CA2038491C - Detersifs - Google Patents

Detersifs

Info

Publication number: CA2038491C
Authority: CA; Canada
Prior art keywords: detergent composition; zeolite map; composition; detergent; citrate
Prior art date: 1990-03-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA002038491A

Other languages

English (en)

Other versions

CA2038491A1 (fr

Inventor

Jelles V. Boskamp

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-03-19

Filing date

1991-03-18

Publication date

1998-08-25

1991-03-18 Application filed by Unilever PLC filed Critical Unilever PLC

1991-09-20 Publication of CA2038491A1 publication Critical patent/CA2038491A1/fr

1998-08-25 Application granted granted Critical

1998-08-25 Publication of CA2038491C publication Critical patent/CA2038491C/fr

2011-03-18 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 75
239000003599 detergent Substances 0.000 title claims abstract description 49
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 55
239000010457 zeolite Substances 0.000 claims abstract description 52
229910021536 Zeolite Inorganic materials 0.000 claims abstract description 49
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims abstract description 22
239000004411 aluminium Substances 0.000 claims abstract description 16
229910052782 aluminium Inorganic materials 0.000 claims abstract description 16
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 16
150000001875 compounds Chemical class 0.000 claims abstract description 16
238000005406 washing Methods 0.000 claims abstract description 10
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 34
239000004744 fabric Substances 0.000 claims description 14
-1 nonionic Chemical group 0.000 claims description 14
150000003839 salts Chemical class 0.000 claims description 14
229910052710 silicon Inorganic materials 0.000 claims description 12
239000010703 silicon Substances 0.000 claims description 12
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 10
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
125000000129 anionic group Chemical group 0.000 claims description 5
229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
239000013078 crystal Substances 0.000 claims description 4
238000000034 method Methods 0.000 claims description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
125000002091 cationic group Chemical group 0.000 claims description 3
229920001577 copolymer Polymers 0.000 claims description 3
238000010936 aqueous wash Methods 0.000 claims description 2
239000007844 bleaching agent Substances 0.000 description 12
229910000323 aluminium silicate Inorganic materials 0.000 description 8
229960004106 citric acid Drugs 0.000 description 8
239000000344 soap Substances 0.000 description 8
239000004615 ingredient Substances 0.000 description 7
239000002736 nonionic surfactant Substances 0.000 description 7
239000000463 material Substances 0.000 description 6
239000002243 precursor Substances 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 5
239000008187 granular material Substances 0.000 description 5
229920000742 Cotton Polymers 0.000 description 4
229920002125 Sokalan® Polymers 0.000 description 4
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
238000004061 bleaching Methods 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
239000008233 hard water Substances 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000002002 slurry Substances 0.000 description 4
239000001509 sodium citrate Substances 0.000 description 4
239000002689 soil Substances 0.000 description 4
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 4
108090000790 Enzymes Proteins 0.000 description 3
102000004190 Enzymes Human genes 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
239000011575 calcium Substances 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
150000001860 citric acid derivatives Chemical class 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 2
244000038022 Chenopodium capitatum Species 0.000 description 2
235000004391 Chenopodium capitatum Nutrition 0.000 description 2
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
229920006243 acrylic copolymer Polymers 0.000 description 2
239000001361 adipic acid Substances 0.000 description 2
235000011037 adipic acid Nutrition 0.000 description 2
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
108010020132 microbial serine proteinases Proteins 0.000 description 2
239000004006 olive oil Substances 0.000 description 2
235000008390 olive oil Nutrition 0.000 description 2
150000004967 organic peroxy acids Chemical class 0.000 description 2
125000000864 peroxy group Chemical group O(O*)* 0.000 description 2
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
150000003333 secondary alcohols Chemical class 0.000 description 2
239000003352 sequestering agent Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
102000005701 Calcium-Binding Proteins Human genes 0.000 description 1
108010045403 Calcium-Binding Proteins Proteins 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
239000005018 casein Substances 0.000 description 1
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
235000021240 caseins Nutrition 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
150000004683 dihydrates Chemical class 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
230000036571 hydration Effects 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000004900 laundering Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000002304 perfume Substances 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
239000000049 pigment Substances 0.000 description 1
238000011020 pilot scale process Methods 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
239000002994 raw material Substances 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000000429 sodium aluminium silicate Substances 0.000 description 1
235000012217 sodium aluminium silicate Nutrition 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
229960000999 sodium citrate dihydrate Drugs 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000008234 soft water Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

CA002038491A 1990-03-19 1991-03-18 Detersifs Expired - Lifetime CA2038491C (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB9006171.4		1990-03-19
GB909006171A GB9006171D0 (en)	1990-03-19	1990-03-19	Detergent compositions

Publications (2)

Publication Number	Publication Date
CA2038491A1 CA2038491A1 (fr)	1991-09-20
CA2038491C true CA2038491C (fr)	1998-08-25

Family

ID=10672874

Family Applications (2)

Application Number	Title	Priority Date	Filing Date
CA002038491A Expired - Lifetime CA2038491C (fr)	1990-03-19	1991-03-18	Detersifs
CA002038490A Abandoned CA2038490A1 (fr)	1990-03-19	1991-03-18	Detersifs

Family Applications After (1)

Application Number	Title	Priority Date	Filing Date
CA002038490A Abandoned CA2038490A1 (fr)	1990-03-19	1991-03-18	Detersifs

Country Status (7)

Country	Link
EP (1)	EP0448298A1 (fr)
JP (1)	JPH04227692A (fr)
AU (1)	AU7296991A (fr)
BR (2)	BR9101075A (fr)
CA (2)	CA2038491C (fr)
GB (2)	GB9006171D0 (fr)
ZA (1)	ZA912024B (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0448297A1 (fr) *	1990-03-19	1991-09-25	Unilever Plc	Compositions détergentes
GB9113675D0 (en) *	1991-06-25	1991-08-14	Unilever Plc	Particulate detergent composition or component
CZ280524B6 (cs) *	1992-01-17	1996-02-14	Unilever Nv	Částicové detergenční směsi
SK278834B6 (sk) *	1992-01-17	1998-03-04	Unilever Nv	Časticová bieliaca detergentná zmes
US6221835B1 (en) *	1999-06-25	2001-04-24	Albemarle Corporation	High density zeolites and their production

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AT330930B (de) *	1973-04-13	1976-07-26	Henkel & Cie Gmbh	Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen
US4605509A (en) *	1973-05-11	1986-08-12	The Procter & Gamble Company	Detergent compositions containing sodium aluminosilicate builders
GB2041394B (en) *	1977-09-26	1982-11-17	Procter & Gamble	Low phosphate detergent composition for fabric washing
US4303556A (en) *	1977-11-02	1981-12-01	The Procter & Gamble Company	Spray-dried detergent compositions
DE2861903D1 (en) *	1977-11-07	1982-08-05	Procter & Gamble	Detergent compositions having improved bleaching effect
JPS601918B2 (ja) *	1980-04-26	1985-01-18	ライオン株式会社	再汚染の少ない無燐洗剤組成物
US4465619A (en) *	1981-11-13	1984-08-14	Lever Brothers Company	Built liquid detergent compositions
GB8502374D0 (en) *	1985-01-30	1985-02-27	Interox Chemicals Ltd	Activation
US4751015A (en) *	1987-03-17	1988-06-14	Lever Brothers Company	Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions
GB8724899D0 (en) *	1987-10-23	1987-11-25	Unilever Plc	Detergent bleach compositions
GB8724900D0 (en) *	1987-10-23	1987-11-25	Unilever Plc	Detergent bleach compositions
CA2001927C (fr) *	1988-11-03	1999-12-21	Graham Thomas Brown	Aluminosilicates et detergents

1990
- 1990-03-19 GB GB909006171A patent/GB9006171D0/en active Pending
1991
- 1991-03-05 GB GB919104613A patent/GB9104613D0/en active Pending
- 1991-03-15 EP EP19910302218 patent/EP0448298A1/fr not_active Withdrawn
- 1991-03-18 CA CA002038491A patent/CA2038491C/fr not_active Expired - Lifetime
- 1991-03-18 CA CA002038490A patent/CA2038490A1/fr not_active Abandoned
- 1991-03-19 AU AU72969/91A patent/AU7296991A/en not_active Abandoned
- 1991-03-19 JP JP3130756A patent/JPH04227692A/ja active Pending
- 1991-03-19 ZA ZA912024A patent/ZA912024B/xx unknown
- 1991-03-19 BR BR919101075A patent/BR9101075A/pt unknown
- 1991-03-19 BR BR919101074A patent/BR9101074A/pt not_active Application Discontinuation

Also Published As

Publication number	Publication date
GB9104613D0 (en)	1991-04-17
BR9101074A (pt)	1991-11-05
JPH04227692A (ja)	1992-08-17
CA2038490A1 (fr)	1991-09-20
ZA912024B (en)	1992-11-25
CA2038491A1 (fr)	1991-09-20
EP0448298A1 (fr)	1991-09-25
AU7296991A (en)	1991-09-19
BR9101075A (pt)	1991-11-05
GB9006171D0 (en)	1990-05-16

Publication	Publication Date	Title
CA1291390C (fr)	1991-10-29	Poudres detersives contenant du succinate et un polycarboxylate polymerique
CA1328065C (fr)	1994-03-29	Compositions detergentes
MXPA05004773A (es)	2005-08-02	Composicion de detergente de lavanderia.
EP0448297A1 (fr)	1991-09-25	Compositions détergentes
US4988454A (en)	1991-01-29	Low phosphorus containing detergent powders and process for preparing them: surfactant, aluminosilicate, sodium silicate and polyacrylate
EP0358473B2 (fr)	1997-12-10	Compositions détergentes
CA2062032C (fr)	1998-06-09	Detergent
CA1323276C (fr)	1993-10-19	Compositions detergentes
AU625910B2 (en)	1992-07-16	Detergent compositions
CA1316790C (fr)	1993-04-27	Compositions de blanchissage sans phosphore
EP0533392B1 (fr)	1998-05-13	Compositions détergentes
CA2038491C (fr)	1998-08-25	Detersifs
US5854198A (en)	1998-12-29	Particulate aluminosilicate-built detergent compositions comprising cogranules of zeolite map and alkali metal silicate
EP0095904B1 (fr)	1986-09-03	Détergents liquides et compositions pour leur utilisation
EP0242141A2 (fr)	1987-10-21	Poudres détergentes et leur procédé de préparation
US6448218B2 (en)	2002-09-10	Modified aluminosilicate
EP0774505B1 (fr)	2001-11-21	Compositions détergentes
JPH04277599A (ja)	1992-10-02	洗剤組成物
JPH01188596A (ja)	1989-07-27	アルミノシリケートをビルダーとする洗剤漂白剤組成物

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