CN104963218A - Printing adhesive and preparing method thereof - Google Patents
Printing adhesive and preparing method thereof Download PDFInfo
- Publication number
- CN104963218A CN104963218A CN201510358864.5A CN201510358864A CN104963218A CN 104963218 A CN104963218 A CN 104963218A CN 201510358864 A CN201510358864 A CN 201510358864A CN 104963218 A CN104963218 A CN 104963218A
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- CN
- China
- Prior art keywords
- adhesive
- preparation
- printing adhesive
- parts
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 45
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 44
- 238000007639 printing Methods 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 16
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 claims abstract description 13
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 11
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims description 24
- 230000005855 radiation Effects 0.000 claims description 14
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000004945 emulsification Methods 0.000 claims description 7
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 abstract description 23
- 230000000694 effects Effects 0.000 abstract description 4
- 229920000642 polymer Polymers 0.000 abstract description 3
- 150000003755 zirconium compounds Chemical class 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- HOHPOKYCMNKQJS-UHFFFAOYSA-N [P].[Br] Chemical class [P].[Br] HOHPOKYCMNKQJS-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a printing adhesive and a preparing method thereof. The adhesive comprises, by weight, 200-320 parts of butyl ester, 50-100 parts of styrene, 5-10 parts of crylic acid, 5-10 parts of cross-linking agent, 1-10 parts of zirconium sulfate solution, and 500-700 parts of water. The invention further relates to the preparing method of the printing adhesive. According to the method, zirconium sulfate is introduced into a high-molecular polymer structure to prepare the printing adhesive, zirconium compounds exist in most efficient fire retardants and are closely combined with other components of the adhesive, and synergistic effect can be generated between zirconium compounds and other components of the adhesive so that the flame-retarding effect of the adhesive can be more remarkable. The adhesive has high fire resistance, good hand feel, high fullness and high color fastness.
Description
Technical field
The invention belongs to chemical field, particularly, relate to a kind of printing adhesive and preparation method thereof.
Background technology
Fire-retardant science and technology is produced and the needs of life to adapt to social safety, and fire preventing occurs, protection people's lives and properties and a science growing up.Fire retardant is the application of flame-retarded technology in real life, and it is a kind of special auxiliary chemicals for improving flammable combustible material combustibility, is widely used in the fire-retardant processing of all kinds of finishing material.Material after fire retardant processing, when being subject to extraneous burning things which may cause a fire disaster and attacking, effectively can stop, delay or stop flame transmission, thus reach fire-retardant effect.
Along with the enhancing day by day of people's environmental protection, safety, health perception, countries in the world start using environment friendly flame retardant as the emphasis researched and developed and apply, and have achieved certain achievement.Along with the development of Chinese synthetic material industry and the continuous expansion of Application Areas, fire retardant has wide market prospects in the every field such as chemical building material, electronic apparatus, communications and transportation, space flight and aviation, household furniture, interior decoration, clothing, food, lodging and transportion--basic necessities of life.In addition, the field such as coalfield, oil field, forest extinguishing also promotes that China is fire-retardant, extinguishing chemical is produced and developed faster.China fire retardant developed into the second largest polymer modification additive being only second to plasticizer, current production capacity 200,000 about t/a, year output between 150,000-17 ten thousand t, year consumption figure 200,000 about t.Insufficient section is mainly from the U.S. and Israel's import, and the principal item of import is organic bromine and halogen-phosphorus flame retardant.Family of fire retardant factory more than 60 of China, can produce more than 50 and plant product, and be mainly bromine phosphorus series, wherein bromide fire retardant is most important series, accounts for 30% of Chinese organic fire-retardant.
The kind of domestic fire retardant and consumption figure are still based on organic fire-retardant, and inorganic combustion inhibitor production and consumption amount is also less, but the development in recent years impetus is better, and market potential is larger.Although halogenated flame retardant the most frequently used in fire retardant has the unrivaled high efficiency of other fire retardant series, it is very important to the harm of environment and people.Environmental issue is the focus that auxiliary agent development and application business pays close attention to, so adjusting the product structure of fire retardant both at home and abroad always, strengthens the exploitation of Efficient environment-friendlyflame flame retardant.
Summary of the invention
For defect of the prior art, the object of this invention is to provide a kind of printing adhesive and preparation method thereof.
The present invention is achieved by the following technical solutions:
First aspect, the present invention relates to a kind of printing adhesive, and described adhesive comprises each component of following parts by weight:
Preferably, described adhesive comprises each component of following parts by weight:
Preferably, described crosslinking agent is silane coupler.
Second aspect, the invention still further relates to the preparation method of aforesaid printing adhesive, and described method comprises the steps:
Step 1, preparation zirconium sulfate solution, its consumption is the 0.2%-1% of monomer consumption, adds in each component pre-emulsification process;
Step 2, by described butyl ester, styrene, acrylic acid, crosslinking agent, water by described parts by weight mixing, the Rate Dispersion turned with 1200-2000, takes out;
Step 3, with Co-60 radiation source, carries out radiation-induced emulsion polymerization;
Step 4, takes out, adjust pH, filters, discharging.
Preferably, in step 1, the mass percent concentration of described zirconium sulfate solution is 10-30%.
Preferably, in step 2, described jitter time is 20-40 minute.
Preferably, in step 3, described irradiation time is 2-5h.
Preferably, in step 3, described polymerization time is 2-4 hour.
Preferably, in step 4, described pH value is 6.5-7.5.
Compared with prior art, the present invention has following beneficial effect:
1, adhesive of the present invention has good fire resistance, feel, richness and COLOR FASTNESS.
2, the present invention is a kind of to introduce the preparation method that zirconium sulfate prepares printing adhesive in high molecular polymer structure, zirconium-containing compound exists in efficient fire retardant more, itself and other components in close of adhesive combine, and the meeting between them produces cooperative effect and then the flame retardant effect of adhesive can be made more obvious.
What 3, this project was selected is zirconium sulfate, and mixed by certain technique and macromolecule pre-emulsion and be dispersed into Uniform Latex shape, make the flame retardant effect of macromolecule printing adhesive significantly improve after radioreaction, soft, washability is also improved.
4, the inventive method additionally uses Co-60 radiotechnology, and each component disperses of adhesive is evenly irradiated by Co-60 radioactive element afterwards, and each component can be made fully effectively to condense together.
5, product of the present invention has good characteristic, and its preparation methods steps is simple, and repeatability is high, and efficiency is high, and cost is low.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art and understand the present invention further, but not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, some distortion and improvement can also be made.These all belong to protection scope of the present invention.
The crosslinking agent that following examples relate to is silane coupler.
embodiment 1
The present embodiment relates to a kind of printing adhesive and preparation method thereof, and described adhesive comprises each component of following parts by weight:
Described method comprises the steps:
Step 1, preparation zirconium sulfate solution, its consumption is the 0.2%-1% of monomer consumption, adds in each component pre-emulsification process;
Step 2, by described butyl ester, styrene, acrylic acid, crosslinking agent, water by described parts by weight mixing, dispersion, takes out;
Step 3, with Co-60 radiation source, carries out radiation-induced emulsion polymerization;
Step 4, takes out after 3 hours, adjust pH, filters, discharging.
embodiment 2
The present embodiment relates to a kind of printing adhesive and preparation method thereof, and described adhesive comprises each component of following parts by weight:
Described method comprises the steps:
Step 1, preparation zirconium sulfate solution, its consumption is the 0.2%-1% of monomer consumption, adds in each component pre-emulsification process;
Step 2, by described butyl ester, styrene, acrylic acid, crosslinking agent, water by described parts by weight mixing, dispersion, takes out;
Step 3, with Co-60 radiation source, carries out radiation-induced emulsion polymerization;
Step 4, takes out after 3 hours, adjust pH, filters, discharging.
embodiment 3
The present embodiment relates to a kind of printing adhesive and preparation method thereof, and described adhesive comprises each component of following parts by weight:
Described method comprises the steps:
Step 1, preparation zirconium sulfate solution, its consumption is the 0.2%-1% of monomer consumption, adds in each component pre-emulsification process;
Step 2, by described butyl ester, styrene, acrylic acid, crosslinking agent, water by described parts by weight mixing, dispersion, takes out;
Step 3, with Co-60 radiation source, carries out radiation-induced emulsion polymerization;
Step 4, takes out after 3 hours, adjust pH, filters, discharging.
embodiment 4
The present embodiment relates to a kind of printing adhesive and preparation method thereof, and described adhesive comprises each component of following parts by weight:
Described method comprises the steps:
Step 1, preparation zirconium sulfate solution, its consumption is the 0.2%-1% of monomer consumption, adds in each component pre-emulsification process;
Step 2, by described butyl ester, styrene, acrylic acid, crosslinking agent, water by described parts by weight mixing, dispersion, takes out;
Step 3, with Co-60 radiation source, carries out radiation-induced emulsion polymerization;
Step 4, takes out after 3 hours, adjust pH, filters, discharging.
embodiment 5
The present embodiment relates to a kind of printing adhesive and preparation method thereof, and described adhesive comprises each component of following parts by weight:
Described method comprises the steps:
Step 1, preparation zirconium sulfate solution, its consumption is the 0.2%-1% of monomer consumption, adds in each component pre-emulsification process;
Step 2, by described butyl ester, styrene, acrylic acid, crosslinking agent, water by described parts by weight mixing, dispersion, takes out;
Step 3, with Co-60 radiation source, carries out radiation-induced emulsion polymerization;
Step 4, takes out after 3 hours, adjust pH, filters, discharging.
In sum, the adhesive prepared by above-described embodiment 1-3, after tested, the performance parameter of its product of the present invention is as follows: COLOR FASTNESS: unlubricated friction 4 grades, wets and rubs 3 grades; Contrast UL-94 testing standard: reach FV-0.
The display of above-mentioned test result, final sample has obvious anti-flammability, high crock fastness, has good feel simultaneously, has more excellent performance to adhesive agent emulsion than ever.
Above specific embodiments of the invention are described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, those skilled in the art can make various distortion or amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (9)
1. a printing adhesive, is characterized in that, described adhesive comprises each component of following parts by weight:
2. printing adhesive as claimed in claim 1, it is characterized in that, described adhesive comprises each component of following parts by weight:
3. printing adhesive as claimed in claim 1 or 2, it is characterized in that, described crosslinking agent is silane coupler.
4. a preparation method for printing adhesive as claimed in claim 1, is characterized in that, described method comprises the steps:
Step 1, preparation zirconium sulfate solution, its consumption is the 0.2%-1% of monomer consumption, adds in each component pre-emulsification process;
Step 2, by described butyl ester, styrene, acrylic acid, crosslinking agent, water by described parts by weight mixing, the Rate Dispersion turned with 1200-2000, takes out;
Step 3, with Co-60 radiation source, carries out radiation-induced emulsion polymerization;
Step 4, takes out, adjust pH, filters, discharging.
5. the preparation method of printing adhesive as claimed in claim 4, it is characterized in that, in step 1, the mass percent concentration of described zirconium sulfate solution is 10-30%.
6. the preparation method of printing adhesive as claimed in claim 4, it is characterized in that, in step 2, described jitter time is 20-40 minute.
7. the preparation method of printing adhesive as claimed in claim 4, it is characterized in that, in step 3, described irradiation time is 2-5h.
8. the preparation method of printing adhesive as claimed in claim 4, it is characterized in that, in step 3, described polymerization time is 2-4 hour.
9. the preparation method of printing adhesive as claimed in claim 4, it is characterized in that, in step 4, described pH value is 6.5-7.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510358864.5A CN104963218A (en) | 2015-06-25 | 2015-06-25 | Printing adhesive and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510358864.5A CN104963218A (en) | 2015-06-25 | 2015-06-25 | Printing adhesive and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104963218A true CN104963218A (en) | 2015-10-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510358864.5A Pending CN104963218A (en) | 2015-06-25 | 2015-06-25 | Printing adhesive and preparing method thereof |
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| Country | Link |
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| CN (1) | CN104963218A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018053828A1 (en) * | 2016-09-26 | 2018-03-29 | 于晶晶 | Adhesive agent and preparation method therefor |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1240509A (en) * | 1967-12-22 | 1971-07-28 | Basf Ag | Reducing the dirt adsorption of binder-containing pigment dyeings and prints on fibrous materials |
| WO2002011994A1 (en) * | 2000-08-08 | 2002-02-14 | 3M Innovative Properties Company | Ink receptive compositions and articles for image transfer |
| CN101240101A (en) * | 2007-09-30 | 2008-08-13 | 合肥安大天辐新材料有限公司 | Preparation method and application of ketone hydrazine cross-linked acrylate-polyurethane composite textile emulsion |
| CN102108110A (en) * | 2010-12-31 | 2011-06-29 | 金华金龙助剂厂 | Method for preparing acrylate printing adhesive |
| CN103103820A (en) * | 2012-12-19 | 2013-05-15 | 上海奇想青晨新材料科技股份有限公司 | Polyacrylate binder for pigment printing and preparation method of polyacrylate binder |
| CN103526599A (en) * | 2013-10-25 | 2014-01-22 | 合肥聚合辐化技术有限公司 | High-brilliance printing adhesive and preparation method thereof |
-
2015
- 2015-06-25 CN CN201510358864.5A patent/CN104963218A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1240509A (en) * | 1967-12-22 | 1971-07-28 | Basf Ag | Reducing the dirt adsorption of binder-containing pigment dyeings and prints on fibrous materials |
| WO2002011994A1 (en) * | 2000-08-08 | 2002-02-14 | 3M Innovative Properties Company | Ink receptive compositions and articles for image transfer |
| CN101240101A (en) * | 2007-09-30 | 2008-08-13 | 合肥安大天辐新材料有限公司 | Preparation method and application of ketone hydrazine cross-linked acrylate-polyurethane composite textile emulsion |
| CN102108110A (en) * | 2010-12-31 | 2011-06-29 | 金华金龙助剂厂 | Method for preparing acrylate printing adhesive |
| CN103103820A (en) * | 2012-12-19 | 2013-05-15 | 上海奇想青晨新材料科技股份有限公司 | Polyacrylate binder for pigment printing and preparation method of polyacrylate binder |
| CN103526599A (en) * | 2013-10-25 | 2014-01-22 | 合肥聚合辐化技术有限公司 | High-brilliance printing adhesive and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018053828A1 (en) * | 2016-09-26 | 2018-03-29 | 于晶晶 | Adhesive agent and preparation method therefor |
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Application publication date: 20151007 |