CA1270076A - Capteurs pour la flottation selective sur mousse de minerais sulfures - Google Patents

Capteurs pour la flottation selective sur mousse de minerais sulfures

Info

Publication number: CA1270076A
Authority: CA; Canada
Prior art keywords: sulfide; metal; minerals; collector; froth
Prior art date: 1985-05-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000501884A

Other languages

English (en)

Inventor

Edwin J. Strojny

Richard R. Klimpel

Robert D. Hansen

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-05-31

Filing date

1986-02-14

Publication date

1990-06-05

1986-02-14 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1990-06-05 Application granted granted Critical

1990-06-05 Publication of CA1270076A publication Critical patent/CA1270076A/fr

2007-06-05 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000009291 froth flotation Methods 0.000 title claims abstract description 27
150000003568 thioethers Chemical class 0.000 title claims description 6
229910052500 inorganic mineral Inorganic materials 0.000 title description 54
239000011707 mineral Substances 0.000 title description 54
229910052751 metal Inorganic materials 0.000 claims abstract description 84
239000002184 metal Substances 0.000 claims abstract description 84
229910052569 sulfide mineral Inorganic materials 0.000 claims abstract description 62
238000000034 method Methods 0.000 claims abstract description 55
229910052592 oxide mineral Inorganic materials 0.000 claims abstract description 34
125000001931 aliphatic group Chemical group 0.000 claims abstract description 23
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 16
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 26
239000010949 copper Substances 0.000 claims description 23
-1 cycloaliphatic Chemical group 0.000 claims description 22
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 21
125000000217 alkyl group Chemical group 0.000 claims description 21
229910052802 copper Inorganic materials 0.000 claims description 21
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
125000003118 aryl group Chemical group 0.000 claims description 16
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 13
229910052750 molybdenum Inorganic materials 0.000 claims description 13
239000011733 molybdenum Substances 0.000 claims description 13
239000011701 zinc Substances 0.000 claims description 12
229910052739 hydrogen Inorganic materials 0.000 claims description 11
239000001257 hydrogen Substances 0.000 claims description 11
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
125000001183 hydrocarbyl group Chemical group 0.000 claims description 9
239000011133 lead Substances 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 9
229910052725 zinc Inorganic materials 0.000 claims description 9
150000001875 compounds Chemical class 0.000 claims description 8
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
229910052759 nickel Inorganic materials 0.000 claims description 8
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 7
229910052770 Uranium Inorganic materials 0.000 claims description 6
229910052951 chalcopyrite Inorganic materials 0.000 claims description 6
DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 claims description 6
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 6
150000002894 organic compounds Chemical class 0.000 claims description 6
JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical group N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 6
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
229910052804 chromium Inorganic materials 0.000 claims description 5
239000011651 chromium Substances 0.000 claims description 5
XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims description 5
229910052954 pentlandite Inorganic materials 0.000 claims description 5
229910052709 silver Inorganic materials 0.000 claims description 5
239000004332 silver Substances 0.000 claims description 5
FOJGPFUFFHWGFQ-UHFFFAOYSA-N 1-(Methylthio)pentane Chemical group CCCCCSC FOJGPFUFFHWGFQ-UHFFFAOYSA-N 0.000 claims description 4
PYPULUCCVXMPFP-UHFFFAOYSA-N 1-ethylsulfanylheptane Chemical compound CCCCCCCSCC PYPULUCCVXMPFP-UHFFFAOYSA-N 0.000 claims description 4
MGVUJBCOCITTRS-UHFFFAOYSA-N 1-ethylsulfanylhexane Chemical compound CCCCCCSCC MGVUJBCOCITTRS-UHFFFAOYSA-N 0.000 claims description 4
WAITXWGCJQLPGH-UHFFFAOYSA-N 1-ethylsulfanyloctane Chemical compound CCCCCCCCSCC WAITXWGCJQLPGH-UHFFFAOYSA-N 0.000 claims description 4
FJDWJOQOEZRIDJ-UHFFFAOYSA-N 1-methylsulfanylheptane Chemical compound CCCCCCCSC FJDWJOQOEZRIDJ-UHFFFAOYSA-N 0.000 claims description 4
LZRXQHHKXDXOIC-UHFFFAOYSA-N 1-methylsulfanylhexane Chemical compound CCCCCCSC LZRXQHHKXDXOIC-UHFFFAOYSA-N 0.000 claims description 4
AHCJTMBRROLNHV-UHFFFAOYSA-N 1-methylsulfanyloctane Chemical compound CCCCCCCCSC AHCJTMBRROLNHV-UHFFFAOYSA-N 0.000 claims description 4
229910052948 bornite Inorganic materials 0.000 claims description 4
229910052961 molybdenite Inorganic materials 0.000 claims description 4
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical group OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
229910052785 arsenic Inorganic materials 0.000 claims description 3
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
229910017052 cobalt Inorganic materials 0.000 claims description 3
239000010941 cobalt Substances 0.000 claims description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
229910052949 galena Inorganic materials 0.000 claims description 3
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
229910052737 gold Inorganic materials 0.000 claims description 3
239000010931 gold Substances 0.000 claims description 3
229910052736 halogen Inorganic materials 0.000 claims description 3
150000002367 halogens Chemical group 0.000 claims description 3
150000002431 hydrogen Chemical group 0.000 claims description 3
229910052697 platinum Inorganic materials 0.000 claims description 3
SOGIWVXLDPPMMF-UHFFFAOYSA-N 1-ethylsulfanylpentane Chemical compound CCCCCSCC SOGIWVXLDPPMMF-UHFFFAOYSA-N 0.000 claims description 2
OTQVGYMGQKHLMY-UHFFFAOYSA-N Cyclopentyl-1-thiaethane Chemical compound CSC1CCCC1 OTQVGYMGQKHLMY-UHFFFAOYSA-N 0.000 claims description 2
239000004593 Epoxy Chemical group 0.000 claims description 2
QQBIOCGHCKNYGP-UHFFFAOYSA-N Methylsulfanylcyclohexane Chemical compound CSC1CCCCC1 QQBIOCGHCKNYGP-UHFFFAOYSA-N 0.000 claims description 2
125000002947 alkylene group Chemical group 0.000 claims description 2
MSFZETFHSWQOQR-UHFFFAOYSA-N ethylsulfanylcyclohexane Chemical compound CCSC1CCCCC1 MSFZETFHSWQOQR-UHFFFAOYSA-N 0.000 claims description 2
CKEKUCLCUOABGC-UHFFFAOYSA-N ethylsulfanylcyclooctane Chemical compound CCSC1CCCCCCC1 CKEKUCLCUOABGC-UHFFFAOYSA-N 0.000 claims description 2
UAGKPNGGDLTAAC-UHFFFAOYSA-N ethylsulfanylcyclopentane Chemical compound CCSC1CCCC1 UAGKPNGGDLTAAC-UHFFFAOYSA-N 0.000 claims description 2
125000000743 hydrocarbylene group Chemical group 0.000 claims description 2
RYGZLCAZWIWVMP-UHFFFAOYSA-N methylsulfanylcycloheptane Chemical compound CSC1CCCCCC1 RYGZLCAZWIWVMP-UHFFFAOYSA-N 0.000 claims description 2
ZJLHAKQYBVOBCX-UHFFFAOYSA-N methylsulfanylcyclooctane Chemical compound CSC1CCCCCCC1 ZJLHAKQYBVOBCX-UHFFFAOYSA-N 0.000 claims description 2
229910052950 sphalerite Inorganic materials 0.000 claims 2
DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims 2
125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
241000854350 Enicospilus group Species 0.000 claims 1
125000003700 epoxy group Chemical group 0.000 claims 1
238000005188 flotation Methods 0.000 abstract description 31
150000002430 hydrocarbons Chemical class 0.000 abstract description 14
229910052799 carbon Inorganic materials 0.000 abstract description 13
229930195733 hydrocarbon Natural products 0.000 abstract description 12
239000004215 Carbon black (E152) Substances 0.000 abstract description 11
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 10
239000002245 particle Substances 0.000 abstract description 8
230000002209 hydrophobic effect Effects 0.000 abstract description 6
125000004434 sulfur atom Chemical group 0.000 abstract description 5
235000010755 mineral Nutrition 0.000 description 53
238000011084 recovery Methods 0.000 description 26
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 22
239000012141 concentrate Substances 0.000 description 13
125000005843 halogen group Chemical group 0.000 description 11
235000016768 molybdenum Nutrition 0.000 description 11
235000008733 Citrus aurantifolia Nutrition 0.000 description 10
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
235000011941 Tilia x europaea Nutrition 0.000 description 10
125000004093 cyano group Chemical group *C#N 0.000 description 10
125000004356 hydroxy functional group Chemical group O* 0.000 description 10
229910052742 iron Inorganic materials 0.000 description 10
239000004571 lime Substances 0.000 description 10
125000003342 alkenyl group Chemical group 0.000 description 9
239000007787 solid Substances 0.000 description 9
WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 8
239000007788 liquid Substances 0.000 description 8
229910052952 pyrrhotite Inorganic materials 0.000 description 8
229910052717 sulfur Inorganic materials 0.000 description 8
125000000753 cycloalkyl group Chemical group 0.000 description 7
239000007789 gas Substances 0.000 description 7
229910052683 pyrite Inorganic materials 0.000 description 7
NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 7
239000011028 pyrite Substances 0.000 description 7
125000003710 aryl alkyl group Chemical group 0.000 description 6
125000000392 cycloalkenyl group Chemical group 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
125000000623 heterocyclic group Chemical group 0.000 description 5
239000005077 polysulfide Substances 0.000 description 5
229920001021 polysulfide Polymers 0.000 description 5
150000008117 polysulfides Polymers 0.000 description 5
239000011593 sulfur Substances 0.000 description 5
238000003723 Smelting Methods 0.000 description 4
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
238000013019 agitation Methods 0.000 description 4
125000002877 alkyl aryl group Chemical group 0.000 description 4
125000000304 alkynyl group Chemical group 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
238000003556 assay Methods 0.000 description 4
230000003750 conditioning effect Effects 0.000 description 4
150000002019 disulfides Chemical class 0.000 description 4
239000000463 material Substances 0.000 description 4
229910052976 metal sulfide Inorganic materials 0.000 description 4
239000002002 slurry Substances 0.000 description 4
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 4
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
241000196324 Embryophyta Species 0.000 description 3
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 3
150000001335 aliphatic alkanes Chemical class 0.000 description 3
229910000366 copper(II) sulfate Inorganic materials 0.000 description 3
150000001924 cycloalkanes Chemical class 0.000 description 3
150000001925 cycloalkenes Chemical class 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 3
229910000029 sodium carbonate Inorganic materials 0.000 description 3
239000012991 xanthate Substances 0.000 description 3
LUAABLIRQSWMGZ-UHFFFAOYSA-N 1-ethylsulfanylnonane Chemical compound CCCCCCCCCSCC LUAABLIRQSWMGZ-UHFFFAOYSA-N 0.000 description 2
LEMIDOZYVQXGLI-UHFFFAOYSA-N 1-heptylsulfanylheptane Chemical compound CCCCCCCSCCCCCCC LEMIDOZYVQXGLI-UHFFFAOYSA-N 0.000 description 2
LHNRHYOMDUJLLM-UHFFFAOYSA-N 1-hexylsulfanylhexane Chemical compound CCCCCCSCCCCCC LHNRHYOMDUJLLM-UHFFFAOYSA-N 0.000 description 2
HKGUUZAACYBIID-UHFFFAOYSA-N 1-methylsulfanyldecane Chemical compound CCCCCCCCCCSC HKGUUZAACYBIID-UHFFFAOYSA-N 0.000 description 2
FCRSULZJMFDBIK-UHFFFAOYSA-N 1-methylsulfanylnonane Chemical compound CCCCCCCCCSC FCRSULZJMFDBIK-UHFFFAOYSA-N 0.000 description 2
LOXRGHGHQYWXJK-UHFFFAOYSA-N 1-octylsulfanyloctane Chemical compound CCCCCCCCSCCCCCCCC LOXRGHGHQYWXJK-UHFFFAOYSA-N 0.000 description 2
JOZDADPMWLVEJK-UHFFFAOYSA-N 1-pentylsulfanylpentane Chemical compound CCCCCSCCCCC JOZDADPMWLVEJK-UHFFFAOYSA-N 0.000 description 2
HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 2
229910002555 FeNi Inorganic materials 0.000 description 2
ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
KUGRPPRAQNPSQD-UHFFFAOYSA-N OOOOO Chemical compound OOOOO KUGRPPRAQNPSQD-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000001345 alkine derivatives Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052932 antlerite Inorganic materials 0.000 description 2
229910052972 bournonite Inorganic materials 0.000 description 2
150000001721 carbon Chemical group 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
BUGICWZUDIWQRQ-UHFFFAOYSA-N copper iron sulfane Chemical compound S.[Fe].[Cu] BUGICWZUDIWQRQ-UHFFFAOYSA-N 0.000 description 2
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
239000008367 deionised water Substances 0.000 description 2
229910021641 deionized water Inorganic materials 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
235000011007 phosphoric acid Nutrition 0.000 description 2
239000010665 pine oil Substances 0.000 description 2
229920001451 polypropylene glycol Polymers 0.000 description 2
238000000926 separation method Methods 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
229910052979 sodium sulfide Inorganic materials 0.000 description 2
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 2
RFKHZOHSRQNNPW-UHFFFAOYSA-M sodium;pentoxymethanedithioate Chemical compound [Na+].CCCCCOC([S-])=S RFKHZOHSRQNNPW-UHFFFAOYSA-M 0.000 description 2
229910052959 stibnite Inorganic materials 0.000 description 2
239000000126 substance Substances 0.000 description 2
WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical group [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 2
150000003464 sulfur compounds Chemical class 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
239000011135 tin Substances 0.000 description 2
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
239000010936 titanium Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
229910000442 triuranium octoxide Inorganic materials 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
229910000010 zinc carbonate Inorganic materials 0.000 description 2
CLBLVLKZMJDLOT-UHFFFAOYSA-N 1-butylsulfanyldecane Chemical compound CCCCCCCCCCSCCCC CLBLVLKZMJDLOT-UHFFFAOYSA-N 0.000 description 1
BGSBXDJLUNXANY-UHFFFAOYSA-N 1-butylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCC BGSBXDJLUNXANY-UHFFFAOYSA-N 0.000 description 1
HYUPOCGXBZUYFY-UHFFFAOYSA-N 1-butylsulfanylheptane Chemical compound CCCCCCCSCCCC HYUPOCGXBZUYFY-UHFFFAOYSA-N 0.000 description 1
YZUHMAFUXBPUKH-UHFFFAOYSA-N 1-butylsulfanylhexane Chemical compound CCCCCCSCCCC YZUHMAFUXBPUKH-UHFFFAOYSA-N 0.000 description 1
FWRIVMHSSSZAFD-UHFFFAOYSA-N 1-butylsulfanylnonane Chemical compound CCCCCCCCCSCCCC FWRIVMHSSSZAFD-UHFFFAOYSA-N 0.000 description 1
UNIAPWPIAGJFDG-UHFFFAOYSA-N 1-butylsulfanyloctane Chemical compound CCCCCCCCSCCCC UNIAPWPIAGJFDG-UHFFFAOYSA-N 0.000 description 1
RNEUXBDXTNIASG-UHFFFAOYSA-N 1-butylsulfanylpentane Chemical compound CCCCCSCCCC RNEUXBDXTNIASG-UHFFFAOYSA-N 0.000 description 1
RKYMVQJWYYOIJB-UHFFFAOYSA-N 1-decylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCCCC RKYMVQJWYYOIJB-UHFFFAOYSA-N 0.000 description 1
XLWHZUYTRGNUML-UHFFFAOYSA-N 1-decylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCCC XLWHZUYTRGNUML-UHFFFAOYSA-N 0.000 description 1
KISJDFYRGLOOKC-UHFFFAOYSA-N 1-decylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCCCCCC KISJDFYRGLOOKC-UHFFFAOYSA-N 0.000 description 1
XJIRSLHMKBUGMR-UHFFFAOYSA-N 1-ethylsulfanylbutane Chemical compound CCCCSCC XJIRSLHMKBUGMR-UHFFFAOYSA-N 0.000 description 1
VSSRSPLEFYQIEK-UHFFFAOYSA-N 1-ethylsulfanyldecane Chemical compound CCCCCCCCCCSCC VSSRSPLEFYQIEK-UHFFFAOYSA-N 0.000 description 1
QECBTJWQRXCSCU-UHFFFAOYSA-N 1-ethylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCC QECBTJWQRXCSCU-UHFFFAOYSA-N 0.000 description 1
OSWITQLVZPPUIR-UHFFFAOYSA-N 1-ethylsulfanylundecane Chemical compound CCCCCCCCCCCSCC OSWITQLVZPPUIR-UHFFFAOYSA-N 0.000 description 1
HYNUNWWVWIDFNI-UHFFFAOYSA-N 1-heptylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCC HYNUNWWVWIDFNI-UHFFFAOYSA-N 0.000 description 1
BMONIUVCBPWHMH-UHFFFAOYSA-N 1-heptylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCC BMONIUVCBPWHMH-UHFFFAOYSA-N 0.000 description 1
RGMJJEGCPWGPIO-UHFFFAOYSA-N 1-heptylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCC RGMJJEGCPWGPIO-UHFFFAOYSA-N 0.000 description 1
YIQMNWHXSGQHED-UHFFFAOYSA-N 1-heptylsulfanyloctane Chemical compound CCCCCCCCSCCCCCCC YIQMNWHXSGQHED-UHFFFAOYSA-N 0.000 description 1
VOSRYWCOCVSNOU-UHFFFAOYSA-N 1-heptylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCCC VOSRYWCOCVSNOU-UHFFFAOYSA-N 0.000 description 1
AHFXEIBVMODMFA-UHFFFAOYSA-N 1-hexylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCC AHFXEIBVMODMFA-UHFFFAOYSA-N 0.000 description 1
UUGCJTQYUMVCAB-UHFFFAOYSA-N 1-hexylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCC UUGCJTQYUMVCAB-UHFFFAOYSA-N 0.000 description 1
MPSAONKRRWETTC-UHFFFAOYSA-N 1-hexylsulfanylheptane Chemical compound CCCCCCCSCCCCCC MPSAONKRRWETTC-UHFFFAOYSA-N 0.000 description 1
OSCWDJOYYNCZON-UHFFFAOYSA-N 1-hexylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCC OSCWDJOYYNCZON-UHFFFAOYSA-N 0.000 description 1
KNTKPCSIJNUXBH-UHFFFAOYSA-N 1-hexylsulfanyloctane Chemical compound CCCCCCCCSCCCCCC KNTKPCSIJNUXBH-UHFFFAOYSA-N 0.000 description 1
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DOTUVVYROYQYEQ-UHFFFAOYSA-N 1-nonylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCCCCC DOTUVVYROYQYEQ-UHFFFAOYSA-N 0.000 description 1
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WTHWPAWEPUFSPY-UHFFFAOYSA-N 1-pentylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCC WTHWPAWEPUFSPY-UHFFFAOYSA-N 0.000 description 1
VPJKGHGSHVZXRB-UHFFFAOYSA-N 1-pentylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCC VPJKGHGSHVZXRB-UHFFFAOYSA-N 0.000 description 1
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AYFCJZQIPPBHOA-UHFFFAOYSA-N 1-pentylsulfanyloctane Chemical compound CCCCCCCCSCCCCC AYFCJZQIPPBHOA-UHFFFAOYSA-N 0.000 description 1
WZIAQSSOQOQJCO-UHFFFAOYSA-N 1-pentylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCC WZIAQSSOQOQJCO-UHFFFAOYSA-N 0.000 description 1
ZBRWJPVULTZZCE-UHFFFAOYSA-N 1-propylsulfanylbutane Chemical compound CCCCSCCC ZBRWJPVULTZZCE-UHFFFAOYSA-N 0.000 description 1
HPJCKXDELORROO-UHFFFAOYSA-N 1-propylsulfanyldecane Chemical compound CCCCCCCCCCSCCC HPJCKXDELORROO-UHFFFAOYSA-N 0.000 description 1
JSIGETQGUMEVQW-UHFFFAOYSA-N 1-propylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCC JSIGETQGUMEVQW-UHFFFAOYSA-N 0.000 description 1
PCPVCHFKVPNTBH-UHFFFAOYSA-N 1-propylsulfanylheptane Chemical compound CCCCCCCSCCC PCPVCHFKVPNTBH-UHFFFAOYSA-N 0.000 description 1
ABZLKKGJOVPBBL-UHFFFAOYSA-N 1-propylsulfanylhexane Chemical compound CCCCCCSCCC ABZLKKGJOVPBBL-UHFFFAOYSA-N 0.000 description 1
AQAOPNMAEGBYHI-UHFFFAOYSA-N 1-propylsulfanylnonane Chemical compound CCCCCCCCCSCCC AQAOPNMAEGBYHI-UHFFFAOYSA-N 0.000 description 1
GPJXDRJGQAKGLH-UHFFFAOYSA-N 1-propylsulfanyloctane Chemical compound CCCCCCCCSCCC GPJXDRJGQAKGLH-UHFFFAOYSA-N 0.000 description 1
MJRCCWJSYFOGBX-UHFFFAOYSA-N 1-propylsulfanylpentane Chemical compound CCCCCSCCC MJRCCWJSYFOGBX-UHFFFAOYSA-N 0.000 description 1
ITNOZFAANYXVSG-UHFFFAOYSA-N 1-propylsulfanylundecane Chemical compound CCCCCCCCCCCSCCC ITNOZFAANYXVSG-UHFFFAOYSA-N 0.000 description 1
BCFOOQRXUXKJCL-UHFFFAOYSA-N 4-amino-4-oxo-2-sulfobutanoic acid Chemical class NC(=O)CC(C(O)=O)S(O)(=O)=O BCFOOQRXUXKJCL-UHFFFAOYSA-N 0.000 description 1
ZOLACKDSSUBCNN-UHFFFAOYSA-N 5,6-dimethylcyclohexa-2,4-diene-1-carboxylic acid Chemical class CC1C(C(O)=O)C=CC=C1C ZOLACKDSSUBCNN-UHFFFAOYSA-N 0.000 description 1
108091005950 Azurite Proteins 0.000 description 1
229910004647 CaMoO4 Inorganic materials 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
241000907663 Siproeta stelenes Species 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
150000005215 alkyl ethers Chemical class 0.000 description 1
125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
150000005347 biaryls Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052933 brochantite Inorganic materials 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
KQBUVDBNXZACHN-UHFFFAOYSA-N butylsulfanylcyclohexane Chemical compound CCCCSC1CCCCC1 KQBUVDBNXZACHN-UHFFFAOYSA-N 0.000 description 1
DFDXFLWUTXLANA-UHFFFAOYSA-N butylsulfanylcyclooctane Chemical compound CCCCSC1CCCCCCC1 DFDXFLWUTXLANA-UHFFFAOYSA-N 0.000 description 1
DALIGXBOEDZLRG-UHFFFAOYSA-N butylsulfanylcyclopentane Chemical compound CCCCSC1CCCC1 DALIGXBOEDZLRG-UHFFFAOYSA-N 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
229910052947 chalcocite Inorganic materials 0.000 description 1
KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
229910000365 copper sulfate Inorganic materials 0.000 description 1
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
PTVDYARBVCBHSL-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu] PTVDYARBVCBHSL-UHFFFAOYSA-N 0.000 description 1
LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000010431 corundum Substances 0.000 description 1
150000001896 cresols Chemical class 0.000 description 1
KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
DQXXYXQMGCYQRE-UHFFFAOYSA-N decylsulfanylcyclohexane Chemical compound CCCCCCCCCCSC1CCCCC1 DQXXYXQMGCYQRE-UHFFFAOYSA-N 0.000 description 1
ZFIYLIBUWJKJIG-UHFFFAOYSA-N decylsulfanylcyclooctane Chemical compound CCCCCCCCCCSC1CCCCCCC1 ZFIYLIBUWJKJIG-UHFFFAOYSA-N 0.000 description 1
PAIKZSPJVHZUJD-UHFFFAOYSA-N decylsulfanylcyclopentane Chemical compound CCCCCCCCCCSC1CCCC1 PAIKZSPJVHZUJD-UHFFFAOYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
ZXOKVTWPEIAYAB-UHFFFAOYSA-N dioxido(oxo)tungsten Chemical compound [O-][W]([O-])=O ZXOKVTWPEIAYAB-UHFFFAOYSA-N 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910052971 enargite Inorganic materials 0.000 description 1
ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical class CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
ROXRBYVOLWVJBB-UHFFFAOYSA-N ethylsulfanylcycloheptane Chemical compound CCSC1CCCCCC1 ROXRBYVOLWVJBB-UHFFFAOYSA-N 0.000 description 1
239000010642 eucalyptus oil Substances 0.000 description 1
229940044949 eucalyptus oil Drugs 0.000 description 1
239000008396 flotation agent Substances 0.000 description 1
150000004675 formic acid derivatives Chemical class 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
229910052595 hematite Inorganic materials 0.000 description 1
239000011019 hematite Substances 0.000 description 1
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
OERSGBOBUAUJQI-UHFFFAOYSA-N heptylsulfanylcycloheptane Chemical compound CCCCCCCSC1CCCCCC1 OERSGBOBUAUJQI-UHFFFAOYSA-N 0.000 description 1
RMUGCJVAFZVYJS-UHFFFAOYSA-N heptylsulfanylcyclohexane Chemical compound CCCCCCCSC1CCCCC1 RMUGCJVAFZVYJS-UHFFFAOYSA-N 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
JBEQZWDPBLEDRR-UHFFFAOYSA-N hexylsulfanylcycloheptane Chemical compound CCCCCCSC1CCCCCC1 JBEQZWDPBLEDRR-UHFFFAOYSA-N 0.000 description 1
QKNNUJPOAKHROZ-UHFFFAOYSA-N hexylsulfanylcyclooctane Chemical compound CCCCCCSC1CCCCCCC1 QKNNUJPOAKHROZ-UHFFFAOYSA-N 0.000 description 1
WCNZLOREXFVTDK-UHFFFAOYSA-N hexylsulfanylcyclopentane Chemical compound CCCCCCSC1CCCC1 WCNZLOREXFVTDK-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
229910052945 inorganic sulfide Inorganic materials 0.000 description 1
125000002346 iodo group Chemical group I* 0.000 description 1
IXQWNVPHFNLUGD-UHFFFAOYSA-N iron titanium Chemical compound [Ti].[Fe] IXQWNVPHFNLUGD-UHFFFAOYSA-N 0.000 description 1
LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
239000003607 modifier Substances 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
RXCAQFBDHQGCFO-UHFFFAOYSA-N nonylsulfanylcycloheptane Chemical compound CCCCCCCCCSC1CCCCCC1 RXCAQFBDHQGCFO-UHFFFAOYSA-N 0.000 description 1
OFHCVKLZOCPXNZ-UHFFFAOYSA-N nonylsulfanylcyclooctane Chemical compound CCCCCCCCCSC1CCCCCCC1 OFHCVKLZOCPXNZ-UHFFFAOYSA-N 0.000 description 1
KGFMETWHGMSZOD-UHFFFAOYSA-N nonylsulfanylcyclopentane Chemical compound CCCCCCCCCSC1CCCC1 KGFMETWHGMSZOD-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
FFIIPKBXAWXOHB-UHFFFAOYSA-N octylsulfanylcyclooctane Chemical compound CCCCCCCCSC1CCCCCCC1 FFIIPKBXAWXOHB-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
QELIZJUXYUEORW-UHFFFAOYSA-N pentylsulfanylcycloheptane Chemical compound CCCCCSC1CCCCCC1 QELIZJUXYUEORW-UHFFFAOYSA-N 0.000 description 1
RKCRLYNCLIKFOM-UHFFFAOYSA-N pentylsulfanylcyclohexane Chemical compound CCCCCSC1CCCCC1 RKCRLYNCLIKFOM-UHFFFAOYSA-N 0.000 description 1
STHWWWFZOXANKN-UHFFFAOYSA-N pentylsulfanylcyclopentane Chemical compound CCCCCSC1CCCC1 STHWWWFZOXANKN-UHFFFAOYSA-N 0.000 description 1
125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
125000003367 polycyclic group Chemical group 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
GRTPNKMNAOQMOK-UHFFFAOYSA-N propylsulfanylcyclohexane Chemical compound CCCSC1CCCCC1 GRTPNKMNAOQMOK-UHFFFAOYSA-N 0.000 description 1
RQCUQPZTBNLEHH-UHFFFAOYSA-N propylsulfanylcyclooctane Chemical compound CCCSC1CCCCCCC1 RQCUQPZTBNLEHH-UHFFFAOYSA-N 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
239000000344 soap Substances 0.000 description 1
HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000002311 subsequent effect Effects 0.000 description 1
PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229910052970 tennantite Inorganic materials 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
229910052969 tetrahedrite Inorganic materials 0.000 description 1
125000000101 thioether group Chemical group 0.000 description 1
150000003585 thioureas Chemical class 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000012989 trithiocarbonate Substances 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
YIIYNAOHYJJBHT-UHFFFAOYSA-N uranium;dihydrate Chemical compound O.O.[U] YIIYNAOHYJJBHT-UHFFFAOYSA-N 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores

Landscapes

Manufacture And Refinement Of Metals (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Treatment Of Water By Oxidation Or Reduction (AREA)

CA000501884A 1985-05-31 1986-02-14 Capteurs pour la flottation selective sur mousse de minerais sulfures Expired - Lifetime CA1270076A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US74009185A	1985-05-31	1985-05-31
US740,091		1985-05-31

Publications (1)

Publication Number	Publication Date
CA1270076A true CA1270076A (fr)	1990-06-05

Family

ID=24975003

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000501884A Expired - Lifetime CA1270076A (fr)	1985-05-31	1986-02-14	Capteurs pour la flottation selective sur mousse de minerais sulfures

Country Status (17)

Country	Link
JP (1)	JPS63100961A (fr)
CN (1)	CN1011765B (fr)
AU (1)	AU576665B2 (fr)
BR (1)	BR8606705A (fr)
CA (1)	CA1270076A (fr)
ES (1)	ES8800077A1 (fr)
FI (1)	FI80834C (fr)
PH (1)	PH23738A (fr)
PL (1)	PL147849B1 (fr)
RO (1)	RO100591B1 (fr)
SE (1)	SE500499C2 (fr)
SU (1)	SU1582978A3 (fr)
WO (1)	WO1986006983A1 (fr)
YU (1)	YU45768B (fr)
ZA (1)	ZA861169B (fr)
ZM (1)	ZM1286A1 (fr)
ZW (1)	ZW4086A1 (fr)

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US4732667A (en) *	1985-02-20	1988-03-22	Berol Kemi Ab	Process and composition for the froth flotation beneficiation of iron minerals from iron ores
ZM1386A1 (en) *	1985-07-12	1988-12-30	Dow Chemical Co	Novel collector compositions for froth flotation
CA1268565A (fr) *	1985-11-29	1990-05-01	Richard R. Klimpel	Compositions de captage pour la flottation sur mousse de minerais
WO1993004783A1 (fr) *	1991-08-28	1993-03-18	Commonwealth Scientific And Industrial Research Organisation	Traitement de minerais
RU2167001C2 (ru) *	1999-07-06	2001-05-20	ОАО "Норильский горно-металлургический комбинат им. А.П. Завенягина"	Способ обогащения сульфидных медно-никелевых руд, содержащих металлы платиновой группы
RU2390382C2 (ru) *	2008-04-15	2010-05-27	Учреждение Российской академии наук Институт проблем комплексного освоения недр РАН (УРАН ИПКОН РАН)	Способ извлечения цветных и благородных металлов
RU2368427C1 (ru) *	2008-04-15	2009-09-27	Институт проблем комплексного освоения недр РАН (ИПКОН РАН)	Способ флотации благородных металлов
RU2393925C1 (ru) *	2008-11-19	2010-07-10	Александр Юрьевич Хмельник	Способ флотационного разделения сульфидов, включающих благородные металлы из полиметаллических железосодержащих руд, и композиционный материал для его реализации
MX2014004720A (es) *	2011-10-18	2014-11-26	Cytec Tech Corp	Procesos de flotacion por espuma.
CN102631993A (zh) *	2012-03-20	2012-08-15	北京矿冶研究总院	一种浮选硫化铜矿的方法
CN103977907B (zh) *	2014-05-15	2016-03-23	中南大学	一种黄原酸酰基酯捕收剂及其制备和应用方法
US10294200B2 (en)	2015-12-28	2019-05-21	Chevron Phillips Chemical Company, Lp	Mixed branched eicosyl polysulfide compositions and methods of making same
US10040758B2 (en)	2015-12-28	2018-08-07	Chevron Phillips Chemical Company Lp	Mixed decyl mercaptans compositions and methods of making same
US9505011B1 (en) *	2015-12-28	2016-11-29	Chevron Phillips Chemical Company Lp	Mixed decyl mercaptans compositions and use thereof as mining chemical collectors
US10011564B2 (en)	2015-12-28	2018-07-03	Chevron Phillips Chemical Company Lp	Mixed decyl mercaptans compositions and methods of making same
US9512071B1 (en)	2015-12-28	2016-12-06	Chevron Phillips Chemical Company Lp	Mixed decyl mercaptans compositions and methods of making same
US9512248B1 (en)	2015-12-28	2016-12-06	Chevron Phillips Chemical Company Lp	Mixed decyl mercaptans compositions and use thereof as chain transfer agents
CN106179767B (zh) *	2016-09-23	2018-04-03	中南大学	一种1，3，4‑噁二唑‑2‑硫酮类浮选捕收剂的应用
CN108057525A (zh) *	2017-11-27	2018-05-22	西北矿冶研究院	一种用于低品位铜矿及铜钼矿提高伴生金的浮选捕收剂及其制备方法
CN108499723B (zh) *	2018-03-06	2020-12-15	昆明理工大学	一种含砷硫精矿除砷及资源综合利用方法
CN109622234B (zh) *	2018-11-16	2021-04-20	西北矿冶研究院	一种适用于尾矿分级再磨的硫化铜矿组合捕收剂
CN109550598B (zh) *	2018-11-21	2019-09-24	中南大学	一种烃氧基丙基硫脲在金属矿浮选中的应用
CN109365138B (zh) *	2018-11-30	2021-03-05	河南城建学院	一种用于硫化铜镍矿浮选的新型复合浮选剂
CN109731693B (zh) *	2019-01-28	2021-09-14	西安建筑科技大学	一种三聚硫氰酸饱和溶液硫化浮选铜铅锌氧化矿的方法
JP7299592B2 (ja) *	2019-11-05	2023-06-28	国立大学法人九州大学	選鉱方法
CN110721817B (zh) *	2019-11-29	2022-05-27	南华大学	一种浮选碳酸铀酰离子的捕收剂及其应用
CN111266195B (zh) *	2020-03-05	2021-09-07	中南大学	一种氧化锌矿浮选组合捕收剂及其应用
AU2021330290A1 (en) *	2020-08-27	2023-03-16	Japan Organization for Metals and Energy Security	Method for selectively recovering arsenic-containing copper mineral, and flotation agent used in same
CN115213016B (zh) *	2021-04-19	2025-02-28	郑州大学	一种氰化尾渣中硫化矿的浮选回收方法
CN113369022B (zh) *	2021-06-08	2023-01-10	金川镍钴研究设计院有限责任公司	一种高钙镁型墨铜矿的选矿方法
CN113477393B (zh) *	2021-08-10	2022-10-28	南华大学	一种从含黄铁矿碳酸盐型铀矿石中浸出铀的方法
CN115254437A (zh) *	2022-07-04	2022-11-01	昆明冶金研究院有限公司	一种相界面调控实现含泥硫化铜钼矿低碱度浮选的方法
JPWO2024172017A1 (fr) *	2023-02-15	2024-08-22
CN116809241A (zh) *	2023-02-24	2023-09-29	昆明冶金研究院有限公司	一种氧硫混合浮选铜矿高效捕收剂及其制备方法与应用
CN117259016B (zh) *	2023-10-31	2025-09-12	中南大学	浮选捕收剂及其制备方法、组合浮选药剂及其应用
CN119186828A (zh) *	2024-09-23	2024-12-27	湖南有色金属研究院有限责任公司	n-甲基-n-戊基硫脲作捕收剂在硫氧混合铜钴矿中的应用及同步浮选方法
CN119425960A (zh) *	2024-11-12	2025-02-14	昆明冶金研究院有限公司	一种适用于高寒地区泥质斑岩铜矿的高效起泡剂及其制备方法
CN119951669B (zh) *	2025-03-24	2025-10-17	昆明理工大学	一种酸性条件下反浮选胶磷矿的捕收剂及其制备方法

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US1774183A (en) *	1927-05-13	1930-08-26	Barrett Co	Concentration of minerals
FR2534492A1 (fr) *	1982-10-13	1984-04-20	Elf Aquitaine	Perfectionnement a la flottation de minerais

1986
- 1986-02-14 ES ES552027A patent/ES8800077A1/es not_active Expired
- 1986-02-14 CA CA000501884A patent/CA1270076A/fr not_active Expired - Lifetime
- 1986-02-14 PH PH33415A patent/PH23738A/en unknown
- 1986-02-17 YU YU23286A patent/YU45768B/sh unknown
- 1986-02-17 CN CN86101682A patent/CN1011765B/zh not_active Expired
- 1986-02-17 ZW ZW40/86A patent/ZW4086A1/xx unknown
- 1986-02-17 ZM ZM12/86A patent/ZM1286A1/xx unknown
- 1986-02-17 ZA ZA861169A patent/ZA861169B/xx unknown
- 1986-02-17 PL PL1986257991A patent/PL147849B1/pl unknown
- 1986-02-18 RO RO12682086A patent/RO100591B1/ro unknown
- 1986-02-18 AU AU54564/86A patent/AU576665B2/en not_active Expired
- 1986-02-18 BR BR8606705A patent/BR8606705A/pt not_active IP Right Cessation
- 1986-02-18 WO PCT/US1986/000350 patent/WO1986006983A1/fr not_active Ceased
- 1986-09-03 JP JP61207632A patent/JPS63100961A/ja active Pending
1987
- 1987-01-28 FI FI870368A patent/FI80834C/fi not_active IP Right Cessation
- 1987-01-30 SE SE8700376A patent/SE500499C2/sv unknown
- 1987-01-30 SU SU4028936A patent/SU1582978A3/ru active

Also Published As

Publication number	Publication date
CN86101682A (zh)	1987-01-28
AU5456486A (en)	1986-12-24
ES8800077A1 (es)	1987-10-16
ZW4086A1 (en)	1987-09-09
FI80834B (fi)	1990-04-30
FI870368A0 (fi)	1987-01-28
FI870368A7 (fi)	1987-01-28
ZA861169B (en)	1987-10-28
RO100591B1 (en)	1992-01-28
SE8700376L (sv)	1987-01-30
BR8606705A (pt)	1987-08-11
PL257991A1 (en)	1987-12-14
YU45768B (sh)	1992-07-20
PH23738A (en)	1989-11-03
JPS63100961A (ja)	1988-05-06
YU23286A (en)	1988-06-30
WO1986006983A1 (fr)	1986-12-04
AU576665B2 (en)	1988-09-01
PL147849B1 (en)	1989-08-31
ES552027A0 (es)	1987-10-16
SU1582978A3 (ru)	1990-07-30
SE500499C2 (sv)	1994-07-04
ZM1286A1 (en)	1988-12-30
CN1011765B (zh)	1991-02-27
FI80834C (fi)	1990-08-10
SE8700376D0 (sv)	1987-01-30

Publication	Publication Date	Title
CA1270076A (fr)	1990-06-05	Capteurs pour la flottation selective sur mousse de minerais sulfures
EP0174866B1 (fr)	1993-03-10	Collecteurs pour la flottation à mousse de minérais enrichis
US5057209A (en)	1991-10-15	Depression of the flotation of silica or siliceous gangue in mineral flotation
US4684459A (en)	1987-08-04	Collector compositions for the froth flotation of mineral values
CA2014882C (fr)	1996-02-20	Diminution de la flottation du silice ou de la gangue siliceuse dans la flottation des minerais
US4797202A (en)	1989-01-10	Froth flotation method
AU588579B2 (en)	1989-09-21	Collector compositions for the froth flotation of mineral values
US4582596A (en)	1986-04-15	Frothers demonstrating enhanced recovery of coarse particles in froth floatation
AU586471B2 (en)	1989-07-13	Collectors for froth flotation
US5173176A (en)	1992-12-22	Dialkylated aryl monosulfonate collectors useful in the flotation of minerals
US4822483A (en)	1989-04-18	Collector compositions for the froth flotation of mineral values
CA1267979A (fr)	1990-04-17	Composition de captage pour separateur par flottation sur mousse
US5126038A (en)	1992-06-30	Process for improved precious metals recovery from ores with the use of alkylhydroxamate collectors
US4676890A (en)	1987-06-30	Collector compositions for the froth flotation of mineral values
US4793852A (en)	1988-12-27	Process for the recovery of non-ferrous metal sulfides
US4702822A (en)	1987-10-27	Novel collector composition for froth flotation
US4735711A (en)	1988-04-05	Novel collectors for the selective froth flotation of mineral sulfides
US3827557A (en)	1974-08-06	Method of copper sulfide ore flotation
US4511464A (en)	1985-04-16	1,3-Oxathiolane-2-thiones as sulfide mineral collectors in froth flotation
US4789392A (en)	1988-12-06	Froth flotation method
US4732668A (en)	1988-03-22	Novel collectors for the selective froth flotation of mineral sulfides
CA1310145C (fr)	1992-11-10	Flottation de minerais et agents de flottation de mineraux utilises a cette fin
USRE32778E (en)	1988-11-08	Frothers demonstrating enhanced recovery of coarse particles in froth floatation
CA1271273A (fr)	1990-07-03	Collecteurs pour la flottation sur mousse des minerais
NO168992B (no)	1992-01-20	Fremgangsmaate for utvinning av metallholdige sulfidmineraler eller sulfifiserte metallholdige oksydmineraler fra enmalm

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2007-06-05	MKEX	Expiry