticorrosive, antirust agent, oxidation and corrosion inhibitor etc..
Content of the invention
It is an object of the invention to provide a kind of lube oil additive and the lubricating oil containing this additive, it is added with this The lubricating oil of additive has excellent antiwear and antifriction ability.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of lube oil additive, is grouped into by the group of following weight portion:Nano magnesia, 30-50 part;Nanometer titanium dioxide Silicon, 20-40 part;Modified calcite in powder, 15-25 part;The particle diameter of each component is 20-80 nanometer;Described modification calcite in powder Preparation method is:Calcite is pulverized in calcining furnace, calcines 3-5h under 500-600 DEG C of temperature conditionss, then take out, Cool down, soak through formic acid, filtering, clear water adds the mercaptoethanol of calcite in powder weight 2-4%, the polyethylene of 3-5% after washing Alcohol, after being ground to required particle diameter, 40-60 DEG C of oven drying at low temperature obtains final product.
Preferably, described lube oil additive is grouped into by the group of following weight portion:Nano magnesia, 40 parts;Nanometer Silicon dioxide, 30 parts;Modified calcite in powder, 20 parts.
Preferably, described lube oil additive is grouped into by the group of following weight portion:Nano magnesia, 30 parts;Nanometer Silicon dioxide, 20 parts;Modified calcite in powder, 15 parts.
Preferably, described lube oil additive is grouped into by the group of following weight portion:Nano magnesia, 50 parts;Nanometer Silicon dioxide, 40 parts;Modified calcite in powder, 25 parts.
The preparation method of above-mentioned lube oil additive is:After each component is mixed, ultrasonic disperse uniformly obtains final product.
A kind of lubricating oil for antiwear and antifriction, lube oil additive addition in lubricating oil accounts for lubrication weight of oil 10-20%.
Advantages of the present invention:
The lube oil additive that the present invention provides can significantly improve the antiwear and antifriction ability of lubricating oil.
Specific embodiment
Further illustrate the essentiality content of the present invention with reference to embodiment, but present invention protection model is not limited with this Enclose.Although being explained in detail to the present invention with reference to preferred embodiment, it will be understood by those within the art that, can be right Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1:The preparation of lube oil additive
Nano magnesia, 40 parts;Nano silicon, 30 parts;Modified calcite in powder, 20 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 550 DEG C of temperature strip Calcine 4h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 3% Ethanol, 4% polyvinyl alcohol, after being ground to required particle diameter, 50 DEG C of oven drying at low temperatures obtain final product.
Embodiment 2:The preparation of lube oil additive
Nano magnesia, 30 parts;Nano silicon, 20 parts;Modified calcite in powder, 15 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 500 DEG C of temperature strip Calcine 5h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 2% Ethanol, 3% polyvinyl alcohol, after being ground to required particle diameter, 40 DEG C of oven drying at low temperatures obtain final product.
Embodiment 3:The preparation of lube oil additive
Nano magnesia, 50 parts;Nano silicon, 40 parts;Modified calcite in powder, 25 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 600 DEG C of temperature strip Calcine 3h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 4% Ethanol, 5% polyvinyl alcohol, after being ground to required particle diameter, 60 DEG C of oven drying at low temperatures obtain final product.
Embodiment 4:The preparation of lube oil additive
Nano magnesia, 40 parts;Nano silicon, 30 parts;Modified calcite in powder, 18 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 550 DEG C of temperature strip Calcine 4h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 3% Ethanol, 4% polyvinyl alcohol, after being ground to required particle diameter, 50 DEG C of oven drying at low temperatures obtain final product.
Embodiment 5:The preparation of lube oil additive
Nano magnesia, 40 parts;Nano silicon, 30 parts;Modified calcite in powder, 22 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 550 DEG C of temperature strip Calcine 4h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 3% Ethanol, 4% polyvinyl alcohol, after being ground to required particle diameter, 50 DEG C of oven drying at low temperatures obtain final product.
Embodiment 6:The preparation of lube oil additive
Nano magnesia, 35 parts;Nano silicon, 30 parts;Modified calcite in powder, 20 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 550 DEG C of temperature strip Calcine 4h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 3% Ethanol, 4% polyvinyl alcohol, after being ground to required particle diameter, 50 DEG C of oven drying at low temperatures obtain final product.
Embodiment 7:The preparation of lube oil additive
Nano magnesia, 45 parts;Nano silicon, 30 parts;Modified calcite in powder, 20 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 550 DEG C of temperature strip Calcine 4h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 3% Ethanol, 4% polyvinyl alcohol, after being ground to required particle diameter, 50 DEG C of oven drying at low temperatures obtain final product.
Embodiment 8:The preparation of lube oil additive
Nano magnesia, 40 parts;Nano silicon, 25 parts;Modified calcite in powder, 20 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 550 DEG C of temperature strip Calcine 4h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 3% Ethanol, 4% polyvinyl alcohol, after being ground to required particle diameter, 50 DEG C of oven drying at low temperatures obtain final product.
Embodiment 9:The preparation of lube oil additive
Nano magnesia, 40 parts;Nano silicon, 35 parts;Modified calcite in powder, 20 parts;The particle diameter of each component is 20-80 nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Described modification calcite in powder preparation method be:Calcite is pulverized in calcining furnace in 550 DEG C of temperature strip Calcine 4h under part, then take out, cool down, adding after formic acid immersion, filtration, clear water washing the sulfydryl of calcite in powder weight 3% Ethanol, 4% polyvinyl alcohol, after being ground to required particle diameter, 50 DEG C of oven drying at low temperatures obtain final product.
Embodiment 10:The contrast of embodiment 1, calcite in powder is not modified
Nano magnesia, 40 parts;Nano silicon, 30 parts;Calcite in powder, 20 parts;The particle diameter of each component is 20-80 Nanometer.After each component is mixed, ultrasonic disperse uniformly obtains final product.
Embodiment 11:Effect example
Carry out being mixed with lubricating oil, base oil using the lube oil additive of embodiment 1-10 preparation with base oil respectively For mineral lubricating oil, addition in lubricating oil for the lube oil additive accounts for the 15% of lubrication weight of oil.
Test the antiwear and friction reduction property of each lubricating oil, lubricating oil test result prepared by embodiment 1,10 additives is as follows, The lubricating oil test result of embodiment 2-9 additive preparation is basically identical with embodiment 1.
Add the present embodiment combined nano inorganic lubricating oil using the vertical omnipotent friction wear testing machine evaluation of MMW-1 type to add Plus the antiwear and friction reduction property of the lubricating oil of agent, test method is using Four ball test mensure coefficient of friction, thrust ring test method Evaluate selfreparing effect.Four ball test experimental condition is:Rotating speed 1450r/min, load 392N, time 30min;Test is used Steel ball manufactures according to GB/308-89, GCr15, two grades of steel balls, diameter 12.7mm, and hardness is 64-66HRc;In thrust ring test, Upper sample is big thrust ring, and No. 45 steel are quenched into 45-50HRC, and external diameter is 50mm, and internal diameter is 42mm, and thickness is 5mm;Lower sample For big test ring, No. 45 steel, it is quenched into 44-46HRC, external diameter is 54mm, internal diameter is 38mm, thickness is 10mm.Test initial load For 50N, after increase 50N every 10min, until 300N terminates;Total time on test is 1h, and test speed is 1200r/min.Room After warm off-test, sample cleans 30min in ultrasonic cleaner, after soak in acetone soln, fully remove sample table Face impurity.With the vertical omnipotent friction wear testing machine test ball coefficient of friction of MMW-1 type, its coefficient of friction computing formula is:
μ=0.233 × T/P
In formula:μ is coefficient of friction;
T is moment of friction;
P is imposed load 395N.
In test measure moment of friction, coefficient of friction is calculated by formula.
Antiwear and friction reduction property test result shows:The lubricating oil adding embodiment 1 lube oil additive compares plain oil Coefficient of friction reduce by 88%, wear resistence increase by 13.5%;Mill speckle surface, with the presence of one layer of obvious surface lubrication film, is avoided that Rubbing surface directly contact, reaches reduction abrasion purpose.And the lubricating oil adding embodiment 10 lube oil additive compares common lubricant The coefficient of friction of oil only reduces by 11%, and wear resistence increases by 1.5%, and anti-wear lubricating effect is substantially not as good as embodiment 1.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent, Essence without deviating from technical solution of the present invention and protection domain.

Claims (6)

1. a kind of lube oil additive is it is characterised in that be grouped into by the group of following weight portion:Nano magnesia, 30-50 part; Nano silicon, 20-40 part;Modified calcite in powder, 15-25 part;The particle diameter of each component is 20-80 nanometer;Described modification The preparation method of calcite in powder is:Calcite is pulverized in calcining furnace, calcines 3-5h under 500-600 DEG C of temperature conditionss, Then take out, cool down, adding after formic acid immersion, filtration, clear water washing mercaptoethanol, the 3-5% of calcite in powder weight 2-4% Polyvinyl alcohol, after being ground to required particle diameter, 40-60 DEG C of oven drying at low temperature obtains final product.
2. lube oil additive according to claim 1 is it is characterised in that be grouped into by the group of following weight portion:Nanometer Magnesium oxide, 40 parts;Nano silicon, 30 parts;Modified calcite in powder, 20 parts.
3. lube oil additive according to claim 1 is it is characterised in that be grouped into by the group of following weight portion:Nanometer Magnesium oxide, 30 parts;Nano silicon, 20 parts;Modified calcite in powder, 15 parts.
4. lube oil additive according to claim 1 is it is characterised in that be grouped into by the group of following weight portion:Nanometer Magnesium oxide, 50 parts;Nano silicon, 40 parts;Modified calcite in powder, 25 parts.
5. the arbitrary described lube oil additive of claim 1-4 preparation method it is characterised in that:After each component is mixed, surpass Sound is uniformly dispersed and obtains final product.
6. a kind of lubricating oil for antiwear and antifriction it is characterised in that:Addition in lubricating oil for the described lube oil additive Account for the 10-20% of lubrication weight of oil.
CN201610891033.9A 2016-10-12 2016-10-12 A kind of lube oil additive and the lubricating oil containing this additive Pending CN106479600A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236582A (en) * 2017-07-04 2017-10-10 内蒙古碳谷科技有限公司 A kind of lube oil additive applied on fullerene
CN108456584A (en) * 2018-03-13 2018-08-28 合肥择浚电气设备有限公司 A kind of lube oil additive and preparation method thereof
CN111548842A (en) * 2020-05-21 2020-08-18 成都玉龙化工有限公司 Lubricant and preparation method thereof

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RU2010105670A (en) * 2010-02-18 2011-08-27 Александр Юрьевич Голяткин (RU) MODIFIER FOR REDUCING THE FRICTION COEFFICIENT
CN102199474A (en) * 2011-04-29 2011-09-28 安徽工业大学 Dry film lubricant used for metal parts
WO2012022025A1 (en) * 2010-08-17 2012-02-23 南京钛威科技有限公司 Preparation method of carbon modified filler
CN104140868A (en) * 2014-07-29 2014-11-12 泰州市嘉迪新材料有限公司 Microencapsulated lubricating oil, lubricating oil coating material and preparation method of microencapsulated lubricating oil

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CN101126047A (en) * 2007-08-07 2008-02-20 上海师范大学 A kind of combined nano inorganic lubricating oil additive and its preparation and application
RU2010105670A (en) * 2010-02-18 2011-08-27 Александр Юрьевич Голяткин (RU) MODIFIER FOR REDUCING THE FRICTION COEFFICIENT
WO2012022025A1 (en) * 2010-08-17 2012-02-23 南京钛威科技有限公司 Preparation method of carbon modified filler
CN102199474A (en) * 2011-04-29 2011-09-28 安徽工业大学 Dry film lubricant used for metal parts
CN104140868A (en) * 2014-07-29 2014-11-12 泰州市嘉迪新材料有限公司 Microencapsulated lubricating oil, lubricating oil coating material and preparation method of microencapsulated lubricating oil

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236582A (en) * 2017-07-04 2017-10-10 内蒙古碳谷科技有限公司 A kind of lube oil additive applied on fullerene
CN107236582B (en) * 2017-07-04 2020-01-31 内蒙古碳谷科技有限公司 lubricant additive for fullerene application
CN108456584A (en) * 2018-03-13 2018-08-28 合肥择浚电气设备有限公司 A kind of lube oil additive and preparation method thereof
CN111548842A (en) * 2020-05-21 2020-08-18 成都玉龙化工有限公司 Lubricant and preparation method thereof

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Application publication date: 20170308