CN1096040A - The safety printing ink that anti-forging and anti-altering is used - Google Patents
The safety printing ink that anti-forging and anti-altering is used Download PDFInfo
- Publication number
- CN1096040A CN1096040A CN 93105891 CN93105891A CN1096040A CN 1096040 A CN1096040 A CN 1096040A CN 93105891 CN93105891 CN 93105891 CN 93105891 A CN93105891 A CN 93105891A CN 1096040 A CN1096040 A CN 1096040A
- Authority
- CN
- China
- Prior art keywords
- printing ink
- ink
- component
- safety
- altering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 29
- 238000005242 forging Methods 0.000 title abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- 230000005855 radiation Effects 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 12
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 5
- 150000002910 rare earth metals Chemical class 0.000 claims description 5
- 150000000918 Europium Chemical class 0.000 claims description 4
- 150000001216 Samarium Chemical class 0.000 claims description 4
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 abstract description 5
- 239000000976 ink Substances 0.000 description 31
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000003746 yttrium Chemical class 0.000 description 3
- ZZNMRBGELWVJND-UHFFFAOYSA-N 3-phenyl-1h-imidazol-2-one Chemical compound O=C1NC=CN1C1=CC=CC=C1 ZZNMRBGELWVJND-UHFFFAOYSA-N 0.000 description 2
- 229910018626 Al(OH) Inorganic materials 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- GLGNXYJARSMNGJ-VKTIVEEGSA-N (1s,2s,3r,4r)-3-[[5-chloro-2-[(1-ethyl-6-methoxy-2-oxo-4,5-dihydro-3h-1-benzazepin-7-yl)amino]pyrimidin-4-yl]amino]bicyclo[2.2.1]hept-5-ene-2-carboxamide Chemical compound CCN1C(=O)CCCC2=C(OC)C(NC=3N=C(C(=CN=3)Cl)N[C@H]3[C@H]([C@@]4([H])C[C@@]3(C=C4)[H])C(N)=O)=CC=C21 GLGNXYJARSMNGJ-VKTIVEEGSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 1
- ZPSJGADGUYYRKE-UHFFFAOYSA-N 2H-pyran-2-one Chemical compound O=C1C=CC=CO1 ZPSJGADGUYYRKE-UHFFFAOYSA-N 0.000 description 1
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000050492 Orchis militaris Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 239000010495 camellia oil Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229940125773 compound 10 Drugs 0.000 description 1
- 229940125758 compound 15 Drugs 0.000 description 1
- ZXJXZNDDNMQXFV-UHFFFAOYSA-M crystal violet Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1[C+](C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 ZXJXZNDDNMQXFV-UHFFFAOYSA-M 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000002990 phenothiazines Chemical class 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N trans-stilbene Chemical group C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to safety printing ink, by commercially available common printed printing ink add the fluorescence radiation material, can with the material of generation variable color of character eliminating liquid kind material or color development reaction and to play the auxiliary of adjusting the ink printing performance formulated.The dual-use function that can have anti-forging and anti-altering simultaneously, the anti-false sign of printing with it can send brightly painted fluorescence under UV-irradiation, then tangible variable color or color development can take place when running into the character eliminating liquid kind material.Therefore the anti-forging and anti-altering performance is all very reliable, and it is convenient, with low cost to produce.
Description
The present invention relates to a kind of printing-ink.
Bank note, security, bond, check or other similarly have valency bank note often to be forged or alter by the lawless person, and this has become the harmful greatly of current society.The existing method that prevents to forge valency bank note roughly is two classes.One class is to print the secret mark pattern with watermark on bank note, but watermark secret mark pattern still is easier to forge.Another kind of is to adopt safety printing ink.So-called safety printing ink is to add to prevent the material forged in common ink, as magnetic substance, ultraviolet ray or infrared absorbent (CN1013681B), the luminophore of forming by flash of light metallic compound and phosphorescent compound (EP253543B), reach the material (J03166276A) that fluorescence takes place under ultraviolet light irradiation, wherein first three plants substance because of the cost height, or make difficult, or reason such as anti-counterfeiting performance is not still good enough, Application and Development is still undesirable, it is then simple for production to add the fluorescence radiation material, cost is low, anti-counterfeiting performance is reliable, only need shine during check and tell the true and false at once, therefore become the main trend of exploitation safety printing ink with the ultra-violet lamp one of specific wavelength.The existing anti-safety printing ink of using instead that is coated with then is to add the material (J59064679A, J58157873A) that variable color or color development (redox reaction) can take place (its main component is for containing oxychloride and oxalic acid etc.) with the character eliminating liquid kind material in common ink.Yet existing anti-counterfeiting or the anti-function singleness that is coated with the safety printing ink of using instead, color developing effect is undesirable.
The purpose of this invention is to provide a kind of novel have false proof and/or anti-correction function, can select the discrimination performance, that manifest bright-coloured fluorescence, variable color or the tangible safety printing ink of color development.
The object of the present invention is achieved like this: the safety printing ink of anti-forging and anti-altering by commercially available printing-ink (A), fluorescence radiation material (B), can with the material (C) of generation variable color of character eliminating liquid kind material or color development reaction, and auxiliary (D) mix and form, the weight ratio of these component content is (A) 50～80%, (B) 0～20%, (C) 0～20%, (D) 0～10%.Change component (B) and/or content (C) and can select the safety printing ink of various anti-counterfeiting performances, exist simultaneously as (B) with (C), and when content changed in 5～20%, the safety ink of being prepared had good anti-counterfeiting and the anti-dual-use function of altering simultaneously; When (B)＞0, (C)=0 o'clock, this safety printing ink has only the anti-counterfeiting function; When (B)=0, (C)＞0 o'clock, then this safety printing ink has only the anti-function of altering.But, (B) and (C) can not be zero simultaneously.
All kinds of commercially available printing-ink that component (A) can select for use paper to use can be printed to such an extent that show red, yellow, blue, green, cyan or cryptomorphic anti-counterfeiting mark under visible light according to the color of selected (A).
Component (B) is selected the compound that can send fluorescence under UV-irradiation for use, as rare-earth complex (europium class complex compound or yttrium class complex compound or samarium class complex compound), toluylene system, imidazoles system, thiophene system, triazole system, imidazolone system, coumalin system or inorganic fluorescent chemicals (as ZnSCuCO, ZnSCu, MgWO
4, the rare earth mineral compound), according to selected (B) difference, under UV-irradiation, can send the fluorescence of different colours, wherein luminous more bright-coloured with rare-earth complex (as europium class complex compound or yttrium class complex compound or samarium class complex compound), ZnSCuCO.
Component (C) is selected for use and is run into the material that variable color or color development reaction (being redox reaction) can take place the character eliminating liquid kind material, as vulkacit D, 1-phenyl-3-imidazolidone, phenothiazines, methyl violet color lake, the colourless U.S. orchid of benzoyl, manganous salt, gallic acid, wherein obvious with the variable color or the color development of vulkacit D especially.
Component (D) can be selected for use and play the material of adjusting the ink printing performance, as BaSO
4, Al(OH)
2, CaCO
3, wilkinite, polyoxyethylene glycol, ink oil, Viscotrol C, Camellia oil, sweet oil, rapeseed oil, soybean oil, the Synolac of various performances, maleic acid resin, ketone acid resin, resol.
The advantage that the present invention compared with prior art has is: owing to added the fluorescence radiation material and with the character eliminating liquid kind material material of variable color or color development reaction can take place in the component of safety printing ink, therefore this safety printing ink can have anti-counterfeiting and anti-function of altering simultaneously, particularly adopt rare-earth complex or ZnSCuCO, the fluorescence that sends is more bright-coloured, adopt vulkacit D, variable color or color development effect are more obvious.
Safety printing ink of the present invention is applicable to various have valency bank note and analogues, particularly is applied on check and the invoice anti-counterfeiting, the anti-dependable performance of altering.
Embodiment 1
Get commercially available finished product golden red China ink 70%(weight, down with), europium class complex compound 15%, vulkacit D 10%, poly(oxyethylene glycol) 400 2%, organism coat CaCO
23%, with all component thorough mixing, stirring, grind, make the safety printing ink of under visible light, using for red anti-forging and anti-altering through three-roller.False proof anti-correction mark with this ink printing sends bright-coloured red fluorescence under UV-irradiation, when running into the ink eradicator correction of oxalic acid and clorox composition, mark becomes black.
Embodiment 2
Get the blue China ink 60% of commercially available offset printing, ZnSCuCO 15%, 1-phenyl-3-imidazolidone 10%, poly(oxyethylene glycol) 400 5%, sweet oil 5%, Al(OH)
22%, wilkinite 3%, with make after above-mentioned component thorough mixing, stirring, the grinding under visible light for blue, that under UV-light, send bright-coloured green fluorescence, run into the safety printing ink that anti-forging and anti-altering that ink eradicator becomes cyan is used.
Embodiment 3
Get commercially available offset printing and remove light dose 80%, yttrium class complex compound 10%, vulkacit D 10%, with these component thorough mixing, stirring, grinding, make the safety printing ink of under visible light, using for anti-forging and anti-altering stealthy or extremely light color, that under UV-irradiation, send bright-coloured yellow fluorescence, that the chance ink eradicator becomes black.
Claims (4)
1, a kind of safety printing ink, it is characterized in that: it by commercially available printing-ink (A), fluorescence radiation material (B), can and can play the auxiliary (D) of adjusting the ink printing performance and mix and form with the material (C) of generation variable color of character eliminating liquid kind material or color development reaction, the weight ratio of these component content is, (A) 50～80%, (B) 0～20%, (C) 0～20%, (D) 0～10%, wherein component (B) and content (C) can not be zero simultaneously.
2, safety printing ink according to claim 1 is characterized in that: the content weight ratio of above-mentioned component (B) is 5～20%, and the content weight ratio of component (C) is 5～20%.
3, safety printing ink according to claim 1 and 2 is characterized in that: component (B) is rare-earth complex (as europium class complex compound or samarium class complex compound or samarium class complex compound) or ZnSCuCO.
4, safety printing ink according to claim 1 and 2 is characterized in that: component (C) is a vulkacit D.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93105891 CN1096040A (en) | 1993-05-31 | 1993-05-31 | The safety printing ink that anti-forging and anti-altering is used |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93105891 CN1096040A (en) | 1993-05-31 | 1993-05-31 | The safety printing ink that anti-forging and anti-altering is used |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1096040A true CN1096040A (en) | 1994-12-07 |
Family
ID=4985972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93105891 Pending CN1096040A (en) | 1993-05-31 | 1993-05-31 | The safety printing ink that anti-forging and anti-altering is used |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1096040A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1041185C (en) * | 1995-04-07 | 1998-12-16 | 南开大学戈德防伪技术公司 | Printing process of anti-forgery mark |
| CN102795009A (en) * | 2012-08-21 | 2012-11-28 | 佛山市三水诚远包装彩印有限公司 | Anti-fake printing production technology |
-
1993
- 1993-05-31 CN CN 93105891 patent/CN1096040A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1041185C (en) * | 1995-04-07 | 1998-12-16 | 南开大学戈德防伪技术公司 | Printing process of anti-forgery mark |
| CN102795009A (en) * | 2012-08-21 | 2012-11-28 | 佛山市三水诚远包装彩印有限公司 | Anti-fake printing production technology |
| CN102795009B (en) * | 2012-08-21 | 2014-12-10 | 佛山市三水诚远包装彩印有限公司 | Anti-fake printing production technology |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |