BRPI0819602A2 - Processo para produzir gás de síntese de amônia - Google Patents
Processo para produzir gás de síntese de amôniaInfo
- Publication number
- BRPI0819602A2 BRPI0819602A2 BRPI0819602A BRPI0819602A2 BR PI0819602 A2 BRPI0819602 A2 BR PI0819602A2 BR PI0819602 A BRPI0819602 A BR PI0819602A BR PI0819602 A2 BRPI0819602 A2 BR PI0819602A2
- Authority
- BR
- Brazil
- Prior art keywords
- synthesis gas
- ammonia synthesis
- producing ammonia
- producing
- gas
- Prior art date
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title 2
- 229910021529 ammonia Inorganic materials 0.000 title 1
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Multi-step processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/068—Ammonia synthesis
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/146—At least two purification steps in series
- C01B2203/147—Three or more purification steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07022984A EP2065337A1 (en) | 2007-11-27 | 2007-11-27 | Process for producing ammonia synthesis gas |
| PCT/EP2008/009341 WO2009068159A1 (en) | 2007-11-27 | 2008-11-06 | Process for producing ammonia synthesis gas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0819602A2 true BRPI0819602A2 (pt) | 2015-05-05 |
| BRPI0819602B1 BRPI0819602B1 (pt) | 2018-12-11 |
Family
ID=39336540
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0819602A BRPI0819602B1 (pt) | 2007-11-27 | 2008-11-06 | processo para produzir gás de síntese de amônia |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9040011B2 (pt) |
| EP (2) | EP2065337A1 (pt) |
| CN (1) | CN101878181A (pt) |
| AR (1) | AR069469A1 (pt) |
| AU (1) | AU2008329268B2 (pt) |
| BR (1) | BRPI0819602B1 (pt) |
| CA (1) | CA2706394C (pt) |
| CL (1) | CL2008003512A1 (pt) |
| DK (1) | DK2227435T3 (pt) |
| MX (1) | MX2010005316A (pt) |
| MY (1) | MY151596A (pt) |
| RU (1) | RU2478564C2 (pt) |
| UA (1) | UA98178C2 (pt) |
| WO (1) | WO2009068159A1 (pt) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100037521A1 (en) * | 2008-08-13 | 2010-02-18 | L'Air Liquide Societe Anonyme Pour L'Etude et l'Exploitatation Des Procedes Georges Claude | Novel Steam Reformer Based Hydrogen Plant Scheme for Enhanced Carbon Dioxide Recovery |
| EP2404869A1 (en) | 2010-07-06 | 2012-01-11 | Ammonia Casale S.A. | Process for producing ammonia synthesis gas |
| EP2502881A1 (en) | 2011-03-24 | 2012-09-26 | Urea Casale S.A. | Process and plant for ammonia-urea production |
| EP2631213A1 (en) | 2012-02-24 | 2013-08-28 | Ammonia Casale S.A. | Process for producing ammonia synthesis gas and a related front-end of an ammonia plant |
| EP2662327A1 (en) * | 2012-05-07 | 2013-11-13 | Ammonia Casale S.A. | Method of revamping of an ammonia plant fed with natural gas |
| EP2867484B1 (en) * | 2012-06-27 | 2020-02-12 | Grannus, LLC | Polygeneration production of power and fertilizer through emissions capture |
| EP2801550A1 (en) | 2013-05-10 | 2014-11-12 | Ammonia Casale S.A. | A process for producing ammonia synthesis gas with high temperature shift and low steam-to-carbon ratio |
| CN103303863A (zh) * | 2013-06-13 | 2013-09-18 | 黄家鹄 | 由焦炉气制取氨合成气的方法 |
| EP2818447A1 (en) | 2013-06-26 | 2014-12-31 | Ammonia Casale S.A. | A process for purification of a synthesis gas containing hydrogen and impurities |
| EP2886513A1 (en) | 2013-12-20 | 2015-06-24 | Casale Sa | Process for producing ammonia synthesis gas |
| US9475696B2 (en) * | 2014-02-24 | 2016-10-25 | Linde Aktiengesellschaft | Methods for producing synthesis gas for ammonia production |
| EP2957544A1 (en) | 2014-06-18 | 2015-12-23 | Casale SA | Process for production of ammonia and derivatives, in particular urea |
| EP2993158A1 (en) | 2014-09-05 | 2016-03-09 | Casale SA | Process for production of ammonia and derivatives, in particular urea |
| EP3018094A1 (en) | 2014-11-06 | 2016-05-11 | Casale SA | Process for producing a synthesis gas |
| EP3050849A1 (en) | 2015-01-27 | 2016-08-03 | Casale SA | A process for the synthesis of ammonia |
| EP3059210A1 (en) | 2015-02-20 | 2016-08-24 | Casale SA | Process for the ammonia production |
| EP3095760A1 (en) | 2015-05-21 | 2016-11-23 | Casale SA | A method for increasing the capacity of an ammonia plant |
| EP3156363A1 (en) * | 2015-10-15 | 2017-04-19 | Casale SA | Process for making a synthesis gas by reforming of a hydrocarbon and including recovery of carbon dioxide at high pressure |
| CA3007124A1 (en) | 2015-12-04 | 2017-06-08 | Grannus, Llc | Polygeneration production of hydrogen for use in various industrial processes |
| EP3241804A1 (en) | 2016-05-03 | 2017-11-08 | Casale SA | Process for producing a synthesis gas |
| MY193298A (en) | 2016-11-09 | 2022-10-03 | 8 Rivers Capital Llc | Systems and methods for power production with integrated production of hydrogen |
| GB201705487D0 (en) * | 2017-04-05 | 2017-05-17 | Johnson Matthey Plc | Process |
| UA127081C2 (uk) | 2017-07-13 | 2023-04-05 | Хальдор Топсьое А/С | Спосіб отримання газу для синтезу аміаку |
| CN114538376B (zh) | 2017-11-09 | 2024-07-30 | 八河流资产有限责任公司 | 用于生产和分离氢气和二氧化碳的系统和方法 |
| EP3623343A1 (en) | 2018-09-11 | 2020-03-18 | Casale Sa | Process for the synthesis of ammonia |
| CN112823139B (zh) * | 2018-10-15 | 2024-02-13 | 国立研究开发法人产业技术综合研究所 | 使用了二氧化碳的氨化学种脱附方法、氨化学种供给剂以及氨化学种吸附/脱附装置 |
| CN109704279B (zh) * | 2019-03-12 | 2022-05-17 | 西南化工研究设计院有限公司 | 一种烃类转化制取合成气的方法及系统 |
| US11859517B2 (en) | 2019-06-13 | 2024-01-02 | 8 Rivers Capital, Llc | Power production with cogeneration of further products |
| MX2024006066A (es) | 2021-11-18 | 2024-07-19 | 8 Rivers Capital Llc | Aparato para la produccion de hidrogeno. |
| US12358792B2 (en) | 2023-10-09 | 2025-07-15 | 8 Rivers Capital, Llc | Systems and methods for producing hydrogen with integrated capture of carbon dioxide |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2789094A (en) * | 1952-02-20 | 1957-04-16 | Texas Co | Manufacture of synthesis gas |
| GB991523A (en) * | 1963-08-14 | 1965-05-12 | Pullman Inc | Production of hydrogen-containing gases particularly useful for ammonia synthesis |
| DE1920001A1 (de) * | 1969-04-19 | 1970-12-17 | Metallgesellschaft Ag | Verfahren zur Erzeugung eines Synthesegases fuer die Herstellung von Ammoniak |
| SU784148A1 (ru) * | 1977-11-17 | 1986-07-15 | Sosna M Kh | Способ двухступенчатой каталитической конверсии углеводородного сырь |
| FR2473032A1 (fr) * | 1980-01-07 | 1981-07-10 | Banquy David | Procede de production d'ammoniac et du gaz de synthese correspondant |
| IT1129704B (it) * | 1980-01-08 | 1986-06-11 | Montedison Spa | Processo di sintesi dell'ammoniaca da idrocarburi |
| IT1141031B (it) * | 1980-08-29 | 1986-10-01 | Snam Progetti | Procedimento per la preparazione di gas contenenti idrogeno ed azoto |
| GB8308343D0 (en) * | 1983-03-25 | 1983-05-05 | Ici Plc | Steam reforming |
| US4822521A (en) * | 1983-06-09 | 1989-04-18 | Uop | Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons |
| US4666680A (en) * | 1984-01-30 | 1987-05-19 | Fluor Corporation | Autothermal production of synthesis gas |
| US4578214A (en) * | 1984-02-06 | 1986-03-25 | C F Braun & Co. | Process for ammonia syngas manufacture |
| US4572829A (en) * | 1984-11-09 | 1986-02-25 | Union Carbide Corporation | Ammonia synthesis gas purification |
| GB8724474D0 (en) * | 1987-10-19 | 1987-11-25 | Ici Plc | Ammonia synthesis gas |
| US4792441A (en) * | 1988-01-19 | 1988-12-20 | Air Products And Chemicals, Inc. | Ammonia synthesis |
| JPH04503659A (ja) * | 1989-10-30 | 1992-07-02 | ゴスダルストベンニ ナウチノ―イススレドバテルスキイ プロエクトニ インスティテュト アゾトノイ プロミシレンノスティ イ プロデュクトフ オルガニチェスコゴ シンテザ | アンモニア製造のための窒素―水素気体混合物の製造方法 |
| US5011625A (en) * | 1989-12-11 | 1991-04-30 | The M. W. Kellogg Company | Autothermal steam reforming process |
| US5122299A (en) * | 1989-12-11 | 1992-06-16 | The M. W. Kellogg Company | Autothermal steam reforming process |
| RU2088517C1 (ru) * | 1991-07-16 | 1997-08-27 | Государственный научно-исследовательский и проектный институт химических технологий "Химтехнология" | Способ двухступенчатой каталитической конверсии углеводородного сырья |
| US5736116A (en) * | 1995-10-25 | 1998-04-07 | The M. W. Kellogg Company | Ammonia production with enriched air reforming and nitrogen injection into the synthesis loop |
| RU2228901C2 (ru) * | 2002-01-09 | 2004-05-20 | Институт нефтехимического синтеза им. А.В. Топчиева РАН | Способ получения синтез-газа |
| EP1698588A1 (en) * | 2005-03-04 | 2006-09-06 | Ammonia Casale S.A. | Ammonia synthesis process |
-
2007
- 2007-11-27 EP EP07022984A patent/EP2065337A1/en not_active Withdrawn
-
2008
- 2008-06-11 UA UAA201007865A patent/UA98178C2/uk unknown
- 2008-10-28 MY MYPI20084291 patent/MY151596A/en unknown
- 2008-11-06 EP EP08853299A patent/EP2227435B1/en not_active Revoked
- 2008-11-06 CA CA2706394A patent/CA2706394C/en not_active Expired - Fee Related
- 2008-11-06 MX MX2010005316A patent/MX2010005316A/es active IP Right Grant
- 2008-11-06 CN CN2008801180841A patent/CN101878181A/zh active Pending
- 2008-11-06 RU RU2010125773/05A patent/RU2478564C2/ru not_active IP Right Cessation
- 2008-11-06 AU AU2008329268A patent/AU2008329268B2/en not_active Ceased
- 2008-11-06 US US12/744,748 patent/US9040011B2/en not_active Expired - Fee Related
- 2008-11-06 BR BRPI0819602A patent/BRPI0819602B1/pt not_active IP Right Cessation
- 2008-11-06 WO PCT/EP2008/009341 patent/WO2009068159A1/en not_active Ceased
- 2008-11-06 DK DK08853299.9T patent/DK2227435T3/da active
- 2008-11-25 AR ARP080105105A patent/AR069469A1/es active IP Right Grant
- 2008-11-26 CL CL2008003512A patent/CL2008003512A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2008329268A1 (en) | 2009-06-04 |
| RU2478564C2 (ru) | 2013-04-10 |
| EP2227435A1 (en) | 2010-09-15 |
| CA2706394A1 (en) | 2009-06-04 |
| AR069469A1 (es) | 2010-01-27 |
| CA2706394C (en) | 2016-01-26 |
| RU2010125773A (ru) | 2012-01-10 |
| EP2065337A1 (en) | 2009-06-03 |
| WO2009068159A1 (en) | 2009-06-04 |
| DK2227435T3 (da) | 2013-04-15 |
| CL2008003512A1 (es) | 2010-01-15 |
| MY151596A (en) | 2014-06-13 |
| MX2010005316A (es) | 2010-09-10 |
| AU2008329268B2 (en) | 2014-07-24 |
| EP2227435B1 (en) | 2013-01-02 |
| US20100303703A1 (en) | 2010-12-02 |
| US9040011B2 (en) | 2015-05-26 |
| CN101878181A (zh) | 2010-11-03 |
| BRPI0819602B1 (pt) | 2018-12-11 |
| UA98178C2 (uk) | 2012-04-25 |
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