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BRPI0819602A2 - Processo para produzir gás de síntese de amônia - Google Patents

Processo para produzir gás de síntese de amônia

Info

Publication number
BRPI0819602A2
BRPI0819602A2 BRPI0819602A BRPI0819602A2 BR PI0819602 A2 BRPI0819602 A2 BR PI0819602A2 BR PI0819602 A BRPI0819602 A BR PI0819602A BR PI0819602 A2 BRPI0819602 A2 BR PI0819602A2
Authority
BR
Brazil
Prior art keywords
synthesis gas
ammonia synthesis
producing ammonia
producing
gas
Prior art date
Application number
Other languages
English (en)
Inventor
Filippi
Ermanno
Badano
Marco
Skinner
Geoffrey Frederick
Original Assignee
Ammonia Casale Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=39336540&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0819602(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ammonia Casale Sa filed Critical Ammonia Casale Sa
Publication of BRPI0819602A2 publication Critical patent/BRPI0819602A2/pt
Publication of BRPI0819602B1 publication Critical patent/BRPI0819602B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025Preparation or purification of gas mixtures for ammonia synthesis
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Multi-step processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415Purification by absorption in liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435Catalytic purification
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/068Ammonia synthesis
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/146At least two purification steps in series
    • C01B2203/147Three or more purification steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00Ammonia; Compounds thereof
    • C01C1/02Preparation, purification or separation of ammonia
    • C01C1/04Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
BRPI0819602A 2007-11-27 2008-11-06 processo para produzir gás de síntese de amônia BRPI0819602B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07022984A EP2065337A1 (en) 2007-11-27 2007-11-27 Process for producing ammonia synthesis gas
PCT/EP2008/009341 WO2009068159A1 (en) 2007-11-27 2008-11-06 Process for producing ammonia synthesis gas

Publications (2)

Publication Number Publication Date
BRPI0819602A2 true BRPI0819602A2 (pt) 2015-05-05
BRPI0819602B1 BRPI0819602B1 (pt) 2018-12-11

Family

ID=39336540

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0819602A BRPI0819602B1 (pt) 2007-11-27 2008-11-06 processo para produzir gás de síntese de amônia

Country Status (14)

Country Link
US (1) US9040011B2 (pt)
EP (2) EP2065337A1 (pt)
CN (1) CN101878181A (pt)
AR (1) AR069469A1 (pt)
AU (1) AU2008329268B2 (pt)
BR (1) BRPI0819602B1 (pt)
CA (1) CA2706394C (pt)
CL (1) CL2008003512A1 (pt)
DK (1) DK2227435T3 (pt)
MX (1) MX2010005316A (pt)
MY (1) MY151596A (pt)
RU (1) RU2478564C2 (pt)
UA (1) UA98178C2 (pt)
WO (1) WO2009068159A1 (pt)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100037521A1 (en) * 2008-08-13 2010-02-18 L'Air Liquide Societe Anonyme Pour L'Etude et l'Exploitatation Des Procedes Georges Claude Novel Steam Reformer Based Hydrogen Plant Scheme for Enhanced Carbon Dioxide Recovery
EP2404869A1 (en) 2010-07-06 2012-01-11 Ammonia Casale S.A. Process for producing ammonia synthesis gas
EP2502881A1 (en) 2011-03-24 2012-09-26 Urea Casale S.A. Process and plant for ammonia-urea production
EP2631213A1 (en) 2012-02-24 2013-08-28 Ammonia Casale S.A. Process for producing ammonia synthesis gas and a related front-end of an ammonia plant
EP2662327A1 (en) * 2012-05-07 2013-11-13 Ammonia Casale S.A. Method of revamping of an ammonia plant fed with natural gas
EP2867484B1 (en) * 2012-06-27 2020-02-12 Grannus, LLC Polygeneration production of power and fertilizer through emissions capture
EP2801550A1 (en) 2013-05-10 2014-11-12 Ammonia Casale S.A. A process for producing ammonia synthesis gas with high temperature shift and low steam-to-carbon ratio
CN103303863A (zh) * 2013-06-13 2013-09-18 黄家鹄 由焦炉气制取氨合成气的方法
EP2818447A1 (en) 2013-06-26 2014-12-31 Ammonia Casale S.A. A process for purification of a synthesis gas containing hydrogen and impurities
EP2886513A1 (en) 2013-12-20 2015-06-24 Casale Sa Process for producing ammonia synthesis gas
US9475696B2 (en) * 2014-02-24 2016-10-25 Linde Aktiengesellschaft Methods for producing synthesis gas for ammonia production
EP2957544A1 (en) 2014-06-18 2015-12-23 Casale SA Process for production of ammonia and derivatives, in particular urea
EP2993158A1 (en) 2014-09-05 2016-03-09 Casale SA Process for production of ammonia and derivatives, in particular urea
EP3018094A1 (en) 2014-11-06 2016-05-11 Casale SA Process for producing a synthesis gas
EP3050849A1 (en) 2015-01-27 2016-08-03 Casale SA A process for the synthesis of ammonia
EP3059210A1 (en) 2015-02-20 2016-08-24 Casale SA Process for the ammonia production
EP3095760A1 (en) 2015-05-21 2016-11-23 Casale SA A method for increasing the capacity of an ammonia plant
EP3156363A1 (en) * 2015-10-15 2017-04-19 Casale SA Process for making a synthesis gas by reforming of a hydrocarbon and including recovery of carbon dioxide at high pressure
CA3007124A1 (en) 2015-12-04 2017-06-08 Grannus, Llc Polygeneration production of hydrogen for use in various industrial processes
EP3241804A1 (en) 2016-05-03 2017-11-08 Casale SA Process for producing a synthesis gas
MY193298A (en) 2016-11-09 2022-10-03 8 Rivers Capital Llc Systems and methods for power production with integrated production of hydrogen
GB201705487D0 (en) * 2017-04-05 2017-05-17 Johnson Matthey Plc Process
UA127081C2 (uk) 2017-07-13 2023-04-05 Хальдор Топсьое А/С Спосіб отримання газу для синтезу аміаку
CN114538376B (zh) 2017-11-09 2024-07-30 八河流资产有限责任公司 用于生产和分离氢气和二氧化碳的系统和方法
EP3623343A1 (en) 2018-09-11 2020-03-18 Casale Sa Process for the synthesis of ammonia
CN112823139B (zh) * 2018-10-15 2024-02-13 国立研究开发法人产业技术综合研究所 使用了二氧化碳的氨化学种脱附方法、氨化学种供给剂以及氨化学种吸附/脱附装置
CN109704279B (zh) * 2019-03-12 2022-05-17 西南化工研究设计院有限公司 一种烃类转化制取合成气的方法及系统
US11859517B2 (en) 2019-06-13 2024-01-02 8 Rivers Capital, Llc Power production with cogeneration of further products
MX2024006066A (es) 2021-11-18 2024-07-19 8 Rivers Capital Llc Aparato para la produccion de hidrogeno.
US12358792B2 (en) 2023-10-09 2025-07-15 8 Rivers Capital, Llc Systems and methods for producing hydrogen with integrated capture of carbon dioxide

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2789094A (en) * 1952-02-20 1957-04-16 Texas Co Manufacture of synthesis gas
GB991523A (en) * 1963-08-14 1965-05-12 Pullman Inc Production of hydrogen-containing gases particularly useful for ammonia synthesis
DE1920001A1 (de) * 1969-04-19 1970-12-17 Metallgesellschaft Ag Verfahren zur Erzeugung eines Synthesegases fuer die Herstellung von Ammoniak
SU784148A1 (ru) * 1977-11-17 1986-07-15 Sosna M Kh Способ двухступенчатой каталитической конверсии углеводородного сырь
FR2473032A1 (fr) * 1980-01-07 1981-07-10 Banquy David Procede de production d'ammoniac et du gaz de synthese correspondant
IT1129704B (it) * 1980-01-08 1986-06-11 Montedison Spa Processo di sintesi dell'ammoniaca da idrocarburi
IT1141031B (it) * 1980-08-29 1986-10-01 Snam Progetti Procedimento per la preparazione di gas contenenti idrogeno ed azoto
GB8308343D0 (en) * 1983-03-25 1983-05-05 Ici Plc Steam reforming
US4822521A (en) * 1983-06-09 1989-04-18 Uop Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons
US4666680A (en) * 1984-01-30 1987-05-19 Fluor Corporation Autothermal production of synthesis gas
US4578214A (en) * 1984-02-06 1986-03-25 C F Braun & Co. Process for ammonia syngas manufacture
US4572829A (en) * 1984-11-09 1986-02-25 Union Carbide Corporation Ammonia synthesis gas purification
GB8724474D0 (en) * 1987-10-19 1987-11-25 Ici Plc Ammonia synthesis gas
US4792441A (en) * 1988-01-19 1988-12-20 Air Products And Chemicals, Inc. Ammonia synthesis
JPH04503659A (ja) * 1989-10-30 1992-07-02 ゴスダルストベンニ ナウチノ―イススレドバテルスキイ プロエクトニ インスティテュト アゾトノイ プロミシレンノスティ イ プロデュクトフ オルガニチェスコゴ シンテザ アンモニア製造のための窒素―水素気体混合物の製造方法
US5011625A (en) * 1989-12-11 1991-04-30 The M. W. Kellogg Company Autothermal steam reforming process
US5122299A (en) * 1989-12-11 1992-06-16 The M. W. Kellogg Company Autothermal steam reforming process
RU2088517C1 (ru) * 1991-07-16 1997-08-27 Государственный научно-исследовательский и проектный институт химических технологий "Химтехнология" Способ двухступенчатой каталитической конверсии углеводородного сырья
US5736116A (en) * 1995-10-25 1998-04-07 The M. W. Kellogg Company Ammonia production with enriched air reforming and nitrogen injection into the synthesis loop
RU2228901C2 (ru) * 2002-01-09 2004-05-20 Институт нефтехимического синтеза им. А.В. Топчиева РАН Способ получения синтез-газа
EP1698588A1 (en) * 2005-03-04 2006-09-06 Ammonia Casale S.A. Ammonia synthesis process

Also Published As

Publication number Publication date
AU2008329268A1 (en) 2009-06-04
RU2478564C2 (ru) 2013-04-10
EP2227435A1 (en) 2010-09-15
CA2706394A1 (en) 2009-06-04
AR069469A1 (es) 2010-01-27
CA2706394C (en) 2016-01-26
RU2010125773A (ru) 2012-01-10
EP2065337A1 (en) 2009-06-03
WO2009068159A1 (en) 2009-06-04
DK2227435T3 (da) 2013-04-15
CL2008003512A1 (es) 2010-01-15
MY151596A (en) 2014-06-13
MX2010005316A (es) 2010-09-10
AU2008329268B2 (en) 2014-07-24
EP2227435B1 (en) 2013-01-02
US20100303703A1 (en) 2010-12-02
US9040011B2 (en) 2015-05-26
CN101878181A (zh) 2010-11-03
BRPI0819602B1 (pt) 2018-12-11
UA98178C2 (uk) 2012-04-25

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B15K Others concerning applications: alteration of classification

Ipc: C01B 3/02 (2006.01), C01B 3/38 (2006.01), C01B 3/4

B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 11/12/2018, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved

Owner name: CASALE SA (CH)

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 13A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2643 DE 31-08-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.