CN104817802A - High-traction rubber sole and preparation method thereof - Google Patents
High-traction rubber sole and preparation method thereof Download PDFInfo
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- CN104817802A CN104817802A CN201510166165.0A CN201510166165A CN104817802A CN 104817802 A CN104817802 A CN 104817802A CN 201510166165 A CN201510166165 A CN 201510166165A CN 104817802 A CN104817802 A CN 104817802A
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- rubber
- high grip
- sulphur
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 59
- 239000005060 rubber Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- -1 polyethylene Polymers 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000005864 Sulphur Substances 0.000 claims abstract description 16
- 229920005557 bromobutyl Polymers 0.000 claims abstract description 15
- 238000004073 vulcanization Methods 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000006229 carbon black Substances 0.000 claims abstract description 13
- 239000002480 mineral oil Substances 0.000 claims abstract description 13
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 13
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 12
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 10
- 239000004698 Polyethylene Substances 0.000 claims abstract description 10
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 10
- 229920001194 natural rubber Polymers 0.000 claims abstract description 10
- 229920000573 polyethylene Polymers 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 22
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 20
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 11
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 11
- 230000003712 anti-aging effect Effects 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 229920000636 poly(norbornene) polymer Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 239000001993 wax Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 description 5
- 238000004513 sizing Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011112 process operation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention relates to a shoe sole, and provides a high-traction rubber sole and a preparation method thereof. The rubber sole comprises the following raw materials of natural rubber, polynorbornene rubber, brominated butyl rubber, mineral oil, white carbon black, an antioxidant, polyethylene glycol, a silane coupling agent, polyethylene wax, zinc oxide, sulphur, a vulcanizing accelerator. The method comprises the following steps: adding the rubber compound besides sulphur and the vulcanizing accelerator in an internal mixer, discharging the rubber at 115-120 DEG C, placing for 24 hours under room temperature, then mixing on a double-roller open mill, adding the sulphur and the vulcanizing accelerator according to accurate weight, uniformly mixing and extruding with uniform sheet shape, and cutting the materials into a sole shape and placing into a rubber shoe sole for vulcanization molding to obtain the high-traction rubber sole.
Description
Technical field
The invention belongs to organic high molecular compound technical field, particularly a kind of high grip rubber soles and preparation method thereof.
Background technology
Poly-norbornene rubber, maintains twin nuclei, all interfixes between every two adjacent carbonss, and the movable difficulty of the carbon atom in structural unit, therefore has higher second-order transition temperature and heat decomposition temperature.The molecular structure of poly-norbornene rubber is the macromole that some segments dependence chemical bond linkage is got up, and mutually tangle between macromolecular chain, the existence of side chain exacerbates mutual entanglement.Certain deformation is produced under external periodic force effect, superpolymer is made to need to overcome the friction resistance between a part of molecular chain at stretching-relax cycle owing to tangling between molecular chain, this deformation lags behind in the process of stress, the form of heat energy is become by changes mechanical energy to dissipate, be presented as that there is high frictional coefficient further, i.e. high grip.
Summary of the invention
The object of the present invention is to provide and a kind ofly have that earth-grasping force is good, the high grip rubber soles of physical strength high, and prepare the preparation method of aforementioned high grip rubber soles.
For achieving the above object, the present invention adopts following technical scheme: a kind of high grip rubber soles, is prepared from by natural rubber, poly-norbornene rubber, brominated butyl rubber, white carbon black, mineral oil, zinc oxide, anti-aging agent, polyoxyethylene glycol, silane coupling agent, polyethylene wax, sulphur, vulcanization accelerator by constituent materials.
Wherein: each constituent materials of described a kind of high grip rubber soles is expressed as by weight:
Natural rubber 15 parts
Poly-norbornene rubber 40-55 parts
Brominated butyl rubber 8-15 parts
White carbon black 25-35 parts
25-35 parts, mineral oil
1-3 part, zinc oxide
1-2 part, anti-aging agent
Polyoxyethylene glycol 2-4 parts
Silane coupling agent 2-3 parts
Polyethylene wax 2-3 parts
2-3 parts, sulphur
Vulcanization accelerator 2-3 parts.
Further, the weight part of each constituent materials is preferably:
Natural rubber 15 parts
Poly-norbornene rubber 50 parts
Brominated butyl rubber 10 parts
White carbon black 30 parts
30 parts, mineral oil
1 part, zinc oxide
1.5 parts, anti-aging agent
Polyoxyethylene glycol 3 parts
Silane coupling agent 3 parts
Polyethylene wax 2 parts
2 parts, sulphur
Vulcanization accelerator 2.2 parts.
Wherein, described poly-norbornene rubber is that molecular weight is at 2,000,000-500 ten thousand daltonian poly-norbornene rubbers.
Wherein, the brominated amount of described brominated butyl rubber is greater than 1.5%.
A kind of preparation method preparing aforementioned high grip rubber soles, natural rubber is weighed according to formula rate, poly-norbornene rubber, brominated butyl rubber, white carbon black, mineral oil, zinc oxide, anti-aging agent, polyoxyethylene glycol, silane coupling agent, polyethylene wax, sulphur, vulcanization accelerator, by constituent materials except sulphur, Banbury mixer banburying put into by sizing material beyond vulcanization accelerator, 110-120 degree binder removal, room temperature places 24 hours, then mixing in two roller mill, and add the sulphur of precise, vulcanization accelerator, mixing evenly after, with uniform sheet slice, finally material is cut into sole shape and puts into rubber boots mould sulfidization molding, namely high grip rubber soles is obtained.
By taking preceding solution, the present invention has following beneficial effect:
1, the Be very effective of high grip rubber soles of the present invention, is embodied in anti-skid property of soles superior, and the on-slip coefficient of dry type, wet type, respectively up to 1.17,0.70, is obviously better than the Antiskid sole of prior art.This is because the distribution of trans base defines the high resistance of intermolecular movement in poly-norbornene rubber structure, there is high frictional coefficient.
2. the material of main part of high damping foam material of the present invention is poly-norbornene rubber, there is surface porosity, extremely strong adsorptive power, with hydrocarbon polymer, there is the features such as high affinity, a large amount of extending oil can be added and do not affect other physical property, improve process operation performance, and reduce production cost.
Embodiment
Now the present invention is further described in conjunction with specific embodiments.
Embodiment 1:
In the present embodiment, a kind of high grip rubber soles is made up of by weight following component:
Natural rubber 15 parts
Poly-norbornene rubber 50 parts
Brominated butyl rubber 10 parts
White carbon black 30 parts
30 parts, mineral oil
1 part, zinc oxide
1,010 1.5 parts, anti-aging agent
Polyoxyethylene glycol 3 parts
Silane coupling agent Si69 3 parts
Polyethylene wax 2 parts
2 parts, sulphur
Vulcanization accelerator 2.2 parts.
The sizing material of constituent materials except sulphur, vulcanization accelerator is put into Banbury mixer banburying, 119 degree of binder removals, room temperature places 24 hours, then mixing in two roller mill, and add sulphur, the vulcanization accelerator of precise, mixing evenly after, with uniform sheet slice, finally material is cut into sole shape and puts into rubber boots mould sulfidization molding, namely obtain high grip rubber soles.
The above-mentioned a kind of high grip rubber soles prepared, density 1.08g/cm
3, wear-resisting 143 mm of hardness A 62, DIN
3, tensile strength 18.2MPa, tear strength 75N/mm, on-slip coefficient dry type heel 1.04 half sole 1.01 level and smooth 1.17, on-slip coefficient wet type heel 0.66 half sole 0.66 level and smooth 0.70, on-slip coefficient wets ice face level and smooth 0.30.
Embodiment 2:
In the present embodiment, a kind of preparation method of high grip rubber soles is basic identical with the preparation method in embodiment 1, and difference is:
Poly-norbornene rubber 55 parts, brominated butyl rubber 8 parts, white carbon black 25 parts, 25 parts, mineral oil, polyoxyethylene glycol 2 parts, silane coupling agent 2 parts.
The above-mentioned a kind of high grip rubber soles prepared, density 1.06g/cm
3, wear-resisting 167 mm of hardness A 59, DIN
3, tensile strength 19.3MPa, tear strength 79N/mm, on-slip coefficient dry type heel 1.02 half sole 1.02 level and smooth 1.06, on-slip coefficient wet type heel 0.63 half sole 0.62 level and smooth 0.65, on-slip coefficient wets ice face level and smooth 0.24.
Embodiment 3:
In the present embodiment, a kind of preparation method of high grip rubber soles is basic identical with the preparation method in embodiment 1, and difference is:
Poly-norbornene rubber 45 parts, brominated butyl rubber 12 parts, white carbon black 35 parts, 35 parts, mineral oil, polyoxyethylene glycol 4 parts, silane coupling agent 3 parts; Control at 120 degree of binder removals.
The above-mentioned a kind of high grip rubber soles prepared, density 1.16g/cm
3, wear-resisting 231 mm of hardness A 69, DIN
3, tensile strength 15.8MPa, tear strength 57N/mm, on-slip coefficient dry type heel 0.96 half sole 0.91 level and smooth 0.96, on-slip coefficient wet type heel 0.49 half sole 0.48 level and smooth 0.52, on-slip coefficient wets ice face level and smooth 0.16.
Embodiment 4:
In the present embodiment, a kind of preparation method of high grip rubber soles is basic identical with the preparation method in embodiment 1, and difference is:
Poly-norbornene rubber 40 parts, brominated butyl rubber 15 parts, white carbon black 35 parts, 25 parts, mineral oil.
The above-mentioned a kind of high grip rubber soles prepared, density 1.19g/cm
3, wear-resisting 287 mm of hardness A 65, DIN
3, tensile strength 14 MPa, tear strength 49N/mm, on-slip coefficient dry type heel 0.83 half sole 0.84 level and smooth 0.88, on-slip coefficient wet type heel 0.47 half sole 0.48 level and smooth 0.49, on-slip coefficient wets ice face level and smooth 0.11.
After the data preparation of above-described embodiment 1 ~ 4, obtain as following table 1 (note: hardness adopts the test of GS-706G sclerometer, DIN is wear-resisting to be tested according to GB/T 9867-2008, tensile strength is tested according to GB/T 528-2009, tear strength tests right-angle tearing test piece according to GB/T 529-2008, and on-slip coefficient is tested according to TM144:2011):
The performance perameter synopsis of the high grip rubber soles of table 1, embodiment 1 ~ 4 preparation
In sum, the high grip rubber soles obtained according to the preparation method of high grip rubber soles of the present invention has that earth-grasping force is good, physical strength high, is particularly suitable for application in sole etc.
Above, be only the embodiment utilizing this origination techniques content, the modification that any those skilled in the art use this creation to do, change, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.
Claims (6)
1. a high grip rubber soles, it is characterized in that, be made up of following raw materials according: natural rubber, poly-norbornene rubber, brominated butyl rubber, white carbon black, mineral oil, zinc oxide, anti-aging agent, polyoxyethylene glycol, silane coupling agent, polyethylene wax, sulphur, vulcanization accelerator.
2. high grip rubber soles according to claim 1, it is characterized in that, the parts by weight of each raw material are:
Natural rubber 15 parts
Poly-norbornene rubber 40-55 parts
Brominated butyl rubber 8-15 parts
White carbon black 25-35 parts
25-35 parts, mineral oil
1-3 part, zinc oxide
1-2 part, anti-aging agent
Polyoxyethylene glycol 2-4 parts
Silane coupling agent 2-3 parts
Polyethylene wax 2-3 parts
2-3 parts, sulphur
Vulcanization accelerator 2-3 parts.
3. high grip rubber soles according to claim 2, it is characterized in that, the parts by weight of each raw material are:
Natural rubber 15 parts
Poly-norbornene rubber 50 parts
Brominated butyl rubber 10 parts
White carbon black 30 parts
30 parts, mineral oil
1 part, zinc oxide
1.5 parts, anti-aging agent
Polyoxyethylene glycol 3 parts
Silane coupling agent 3 parts
Polyethylene wax 2 parts
2 parts, sulphur
Vulcanization accelerator 2.2 parts.
4. high grip rubber soles according to claim 1 or 2, is characterized in that: poly-norbornene rubber is that molecular weight is at 2,000,000-500 ten thousand daltonian poly-norbornene rubbers.
5. high grip rubber soles according to claim 1 or 2, is characterized in that: the brominated amount of described brominated butyl rubber is greater than 1.5%.
6. prepare the preparation method of the arbitrary described high grip rubber soles of claim 1-5 for one kind, it is characterized in that: first by natural rubber, poly-norbornene rubber, brominated butyl rubber, white carbon black, mineral oil, zinc oxide, anti-aging agent, polyoxyethylene glycol, silane coupling agent, polyethylene wax puts into Banbury mixer banburying, 115-120 degree binder removal, room temperature places 24 hours, then mixing in two roller mill, and add the sulphur of precise, vulcanization accelerator, mixing evenly after, with uniform sheet slice, finally material is cut into sole shape and puts into rubber boots mould sulfidization molding, namely high grip rubber soles is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510166165.0A CN104817802B (en) | 2015-04-09 | 2015-04-09 | A kind of high grip rubber soles and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510166165.0A CN104817802B (en) | 2015-04-09 | 2015-04-09 | A kind of high grip rubber soles and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN104817802A true CN104817802A (en) | 2015-08-05 |
| CN104817802B CN104817802B (en) | 2017-09-12 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153488A (en) * | 2015-10-09 | 2015-12-16 | 际华三五三七制鞋有限责任公司 | Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof |
| CN105801948A (en) * | 2016-04-26 | 2016-07-27 | 茂泰(福建)鞋材有限公司 | Antiskid rubber composition for ice surface and production method thereof |
| CN106065098A (en) * | 2016-06-02 | 2016-11-02 | 泉州市晋科技术检测有限公司 | A kind of ski-proof snow land boots |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN102061017A (en) * | 2010-12-06 | 2011-05-18 | 安踏（中国）有限公司 | Rubber for sneaker sole and preparation method thereof |
| CN104163946A (en) * | 2014-07-16 | 2014-11-26 | 宁国中辰密封件有限公司 | Automobile shock absorber bushing |
| CN104277274A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Oil-proof antiskid rubber sole and preparation method thereof |
-
2015
- 2015-04-09 CN CN201510166165.0A patent/CN104817802B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101885865A (en) * | 2010-08-09 | 2010-11-17 | 中国皮革和制鞋工业研究院 | High shock-resistant, wear-resistant sport shoe sole material and manufacturing method thereof |
| CN102061017A (en) * | 2010-12-06 | 2011-05-18 | 安踏（中国）有限公司 | Rubber for sneaker sole and preparation method thereof |
| CN104163946A (en) * | 2014-07-16 | 2014-11-26 | 宁国中辰密封件有限公司 | Automobile shock absorber bushing |
| CN104277274A (en) * | 2014-08-07 | 2015-01-14 | 茂泰(福建)鞋材有限公司 | Oil-proof antiskid rubber sole and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 吴棣华等: "《弹性体手册（第二版）》", 31 January 2005, 中国石化出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153488A (en) * | 2015-10-09 | 2015-12-16 | 际华三五三七制鞋有限责任公司 | Intermittent steam vulcanization calendered and externally bonded earth yellow shoe sole rubber as well as preparation method and application thereof |
| CN105801948A (en) * | 2016-04-26 | 2016-07-27 | 茂泰(福建)鞋材有限公司 | Antiskid rubber composition for ice surface and production method thereof |
| CN106065098A (en) * | 2016-06-02 | 2016-11-02 | 泉州市晋科技术检测有限公司 | A kind of ski-proof snow land boots |
| CN106065098B (en) * | 2016-06-02 | 2018-01-30 | 泉州市晋科技术检测有限公司 | A kind of ski-proof snow land boots |
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| Publication number | Publication date |
|---|---|
| CN104817802B (en) | 2017-09-12 |
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Inventor after: Lu Xin Inventor after: Luo Xianfa Inventor after: Ding Sibo Inventor after: Liao Yibin Inventor after: Guo Cailian Inventor after: Lin Hexiang Inventor after: Lin Chouzhi Inventor after: Jin Xiaohong Inventor after: Zheng Rongda Inventor before: Ding Sibo Inventor before: Zheng Rongda Inventor before: Lu Xin Inventor before: Luo Xianfa Inventor before: Liao Yibin Inventor before: Guo Cailian Inventor before: Wang Yuling Inventor before: Zhou Xiaolan Inventor before: Lin Jiang Inventor before: Jin Xiaohong |
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