CN1040728A - 水溶性或水分散性农药颗粒 - Google Patents
水溶性或水分散性农药颗粒 Download PDFInfo
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- CN1040728A CN1040728A CN89106985A CN89106985A CN1040728A CN 1040728 A CN1040728 A CN 1040728A CN 89106985 A CN89106985 A CN 89106985A CN 89106985 A CN89106985 A CN 89106985A CN 1040728 A CN1040728 A CN 1040728A
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- Prior art keywords
- water
- amino
- composition
- methyl
- soluble
- Prior art date
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- 239000000575 pesticide Substances 0.000 title claims abstract description 19
- 239000008187 granular material Substances 0.000 title claims description 11
- 239000000203 mixture Substances 0.000 claims abstract description 68
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 37
- 239000011159 matrix material Substances 0.000 claims abstract description 27
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 25
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 49
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims description 40
- 239000002245 particle Substances 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 28
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 25
- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 23
- 239000003905 agrochemical Substances 0.000 claims description 22
- 229940095102 methyl benzoate Drugs 0.000 claims description 20
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 18
- 239000004202 carbamide Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 claims description 7
- 239000005583 Metribuzin Substances 0.000 claims description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- RRVIAQKBTUQODI-UHFFFAOYSA-N Methabenzthiazuron Chemical compound C1=CC=C2SC(N(C)C(=O)NC)=NC2=C1 RRVIAQKBTUQODI-UHFFFAOYSA-N 0.000 claims description 5
- 239000004549 water soluble granule Substances 0.000 claims description 5
- 239000005562 Glyphosate Substances 0.000 claims description 4
- PGBFYLVIMDQYMS-UHFFFAOYSA-N Methyl thiophene-2-carboxylate Chemical class COC(=O)C1=CC=CS1 PGBFYLVIMDQYMS-UHFFFAOYSA-N 0.000 claims description 4
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 4
- 229940097068 glyphosate Drugs 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000007931 coated granule Substances 0.000 claims description 3
- WVWZECQNFWFVFW-UHFFFAOYSA-N methyl 2-methylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C WVWZECQNFWFVFW-UHFFFAOYSA-N 0.000 claims description 3
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 claims description 3
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims description 2
- 230000011218 segmentation Effects 0.000 claims description 2
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- HXKWSTRRCHTUEC-UHFFFAOYSA-N 2,4-Dichlorophenoxyaceticacid Chemical compound OC(=O)C(Cl)OC1=CC=C(Cl)C=C1 HXKWSTRRCHTUEC-UHFFFAOYSA-N 0.000 claims 1
- OVSKIKFHRZPJSS-DOMIDYPGSA-N 2-(2,4-dichlorophenoxy)acetic acid Chemical compound OC(=O)[14CH2]OC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-DOMIDYPGSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 238000012423 maintenance Methods 0.000 claims 1
- 239000011230 binding agent Substances 0.000 abstract description 2
- -1 2-[[(4,6-dimethoxypyridin-2-yl) aminocarbonyl] sulfamoyl]-3-picolinic acid methyl esters Chemical class 0.000 description 35
- 239000004009 herbicide Substances 0.000 description 24
- 159000000000 sodium salts Chemical class 0.000 description 17
- 230000002363 herbicidal effect Effects 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 15
- 239000002253 acid Substances 0.000 description 14
- 229920002594 Polyethylene Glycol 8000 Polymers 0.000 description 13
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Substances CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 13
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 10
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 10
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 6
- 235000015320 potassium carbonate Nutrition 0.000 description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 description 6
- 235000019260 propionic acid Nutrition 0.000 description 6
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 description 6
- 238000013019 agitation Methods 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 229940124530 sulfonamide Drugs 0.000 description 5
- 150000003456 sulfonamides Chemical class 0.000 description 5
- CTSLUCNDVMMDHG-UHFFFAOYSA-N 5-bromo-3-(butan-2-yl)-6-methylpyrimidine-2,4(1H,3H)-dione Chemical compound CCC(C)N1C(=O)NC(C)=C(Br)C1=O CTSLUCNDVMMDHG-UHFFFAOYSA-N 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 3
- 239000004353 Polyethylene glycol 8000 Substances 0.000 description 3
- 229940100389 Sulfonylurea Drugs 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 150000003851 azoles Chemical class 0.000 description 3
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- GLUUGHFHXGJENI-UHFFFAOYSA-N diethylenediamine Natural products C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 3
- OGGXGZAMXPVRFZ-UHFFFAOYSA-N dimethylarsinic acid Chemical compound C[As](C)(O)=O OGGXGZAMXPVRFZ-UHFFFAOYSA-N 0.000 description 3
- XXOYNJXVWVNOOJ-UHFFFAOYSA-N fenuron Chemical compound CN(C)C(=O)NC1=CC=CC=C1 XXOYNJXVWVNOOJ-UHFFFAOYSA-N 0.000 description 3
- 230000009969 flowable effect Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229910003002 lithium salt Inorganic materials 0.000 description 3
- 159000000002 lithium salts Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 235000006408 oxalic acid Nutrition 0.000 description 3
- 229940085678 polyethylene glycol 8000 Drugs 0.000 description 3
- 235000019446 polyethylene glycol 8000 Nutrition 0.000 description 3
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 3
- 229940080818 propionamide Drugs 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 3
- GETTZEONDQJALK-UHFFFAOYSA-N (trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=CC=C1 GETTZEONDQJALK-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- YOYAIZYFCNQIRF-UHFFFAOYSA-N 2,6-dichlorobenzonitrile Chemical compound ClC1=CC=CC(Cl)=C1C#N YOYAIZYFCNQIRF-UHFFFAOYSA-N 0.000 description 2
- OWZPCEFYPSAJFR-UHFFFAOYSA-N 2-(butan-2-yl)-4,6-dinitrophenol Chemical compound CCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O OWZPCEFYPSAJFR-UHFFFAOYSA-N 0.000 description 2
- LLWADFLAOKUBDR-UHFFFAOYSA-N 2-methyl-4-chlorophenoxybutyric acid Chemical compound CC1=CC(Cl)=CC=C1OCCCC(O)=O LLWADFLAOKUBDR-UHFFFAOYSA-N 0.000 description 2
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- FMGYKKMPNATWHP-UHFFFAOYSA-N Cyperquat Chemical compound C1=C[N+](C)=CC=C1C1=CC=CC=C1 FMGYKKMPNATWHP-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000005510 Diuron Substances 0.000 description 2
- 241000192043 Echinochloa Species 0.000 description 2
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
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- NEKOXWSIMFDGMA-UHFFFAOYSA-N Isopropalin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(C)C)C=C1[N+]([O-])=O NEKOXWSIMFDGMA-UHFFFAOYSA-N 0.000 description 2
- OKIBNKKYNPBDRS-UHFFFAOYSA-N Mefluidide Chemical compound CC(=O)NC1=CC(NS(=O)(=O)C(F)(F)F)=C(C)C=C1C OKIBNKKYNPBDRS-UHFFFAOYSA-N 0.000 description 2
- LBJVHMAYBNQJBK-UHFFFAOYSA-N N-(2,6-diethylphenyl)-2-chloroacetamide Chemical compound CCC1=CC=CC(CC)=C1NC(=O)CCl LBJVHMAYBNQJBK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- UMKANAFDOQQUKE-UHFFFAOYSA-N Nitralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(S(C)(=O)=O)C=C1[N+]([O-])=O UMKANAFDOQQUKE-UHFFFAOYSA-N 0.000 description 2
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
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- 230000003213 activating effect Effects 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- SMDHCQAYESWHAE-UHFFFAOYSA-N benfluralin Chemical compound CCCCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O SMDHCQAYESWHAE-UHFFFAOYSA-N 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 230000000975 bioactive effect Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- GTCAXTIRRLKXRU-UHFFFAOYSA-N carbamic acid methyl ester Natural products COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 2
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- 239000003795 chemical substances by application Substances 0.000 description 2
- WYKYKTKDBLFHCY-UHFFFAOYSA-N chloridazon Chemical compound O=C1C(Cl)=C(N)C=NN1C1=CC=CC=C1 WYKYKTKDBLFHCY-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- MZZBPDKVEFVLFF-UHFFFAOYSA-N cyanazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C#N)=N1 MZZBPDKVEFVLFF-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 125000001841 imino group Chemical group [H]N=* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- NRXQIUSYPAHGNM-UHFFFAOYSA-N ioxynil Chemical compound OC1=C(I)C=C(C#N)C=C1I NRXQIUSYPAHGNM-UHFFFAOYSA-N 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- QYPPRTNMGCREIM-UHFFFAOYSA-N methylarsonic acid Chemical compound C[As](O)(O)=O QYPPRTNMGCREIM-UHFFFAOYSA-N 0.000 description 2
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- BMLIZLVNXIYGCK-UHFFFAOYSA-N monuron Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C=C1 BMLIZLVNXIYGCK-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- XOOVLDXDHKQPCR-UHFFFAOYSA-N o-propan-2-yl carbamothioate Chemical compound CC(C)OC(N)=S XOOVLDXDHKQPCR-UHFFFAOYSA-N 0.000 description 2
- SOWBFZRMHSNYGE-UHFFFAOYSA-N oxamic acid Chemical compound NC(=O)C(O)=O SOWBFZRMHSNYGE-UHFFFAOYSA-N 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 description 2
- LZMATGARSSLFMQ-UHFFFAOYSA-N propan-2-ylurea Chemical compound CC(C)NC(N)=O LZMATGARSSLFMQ-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 2
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 2
- GXEKYRXVRROBEV-FBXFSONDSA-N (1r,2s,3r,4s)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1C[C@@H]2[C@@H](C(O)=O)[C@@H](C(=O)O)[C@H]1O2 GXEKYRXVRROBEV-FBXFSONDSA-N 0.000 description 1
- WNTGYJSOUMFZEP-SSDOTTSWSA-N (R)-mecoprop Chemical compound OC(=O)[C@@H](C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-SSDOTTSWSA-N 0.000 description 1
- XGWIJUOSCAQSSV-XHDPSFHLSA-N (S,S)-hexythiazox Chemical compound S([C@H]([C@@H]1C)C=2C=CC(Cl)=CC=2)C(=O)N1C(=O)NC1CCCCC1 XGWIJUOSCAQSSV-XHDPSFHLSA-N 0.000 description 1
- JARFAUHJHIUGCO-UHFFFAOYSA-N 1,2-dimethyl-3,5-diphenyl-3h-pyrazole Chemical class CN1N(C)C(C=2C=CC=CC=2)C=C1C1=CC=CC=C1 JARFAUHJHIUGCO-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- ZWXCVXDBSCHLQQ-UHFFFAOYSA-N 1-(4,6-dimethoxypyridin-2-yl)-3-[3-(trifluoromethyl)pyridin-2-yl]sulfonylurea Chemical compound COC1=CC(OC)=CC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(F)(F)F)=N1 ZWXCVXDBSCHLQQ-UHFFFAOYSA-N 0.000 description 1
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- FZMKKCQHDROFNI-UHFFFAOYSA-N sulfometuron Chemical compound CC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 FZMKKCQHDROFNI-UHFFFAOYSA-N 0.000 description 1
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 description 1
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- REEQLXCGVXDJSQ-UHFFFAOYSA-N trichlopyr Chemical compound OC(=O)COC1=NC(Cl)=C(Cl)C=C1Cl REEQLXCGVXDJSQ-UHFFFAOYSA-N 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- WTHDKMILWLGDKL-UHFFFAOYSA-N urea;hydrate Chemical compound O.NC(N)=O WTHDKMILWLGDKL-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000012873 virucide Substances 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了一种新的水溶性或水分散性颗粒组合物，其制备方法是：利用水溶性聚乙二醇结合剂将水溶性农药或农药的水溶性或水分散性组成与颗粒基质结合。
Description
水溶性或水分散性农药颗粒组合物的制备方法通常是利用盘式床或流化床成粒后，填充、制片，或者将活性成分喷于预成型的载体上。
1975年11月18日公布的美国专利3，920，442号中公开了一种生产水分散性颗粒组合物的方法。
1980年4月8日公布的美国专利4，197，112号中介绍了一种由三嗪除草剂和表面活性剂组成的水分散性三嗪除草剂组合物。
日本专利申请52/30577（CA88：1627P）描述了一种缓慢释放的农药-肥料组合物，它含有杀虫剂、聚氧乙烯单油酸酯以及尿素。
日本专利申请47/43822（CA80：67436S）公开了一种稳定的杀虫剂组合物，它包含二嗪农、聚乙二醇-400、尿素、硅酸水合物和硅藻土。
本发明包括水溶性或水分散性的分层的农药颗粒组合物，其中至少有一层包含以下成分，其含量按该层和基质的总重量计算，即包含：
（1）0.1至50%的一种或多种水溶性农药，或其水溶性组成，或农药的水分散性组成（以下称为包衣农药），它们由以下载体携带;
（2）1至20%的载体，它包含水溶性聚乙二醇、聚丙二醇，或它们的衍生物，所述载体的平均分子量在150至8000之间;
（3）50至98.9%平均粒径约为500微米的水溶性或水分散性颗粒基质。
特别优选的颗粒基质为碳酸钾，尿素颗粒，粒状2，4-二氯苯氧乙酸、4-氯-2-甲基苯氧乙酸、（+/-）-或（R，+）-2-（4-氯-2-甲基苯氧基）丙酸、草甘膦、赛克津、噻唑隆、或其粒状组合物、或其它农业上适宜的盐或固体配方。
优选的颗粒组合物应该是：其中的包衣农药埋置在载体中，且包衣农药占总重量的0.5至40%，聚乙二醇、聚丙二醇、或它们的衍生物占总重量的3-15%，基质占总重量的70-98%。
可作为包衣农药的特别优选的化合物为：
2-[[[[N（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氨基]羰基]氨基]磺酰基]苯甲酸甲酯，
3-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]-2-噻吩羧酸甲酯，
2-[[[[（4，6-二甲氧基-2-嘧啶基）-氨基]羰基]氨基]磺酰基]甲基笨甲酸甲酯，及其农业上适宜的盐或其水分散性粉状配方，
2-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]苯甲酸甲酯，
2-氯-N-[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]苯磺酰胺，
及其农业上适宜的盐和水分散性粉状组成。
最常用的农药应用方法是将农药稀释于溶剂中，然后将所得溶液或分散液喷雾。由于非水性溶剂增加成本，并且其中一些具有毒性，水溶性或水分散性颗粒组合物日益受到欢迎。就这类组合物而言，稀释后所形成的分散性颗粒的最大粒径应不超过50微米，这样可避免喷嘴堵塞或过早沉淀，从而也消除了农药的不均匀喷洒的现象。因此，较为理想的是使组合物中的所有成分均能迅速而彻底地溶解于稀释水中。
制备水溶性或水分散性颗粒的惯用方法包括利用流化床或盘式床成粒技术或用含活性农药成分的液体浸渍预成型的矿物颗粒。通过流化床或盘式床成粒工艺制备的颗粒在稀释后通常是可喷雾的，而浸渍组合物在使用时需借助机械装置，例如利用喷洒器。
通常，较理想的是采用具有不同功能的两种或两种以上农药混合物（如：除草剂和杀虫剂的混合物），以产生对多种杂草和/或有害微生物具有广谱活性的抑制作用。遗憾的是，有些成分作为混合物存在时，在物理性质上或化学性质上是不相容的，尤其是在长期存贮的情况下更是如此。例如，在碱性成分存在下，氨基甲酸脂杀虫剂通常是不稳定的，而在酸性物质存在下，磺酰脲类除草剂不稳定。这种化学上的不相容性可归因于互补农药中所存在的杂质，而不是生物活性成分本身。因此，最好有一种由颗粒组成的可喷雾的组合物产物，其中的活性成分实际上是分离的。
本发明包括按以下方法制备的成本低廉的水溶性颗粒或水分散性颗粒组合物。所述方法是：利用水溶性聚乙二醇作为结合剂，将水溶性农药或预配制的水分散性农药涂覆于或包覆于本身具水溶性或水分散性的颗粒基质上。与流化床和盘式床成粒工艺所需的专门技术和设备相比，制备这些组合物只需采用的简单混合技术和设备。采用的混合工艺，还可使佐剂和稳定剂的混入变得简易。
按本发明的方法，已将多种农药配制成适于包衣的流动性固体颗粒组合物。它们包括：磺酰胺除草剂、苯醚除草剂、草甘膦、赛克津、噻唑隆、除草定、敌草隆、六嗪酮、代森锰、氟杀唑（flusilazol）、草氨酰和Hexythiazox。
水溶性农药指的是：在应用（如喷雾溶液）温度和浓度等条件下基本上溶解于水的化合物。
农药（活性成分）指的是除草剂、杀真菌剂、杀虫剂、杀线虫剂、杀螨剂、杀病毒剂、杀藻剂、杀菌剂、植物生长调节剂、脱叶剂、捕虫饵和驱虫剂，尤其是上述成分的混合物。理想的除草剂选自磺酰脲类除草剂，其非限定性实例包括以下化合物。这些化合物都是水可溶的，或者都可配制成水溶性或水分散性组合物：
2-氯-N-[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]苯磺酰胺
Chlorsulfuron
12-[[[[（4，6-二甲基-2-嘧啶基）氨基]羰基]氨基]磺酰基]苯甲酸甲酯
Sulfometuron methyl
2-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]苯甲酸甲酯
Metsulfuron
2-[[[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氧基]羰基]氨基]磺酰基]苯甲酸甲酯
Express（TM）
2-[[[[（4-氯-6-甲氧基-2-嘧啶基）氨基]羰基]氨基]磺酰基]苯甲酸乙酯
Chlorimuron ethyl
2-[[（4-乙氧基-6-甲氨基-1，3，5-三嗪-2-基）氨羰基]氨磺酰基]苯甲酸甲酯
Muster（TM）
2-[[（4，6-二甲氧基-1，3，5-三嗪-2-基）氨羰基]氨磺酰基]-4-（2，2，2-三氟乙氧基）苯甲酸乙酯4-氯-2-[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨羰基]氨磺酰基]苯甲酸异丙酯
3-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]-2-噻吩羧酸甲酯
Thiameturon methyl
2-[[[[（4，6-二甲氧基-2-嘧啶基）氨基]羰基]氨基]磺酰基]甲基苯甲酸甲酯
Bensulfuron methyl
2-[[（4，6-二甲氧嘧啶-2-基）氨羰基]氨磺酰基]-N，N-二甲基-3-吡啶酰胺
2-[[（4，6-二甲氧基嘧啶-2-基）氨羰基]氨磺酰基]-3-吡啶羧酸甲酯
N-[（4，6-二甲氧基嘧啶-2-基）氨羰基]-3-（乙基磺酰基）-2-吡啶磺酰胺
N-[（4，6-二甲氧基嘧啶-2-基）氨羰基]-2，3-二氢-2-甲基-苯并（b）噻吩-7-磺酰胺1，1-二氧化物
2-[[[[（4，6-双（二氟甲氧基）-2-嘧啶基]氨基]羰基]氨基]磺酰基]苯甲酸甲酯
5-[3-（4，6-二甲氧基嘧啶-2-基）脲基磺酰基]-1-甲基吡唑-4-羧酸乙酯
N-[（6-甲氧基-4-甲基-1，3，5-三嗪-2-基）氨基羰基]-2-（2-氯代乙氧基）苯磺酰胺
N-[（4，6-二甲氧基-1，3，5-三嗪-2-基）氨基-羰基]-2-（2-甲氧基乙氧基）苯磺酰胺
N-[[（4，6-二甲氧基嘧啶-2-基）氨基]羰基]-3-三氟甲基-2-吡啶磺酰胺。
本发明中可采用的其它类型除草剂列出如下：
普通名 化学名
乙酰氯 2-氯-N-（乙氧基甲基）-N-（2-乙基-6-甲苯基）乙酰胺
氟苯酸（acifluorfen） 5-[2-氯-4-（三氟甲基）苯氧基]-2-硝基苯甲酸
丙烯醛 2-丙烯醛
草不绿 2-氯-N-（2，6-二乙苯基）-N-（甲氧甲基）乙酰胺
莠灭净 N-乙基-N′-（1-甲基乙基）-6-（甲硫基）-1，3，5-三嗪-2，4-二胺
氨基磺酸铵 氨基磺酸铵
黄草灵 [（4-氨基苯基）磺酰基]氨基甲酸甲酯
莠去津 6-氯-N-乙基-N′-（1-甲基乙基）-1，3，5-三嗪-2，4-二胺
燕麦灵 4-氯-2-丁炔基3-氯-氨基甲酸酯
氟草胺 N-丁基-N-乙基-2，6-二硝基-4-（三氟甲基）苯胺
地散磷 0，0-双（1-甲基乙基）S-[2[（苯基磺酰基）氨基]乙基]二硫代磷酸酯
噻草平 3-（1-甲基乙基）-（1H）-2
1，3-苯并噻二嗪-4（3H）-酮2-2-二氧化物
苯并氟 N-[4-（乙硫基）-2-（三氟甲基）苯基]甲磺酰胺
新燕灵 N-苯甲酰基-（3，4-二氯苯基）-氨基丙酸
治草醚 5-（2，4-二氯苯氧基）-2-硝基苯甲酸甲酯
除草定 5-溴-6-甲基-3-（1-甲基丙基）2，4（1H，3H）嘧啶二酮
溴苯腈 3，5-二溴-4-羟基苯腈
去草胺 N-（丁氧甲基）-2-氯-N-（2，6-二乙基苯基）乙酰胺
布刹唑（buthidazole） 3-[5-（1，1-二甲基乙基）-1，3，4-噻二唑-2-基]-4-羟基-1-甲基-2-咪唑啉酮
布快灵（butralin） 4-（1，1-二甲基乙基）-N-（1-甲基丙基）-2，6-二硝基苯胺
苏达灭 S-乙基 双（2-甲丙基）氨基硫代酸酯
二甲胂酸 胂酸二甲酯
草毒死 2-氯-N，N-二-2-丙烯基-乙酰胺
草克死 2-氯代烯丙基 二乙基二硫代氨基甲酸酯
草灭平 3-氨基-2，5-二氯苯甲酸
氯溴隆 3-（4-溴-3-氯苯基）-1-甲氧基-1-甲基脲
氯嘧隆（chlorimuron） 2-[[[[（4-氯-6-甲氧基-2-嘧乙啶基）乙氨基]羰基]氨基]磺酰基]苯甲酸乙酯
枯草隆 N′-[4-（4-氯苯氧基）苯基]-N，N-二甲基脲
氯苯胺 1-甲基乙基 3-氯苯基-氨基甲酸酯
绿麦隆 N′-（3-氯-4-甲苯基）-N，N-二甲基脲
新灭灵（cinmethylin） 挂-1-甲基-4-（1-甲基乙基）-2-[（2-甲基苯基）甲氧基]-7-噁二环[2.2.1]庚烷
克草酮（Clethodim） （E，E）-（+）-2-[1-[[3-氯-2-丙烯基）氧基]亚氨基]丙基]-5-[2-（乙硫基）丙基]-3-羟基-2-环己烯-1-酮
氯甲唑酮（Clomazone） 2-[（2-氯苯基）甲基]-4，4-二甲基-3-异噁唑烷酮
氯草定（Cloproxydim） （E，E）-2-[1-[[（3-氯-2-丙烯基氧基）亚氨基]丁基]-5-[2-（乙硫基）丙基]-3-羟基-2-环己烯-1-酮
氯吡啶酸（Clopyralid） 3，6-二氯-2-吡啶羧酸
甲基胂酸钙 MAA的钙盐
草净津 2-[[4-氯-6-（乙氨基）-1，3，5-三嗪-2-基]氨基]-2-甲基丙腈
草灭特 环己基乙基氨基硫代酸酯S-乙基
环莠隆 3-环辛基-1，1-二甲基脲
杀草快（Cyperquat） 1-甲基-4-苯基吡啶嗡
环草津 2-氯-4-（环丙基氨基）-6-（异丙基氨基）-S-三嗪
环草唑（Cyprazole） N-[5-（2-氯-1，1-二甲基乙基）-1，3，4-噻二唑-2-基]环丙酰胺
环草胺 N-苯基-3′，4′-二氯环丙烷基酰胺
茅草枯 2，2-二氯丙酸
棉隆 四氢-3，5-二甲基-2H-1，3，5-噻二嗪-2-硫酮
敌稗 2，3，5，6-四氯-1，4-苯-
二羧酸二甲酯
敌草苯（desmediphan） [3-[[（苯氨基）-羰基]氧基]苯基]氨基甲酸乙酯
敌草净 2-（异丙氨基）-4-（甲氨基）-6（甲硫基）-S-三嗪
燕麦敌 S-（2，3-二氯-2-丙烯基）双（1-甲基乙基）硫代氨基甲酸酯
麦草畏 3，6-二氯-2-甲氧苯甲酸
敌草腈 2，6-二氯苯并腈
敌草酸（dichlorprop） （+）-2-（2，4-二氯苯氧基）-丙酸
敌草苯酸（dichlofop） （+）-2-[4-（2，4-二氯苯氧基）-苯氧基]丙酸
敌草氨酸（diethatyl） N-（氯乙酰基）-N-（2，6-二乙苯基）甘氨酸
二苯吡唑（difenzoquat） 1，2-二甲基-3，5-二苯基-1H-吡唑嗡
敌乐胺 N3，N3-二乙基-2，4-二硝基-6-（三氟甲基）-1，3-苯二胺
敌乐酚（dinoseb） 2-（1-甲基丙基）-4，6-二硝基苯酚
地乐酚 N，N-二甲基-a-苯基苯乙酰胺
杀草净 6-（乙硫基）-N，N′-双（1-甲基乙基）-1，3，5-三嗪-2，4-二胺
敌草快 6，7-二氢吡啶并[1，2-a：2′，1′-c]吡嗪二嗡离子
敌草隆 N′-（3，4-二氯苯基）-N，N′-二甲基脲
二硝甲酚 2-甲基-4，6-二硝基苯酚
甲胂钠 MAA的二钠盐
草藻灭 7-噁二环[2.2.1]庚烷-2，3-二羧酸
扑草灭 S-乙基二丙基硫代氨基甲酸酯
乙氟灵（ethalfluralin） N-乙基-N-（2-甲基-2-丙烯
基）-2，6-二硝基-4-（三氟甲基）苯胺
乙呋麦刹（ethofumesate） （+）-2-乙氧基-2，3-二氢-3，3-二甲基-15-苯并呋喃基甲磺酸酯
伐草克 2，3，6-三氯苯乙酸
苯噁酸（fenoxaprop） （+）-2-[4-[（6-氯-2-苯并噁唑基）氧基]苯氧基]丙酸
非草隆 N，N-二甲基-N′-苯基脲
去草隆 非草隆和TCA的盐
伐草胺（flamprop） N-苯甲酰基-N-（3-氯-4-氟苯基）DL-苯胺
伐草酸（fluazifop） （+）-2-[4-[[5-（三氟甲基）-2-吡啶基]氧基]苯氧基]丙酸
伐草酸-P（fluazifop-P） （R）-2-[4-[[5-（三氟甲基）-2-吡啶基]氧基]苯氧基]丙酸
氟消草 N-（2-氯乙基）-2，6-二硝基-N-丙基-4-（三氟甲基）-苯胺
伏草隆 N，N-二甲基-N′-[3-（三氟甲基）苯基）]脲
氟氯酮（fluorochloridone） 3-氯-4（氯甲基）-1-[3-（三氟甲基）苯基]-2-吡咯烷酮
消草醚 对硝基苯基α，α，α-三氟-2-硝基-对甲苯基醚
氟克草（fluoroglycofen） 5-[2-氯-4-（三氟甲基）苯氧基]-2-硝基苯甲酸羧甲基酯
氟苯酮（fluidone） 1-甲基-3-苯基-5-[3-（三氟甲基）苯基]-4（1H）-吡啶酮
伏草酯（fluroxypyr） 2-[[[4-氨基-3，5-二氯-6-氟-2-吡啶基]氧基]]-乙酸，[[甲基庚基]酯]
氯刹胺（fomesafen） 5-[2-氯-4-（二氟甲基）-苯氧基]-N-（甲基磺酰基）-2-硝基苯胺
伐草磷（fosamine） （氨羰基）磷酸氢乙酯
草甘膦 N-（膦酰基甲基）甘氨酸
刹草酸（haloxyfop） 2-[4-[[3-氯-5-（三氟甲基）-2-吡啶基]氧基]-苯氧基]丙酸
六氟盐 六氟砷酸钾
己嗪酮 3-环己基-6-（二甲氨基）-1-甲基-1，3，5-三嗪-2，4（1H3H）-二酮
咪刹苯（imazamethabenz） 6-（4-异丙基-4-甲基-5-氧-2-咪唑啉-2-基）-间-甲基苯甲酸甲酯和6-（4-异丙基-4-甲基-5-氧-2-咪唑啉-2-基）对甲基苯酸甲酯
咪刹稗（imazapyr） （+）-2-[4，5-二氢-4-甲基-4-（1-甲基乙基）-5-氧-
1H-咪唑-2-基）-3-吡啶羧酸
乙基味刹稗（imazethapyr） （+）-2-[4，5-二氢-4-甲基-4-（1-甲基乙基）-5-氧-1H-咪唑-2-基]-5-乙基-3
-吡啶羧酸
碘苯腈 4-羟基-3，5-二碘苯并腈
异乐灵 4-（1-甲基乙基）-2，6-二硝基-N，N-二丙基苯胺
异丙脲（isoproturon） N-（4-异丙苯基）-N，N-二甲基脲
异恶脲（isouron） N′-[5-（1，1-二甲基乙基）-3-异噁唑基]-N，N-二甲基脲
异恶苯（isoxaben） N-[3-（1-乙基-1-甲基丙基）-5-异噁唑基]-2，6-二甲氧基苯甲酰胺
卡草灵 3-[[（二甲氨基）羰基]氨基]苯基-（1，1-二甲基乙基）氨基甲酸酯
除草奋（lactofen） （+）-2-乙氧基-1-甲基-2-氧-乙基5-[2-氯-4-（三氟甲基）苯氧基]-2-硝基苯酸酯
环草定 3-环己基-6，7-二氢-1H-环戊嘧啶-2，4（3H，5H）-二酮
利谷隆 N′-（3，4-二氯苯基）-N-甲氧基-N-甲基脲
甲胂钠 甲肿酸
甲胂一铵 甲胂钠一铵盐
2甲4氯 （4-氯-2-甲基苯氧基）乙酸
2甲4氯丁酸 4-（4-氯-2-甲基苯氧基）丁酸
2甲4氯丙酸 （+）-2-（4-氯-2-甲基苯氧基）丙酸
甲氟胺（mefluidide） N-[2，4-二甲基-5-[[（三氟甲基）磺酰基]氨基]苯基]乙酰胺
麦草灵（methalpropalin） N-（2-甲基-2-丙烯基）-2，6-二硝基-N-4-（三氟甲基）苯酰胺
噻唑隆 1，3-二甲基-3-（2-苯并噻唑基）脲
威百亩 甲基二硫代氨基甲酸
灭草定 2-（3，4-二氯苯基）-4-甲基-1，2，4-噁二唑-3，5-二酮
甲氧隆（mathoxuron） N′-（3-氯-4-甲氧基苯基）-N，N-二甲基脲
甲消草（metolachor） 2-氯-N-（2-乙基-6-甲基苯基）-N-（2-甲氧基-1-甲基乙基）乙酰胺
赛克津 4-氨基-6-（1，1-二甲基乙基）-3-（甲硫基）-1，2，4-三嗪-5（4H）-酮
抑芽丹 1，2-二氢-3，6-哒嗪二酮
草达灭 S-乙基 六氢-1H-氮杂 
-1-硫代羧酸酯
绿谷隆 3-（对-氯苯基）-1-甲氧基-1-甲基脲
灭草隆 N′-（4-氯苯基）-N，N-二甲基脲
季草隆 灭草隆和TCA的盐
甲胂一钠 MAA一钠盐
草萘胺 N，N-二乙基-2-（1-萘烯基氧基）丙酰胺
抑草生 2-[（1-萘烯基氨基）羰基]苯甲酸
草不隆 1-丁基-3-（3，4-二氯苯基）-1-甲基脲
磺乐灵 4-（甲基磺酰基）-2，6-二硝基-N，N-二丙基苯胺
除草醚 2，4-二氯-1-（4-硝基苯氧基）-苯
nitrofluorfen 2-氯-1-（4-硝基苯氧基）-4-（三氟甲基）苯
草完隆 N，N-二甲基-N′-（八氢-4，7-甲醇-1H-茚-5-基）脲，3a，4，5，7，7a-异构体
达草灭 4-氯-5-（甲氨基）-2-[3-（三氟甲基）苯基]-3（2H）哒嗪酮
黄草消 4-（二丙氨基）-3，5-二硝基苯
磺酰胺
恶草灵 3-[2，4-二氯-5-（1-甲基乙氧基）苯基]-5-（1，1-二甲基乙基）-1，3，4-噁二唑-2（3H）-酮
氧氟苯（oxyfluorfen） 2-氯-1-（3-乙氧基-4-硝苯氧基）-4-（三氟甲基）苯
对草快 1，1′-二甲基-4，4′-二吡啶嗡（盐）离子
克草猛 S-丙基 丁基乙基硫代氨基甲酸酯
戊二甲灵 N-（1-乙基丙基）-3，4-二甲基-2，6-二硝基苯胺
三氟磺酰胺 1，1，1-三氯-N-[2-甲基-4-（苯磺酰基）苯基]甲磺酰胺
苯敌草 3-[（甲氧羰基）氨基]苯基（3-甲基苯基）氨基甲酸酯
毒莠定 4-氨基-3，5，6-三氯-2-吡啶羧酸
PPG-1013 5-[2-氯-4-（三氟甲基）-苯氧基]-2-硝基苯乙酮肟-O-乙酸甲酯
环丙嗪（procyazine） 2-[[4-氯-6-（环丙基氨基）-1，3，5-三嗪-2-基）氨基]-2-甲基丙腈
丙氟灵（profluralin） N-（环丙基甲基）-2，6-二硝基-N-丙基-4-（三氟甲基）苯胺
扑灭通 6-甲氧基-N，N′-双（1-甲基乙基）-1，3，5-三嗪-2，4-二胺
扑草净 N，N′-双（1-甲基乙基）-6-（甲硫基）-1，3，5-三嗪-2，4-二胺
拿草特 3，5-二氯-N-（1，1-二甲基-2-丙炔基）苯甲酰胺
毒草安 2-氯-N-（1-甲基乙基）-N-苯基乙酰胺
敌稗 N-（3，4-二氯苯基）丙酰胺
扑灭津 6-氯-N，N′-双（1-甲基乙基）-1，3，5-三嗪-2，4-二胺
苯胺灵 1-甲基乙基 苯基氨基甲酸酯
扑刹灵（prosulfalin） N-[[4-（二丙基氨基）-3，5-二硝基苯基]磺酰基]-S，S-二甲基
丙炔氯（prynachlor） 2-氯-N-（1-甲基-2-丙炔基）乙酰苯胺
杀草敏 5-氨基-4-氯-2-苯基-3（2H）-哒嗪酮
喹苯醚（quizalofop） （+）-2-[4-[（6-氯-2-喹喔啉基）乙氧基]-苯氧基]丙酸乙酯
消草嗪（secbumeton） N-乙基-6-甲氧基-N′-（1-甲基丙基）-1，3，5-三嗪-2，
4-二胺
草敌（sethoxydim）＊t300R 2-[1-（乙氧基亚氨基）丁基]-5-[2-（乙硫基）丙基]-3-羟基-2-环己烯-1-酮
环草隆 N-（2-甲基环己基）-N′-苯基脲
西玛津 6-氯-N，N′-二乙基-1，3，5-三嗪-2，4-二胺
刹麦隆（sulfometuron） 2-[[[[（4，6-二甲基-2-嘧啶基甲氨基]羰基]氨基]磺酰基]苯甲酸甲酯
TCA 三氯乙酸
丁噻脲（tebuthiuron） N-[5[（1，1-二甲基乙基）-1，3，4-噻二唑-2-基]-N，N′-二甲基脲
特草定 5-氯-3-（1，1-二甲基乙基）-6-甲基-2，4（1H，3H）-嘧啶二酮
特丁氯 N-（丁氧基甲基）-2-氯-N-[2-（1，1-二甲基乙基）-6-甲基苯基]乙酰胺
特丁津 2-（叔丁基氨基）-4-氯-6-（乙基氨基）-S-三嗪
芽根灵 2，6-二叔丁基-对甲苯基 甲基氨基甲酸酯
去草净 N-（1，1-二甲基乙基）-N′-
乙基-6-（甲硫基）-1，3，5-三嗪-2，4-二胺
硫苯卡巴（thiobencarbd） S-[（4-氯苯基）甲基]二乙基硫代氨基甲酸酯
野麦畏 S-（2，3，3-三氯-2-丙烯基）-双（1-甲基乙基）硫代氨基甲酸酯
三氯吡啶酸（triclopyr） [（3，5，6-三氯-2-吡啶基）氧基]乙酸
氯敌草（tridiphane） 2-（3，5-二氯苯基）-2-（2，2，2-三氯乙基）环氧乙烷
氟乐灵 2，6-二硝基-N，N-二丙基-4-（三氟甲基）苯胺
三甲隆 1-（对-氯苯基）-2，3，3-三甲基假脲
2，4-滴 （2，4-二氯苯氧基）乙酸
2，4-滴丁酸 4-（2，4-二氯苯氧基）丁酸
灭草猛 S-丙基 二丙基硫代胺基甲酸酯
甲苯氯酰胺（xylachlor） 2-氯-N-（2，3-二甲基苯基）-N-（1-甲基乙基）乙酰胺
优选的包衣农药系磺酰脲类除草剂的农业上适宜的盐。
特别优选的包衣农药系2-[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氨基羰基]-氨磺醌]苯甲酸甲酯的锂盐和钠盐。
农药的水分散性组成指的是各种农业上适宜的组合物，包括用于包衣的可湿性粉剂和用作颗粒基质的干性流动剂。可用作基质的优选配方是具有除草成分和尿素颗粒的干性流动剂组合物。
优选的水溶性聚乙二醇是平均分子量为3000至8000的固体。具体实例包括标明平均分子量的Carbowax（R）聚乙二醇（联合碳化物公司出品）。水溶性乙二醇衍生物（如：酯和醚）也是实用的。具体实例包括Macol（R）DNP150（Mazer Chemicals，Inc.生产的壬基苯酚衍生物）和Carbowax（R）甲氧聚乙二醇5000（联合碳化物公司出品）。具有过高分子量的聚乙二醇是不实用的，因为这会降低溶解速率。此外，通常呈液态的低分子量聚乙二醇或聚丙二醇聚合物及其衍生物也是理想的。然而，可混入包覆层的活性物质的最高量应低于固体结合剂的量。液体结合剂的例子是聚乙二醇或分子量为200～600的甲氧聚乙二醇，聚丙二醇，聚乙二醇衍生物，例如液体Pluronic（R）聚乙二醇/聚丙二醇共聚物，以及其它市售的水溶性聚乙二醇衍生物，例如Tween（R）20和40表面活性剂（ICI），它们系聚氧乙烯脱水山梨（糖）醇的酯肪酸酯。
大量物质可用作颗粒载体基质，具体包括颗粒物质（如：尿素、硝酸铵）、晶体（如：糖）或其它农药或肥料（如：磺酰胺除草剂、苯醚除草剂和膦酰基甘氨酸衍生物除草剂）的均匀水溶性或水分散性颗粒组合物。采用这类颗粒组合物作固体域体，可将在其它方法中不相容的农药混合物制成水溶性或水分散性颗粒组合物，在该组合物中各成分独立地存在于各自的层里。所述基质可包含单独存在的颗粒农药或其与上述惰性物质或肥料或一种或多种不同农药的混合物。
当这种基质是产生碱溶液的物质且农药为磺酰胺除草剂时，该磺酰胺除草剂可用于工业生产，当将颗粒加到水中制成喷雾液后，可产生更多的水溶性盐。碱性基质的例子是碳酸钾颗粒。这种改进可省去盐分离促进剂。
当活性成分相互之间不产生有害的作用时，所述载体可含有一种以上的活性成分。为防止有害的相互作用，可采用多重载体层，从而使各成分分离。
在众多的已知制备装置中，优选的是机械搅拌器。
作为一个实施例，在恒定搅拌下，将颗粒基质与固体聚乙二醇或衍生物结合剂混合，并加热至60～125℃，最好是70～90℃，直至该基质被包覆。然后将活性剂或细分的活性化合物混合物加到加热过的基质中，并将混合物缓慢冷却至室温，上述操作均在恒定搅拌下进行。若要另外加一层，则可在冷却前补加结合剂，继之以补加农药。另外，可将冷却的组合物再加热，按前述方法再涂一层。
若基质是生物活性物质或生物活性物质的组合物，则用结合剂和另一种生物活性化合物涂覆表面可产生层状颗粒产物，其中各活性化合物实际上是分离的。
另外，可将活性剂或活性剂混合物同熔融的粘合剂预混合，最后加基质。
当采用液态结合剂时，也可遵循上述步骤，但省去了加热这一步。
以下实施例用以说明而不是限制本发明的组合物。
实施例1：
在缓慢搅拌下，将5.0g尿素颗粒和0.3g平均分子量为8000的聚乙二醇（Carbowax（R）聚乙二醇8000，联合碳化物公司出品）的混合物于蒸气浴中加热，直至颗粒完全被聚合物包覆。接着，在继续搅拌和加热下，加入1.0g呈粉状的2-[[N-4-甲氧基-6-甲基-1，3-三嗪-2-基）-N-甲氨基羰基]氨磺酰基]苯甲酸甲酯。一旦颗粒被均匀包上活性成分后，即停止加热，并于恒定搅拌下将所得颗粒冷却至室温。产物中含15%2-[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲基氨基羰基]氨基磺酰基]苯甲酸甲酯。在缓慢搅拌下，1.0g试样可于45秒内完全溶解于22℃的100ml自来水中。
实施例2
用0.9g2，4-二氯苯氧乙酸的锂盐和0.1g2-[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氨基羰基]氨基磺酰基]苯甲酸甲酯作活性成分，重复实施例1的步骤。在与实施例1所述的相同条件下，生成的颗粒于38秒内完全溶解于水。
实施例3
用0.9g二氯丙-P（R）-2-（2，4-二氯苯氧）丙酸混合物的镁盐和0.1g2-[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氨基羰基]氨基磺酰基]苯甲酸甲酯作活性成分，重复实施例1的步骤。形成的颗粒于60秒钟内溶于水。
实施例4
用Macol（R）DNP150（聚乙二醇的二壬基苯酚衍生物，分子量为6000，由Mazer Chemicals，Inc.出品）代替聚乙二醇，重复实施例1的步骤。溶解时间为55秒。
实施例5
在转盘中，将尿素颗粒（28.8g）加热至80℃，并用4.6g Carbowax（R）8000分次处理。连续搅拌，直至全部颗粒被包覆。然后将20.5g ExrpessTM钠盐逐渐加入，同时继续旋转，以确保彻底混合。之后，依次逐渐补加4.0g Carbowax（R）结合剂和9.0g ExpressTM钠盐。然后，在恒定旋转下，使包衣颗粒冷却，得到含41%ExpressTM的颗粒产物。
采用实施例1中所述的方法，制得下列颗粒产物。
实施例编号 活性包衣成分 结合剂 颗粒基质
6 Express TM钠盐 PEG8000 CaCl2
7 Express TM钠盐 PEG8000 糖
8 thiameturon PEG8000 尿素
甲基钠盐+ExpressTM
钠盐（2：1）
9 thiameturon methyl PEG8000 K2CO3
10 Express TM PEG8000 K2CO3
11 thiameturon methy1+ PEG8000 K2CO3
Express TM（2：1）
12 thiameturon methy1+ PEG8000 K2CO3
ExpressTM钠盐（2：1）
13 bensulfuron methy1+ PEG8000 尿素
14 Express TM PEG8000 CaCl2
钠盐
15 Express TM PEG8000 糖
钠盐
实施例16
加热下，于蒸气浴中将0.3g Carbowax（R）聚乙二醇8000和0.5g粉状的2-[[[[（4-氯-6-甲氧基-2-嘧啶基）氨基]羰基]氨基]磺酰基]苯甲酸乙酯一起混合搅拌，直至粉末被聚合物湿润。然后加5.0g Lexone（R）水分散性颗粒（75%赛克津，制造商为E.I.du Pont de Nemours & Company），加热下搅拌该混合物，直至形成均匀包衣层。然后，在恒定搅拌下，将颗粒冷却至室温。所得产物于60秒内分散于水中，从而得到含水分散性和水溶性赛克津以及2-[[[[4-氯-6-甲氧基-2-嘧啶基）氨基]羰基]氨基]磺酰基]苯甲酸乙酯水溶性钠盐的喷雾混合物。
实施例17
用颗粒除草剂作基质，用0.6g聚乙二醇8000作结合剂，重复实施例的步骤。所形成的颗粒具水溶性，含36%2-（2-氯-苯基）甲基-4，4-二甲基-3-异噁唑烷酮。
按实施例16中所述的方法制得以下颗粒产物。
实施例编号 活性包衣成分 结合剂 干性可流动的
颗粒组合物
18 Express TM钠盐 PEG8000 2，4-D的钠盐
60%a.i.
19 thiameturon PEG8000 2，4-D的钠盐
methy1，锂盐 60%a.i.
20 Express TM PEG8000 KrovarⅡ
（除草定）
实施例21
采用8.0g尿素颗粒、0.54g Carbowax（R）和1.74g含60%2-[[[[4，6-二甲氧基-2-嘧啶基）氨基]羰基]氨基]磺酰基]苯甲酸甲酯和40%佐剂的Londax（R），重复实施例1的步骤。该粉状产物已用于制备未包衣的Londax（R）60 DI，一种用以抑制稻类杂草的市售产物。所得包衣颗粒含10.1%活性成分，稀释后约1分钟，于轻微搅拌下，活性成分细密地分散于水中。
实施例22
用8.6g尿素颗粒、0.28g Carbowax（R）8000、1.0g实施例1所用的粉状预混物和0.12g氢氧化钠粉，重复实施例1的产物。所得颗粒含10.1%活性成分。于缓慢搅拌下，将产物加到水中后，它在约1分钟内完全溶解，这是与氢氧化钠反应后直接形成活性成分水溶性盐所致。
实施例23
搅拌10g尿素颗粒和46g平均分子量为200的聚乙二醇（Carbowax（R）聚乙二醇200，联合碳化物公司出品）的混合物，直至聚合物完全包覆于颗粒。接着继续搅拌下加入19.3g呈粉状的2-[[N-4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氨基羰基]氨基磺酰基]苯甲酸甲酯。一旦颗粒被均匀地涂上活性成分后，即停止搅拌，所得产物含14.7%2-[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲基-氨基羰基]氨磺酰基]苯甲酸甲酯。在缓慢搅拌下，于45秒内，1.0g试样可完全溶解于100ml22℃的自来水中。
采用实施例23中所述的步骤，制得下列颗粒产物。
实施例 包衣活性 颗粒
编号 成分 结合剂 基质
24 thiameturon methy1 PEG200 K2CO3
25 thiameturon methy1+ 甲氧基PEG
Express TM（2：1）
26 Express TM PEG400 钠盐
钠盐 2，4-D 60% A，I
27 Express TM 聚乙二醇MW 尿素
钠盐 425
28 Express TM PLURONIC 尿素
钠盐 L35
Claims (16)
1、一种水溶性或水分散性的分层的农药颗粒组合物，其特征在于至少有一层包含以下成分：
(1)0.1%至50%水溶性农药或其水溶性组成或农药的水分散性组成，这些成分由以下载体所携载；
(2)1%至20%载体，选自平均分子量为150～8000的水溶性聚乙二醇聚丙二醇或其衍生物、共聚物或混合物；
(3)50%至98.9%粒径至少为500微米的水溶性或水分散性颗粒基质；
以上成分按该层和基质的总重量计算。
2、按权利要求1的颗粒组合物，其中农药埋置于载体中。
3、按权利要求1的组合物，其中农药、聚乙二醇和基质所占的百分数分别为0.5%至40%，3%至15%和70%至98%。
4、按权利要求2的组合物，其中聚乙二醇的平均分子量为3000～8000。
5、按权利要求3的组合物，其中聚乙二醇的平均分子量为3000～8000。
6、按权利要求3的组合物，其中农药选自以下化合物：
2-[[[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氨基]羰基]氨基]磺酰基]苯甲酸甲酯，
3-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]-2-噻吩羧酸甲酯，
2-[[[[（4，6-二甲氧基-2-嘧啶基]氨基]羰基]氨基]磺酰基]甲基苯甲酸甲酯，
2-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]苯甲酸甲酯，
2-氯-N-[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基-苯磺酰胺，
及其农业上适宜的盐和水分散性组合物。
7、按权利要求6的组合物，其中基质呈颗粒状。
8、按权利要求7的组合物，其中颗粒为脲素颗粒。
9、按权利要求6的组合物，其中聚乙二醇的平均分子量为3000-6000。
10、按权利要求3的组合物，其中基质选自：
2，4-二氯苯氧乙酸，
4-氯-2-甲基苯氧乙酸，
（+/-）-或（R，+）-2-（4-氯-2-甲基苯氧基）-丙酸，
草甘膦，
赛克津，
噻唑隆
的颗粒，及其混合物和农业上适宜的盐和固体组合物。
11、按权利要求10的组合物，其中包衣农药选自：
2-[[[[N-（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）-N-甲氨基]羰基]氨基]磺酰基]苯甲酸甲酯，
3-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]-2-噻吩羧酸甲酯，
2-[[[[（4，6-二甲氧基-2-嘧啶基]氨基]羰基]氨基]磺酰基]甲基苯甲酸甲酯，
2-[[[[（4-甲氧基-6-甲基-1，3，5-三嗪-2-基）氨基]羰基]氨基]磺酰基]苯甲酸甲酯，
及其农业上适宜的盐和水分散性组合物。
12、一种制备分层的颗粒的方法，该方法包括将水溶性或水分散性颗粒基质与聚乙二醇结合剂接触，由此包覆基质，将仍呈液态的包衣基质与水溶性或水分散性农药细粉接触，最后获得包衣颗粒。
13、接权利要求12的方法，其中农药与所述乙二醇一起混入。
14、一种制备层状颗粒的方法，该方法包括：将水溶性或水分散性颗粒基质与聚乙二醇结合剂接触，将所得混合物加热至60～125℃，至少部分地将聚乙二醇熔化，由此包覆于基质，将仍呈熔化态的包衣基质与细分的水溶性或水分散性农药接触，最后于搅拌下将所得组合物冷却，使乙二醇固化。
15、按权利要求14的方法，其中将温度维持在70～90℃。
16、按权利要求10的组合物，其中基质为2，4-二氯苯氧乙酸及其农业上适宜的盐和固体组合物。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24089688A | 1988-09-02 | 1988-09-02 | |
| US240,896 | 1988-09-02 |
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| CN1040728A true CN1040728A (zh) | 1990-03-28 |
Family
ID=22908374
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|---|---|---|---|
| CN89106985A Pending CN1040728A (zh) | 1988-09-02 | 1989-09-02 | 水溶性或水分散性农药颗粒 |
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|---|---|
| EP (2) | EP0432200A1 (zh) |
| JP (1) | JPH04500515A (zh) |
| KR (1) | KR900701156A (zh) |
| CN (1) | CN1040728A (zh) |
| AR (1) | AR244939A1 (zh) |
| AT (1) | ATE104827T1 (zh) |
| AU (1) | AU633848B2 (zh) |
| BR (1) | BR8907620A (zh) |
| DE (1) | DE68914924T2 (zh) |
| DK (1) | DK37491A (zh) |
| ES (1) | ES2063138T3 (zh) |
| FI (1) | FI911052A7 (zh) |
| HU (1) | HUT58456A (zh) |
| MX (1) | MX17402A (zh) |
| MY (1) | MY106597A (zh) |
| NZ (1) | NZ230497A (zh) |
| PL (1) | PL163717B1 (zh) |
| PT (1) | PT91617B (zh) |
| TR (1) | TR26943A (zh) |
| WO (1) | WO1990002486A1 (zh) |
| ZA (1) | ZA896725B (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1303895C (zh) * | 1999-02-10 | 2007-03-14 | 巴斯福股份公司 | 含饲料酶的粒化物 |
| CN101668515B (zh) * | 2007-03-29 | 2013-03-20 | 弗·哈夫曼-拉罗切有限公司 | 药物组合物和方法 |
| WO2013106972A1 (zh) * | 2012-01-19 | 2013-07-25 | 山东潍坊润丰化工有限公司 | 一种2,4-d盐水溶性粒剂及其制备方法 |
| CN107249324A (zh) * | 2015-02-20 | 2017-10-13 | 巴斯夫欧洲公司 | 由聚烷氧基化物、分散剂、糖和聚乙烯基吡咯烷酮制成的农业化学颗粒 |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3834875A1 (de) * | 1988-10-13 | 1990-04-19 | Sandoz Ag | Staubfreie zusammensetzungen |
| JP2770400B2 (ja) * | 1989-04-18 | 1998-07-02 | 住友化学工業株式会社 | 農薬固型製剤 |
| US5599769A (en) * | 1990-11-13 | 1997-02-04 | Hoechst Aktiengesellschaft | Synergistic herbicidal compositions comprising glyphosate or glufosinate in combination with a sulfonylurea herbicide |
| ATE150254T1 (de) * | 1991-01-24 | 1997-04-15 | Monsanto Co | Formulierungen von glyphosaten |
| MY111437A (en) * | 1992-07-31 | 2000-05-31 | Monsanto Co | Improved glyphosate herbicide formulation. |
| FR2704387B1 (fr) | 1993-04-28 | 1995-06-09 | Rhone Poulenc Agrochimie | Compositions concentrees de matieres actives en agriculture. |
| BRPI0508542B1 (pt) | 2004-03-10 | 2014-09-16 | Monsanto Technology Llc | Composições de concentrado herbicida compreendendo glifosato e herbicida auxina |
| US8324132B2 (en) | 2010-03-31 | 2012-12-04 | E. I. Du Pont De Nemours And Company | Mixture and method for controlling undesired vegetation |
| CA2853120C (en) | 2011-10-26 | 2019-12-17 | Monsanto Technology Llc | Salts of carboxylic acid herbicides |
| US10736322B2 (en) | 2012-06-04 | 2020-08-11 | Monsanto Technology Llc | Aqueous concentrated herbicidal compositions containing glyphosate salts and dicamba salts |
| CN104284582B (zh) * | 2012-06-11 | 2017-02-15 | Upl 有限公司 | 除草剂组合物及其工艺 |
| US10285404B2 (en) | 2013-02-27 | 2019-05-14 | Monsanto Technology Llc | Glyphosate composition for dicamba tank mixtures with improved volatility |
| US20210051949A1 (en) * | 2018-03-29 | 2021-02-25 | Upl Ltd | Solid agrochemical compositions |
| AU2022200414A1 (en) * | 2022-01-21 | 2023-08-10 | Leadfarm (Australia) Pty Ltd | Herbicide preparations and processes for manufacture thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA589926A (en) * | 1957-03-16 | 1959-12-29 | E. Creasy Lawrence | Granular pesticides |
| US4015970A (en) * | 1968-09-06 | 1977-04-05 | Airwick Industries, Inc. | Granular products for soil treatment |
| DE3544399A1 (de) * | 1985-12-16 | 1987-06-19 | Sueddeutsche Kalkstickstoff | Verfahren zur herstellung von stickstoffduengern |
| IL87987A0 (en) * | 1987-10-20 | 1989-06-30 | Exxon Chemical Patents Inc | Pesticides coated with sulfonated polymers and their production |
| DE59003725D1 (de) * | 1989-01-18 | 1994-01-20 | Bayer Ag | Flüssige und feste Wirkstoffe enthaltende Trägergranulate. |
-
1989
- 1989-08-30 NZ NZ230497A patent/NZ230497A/en unknown
- 1989-08-31 DE DE68914924T patent/DE68914924T2/de not_active Expired - Fee Related
- 1989-08-31 AU AU41936/89A patent/AU633848B2/en not_active Ceased
- 1989-08-31 EP EP89909940A patent/EP0432200A1/en active Pending
- 1989-08-31 FI FI911052A patent/FI911052A7/fi not_active Application Discontinuation
- 1989-08-31 BR BR898907620A patent/BR8907620A/pt not_active Application Discontinuation
- 1989-08-31 ES ES89308836T patent/ES2063138T3/es not_active Expired - Lifetime
- 1989-08-31 EP EP89308836A patent/EP0360441B1/en not_active Expired - Lifetime
- 1989-08-31 HU HU895769A patent/HUT58456A/hu unknown
- 1989-08-31 KR KR1019900700886A patent/KR900701156A/ko not_active Ceased
- 1989-08-31 JP JP1509282A patent/JPH04500515A/ja active Pending
- 1989-08-31 AT AT8989308836T patent/ATE104827T1/de not_active IP Right Cessation
- 1989-08-31 WO PCT/US1989/003713 patent/WO1990002486A1/en not_active Ceased
- 1989-09-01 MX MX1740289A patent/MX17402A/es unknown
- 1989-09-01 ZA ZA896725A patent/ZA896725B/xx unknown
- 1989-09-01 TR TR00702/89A patent/TR26943A/xx unknown
- 1989-09-01 AR AR89314820A patent/AR244939A1/es active
- 1989-09-01 PT PT91617A patent/PT91617B/pt active IP Right Grant
- 1989-09-01 PL PL89281267A patent/PL163717B1/pl unknown
- 1989-09-02 CN CN89106985A patent/CN1040728A/zh active Pending
- 1989-09-02 MY MYPI89001195A patent/MY106597A/en unknown
-
1991
- 1991-03-01 DK DK037491A patent/DK37491A/da unknown
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1303895C (zh) * | 1999-02-10 | 2007-03-14 | 巴斯福股份公司 | 含饲料酶的粒化物 |
| CN101668515B (zh) * | 2007-03-29 | 2013-03-20 | 弗·哈夫曼-拉罗切有限公司 | 药物组合物和方法 |
| WO2013106972A1 (zh) * | 2012-01-19 | 2013-07-25 | 山东潍坊润丰化工有限公司 | 一种2,4-d盐水溶性粒剂及其制备方法 |
| US9408384B2 (en) | 2012-01-19 | 2016-08-09 | Shandong Weifang Rainbow Chemical Co., Ltd. | Water-soluble granule formulation of 2,4-D salt and preparation method thereof |
| US9854798B2 (en) | 2012-01-19 | 2018-01-02 | Shangdong Weifang Rainbow Chemical Co., Ltd. | Water-soluble granule formulation of 2,4-D salt and preparation method thereof |
| CN107249324A (zh) * | 2015-02-20 | 2017-10-13 | 巴斯夫欧洲公司 | 由聚烷氧基化物、分散剂、糖和聚乙烯基吡咯烷酮制成的农业化学颗粒 |
| US11297832B2 (en) | 2015-02-20 | 2022-04-12 | Basf Se | Agrochemical granules made of polyalkoxylate, dispersant, sugar, and polyvinylpyrrolidone |
Also Published As
| Publication number | Publication date |
|---|---|
| DK37491A (da) | 1991-05-02 |
| HUT58456A (en) | 1992-03-30 |
| KR900701156A (ko) | 1990-12-01 |
| PT91617B (pt) | 1995-05-04 |
| DE68914924D1 (de) | 1994-06-01 |
| AU633848B2 (en) | 1993-02-11 |
| EP0360441A1 (en) | 1990-03-28 |
| TR26943A (tr) | 1994-08-29 |
| AR244939A1 (es) | 1993-12-30 |
| DE68914924T2 (de) | 1994-11-03 |
| MY106597A (en) | 1995-06-30 |
| PT91617A (pt) | 1990-03-30 |
| DK37491D0 (da) | 1991-03-01 |
| ATE104827T1 (de) | 1994-05-15 |
| HU895769D0 (en) | 1991-12-30 |
| JPH04500515A (ja) | 1992-01-30 |
| EP0432200A1 (en) | 1991-06-19 |
| FI911052A0 (fi) | 1991-03-01 |
| BR8907620A (pt) | 1991-07-02 |
| MX17402A (es) | 1993-11-01 |
| EP0360441B1 (en) | 1994-04-27 |
| ES2063138T3 (es) | 1995-01-01 |
| NZ230497A (en) | 1992-05-26 |
| PL163717B1 (pl) | 1994-04-29 |
| FI911052A7 (fi) | 1991-03-01 |
| ZA896725B (en) | 1991-05-29 |
| AU4193689A (en) | 1990-04-02 |
| WO1990002486A1 (en) | 1990-03-22 |
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