CN106009936A - Compound waterproof emulsible paste containing papermaking sludge and preparation method - Google Patents
Compound waterproof emulsible paste containing papermaking sludge and preparation method Download PDFInfo
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- CN106009936A CN106009936A CN201610573092.1A CN201610573092A CN106009936A CN 106009936 A CN106009936 A CN 106009936A CN 201610573092 A CN201610573092 A CN 201610573092A CN 106009936 A CN106009936 A CN 106009936A
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- emulsion
- styrene
- nordes
- paper mill
- mill sludge
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- 239000010802 sludge Substances 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 150000001875 compounds Chemical class 0.000 title claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 156
- 239000002131 composite material Substances 0.000 claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 52
- 238000003756 stirring Methods 0.000 claims abstract description 37
- 229920000642 polymer Polymers 0.000 claims abstract description 30
- 239000013067 intermediate product Substances 0.000 claims abstract description 24
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 11
- 239000003755 preservative agent Substances 0.000 claims abstract description 11
- 230000002335 preservative effect Effects 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 230000001954 sterilising effect Effects 0.000 claims abstract description 4
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 69
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 23
- 229920001296 polysiloxane Polymers 0.000 claims description 23
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 23
- 239000000052 vinegar Substances 0.000 claims description 23
- 235000021419 vinegar Nutrition 0.000 claims description 23
- 239000006185 dispersion Substances 0.000 claims description 22
- 229920000058 polyacrylate Polymers 0.000 claims description 22
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 22
- 239000011118 polyvinyl acetate Substances 0.000 claims description 22
- 239000002174 Styrene-butadiene Substances 0.000 claims description 21
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 21
- 239000011115 styrene butadiene Substances 0.000 claims description 21
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 14
- 210000000481 breast Anatomy 0.000 claims description 13
- 229920002635 polyurethane Polymers 0.000 claims description 12
- 239000004814 polyurethane Substances 0.000 claims description 12
- 230000000844 anti-bacterial effect Effects 0.000 claims description 10
- XYRAEZLPSATLHH-UHFFFAOYSA-N trisodium methoxy(trioxido)silane Chemical compound [Na+].[Na+].[Na+].CO[Si]([O-])([O-])[O-] XYRAEZLPSATLHH-UHFFFAOYSA-N 0.000 claims description 8
- XTIIITNXEHRMQL-UHFFFAOYSA-N tripotassium methoxy(trioxido)silane Chemical compound [K+].[K+].[K+].CO[Si]([O-])([O-])[O-] XTIIITNXEHRMQL-UHFFFAOYSA-N 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 5
- 230000002421 anti-septic effect Effects 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims 2
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- -1 poly-ammonia Ester Chemical class 0.000 claims 1
- 238000007789 sealing Methods 0.000 abstract description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000004816 latex Substances 0.000 description 23
- 229920000126 latex Polymers 0.000 description 23
- 239000000047 product Substances 0.000 description 10
- 238000010276 construction Methods 0.000 description 9
- 238000002156 mixing Methods 0.000 description 7
- 238000007711 solidification Methods 0.000 description 7
- 230000008023 solidification Effects 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000001680 brushing effect Effects 0.000 description 3
- 239000002910 solid waste Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000004078 waterproofing Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920002488 Hemicellulose Polymers 0.000 description 2
- 241001597008 Nomeidae Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 241000222065 Lycoperdon Species 0.000 description 1
- 241000768494 Polymorphum Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- NCWQJOGVLLNWEO-UHFFFAOYSA-N methylsilicon Chemical compound [Si]C NCWQJOGVLLNWEO-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000006041 probiotic Substances 0.000 description 1
- 235000018291 probiotics Nutrition 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/02—Cellulose; Modified cellulose
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
- C09D105/14—Hemicellulose; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D197/00—Coating compositions based on lignin-containing materials
- C09D197/005—Lignin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Treatment Of Sludge (AREA)
Abstract
The invention relates to compound waterproof emulsible paste containing papermaking sludge. The compound waterproof emulsible paste contains 16-66% of papermaking sludge by weight. A preparation method includes the following steps that A, the papermaking sludge is put in a reaction container, an equal amount of water is added, even stirring is performed, a sterilization preservative with the amount 0.1-0.5% of the total amount of the papermaking sludge is added, even heating is performed in a stirring state to reach the temperature of 30-70 DEG C, constant-temperature reaction is performed for 6-24 hours, and then cooling is performed to reach room temperature; B, the pH of the materials is regulated to be 7.5-9.0 with ammonia water containing ammonia and water at the ratio of 1:(1-10), and then the material is put in the environment of 4-40 DEG C to perform sealed storage for 3-90 days; C, a papermaking sludge intermediate product obtained after treatment in the step B is mixed with a water-based composite polymer emulsion material according to the proportion of 2:0.5-4, an organic silicate defoaming agent with the amount 0.15-1.5% of the total amount of the papermaking sludge is added, even stirring is performed, the mixture is charged into a material bucket for sealing, and sealed storage is performed in the environment of 4-40 DEG C for 3-90 days. The compound waterproof emulsible paste can be used for any working face subjected to waterproof treatment of building roof waterproof layers, interior and exterior wall waterproof base layers, exterior wall waterproof layers, indoor waterproof base layers, kitchen and toilet waterproof base layers, road waterproof base layers and the like.
Description
Technical field
The present invention provides a kind of method utilizing paper mill sludge to prepare composite water-proof emulsifiable paste, belongs to
The Appropriate application technical field of papermaking waste.
Background technology
Paper industry is that resources and energy consumption intensity is high, pollutant generation amount is big, environmental effect
Serious processing and manufacturing industry.Paper-making process can produce substantial amounts of solid waste, along with product
The gradually expansion of industry scale, the environmental effect that these solid waste are brought also becomes increasingly conspicuous, with
And come various ecological problems and social problem the most gradually highlight.
Paper-making process meeting produces a large amount of papermaking preliminary sludge, its composition predominantly cellulose,
Hemicellulose, lignin and derivant thereof and other Organic substance, inorganic matter etc..Due to aqueous
Amount high (>=80%), in mud state, complicated component, process utilize difficulty big, the most greatly
Part is the most only taked simply to burn, throws sea, is stacked and fill.Although various research reports
Accuse many, but in general, the green circulation economy chain not yet shape of papermaking solid waste
Becoming, various application technology as the second resource are in the starting stage more.
Summary of the invention
It is an object of the invention to provide a kind of with papermaking preliminary sludge as raw material, pass through microorganism
And the method that chemical modification reaction manufactures the composite high-molecular waterproof emulsifiable paste of series, provide for paper mill sludge
Sourceization utilizes provides a practicable Technology Ways.
The present invention is realized by techniques below means and measure: this containing paper mill sludge
Composite water-proof emulsifiable paste, component comprises part by weight 16～the paper mill sludge of 66%.
The described composite water-proof emulsifiable paste containing paper mill sludge, preparation method comprises the following steps:
A, being placed in reaction vessel by paper mill sludge, stir after adding equivalent water, addition is made
Paper mud gross weight 0.1～the sterilization antiseptic of 0.5%, be heated uniformly under stirring
30～70 DEG C, isothermal reaction 6～24 hours, then it is cooled to room temperature；
B, with 1: 1～10 ammonia adjust material pH be 7.5～9.0, be subsequently placed in 4～40 DEG C
Environment in seal deposit 3～90 days；
Paper mill sludge intermediate products after the process of C, step B and water-soluble composite high molecular polymer emulsion thing
Expect to mix in the ratio of 2: 0.5～4, add organosilicate defoamer 0.15～1.5%, stir
Mix uniformly, load in material barrel and seal, seal in the environment of 4～40 DEG C and deposit 3～90 days.
The preparation method of the described composite water-proof emulsifiable paste containing paper mill sludge, kills described in step A
Bacterium preservative is chosen as: MIT, Nordes C15, Nordes EPW,
Dao Weixier-75, BIT one of which or several compound.
The preparation method of the described composite water-proof emulsifiable paste containing paper mill sludge, described composite bactericidal is prevented
Rotten agent weight percent composition is chosen as: MIT is 15%, Nordes
C15 is 25%, and Nordes EPW is 30%, and Dao Weixier-75 is 20%, 1,2-benzo
Isothiazoline-3-ketone is 10%；
Or
MIT is 10%, and Nordes C15 is 20%, Nordes
EPW is 20%, and Dao Weixier-75 is 30%, and BIT is 20%；
Or
MIT is 10%, and Nordes C15 is 10%, Nordes
EPW is 30%, and Dao Weixier-75 is 30%, and BIT is 20%；
Or
MIT is 10%, and Nordes C15 is 10%, Nordes
EPW is 30%, and Dao Weixier-75 is 35%, and BIT is 15%；
Or
MIT is 5%, and Nordes C15 is 10%, Nordes EPW
Being 15%, Dao Weixier-75 is 30%, and BIT is 40%；
Or
MIT is 30%, and Nordes C15 is 5%, Nordes EPW
Being 30%, Dao Weixier-75 is 30%, and BIT is 5%；
Or
MIT is 28%, and Nordes C17 is 5%, Nordes EPW
Being 27%, Dao Weixier-75 is 30%, and BIT is 8%.
The preparation method of the composite water-proof emulsifiable paste containing paper mill sludge, the aqueous described in step C
Composite polymer latex weight of material percentage composition is: silicone acrylic emulsion 1～5%；Styrene-acrylic emulsion
10～50%；EVA emulsion 5～30%；Polyvinyl acetate emulsion 1～10%；Polyacrylic acid
Ester emulsion 5～50%；Styrene-butadiene emulsion 5～20%；Vinegar benzene emulsion 5～15%；Polyaminoester emulsion
5～10%.
The preparation method of the described composite water-proof emulsifiable paste containing paper mill sludge, described in step C
Water-soluble composite high molecular polymer emulsion weight of material percentage composition is: silicone acrylic emulsion 3%, styrene-acrylic emulsion
10%, EVA emulsion 20%, polyvinyl acetate emulsion 2%, polyacrylate dispersion 40%,
Styrene-butadiene emulsion 10%, vinegar benzene emulsion 10%, polyaminoester emulsion 5%；
Or
Silicone acrylic emulsion 5%, styrene-acrylic emulsion 30%, EVA emulsion 5%, polyvinyl acetate emulsion
10%, polyacrylate dispersion 20%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 15%, polyurethane
Emulsion 10%；
Or
Silicone acrylic emulsion 1%, styrene-acrylic emulsion 40%, EVA emulsion 15%, polyvinyl acetate emulsion
6%, polyacrylate dispersion 10%, styrene-butadiene emulsion 15%, vinegar benzene emulsion 5%, polyurethane breast
Liquid 8%；
Or
Silicone acrylic emulsion 5%, styrene-acrylic emulsion 45%, EVA emulsion 10%, polyvinyl acetate emulsion
5%, polyacrylate dispersion 15%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 10%, polyurethane breast
Liquid 5%；
Or
Silicone acrylic emulsion 3%, styrene-acrylic emulsion 20%, EVA emulsion 30%, polyvinyl acetate emulsion
2%, polyacrylate dispersion 30%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 5%, polyurethane breast
Liquid 5%；
Or
Silicone acrylic emulsion 2%；Styrene-acrylic emulsion 30%；EVA emulsion 15%；Polyvinyl acetate emulsion
3%；Polyacrylate dispersion 30%；Styrene-butadiene emulsion 10%；Vinegar benzene emulsion 5%；Polyurethane breast
Liquid 5%；
Or
Silicone acrylic emulsion 1%, styrene-acrylic emulsion 20%, EVA emulsion 9%, polyvinyl acetate emulsion
5%, polyacrylate dispersion 50%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 5%, polyurethane breast
Liquid 5%.
The preparation method of the described composite water-proof emulsifiable paste containing paper mill sludge, described in step C
Organosilicate defoamer is sodium methyl silicate or/and potassium methyl silicate.
The technological progress effect of the present invention shows: through the paper mill sludge of pretreatment, and itself is
Through having certain film-forming base performance indications.The addition of composite polymer latex, acts primarily as increasing
Adding suppleness, degree of adhesion and improve the effect of water resistance further, the present invention is produced
The composite high-molecular waterproof emulsifiable paste of series, can be used for serving as building top waterproof layer, inner-outer wall is prevented
Water base bottom, external wall waterproof layer, indoor waterproof sub-base layer, lavatory, kitchen waterproof sub-base layer, road
Any work surfaces needing water-proofing treatment such as road waterproof sub-base floor.
Detailed description of the invention
Paper mill sludge of the present invention is that all cellulose, hemicellulose, lignin etc. are organic
Matter and derivant thereof and the primary biological sludge of the element such as a small amount of calcium carbonate and N P and K.
Embodiment 1.
100kg paper mill sludge is placed in reactor, stirs after adding 100kg water, add
Enter the MIT of 0.1kg,
Or composite bactericidal preservative: wherein MIT is 15%, Nordes
C15 is 25%, and Nordes EPW is 30%, and Dao Weixier-75 is 20%, 1,2-benzo
Isothiazoline-3-ketone is 10%,
30 DEG C it are heated uniformly under stirring, isothermal reaction 24 hours, then it is cooled to
Room temperature；Adjusting material pH with 1: 10 ammonia is 7.5～8.0, stirs.
Being subsequently placed in material barrel, seal and deposit 60 days in the environment of about 10 DEG C, this is
Paper mill sludge intermediate products.
In stirred tank, above-mentioned paper mill sludge intermediate products are pressed with composite polymer latex material
The ratio batch mixing of 2: 0.5, i.e. paper mill sludge intermediate products about 200kg, composite polymer latex
50kg, composite polymer latex material ratio is: silicone acrylic emulsion 3%；Styrene-acrylic emulsion 10%；
EVA emulsion 20%；Polyvinyl acetate emulsion 2%；Polyacrylate dispersion 40%；Butylbenzene breast
Liquid 10%；Vinegar benzene emulsion 10%；Polyaminoester emulsion 5%；Add defoamer sodium methyl silicate and
The each 0.5kg of potassium methyl silicate, stirs, and loads in material barrel and seals, in the environment of 10 DEG C
Middle sealing deposits 36 days.
Embodiment 2
100kg paper mill sludge is placed in reactor, stirs after adding 100kg water, add
Enter the Nordes C15 of 0.2kg；
Or composite bactericidal preservative: MIT is 10%, Nordes C15
Being 20%, Nordes EPW is 20%, and Dao Weixier-75 is 30%, 1,2-benzisothia
Oxazoline-3-ketone is 20%；
40 DEG C it are heated uniformly under stirring, isothermal reaction 18 hours, then it is cooled to
Room temperature；Adjusting material pH with 1: 8 ammonia is 7.5～8.0, stirs；
Being subsequently placed in material barrel, seal and deposit 45 days in the environment of about 15 DEG C, this is
Paper mill sludge intermediate products.
In stirred tank, above-mentioned paper mill sludge intermediate products are pressed with composite polymer latex material
The ratio batch mixing of 2: 1, i.e. paper mill sludge intermediate products about 200kg, composite polymer latex
100kg；
Described composite polymer latex material ratio is: silicone acrylic emulsion 5%；Styrene-acrylic emulsion 30%；
EVA emulsion 5%；Polyvinyl acetate emulsion 10%；Polyacrylate dispersion 20%；Butylbenzene breast
Liquid 5%；Vinegar benzene emulsion 15%；Polyaminoester emulsion 10%；Add sodium methyl silicate and methyl silicon
The acid each 0.75kg of potassium, stirs, and loads in material barrel and seals, close in the environment of 15 DEG C
Seal up for safekeeping and put 28 days.
Embodiment 3
100kg paper mill sludge is placed in reactor, stirs after adding 100kg water, add
Enter the Nordes EPW of 0.25kg
Or composite bactericidal preservative MIT is 10%, Nordes C15
Being 10%, Nordes EPW is 30%, and Dao Weixier-75 is 30%, 1,2-benzisothia
Oxazoline-3-ketone is 20%；
50 DEG C it are heated uniformly under stirring, isothermal reaction 12 hours, then it is cooled to
Room temperature；Adjusting material pH with 1: 6 ammonia is 7.5～8.0, stirs；
Being subsequently placed in material barrel, seal and deposit 27 days in the environment of about 25 DEG C, this is
Paper mill sludge intermediate products.
In stirred tank, above-mentioned paper mill sludge intermediate products are pressed with composite polymer latex material
The ratio batch mixing of 2: 2, i.e. paper mill sludge intermediate products about 200kg, composite polymer latex
200kg, described composite polymer latex material ratio is: silicone acrylic emulsion 1%；Styrene-acrylic emulsion
40%；EVA emulsion 15%；Polyvinyl acetate emulsion 6%；Polyacrylate dispersion 10%；
Styrene-butadiene emulsion 15%；Vinegar benzene emulsion 5%；Polyaminoester emulsion 8%；Add sodium methyl silicate and
The each 1.0kg of potassium methyl silicate, stirs, and loads in material barrel and seals, in the environment of 20 DEG C
Middle sealing deposits 25 days.
Embodiment 4
100kg paper mill sludge is placed in reactor, stirs after adding 100kg water, add
Enter the Dao Weixier-75 of 0.3kg
Or composite bactericidal preservative MIT is 10%, Nordes C15
Being 10%, Nordes EPW is 30%, and Dao Weixier-75 is 35%, 1,2-benzisothia
Oxazoline-3-ketone is 15%；
60 DEG C it are heated uniformly under stirring, isothermal reaction 8 hours, then it is cooled to
Room temperature；Adjusting material pH with 1: 4 ammonia is 7.5～8.0, stirs；
Being subsequently placed in material barrel, seal and deposit 27 days in the environment of about 25 DEG C, this is
Paper mill sludge intermediate products.
In stirred tank, above-mentioned paper mill sludge intermediate products are pressed with composite polymer latex material
The ratio batch mixing of 2: 2, i.e. paper mill sludge intermediate products about 200kg, composite polymer latex
200kg, described composite polymer latex material ratio is: silicone acrylic emulsion 5%；Styrene-acrylic emulsion
45%；EVA emulsion 10%；Polyvinyl acetate emulsion 5%；Polyacrylate dispersion 15%；
Styrene-butadiene emulsion 5%；Vinegar benzene emulsion 10%；Polyaminoester emulsion 5%；Add sodium methyl silicate and
The each 1.5kg of potassium methyl silicate, stirs, and loads in material barrel and seals, in the environment of 25 DEG C
Middle sealing deposits 20 days.
Embodiment 5
100kg paper mill sludge is placed in reactor, stirs after adding 100kg water, add
Enter the BIT (BIT) of 0.4kg
Or composite bactericidal preservative MIT is 5%, Nordes C15
Being 10%, Nordes EPW is 15%, and Dao Weixier-75 is 30%, 1,2-benzisothia
Oxazoline-3-ketone is 40%；
70 DEG C it are heated uniformly under stirring, isothermal reaction 6 hours, then it is cooled to
Room temperature；Adjusting material pH with 1: 2 ammonia is 7.5～8.5, stirs；
Being subsequently placed in material barrel, seal and deposit 18 days in the environment of about 30 DEG C, this is
Paper mill sludge intermediate products.
In stirred tank, above-mentioned paper mill sludge intermediate products are pressed with composite polymer latex material
The ratio batch mixing of 2: 3, i.e. paper mill sludge intermediate products about 200kg, composite polymer latex
300kg, described composite polymer latex material ratio is: silicone acrylic emulsion 3%；Styrene-acrylic emulsion
20%；EVA emulsion 30%；Polyvinyl acetate emulsion 2%；Polyacrylate dispersion 30%；
Styrene-butadiene emulsion 5%；Vinegar benzene emulsion 5%；Polyaminoester emulsion 5%；Add sodium methyl silicate and first
The each 1.75kg of base potassium silicate, stirs, and loads in material barrel and seals, in the environment of 25 DEG C
Middle sealing deposits 20 days.
Embodiment 6
100kg paper mill sludge is placed in reactor, stirs after adding 100kg water, add
The composite bactericidal preservative MIT entering 0.5kg is 30%, Nordes
C15 is 5%, and Nordes EPW is 30%, and Dao Weixier-75 is 30%, 1,2-benzo
Isothiazoline-3-ketone is 5%；Being heated uniformly to 65 DEG C under stirring, isothermal reaction 7 is little
Time, then it is cooled to room temperature；Adjusting material pH with 1: 1 ammonia is 7.5～9.0, stirring
Uniformly；
Being subsequently placed in material barrel, seal and deposit 3 days in the environment of about 40 DEG C, this is
Paper mill sludge intermediate products.
In stirred tank, above-mentioned paper mill sludge intermediate products are pressed with composite polymer latex material
The ratio batch mixing of 2: 4, i.e. paper mill sludge intermediate products about 200kg, composite polymer latex
400kg, described composite polymer latex material ratio is: silicone acrylic emulsion 2%；Styrene-acrylic emulsion
30%；EVA emulsion 15%；Polyvinyl acetate emulsion 3%；Polyacrylate dispersion 30%；
Styrene-butadiene emulsion 10%；Vinegar benzene emulsion 5%；Polyaminoester emulsion 5%；Add sodium methyl silicate 5kg,
Stir, load in material barrel and seal, seal in the environment of 50 DEG C and deposit 5 days.
Embodiment 7
100kg paper mill sludge is placed in reactor, stirs after adding 100kg water, add
The composite bactericidal preservative MIT entering 0.35kg is 28%, Nordes
C17 is 5%, and Nordes EPW is 27%, and Dao Weixier-75 is 30%, 1,2-benzo
Isothiazoline-3-ketone is 8%, is heated uniformly to 45 DEG C, isothermal reaction 14 under stirring
Hour, then it is cooled to room temperature；Adjusting material pH with 1: 2.5 ammonia is 7.5～9.0, stirs
Mix uniformly；
Being subsequently placed in material barrel, seal and deposit 9 days in the environment of about 36 DEG C, this is
Paper mill sludge intermediate products.
In stirred tank, above-mentioned paper mill sludge intermediate products are pressed with composite polymer latex material
The ratio batch mixing of 2: 2.5, i.e. paper mill sludge intermediate products about 200kg, composite polymer latex
250kg, described composite polymer latex material ratio is: silicone acrylic emulsion 1%；Styrene-acrylic emulsion
20%；EVA emulsion 9%；Polyvinyl acetate emulsion 5%；Polyacrylate dispersion 50%；
Styrene-butadiene emulsion 5%；Vinegar benzene emulsion 5%；Polyaminoester emulsion 5%；Add potassium methyl silicate 5kg,
Stir, load in material barrel and seal, seal in the environment of 30 DEG C and deposit 16 days.
The composite high-molecular waterproof emulsifiable paste color of series produced according to the present invention: milky white～
Lycoperdon polymorphum Vitt；Density: 0.8～1.5g/cm3；Viscosity: 1000～4000CPS (23 DEG C)；Solid contains
Amount: 20～50%；Minimum film formation temperature: 0 DEG C；PH:5.5～9.0.
The fundamental performance parameter of the dry solidification layer of product of the present invention is described as: have ventilative hydrophobic
Property micropore；Heat resistant (180 DEG C × 24 hours × 100)；Low temperature resistant freezing (-30 DEG C × 24
Hour × 365)；Ultraviolet-resistant aging (energy of light source 365nm and 254nm；Irradiation distance
1～2cm；Light source power 16W；Irradiation time 24 hours × 200)；Suppleness or ductility
(30～300%)；Water absorption rate 0.3～3%；Permeable optimal pressure 0.3Mpa × 30min (coating
Thickness～1mm)；Rate of expanding with heat and contract with cold～0.5%；
After the product drying solidification of the present invention color of coating be light brown to brown, but the present invention
Product can mix with various pigment, formed series relevant colors product.
The composite high-molecular waterproof emulsifiable paste of series produced according to the present invention can use scrubbing water
All source waters in addition are diluted to any ratio being suitable to construction.
The composite high-molecular waterproof emulsifiable paste of series produced according to the present invention, can be used for serving as
Building top waterproof layer, inner-outer wall waterproof sub-base layer, external wall waterproof layer, indoor waterproof sub-base layer,
Any work needing water-proofing treatment such as lavatory, kitchen waterproof sub-base layer, waterproofing performance of roads basal layer
Face.
Product of the present invention can bond (such as water with nearly all metal with non-metal material surface
Mud, cement brick, clay brick, Ceramic Tiles, timber, glass, high molecule plastic, metal material
Deng).And brushing, round brush can be used, spray and smear construction technology.
The composite bactericidal preservative that the present invention uses mainly kills some harmful bacteria, prevents material
Corrupt.But result of study display is after step B completes, the coarse fiber sense of material becomes
The paste sense of smooth exquisiteness, curing of coating is dried, and the physical and chemical performance having had been provided with basis refers to
Mark.Can only speculate accordingly in mechanism: sealed fermenting (or ageing) some probiotics of process or enzyme
Being retained, occur biochemical reaction to make chemical bond rupture in fiber modified, natural polymer drops
Solving, physical and chemical performance significantly changes, and material is bonded into film properties to be improved.But the suppleness of film forming,
Intensity and the main performance index such as waterproof are not ideal enough, so also needing to and water-soluble composite high molecular polymer
Emulsion compound use is to reaching preferable intensity and suppleness, and smooth construction surface can be direct
Construction.
Construction technology of the present invention is: cleaned up by work surface, brushing, round brush, sprays and is coated with
Smear the water dilution of this product, make waterproof emulsifiable paste penetrate into work surface, with substrate strong bonded.
After basic unit's dry solidification, it is possible to use any viscosity or the construction of former cream, until forming reasonably thick
The dry solidification layer of degree.The construction of each layer, will be carried out after preceding layer dry solidification.Thick
Degree does not has strict restriction, but combination property becomes non-linear direct ratio with thickness.Examine for cost performance
Consider, it is proposed that dry solidification layer controls 0.6～3mm.If construction surface is rough and uneven in surface, can make should
Power is uneven, easily causes the be full of cracks of solidification coating, the water resistance of impact local.For so
Work surface, should first significantly hole and crack be repaired before construction, then dilute by appropriateness
This product bonding layer of glass net (all can the using of all size size, but aperture released
Net performance is more preferably), then at online brushing, round brush, to spray and smear this product the most required
Thickness.
Product processes of the present invention do not has liquid and waste slag produced generation, the most in a large number to environment and
The gas of human hazard produces.Reaction temperature is in the region of gentleness, so process energy consumption compares
Little.Technological reaction pH is positioned at weak acid to weak base region, so the corrosion to equipment is the least, right
Operator are also without threatening.Without control class material in reaction raw materials, also without inflammable and explosive class chemistry
Dangerous materials, safety in production is ensured.
Claims (7)
1. the composite water-proof emulsifiable paste containing paper mill sludge, it is characterised in that waterproof emulsifiable paste
Component comprises part by weight 16～the paper mill sludge of 66%.
Composite water-proof emulsifiable paste containing paper mill sludge the most according to claim 1, preparation
Method comprises the following steps:
A, being placed in reaction vessel by paper mill sludge, stir after adding equivalent water, addition is made
Paper mud gross weight 0.1～the sterilization antiseptic of 0.5%, be heated uniformly under stirring
30～70 DEG C, isothermal reaction 6～24 hours, then it is cooled to room temperature；
B, with 1: 1～10 ammonia adjust material pH be 7.5～9.0, be subsequently placed in 4～40 DEG C
Environment in seal deposit 3～90 days；
Paper mill sludge intermediate products after the process of C, step B and water-soluble composite high molecular polymer emulsion thing
Expect to mix in the ratio of 2: 0.5～4, add organosilicate defoamer 0.15～1.5%, stir
Mix uniformly, load in material barrel and seal, seal in the environment of 4～40 DEG C and deposit 3～90 days.
Contain the preparation side of the composite water-proof emulsifiable paste of paper mill sludge the most according to claim 2
Method, it is characterised in that described in step A, sterilization antiseptic is chosen as: 2-methyl-4-isothiazoline
-3-ketone, Nordes C15, Nordes EPW, Dao Weixier-75,1,2-benzisothiazole
-3-ketone one of which or several compound.
Contain the preparation side of the composite water-proof emulsifiable paste of paper mill sludge the most according to claim 3
Method, it is characterised in that described composite bactericidal preservative weight percent composition is chosen as: 2-methyl
-4-isothiazoline-3-ketone is 15%, and Nordes C15 is 25%, and Nordes EPW is 30%,
Dao Weixier-75 is 20%, and BIT is 10%；
Or
MIT is 10%, and Nordes C15 is 20%, Nordes
EPW is 20%, and Dao Weixier-75 is 30%, and BIT is 20%；
Or
MIT is 10%, and Nordes C15 is 10%, Nordes
EPW is 30%, and Dao Weixier-75 is 30%, and BIT is 20%；
Or
MIT is 10%, and Nordes C15 is 10%, Nordes
EPW is 30%, and Dao Weixier-75 is 35%, and BIT is 15%；
Or
MIT is 5%, and Nordes C15 is 10%, Nordes EPW
Being 15%, Dao Weixier-75 is 30%, and BIT is 40%；
Or
MIT is 30%, and Nordes C15 is 5%, Nordes EPW
Being 30%, Dao Weixier-75 is 30%, and BIT is 5%；
Or
MIT is 28%, and Nordes C17 is 5%, Nordes EPW
Being 27%, Dao Weixier-75 is 30%, and BIT is 8%.
Contain the preparation side of the composite water-proof emulsifiable paste of paper mill sludge the most according to claim 2
Method, it is characterised in that the water-soluble composite high molecular polymer emulsion weight of material percentage group described in step C
Become: silicone acrylic emulsion 1～5%；Styrene-acrylic emulsion 10～50%；EVA emulsion 5～30%；Poly-
Acetate emulsion 1～10%；Polyacrylate dispersion 5～50%；Styrene-butadiene emulsion 5～20%；
Vinegar benzene emulsion 5～15%；Polyaminoester emulsion 5～10%.
Contain the preparation side of the composite water-proof emulsifiable paste of paper mill sludge the most according to claim 5
Method, it is characterised in that the water-soluble composite high molecular polymer emulsion weight of material percentage group described in step C
Become: silicone acrylic emulsion 3%, styrene-acrylic emulsion 10%, EVA emulsion 20%, polyvinyl acetate breast
Liquid 2%, polyacrylate dispersion 40%, styrene-butadiene emulsion 10%, vinegar benzene emulsion 10%, poly-ammonia
Ester emulsion 5%；
Or
Silicone acrylic emulsion 5%, styrene-acrylic emulsion 30%, EVA emulsion 5%, polyvinyl acetate emulsion
10%, polyacrylate dispersion 20%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 15%, polyurethane
Emulsion 10%；
Or
Silicone acrylic emulsion 1%, styrene-acrylic emulsion 40%, EVA emulsion 15%, polyvinyl acetate emulsion
6%, polyacrylate dispersion 10%, styrene-butadiene emulsion 15%, vinegar benzene emulsion 5%, polyurethane breast
Liquid 8%；
Or
Silicone acrylic emulsion 5%, styrene-acrylic emulsion 45%, EVA emulsion 10%, polyvinyl acetate emulsion
5%, polyacrylate dispersion 15%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 10%, polyurethane breast
Liquid 5%；
Or
Silicone acrylic emulsion 3%, styrene-acrylic emulsion 20%, EVA emulsion 30%, polyvinyl acetate emulsion
2%, polyacrylate dispersion 30%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 5%, polyurethane breast
Liquid 5%；
Or
Silicone acrylic emulsion 2%；Styrene-acrylic emulsion 30%；EVA emulsion 15%；Polyvinyl acetate emulsion
3%；Polyacrylate dispersion 30%；Styrene-butadiene emulsion 10%；Vinegar benzene emulsion 5%；Polyurethane breast
Liquid 5%；
Or
Silicone acrylic emulsion 1%, styrene-acrylic emulsion 20%, EVA emulsion 9%, polyvinyl acetate emulsion
5%, polyacrylate dispersion 50%, styrene-butadiene emulsion 5%, vinegar benzene emulsion 5%, polyurethane breast
Liquid 5%.
Contain the preparation side of the composite water-proof emulsifiable paste of paper mill sludge the most according to claim 2
Method, it is characterised in that the organosilicate defoamer described in step C be sodium methyl silicate or/and
Potassium methyl silicate.
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|---|---|---|---|---|
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| CN101368017A (en) * | 2008-08-29 | 2009-02-18 | 北京盖雅技术中心有限公司 | Formulating method for exterior wall latex paint with papermaking sewage sludge as filling material |
| CN104418579A (en) * | 2013-08-30 | 2015-03-18 | 宁波天劲新材料有限公司 | High-strength inorganic composite plate manufactured from paper-making sludge and manufacturing method of high-strength inorganic composite plate |
| CN104863012A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Method of preparing environment friendly paper coating from paper mill sludge |
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2016
- 2016-07-20 CN CN201610573092.1A patent/CN106009936A/en active Pending
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|---|---|---|---|---|
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN101368017A (en) * | 2008-08-29 | 2009-02-18 | 北京盖雅技术中心有限公司 | Formulating method for exterior wall latex paint with papermaking sewage sludge as filling material |
| CN104418579A (en) * | 2013-08-30 | 2015-03-18 | 宁波天劲新材料有限公司 | High-strength inorganic composite plate manufactured from paper-making sludge and manufacturing method of high-strength inorganic composite plate |
| CN104863012A (en) * | 2015-06-16 | 2015-08-26 | 华东理工大学 | Method of preparing environment friendly paper coating from paper mill sludge |
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