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CA3038448C - Hydroxyde de zirconium acide - Google Patents

Hydroxyde de zirconium acide Download PDF

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Publication number
CA3038448C
CA3038448C CA3038448A CA3038448A CA3038448C CA 3038448 C CA3038448 C CA 3038448C CA 3038448 A CA3038448 A CA 3038448A CA 3038448 A CA3038448 A CA 3038448A CA 3038448 C CA3038448 C CA 3038448C
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Canada
Prior art keywords
zirconium
oxide
hydroxide
zirconium hydroxide
doped zirconium
Prior art date
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Active
Application number
CA3038448A
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English (en)
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CA3038448A1 (fr
Inventor
Hazel Stephenson
Iryna CHEPURNA
Deborah Jayne Harris
David SCAPENS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Magnesium Elektron Ltd
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Magnesium Elektron Ltd
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Filing date
Publication date
Priority claimed from PCT/GB2016/053335 external-priority patent/WO2017072509A1/fr
Application filed by Magnesium Elektron Ltd filed Critical Magnesium Elektron Ltd
Publication of CA3038448A1 publication Critical patent/CA3038448A1/fr
Application granted granted Critical
Publication of CA3038448C publication Critical patent/CA3038448C/fr
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G19/00—Compounds of tin
    • C01G19/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/06—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00—Compounds of niobium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G35/00—Compounds of tantalum
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G39/00—Compounds of molybdenum
    • C01G39/02—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C01P2006/13—Surface area thermal stability thereof at high temperatures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un hydroxyde de zirconium ou un oxyde de zirconium comprenant, sur une base d'oxyde, jusqu'à 30 % en poids d'un dopant comprenant un ou plusieurs éléments parmi le silicium, le sulfate, le tungstène, le niobium, l'aluminium, le molybdène, le titane ou l'étain, et ayant des sites acides, la majorité des sites acides étant des sites acides de Lewis. De plus, l'invention concerne un catalyseur, un support ou un précurseur catalyseur, un liant, un liant fonctionnel, un revêtement ou un sorbant comprenant l'hydroxyde de zirconium ou l'oxyde de zirconium. L'invention concerne également un procédé de préparation d'hydroxyde de zirconium, le procédé comprenant les étapes consistant à : (a) dissoudre un sel de zirconium dans un acide aqueux, (b) ajouter un ou plusieurs agents complexants à la solution ou le sol résultant, le ou les agents complexants étant un composé organique comprenant au moins l'un des groupes fonctionnels suivants: une amine, un organosulfate, un sulfonate, un hydroxyle, un éther ou un groupe acide carboxylique, (c) chauffer la solution ou le sol formé à l'étape (b), (d) ajouter un agent de sulfatation, et (e) ajouter une base pour former un hydroxyde de zirconium, et (f) ajouter éventuellement un dopant.
CA3038448A 2016-10-27 2017-01-30 Hydroxyde de zirconium acide Active CA3038448C (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GBPCT/GB2016/053335 2016-10-27
GBPCT/GB2016/053332 2016-10-27
PCT/GB2016/053335 WO2017072509A1 (fr) 2015-10-27 2016-10-27 Compositions à base de zircone destinées à être utilisées comme convertisseurs catalytiques à trois voies
PCT/GB2016/053332 WO2017072507A1 (fr) 2015-10-27 2016-10-27 Solutions de zirconium structurées
PCT/GB2017/050233 WO2018078313A1 (fr) 2016-10-27 2017-01-30 Hydroxyde de zirconium acide

Publications (2)

Publication Number Publication Date
CA3038448A1 CA3038448A1 (fr) 2018-05-03
CA3038448C true CA3038448C (fr) 2023-11-07

Family

ID=57984968

Family Applications (1)

Application Number Title Priority Date Filing Date
CA3038448A Active CA3038448C (fr) 2016-10-27 2017-01-30 Hydroxyde de zirconium acide

Country Status (3)

Country Link
EP (1) EP3532433A1 (fr)
CA (1) CA3038448C (fr)
WO (1) WO2018078313A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11731121B2 (en) * 2020-02-19 2023-08-22 Viridis Chemicals Private Limited Process for preparation of highly coordinated sulfated mixed metal oxide catalyst having high crushing strength
FR3128132A1 (fr) * 2021-10-19 2023-04-21 IFP Energies Nouvelles Catalyseur comprenant un oxyde de zirconium sulfaté dopé
CN116022843A (zh) * 2021-10-26 2023-04-28 中国石油化工股份有限公司 无定形氢氧化锆及其制备方法和应用
JP7162716B1 (ja) 2021-11-01 2022-10-28 第一稀元素化学工業株式会社 水酸化ジルコニウム粉末

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5234870A (en) * 1988-07-21 1993-08-10 Nippon Shokubai Kagaku Kogyo Co., Ltd. Zirconia sol and method for production thereof
JPH11292538A (ja) 1998-04-09 1999-10-26 Daiichi Kigensokagaku Kogyo Co Ltd ジルコニア−セリア組成物の製造方法
JP3985116B2 (ja) 1999-03-04 2007-10-03 第一稀元素化学工業株式会社 水酸化ジルコニウム及びその製造方法
EP1625097B1 (fr) 2003-04-30 2010-08-11 Magnesium Elektron Ltd. Procede de preparation d'oxydes de zirconium et d'oxydes mixtes a base de zirconium
GB0602217D0 (en) 2006-02-03 2006-03-15 Magnesium Elektron Ltd Zirconium hydroxide
AU2013355341A1 (en) * 2012-12-04 2015-06-04 Research Triangle Institute Catalyst compositions and use thereof in catalytic biomass pyrolysis
CN103191712B (zh) * 2013-04-03 2014-12-31 潮州三环（集团）股份有限公司 一种具有良好抗老化性能、高还原活性的氧化铈氧化锆基复合稀土氧化物及其制备方法
JP5744274B1 (ja) * 2014-03-28 2015-07-08 第一稀元素化学工業株式会社 ジルコニア系多孔質体及びその製造方法

Also Published As

Publication number Publication date
WO2018078313A1 (fr) 2018-05-03
CA3038448A1 (fr) 2018-05-03
EP3532433A1 (fr) 2019-09-04

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