CN1064386C - Anti-counterfeiting printing ink for railway ticket and steamer ticket - Google Patents
Anti-counterfeiting printing ink for railway ticket and steamer ticket Download PDFInfo
- Publication number
- CN1064386C CN1064386C CN 92111252 CN92111252A CN1064386C CN 1064386 C CN1064386 C CN 1064386C CN 92111252 CN92111252 CN 92111252 CN 92111252 A CN92111252 A CN 92111252A CN 1064386 C CN1064386 C CN 1064386C
- Authority
- CN
- China
- Prior art keywords
- ticket
- ink
- printing
- ultraluminescence
- class
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000007639 printing Methods 0.000 title claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract 2
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 3
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 3
- 150000002910 rare earth metals Chemical class 0.000 claims description 3
- 150000000918 Europium Chemical class 0.000 claims description 2
- 150000001216 Samarium Chemical class 0.000 claims description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 2
- -1 stearyl alcohol sodium sulfovinate salt Chemical class 0.000 claims description 2
- 150000003746 yttrium Chemical class 0.000 claims description 2
- 239000000976 ink Substances 0.000 abstract description 34
- 239000000463 material Substances 0.000 abstract description 4
- 230000001464 adherent effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000007645 offset printing Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- UYQMAGRFYJIJOQ-UHFFFAOYSA-N 4,4,4-trifluoro-1-naphthalen-1-ylbutane-1,3-dione Chemical compound C1=CC=C2C(C(=O)CC(=O)C(F)(F)F)=CC=CC2=C1 UYQMAGRFYJIJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- 229960003540 oxyquinoline Drugs 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- ZMBHCYHQLYEYDV-UHFFFAOYSA-N trioctylphosphine oxide Chemical compound CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC ZMBHCYHQLYEYDV-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical class [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention belongs to printing inks. At least one ultraviolet fluorescence material and a matched surfactant are added to the existing ink used for train tickets or steamship tickets so as to obtain an ultraviolet fluorescence anti-counterfeiting ink for train tickets or steamship tickets.
Description
The invention belongs to printing-ink based on artificial resin.
All being a kind of Valued Securities, is to adopt the prevailing commercially available printing ink that does not add false proof measure to print now, is easy to be forged, and its reason is exactly not adopt anti-forgery ink.So far yet there are no the information dissemination of being about the anti-forgery ink that is used for train ticket and ferry ticket.
The purpose of this invention is to provide a kind of be easy to the discern train ticket and the ferry ticket true and false, can effectively prevent the car and boat ticket anti-forgery ink of the special use of fake ticket and ferry ticket.
The object of the present invention is achieved like this: based on existing train ticket or take turns the composition of raw materials of printing ink peculiar to vessel, add and at least aly absorb UV-light and send the Ultraluminescence material of characteristic fluorescence and the tensio-active agent that is complementary with it and make the Ultraluminescence anti-forgery ink that train ticket, ferry ticket are used, the composition weight ratio of three kinds of components is common car and boat ticket printing-ink in the made printing ink: rare earth class Ultraluminescence title complex: tensio-active agent=100: 15～30: 0.25.When keeping existing train ticket or ferry ticket with the coloured pigment dyestuff in the ink raw materials, what make is the Ultraluminescence anti-forgery ink of showing one's color; When removing existing train ticket or take turns coloured pigment dyestuff in the ink raw materials peculiar to vessel, and the Ultraluminescence material that adds is a white or when faint yellow, what make is stealthy Ultraluminescence anti-forgery ink.
Used Ultraluminescence material is that the organic ultraviolet high-visibility pigment is (as disperseing fluorescein 2LG in the Ultraluminescence anti-forgery ink prescription of the present invention, Luo Daming B etc.), or inorganic Ultraluminescence pigment (as the zinc sulphide class), or rare earth class Ultraluminescence complex compound (as europium class Ultraluminescence complex compound, yttrium class Ultraluminescence complex compound, samarium class Ultraluminescence complex compound etc.).Used tensio-active agent has sulfonated castor oil, or higher alcohols sulfuric acid.
Ultraluminescence anti-forgery ink of the present invention both can be used for the false proof of train ticket and ferry ticket, also can be used for the false proof of plane ticket and other vehicles bills.
The present invention compared with prior art, the advantage that has is: train ticket of printing with Ultraluminescence anti-forgery ink of the present invention and the shading on the steamer ticket and/or mark and/or literal all show bright-coloured characteristic fluorescence under the uviolizing of suitable wavelength, thereby can discern the true and false of train ticket or ferry ticket rapidly, exactly, thereby played anti-fake effect.
Embodiment 1
Enchashment has prints 100 parts of the pale pink color inks (allocated by a certain percentage and formed by the pale yellow offset printing China ink of pink offset printing China ink, white glues seal China ink) that train ticket or ferry ticket use, Eu
3+25 parts of the ternary complexes of forming with naphthoyl trifluoroacetone and o-phenanthroline, 0.25 part of sulfonated castor oil grinds to form shading that the pulpous state adherent promptly makes train ticket or the ferry ticket Ultraluminescence anti-forgery ink of showing one's color through three-roller.This printing ink produces the characteristic fluorescence of 600～620nm under uviolizing.
Embodiment 2
Get 100 parts in water white transparency offset printing Lacquer finish China ink, disperse 30 parts of fluorescein 2LG, 0.25 part of stearyl alcohol sulfuric ester sodium salt becomes the pulpous state adherent through the three-roller grinding and promptly makes the shading of train ticket or ferry ticket or the stealthy Ultraluminescence anti-forgery ink of mark or literal.This printing ink produces the characteristic fluorescence of 600～620nm under uviolizing.
Embodiment 3
Get 100 parts of offset printing luminous slurries, Sm
3+20 parts of the binary complexs of forming with vulkacit D and trioctyl phosphine oxide, 0.25 part of sulfonated castor oil, grinding through three-roller becomes the pulpous state adherent and promptly makes the stealthy Ultraluminescence anti-forgery ink that train ticket or ferry ticket are used.This printing ink produces the characteristic fluorescence of 550～570nm under uviolizing.
Embodiment 4
Enchashment has prints 100 parts of the letterpress printing inks that train ticket or ferry ticket use, Y
3+With 3,15 parts of the binary complexs formed of 7-dichloro-8-hydroxyquinoline, 0.25 part of sulfonated castor oil, grinding through three-roller becomes the pulpous state adherent and promptly makes the Ultraluminescence anti-forgery ink of showing one's color that train ticket or ferry ticket are used.This printing ink produces the characteristic fluorescence of 500～520nm under uviolizing.
Claims (2)
1. train ticket and ferry ticket printing-ink, it is characterized in that it by the Ultraluminescence anti-forgery ink that common car and boat ticket printing-ink and europium class, yttrium class or samarium class fluorescence complex and sulfonated castor oil or stearyl alcohol sodium sulfovinate salt surfactant are formed, wherein the composition weight ratio of three kinds of components is common car and boat ticket printing-ink: rare earth class Ultraluminescence title complex: tensio-active agent=100: 15～30: 0.25.
2. train ticket according to claim 1 and ferry ticket is characterized in that this printing ink is applied in the anti-counterfeit printing of car and boat ticket with the application of printing-ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92111252 CN1064386C (en) | 1992-10-13 | 1992-10-13 | Anti-counterfeiting printing ink for railway ticket and steamer ticket |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92111252 CN1064386C (en) | 1992-10-13 | 1992-10-13 | Anti-counterfeiting printing ink for railway ticket and steamer ticket |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1073699A CN1073699A (en) | 1993-06-30 |
| CN1064386C true CN1064386C (en) | 2001-04-11 |
Family
ID=4945248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92111252 Expired - Fee Related CN1064386C (en) | 1992-10-13 | 1992-10-13 | Anti-counterfeiting printing ink for railway ticket and steamer ticket |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1064386C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1785688B (en) * | 2005-06-13 | 2010-06-30 | 张重光 | Antifalse rail road ticket capable of machine reading |
| US9353275B2 (en) * | 2007-11-14 | 2016-05-31 | Hewlett-Packard Development Company, L.P. | Ink visible under narrow band UV radiation |
| CN109096826A (en) * | 2018-11-01 | 2018-12-28 | 陕西科技大学 | The method of Application in Anti-counterfeiting in a kind of preparation of rare earth luminescent material and printing ink |
-
1992
- 1992-10-13 CN CN 92111252 patent/CN1064386C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1073699A (en) | 1993-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| OR01 | Other related matters | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |