BRPI0910458A2 - catalisador para preparar acroleína ou ácido acrílico por reação de desidratação de glicerina e método para produzir o mesmo - Google Patents
catalisador para preparar acroleína ou ácido acrílico por reação de desidratação de glicerina e método para produzir o mesmoInfo
- Publication number
- BRPI0910458A2 BRPI0910458A2 BRPI0910458A BRPI0910458A BRPI0910458A2 BR PI0910458 A2 BRPI0910458 A2 BR PI0910458A2 BR PI0910458 A BRPI0910458 A BR PI0910458A BR PI0910458 A BRPI0910458 A BR PI0910458A BR PI0910458 A2 BRPI0910458 A2 BR PI0910458A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- produce
- acrylic acid
- same
- dehydration reaction
- Prior art date
Links
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 title 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 238000006297 dehydration reaction Methods 0.000 title 1
- 235000011187 glycerol Nutrition 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008107352 | 2008-04-16 | ||
| PCT/JP2009/057819 WO2009136537A1 (ja) | 2008-04-16 | 2009-04-14 | グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0910458A2 true BRPI0910458A2 (pt) | 2018-03-27 |
Family
ID=41264593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0910458A BRPI0910458A2 (pt) | 2008-04-16 | 2009-04-14 | catalisador para preparar acroleína ou ácido acrílico por reação de desidratação de glicerina e método para produzir o mesmo |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20110112330A1 (pt) |
| EP (1) | EP2275204A4 (pt) |
| JP (1) | JP5297450B2 (pt) |
| KR (1) | KR20110011603A (pt) |
| CN (2) | CN102066001B (pt) |
| BR (1) | BRPI0910458A2 (pt) |
| MY (1) | MY176982A (pt) |
| WO (1) | WO2009136537A1 (pt) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009127889A1 (en) * | 2008-04-16 | 2009-10-22 | Arkema France | Process for manufacturing acrolein from glycerol |
| FR2939791B1 (fr) | 2008-12-16 | 2011-01-14 | Adisseo France Sas | Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute |
| SG179188A1 (en) | 2009-09-18 | 2012-04-27 | Nippon Kayaku Kk | Catalyst and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin |
| WO2011046232A1 (en) * | 2009-10-15 | 2011-04-21 | Nippon Kayaku Kabushiki Kaisha | Process for preparing catalyst used in production of unsaturated aldehyde and/or unsaturated carboxylic acid by dehydration reaction of glycerin, and catalyst obtained |
| CN102781579A (zh) * | 2010-03-31 | 2012-11-14 | 株式会社日本触媒 | 甘油脱水用催化剂以及使用该催化剂的丙烯醛的制备方法和丙烯酸的制备方法及亲水性树脂的制备方法 |
| FR2961507B1 (fr) * | 2010-06-17 | 2016-03-04 | Adisseo France Sas | Procede de preparation d'acroleine a partir de glycerol ou de glycerine |
| EP2591854A1 (en) * | 2010-07-09 | 2013-05-15 | Nippon Kayaku Kabushiki Kaisha | Novel glycerol dehydration catalyst and production method therefor |
| KR101268461B1 (ko) * | 2011-04-14 | 2013-06-04 | 서울대학교산학협력단 | 글리세롤의 탈수반응을 통한 아크롤레인 생산 반응용 촉매 및 그 제조방법 |
| KR101268459B1 (ko) * | 2011-04-14 | 2013-06-04 | 서울대학교산학협력단 | 글리세롤의 탈수반응을 통한 아크롤레인 생산 반응용 촉매 및 그 제조방법 |
| WO2013008279A1 (en) | 2011-07-14 | 2013-01-17 | Nippon Kayaku Kabushiki Kaisha | Process for preparing catalyst used in production of acrolein and/or acrylic acid and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin |
| WO2013017904A1 (en) * | 2011-07-29 | 2013-02-07 | Arkema France | Improved process of dehydration reactions |
| JPWO2013018752A1 (ja) * | 2011-07-29 | 2015-03-05 | 日本化薬株式会社 | グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造法 |
| KR101369924B1 (ko) * | 2011-12-20 | 2014-03-06 | 서울대학교산학협력단 | 열린 기공 구조를 갖는 구형의 실리카 담체에 담지된 헤테로폴리산 촉매 및 이를 이용한 아크롤레인 제조방법 |
| CN102659540A (zh) * | 2012-04-28 | 2012-09-12 | 江苏大学 | 一种杂多酸碱金属盐催化甘油液相脱水制备丙烯醛的方法 |
| JP2013040179A (ja) * | 2012-09-14 | 2013-02-28 | Nippon Kayaku Co Ltd | グリセリンの脱水反応によってアクロレインおよび／またはアクリル酸を製造するための触媒および方法 |
| KR101616528B1 (ko) * | 2013-07-16 | 2016-04-28 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법 |
| WO2015046716A1 (ko) * | 2013-09-30 | 2015-04-02 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법 |
| KR101606191B1 (ko) | 2013-09-30 | 2016-03-24 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법 |
| KR20150055402A (ko) | 2013-11-13 | 2015-05-21 | 주식회사 엘지화학 | 글리세린 탈수반응용 촉매의 제조 방법 및 아크롤레인의 제조 방법 |
| KR101774543B1 (ko) * | 2014-12-19 | 2017-09-04 | 주식회사 엘지화학 | 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법 |
| WO2016099066A1 (ko) * | 2014-12-19 | 2016-06-23 | 주식회사 엘지화학 | 글리세린 탈수 반응용 촉매， 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법 |
| WO2017070874A1 (zh) * | 2015-10-29 | 2017-05-04 | 北华大学 | 一种催化木质纤维素定向转化多酸催化剂 |
| KR102052708B1 (ko) * | 2015-12-22 | 2019-12-09 | 주식회사 엘지화학 | 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법 |
| CN106944144B (zh) * | 2016-01-07 | 2019-07-12 | 中国石油化工股份有限公司 | 杂多酸铵型催化剂的制备方法 |
| CN110505917B (zh) * | 2017-03-31 | 2023-06-06 | 三菱化学株式会社 | 不饱和羧酸制造用催化剂、不饱和羧酸的制造方法和不饱和羧酸酯的制造方法 |
| EP3608305A1 (en) | 2018-08-10 | 2020-02-12 | Röhm GmbH | Process for producing methacrylic acid or methacrylic acid esters |
| CN109603870B (zh) * | 2018-12-20 | 2021-04-20 | 大连理工大学 | 一种双金属取代固体杂多酸盐复合催化剂的制备与应用 |
| EP4655277A1 (en) | 2023-01-25 | 2025-12-03 | Universität Hamburg | Liquid phase process for preparing acrylic acid from glycerol |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2558520A (en) | 1948-01-29 | 1951-06-26 | Us Ind Chemicals Inc | Production of acrolein from glycerol |
| JP2947602B2 (ja) | 1990-09-27 | 1999-09-13 | 昭和電工株式会社 | 低級脂肪酸エステルの製造方法 |
| DE69206781T2 (de) * | 1992-03-25 | 1996-08-22 | Showa Denko Kk | Verfahren zum Herstellen von niedrigen Fettsäureestern |
| EP0562139B1 (en) * | 1992-03-25 | 1995-12-13 | Showa Denko Kabushiki Kaisha | Process for preparation of lower fatty acid ester |
| DE4238493C1 (de) * | 1992-11-14 | 1994-04-21 | Degussa | Verfahren zur Herstellung von Acrolein und dessen Verwendung |
| US5919725A (en) * | 1993-11-19 | 1999-07-06 | Exxon Research And Engineering Co. | Heteropoly salts or acid salts deposited in the interior of porous supports |
| US5710225A (en) * | 1996-08-23 | 1998-01-20 | The Lubrizol Corporation | Heteropolyacid catalyzed polymerization of olefins |
| JP3767309B2 (ja) * | 2000-03-07 | 2006-04-19 | 住友化学株式会社 | ヘテロポリ酸系触媒の製造方法およびメタクリル酸の製造方法 |
| KR100413801B1 (ko) * | 2001-10-30 | 2004-01-03 | 삼성전자주식회사 | 전도성 무기 나노 입자 함유 고분자 전해질 및 이를채용한 연료전지 |
| JP2005131470A (ja) * | 2003-10-28 | 2005-05-26 | Nippon Shokubai Co Ltd | 金属微粒子担持体 |
| JP4649610B2 (ja) | 2004-09-15 | 2011-03-16 | 国立大学法人名古屋大学 | エステル化触媒及びエステル製造方法 |
| GB0427021D0 (en) * | 2004-12-09 | 2005-01-12 | Bp Chem Int Ltd | Process |
| FR2882052B1 (fr) | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acroleine |
| FR2882053B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acrolene |
| JP4909526B2 (ja) | 2005-04-12 | 2012-04-04 | 花王株式会社 | アクロレインの製造方法 |
| WO2007058221A1 (ja) | 2005-11-15 | 2007-05-24 | Nippon Shokubai Co., Ltd. | 多価アルコールの脱水方法 |
-
2009
- 2009-04-14 KR KR1020107022895A patent/KR20110011603A/ko not_active Withdrawn
- 2009-04-14 EP EP09742662A patent/EP2275204A4/en not_active Withdrawn
- 2009-04-14 BR BRPI0910458A patent/BRPI0910458A2/pt not_active IP Right Cessation
- 2009-04-14 JP JP2010511039A patent/JP5297450B2/ja active Active
- 2009-04-14 WO PCT/JP2009/057819 patent/WO2009136537A1/ja not_active Ceased
- 2009-04-14 CN CN2009801227861A patent/CN102066001B/zh not_active Expired - Fee Related
- 2009-04-14 US US12/988,043 patent/US20110112330A1/en not_active Abandoned
- 2009-04-14 MY MYPI2010004881A patent/MY176982A/en unknown
- 2009-04-14 CN CN201310421272.4A patent/CN103521250A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20110112330A1 (en) | 2011-05-12 |
| EP2275204A1 (en) | 2011-01-19 |
| WO2009136537A1 (ja) | 2009-11-12 |
| EP2275204A4 (en) | 2011-09-28 |
| JPWO2009136537A1 (ja) | 2011-09-08 |
| CN103521250A (zh) | 2014-01-22 |
| KR20110011603A (ko) | 2011-02-08 |
| CN102066001A (zh) | 2011-05-18 |
| MY176982A (en) | 2020-08-31 |
| CN102066001B (zh) | 2013-10-23 |
| JP5297450B2 (ja) | 2013-09-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 7A, 8A E 9A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |