CN106008815A - Preparation method of light-colored terpene resin - Google Patents
Preparation method of light-colored terpene resin Download PDFInfo
- Publication number
- CN106008815A CN106008815A CN201610477417.6A CN201610477417A CN106008815A CN 106008815 A CN106008815 A CN 106008815A CN 201610477417 A CN201610477417 A CN 201610477417A CN 106008815 A CN106008815 A CN 106008815A
- Authority
- CN
- China
- Prior art keywords
- terpene resin
- preparation
- weight
- light
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011347 resin Substances 0.000 title claims abstract description 20
- 229920005989 resin Polymers 0.000 title claims abstract description 20
- 150000003505 terpenes Chemical class 0.000 title claims abstract description 20
- 235000007586 terpenes Nutrition 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 17
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 8
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 6
- 238000009413 insulation Methods 0.000 claims description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 1
- 239000001739 pinus spp. Substances 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 229940036248 turpentine Drugs 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000011505 plaster Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- -1 thermosol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
- C08F232/08—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having condensed rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a preparation method of light-colored terpene resin, and belongs to the technical field of rosin deep processing. The preparation method comprises the steps that 25-30 parts by weight of methylbenzene, 30-35 parts by weight of turpentine, 0.1-0.2 part by weight of aluminum trichloride anhydrous, 0.2-0.3 part by weight of chlorotrifluoroethylene and 0.05-0.1 part by weight of tetrafluoroethylene are put into a reaction kettle to be mixed to be uniform, heat preservation reacting is conducted for 0.5 h to 1 h at 0 DEG C to 5 DEG C, and distilling is conducted. According to the preparation method of the light-colored terpene resin, on the basis of a preparation method of existing terpene resin, due to the fact that a certain proportion of chlorotrifluoroethylene and 0.05-0.1 part of tetrafluoroethylene are added in the preparation process of the light-colored terpene resin, the color of the prepared product terpene resin becomes lighter.
Description
Technical field
The invention belongs to Colophonium deep process technology field, the preparation method of a kind of light color terpene resin.
Background technology
Terpene resin is some thermoplastic block copolymers, there is low abnormal smells from the patient, high rigidity, high adhesion force, non-oxidizability and Heat stability is good, the compatibility and the advantage such as dissolubility is good, SIS system of EVA system especially, the thermosols such as SBS system have the excellent compatibility and weatherability and Efficient Adhesive Promotion, it is widely used in adhesive, solid, two-sided tape, solvent-borne type glue, bookbinding version, color fills, adhesive plaster, alkene adhesive plaster, kraft paper card adhesive plaster, tapes labels, carpenter's glue, pressure sensitive adhesive, thermosol, fluid sealant, paint and the aspect such as ink and other polymer modification agent.But it is deeper to there is also some very important shortcomings, i.e. color.
Summary of the invention
The present invention provides the preparation method of a kind of light color terpene resin, and the terpene resin that the method prepares has light-colored advantage.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
By weight, 25 parts～30 parts of toluene, 30 parts～35 parts of Oleum Terebinthinaes, 0.1 part～0.2 part of aluminum trichloride (anhydrous), 0.2 part～0.3 part of CTFE, 0.05 part～0.1 part of tetrafluoroethene are put into mix homogeneously in reactor, and at 0 DEG C～5 DEG C insulation reaction 0.5 hour～1 hour, then distill.
Owing to using technique scheme, there is advantages that
The present invention is on the basis of the preparation method of existing terpene resin, by adding a certain proportion of CTFE, tetrafluoroethene in its preparation process so that the product terpene resin color that the present invention prepares becomes more shallow.
Detailed description of the invention
Below in conjunction with instantiation, the invention will be further described:
The method of embodiment 1--making light color terpene resin:
25kg toluene, 30kg Oleum Terebinthinae, 0.2kg aluminum trichloride (anhydrous), 0.3kg CTFE, 0.05kg tetrafluoroethene are put into mix homogeneously in reactor, and insulation reaction 1 hour at 0 DEG C, then distills.
Ghana's color number of the product terpene resin that the present embodiment prepares is 1.
The method of embodiment 2--making light color terpene resin:
30kg toluene, 32kg Oleum Terebinthinae, 0.15kg aluminum trichloride (anhydrous), 0.2kg CTFE, 0.1kg tetrafluoroethene are put into mix homogeneously in reactor, and insulation reaction 0.5 hour at 5 DEG C, then distills.
Ghana's color number of the product terpene resin that the present embodiment prepares is 1.
The method of embodiment 3--making light color terpene resin:
26kg toluene, 35kg Oleum Terebinthinae, 0.1kg aluminum trichloride (anhydrous), 0.25kg CTFE, 0.08kg tetrafluoroethene are put into mix homogeneously in reactor, and insulation reaction 0.5 hour at 3 DEG C, then distills.
Ghana's color number of the product terpene resin that the present embodiment prepares is 1.
Claims (1)
1. the preparation method of a light terpene resin, it is characterised in that comprise the following steps:
By weight, 25 parts～30 parts of toluene, 30 parts～35 parts of Oleum Terebinthinaes, 0.1 part～0.2 part of aluminum trichloride (anhydrous), 0.2 part～0.3 part of CTFE, 0.05 part～0.1 part of tetrafluoroethene are put into mix homogeneously in reactor, and at 0 DEG C～5 DEG C insulation reaction 0.5 hour～1 hour, then distill.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610477417.6A CN106008815A (en) | 2016-06-27 | 2016-06-27 | Preparation method of light-colored terpene resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610477417.6A CN106008815A (en) | 2016-06-27 | 2016-06-27 | Preparation method of light-colored terpene resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106008815A true CN106008815A (en) | 2016-10-12 |
Family
ID=57084350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610477417.6A Pending CN106008815A (en) | 2016-06-27 | 2016-06-27 | Preparation method of light-colored terpene resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106008815A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919181A (en) * | 1973-10-11 | 1975-11-11 | Schenectady Chemical | Preparation of hydrocarbon resins using zirconium tetrachloride |
| US4081425A (en) * | 1975-11-21 | 1978-03-28 | Hoechst Aktiengesellschaft | Process for the manufacture of light color terpenephenols |
| CN1644595A (en) * | 2004-01-23 | 2005-07-27 | 大金工业株式会社 | Production of pte polymer |
| CN102382220A (en) * | 2011-08-30 | 2012-03-21 | 广东华林化工有限公司 | Ultralight-colored polyterprene resin production process |
| CN104877076A (en) * | 2015-05-19 | 2015-09-02 | 广西众昌树脂有限公司 | Preparation method of colorless terpene resin |
-
2016
- 2016-06-27 CN CN201610477417.6A patent/CN106008815A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919181A (en) * | 1973-10-11 | 1975-11-11 | Schenectady Chemical | Preparation of hydrocarbon resins using zirconium tetrachloride |
| US4081425A (en) * | 1975-11-21 | 1978-03-28 | Hoechst Aktiengesellschaft | Process for the manufacture of light color terpenephenols |
| CN1644595A (en) * | 2004-01-23 | 2005-07-27 | 大金工业株式会社 | Production of pte polymer |
| CN102382220A (en) * | 2011-08-30 | 2012-03-21 | 广东华林化工有限公司 | Ultralight-colored polyterprene resin production process |
| CN104877076A (en) * | 2015-05-19 | 2015-09-02 | 广西众昌树脂有限公司 | Preparation method of colorless terpene resin |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161012 |