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BRPI0916175A8 - Composição de procatalisador, composição de catalisador e processo para produzir um polímero baseado em olefina - Google Patents

Composição de procatalisador, composição de catalisador e processo para produzir um polímero baseado em olefina

Info

Publication number
BRPI0916175A8
BRPI0916175A8 BRPI0916175A BRPI0916175A BRPI0916175A8 BR PI0916175 A8 BRPI0916175 A8 BR PI0916175A8 BR PI0916175 A BRPI0916175 A BR PI0916175A BR PI0916175 A BRPI0916175 A BR PI0916175A BR PI0916175 A8 BRPI0916175 A8 BR PI0916175A8
Authority
BR
Brazil
Prior art keywords
electron donor
composition
olefin
component
producing
Prior art date
Application number
BRPI0916175A
Other languages
English (en)
Inventor
Chen Linfeng
Original Assignee
Union Carbide Chem Plastic
Grace W R & Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic, Grace W R & Co filed Critical Union Carbide Chem Plastic
Publication of BRPI0916175A2 publication Critical patent/BRPI0916175A2/pt
Publication of BRPI0916175A8 publication Critical patent/BRPI0916175A8/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/656Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651Pretreating with non-metals or metal-free compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04Broad molecular weight distribution, i.e. Mw/Mn > 6

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

COMPOSIÇÃO DE PROCATALISADOR, COMPOSIÇÃO DE CATALISADOR E PROCESSO PARA PRODUZIR UM POLÍMERO BASEADO EM OLEFINA. É provida uma composição de procatalisador contendo um doador de elétrons ínterno múltiplo com pelo menos dois componentes, um dos quais sendo um éster de silíla. O outro componente do doador de elétrons interno misto poderá ser um componente doador de elétrons. O componente doador de elétrons poderá ser um éster de ácido aromático, um di-éter, e combinações destes. Composíções de catalisador contendo o doador de elétrons interno múltiplo exibem resposta a hidrogênio melhorada durante a polimerização da olefina e produzem polimeros baseados em propileno com ampla distribuição de peso molecular, alto módulo flexional, e alta taxa de fluxo de fundido.
BRPI0916175A 2008-11-25 2009-11-23 Composição de procatalisador, composição de catalisador e processo para produzir um polímero baseado em olefina BRPI0916175A8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11776308P 2008-11-25 2008-11-25
PCT/US2009/065461 WO2010065359A1 (en) 2008-11-25 2009-11-23 Procatalyst composition multiple internal donor having silyl ester and method

Publications (2)

Publication Number Publication Date
BRPI0916175A2 BRPI0916175A2 (pt) 2015-11-03
BRPI0916175A8 true BRPI0916175A8 (pt) 2017-09-19

Family

ID=41698383

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0916175A BRPI0916175A8 (pt) 2008-11-25 2009-11-23 Composição de procatalisador, composição de catalisador e processo para produzir um polímero baseado em olefina

Country Status (11)

Country Link
US (1) US8222357B2 (pt)
EP (1) EP2350143B1 (pt)
JP (2) JP6097480B2 (pt)
KR (1) KR101589779B1 (pt)
CN (1) CN102292358B (pt)
BR (1) BRPI0916175A8 (pt)
MX (1) MX2011005543A (pt)
MY (1) MY162815A (pt)
RU (1) RU2497834C2 (pt)
SG (1) SG171397A1 (pt)
WO (1) WO2010065359A1 (pt)

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US8288585B2 (en) 2008-12-31 2012-10-16 Dow Global Technologies Llc Procatalyst composition with substitute 1,2-phenylene aromatic diester internal donor and method
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US9790291B2 (en) 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
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WO2015177733A2 (en) * 2014-05-20 2015-11-26 Reliance Industries Limited A polyolefin and a process for preparing the same
US9593184B2 (en) 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
US10246529B2 (en) 2015-01-21 2019-04-02 Sabic Global Technologies B.V. Procatalyst for polymerization of olefins
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
KR20190057289A (ko) 2016-08-30 2019-05-28 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. 저회분 함량의 폴리올레핀들 및 그 제조방법
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US10822438B2 (en) 2017-05-09 2020-11-03 Formosa Plastics Corporation Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
US10124324B1 (en) 2017-05-09 2018-11-13 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
CA3200737A1 (en) * 2020-12-07 2022-06-16 Jan W. Van Egmond Polypropylene polymer for producing biaxially oriented films and other articles
CN115433296B (zh) * 2021-06-03 2024-04-05 中国科学院化学研究所 一种催化剂组合物及其在烯烃聚合中的应用
CN115607998B (zh) * 2022-09-27 2025-08-12 洛阳中硅高科技有限公司 硅基电子化学品的提纯装置与方法
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US20250066514A1 (en) 2023-08-24 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors
US20250115687A1 (en) 2023-10-06 2025-04-10 Formosa Plastics Corporation, U.S.A. Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins
US20250115686A1 (en) 2023-10-09 2025-04-10 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate
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Also Published As

Publication number Publication date
MX2011005543A (es) 2011-06-17
RU2011126140A (ru) 2013-01-10
KR20110094086A (ko) 2011-08-19
CN102292358A (zh) 2011-12-21
KR101589779B1 (ko) 2016-01-28
MY162815A (en) 2017-07-31
JP6130436B2 (ja) 2017-05-17
EP2350143A1 (en) 2011-08-03
CN102292358B (zh) 2014-04-30
EP2350143B1 (en) 2016-02-17
JP2012509963A (ja) 2012-04-26
US8222357B2 (en) 2012-07-17
JP6097480B2 (ja) 2017-03-15
SG171397A1 (en) 2011-07-28
US20100130710A1 (en) 2010-05-27
JP2015155557A (ja) 2015-08-27
WO2010065359A1 (en) 2010-06-10
RU2497834C2 (ru) 2013-11-10
BRPI0916175A2 (pt) 2015-11-03

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